JP2007272175A5 - - Google Patents

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JP2007272175A5
JP2007272175A5 JP2006215700A JP2006215700A JP2007272175A5 JP 2007272175 A5 JP2007272175 A5 JP 2007272175A5 JP 2006215700 A JP2006215700 A JP 2006215700A JP 2006215700 A JP2006215700 A JP 2006215700A JP 2007272175 A5 JP2007272175 A5 JP 2007272175A5
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photosensitive member
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electrophotographic photosensitive
member according
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JP2006215700A
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JP4847251B2 (en
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Claims (8)

導電性支持体上に、該導電性支持体側から電荷発生層および電荷輸送層をこの順に積層してなる電子写真感光体において、
該電荷輸送層が下記式(1)で示される繰り返し構造単位を含有するポリアリレート樹脂および下記式(A)で示される電荷輸送性物質を含有し、かつ、
下記式(1)で示される繰り返し構造単位が、ポリアリレート樹脂の全繰り返し構造単位中、モル比換算で60100%である
ことを特徴とする電子写真感光体。
Figure 2007272175

(式(1)中、R11〜R18およびR21〜R28は、それぞれ独立に、水素原子、アルキル基、アリール基、または、アルコキシ基を示す。Xは、単結合、酸素原子、硫黄原子、または、下記式(2)で示される構造を有する2価の基を示す。
Figure 2007272175

式(2)中、R31およびR32は、それぞれ独立に、水素原子、アルキル基、フッ化アルキル基、アルコキシ基、または、アリール基を示す、あるいは、R31とR32とが結合して形成されるシクロアルキリデン基、または、フルオレニリデン基を示す。
Figure 2007272175

(式(A)中、R41〜R50は、それぞれ独立に、水素原子、アルキル基、または、アルコキシ基を示し、ArおよびArは、それぞれ独立に、置換基を有してもよい芳香族炭化水素基を示し、Yは、酸素原子、硫黄原子、または、下記式(B)で示される構造を有する2価の基を示す。
Figure 2007272175

式(B)中、R51およびR52は、それぞれ独立に、水素原子、アルキル基、フッ化アルキル基、アルコキシ基、または、アリール基を示す、あるいは、R51とR52とが結合して形成されるシクロアルキリデン基、または、フルオレニリデン基を示す。
In the electrophotographic photosensitive member formed by laminating a charge generation layer and a charge transport layer in this order on the conductive support from the conductive support side,
Charge transport layer, polyarylate resin containing a repeating structural unit represented by the following formula (1), and contains a charge-transporting substance represented by the following formula (A), and,
An electrophotographic photoreceptor, wherein the repeating structural unit represented by the following formula (1) is 60 to 100% in terms of molar ratio in all repeating structural units of the polyarylate resin.
Figure 2007272175

(In the formula (1), R 11 to R 18 and R 21 to R 28 each independently represent a hydrogen atom, an alkyl group, an aryl group, or an alkoxy group. X represents a single bond, an oxygen atom, or sulfur. An atom or a divalent group having a structure represented by the following formula (2) is shown.
Figure 2007272175

(In Formula (2), R 31 and R 32 each independently represent a hydrogen atom, an alkyl group, a fluorinated alkyl group, an alkoxy group, or an aryl group, or R 31 and R 32 are bonded to each other. cycloalkylidene group formed Te or, shows a fluorenylidene group.))
Figure 2007272175

(In Formula (A), R 41 to R 50 each independently represent a hydrogen atom, an alkyl group, or an alkoxy group, and Ar 1 and Ar 2 may each independently have a substituent. Represents an aromatic hydrocarbon group, and Y represents an oxygen atom, a sulfur atom, or a divalent group having a structure represented by the following formula (B).
Figure 2007272175

(In formula (B), R 51 and R 52 each independently represent a hydrogen atom, an alkyl group, a fluorinated alkyl group, an alkoxy group, or an aryl group, or R 51 and R 52 are bonded to each other. cycloalkylidene group formed Te or, shows a fluorenylidene group.))
前記電荷輸送層の680nmの波長における透過率が95%以上である請求項1に記載の電子写真感光体。 The electrophotographic photosensitive member according to Motomeko 1 transmittance Ru der 95% or more at a wavelength of 680nm of the charge transport layer. 記式(A)のYが、前記式(B)で示される構造を有する2価の基であり、前記式(B)中の 51 およびR 52 が、51とR52とが結合して形成されるシクロへキシリデン基である請求項1または2に記載の電子写真感光体。 Y in front above formula (A) is a divalent group having a structure represented by the formula (B), R 51 and R 52 in the front above formula (B) is an R 51 and R 52 There electrophotographic photosensitive member according to Motomeko 1 or 2 Ru cyclohexylidene group der cycloheteroalkyl which is formed by bonding. 前記ポリアリレート樹脂に含有される前記式(1)で示される繰り返し構造単位が、前記ポリアリレート樹脂の全繰り返し構造単位中、モル比換算で80100%である請求項1〜のいずれかに記載の電子写真感光体。 The polyarylate resin before following formula contained (1) the repeating structural unit represented by the said polyarylate all repeating in the structural units of the resin, Motomeko 1-3 Ru 80-100% der in molar ratio terms The electrophotographic photosensitive member according to any one of the above. 前記ポリアリレート樹脂の重量平均分子量(Mw)が、80000≦Mw≦300000である請求項1〜のいずれかに記載の電子写真感光体。 Wherein the poly weight average molecular weight of polyarylate resin (Mw) is an electrophotographic photosensitive member according to any of 80000 ≦ Mw ≦ 300000 Der Ru請 Motomeko 1-4. 請求項1〜のいずれかに記載の電子写真感光体、ならびに、帯電手段、現像手段およびクリーニング手段からなる群より選ばれた少なくとも1つの手段を一体に支持し、電子写真装置本体に着脱自在であることを特徴とするプロセスカートリッジ。 The electrophotographic photosensitive member according to any one of claims 1 to 5, and charging means, at least one means selected from the group consisting of the developing means and the cleaning means integrally supported, detachably attached to an electrophotographic apparatus main body Process cartridge characterized by being. 請求項1〜のいずれかに記載の電子写真感光体、帯電手段、露光手段、現像手段、転写手段およびクリーニング手段を有することを特徴とする電子写真装置。 The electrophotographic photosensitive member according to any one of claims 1 to 5, a charging means, an exposure means, a developing means, an electrophotographic apparatus, characterized in that it comprises a transfer means and a cleaning means. 前記露光手段が、前記電子写真感光体に対して波長380〜450nmの光を露光光として照射するための手段である請求項に記載の電子写真装置。 The electrophotographic apparatus according to claim 7 , wherein the exposure unit is a unit for irradiating the electrophotographic photosensitive member with light having a wavelength of 380 to 450 nm as exposure light.
JP2006215700A 2006-03-10 2006-08-08 Electrophotographic photosensitive member, process cartridge, and electrophotographic apparatus Active JP4847251B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2006215700A JP4847251B2 (en) 2006-03-10 2006-08-08 Electrophotographic photosensitive member, process cartridge, and electrophotographic apparatus

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JP2006065903 2006-03-10
JP2006065903 2006-03-10
JP2006215700A JP4847251B2 (en) 2006-03-10 2006-08-08 Electrophotographic photosensitive member, process cartridge, and electrophotographic apparatus

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JP2007272175A JP2007272175A (en) 2007-10-18
JP2007272175A5 true JP2007272175A5 (en) 2009-09-10
JP4847251B2 JP4847251B2 (en) 2011-12-28

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JP4992484B2 (en) * 2006-11-13 2012-08-08 コニカミノルタビジネステクノロジーズ株式会社 Organic photoreceptor, image forming method and image forming apparatus
JP5003446B2 (en) * 2007-12-07 2012-08-15 コニカミノルタビジネステクノロジーズ株式会社 Electrophotographic photoreceptor and image forming method
JP5151546B2 (en) * 2008-02-27 2013-02-27 コニカミノルタビジネステクノロジーズ株式会社 Electrophotographic photoreceptor
JP4663768B2 (en) * 2008-04-15 2011-04-06 シャープ株式会社 Image forming apparatus provided with electrophotographic photosensitive member
JPWO2010024060A1 (en) * 2008-08-25 2012-01-26 コニカミノルタビジネステクノロジーズ株式会社 Electrophotographic photoreceptor and image forming apparatus
KR101782660B1 (en) * 2009-10-19 2017-09-27 이 아이 듀폰 디 네모아 앤드 캄파니 Triarylamine compounds for electronic applications
JP5540687B2 (en) * 2009-12-18 2014-07-02 コニカミノルタ株式会社 Electrophotographic photoreceptor, image forming method and image forming apparatus

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CA1129426A (en) * 1977-11-28 1982-08-10 Suzanne P. Clark Photoconductive compositions
JP3537065B2 (en) * 1996-07-01 2004-06-14 キヤノン株式会社 Electrophotographic photoreceptor, process cartridge and electrophotographic apparatus
JP4200781B2 (en) * 2002-06-20 2008-12-24 三菱化学株式会社 Method for producing electrophotographic photosensitive member
JP4517964B2 (en) * 2004-07-16 2010-08-04 三菱化学株式会社 Electrophotographic photoreceptor
JP4640154B2 (en) * 2004-12-17 2011-03-02 三菱化学株式会社 Electrophotographic photosensitive member, image forming apparatus using the photosensitive member, and electrophotographic cartridge using the photosensitive member
JP4655940B2 (en) * 2005-01-05 2011-03-23 三菱化学株式会社 Electrophotographic photoreceptor
JP4862662B2 (en) * 2006-01-13 2012-01-25 三菱化学株式会社 Electrophotographic photosensitive member, image forming apparatus using the same, and electrophotographic cartridge
JP5040319B2 (en) * 2006-01-13 2012-10-03 三菱化学株式会社 Positively charged electrophotographic photosensitive member, image forming apparatus, image forming method, and electrophotographic photosensitive member cartridge
JP2007213050A (en) * 2006-01-13 2007-08-23 Mitsubishi Chemicals Corp Image forming device
JP5040318B2 (en) * 2006-01-13 2012-10-03 三菱化学株式会社 Photosensitive layer forming coating solution, electrophotographic photosensitive member, electrophotographic photosensitive member cartridge, and image forming apparatus
JP4862663B2 (en) * 2006-01-13 2012-01-25 三菱化学株式会社 Electrophotographic photosensitive member, image forming apparatus using the same, and electrophotographic cartridge
JP4862661B2 (en) * 2006-01-13 2012-01-25 三菱化学株式会社 Photosensitive layer forming coating solution, electrophotographic photosensitive member, electrophotographic photosensitive member cartridge, and image forming apparatus

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