JP2007257972A - Fuel cell system - Google Patents

Fuel cell system Download PDF

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JP2007257972A
JP2007257972A JP2006080015A JP2006080015A JP2007257972A JP 2007257972 A JP2007257972 A JP 2007257972A JP 2006080015 A JP2006080015 A JP 2006080015A JP 2006080015 A JP2006080015 A JP 2006080015A JP 2007257972 A JP2007257972 A JP 2007257972A
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fuel cell
fuel
power generation
fuel gas
gas
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Atsushi Ogino
温 荻野
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Toyota Motor Corp
Aisin Corp
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Aisin Seiki Co Ltd
Toyota Motor Corp
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

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Abstract

<P>PROBLEM TO BE SOLVED: To provide a fuel cell system with a total energy utilization efficiency improved. <P>SOLUTION: The system is provided with a plurality of power generating devices 3 each equipped with a fuel cell 9 generating power by electrochemical reaction between fuel gas and oxidizing gas, and a reformer producing fuel gas supplied to toe the fuel cell 9 with the use of exhaust heat of the latter 9. Each power generating device 3, 3 and a fuel gas station 20 share surplus fuel gas against fuel gas needed for generation of the fuel cell 9 out of the fuel gas produced at the reformer 7. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は、酸化ガス及び燃料ガスの反応により発電する燃料電池を備えた燃料電池システムに関する。   The present invention relates to a fuel cell system including a fuel cell that generates electric power by a reaction between an oxidizing gas and a fuel gas.

近年、酸化ガスと燃料ガスとの電気化学反応によって発電する燃料電池をエネルギ源とした燃料電池システムが注目されている。このような燃料電池システムにおいて、燃料ガスとしての水素と排熱と電力とを複数の設備(コンビニエンスストア、一般家庭、発電所及び水素ステーション等)で共有する技術がある(例えば特許文献1参照)。この技術では、水素は水素、排熱は排熱、電力は電力で、それぞれ別々に共有するようになっている。
特開2004−355838号公報
In recent years, a fuel cell system using a fuel cell that generates power by an electrochemical reaction between an oxidizing gas and a fuel gas as an energy source has attracted attention. In such a fuel cell system, there is a technique for sharing hydrogen as fuel gas, exhaust heat, and electric power among a plurality of facilities (convenience store, general household, power plant, hydrogen station, etc.) (see, for example, Patent Document 1). . In this technology, hydrogen is hydrogen, exhaust heat is exhaust heat, and electric power is electric power.
JP 2004-355838 A

上記した技術の場合、特に排熱を設備間で共有する場合のエネルギーの損失が大きく、全体としてエネルギーを十分に有効利用できていない。   In the case of the above-described technology, energy loss is particularly large when waste heat is shared between facilities, and the energy cannot be effectively utilized as a whole.

本発明は、かかる事情に鑑みてなされたものであり、全体のエネルギー利用効率を向上させることができる燃料電池システムを提供することを目的とする。   The present invention has been made in view of such circumstances, and an object thereof is to provide a fuel cell system capable of improving the overall energy utilization efficiency.

前記目的を達成するため、本発明に係る燃料電池システムは、燃料ガスと酸化ガスとの電気化学反応によって発電する燃料電池と、該燃料電池の排熱を利用して該燃料電池に供給される燃料ガスを生成する改質器と、を有する発電設備を複数備え、前記各発電設備において前記改質器で生成された燃料ガスのうち前記燃料電池の発電に要する燃料ガスに対する余剰燃料ガスを、前記発電設備間あるいは前記発電設備と他の設備との間で共有する。   In order to achieve the above object, a fuel cell system according to the present invention supplies a fuel cell that generates power by an electrochemical reaction between a fuel gas and an oxidizing gas, and supplies the fuel cell using exhaust heat of the fuel cell. A plurality of power generation equipment having a reformer that generates fuel gas, and surplus fuel gas with respect to the fuel gas required for power generation of the fuel cell among the fuel gas generated by the reformer in each power generation equipment, Sharing between the power generation facilities or between the power generation facility and other facilities.

また、本発明に係る燃料電池システム内のガス共有方法は、燃料ガスと酸化ガスとの電気化学反応によって発電する燃料電池と、該燃料電池の排熱を利用して該燃料電池に供給される燃料ガスを生成する改質器と、を有する発電設備を複数備えた燃料電池システム内のガス共有方法であって、前記各発電設備において前記改質器で生成された燃料ガスのうち前記燃料電池の発電に要する燃料ガスに対する余剰燃料ガスを、前記発電設備間あるいは前記発電設備と他の設備との間で共有する。   Further, the gas sharing method in the fuel cell system according to the present invention is supplied to the fuel cell using the fuel cell that generates power by the electrochemical reaction between the fuel gas and the oxidizing gas, and the exhaust heat of the fuel cell. A gas sharing method in a fuel cell system comprising a plurality of power generation equipment having a reformer that generates fuel gas, wherein the fuel cell is a fuel gas generated by the reformer in each power generation equipment. The surplus fuel gas for the fuel gas required for power generation is shared between the power generation facilities or between the power generation facilities and other facilities.

以上の構成によれば、発電設備間あるいは発電設備と他の設備との間(以下、単に「設備間」という。)で共有することによるエネルギー損失が大きい燃料電池の排熱については、同一発電設備内の改質器による燃料ガスの生成に用いることで、その損失を小さく抑えることができ、効率良く利用できることになる。そして、このようにして各発電設備において排熱を効率良く利用して改質器で生成した、設備間での共有でも損失が生じにくい燃料ガスについて、その余剰燃料ガスを設備間で共有する。   According to the above configuration, the same power generation is applied to the exhaust heat of a fuel cell having a large energy loss due to sharing between power generation facilities or between a power generation facility and another facility (hereinafter simply referred to as “between facilities”). By using it for the production | generation of the fuel gas by the reformer in an installation, the loss can be restrained small and it can utilize efficiently. Then, the surplus fuel gas is shared between the facilities for the fuel gas that is generated by the reformer by efficiently using the exhaust heat in each power generation facility in this way and is less likely to be lost even between the facilities.

前記燃料電池としては、例えば固体酸化物型燃料電池の採用が可能である。   For example, a solid oxide fuel cell can be used as the fuel cell.

本発明によれば、全体のエネルギー利用効率を向上させることができる。   According to the present invention, the overall energy utilization efficiency can be improved.

以下、図面を参照して、本発明の一実施形態に係る燃料電池システムについて説明する。   Hereinafter, a fuel cell system according to an embodiment of the present invention will be described with reference to the drawings.

本実施形態に係る燃料電池システム1は、家庭や業務場所(例えば、コンビニエンスストア、銭湯、理容店、レストラン等)である複数の設置場所2,2,…にそれぞれ個別の発電設備3を備えて構成されている。   The fuel cell system 1 according to this embodiment includes individual power generation facilities 3 at a plurality of installation locations 2, 2,... That are homes or business locations (for example, convenience stores, public baths, barber shops, restaurants, etc.). It is configured.

各発電設備3,3,…は、それぞれ、メタン等の炭化水素系燃料からなる原燃料を貯留する原燃料貯留設備5と、この原燃料貯留設備5に配管6を介して接続されこの原燃料貯留設備5からの原燃料を水素リッチな燃料ガスに改質する改質器7と、改質器7に配管8を介して接続されこの改質器7から供給される燃料ガスと酸化ガスである空気との電気化学反応によって発電する定置型の燃料電池9とを有している。   Each of the power generation facilities 3, 3,... Is connected to a raw fuel storage facility 5 that stores a raw fuel made of a hydrocarbon-based fuel such as methane, and the raw fuel storage facility 5 via a pipe 6. A reformer 7 for reforming the raw fuel from the storage facility 5 into a hydrogen-rich fuel gas, and a fuel gas and an oxidant gas connected to the reformer 7 via a pipe 8 and supplied from the reformer 7 It has a stationary fuel cell 9 that generates electricity by an electrochemical reaction with certain air.

そして、各発電設備3,3,…において、燃料電池9は、それぞれ同じ設置場所2に設けられて電力を消費する電気機器類(電力消費装置)10の要求電力に応じて発電する、あるいは、要求電力とは無関係に定格で発電する。   And in each of the power generation facilities 3, 3,..., The fuel cell 9 generates power in accordance with the required power of electric devices (power consuming devices) 10 that are provided at the same installation location 2 and consume power, or Power is generated at the rated value regardless of the required power.

ここで、燃料電池9は、定置型として用いられる発電効率が高い固体酸化物型燃料電池(SOFC)である。この燃料電池9は、作動温度が例えば700℃〜1000℃と高温であるため、発電時に比較的高温となり発熱量が多い。このため、燃料電池9が発生する熱を同じ設置場所2に設けられた給湯機器等の排熱使用機器類11で使用するとともに(図1矢印A参照)、燃料電池9に改質器7を付設して、排熱使用機器類11で使用しない残りの排熱を全面的に改質器7の改質反応の促進に利用するようになっている(図1矢印B参照)。   Here, the fuel cell 9 is a solid oxide fuel cell (SOFC) that is used as a stationary type and has high power generation efficiency. Since this fuel cell 9 has an operating temperature as high as 700 ° C. to 1000 ° C., for example, the fuel cell 9 has a relatively high temperature during power generation and generates a large amount of heat. For this reason, the heat generated by the fuel cell 9 is used in the exhaust heat using equipment 11 such as a hot water supply equipment provided in the same installation place 2 (see arrow A in FIG. 1), and the reformer 7 is attached to the fuel cell 9. In addition, the remaining exhaust heat that is not used in the exhaust heat using equipment 11 is used for promoting the reforming reaction of the reformer 7 entirely (see arrow B in FIG. 1).

そして、上記のような複数の各発電設備3,3,…の改質器7と燃料電池9とを結ぶ配管8からは、それぞれ分岐配管14が分岐しており、これら分岐配管14,14,…が複数の各発電設備3,3,…同士を結ぶ共用配管15に接続されている。   A branch pipe 14 branches from a pipe 8 connecting the reformer 7 and the fuel cell 9 of each of the plurality of power generation facilities 3, 3,..., And the branch pipes 14, 14,. Are connected to a common pipe 15 that connects the plurality of power generation facilities 3, 3,.

また、複数の各発電設備3,3,…において、それぞれ配管8における分岐配管14の分岐位置には、改質器7からの燃料ガスを燃料電池9と分岐配管14とに適宜分配する分配器17が設けられている。さらに、各発電設備3,3,…においては、燃料電池9及び電気機器類10の状態に応じて分配器17を制御する制御装置18が設けられている。   Further, in each of the plurality of power generation facilities 3, 3,..., A distributor that appropriately distributes the fuel gas from the reformer 7 to the fuel cell 9 and the branch pipe 14 at the branch position of the branch pipe 14 in the pipe 8. 17 is provided. Further, in each of the power generation facilities 3, 3,..., A control device 18 that controls the distributor 17 in accordance with the state of the fuel cell 9 and the electrical equipment 10 is provided.

上記した共用配管15には、上記した複数の発電設備3,3,…に加えて、燃料ガスステーション(他の設備)20が配管21を介して接続されている。   In addition to the plurality of power generation facilities 3, 3,..., A fuel gas station (another facility) 20 is connected to the common pipe 15 through a pipe 21.

この燃料ガスステーション20は、配管21に接続されるとともに燃料ガスを貯留するガスタンク22と、ガスタンク22に貯留している燃料ガスを、燃料電池の発電で電動モータを駆動して走行する燃料電池走行車両や燃料ガスを燃焼させる内燃機関の駆動力で走行する燃料ガス走行車両等の車両23の車載タンク23aに供給するガス供給装置24とを有している。   The fuel gas station 20 is connected to a pipe 21 and has a gas tank 22 for storing the fuel gas, and a fuel cell traveling for driving the fuel gas stored in the gas tank 22 by driving an electric motor by power generation of the fuel cell. And a gas supply device 24 that supplies the vehicle 23 to the vehicle-mounted tank 23a of the vehicle 23 such as a fuel gas traveling vehicle that travels with the driving force of the internal combustion engine that burns the vehicle and fuel gas.

そして、各発電設備3,3,…においては、それぞれ、制御装置18が、原燃料貯留設備5に貯留された原燃料を改質器7で改質させて燃料ガスを生成し、この燃料ガスを用いて燃料電池9に、同じ設置場所2に設けられた電気機器類10の要求電力に応じて、あるいは、定格で発電させることになるが、その際に発生する燃料電池9の排熱を、必要により同じ設置場所2に設けられた排熱使用機器類11が使用し、残りの排熱は、付設された改質器7による改質反応つまり燃料ガスの生成を促進するために用いることになる。   In each of the power generation facilities 3, 3,..., The control device 18 reforms the raw fuel stored in the raw fuel storage facility 5 with the reformer 7, and generates fuel gas. The fuel cell 9 is caused to generate power according to the required power of the electrical equipment 10 provided in the same installation place 2 or at a rated power, but the exhaust heat of the fuel cell 9 generated at that time is reduced. If necessary, the exhaust heat using equipment 11 provided in the same installation place 2 is used, and the remaining exhaust heat is used to promote the reforming reaction by the attached reformer 7, that is, the generation of the fuel gas. become.

このとき、改質器7で生成された燃料ガスに対して、同じ発電設備3の燃料電池9による要求電力の発電に要する燃料ガスが少ない場合があり、このような場合であっても、改質器7では排熱使用機器類11に使用する以外の燃料電池9の排熱を全面的に改質反応に利用して燃料ガスを最大限生成し続ける。   At this time, the fuel gas generated by the reformer 7 may require less fuel gas to generate the required power by the fuel cell 9 of the same power generation facility 3. In the mass device 7, the exhaust heat of the fuel cell 9 other than that used for the exhaust heat using equipment 11 is fully utilized for the reforming reaction, and the fuel gas is continuously generated to the maximum extent.

そして、制御装置18が、分配器17を制御して、改質後の燃料ガスのうち、燃料電池9による要求電力の発電に要する燃料ガスだけを燃料電池9に送り、残りの余剰燃料ガスを、分岐配管14から共用配管15に送って、例えば近隣の燃料ガスステーション20のガスタンク22に貯留させることになる。つまり、余剰燃料ガスを発電設備3と他の設備である燃料ガスステーション20との間で共有する。   Then, the control device 18 controls the distributor 17 to send only the fuel gas required for power generation of the required power by the fuel cell 9 among the reformed fuel gas to the fuel cell 9 and the remaining surplus fuel gas. Then, the gas is sent from the branch pipe 14 to the common pipe 15 and stored in the gas tank 22 of the adjacent fuel gas station 20, for example. That is, the surplus fuel gas is shared between the power generation facility 3 and the fuel gas station 20 which is another facility.

すると、燃料ガスステーション20から燃料ガスの供給を受ける車両23が、上記した余剰燃料ガスを含む燃料ガスの供給を受けることになる。つまり、発電設備3における余剰燃料ガスが、燃料ガスステーション20を介して、複数の車両23にも共有されることになる。   Then, the vehicle 23 that receives the supply of the fuel gas from the fuel gas station 20 receives the supply of the fuel gas containing the surplus fuel gas described above. That is, surplus fuel gas in the power generation facility 3 is also shared by the plurality of vehicles 23 via the fuel gas station 20.

また、例えば、他の発電設備3において、原燃料貯留設備5内の原燃料が不足すること等によって、燃料電池9に供給される発電用の燃料ガスが不足している場合に、この発電設備3の分配器17を制御することでこの発電設備3に共用配管15及び分岐配管14を介して余剰燃料ガスを供給することになる。   In addition, for example, when the power generation fuel gas supplied to the fuel cell 9 is insufficient in another power generation facility 3 due to a shortage of raw fuel in the raw fuel storage facility 5, this power generation facility The surplus fuel gas is supplied to the power generation equipment 3 through the common pipe 15 and the branch pipe 14 by controlling the third distributor 17.

以上に述べた本実施形態に係る燃料電池システム1によれば、複数の各発電設備3,3,…において、設備間で共有することによるエネルギー損失が大きい燃料電池9の排熱については、同一設備内の改質器7による燃料ガスの生成に用いることで、その損失を小さく抑えることができ、効率良く利用できることになる。   According to the fuel cell system 1 according to the present embodiment described above, in each of the plurality of power generation facilities 3, 3,..., The exhaust heat of the fuel cell 9 having a large energy loss due to sharing between facilities is the same. By using it for the production of fuel gas by the reformer 7 in the facility, the loss can be suppressed to a low level and it can be used efficiently.

このように燃料電池9の発電時に発生する排熱を改質反応に必要なエネルギーとして利用すると、燃料ガスの改質効率は利用しない場合の60%に対して100%近くまで上昇することになる。そして、このようにして各発電設備3,3,…において排熱を効率良く利用して改質器7で生成した、設備間での共有でも損失が生じにくい燃料ガスについて、その余剰燃料ガスを、発電設備3,3,…及び燃料ガスステーション20を含む複数の設備間で共有する。   As described above, when the exhaust heat generated at the time of power generation of the fuel cell 9 is used as energy necessary for the reforming reaction, the reforming efficiency of the fuel gas increases to nearly 100% with respect to 60% when not used. . Then, with respect to the fuel gas that is generated by the reformer 7 using the exhaust heat efficiently in each of the power generation facilities 3, 3,. , And the power generation facilities 3, 3... And the fuel gas station 20.

したがって、全体のエネルギー利用効率を向上させることができる。つまり、炭化水素系燃料を出発原燃料とするエネルギーフローの中で効率の高いシステムとなり、一時エネルギー消費削減及び二酸化炭素発生量削減に繋がることになる。   Therefore, the overall energy utilization efficiency can be improved. That is, it becomes a highly efficient system in the energy flow using hydrocarbon fuel as the starting raw fuel, which leads to reduction of temporary energy consumption and reduction of carbon dioxide generation.

なお、上記した発電設備3としては、例えば集合住宅等において各住戸に対する発電を一箇所で集中して行う集中型の発電設備も含まれることになり、この場合も、集中型の発電設備に大型の燃料電池9及び大型の改質器7を設置し、発電の排熱で改質器7で改質を行い、余った燃料ガスを燃料ガスステーション20等の他の設備に送ることになる。   The above-described power generation equipment 3 includes, for example, a centralized power generation facility that concentrates power generation for each dwelling unit at one place in an apartment house or the like. The fuel cell 9 and the large reformer 7 are installed, reforming is performed by the reformer 7 by the exhaust heat of power generation, and surplus fuel gas is sent to other equipment such as the fuel gas station 20.

また、上記実施形態では、原燃料供給源として原燃料貯留設備5を例に挙げているが、このような貯留設備に限らず、例えば都市ガス等のパイプラインを使用することも可能である。   Moreover, in the said embodiment, although the raw fuel storage facility 5 is mentioned as an example as a raw fuel supply source, it is not restricted to such a storage facility, For example, it is also possible to use pipelines, such as city gas.

本発明の一実施形態に係る燃料電池システムの構成図である。1 is a configuration diagram of a fuel cell system according to an embodiment of the present invention.

符号の説明Explanation of symbols

1…燃料電池システム、3…発電設備(他の設備)、7…改質器、9…燃料電池、10…電気機器類(電力消費装置)、20…燃料ガスステーション(設備)。   DESCRIPTION OF SYMBOLS 1 ... Fuel cell system, 3 ... Power generation equipment (other equipment), 7 ... Reformer, 9 ... Fuel cell, 10 ... Electric equipment (electric power consumption apparatus), 20 ... Fuel gas station (equipment).

Claims (3)

燃料ガスと酸化ガスとの電気化学反応によって発電する燃料電池と、該燃料電池の排熱を利用して該燃料電池に供給される燃料ガスを生成する改質器と、を有する発電設備を複数備え、
前記各発電設備において前記改質器で生成された燃料ガスのうち前記燃料電池の発電に要する燃料ガスに対する余剰燃料ガスを、前記発電設備間あるいは前記発電設備と他の設備との間で共有する燃料電池システム。
A plurality of power generation facilities having a fuel cell that generates power by an electrochemical reaction between a fuel gas and an oxidizing gas, and a reformer that generates fuel gas to be supplied to the fuel cell using exhaust heat of the fuel cell Prepared,
Of the fuel gas generated by the reformer in each power generation facility, surplus fuel gas for the fuel gas required for power generation of the fuel cell is shared between the power generation facilities or between the power generation facility and other facilities. Fuel cell system.
前記燃料電池は、固体酸化物型燃料電池である請求項1に記載の燃料電池システム。   The fuel cell system according to claim 1, wherein the fuel cell is a solid oxide fuel cell. 燃料ガスと酸化ガスとの電気化学反応によって発電する燃料電池と、該燃料電池の排熱を利用して該燃料電池に供給される燃料ガスを生成する改質器と、を有する発電設備を複数備えた燃料電池システム内のガス共有方法であって、
前記各発電設備において前記改質器で生成された燃料ガスのうち前記燃料電池の発電に要する燃料ガスに対する余剰燃料ガスを、前記発電設備間あるいは前記発電設備と他の設備との間で共有する燃料電池システム内のガス共有方法。

A plurality of power generation facilities having a fuel cell that generates power by an electrochemical reaction between a fuel gas and an oxidizing gas, and a reformer that generates fuel gas to be supplied to the fuel cell using exhaust heat of the fuel cell A gas sharing method in a fuel cell system comprising:
Of the fuel gas generated by the reformer in each power generation facility, surplus fuel gas for the fuel gas required for power generation of the fuel cell is shared between the power generation facilities or between the power generation facility and other facilities. Gas sharing method in a fuel cell system.

JP2006080015A 2006-03-23 2006-03-23 Fuel cell system Pending JP2007257972A (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH117972A (en) * 1997-06-16 1999-01-12 Fuji Electric Co Ltd Fuel-cell power generator
JP2004006281A (en) * 2002-03-29 2004-01-08 Kri Inc Energy formation device and energy carrier system

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH117972A (en) * 1997-06-16 1999-01-12 Fuji Electric Co Ltd Fuel-cell power generator
JP2004006281A (en) * 2002-03-29 2004-01-08 Kri Inc Energy formation device and energy carrier system

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