JP2007231382A - Method for recovering rare earth element - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a recovery method for obtaining a rare earth element from a rare earth element-containing object for recovery. <P>SOLUTION: In this method, an object for recovery comprising at least one rare earth element among yttrium and lanthanoids from lanthanum La to lutetium Lu whose atomic number is 57 to 71 is dissolved with mineral acid so as to be a solution, its pH is regulated in such a manner that the precipitation of hydroxide including elements other than the rare earth element is formed, then, the precipitate is separated away, and thereafter, the rare earth element dissolved in the solution is recovered as a rare earth compound. Further, the invention relates to a method for recovering a high purity rare earth element by a simple process, and the method particularly suitable as the method for recovering cerium based abrasives. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

  The present invention relates to a method for recovering a rare earth element from a recovery object containing the rare earth element.

  Rare earth elements are used in a very wide range of fields as functional materials such as magnets, ceramic capacitors, hydrogen storage alloys, glass, catalysts, ultraviolet absorbers, and abrasives. The supply of rare earth elements is made from rare earth minerals buried all over the world.

  In Japan, the consumption of rare earth elements is increasing due to the above-mentioned many uses, while the rare earth minerals as raw materials are not buried in the country, and supply depends on imports from abroad. In addition, many materials containing rare earth elements are sometimes handled as industrial waste after use, and there is a problem of waste disposal. For example, in the case of abrasive waste, since it is cake-like and contains a large amount of water, it has difficulty in landfilling. For these reasons, there is a need for rare earth elements to be effectively used as resources and to reduce the amount of waste after use.

  In order to solve the above-mentioned problem, as a method for recovering and reusing the rare earth element, a conventional method for producing a rare earth element can be considered. As a method for producing rare earth elements, there is known a method of removing impurities by alkaline decomposition or the like using a concentrate obtained by selecting rare earth ore, and further separating and purifying each rare earth element by ion exchange or solvent extraction. Yes. Moreover, the following patent documents are disclosed as a method of recycle | reusing the used abrasives containing a rare earth element, and collect | recovering raw materials for abrasives.

For example, Patent Document 1 discloses a method in which polishing waste containing rare earth elements is used to add alkali to dissolve glass powder, polishing cloth, and the like, and to separate the abrasive from the remaining solids. Patent Document 2 discloses a method in which abrasive waste is dissolved with mineral acid, oxalic acid is added to precipitate rare earth elements, and then converted into hydroxides and recovered. Further, in the recovery method of Patent Document 3, after mixing and heating a polishing waste liquid containing a rare earth element and an acid to dissolve the rare earth element and separating and removing undissolved substances such as silica gel and polishing pad scraps, Recovery is performed by adding carbonic acid or oxalic acid to the dissolved rare earth element. Furthermore, Patent Document 4 describes a cerium recovery method in which chromium is precipitated and removed as a hydroxide from cerium and chromium in a chromium etching waste solution.
JP-A-11-90825 JP 2000-87154 A Japanese Patent Laid-Open No. 2004-175552 Japanese Patent Laid-Open No. 11-236632

When collecting used rare earth elements, the method used for the production of rare earth elements is effective in large-scale refining facilities, but is not suitable as a method for easily collecting rare earth elements from a collection object. It is. In addition, in the recovery methods of Patent Documents 1 to 3 described above, foreign substances such as glass pieces and polishing scraps can be removed, but elements other than rare earth elements cannot be removed, and they are precipitated together with the rare earth elements and collected while being mixed. Will be. The cerium recovery method of Patent Document 4 is a recovery method specialized for the removal of chromium, and there is room for further improvement when elements other than rare earth elements are contained in addition to chromium. In particular, when the recovered rare earth element is used as an abrasive, as disclosed in Patent Document 5, if an element such as iron remains contained, it becomes a cause of occurrence of abrasive scratches.
International Publication No. 2002/028979

  Therefore, the present invention provides a method for recovering high-purity rare earth elements by separating and removing not only foreign substances but also elements other than rare earth elements from an object to be collected containing rare earth elements.

  In order to solve the above-mentioned problems, the present inventors have intensively studied a recovery method for separating and removing elements other than rare earth elements from a recovery object containing rare earth elements. As a result, after dissolving the recovery object, it was found that elements other than the rare earth element can be separated and removed from the rare earth element by adjusting to a pH at which a hydroxide is formed.

  That is, in the present invention, a recovery object containing a rare earth element is dissolved in a mineral acid to form a solution, the pH is adjusted so that a hydroxide precipitate containing an element other than the rare earth element is formed, and the precipitate is separated. After the removal, the rare earth element dissolved in the solution is recovered as a rare earth compound. In the present invention, the rare earth element indicates at least one of lanthanoids from lanthanum La to lutetium Lu having yttrium Y and atomic numbers of 57 to 71.

  Here, the mineral acid that dissolves the recovery object is preferably at least one of hydrochloric acid, sulfuric acid, and nitric acid, and can be used by mixing. However, such as hydrofluoric acid is not so desirable because it binds to a rare earth compound and easily precipitates as a compound with low solubility. It is also desirable to improve the solubility of the recovery object by adding a substance having a reducing action in advance before adding the mineral acid. For example, when cerium Ce is included as a rare earth element, Ce is often in a tetravalent state with poor solubility. Therefore, after adding a reducing substance such as hydrogen peroxide to obtain a trivalent state with high solubility. Can be dissolved with mineral acid.

  In the case where foreign substances are present in the recovery object, they can be removed in advance by a method such as filtration in order to reduce the labor required for dissolution with mineral acid. For example, in the case where the object to be collected is a slurry containing a polishing material after glass polishing, water as a main component, a glass component as a polishing material, a polishing pad, etc. are included. It is preferable to perform such operations. It is also possible to add an alkali or the like to dissolve and remove glass components and the like.

  Moreover, it is preferable to use ammonia, urea, ammonium carbonate, ammonium hydrogen carbonate, etc. as an alkali used in pH adjustment so that elements other than rare earth elements may form a hydroxide. Alkali metal hydroxide, alkaline earth metal hydroxide, alkali metal carbonate, etc. can also be used, but in applications that require heat treatment after recovery, if alkali metal or alkaline earth metal is included, This is because the particles may grow abnormally. For example, when producing cerium-based abrasives using recovered rare earth elements as raw materials, if alkali metals or alkaline earth metals are included, abnormal growth of particles occurs in the roasting process, and when used as an abrasive, It will cause scratches.

  It is preferable to separate and remove the precipitate produced by the formation of hydroxide by the elements other than the rare earth element by the pH adjustment described above from the solution in which the rare earth element is dissolved by filtration, centrifugation, or the like. Thereafter, the rare earth element dissolved in the solution can be recovered by adding a precipitant or water-soluble rare earth chloride. In the case of adding a precipitant, it is preferable to use ammonium hydrogen carbonate, ammonium carbonate, oxalic acid or the like. Alkali metal hydroxide, alkaline earth metal hydroxide, and the like can be used, but when the heat treatment is performed after recovery, rare earth element particles may grow abnormally for the same reason as described above.

  And when making a collection | recovery target object melt | dissolve with a mineral acid and setting it as a solution, it is preferable to adjust pH of a solution to 0-7. In this range, elements other than rare earth elements can be precipitated as hydroxides while the rare earth elements are dissolved. When the pH is higher than 7, the rare earth element itself tends to form hydroxide, and the final rare earth element recovery rate tends to decrease. In order to effectively precipitate elements other than rare earth elements, the pH adjustment range is more preferably 1 to 6, and further preferably pH 2 to 6.

Further, according to the study by the present inventors, the element other than the rare earth element preferably contains at least one metal component M of iron Fe, titanium Ti, and zirconium Zr. Hydroxide solubility product _{K sp} (Chemical Handbook Fundamentals, third revised edition, issued June 25, 1984, (company) edited by The Chemical Society of Japan, with reference to the description of the II-p.177~182) According to the The hydroxides of rare earth elements are La (OH) ₃ K _sp = 5 × 10 ⁻²⁰ , Ce (OH) ₃ K _sp = 1 × 10 ⁻²³ , Lu (OH) ₃ K _sp = 1 × 10 ⁻²⁷ Etc., while the hydroxides of Fe, Ti, and Zr are Fe (OH) ₃ K _sp = 3 × 10 ⁻³⁸ , Ti (OH) ₄ K _sp = 8 × 10 ⁻⁵⁴ , and Zr, respectively. (OH) ₄ K _sp = 8 × 10 ⁻⁵² , and the difference in solubility product between the rare earth element and other elements is large. Therefore, Fe, Ti, and Zr can be separated and removed as a precipitate of hydroxide while the rare earth element is still dissolved by the pH adjustment method. In addition, when Fe precipitates as a hydroxide, it has an effect of adsorbing components such as chromium and manganese contained in the object to be recovered, and has an effect of improving the purity of the recovered rare earth element.

  As described above, it is more preferable to adjust the pH for forming a hydroxide of an element other than the rare earth element to 1 to 6, but when Fe is contained as an element other than the rare earth element, the pH adjustment is adjusted to pH 2 to 6 is more preferable, and a pH of 3 to 6 is even more preferable. This is because the solubility product of Fe is slightly larger than that of Ti or Zr in the above-described solubility product, so that a slight difference occurs in a preferable pH adjustment range.

Depending on the object to be recovered, elements other than rare earth elements may exist as Fe (OH) ₂ or Ti (OH) ₃ when dissolved with mineral acid. In this case, it is possible to adjust beforehand to Fe (OH) ₃ or Ti (OH) ₄ using an oxidizing agent. At this time, it is preferable that the amount of the oxidizing agent added is such that the rare earth element is not oxidized excessively and changes to Ce (OH) ₄ or the like.

  In the recovered rare earth compound, the content M / TREO of the metal component M described above with respect to the weight converted to total rare earth oxide (TREO) is preferably 0.5% by mass or less, The mass% or less is more preferable. This is because it is desirable that the purity of the rare earth element is high when the collected rare earth element is reused as a resource. Moreover, when two or more types of elements are contained in the metal component M, it is preferable to adjust so that M / TREO may be 0.5 mass% or less in each element.

  The present invention described above is a suitable recovery method when the main component of the rare earth element contained in the recovered rare earth compound is cerium. This is because cerium is used as cerium oxide contained in abrasives and catalysts for glass, and it is desirable to recover and reuse it. Moreover, since cerium is an inexpensive component among rare earth elements, it is a component that requires a simple and efficient technique that can be recovered. Cerium hydroxide has a large solubility product among the rare earth elements, and can be easily separated from elements other than the rare earth elements.

  By the way, cerium-based abrasives, which are one of the uses of rare earth compounds, may contain metal elements such as iron in the manufacturing process and polishing process, and so-called used cerium-based abrasives to be collected In the case of recovering rare earth elements from the above, it is desirable to apply the present invention described above. Specifically, in the method of recovering a rare earth element from a recovery object including at least one rare earth element among lanthanoids from lanthanum La to lutetium Lu having an atomic number of 57 to 71 and yttrium Y, The object contains a cerium-based abrasive, and after the recovery object is dissolved in mineral acid to form a solution, at least one metal component M of iron Fe, titanium Ti, and zirconium Zr is used as a hydroxide. In this method, the pH is adjusted to 0 to 7 so as to precipitate, the precipitate is separated and removed, and then the rare earth element dissolved in the solution is recovered as a rare earth compound. According to the present invention, since the separation of the rare earth element and iron Fe, titanium Ti, and zirconium Zr can be easily performed, when the collection target contains a cerium-based abrasive, it is a suitable method for collecting the rare earth element.

  Moreover, in this invention, when the collection | recovery object contains a cerium-type abrasive, content M / TREO of the metal component M in the rare earth compound collect | recovered by said collection | recovery method is 0.001-0.5 mass%. Preferably there is. The metal component contained in the rare earth compound acts as a sintering aid in the roasting step and enables roasting at a low temperature when an abrasive is produced from the collected rare earth compound. For this reason, if M / TREO exceeds 0.5% by mass, sintering proceeds excessively in the roasting process, and abnormal growth of rare earth element particles is promoted, resulting in an abrasive that tends to cause abrasive scratches. There is. In addition, the oxide of the metal component itself may be present independently in the abrasive and may cause abrasive scratches. On the other hand, when M / TREO is less than 0.001% by mass, an effect as a sintering aid for metal components cannot be expected, and the polishing material may be difficult to obtain a polishing rate. And in order to obtain a polishing speed, it becomes necessary to raise the roasting temperature. As a result, the resulting abrasive tends to contain coarse particles. Therefore, when manufacturing the cerium-based abrasive, the size of the abrasive particles can be adjusted according to the purpose by adjusting the content of the metal component and expanding the selection range of the roasting conditions. As a metal component acting as a sintering aid, Fe is particularly suitable among Fe, Ti, and Zr.

  By the way, some rare earth ores that are raw materials for rare earth elements contain fluorine, and the cerium-based abrasive after use also contains 1% by mass or more of fluorine as an additive. is there. For this reason, in some cases, the recovery object contains fluorine in advance, and when dissolved with mineral acid, a precipitate of a rare earth fluoride compound with low solubility is likely to be formed. Here, since fluorine has a problem as a cause of environmental pollution, it is desirable to reduce the content of the recovered rare earth element. In addition, when the recovered rare earth element is used as an abrasive, if the fluorine content is too high, it may cause abrasive scratches.

  Therefore, when the recovery object contains a fluorine component, it is preferable to separate and recover the insoluble rare earth fluoride compound that precipitates when dissolved with a mineral acid. For example, a recovery target containing fluorine and lanthanum forms a precipitate such as lanthanum fluoride having a low solubility when dissolved with a mineral acid, so that the fluorine component can be easily separated.

  The present inventors include a rare earth compound whose main component is Ce among rare earth compounds recovered by the above method, a rare earth compound recovered from a recovery object including a cerium-based abrasive, or a fluorine component. It has been found that a compound containing at least one of the rare earth fluoride compounds recovered from the object to be recovered is preferable as a cerium-based abrasive material.

  As described above, since the rare earth compound obtained by the recovery method of the present invention can be adjusted to a content in a preferable range that functions as a sintering aid for elements other than rare earth elements such as Fe, for cerium-based abrasives Suitable as a raw material. When no rare earth fluoride compound is added as a raw material, a high-purity abrasive that does not contain fluorine can be produced. Conversely, in the production of abrasives that require high polishing speeds, cerium-based abrasives with adjusted polishing speeds can be obtained by adding the required amount of rare earth fluoride compounds, making effective use of fluorine resources. Can contribute. Therefore, the recovery method of the present invention is suitable for a cerium-based abrasive produced using the above-mentioned cerium-based abrasive material and a method for producing the same.

  As described above, when the method of the present invention is used, elements other than rare earth elements are precipitated and separated as a hydroxide from the object to be recovered containing rare earth elements, and are diluted with fluoride when dissolved in mineral acid. High-purity rare earth elements with reduced fluorine as an earth compound can be recovered. Further, since a complicated purification process such as solvent extraction is not required, the rare earth element can be obtained only by a simple process. In particular, since the recovered rare earth element can adjust the iron and fluorine content to an appropriate level, it is suitable as a method for recovering the abrasive raw material from the cerium-based abrasive used as the glass abrasive.

  Hereinafter, preferred embodiments of the present invention will be described.

First Embodiment: In this embodiment, a method for recovering rare earth elements from a polishing slurry after polishing a glass substrate will be described.

The polishing slurry used for polishing the glass substrate was used as a recovery object. The abrasive concentration of the polishing slurry is 10% by mass, and the contents of rare earth elements and elements other than rare earths are La ₂ O ₃ / TREO = 25% by mass, CeO ₂ / TREO = 60% by mass, F / TREO = They were 6 mass% and Fe / TREO = 0.6 mass%. This abrasive slurry was concentrated by sedimentation to obtain a mud substance, hydrochloric acid was added as a mineral acid, and the mixture was stirred for 3 hours at 60 ° C. to dissolve. After dissolution, insoluble matter containing fluorine was removed by filtration. This insoluble matter was F / TREO = 25 mass%, La ₂ O ₃ / TREO = 30 mass%, and CeO ₂ / TREO = 55 mass%. In addition, about the quantitative analysis of each element, it measured as follows.

Quantitative analysis method: Regarding the TREO content, decompose the sample with a mixture of perchloric acid and hydrogen peroxide, add oxalic acid, adjust the pH to 1.5 and precipitate the resulting precipitate. Separately, it can be baked at 1000 ° C. and measured as a TREO oxide by weight measurement. In addition, the content of each rare earth element can be determined by performing an ICP analysis after melting the sample with alkali and converting each element into an oxide weight as necessary. As a quantification method of the fluorine component, a sample having a fluorine content exceeding 0.1% by weight can be measured by a fluorine ion electrode method after being alkali-melted and extracted with warm water. In the case of less than% by weight, it can be measured by lanthanum-alizarin complexone spectrophotometry (JIS H1698) after thermal hydrolysis.

  Ammonia was added to the solution from which the insoluble matter containing fluorine was removed so that pH = 1, and the precipitate formed in the solution was removed by filtration. When this precipitate was analyzed, it was a hydroxide mainly composed of Fe. Next, ammonium hydrogen carbonate was added to the solution from which the hydroxide precipitate was removed, and the rare earth component in the solution was recovered as a rare earth carbonate. The above recovery method is referred to as Example 1. For comparison, in Example 2, the precipitate formed in the solution after adding ammonia was not removed by filtration, but ammonium hydrogen carbonate was added, and the rare earth component in the solution was recovered as a rare earth carbonate (comparative). Example 1).

  Rare earth elements were recovered using the same method as in Example 1 except that the pH was adjusted to 2, 6, 7, and 8 when ammonia was added. The contents of rare earth compounds and the like contained in the recovered rare earth carbonate are shown in Table 1 below as Examples 2, 3, 4, and 5, respectively.

  From Table 1, the fluorine content F / TREO was able to be significantly reduced as compared with the content in the polishing slurry. Regarding Example 5, since the TREO recovery rate was low, it was confirmed that the pH at which the hydroxide was precipitated was preferably 7 or less. Moreover, about Example 1, since Fe / TREO was a little high, it can be said that pH of 2 or more is more preferable. On the other hand, in Comparative Example 1, since the precipitate generated when the pH was adjusted to 2 by adding ammonia was not removed by filtration, Fe / TREO did not decrease.

  Next, an abrasive was produced using the recovered rare earth carbonate as a raw material, and the abrasive value and the abrasive scratch were evaluated as the abrasive performance.

Abrasive Material Production Method: Each rare earth carbonate collected in each example was wet pulverized with a bead mill using zirconia as a pulverization medium, the slurry was filtered, dried, and then fired at 1000 ° C. for 4 hours. The fired product was dry pulverized with an atomizer, classified with an air classifier with a classification point set to 5 μm, and coarse particles were removed to obtain a powder. The obtained powder was adjusted to a slurry concentration of 10% by mass and used in the following polishing test.

Polishing test: An Oscar type polishing tester (Taito Seiki Co., Ltd., HSP-2I type) was used as the polishing machine. This polishing tester polishes a polishing target surface with a polishing pad while supplying a slurry-like polishing material to the polishing target surface. The dispersion medium was water only, and the abrasive grain concentration of the abrasive slurry was 10 wt%. In this polishing test, a slurry-like abrasive was supplied at a rate of 5 L / min, and the abrasive was circulated. The polishing object was a glass for a flat panel having a diameter of 65 mm. A polishing pad made of polyurethane was used. The pressure of the polishing pad against the polishing surface was 78.4 kPa (800 g / cm ² ), the rotation speed of the polishing tester was set to 600 min ⁻¹ (rpm), and polishing treatment was performed for 10 minutes.

Particle size and specific surface area: Regarding the particle size of the abrasive, the specific surface area was determined according to the method described in "7.1 Specific surface area test" of JIS R5201-1997 "Physical test method for cement" (Brain method). The value was measured, and the brain diameter was calculated based on the measured value. For example, in the case where the specific surface area is S (m ² / g) and the density of the cerium-based abrasive is p (g / cm ³ ), the calculation is performed as the brane diameter d (μm) = 6 / (S × p). The specific surface area is cerium in accordance with “6.2 (3.5) One-point method of flow method” in JIS R 1626-1996 (Method for measuring specific surface area of fine ceramic powder by gas adsorption BET method). The specific surface area of the system abrasive was measured. At that time, a mixed gas of helium as a carrier gas and nitrogen as an adsorbate gas was used.

Abrasive performance: The polishing value was evaluated based on the reduction rate of the glass weight by polishing by measuring the glass weight before and after polishing. In addition, this grinding | polishing value made Example 1 the standard (100), and calculated the relative evaluation value about the other Example. Next, polishing scratches are a reflection method using a 300,000 lux halogen lamp as a light source, observing the polished glass surface, scoring the number of large scratches and fine scratches, and evaluating 100 points as a perfect score. Evaluation was performed by the method. Table 2 below shows the evaluation results of the abrasive performance.

  From the above results, when the rare earth element recovered by the method of the present invention was used, an abrasive with controlled particle size and specific surface area could be obtained. However, since Example 1 has many abrasive scratches, it is appropriate to use it for purposes other than high-accuracy abrasive materials. Moreover, in Example 5, although the abrasion damage was not conspicuous, it was recognized that the polishing value was somewhat small. On the other hand, Comparative Example 1 had many abrasive scratches, and the evaluation score of the abrasive scratches was as bad as -65 points. Therefore, when the precipitate at the time of ammonia addition was not separated, Fe / TREO was high, and the abrasive was easily damaged.

Second Embodiment: In this embodiment, a method for recovering rare earth elements from an acidic nitric acid solution containing Zr and rare earth elements will be described.

The proportions of the compounds contained in the acidic solution of nitric acid as the collection target were CeO ₂ / TREO = 60 wt%, La ₂ O ₃ / TREO = 21 wt%, and Zr / TREO = 6.7 wt%. Regarding the method for recovering rare earth elements, the same method as in Example 1 except that the pH for precipitating Zr as a hydroxide was set to 0, 1, 7, and 8, and Examples 6, 7, 8, and 9 were used respectively. It went by. Moreover, as Comparative Example 2, the precipitate formed when ammonia was added was not removed by filtration, and ammonium hydrogen carbonate was added to recover the rare earth component in the solution as a rare earth carbonate. Table 3 below shows the contents of rare earth compounds and Zr contained in the recovered rare earth carbonate.

  From Table 3, it was confirmed that even when Zr is contained as an element other than the rare earth element, most of the rare earth element contained in the nitric acid acidic solution can be recovered. In particular, it was shown that when a Zr hydroxide was formed at a pH of 1 or higher, the Zr content was small and high-purity rare earth elements could be recovered. Considering the TREO recovery rate, it was found that the pH is preferably 7 or less. On the other hand, in Comparative Example 2, the precipitate produced when ammonia was added to adjust the pH to 1 was not removed by filtration, so Zr / TREO did not decrease.

  Next, using the same method as in the first embodiment, an abrasive was produced using the recovered rare earth carbonate as a raw material, and the polishing value and the scratches were evaluated as the abrasive performance. The results are shown in Table 4 below.

From the above results, in all of Examples 6 to 9, it was possible to obtain abrasives having a substantially constant particle diameter and specific surface area. However, in Example 6, although the polishing value was very excellent, many conspicuous scratches were observed on the entire glass surface after polishing, and the evaluation score of the polishing scratch was less than -200 points, which was extremely bad. In Example 9, the polishing value was slightly low. On the other hand, also in Comparative Example 2, many conspicuous scratches were observed on the entire glass surface. Accordingly, it has been found that when Zr / TREO is high, the polishing material is likely to cause abrasive scratches.

Claims (9)

In a method for recovering rare earth elements from a recovery object containing at least one rare earth element among lanthanoids from lanthanum La to lutetium Lu having yttrium Y and atomic numbers of 57 to 71,
The recovered object is dissolved in mineral acid to form a solution, and the pH is adjusted so that a precipitate of hydroxide containing an element other than the rare earth element is formed,
A method for recovering a rare earth element, comprising separating and removing the precipitate and then recovering the rare earth element dissolved in the solution as a rare earth compound. The method for recovering a rare earth element according to claim 1, wherein the recovery object is dissolved in a mineral acid to form a solution, and the pH of the solution is adjusted to 0 to 7. The method for recovering a rare earth element according to claim 1 or 2, wherein the element other than the rare earth element contains at least one metal component M of iron Fe, titanium Ti, and zirconium Zr. The method for recovering a rare earth element according to claim 3, wherein the recovered rare earth compound has a content M / TREO of the metal component M with respect to the weight in terms of total rare earth oxide (TREO) of 0.5% by mass or less. The method for recovering a rare earth element according to any one of claims 1 to 4, wherein a main component of the rare earth element contained in the recovered rare earth compound is cerium Ce. In a method for recovering rare earth elements from a recovery object containing at least one rare earth element among lanthanoids from lanthanum La to lutetium Lu having yttrium Y and atomic numbers of 57 to 71,
The collection object contains cerium-based abrasives,
After the recovered object is dissolved in mineral acid to make a solution, the pH is adjusted to 0 to 7 so that at least one metal component M of iron Fe, titanium Ti, and zirconium Zr is precipitated as a hydroxide. And
A method for recovering a rare earth element, comprising separating and removing the precipitate and then recovering the rare earth element dissolved in the solution as a rare earth compound. The recovered rare earth compound has a content M / TREO of the metal component M with respect to the weight in terms of total rare earth oxide (TREO) of 0.001 to 0.5 mass%, and the rare earth element according to claim 6. Collection method. The rare earth element recovery method according to any one of claims 1 to 7, wherein the recovery object contains a fluorine component, and the recovery object is dissolved with a mineral acid and then insoluble in a rare earth fluoride compound. A method for recovering rare earth elements by separating and recovering. It is a raw material used in order to manufacture a cerium type abrasive | polishing material, Comprising: By the rare earth compound collect | recovered by the recovery method of the rare earth elements in any one of Claims 5-7, or the recovery method of Claim 8 A raw material for a cerium-based abrasive comprising at least one of the recovered rare earth fluoride compounds.