JP2007224257A - Strongly adhering one pot type luminous coating - Google Patents

Strongly adhering one pot type luminous coating Download PDF

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JP2007224257A
JP2007224257A JP2006079725A JP2006079725A JP2007224257A JP 2007224257 A JP2007224257 A JP 2007224257A JP 2006079725 A JP2006079725 A JP 2006079725A JP 2006079725 A JP2006079725 A JP 2006079725A JP 2007224257 A JP2007224257 A JP 2007224257A
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phosphorescent
agent
paint
binder
pot type
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JP2006079725A
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Kazuo Saito
一夫 斉藤
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a strongly adhering one pot type luminous coating securing a higher brightness and extending more afterglow time than those of conventional ones by the utilization of a large diameter particle-formed luminous agent and further realizing the simplification of coating process by using the mixed one pot of the luminous agent with a binder. <P>SOLUTION: This strongly adhering one pot type luminous coating is formed by mixing the luminous agent with a binder obtained by adding a thickening agent and film-forming assistant to an acrylic synthetic resin emulsion. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は、大径粒状蓄光剤の活用により、従来よりも高輝度の確保と残光時間の延長が可能で、さらに、蓄光剤と結合材の混合一液により、塗装工程の簡易化を実現する強度粘着一液式蓄光塗料に関する。  By utilizing a large-diameter granular phosphorescent agent, it is possible to ensure higher brightness and extend the afterglow time than before, and to simplify the painting process with a single liquid mixture of phosphorescent agent and binder. The present invention relates to a pressure-sensitive adhesive one-part phosphorescent paint.

従来より、光を蓄え自然発光が可能な蓄光剤においては、高い付加価値と優れた利便性から多方面に亘り利用されている。その利用方法の一例として、樹脂中に混合して造形物を形成したり、塗料に混合して壁面や天井表面等に塗布したりするといった方法が挙げられる。  2. Description of the Related Art Conventionally, phosphorescent agents capable of storing light and spontaneously emitting light have been used in various fields because of high added value and excellent convenience. As an example of the utilization method, there are a method of mixing in a resin to form a modeled object, or a method of mixing in a paint and applying to a wall surface or ceiling surface.

また、蓄光塗料の乾燥過程においても蓄光材料の粒子が沈殿することなく塗料層内で均一に拡散した状態を保つことができ、白色塗料による下塗りを施すことなく、従来の蓄光塗料に比して蓄光効率が高くて発光時間の長い蓄光塗料およびその使用方法がある(例えば、特許文献1参照)。
上掲特許文献1には、無色透明クリヤー塗料に硬化剤とシンナーとを混合した塗料原液に、分散剤、沈降防止剤および蓄光材料が混合されている蓄光塗料が開示されている。
特開2000−109730号公報(第1−2頁、図1)
Also, even during the drying process of phosphorescent paints, the phosphorescent material particles can be kept uniformly diffused in the paint layer without settling, and compared with conventional phosphorescent paints without undercoating with white paint. There is a phosphorescent paint having a high luminous efficiency and a long emission time, and a method for using the same (for example, see Patent Document 1).
The above-mentioned Patent Document 1 discloses a phosphorescent paint in which a dispersant, an anti-settling agent, and a phosphorescent material are mixed in a paint stock solution obtained by mixing a colorless transparent clear paint with a curing agent and thinner.
JP 2000-109730 A (page 1-2, FIG. 1)

しかしながら、蓄光剤を樹脂中に混合して造形物を形成したり、塗料原液に混合したりして蓄光塗料として使用する場合、蓄光材料の粒子の直径を7μm〜30μm程度にパウダー化する必要があり、多くの手間とコスト高に繋がるという問題があった。また、100μm以上の大径粒状の蓄光剤を塗料原液に混ぜて使用した場合、大径粒状蓄光剤と塗料の比重が格段に違うので、吹き付け塗装をしても粘着液のみが張り付き、蓄光剤は落下してしまい塗装にはならなかった。  However, when a phosphorescent agent is mixed in a resin to form a modeled object or mixed with a coating stock solution and used as a phosphorescent paint, it is necessary to make the particle diameter of the phosphorescent material into a powder of about 7 μm to 30 μm. There was a problem that it led to many troubles and high costs. Also, when a large-diameter granular phosphorescent agent with a particle size of 100 μm or more is mixed with the paint stock solution, the specific gravity of the large-diameter granular phosphorescent agent and the paint is significantly different. Fell and did not paint.

そこで本発明は上記の点に鑑み、大径粒状蓄光剤の活用により、従来よりも高輝度の確保と残光時間の延長が可能で、さらに、蓄光剤と結合材の混合一液により、塗装工程の簡易化を実現する強度粘着一液式蓄光塗料を提供することにある。  Therefore, in view of the above points, the present invention can ensure a higher luminance and extend the afterglow time than before by using a large-diameter granular phosphorescent agent, and further, can be applied with a mixed liquid of the phosphorescent agent and a binder. An object of the present invention is to provide a strength-adhesive one-part phosphorescent paint that can simplify the process.

上記問題を解決するために本発明の強度粘着一液式蓄光塗料は、蓄光剤と、アクリル系合成樹脂エマルジョンに増粘剤と造膜助剤を加えた結合材とを混合して形成されることを特徴とする。  In order to solve the above problem, the strength-adhesive one-component phosphorescent paint of the present invention is formed by mixing a phosphorescent agent and a binder obtained by adding a thickener and a film-forming aid to an acrylic synthetic resin emulsion. It is characterized by that.

蓄光剤と、アクリル系合成樹脂エマルジョンに増粘剤と造膜助剤を加えた結合材とを混合するため、高い粘着力が得られ100μm以上の大径粒状の蓄光剤を使用することが可能になる。また、壁面や天井表面の塗布材として使用した場合でも、乾燥後、蓄光剤が剥がれ落ちるといった問題を解消できる。また、蓄光材料の粒子の直径を7μm〜30μm程度にパウダー化する必要もなく、作業効率の向上とコスト削減も実現できる。さらに、大径粒状蓄光剤の活用により、高輝度の確保と残光時間の延長が可能になる。  Mixing a phosphorescent agent and a binder with a thickening agent and a film-forming aid added to an acrylic synthetic resin emulsion, it is possible to use a large-diameter granular phosphorescent agent with a high adhesive strength of 100 μm or more. become. Moreover, even when it is used as a coating material on the wall surface or ceiling surface, the problem that the phosphorescent agent peels off after drying can be solved. Moreover, it is not necessary to make the diameter of the phosphorescent material particles into a powder of about 7 μm to 30 μm, and it is possible to improve work efficiency and reduce costs. Furthermore, by using a large-diameter granular phosphorescent agent, it is possible to ensure high luminance and extend the afterglow time.

以下、本発明における強度粘着一液式蓄光塗料の実施の形態を図面に基づき説明する。
図1に示す強度粘着一液式蓄光塗料1は、蓄光剤2と、アクリル系合成樹脂エマルジョンに増粘剤と造膜助剤を加えたと結合材3とを混合することにより形成される。また前記強度粘着一液式蓄光塗料1は、優れた粘着力を有するため、壁面や天井表面の塗布材として幅広く使用することができる。さらに本発明の強度粘着一液式蓄光塗料1は、前記蓄光剤2と結合材3との混合一液からなるため、塗装工程の簡易化も図れる。
DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, embodiments of a strength-adhesive one-component phosphorescent paint according to the present invention will be described with reference to the drawings.
The strength-adhesive one-component phosphorescent paint 1 shown in FIG. 1 is formed by mixing a phosphorescent agent 2 and a binder 3 with a thickener and a film-forming aid added to an acrylic synthetic resin emulsion. Moreover, since the said strong adhesion one-pack type phosphorescent paint 1 has the outstanding adhesive force, it can be used widely as a coating material of a wall surface or a ceiling surface. Furthermore, the strength-adhesive one-component phosphorescent paint 1 according to the present invention comprises a mixed one-component solution of the phosphorescent agent 2 and the binder 3, so that the painting process can be simplified.

図2の(a)に示す蓄光剤2は、太陽光や照明器具等の光を蓄え、暗闇や夜間において幻想的な蛍光色を自然発光するもので、例えば、アルミン酸ストロンチューム系の蓄光剤が挙げられる。またその他、周知の金属化合物や希土類を複数混合し、汎用の展色剤を混合して生成されるものを使用してもよく、素材やその混合比率は特に限定されたものではない。  The phosphorescent agent 2 shown in FIG. 2 (a) accumulates light such as sunlight or lighting equipment and spontaneously emits a fantastic fluorescent color in the dark or at night. For example, a strontium aluminate-based phosphorescent agent Is mentioned. In addition, a material produced by mixing a plurality of known metal compounds or rare earths and mixing a general-purpose color developing agent may be used, and the material and the mixing ratio thereof are not particularly limited.

また蓄光剤2の径aは100μm以上、特に150μm〜5000μmまでの大径粒状の蓄光剤を使用することができる。そのことにより、粉砕機を利用して蓄光材料の粒子を7μm〜30μm程度にパウダー化する必要もなく、作業効率の向上とコストの削減が実現できる。  Moreover, the diameter a of the phosphorescent agent 2 is 100 μm or more, and in particular, a large-diameter granular phosphorescent agent having a diameter of 150 μm to 5000 μm can be used. Thereby, it is not necessary to powder the phosphorescent material particles to about 7 μm to 30 μm by using a pulverizer, and it is possible to improve work efficiency and reduce costs.

図2の(b)に示す結合材3は、アクリル系合成樹脂エマルジョンに増粘剤と造膜助剤を加えることにより形成され、前記蓄光剤2を混合した際、高い粘着力を発揮する。そのことにより、例えば壁面や天井表面に塗布した場合、乾燥後でも蓄光剤が剥がれ落ちるといった問題を解消できる。  The binder 3 shown in FIG. 2 (b) is formed by adding a thickener and a film-forming aid to an acrylic synthetic resin emulsion, and exhibits high adhesive strength when the phosphorescent agent 2 is mixed. Thereby, for example, when applied to a wall surface or a ceiling surface, the problem that the phosphorescent agent is peeled off even after drying can be solved.

また前記結合材3を構成するアクリル系合成樹脂エマルジョンと増粘剤と造膜助剤との混合比率は特に限定されず、用途や使用する場所、また温度や湿度に応じて適宜調整することが好ましい。さらに、前記蓄光剤2と結合材3との混合比率も特に限定はなく、発光輝度やコストに応じて調整することが望ましい。  Moreover, the mixing ratio of the acrylic synthetic resin emulsion, the thickener and the film-forming aid constituting the binder 3 is not particularly limited, and can be appropriately adjusted according to the use, the place where it is used, and the temperature and humidity. preferable. Furthermore, the mixing ratio of the phosphorescent agent 2 and the binder 3 is not particularly limited, and it is desirable to adjust according to the light emission luminance and cost.

また前記構造の強度粘着一液式蓄光塗料1は、刷毛等を利用し壁面や天井表面に塗布することができるが、水を添加し希釈することで、リスタガンやリシンガンに詰めて吹き付け塗布することも可能となる。  The strength-adhesive one-component phosphorescent paint 1 having the above structure can be applied to the wall surface or ceiling surface using a brush or the like. Is also possible.

容器に収容された強度粘着一液式蓄光塗料を示す。The strength adhesion one-pack type phosphorescent paint contained in a container is shown. (a)は容器に収容された蓄光剤を(b)は結合材を示す。(A) shows the luminous agent accommodated in the container, and (b) shows the binder.

符号の説明Explanation of symbols

1・・・強度粘着一液式蓄光塗料
2・・・蓄光剤
3・・・結合材
a・・・蓄光剤の径
DESCRIPTION OF SYMBOLS 1 ... Strength adhesive one-component type phosphorescent paint 2 ... Phosphorescent agent 3 ... Binding material a ... Diameter of phosphorescent agent

Claims (1)

蓄光剤と、アクリル系合成樹脂エマルジョンに増粘剤と造膜助剤を加えた結合材とを混合して形成されることを特徴とする強度粘着一液式蓄光塗料。  A strength-adhesive one-part phosphorescent paint characterized by being formed by mixing a phosphorescent agent and a binder obtained by adding a thickener and a film-forming aid to an acrylic synthetic resin emulsion.
JP2006079725A 2006-02-22 2006-02-22 Strongly adhering one pot type luminous coating Pending JP2007224257A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103937344A (en) * 2014-03-20 2014-07-23 常熟市方塔涂料化工有限公司 Long-acting luminous paint and its preparation method
CN109651898A (en) * 2019-01-24 2019-04-19 苏州拓博琳新材料科技有限公司 A kind of aqueous self-luminous gage mark coating and preparation method thereof
CN113321961A (en) * 2021-06-17 2021-08-31 浙江億帆节能科技有限公司 Paint for light-storage type self-luminous colorful light supplementing lamp

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103937344A (en) * 2014-03-20 2014-07-23 常熟市方塔涂料化工有限公司 Long-acting luminous paint and its preparation method
CN109651898A (en) * 2019-01-24 2019-04-19 苏州拓博琳新材料科技有限公司 A kind of aqueous self-luminous gage mark coating and preparation method thereof
CN113321961A (en) * 2021-06-17 2021-08-31 浙江億帆节能科技有限公司 Paint for light-storage type self-luminous colorful light supplementing lamp

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