CN113321961A - Paint for light-storage type self-luminous colorful light supplementing lamp - Google Patents
Paint for light-storage type self-luminous colorful light supplementing lamp Download PDFInfo
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- CN113321961A CN113321961A CN202110674114.4A CN202110674114A CN113321961A CN 113321961 A CN113321961 A CN 113321961A CN 202110674114 A CN202110674114 A CN 202110674114A CN 113321961 A CN113321961 A CN 113321961A
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- fatty acid
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/22—Luminous paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/29—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Luminescent Compositions (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a light-storage self-luminous colorful paint for a light supplementing lamp, which comprises the following components in parts by weight: acrylic varnish 150 and 230 parts; 80-130 parts of light-storing luminescent powder; 20-35 parts of a filler; 2-3 parts of a silane coupling agent; 6-10 parts of an accelerant; 0.2-0.5 part of fluorescent powder; the filler is calcium carbonate or a mixture of calcium carbonate and kaolin which are mixed according to any proportion; the invention is easy to coat and has good adhesion performance, thus being beneficial to market popularization and application.
Description
Technical Field
The invention relates to the technical field of coatings, in particular to a coating for a light-storing self-luminous colorful light supplement lamp.
Background
The light-storing luminous paint is one kind of light functional paint, which absorbs and stores light energy under the irradiation of sunlight, lamplight and other visible light, releases the absorbed energy slowly in the form of visible light after the illumination is stopped, and repeats the processes of light absorption, light storage, light emission and light absorption. The light-storing luminous paint is one of special functional paints in the 21 st century, and has the advantages of super-long afterglow, high luminous brightness, long luminous time and the like, and has wide application.
Among the prior art, in view road construction field, in order to satisfy the road at the lighting needs on night energy can be saved simultaneously, generally can set the road into the road surface of self-luminous, simultaneously in order to guarantee the illuminating effect on self-luminous road surface, still can set up a light filling lamp in illumination condition relatively poor position department, and in order to further save the energy when the light filling lamp uses, still generally can be used for improving the illuminating effect of light filling lamp at the inside irradiant position department coating one deck energy storage type self-luminous coating of light filling lamp, the most adhesion performance of energy storage type self-luminous coating of conventional use among the prior art is relatively poor, user effect can's requirement can't be satisfied.
Disclosure of Invention
In order to solve the problems, the invention provides the light-storing type self-luminous colorful paint for the light supplement lamp, which is easy to coat and has good adhesion performance.
The invention adopts the following technical scheme:
the paint for the light-storing type self-luminous colorful light supplementing lamp comprises the following components in parts by weight:
acrylic varnish 150 and 230 parts;
80-130 parts of light-storing luminescent powder;
20-35 parts of a filler;
2-3 parts of a silane coupling agent;
6-10 parts of an accelerant;
0.2-0.5 part of fluorescent powder;
the filler is calcium carbonate or a mixture of calcium carbonate and kaolin which are mixed according to any proportion;
as a preferred technical scheme of the invention, the calcium carbonate is active nano calcium carbonate modified by a surface modifier;
as a preferred technical scheme of the invention, the surface modifier is prepared from the following components in parts by weight:
1-1.5 parts of DOP;
8-10 parts of saturated fatty acid saponification liquid;
4-5 parts of polyamide wax;
as a preferred technical scheme of the invention, the preparation process of the saponification solution of saturated fatty acid is as follows:
step 1, heating distilled water to 95-100 ℃,
step 2, adding sodium hydroxide into distilled water, and stirring until the sodium hydroxide is fully dissolved;
step 3, adding saturated fatty acid into the solution obtained in the step 2 for saponification, and continuously heating for 30-40 min to obtain saponification liquid of the saturated fatty acid;
the proportion of the distilled water, the sodium hydroxide and the saturated fatty acid is as follows:
distilled water: sodium hydroxide: saturated fatty acids =100 ml: (10-20) g: (6-15) g.
As a preferable technical scheme of the invention, the accelerator comprises the following components in parts by weight:
oxalic acid 20-35 parts
18-25 parts of chlorinated polyolefin
30-45 parts of ethyl acetate
The invention has the beneficial effects that:
according to the invention, the adhesion performance between the paint and a light supplement lamp can be effectively realized by adding the accelerator containing oxalic acid and chlorinated polyolefin and the silane coupling agent in the paint when the paint is used; meanwhile, the active nano calcium carbonate acting filler modified by the polyamide wax is added into the coating, so that the thixotropy of the coating in use can be effectively improved, and the coating is easier to coat in use.
Detailed Description
The present invention will now be described in further detail with reference to examples.
Example 1
The paint for the light-storing type self-luminous colorful light supplementing lamp comprises the following components in parts by weight:
150 parts of acrylic varnish;
80 parts of light-storing luminescent powder;
20 parts of a filler;
2 parts of a silane coupling agent;
6 parts of an accelerant;
0.2 part of fluorescent powder;
the filler is calcium carbonate or a mixture of calcium carbonate and kaolin which are mixed according to any proportion;
the calcium carbonate is active nano calcium carbonate modified by a surface modifier;
the surface modifier is prepared from the following components in parts by weight:
15 parts of DOP;
8 parts of saturated fatty acid saponification liquid;
4 parts of polyamide wax;
the preparation process of the saponification solution of saturated fatty acid is as follows:
step 1, heating distilled water to 95-100 ℃,
step 2, adding sodium hydroxide into distilled water, and stirring until the sodium hydroxide is fully dissolved;
step 3, adding saturated fatty acid into the solution obtained in the step 2 for saponification, and continuously heating for 30-40 min to obtain saponification liquid of the saturated fatty acid;
the proportion of the distilled water, the sodium hydroxide and the saturated fatty acid is as follows:
distilled water: sodium hydroxide: saturated fatty acids =100 ml: 10 g: 6 g.
The accelerant comprises the following components in parts by weight:
oxalic acid 20 parts
Chlorinated polyolefin 18 parts
30 portions of ethyl acetate
Example 2
The paint for the light-storing type self-luminous colorful light supplementing lamp comprises the following components in parts by weight:
230 parts of acrylic varnish;
130 parts of light-storing luminescent powder;
35 parts of a filler;
3 parts of a silane coupling agent;
10 parts of an accelerator;
0.5 part of fluorescent powder;
the filler is calcium carbonate or a mixture of calcium carbonate and kaolin which are mixed according to any proportion;
the calcium carbonate is active nano calcium carbonate modified by a surface modifier;
the surface modifier is prepared from the following components in parts by weight:
1.5 parts of DOP;
10 parts of saturated fatty acid saponification liquid;
5 parts of polyamide wax;
the preparation process of the saponification solution of saturated fatty acid is as follows:
step 1, heating distilled water to 95-100 ℃,
step 2, adding sodium hydroxide into distilled water, and stirring until the sodium hydroxide is fully dissolved;
step 3, adding saturated fatty acid into the solution obtained in the step 2 for saponification, and continuously heating for 30-40 min to obtain saponification liquid of the saturated fatty acid;
the proportion of the distilled water, the sodium hydroxide and the saturated fatty acid is as follows:
distilled water: sodium hydroxide: saturated fatty acids =100 ml: 20 g: 15 g.
The accelerant comprises the following components in parts by weight:
oxalic acid 35 parts
Chlorinated polyolefin 25 parts
Ethyl acetate 45 parts
Example 3
The paint for the light-storing type self-luminous colorful light supplementing lamp comprises the following components in parts by weight:
200 parts of acrylic varnish;
100 parts of light-storing luminescent powder;
30 parts of a filler;
3 parts of a silane coupling agent;
8 parts of an accelerator;
0.3 part of fluorescent powder;
the filler is calcium carbonate or a mixture of calcium carbonate and kaolin which are mixed according to any proportion;
the calcium carbonate is active nano calcium carbonate modified by a surface modifier;
the surface modifier is prepared from the following components in parts by weight:
1 part of DOP;
9 parts of saturated fatty acid saponification liquid;
4 parts of polyamide wax;
the preparation process of the saponification solution of saturated fatty acid is as follows:
step 1, heating distilled water to 95-100 ℃,
step 2, adding sodium hydroxide into distilled water, and stirring until the sodium hydroxide is fully dissolved;
step 3, adding saturated fatty acid into the solution obtained in the step 2 for saponification, and continuously heating for 30-40 min to obtain saponification liquid of the saturated fatty acid;
the proportion of the distilled water, the sodium hydroxide and the saturated fatty acid is as follows:
distilled water: sodium hydroxide: saturated fatty acids =100 ml: 15 g: 10 g.
The accelerant comprises the following components in parts by weight:
oxalic acid 30 parts
Chlorinated polyolefin 20 parts
40 parts of ethyl acetate
Finally, it should be noted that: these embodiments are merely illustrative of the present invention and do not limit the scope of the present invention. In addition, other variations and modifications will be apparent to persons skilled in the art based on the foregoing description. And are neither required nor exhaustive of all embodiments. And obvious variations or modifications of the invention may be made without departing from the scope of the invention.
Claims (5)
1. The paint for the light-storing type self-luminous colorful light supplementing lamp comprises the following components in parts by weight:
acrylic varnish 150 and 230 parts;
80-130 parts of light-storing luminescent powder;
20-35 parts of a filler;
2-3 parts of a silane coupling agent;
6-10 parts of an accelerant;
0.2-0.5 part of fluorescent powder;
the filler is calcium carbonate or a mixture of calcium carbonate and kaolin which are mixed according to any proportion.
2. The paint for the light-accumulating self-luminous colorful supplementary light lamp according to claim 1, characterized in that: the calcium carbonate is active nano calcium carbonate modified by adopting a surface modifier.
3. The paint for the light-accumulating type self-luminous colorful supplementary light lamp according to claim 2, characterized in that: the surface modifier is prepared from the following components in parts by weight:
1-1.5 parts of DOP;
8-10 parts of saturated fatty acid saponification liquid;
4-5 parts of polyamide wax.
4. The paint for the light-accumulating self-luminous colorful supplementary light lamp according to claim 3, characterized in that: the preparation process of the saponification solution of saturated fatty acid is as follows:
step 1, heating distilled water to the temperature of 95-100 ℃;
step 2, adding sodium hydroxide into distilled water, and stirring until the sodium hydroxide is fully dissolved;
step 3, adding saturated fatty acid into the solution obtained in the step 2 for saponification, and continuously heating for 30-40 min to obtain saponification liquid of the saturated fatty acid;
the proportion of the distilled water, the sodium hydroxide and the saturated fatty acid is as follows:
distilled water: sodium hydroxide: saturated fatty acids =100 ml: (10-20) g: (6-15) g.
5. The paint for the light-accumulating self-luminous colorful supplementary light lamp according to claim 1, characterized in that: the accelerant comprises the following components in parts by weight:
oxalic acid 20-35 parts
18-25 parts of chlorinated polyolefin
30-45 parts of ethyl acetate.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN202110674114.4A CN113321961A (en) | 2021-06-17 | 2021-06-17 | Paint for light-storage type self-luminous colorful light supplementing lamp |
Applications Claiming Priority (1)
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CN202110674114.4A CN113321961A (en) | 2021-06-17 | 2021-06-17 | Paint for light-storage type self-luminous colorful light supplementing lamp |
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CN113321961A true CN113321961A (en) | 2021-08-31 |
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CN202110674114.4A Pending CN113321961A (en) | 2021-06-17 | 2021-06-17 | Paint for light-storage type self-luminous colorful light supplementing lamp |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007224257A (en) * | 2006-02-22 | 2007-09-06 | Kazuo Saito | Strongly adhering one pot type luminous coating |
CN104497634A (en) * | 2014-11-25 | 2015-04-08 | 广西华纳新材料科技有限公司 | Preparation method of nano calcium carbonate used for weather proofing silicone sealant |
CN104629568A (en) * | 2015-02-04 | 2015-05-20 | 陕西世纪交通工程有限公司 | Full-color three-dimensional self-luminous road line paint and preparation method thereof |
CN110982301A (en) * | 2019-11-01 | 2020-04-10 | 连州市凯恩斯纳米材料有限公司 | Nano calcium carbonate with plasticizing function and preparation method thereof |
CN112143308A (en) * | 2020-08-14 | 2020-12-29 | 江苏固迈新材料技术有限公司 | Light-storage self-luminous coating |
-
2021
- 2021-06-17 CN CN202110674114.4A patent/CN113321961A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007224257A (en) * | 2006-02-22 | 2007-09-06 | Kazuo Saito | Strongly adhering one pot type luminous coating |
CN104497634A (en) * | 2014-11-25 | 2015-04-08 | 广西华纳新材料科技有限公司 | Preparation method of nano calcium carbonate used for weather proofing silicone sealant |
CN104629568A (en) * | 2015-02-04 | 2015-05-20 | 陕西世纪交通工程有限公司 | Full-color three-dimensional self-luminous road line paint and preparation method thereof |
CN110982301A (en) * | 2019-11-01 | 2020-04-10 | 连州市凯恩斯纳米材料有限公司 | Nano calcium carbonate with plasticizing function and preparation method thereof |
CN112143308A (en) * | 2020-08-14 | 2020-12-29 | 江苏固迈新材料技术有限公司 | Light-storage self-luminous coating |
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Application publication date: 20210831 |