JP2007202417A - Oil-in-water emulsified substance for frozen dessert - Google Patents

Oil-in-water emulsified substance for frozen dessert Download PDF

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JP2007202417A
JP2007202417A JP2006021960A JP2006021960A JP2007202417A JP 2007202417 A JP2007202417 A JP 2007202417A JP 2006021960 A JP2006021960 A JP 2006021960A JP 2006021960 A JP2006021960 A JP 2006021960A JP 2007202417 A JP2007202417 A JP 2007202417A
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oil
fat
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milk
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JP4466577B2 (en
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Hiroyuki Ichiyama
裕之 市山
Hiroshi Hidaka
博志 日高
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Fuji Oil Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide oil-in-water emulsified substance for frozen dessert excellent in palate feeling, meltability in the mouth, flavor and retention of milk taste. <P>SOLUTION: The oil-in-water emulsified substance for frozen dessert contains oil and fat, non-fat milk solid and water, wherein the oil and fat contains S2L-type triglyceride (wherein, S in the formula is stearic acid and palmitic acid, and L is linoleic acid). The oil and fat content accounts for 2-20 wt.%, the oil and fat comprises non dairy cream [(A) type], or a combination of non dairy cream and dairy cream (B type). The S2L-type triglyceride in the (A) type oil and fat accounts for 1-20 wt.%, and the S2L-type triglyceride in the B type oil and fat accounts for 2-30 wt.%. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は、アイスクリーム、アイスミルク、ラクトアイス等の冷菓用水中油型乳化物の食感、乳味の持続性の改良に関する。   The present invention relates to improving the texture and milky taste sustainability of oil-in-water emulsions for frozen desserts such as ice cream, ice milk, and lacto ice.

アイスクリーム類の食感、口溶け、乳味の持続性を改良するにあたり、特許文献1では油脂のシャープな口溶けを意図してココアバターを冷菓に使用することが提案されている。しかしココアバターのような主として対称型トリグリセリド(SUS)を含有する油脂は乳化状態が不安定となり、アイスクリーム類の製造工程において調製されるミックス液の安定性が悪く、ボテ(可塑性)現象を呈したり、またフリージング工程において解乳化現象を起こしやすく、脂肪凝集を発生したりして、製品の口溶けを重くする等、種々欠点を有しており、特にこの傾向は油脂配合率が高い場合に顕著である。さらにココア風味という限定された風味であり、冷菓全般に利用できるような汎用性は期待できない。
特許文献2では脂肪源としてヤシ油60〜80%とパーム油40〜20%との混合油を冷菓に使用することが提案されている。しかしながらヤシ油が多いとシャープな融解性状を示すものの食感及び風味の点でコクがない。また、パーム油あるいは菜種油は安価であるが口溶けの点で好ましくなく、かつ冷菓としてのキメや組織が不良となる。
特許文献3では対称型トリグリセリド(SUS)を40%以上含有する油脂95〜40%とラウリン系油脂5〜60%を含有する冷菓用油脂が提案されている。これは口溶けのシャープさ、キレに効果を発揮するものであった。本発明のような特定の油脂の使用による食感、口溶け、乳味の持続性等の改良を図った例を見ることは出来ない。
In improving the texture, melting in the mouth and persistence of milky taste of ice creams, Patent Document 1 proposes the use of cocoa butter in a frozen dessert with the intention of sharp melting of fats and oils. However, fats and oils containing mainly symmetric triglycerides (SUS) such as cocoa butter are unstable in the emulsified state, the stability of the mixed liquid prepared in the manufacturing process of ice creams is poor, and the phenomenon of plasticity is exhibited. In addition, it tends to cause a demulsification phenomenon in the freezing process, and it has various disadvantages such as fat agglomeration and heavy melting of the product. Especially, this tendency is remarkable when the fat and oil content is high. It is. Furthermore, it is a limited flavor called cocoa flavor, and versatility that can be used for all frozen desserts cannot be expected.
Patent Document 2 proposes to use a mixed oil of palm oil 60 to 80% and palm oil 40 to 20% as a fat source in a frozen dessert. However, when there is much coconut oil, although it shows a sharp melting property, there is no richness in terms of texture and flavor. Palm oil or rapeseed oil is inexpensive but is not preferable in terms of melting in the mouth, and texture and texture as a frozen dessert are poor.
Patent Document 3 proposes a fat and oil for frozen desserts containing 95 to 40% fat and oil containing 40% or more of symmetric triglyceride (SUS) and 5 to 60% lauric fat and oil. This was effective for the sharpness and sharpness of melting in the mouth. The example which aimed at improvement of the food texture by the use of specific fats and oils like this invention, a mouth melt, the sustainability of milky taste cannot be seen.

特開平4−316453号公報JP-A-4-316453 特開昭57−36943号公報JP 57-36943 A 特開平8−298934号公報JP-A-8-298934

本発明の目的は、食感、口溶け、風味、乳味の持続性に優れている冷菓用水中油型乳化物を提供する事にある。   An object of the present invention is to provide an oil-in-water emulsion for frozen desserts that is excellent in texture, mouth melt, flavor, and milky sustainability.

本発明者らは鋭意研究を行った結果、油脂中に特定の油脂、S2L型トリグリセリドを特定量使用することによって、本発明の目的を達成し、本発明を完成するに至った。即ち本発明の第1は、油脂、無脂乳固形分及び水を含む水中油型乳化物において、油脂中にS2L型トリグリセリド(但し、式中のSはステアリン酸及びパルミチン酸、Lはリノール酸)を含有することを特徴とする冷菓用水中油型乳化物である。第2は、油脂分が2〜20重量%である、第1記載の冷菓用水中油型乳化物である。第3は、油脂が非乳脂(Aタイプ)又は、非乳脂及び乳脂(Bタイプ)であって、Aタイプの場合は油脂中のS2L型トリグリセリドが1〜20重量%の範囲であり、Bタイプの場合は2〜30重量%の範囲である、第1記載の冷菓用水中油型乳化物である。   As a result of intensive studies, the present inventors have achieved the object of the present invention and completed the present invention by using a specific amount of specific fat and oil, S2L type triglyceride in the fat and oil. That is, the first of the present invention is an oil-in-water emulsion containing fats and oils, non-fat milk solids and water, and S2L-type triglycerides in the fats and oils (wherein S is stearic acid and palmitic acid, L is linoleic acid) ) In an oil-in-water emulsion for frozen desserts. The second is the oil-in-water emulsion for frozen desserts according to the first aspect, wherein the fat and oil content is 2 to 20% by weight. Third, the fat is non-milk fat (A type) or non-milk fat and milk fat (B type), and in the case of the A type, the S2L type triglyceride in the fat is in the range of 1 to 20% by weight. Is the oil-in-water emulsion for frozen desserts according to the first aspect, in the range of 2 to 30% by weight.

本発明により、食感特に滑らかな食感を有し、口溶け、風味、乳味の持続性に優れた冷菓用水中油型乳化物を提供することが可能になった。   According to the present invention, it is possible to provide an oil-in-water emulsion for frozen dessert that has a texture, particularly a smooth texture, and is excellent in meltability in the mouth, flavor, and milky taste.

本発明の冷菓用水中油型乳化物は、油脂、無脂乳固形分及び水を含む水中油型乳化物において、油脂中にS2L型トリグリセリド(但し、式中のSはステアリン酸及びパルミチン酸、Lはリノール酸)を含有する必要がある。
アイスクリーム類は、わが国の乳及び乳製品の成分規格等に関する省令(乳等省令)によると、乳固形分15%以上うち乳脂肪8%以上のものをアイスクリームと称し、アイスミルクは乳固形分10%以上うち乳脂肪3%以上のもの、ラクトアイスは乳固形分3%以上のものと規定されている。
本発明において「冷菓」とは、「アイスクリーム」「アイスミルク」及び「ラクトアイス」を包含するものであって、これらに類するものである。
The oil-in-water emulsion for frozen desserts of the present invention is an oil-in-water emulsion containing fats and oils, non-fat milk solids and water, and S2L-type triglycerides in fats and oils (wherein S is stearic acid and palmitic acid, L Must contain linoleic acid).
According to the ministerial ordinance on milk and dairy product ingredients in Japan (Ministerial Ordinance for Milk, etc.), ice cream is called ice cream when its milk content is 15% or more and milk fat is 8% or more. It is specified that milk fat is 3% or more out of 10% or more and lacto ice is milk solid content of 3% or more.
In the present invention, “frozen confectionery” includes “ice cream”, “ice milk”, and “lacto ice”, and is similar to these.

本発明でいうS2L型トリグリセリドとは、Sはステアリン酸St、パルミチン酸Pの飽和脂肪酸であり、Lはリノール酸の多価不飽和脂肪酸であり、Lがα位に結合したSSL、β位に結合したSLS及びそれらの混合物のいずれでもよいが β位に結合したSLSが好ましい。
そして、S2L型トリグリセリドの量Yは、Y=Ys+Ypで表わせれ、YsはSt2L型トリグリセリドの量を表わし、YpはP2L型トリグリセリドの量を表わす。
S2L型トリグリセリドはリノール酸を多く含む油脂、例えばサフラワー油、ひまわり油、コーン油、菜種油、大豆油とりわけ前2者の油脂を飽和脂肪酸(ステアリン酸、パルミチン酸)に富むエステル又は脂肪酸と公知の方法でエステル交換し、必要に応じて分別を行うことにより得られる。
又、S2L型トリグリセリドを多く含む油脂例えば綿実油等から分別し高濃度に含有するS2L含有油脂を使用するのが好ましく、濃度としては40%以上含有するのが好ましい。
The S2L type triglyceride referred to in the present invention is S is a saturated fatty acid of Stearic acid St and palmitic acid P, L is a polyunsaturated fatty acid of linoleic acid, L is SSL bonded to α-position, and β-position Any of bound SLS and mixtures thereof may be used, but SLS bound to the β-position is preferred.
The amount Y of S2L type triglyceride can be expressed as Y = Ys + Yp, Ys represents the amount of St2L type triglyceride, and Yp represents the amount of P2L type triglyceride.
S2L-type triglycerides are known as fats and oils rich in linoleic acid, such as safflower oil, sunflower oil, corn oil, rapeseed oil, soybean oil, especially the former two fats and esters or fatty acids rich in saturated fatty acids (stearic acid, palmitic acid). It is obtained by performing transesterification by a method and performing fractionation as necessary.
In addition, it is preferable to use S2L-containing oils and fats that are separated from oils and fats containing a large amount of S2L-type triglycerides, such as cottonseed oil, and contained in high concentrations, and the concentration is preferably 40% or more.

本発明におけるS2L型トリグリセリド以外の油脂としては、動植物性油脂及びそれらの硬化油脂の単独又は2種以上の混合物或いはこれらのものに種々の化学処理又は物理処理を施したものが例示できる。かかる油脂の由来としては、大豆油、綿実油、コーン油、サフラワー油、オリーブ油、パーム油、菜種油、米ぬか油、ゴマ油、カポック油、ヤシ油、パーム核油、乳脂、ラード、魚油、鯨油等の各種の動植物油脂及びそれらの硬化油、分別油、エステル交換油等の加工油脂(融点15〜40℃程度のもの)が例示できる。
本発明での乳脂は、牛乳、生クリーム、バター等の乳由来の乳脂はもちろんのこと、これらの原料を加工処理して得られるバターオイルも含むのもである。
油脂分は2〜20重量%が好ましく、さらに好ましくは3〜18重量%、最も好ましくは3〜16重量%である。
油脂分が少ないと、冷菓用水中油型乳化物の風味、コク味が乏しいものとなってしまう。油脂分が多いと口溶けが悪くなったり、食感が重たくなったり、ミックス液の乳化安定性が悪くなる。
Examples of the fats and oils other than S2L type triglycerides in the present invention include animal and vegetable oils and fats and hardened fats and oils, or a mixture of two or more thereof, or those obtained by subjecting them to various chemical treatments or physical treatments. Such fats and oils include soybean oil, cottonseed oil, corn oil, safflower oil, olive oil, palm oil, rapeseed oil, rice bran oil, sesame oil, kapok oil, coconut oil, palm kernel oil, milk fat, lard, fish oil, whale oil, etc. Examples include various types of animal and plant oils and fats, processed oils and fats thereof such as hydrogenated oils, fractionated oils, and transesterified oils (having a melting point of about 15 to 40 ° C.).
The milk fat in the present invention includes butter oil obtained by processing these raw materials as well as milk fat derived from milk such as milk, fresh cream and butter.
The oil and fat content is preferably 2 to 20% by weight, more preferably 3 to 18% by weight, and most preferably 3 to 16% by weight.
If the oil and fat content is low, the flavor and richness of the oil-in-water emulsion for frozen desserts will be poor. When there is much oil and fat content, mouth meltability will worsen, food texture will become heavy, and the emulsification stability of a mix liquid will worsen.

本発明の冷菓用水中油型乳化物は、「アイスクリーム」「アイスミルク」及び「ラクトアイス」を包含するものであって、これらに類するものであり、冷菓用水中油型乳化物に乳味やコク味を付与しようとする場合は、従来乳固形分の量を多く特に乳脂を多くするという方法が採用されてきた。このような内容において冷菓用水中油型乳化物の油脂は形態として、非乳脂、非乳脂及び乳脂、乳脂の3つに大別できる。
冷菓用油脂としては段落番号〔0009〕に挙げた油脂から適宜選択して使用するのであるが非乳脂の場合は、ヤシ油、パーム油、パーム核油、菜種油、米ぬか油、大豆油、綿実油、コーン油等の各種の油脂及びそれらの硬化油、分別油、エステル交換油等の油脂を使用するのが好ましい。これらの油脂を使用した場合口溶け、冷感に優れているがコク味、乳味の持続性は不充分であった。S2L型トリグリセリドを含有することにより、コク味、乳味の持続性を得ることができる。
本発明におけるS2L型トリグリセリドの含有量は非乳脂(Aタイプ)の場合は、油脂中の1〜20重量%であり、さらに好ましくは2〜20重量%であり、最も好ましくは3〜20重量%である。
S2L型トリグリセリドの含有量が少ないと滑らかな食感が得難くなり、乳味の持続性が乏しいものとなる。多すぎるとより滑らかにはなるが、甘味とのバランスが悪くなり好ましくない。。
S2L型トリグリセリドのこのような効果は他の油脂では見られないS2L型トリグリセリドの特異な結晶性癖によると推察している。
The oil-in-water emulsion for frozen desserts of the present invention includes “ice cream”, “ice milk” and “lacto ice”, and is similar to these. In the case of trying to impart the amount of milk, conventionally, a method of increasing the amount of milk solids and particularly increasing the amount of milk fat has been adopted. In such contents, the fats and oils of the oil-in-water emulsion for frozen desserts can be roughly classified into three types: non-milk fat, non-milk fat, milk fat, and milk fat.
As the fats and oils for frozen dessert, it is used by appropriately selecting from the fats and oils listed in paragraph [0009], but in the case of non-milk fats, palm oil, palm oil, palm kernel oil, rapeseed oil, rice bran oil, soybean oil, cottonseed oil, It is preferable to use various fats and oils such as corn oil and fats and oils such as hardened oil, fractionated oil and transesterified oil. When these fats and oils were used, they melted in the mouth and were excellent in cold feeling, but the sustainability of the richness and milky taste was insufficient. By containing the S2L type triglyceride, the sustainability of the richness and milky taste can be obtained.
In the case of non-milk fat (A type), the content of S2L type triglyceride in the present invention is 1 to 20% by weight, more preferably 2 to 20% by weight, and most preferably 3 to 20% by weight. It is.
When the content of the S2L type triglyceride is small, it becomes difficult to obtain a smooth texture and the milky taste is poor. If it is too much, it will become smoother, but the balance with sweetness will deteriorate, which is not preferable. .
It is speculated that such an effect of the S2L type triglyceride is due to the unique crystal habit of the S2L type triglyceride that is not found in other oils and fats.

冷菓用油脂に乳脂を含む場合もS2L型トリグリセリドの効果はS2L型トリグリセリドを使用することで、油っぽさ、ネタつきがなく、乳味の持続性を引き出すことが出来る。乳脂の比率が少なくても添加量以上の乳味を引き出すことができコストにおいてメリットが大きい。又、乳脂は動物性であるので健康面からも、植物性を使用することが望ましい。
本発明におけるS2L型トリグリセリドの含有量は非乳脂及び乳脂(Bタイプ)の場合は、油脂中の2〜30重量%であり、さらに好ましくは3〜30重量%であり、最も好ましくは4〜30重量%である。
S2L型トリグリセリドの含有量が少ないと乳味の持続性が乏しいものとなる。多すぎると甘味とのバランスが悪くなり好ましくない。
Even when milk fat is included in the fats and oils for frozen desserts, the effect of the S2L type triglyceride is not oily and sticky, and the sustainability of the milky taste can be derived by using the S2L type triglyceride. Even if the ratio of milk fat is small, the milk taste more than the added amount can be drawn, and the merit in cost is great. Moreover, since milk fat is animal, it is desirable to use plant nature also from a health viewpoint.
In the case of non-milk fat and milk fat (B type), the content of S2L type triglyceride in the present invention is 2 to 30% by weight, more preferably 3 to 30% by weight, and most preferably 4 to 30%. % By weight.
When there is little content of S2L type triglyceride, it will become a thing with insufficient sustainability of milky taste. If the amount is too large, the balance with sweetness is deteriorated.

冷菓用水中油型乳化物は油脂、無脂乳固形分及び水を含む水中油型乳化物であって、原料としては油脂類、乳類、乳製品、甘味料、安定剤、香料などを使用して、通常の水中油型乳化物の調製方法で得ることが出来る。冷菓としては、アイスクリーム、アイスミルク、ラクトアイス等が例示できる。   Oil-in-water emulsions for frozen desserts are oil-in-water emulsions containing fats and oils, non-fat milk solids and water, and use fats and oils, milk, dairy products, sweeteners, stabilizers, flavors, etc. as raw materials. And can be obtained by a conventional method for preparing an oil-in-water emulsion. Examples of frozen desserts include ice cream, ice milk, and lact ice.

本発明の無脂乳固形分としては、牛乳の全固形分から乳脂肪分を差し引いた成分をいい、生乳、牛乳、脱脂乳、生クリーム、濃縮乳、無糖練乳、加糖練乳、全脂粉乳、脱脂粉乳、バターミルクパウダー、ホエー蛋白、カゼイン、カゼインナトリウム等の乳由来の原料が例示でき、無脂乳固形分が1〜20重量%が好ましく、さらに好ましくは2〜18重量%、最も好ましくは3〜16重量%である。無脂乳固形分が少ない場合は、水中油型乳化物の乳化安定性が悪くなり、乳味感も少なくなって風味が悪くなる。多い場合は、水中油型乳化物の粘度が高くなり、コストも高くなり、量に見合った効果が得難くなる。   Non-fat milk solid content of the present invention refers to a component obtained by subtracting milk fat content from the total solid content of milk, raw milk, cow milk, skim milk, fresh cream, concentrated milk, sugar-free condensed milk, sweetened condensed milk, whole milk powder, Non-fat dry milk, buttermilk powder, whey protein, casein, sodium casein and other milk-derived raw materials can be exemplified, and the nonfat milk solid content is preferably 1 to 20% by weight, more preferably 2 to 18% by weight, most preferably 3 to 16% by weight. When there is little non-fat milk solid content, the emulsion stability of an oil-in-water emulsion will worsen, milky feeling will also decrease, and flavor will worsen. When the amount is large, the viscosity of the oil-in-water emulsion is increased, the cost is increased, and it is difficult to obtain an effect commensurate with the amount.

本発明の冷菓の代表的な例示がアイスクリーム類であって、アイスクリーム類を例にとって説明すると、アイスクリーム類の成分は、乳脂肪、無脂乳固形分、甘味料、安定剤、乳化剤、香味料、着色料、水分などからなる。
無脂乳固形分はアイスクリームの組織改善およびオーバーランの増加とともにアイスクリーム類へ乳味感を付与するという効果を有する。この乳固形分としては、脱脂乳、脱脂粉乳、全脂粉乳などが例示できる。
甘味料はアイスクリーム類に甘味を与えるほかミックスの粘性を増し組織を改良するという効果を有する。甘味料としてはショ糖がもっとも普通に使用されるが、他に転化糖、混合液糖、水飴等が使用され、通常全量に対し13〜17重量%程度使用される。
安定剤は組織を滑らかにし、適度の粘性を与え、オーバーランの調整に関与するという効果を有する。このような安定剤として、グアーガム、ローカストビーンガム、キサンタンガム、アラビアガムのようなガム類、カラギーナン、アルギン酸ナトリウム、CMC、水溶性ヘミセルロース、ゼラチン、寒天、ペクチン、コーンスターチの他、リン酸塩の如き種々の塩類が例示できる。これらの安定剤を通常製品全体に対し0.1〜1.0重量%程度添加するが、種類によっては口中で粘りを感じるようなことがあるので、そのときは添加量を減じるのがよい。
A typical example of the frozen dessert of the present invention is ice cream, and an ice cream will be described as an example. The components of ice cream are milk fat, non-fat milk solids, sweetener, stabilizer, emulsifier, Consists of flavoring agents, coloring agents, moisture, and the like.
The non-fat milk solid content has an effect of imparting a milky feeling to the ice creams with an improvement in the structure of the ice cream and an increase in overrun. Examples of the milk solid content include skim milk, skim milk powder, and whole milk powder.
Sweeteners have the effect of sweetening ice cream and increasing the viscosity of the mix and improving the tissue. As a sweetener, sucrose is most commonly used, but invert sugar, mixed sugar, syrup, etc. are also used, usually about 13 to 17% by weight based on the total amount.
Stabilizers have the effect of smoothing the tissue, imparting moderate viscosity and participating in overrun adjustment. Such stabilizers include gums such as guar gum, locust bean gum, xanthan gum, gum arabic, carrageenan, sodium alginate, CMC, water-soluble hemicellulose, gelatin, agar, pectin, corn starch, and various phosphates. Examples of the salts are: These stabilizers are usually added in an amount of about 0.1 to 1.0% by weight based on the entire product, but depending on the type, there may be a stickiness in the mouth, so in that case the amount added should be reduced.

乳化剤は組織を滑らかにし、脂肪分の分散保持とフリージング中の脂肪分の凝集を適度に行う。これらの乳化剤の例としては公知のものが使用でき、例えばレシチン、アルコール等による分画レシチン、酸またはアルカリあるいは酵素等による部分加水分解レシチン、ショ糖脂肪酸エステル、プロピレングリコール脂肪酸エステル、ソルビタン脂肪酸エステル、グリセリン脂肪酸エステルおよびポリグリセロール脂肪酸エステル、さらに酢酸モノグリセリド、酒石酸モノグリセリド、酢酸酒石酸混合モノグリセリド、クエン酸モノグリセリド、ジアセチル酒石酸モノグリセリド、乳酸モノグリセリド、コハク酸モノグリセリド、リンゴ酸モノグリセリド等各種有機酸モノグリセリドが例示できる。これらの乳化剤を通常0.1〜0.5重量%程度添加する。   The emulsifier smoothes the tissue and moderately maintains the dispersion of fat and aggregates the fat during freezing. Examples of these emulsifiers may include known ones such as lecithin, fractionated lecithin with alcohol, partially hydrolyzed lecithin with acid, alkali or enzyme, sucrose fatty acid ester, propylene glycol fatty acid ester, sorbitan fatty acid ester, Examples include glycerin fatty acid esters and polyglycerol fatty acid esters, and various organic acid monoglycerides such as acetic acid monoglyceride, tartaric acid monoglyceride, acetic acid tartaric acid mixed monoglyceride, citric acid monoglyceride, diacetyltartaric acid monoglyceride, lactic acid monoglyceride, succinic acid monoglyceride and malic acid monoglyceride. About 0.1 to 0.5% by weight of these emulsifiers are usually added.

また香味料、着色料はアイスクリーム類にとっては重要な添加剤であり、嗜好食品であるだけに消費者の嗜好に応じて選択使用する必要がある。香味料としては多数あるがバニラが一般的であり、チョコレートやストロベリーがよく好まれる。
上記したように、油脂として特異なS2L型トリグリセリドを冷菓用水中油型乳化物に使用することによって、特異な結晶状態を形成することによって高い乳化安定性と良好なホイップ性状が得られ、ホイップされた起泡状態のものは、食感、口溶け、風味、乳味の持続性に優れたものとなると推察している。
Further, flavoring agents and coloring agents are important additives for ice creams, and since they are favorite foods, they need to be selected and used according to consumer preferences. There are many flavoring agents, but vanilla is common, and chocolate and strawberry are often preferred.
As described above, by using a unique S2L type triglyceride as an oil and fat in an oil-in-water emulsion for frozen desserts, high emulsion stability and good whipping properties were obtained and whipped by forming a unique crystalline state It is presumed that the foamed product is excellent in texture, melted mouth, flavor and milky sustainability.

上記の原料を用いたアイスクリーム類の標準的な製造法は次の通りである。まず、原料を選択し、次いで各原料を混合、溶解・分散して乳化物を調製する。この場合、粉体原料はママコになりやすいので特に注意して混合溶解・分散する。温度はあまり高くするのは好ましくない。通常は50〜60℃程度である。このようにして調製した乳化物を、均質化する。均質化圧などの条件は一段圧式または二段圧式など均質機により一概に規定できないが、通常前者の一段式圧では100〜180Kg/cm2でよく、また二段圧式では第一バルブで約100Kg/cm2、第二バルブ圧で約40〜70Kg/cm2がよい。均質化温度は50〜70℃程度が一般的である。
次いで均質化処理を経た水中油型乳化物を殺菌ないし滅菌処理する。通常はUHT滅菌処理する。UHT滅菌には間接加熱方式と直接加熱方式とがあり、間接加熱処理する装置としてはAPVプレート式UHT処理装置(APV社製)、CP−UHT滅菌装置(クリマティ・パッケージ社製)、ストルク・チューブラー型滅菌装置(ストルク社製)、コンサーム掻き取り式UHT滅菌装置(テトラパック・アルファラバル社製)等が例示できるが、特にこれらにこだわるものではない。また、直接加熱滅菌装置としては、ユーペリゼーション滅菌装置(テトラパック・アルファラバル社製)、VTIS滅菌装置(テトラパック・アルファラバル社製)、ラギアーUHT滅菌装置(ラギアー社製)、パラリゼーター(パッシュ・アンド・シルケボーグ社製)、C.P.Vac−Heat・UHT滅菌装置(クリマティー・パッケージ社製)等のUHT滅菌処理装置が例示でき、これらの何れの装置を使用してもよい。
The standard method for producing ice creams using the above raw materials is as follows. First, raw materials are selected, and then the respective raw materials are mixed, dissolved and dispersed to prepare an emulsion. In this case, the powder raw material is likely to be mamako, so mix and dissolve and disperse with particular care. It is not preferable to set the temperature too high. Usually, it is about 50-60 degreeC. The emulsion thus prepared is homogenized. The conditions such as the homogenization pressure cannot be generally defined by a homogenizer such as a one-stage pressure type or a two-stage pressure type, but usually the former one-stage pressure may be 100 to 180 kg / cm 2 , and the two-stage pressure type is about 100 kg with the first valve. / cm 2 and about 40 to 70 kg / cm 2 at the second valve pressure are preferable. The homogenization temperature is generally about 50 to 70 ° C.
Next, the oil-in-water emulsion after homogenization is sterilized or sterilized. Usually, UHT sterilization is performed. UHT sterilization has an indirect heating method and a direct heating method. As an apparatus for indirect heating processing, an APV plate type UHT processing device (manufactured by APV), a CP-UHT sterilizing device (manufactured by Crimaty Package), and a torque tube. Examples thereof include a sterilization apparatus (manufactured by Stork Co., Ltd.), a scraping UHT sterilization apparatus (manufactured by Tetra Pak Alfa Laval Co., Ltd.) and the like, but are not particularly limited to these. As direct heat sterilizers, operation sterilizers (Tetra Pak Alfa Laval Co.), VTIS sterilizers (Tetra Pak Alfa Laval Co.), Ragia UHT sterilizers (Ragia Ru), Paralyzer (Pash)・ And Silkeborg Co., Ltd.), C.I. P. A UHT sterilization apparatus such as a Vac-Heat / UHT sterilization apparatus (manufactured by Crimaty Package) can be exemplified, and any of these apparatuses may be used.

次に殺菌または滅菌処理した水中油型乳化物を冷却後0〜5℃で3〜24時間一時的に貯蔵、すなわちエージング(ストレージ)する。このエージングにより乳化物中の各成分を安定化させる。次いで乳化物を攪拌しながら香味料を添加する。しかる後、フリージングする。この工程は乳化物をフリーザーにより急激に冷却させて水分を凍結させながら適当量の空気を混入させ、乳化物中に微細な気泡と氷の結晶粒子、脂肪粒子を分散させ、半流動状のソフトクリーム状にする工程であって、この工程の処理如何によってアイスクリームの滑らかな組織と食感が左右されるという重要な工程である。後は所定の容器に充填し包装した後、−20〜−30℃に急冷し一定の形を保持するまで凍結させる硬化を行い、出荷されるまで貯蔵しておく。   Next, the sterilized or sterilized oil-in-water emulsion is cooled and temporarily stored at 0 to 5 ° C. for 3 to 24 hours, that is, aged (storage). This aging stabilizes each component in the emulsion. The flavor is then added while stirring the emulsion. After that, it is frozen. In this process, the emulsion is rapidly cooled by a freezer to freeze the moisture, and an appropriate amount of air is mixed in to disperse fine bubbles, ice crystal particles, and fat particles in the emulsion, and a semi-fluid soft This is an important step in which the smooth structure and texture of the ice cream are affected by the process of this step. Then, after filling and packaging in a predetermined container, it is rapidly cooled to -20 to -30 ° C, frozen until it keeps a certain shape, and stored until shipped.

以下に本発明の実施例を示し本発明をより詳細に説明するが、本発明の精神は以下の実施例に限定されるものではない。なお、例中、%及び部は重量基準を意味する。特に、添加剤の添加順序或いは油相を水相へ又は水相を油相へ加える等の乳化順序が以下の例示によって限定されるものではないことは言うまでもない。また、結果については以下の方法で評価した。   EXAMPLES The present invention will be described in more detail with reference to the following examples, but the spirit of the present invention is not limited to the following examples. In the examples,% and part mean weight basis. In particular, it goes without saying that the order of addition of the additives or the emulsification order of adding the oil phase to the water phase or the water phase to the oil phase is not limited by the following examples. The results were evaluated by the following method.

冷菓の評価
A 冷菓用水中油型乳化物を起泡させた場合の評価方法
日世株式会社の自動殺菌ソフトサーバー(NA6062WF型)を使用する。 冷菓用水中油型乳化物を4L用意し、そのうち1.7Lをフリージング機械のシリンダー内に入れる。ミックスバルブを「閉」の位置にしてミックス供給口に差し込む。始めに用意した冷菓用水中油型乳化物のうち、シリンダーに入れた後の水中油型乳化物(約2.3L)をミックスタンクに補給する。運転スイッチを押す。出来上がり後、フットペダルを踏んで、製品出口よりソフトクリームを取り出す。
(1)オーバーラン:[(一定容積の水中油型乳化物重量)ー(一定容積の起泡後の起泡物重量)]÷(一定容積の起泡後の起泡物重量)×100
(2)風味、食感、口溶け、冷感、乳味の持続性:専門パネラーに20名により、優れている順に「5」、「4」、「3」、「2」、「1」の5段階にて評価を行い、平均化した評価を結果とした。
Evaluation of frozen confectionery A Evaluation method when foaming an oil-in-water emulsion for frozen confectionery An automatic sterilization software server (NA6062WF type) manufactured by Nissei Corporation is used. Prepare 4 L of oil-in-water emulsion for frozen dessert, and put 1.7 L in the cylinder of the freezing machine. Insert the mix valve into the mix supply port in the “closed” position. Of the oil-in-water emulsion for frozen desserts prepared at the beginning, the oil-in-water emulsion (about 2.3 L) after being put in the cylinder is supplied to the mix tank. Press the operation switch. After completion, step on the foot pedal to remove the soft cream from the product outlet.
(1) Overrun: [(weight of oil-in-water emulsion of a certain volume) − (weight of foam after a certain volume of foaming)] ÷ (weight of foam after a certain volume of foaming) × 100
(2) Flavor, texture, melted mouth, cold feeling, sustainability of milkiness: 20 professional panelists, in order of “5”, “4”, “3”, “2”, “1” Evaluation was performed in five stages, and the averaged evaluation was taken as the result.

実験例1;S2L含有油脂の調製(1)
サフラワー油20部、ステアリン酸80部を1,3位特異性を有するリパーゼを用いてエステル交換し、蒸留によりエチルエステル部を除去し、S2L含有油脂(1)を得た。
Experimental Example 1 Preparation of S2L-containing oil and fat (1)
20 parts of safflower oil and 80 parts of stearic acid were transesterified using a lipase having 1,3-position specificity, and the ethyl ester part was removed by distillation to obtain S2L-containing fat (1).

実験例2;S2L含有油脂の調製(2)
綿実油:アセトン=20:80の比率の混合物を混合溶解し、攪拌しながら混合物を−10℃まで冷却し、30分保持し結晶を析出させた。その後、減圧濾過して結晶部と液状部に分画した。
得られた結晶部は常法によりアセトンを除去し、更に常法により脱色、脱臭し、S2L含有油脂(2)を得た。
Experimental Example 2: Preparation of S2L-containing fat (2)
A mixture of cottonseed oil: acetone = 20: 80 was mixed and dissolved, and the mixture was cooled to −10 ° C. with stirring and kept for 30 minutes to precipitate crystals. Then, it filtered under reduced pressure and fractionated into the crystal | crystallization part and the liquid part.
Acetone was removed from the obtained crystal part by a conventional method, and further, decolorization and deodorization were performed by a conventional method to obtain an S2L-containing fat (2).

実験例3
起泡性水中油型乳化物の調製に使用したS2L含有油脂(1)、S2L含有油脂(2)、パーム中融点部、大豆パーム混合硬化油、菜種パーム混合硬化油について、液体クロマトグラフィー法、ガスクロマトグラフィー法を用いてSt2L、P2L量を求め、結果を表1に纏めた。

Figure 2007202417
Experimental example 3
S2L-containing oil and fat (1), S2L-containing oil and fat (2) used for the preparation of the foamable oil-in-water emulsion, palm mid-melting point, soybean palm mixed hardened oil, rapeseed palm mixed hardened oil, liquid chromatography method, The amounts of St2L and P2L were determined using a gas chromatography method, and the results are summarized in Table 1.
Figure 2007202417

実施例1
パーム中融点部(融点34℃)3.5部、精製ヤシ油4部、S2L含有油脂(1)0.5部、にグリセリン脂肪酸エステル0.1%を添加混合溶解し油相とする。これとは別に水69.8部に脱脂粉乳10部、グラニュー糖12部、第2リン酸塩0.1部を溶解し水相を調整する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、100Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、水中油型乳化物を得た。この乳化物を上記の方法に従ってフリーザーにかけ、評価した。風味・食感・口溶け・冷感は良好であり、乳味を持続していた。
Example 1
An oil phase is obtained by adding and dissolving 0.1% of glycerin fatty acid ester in 3.5 parts of palm melting point (melting point: 34 ° C.), 4 parts of refined coconut oil, and 0.5 part of S2L-containing fat (1). Separately, 10 parts of nonfat dry milk, 12 parts of granulated sugar and 0.1 part of secondary phosphate are dissolved in 69.8 parts of water to adjust the aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 100 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain an oil-in-water emulsion. The emulsion was subjected to a freezer according to the method described above and evaluated. The flavor, texture, melted mouth, and cold feeling were good, and the milky taste was maintained.

実施例2
パーム中融点部(融点34℃)3部、精製ヤシ油4部、S2L含有油脂(1)1部、にグリセリン脂肪酸エステル0.1%を添加混合溶解し油相とする。これとは別に水69.8部に脱脂粉乳10部、グラニュー糖12部、第2リン酸塩0.1部を溶解し水相を調整する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、100Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、水中油型乳化物を得た。この乳化物を上記の方法に従ってフリーザーにかけ、評価した。風味・食感・口溶け・冷感は良好であり、乳味を持続していた。
Example 2
0.1 part of glycerin fatty acid ester is added and dissolved in 3 parts of middle melting point of palm (melting point of 34 ° C.), 4 parts of refined coconut oil and 1 part of S2L-containing fat (1) to obtain an oil phase. Separately, 10 parts of nonfat dry milk, 12 parts of granulated sugar and 0.1 part of secondary phosphate are dissolved in 69.8 parts of water to adjust the aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 100 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain an oil-in-water emulsion. The emulsion was subjected to a freezer according to the method described above and evaluated. The flavor, texture, melted mouth, and cold feeling were good, and the milky taste was maintained.

実施例3
パーム中融点部(融点34℃)3部、精製ヤシ油3部、S2L含有油脂(1)2部、にグリセリン脂肪酸エステル0.1%を添加混合溶解し油相とする。これとは別に水69.8部に脱脂粉乳10部、グラニュー糖12部、第2リン酸塩0.1部を溶解し水相を調整する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、100Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、水中油型乳化物を得た。この乳化物を上記の方法に従ってフリーザーにかけ、評価した。風味・食感・口溶け・冷感は良好であり、乳味を持続していた。
Example 3
An oil phase is prepared by adding and dissolving 0.1% glycerin fatty acid ester in 3 parts of palm middle melting point (melting point: 34 ° C.), 3 parts of refined coconut oil and 2 parts of S2L-containing oil (1). Separately, 10 parts of nonfat dry milk, 12 parts of granulated sugar and 0.1 part of secondary phosphate are dissolved in 69.8 parts of water to adjust the aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 100 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain an oil-in-water emulsion. The emulsion was subjected to a freezer according to the method described above and evaluated. The flavor, texture, melted mouth, and cold feeling were good, and the milky taste was maintained.

実施例4
パーム中融点部(融点34℃)3部、精製ヤシ油3部、S2L含有油脂(1)4部、にグリセリン脂肪酸エステル0.1%を添加混合溶解し油相とする。これとは別に水67.8部に脱脂粉乳10部、グラニュー糖12部、第2リン酸塩0.1部を溶解し水相を調整する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、100Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、水中油型乳化物を得た。この乳化物を上記の方法に従ってフリーザーにかけ、評価した。風味・食感・口溶け・冷感は良好であり、乳味を持続していた。
Example 4
0.1 part of glycerin fatty acid ester is added and dissolved in 3 parts of palm middle melting point (melting point 34 ° C.), 3 parts of refined coconut oil and 4 parts of S2L-containing oil (1) to obtain an oil phase. Separately, 10 parts of skim milk powder, 12 parts of granulated sugar and 0.1 part of dibasic phosphate are dissolved in 67.8 parts of water to adjust the aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 100 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain an oil-in-water emulsion. The emulsion was subjected to a freezer according to the method described above and evaluated. The flavor, texture, melted mouth, and cold feeling were good, and the milky taste was maintained.

実施例5
S2L含有油脂(1)1.2部、バターオイル 10.8部にグリセリン脂肪酸エステル0.1%を添加混合溶解し油相とする。これとは別に水65.8部に脱脂粉乳10部、グラニュー糖12部、第2リン酸塩0.1部を溶解し水相を調整する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、100Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、水中油型乳化物を得た。この乳化物を上記の方法に従ってフリーザーにかけ、評価した。風味・食感・口溶け・冷感は良好であり、乳味を持続していた。
Example 5
An oil phase is obtained by adding and dissolving 0.1% of glycerin fatty acid ester in 1.2 parts of S2L-containing fat (1) and 10.8 parts of butter oil. Separately, 10 parts of skim milk powder, 12 parts of granulated sugar and 0.1 part of dibasic phosphate are dissolved in 65.8 parts of water to adjust the aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 100 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain an oil-in-water emulsion. The emulsion was subjected to a freezer according to the method described above and evaluated. The flavor, texture, melted mouth, and cold feeling were good, and the milky taste was maintained.

実施例6
S2L含有油脂(1)2.4部、バターオイル 9.6部にグリセリン脂肪酸エステル0.1%を添加混合溶解し油相とする。これとは別に水65.8部に脱脂粉乳10部、グラニュー糖12部、第2リン酸塩0.1部を溶解し水相を調整する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、100Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、水中油型乳化物を得た。この乳化物を上記の方法に従ってフリーザーにかけ、評価した。風味・食感・口溶け・冷感は良好であり、乳味を持続していた。
Example 6
Add 0.1% of glycerin fatty acid ester to 2.4 parts of S2L-containing fats and oils (1) and 9.6 parts of butter oil, and dissolve to obtain an oil phase. Separately, 10 parts of skim milk powder, 12 parts of granulated sugar and 0.1 part of dibasic phosphate are dissolved in 65.8 parts of water to adjust the aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 100 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain an oil-in-water emulsion. The emulsion was subjected to a freezer according to the method described above and evaluated. The flavor, texture, melted mouth, and cold feeling were good, and the milky taste was maintained.

実施例7
S2L含有油脂(1)4.8部、バターオイル 7.2部にグリセリン脂肪酸エステル0.1%を添加混合溶解し油相とする。これとは別に水65.8部に脱脂粉乳10部、グラニュー糖12部、第2リン酸塩0.1部を溶解し水相を調整する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、100Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、水中油型乳化物を得た。この乳化物を上記の方法に従ってフリーザーにかけ、評価した。風味・食感・口溶け・冷感は良好であり、乳味を持続していた。
Example 7
Add glycerol fatty acid ester 0.1% to 4.8 parts of S2L-containing oil and fat (1) and 7.2 parts of butter oil, and dissolve to obtain an oil phase. Separately, 10 parts of skim milk powder, 12 parts of granulated sugar and 0.1 part of dibasic phosphate are dissolved in 65.8 parts of water to adjust the aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 100 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain an oil-in-water emulsion. The emulsion was subjected to a freezer according to the method described above and evaluated. The flavor, texture, melted mouth, and cold feeling were good, and the milky taste was maintained.

実施例8
S2L含有油脂(1)7.2部、バターオイル 4.8部にグリセリン脂肪酸エステル0.1%を添加混合溶解し油相とする。これとは別に水65.8部に脱脂粉乳10部、グラニュー糖12部、第2リン酸塩0.1部を溶解し水相を調整する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、100Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、水中油型乳化物を得た。この乳化物を上記の方法に従ってフリーザーにかけ、評価した。風味・食感・口溶け・冷感は良好であり、乳味を持続していた。
Example 8
The oil phase is prepared by adding and dissolving 0.1% glycerin fatty acid ester in 7.2 parts of S2L-containing oil and fat (1) and 4.8 parts of butter oil. Separately, 10 parts of skim milk powder, 12 parts of granulated sugar and 0.1 part of dibasic phosphate are dissolved in 65.8 parts of water to adjust the aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 100 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain an oil-in-water emulsion. The emulsion was subjected to a freezer according to the method described above and evaluated. The flavor, texture, melted mouth, and cold feeling were good, and the milky taste was maintained.

表2に実施例1〜実施例8の結果を纏めた。

Figure 2007202417
Table 2 summarizes the results of Examples 1 to 8.
Figure 2007202417

比較例1
パーム中融点部(融点34℃)4部、精製ヤシ油4部にグリセリン脂肪酸エステル0.1%を添加混合溶解し油相とする。これとは別に水69.8部に脱脂粉乳10部、グラニュー糖12部、第2リン酸塩0.1部を溶解し水相を調整する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、100Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、水中油型乳化物を得た。この乳化物を上記の方法に従ってフリーザーにかけ、評価した。風味・口溶け・冷感は良好であるが、滑らかな食感は得られず、乳味の持続性もなかった。
Comparative Example 1
An oil phase is prepared by adding and dissolving 0.1% of glycerin fatty acid ester in 4 parts of the middle melting point (melting point 34 ° C.) of palm and 4 parts of refined palm oil. Separately, 10 parts of nonfat dry milk, 12 parts of granulated sugar and 0.1 part of secondary phosphate are dissolved in 69.8 parts of water to adjust the aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 100 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain an oil-in-water emulsion. The emulsion was subjected to a freezer according to the method described above and evaluated. The flavor, melting in the mouth, and cooling sensation were good, but a smooth texture was not obtained and the milky taste was not sustained.

比較例2
精製ヤシ油0.7部、S2L含有油脂(1)0.3部にグリセリン脂肪酸エステル0.1%を添加混合溶解し油相とする。これとは別に水76.8部に脱脂粉乳10部、グラニュー糖12部、第2リン酸塩0.1部を溶解し水相を調整する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、100Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、水中油型乳化物を得た。この乳化物を上記の方法に従ってフリーザーにかけ、評価した。風味は薄く、口溶け悪く、冷感もなく、滑らかな食感は得られず、乳味の持続性もなかった。
Comparative Example 2
0.1 part of glycerin fatty acid ester is added and dissolved in 0.7 part of refined coconut oil and 0.3 part of S2L-containing fat (1) to obtain an oil phase. Separately, 10 parts of skim milk powder, 12 parts of granulated sugar and 0.1 part of dibasic phosphate are dissolved in 76.8 parts of water to adjust the aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 100 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain an oil-in-water emulsion. The emulsion was subjected to a freezer according to the method described above and evaluated. The flavor was thin, the mouth melted poorly, there was no cold feeling, a smooth texture was not obtained, and the milky taste was not sustained.

比較例3
パーム中融点部(融点34℃)8部、精製ヤシ油8部、S2L含有油脂(1)6部にグリセリン脂肪酸エステル0.1%を添加混合溶解し油相とする。これとは別に水55.8部に脱脂粉乳10部、グラニュー糖12部、第2リン酸塩0.1部を溶解し水相を調整する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、100Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、水中油型乳化物を得た。この乳化物を上記の方法に従ってフリーザーにかけたが、良好な状態のものが得られなかった。
Comparative Example 3
An oil phase is prepared by adding and dissolving 0.1% of glycerin fatty acid ester in 8 parts of a middle melting point of palm (melting point 34 ° C.), 8 parts of refined coconut oil, and 6 parts of S2L-containing oil (1). Separately, 10 parts of skim milk powder, 12 parts of granulated sugar and 0.1 part of dibasic phosphate are dissolved in 55.8 parts of water to adjust the aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 100 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain an oil-in-water emulsion. This emulsion was subjected to a freezer according to the above method, but a good product was not obtained.

比較例4
パーム中融点部(融点34℃)2部、精製ヤシ油2部、S2L含有油脂(1)4部にグリセリン脂肪酸エステル0.1%を添加混合溶解し油相とする。これとは別に水69.8部に脱脂粉乳10部、グラニュー糖12部、第2リン酸塩0.1部を溶解し水相を調整する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、100Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、水中油型乳化物を得た。この乳化物を上記の方法に従ってフリーザーにかけ、評価した。風味は良好で、乳味の持続性もあるが、食感は柔らかすぎ、口溶けは重たく、冷感がなかった。
Comparative Example 4
An oil phase is obtained by adding and dissolving 0.1% glycerin fatty acid ester in 2 parts of palm middle melting point (melting point 34 ° C.), 2 parts of refined coconut oil, and 4 parts of S2L-containing fat (1). Separately, 10 parts of nonfat dry milk, 12 parts of granulated sugar and 0.1 part of secondary phosphate are dissolved in 69.8 parts of water to adjust the aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 100 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain an oil-in-water emulsion. The emulsion was subjected to a freezer according to the method described above and evaluated. The flavor was good and the milky taste was persistent, but the texture was too soft, the mouth melted heavy, and there was no cold feeling.

比較例5
バターオイル 12部にグリセリン脂肪酸エステル0.1%を添加混合溶解し油相とする。これとは別に水65.8部に脱脂粉乳10部、グラニュー糖12部、第2リン酸塩0.1部を溶解し水相を調整する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、100Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、水中油型乳化物を得た。この乳化物を上記の方法に従ってフリーザーにかけ、評価した。風味・食感は良好であるが、口溶けが悪く、冷感もなく、乳味の持続性もなかった。
Comparative Example 5
To 12 parts of butter oil, 0.1% glycerin fatty acid ester is added and dissolved to obtain an oil phase. Separately, 10 parts of skim milk powder, 12 parts of granulated sugar and 0.1 part of dibasic phosphate are dissolved in 65.8 parts of water to adjust the aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 100 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain an oil-in-water emulsion. The emulsion was subjected to a freezer according to the method described above and evaluated. The flavor and texture were good, but the mouth melted poorly, there was no cold feeling, and the milky taste was not sustained.

比較例6
S2L含有油脂(1)9.6部、バターオイル 2.4部にグリセリン脂肪酸エステル0.1%を添加混合溶解し油相とする。これとは別に水65.8部に脱脂粉乳10部、グラニュー糖12部、第2リン酸塩0.1部を溶解し水相を調整する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、100Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、水中油型乳化物を得た。この乳化物を上記の方法に従ってフリーザーにかけ、評価した。風味・食感良好で、乳味の持続性もあるものの、口溶け悪く、冷感もなかった。
Comparative Example 6
S2L-containing fats and oils (1) 9.6 parts, butter oil 2.4 parts of glycerin fatty acid ester 0.1% is added and dissolved to form an oil phase. Separately, 10 parts of skim milk powder, 12 parts of granulated sugar and 0.1 part of dibasic phosphate are dissolved in 65.8 parts of water to adjust the aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 100 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain an oil-in-water emulsion. The emulsion was subjected to a freezer according to the method described above and evaluated. Although the flavor and texture were good and the milky taste was persistent, the mouth melted poorly and there was no cold feeling.

表3に比較例1〜比較例6の結果を纏めた。

Figure 2007202417
Table 3 summarizes the results of Comparative Examples 1 to 6.
Figure 2007202417

本発明は、アイスクリーム、アイスミルク、ラクトアイス等の冷菓用水中油型乳化物の食感、乳味の持続性の改良に関する。   The present invention relates to improving the texture and milky taste sustainability of oil-in-water emulsions for frozen desserts such as ice cream, ice milk, and lacto ice.

Claims (3)

油脂、無脂乳固形分及び水を含む水中油型乳化物において、油脂中にS2L型トリグリセリド(但し、式中のSはステアリン酸及びパルミチン酸、Lはリノール酸)を含有することを特徴とする冷菓用水中油型乳化物。 In an oil-in-water emulsion containing fats and oils, non-fat milk solids and water, the oil and fat contains S2L-type triglycerides (wherein S is stearic acid and palmitic acid, and L is linoleic acid). An oil-in-water emulsion for frozen desserts. 油脂分が2〜20重量%である、請求項1記載の冷菓用水中油型乳化物。 The oil-in-water emulsion for frozen desserts of Claim 1 whose fats and oils are 2 to 20 weight%. 油脂が非乳脂(Aタイプ)又は、非乳脂及び乳脂(Bタイプ)であって、Aタイプの場合は油脂中のS2L型トリグリセリドが1〜20重量%の範囲であり、Bタイプの場合は2〜30重量%の範囲である、請求項1記載の冷菓用水中油型乳化物。 Fats and oils are non-milk fat (A type) or non-milk fat and milk fat (B type), and in the case of A type, S2L type triglyceride in fats and oils is in the range of 1 to 20% by weight. The oil-in-water emulsion for frozen desserts according to claim 1, which is in the range of -30% by weight.
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009148168A (en) * 2007-12-18 2009-07-09 Akagi Nyugyo Co Ltd Soft cream mix composition and method for producing the same
JP2012527872A (en) * 2009-05-29 2012-11-12 ユニリーバー・ナームローゼ・ベンノートシヤープ Oil-in-water emulsion
JP2012527871A (en) * 2009-05-29 2012-11-12 ユニリーバー・ナームローゼ・ベンノートシヤープ Oil-in-water emulsion
US9115349B2 (en) 2008-10-16 2015-08-25 Conopco, Inc. Hydrophobin solution containing antifoam
JP2018134032A (en) * 2017-02-22 2018-08-30 日清オイリオグループ株式会社 Frozen confectionery mix and frozen confectionery using same
CN115413714A (en) * 2022-09-16 2022-12-02 河南工业大学 Special quick-freezing grease and preparation method and application thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009148168A (en) * 2007-12-18 2009-07-09 Akagi Nyugyo Co Ltd Soft cream mix composition and method for producing the same
US9115349B2 (en) 2008-10-16 2015-08-25 Conopco, Inc. Hydrophobin solution containing antifoam
JP2012527872A (en) * 2009-05-29 2012-11-12 ユニリーバー・ナームローゼ・ベンノートシヤープ Oil-in-water emulsion
JP2012527871A (en) * 2009-05-29 2012-11-12 ユニリーバー・ナームローゼ・ベンノートシヤープ Oil-in-water emulsion
JP2018134032A (en) * 2017-02-22 2018-08-30 日清オイリオグループ株式会社 Frozen confectionery mix and frozen confectionery using same
CN115413714A (en) * 2022-09-16 2022-12-02 河南工业大学 Special quick-freezing grease and preparation method and application thereof

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