JP2007190448A - Mixed gas manufacturing apparatus and method - Google Patents

Mixed gas manufacturing apparatus and method Download PDF

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JP2007190448A
JP2007190448A JP2006008183A JP2006008183A JP2007190448A JP 2007190448 A JP2007190448 A JP 2007190448A JP 2006008183 A JP2006008183 A JP 2006008183A JP 2006008183 A JP2006008183 A JP 2006008183A JP 2007190448 A JP2007190448 A JP 2007190448A
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gas
flow rate
mixed gas
concentration
product
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Masaya Yamawaki
正也 山脇
Yoshio Ishihara
良夫 石原
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Taiyo Nippon Sanso Corp
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a mixed gas manufacturing apparatus capable of accurately and stably maintaining a composition of a product, i.e., a mixed gas regardless of variation in the composition of the mixed gas becoming a material and a flow rate of the product mixed gas used, and a method. <P>SOLUTION: A pressure of the material gas comprising the mixed gas is adjusted to a set pressure, a pressure of an addition gas is adjusted to a set pressure and the flow rate is adjusted. The material gas adjusted to the set pressure and the addition gas adjusted to the set pressure and flow rate-adjusted are mixed to create the product mixed gas. A part of the product mixed gas is taken out, a concentration of at least one kind of gas in the product mixed gas is measured and a flow rate of the product mixed gas is measured. The flow rate of the addition gas is adjusted from the concentration of at least one kind of gas of the previously set product mixed gas, a concentration measurement value of at least one kind of gas in the product mixed gas and a variation ratio of the flow rate measurement value of the product mixed gas. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は、混合ガス製造装置及び方法に関し、詳しくは、複数の主要ガス成分を含有する原料混合ガスに前記主要ガス成分のいずれか少なくとも1種類のガスを添加することにより、あらかじめ設定された組成及び流量に調整した製品混合ガスを製造する混合ガス製造装置及び方法に関する。   The present invention relates to a mixed gas production apparatus and method, and more specifically, a composition set in advance by adding at least one of the main gas components to a raw material mixed gas containing a plurality of main gas components. And a mixed gas production apparatus and method for producing a product mixed gas adjusted to a flow rate.

近年、ガスを使用する製造現場において、単一成分のガスのみを使用することは稀であり、多くは複数成分のガスを目的とする組成に調整した混合ガスとして使用している。混合ガスの供給形態としては、複数成分のガスが目的とする濃度で混合された混合ガスが充填されたボンベ等から供給する場合と、複数のガスを目的とする濃度になるように混合器等を介して混合させてから供給する場合があるが、一般的にコスト、使用頻度、使用量等の点から後者を用いる場合が多い。このような状況の中で、複数のガスを用いて目的とする組成の混合ガスを製造する混合ガス製造装置は多く利用されている。   In recent years, it is rare to use only a single component gas at a manufacturing site where gas is used, and many of them are used as a mixed gas adjusted to a target composition of a plurality of component gases. As for the supply form of the mixed gas, a case where the mixed gas is supplied from a cylinder filled with a mixed gas in which a plurality of component gases are mixed at a target concentration, a mixer or the like so that a plurality of gases are at a target concentration, etc. In some cases, the mixture is supplied after mixing, but generally the latter is often used from the viewpoint of cost, frequency of use, amount of use, and the like. In such a situation, a mixed gas production apparatus that produces a mixed gas having a target composition using a plurality of gases is widely used.

従来までの混合ガス製造装置で用いる濃度制御システムでは、複数の単一成分ガスを原料ガス及び添加ガスとして用い、製品混合ガスとして予め設定された濃度及び流量に応じて原料ガス及び添加ガスの流量を制御するものが主流であった。原料ガス及び添加ガスに混合ガスを用いる場合でも、予め前記混合ガスの濃度情報を得ている必要があった。   In a conventional concentration control system used in a mixed gas production apparatus, a plurality of single component gases are used as a raw material gas and an additive gas, and the flow rates of the raw material gas and the additive gas are set according to the concentration and flow rate preset as the product mixed gas. It was the mainstream that controlled. Even when a mixed gas is used for the source gas and the additive gas, it is necessary to obtain concentration information of the mixed gas in advance.

これに対し、原料ガスと添加ガスに濃度が特定されない高濃度酸素と低濃度酸素を用い、ミキサー等で混合して製品混合ガスを製造する装置において、製品混合ガスの酸素濃度信号が所定の値になるように前記原料ガスと添加ガスの供給流量制御へフィードバックするガス混合装置が開示されている(特許文献1参照。)。
特開平1−321508号公報
On the other hand, in an apparatus that uses high-concentration oxygen and low-concentration oxygen whose concentrations are not specified for the raw material gas and the additive gas to produce a product mixed gas by mixing with a mixer or the like, the oxygen concentration signal of the product mixed gas has a predetermined value. A gas mixing device that feeds back to the supply flow rate control of the source gas and additive gas is disclosed (see Patent Document 1).
JP-A-1-321508

特許文献1記載のガス混合装置では、混合前の原料ガス及び添加ガスの酸素濃度に関係なく、一定の製品混合ガス流量において、正確かつ安定に酸素濃度値を維持することができるとしている。しかしながら、得られる製品混合ガスは一定流量でなければならず、濃度を正確に維持した混合ガスを自由な流量で使用したいという要求を満たすことはできなかった。   In the gas mixing device described in Patent Document 1, the oxygen concentration value can be accurately and stably maintained at a constant product mixed gas flow rate regardless of the oxygen concentrations of the raw material gas and the additive gas before mixing. However, the product mixed gas obtained must have a constant flow rate, and it has not been possible to satisfy the demand for using a mixed gas whose concentration is accurately maintained at a free flow rate.

そこで本発明は、製品混合ガスの組成を任意に設定することが可能であって、しかも、製品混合ガスの組成を原料となる混合ガスの組成変動や、製品混合ガスの使用流量に拘わらず、正確かつ安定に維持することができる混合ガス製造装置及び方法を提供することを目的としている。   Therefore, the present invention can arbitrarily set the composition of the product mixed gas, and the composition of the product mixed gas can be set regardless of the composition variation of the mixed gas as a raw material and the flow rate of the product mixed gas. An object of the present invention is to provide a mixed gas production apparatus and method that can be accurately and stably maintained.

上記目的を達成するため、本発明の混合ガス製造装置は、少なくとも2種類の主要ガス成分を含有し、組成及び流量が経時変化する混合ガスを原料ガスとし、前記主要ガス成分の少なくとも1種類を含むガスを添加ガスとして前記原料ガスに添加し、添加後の混合ガスにおける前記主要ガス成分の少なくとも1種類のガスの濃度をあらかじめ設定された濃度に調整した製品混合ガスを製造する混合ガス製造装置において、前記原料ガスの圧力を設定圧力に調整して流出させる原料ガス圧力調整手段と、前記添加ガスの圧力を設定圧力に調整して流出させる添加ガス圧力調整手段と、前記添加ガスの流量を調整する添加ガス流量調整手段と、設定圧力に調整された前記原料ガスと設定圧力に調整されて流量調整された前記添加ガスとを混合するガス混合手段と、該ガス混合手段で混合した製品混合ガスの一部を取り出して該製品混合ガス中の少なくとも1種類のガスの濃度を測定する分析手段と、前記製品混合ガスの流量を測定する製品混合ガス流量測定手段と、前記製品混合ガスの少なくとも1種類のガスの濃度を設定する設定濃度入力手段と、該設定濃度入力手段に入力された設定濃度と前記分析手段で測定した濃度測定値と前記製品混合ガス流量測定手段で測定した流量測定値の変化率とに基づいて前記添加ガス流量調整手段の添加ガス流量設定値を算出する演算手段とを備えていることを特徴としている。   In order to achieve the above object, the mixed gas production apparatus of the present invention contains at least two kinds of main gas components, a mixed gas whose composition and flow rate change with time is used as a raw material gas, and at least one kind of the main gas components is used. A mixed gas production apparatus for producing a product mixed gas in which a gas containing the mixture is added to the raw material gas as an additive gas and the concentration of at least one of the main gas components in the mixed gas after the addition is adjusted to a preset concentration The source gas pressure adjusting means for adjusting the pressure of the source gas to flow out, the additive gas pressure adjusting means for adjusting the pressure of the additive gas to flow out to the set pressure, and the flow rate of the additive gas The additive gas flow rate adjusting means to be adjusted is mixed with the source gas adjusted to the set pressure and the additive gas adjusted to the set pressure and the flow rate adjusted. Mixing means, an analysis means for taking out a part of the product mixed gas mixed by the gas mixing means and measuring the concentration of at least one kind of gas in the product mixed gas, and measuring the flow rate of the product mixed gas Product mixed gas flow rate measuring means, set concentration input means for setting the concentration of at least one kind of gas in the product mixed gas, set concentration input to the set concentration input means, and concentration measurement value measured by the analyzing means And a calculating means for calculating an additive gas flow rate setting value of the additive gas flow rate adjusting means based on a change rate of the flow rate measurement value measured by the product mixed gas flow rate measuring means.

さらに、本発明の混合ガス製造装置では、前記ガス混合手段として、直管の中間部から直角に分岐した分岐管を有するT字状に形成され、前記直管の一方の開口側に前記原料ガスを導入する原料ガス導入部が、該直管の他方の開口側に前記添加ガスを導入する添加ガス導入部が、前記分岐管に製品混合ガス導出部が、それぞれ設けられているガス混合器を使用することを特徴としている。   Furthermore, in the mixed gas manufacturing apparatus of the present invention, the gas mixing means is formed in a T-shape having a branch pipe branched at a right angle from an intermediate portion of the straight pipe, and the source gas is formed on one opening side of the straight pipe. A gas mixer in which a raw material gas introduction part for introducing the additive gas is introduced to the other opening side of the straight pipe, a product mixed gas outlet part is provided in the branch pipe, respectively. It is characterized by use.

また、本発明の混合ガス製造方法は、少なくとも2種類の主要ガス成分を含有し、組成及び流量が経時変化する混合ガスを原料ガスとし、前記主要ガス成分の少なくとも1種類を含むガスを添加ガスとして前記原料ガスに添加し、添加後の混合ガスにおける前記主要ガス成分の少なくとも1種類のガスの濃度をあらかじめ設定された濃度に調整した製品混合ガスを製造する混合ガス製造方法において、前記原料ガスの圧力を設定圧力に調整し、前記添加ガスの圧力を設定圧力に調整するとともに流量を調整し、設定圧力に調整された前記原料ガスと設定圧力に調整されて流量調整された前記添加ガスとを混合して製品混合ガスとし、該製品混合ガスの一部を取り出して該製品混合ガス中の少なくとも1種類のガスの濃度を測定するとともに、前記製品混合ガスの流量を測定し、あらかじめ設定された製品混合ガスの少なくとも1種類のガスの濃度と、製品混合ガス中の少なくとも1種類のガスの濃度測定値と、製品混合ガスの流量測定値の変化率とに基づいて前記添加ガスの流量を調整することを特徴としている。   Further, the mixed gas production method of the present invention uses at least two main gas components, a mixed gas whose composition and flow rate change over time as a raw material gas, and a gas containing at least one of the main gas components as an additive gas In the mixed gas production method for producing a product mixed gas, which is added to the raw material gas and the concentration of at least one kind of the main gas component in the mixed gas after the addition is adjusted to a preset concentration, The pressure of the additive gas is adjusted to the set pressure, the flow rate is adjusted, the source gas adjusted to the set pressure, and the additive gas adjusted to the set pressure and the flow rate adjusted Is mixed into a product mixed gas, a part of the product mixed gas is taken out and the concentration of at least one kind of gas in the product mixed gas is measured, The flow rate of the product mixed gas is measured, the concentration of at least one kind of gas in the preset product mixed gas, the measured concentration value of at least one kind of gas in the product mixed gas, and the measured flow rate value of the product mixed gas The flow rate of the additive gas is adjusted on the basis of the change rate.

本発明によれば、原料ガスの組成が変動したり、製品混合ガスの設定濃度が変更されたりした場合は、分析した特定成分の濃度測定値からフィードバック制御演算により、製品混合ガスの組成変動に追従して添加ガス流量を変化させ、原料ガスの流量が変動した場合は、ガス混合手段を導出した製品混合ガスの流量変化率に応じて添加ガス流量を変化させることにより、原料ガスの組成及び流量が経時変化する場合でも、製品混合ガスの組成を高精度に保つことができる。また、T字状に形成したガス混合器を使用することにより、原料ガスと添加ガスとを短時間で効率よく混合することができる。   According to the present invention, when the composition of the raw material gas is changed or the set concentration of the product mixed gas is changed, the composition of the product mixed gas is changed by the feedback control calculation from the measured concentration value of the specific component analyzed. When the flow rate of the additive gas is changed following the change, the flow rate of the additive gas is changed according to the flow rate change rate of the product mixed gas derived from the gas mixing means. Even when the flow rate changes with time, the composition of the product mixed gas can be maintained with high accuracy. Further, by using a gas mixer formed in a T shape, the source gas and the additive gas can be mixed efficiently in a short time.

図1は本発明の混合ガス製造装置の一形態例を示す系統図である。この混合ガス製造装置は、原料ガスが導入される原料ガス導入経路11と、添加ガスが導入される添加ガス導入経路12と、両導入経路11,12から導入された原料ガスと添加ガスとを混合するガス混合手段13と、該ガス混合手段13で混合した製品混合ガスの一部を取り出す分析経路14と、前記製品混合ガスの残部を製品として送出する製品ガス供給経路15とを備えている。   FIG. 1 is a system diagram showing an embodiment of the mixed gas production apparatus of the present invention. This mixed gas manufacturing apparatus includes a source gas introduction path 11 through which a source gas is introduced, an additive gas introduction path 12 through which an additive gas is introduced, and a source gas and an additive gas introduced from both the introduction paths 11 and 12. A gas mixing means 13 for mixing, an analysis path 14 for taking out a part of the product mixed gas mixed by the gas mixing means 13, and a product gas supply path 15 for sending the remainder of the product mixed gas as a product are provided. .

さらに、前記原料ガス導入経路11には原料ガス圧力調整手段21が、前記添加ガス導入経路12には添加ガス圧力調整手段22及び添加ガス流量調整手段23が、前記分析経路14には分析ガス圧力調整手段24,分析手段25及び分析ガス流量調整手段26が、前記製品ガス供給経路15には製品流量測定手段27及び製品供給弁28が、それぞれ設けられている。   Further, a source gas pressure adjusting means 21 is provided in the source gas introduction path 11, an additive gas pressure adjusting means 22 and an additive gas flow rate adjusting means 23 are provided in the additive gas introduction path 12, and an analysis gas pressure is provided in the analysis path 14. The adjustment means 24, the analysis means 25, and the analysis gas flow rate adjustment means 26 are provided in the product gas supply path 15, and the product flow rate measurement means 27 and the product supply valve 28 are provided, respectively.

前記分析手段25の濃度測定値25a、前記分析ガス流量設定手段26の流量設定値26a、前記製品流量測定手段27の流量測定値27aは、製品混合ガスの特定の成分の濃度を設定する設定濃度入力手段31に入力された設定濃度31aと共に演算手段32に電気信号として入力され、該演算手段32でこれらの入力値に基づいて算出した添加ガス流量設定値32aが前記添加ガス流量調整手段23に電気信号として出力され、該添加ガス流量設定値32aに基づいて添加ガス流量調整手段23が作動することにより、添加ガス導入経路12から導入される添加ガスの流量が調整される。   The concentration measurement value 25a of the analysis unit 25, the flow rate setting value 26a of the analysis gas flow rate setting unit 26, and the flow rate measurement value 27a of the product flow rate measurement unit 27 are set concentrations that set the concentration of a specific component of the product mixed gas. The added gas flow rate setting value 32a calculated based on these input values by the calculation means 32 together with the set concentration 31a input to the input means 31 is input to the calculation means 32 as an electrical signal. The flow rate of the additive gas introduced from the additive gas introduction path 12 is adjusted by operating the additive gas flow rate adjusting means 23 based on the additive gas flow rate setting value 32a.

原料ガス導入経路11から導入される原料ガスは、少なくとも2種類の主要ガス成分を含有し、組成及び流量が経時変化する混合ガスであって、例えば、様々な設備、装置、機器から排出される排ガス等を原料ガスとして使用することができる。また、製品ガス供給経路15から送出される製品混合ガスの供給先も、各種混合ガスを使用する様々な設備、装置、機器を対象とすることができ、これらは特に限定されるものではない。   The raw material gas introduced from the raw material gas introduction path 11 is a mixed gas containing at least two kinds of main gas components and changing in composition and flow rate with time. For example, the raw material gas is discharged from various facilities, apparatuses, and devices. Exhaust gas or the like can be used as a raw material gas. Moreover, the supply destination of the product mixed gas delivered from the product gas supply path 15 can also target various facilities, apparatuses, and devices that use various mixed gases, and these are not particularly limited.

分析手段25は、製品混合ガス中の主要ガス成分の少なくとも1種類のガスの濃度を連続的に測定できるものならば任意の分析器、分析計を使用することができ、主要ガス成分の全てを同時に分析できるものであってもよい。また、分析ガス圧力調整手段24や分析ガス流量調整手段26は、分析手段25とは別に設けられたものであってもよく、分析手段25に装備されたものであってもよい。   The analysis means 25 can use any analyzer or analyzer as long as it can continuously measure the concentration of at least one of the main gas components in the product mixed gas. It may be one that can be analyzed simultaneously. Further, the analysis gas pressure adjusting means 24 and the analysis gas flow rate adjusting means 26 may be provided separately from the analysis means 25 or may be provided in the analysis means 25.

なお、原料ガスとなる混合ガスにおける主要ガス成分とは、通常は、1〜数%以上の濃度で存在する成分であって、製品混合ガス中の特定成分濃度も、製品混合ガスの使用条件によって異なるが、通常は、1〜数%以上の濃度に調整されたものとする。例えば、大気ならば、窒素、酸素及びアルゴンを主要ガス成分ということができる。   The main gas component in the mixed gas that is the raw material gas is usually a component that exists at a concentration of 1 to several percent or more, and the specific component concentration in the product mixed gas also depends on the use conditions of the product mixed gas. Usually, it is assumed that the concentration is adjusted to 1 to several percent or more. For example, in the atmosphere, nitrogen, oxygen, and argon can be referred to as main gas components.

添加ガス導入経路12から導入する添加ガスは、原料ガスの組成及びその変動状況、製品混合ガスに望まれる組成、製品混合ガス供給先の使用条件等に応じて選択することができ、前記原料ガスの主要ガス成分の少なくとも1種類のガス(単一成分)、あるいは、複数の主要ガス成分があらかじめ所定の濃度で混合された混合ガス、あるいは、主要ガス成分の少なくとも1種類のガスと主要ガス成分以外のガスとの混合ガスを使用することができる。なお、主要ガス成分以外のガスとの混合ガスを使用する場合、主要ガス成分以外のガスは、製品混合ガス中に混在しても不都合を生じない成分を選択する。   The additive gas introduced from the additive gas introduction path 12 can be selected according to the composition of the raw material gas and its fluctuation state, the composition desired for the product mixed gas, the use conditions of the product mixed gas supply destination, etc. At least one kind of main gas component (single component), a mixed gas in which a plurality of main gas components are mixed in advance at a predetermined concentration, or at least one kind of main gas component and main gas component A mixed gas with other gases can be used. When a mixed gas with a gas other than the main gas component is used, a gas that does not cause inconvenience even when mixed in the product mixed gas is selected as the gas other than the main gas component.

また、前記分析手段25で分析するガス成分と、添加ガスとして添加するガス成分とは、同一であってもよく、異なっていてもよく、濃度管理が厳密なガス成分や、分析が容易なガス成分を分析手段25で分析することが好ましい。   Further, the gas component analyzed by the analyzing means 25 and the gas component added as the additive gas may be the same or different, and the gas component whose concentration control is strict or the gas which is easy to analyze The components are preferably analyzed by the analyzing means 25.

このように形成した混合ガス製造装置を使用して製品混合ガスを製造するには、まず、設定濃度入力手段31に製品混合ガスにおける特定成分の設定濃度を入力した後、製品供給弁28を閉じた状態で、原料ガス圧力調整手段21の設定圧力を、製品混合ガスの供給圧力以上の圧力に設定するとともに、添加ガス圧力調整手段22の設定圧力を、添加ガス流量調整手段23での圧力損失を考慮して原料ガスの設定圧力より僅かに高い圧力に設定する。また、分析ガス圧力調整手段24及び分析ガス流量調整手段26は、分析手段25における分析圧力、分析流量を考慮してそれぞれ設定する。   In order to manufacture a product mixed gas using the mixed gas manufacturing apparatus formed in this way, first, the set concentration of a specific component in the product mixed gas is input to the set concentration input means 31, and then the product supply valve 28 is closed. In this state, the set pressure of the raw material gas pressure adjusting means 21 is set to a pressure equal to or higher than the supply pressure of the product mixed gas, and the set pressure of the additive gas pressure adjusting means 22 is set to a pressure loss at the additive gas flow rate adjusting means 23. Is set to a pressure slightly higher than the set pressure of the raw material gas. The analysis gas pressure adjusting unit 24 and the analysis gas flow rate adjusting unit 26 are set in consideration of the analysis pressure and the analysis flow rate in the analysis unit 25.

この状態で混合ガス発生源41から原料ガス導入経路11に原料となる混合ガスを導入すると、原料ガスは、圧力が原料ガス圧力調整手段21の設定圧力に調整されてガス混合手段13に導入される。同時に、添加ガス供給源から添加ガス導入経路12に添加ガスを導入すると、添加ガスは、圧力が添加ガス圧力調整手段22の設定圧力に調整され、流量が添加ガス流量調整手段23に設定された流量に調整されるとともに、添加ガス流量調整手段23を通過する際の圧力損失で原料ガスの圧力と略同じ圧力となってガス混合手段13に導入される。   In this state, when a mixed gas as a raw material is introduced from the mixed gas generation source 41 to the raw material gas introduction path 11, the pressure of the raw material gas is adjusted to the set pressure of the raw material gas pressure adjusting means 21 and introduced into the gas mixing means 13. The At the same time, when the additive gas is introduced from the additive gas supply source into the additive gas introduction path 12, the pressure of the additive gas is adjusted to the set pressure of the additive gas pressure adjusting means 22, and the flow rate is set to the additive gas flow adjusting means 23. While being adjusted to the flow rate, the pressure loss when passing through the additive gas flow rate adjusting means 23 becomes substantially the same as the pressure of the raw material gas and is introduced into the gas mixing means 13.

ガス混合手段13で原料ガスと添加ガスとが混合した混合ガスは、製品混合ガスとして製品ガス供給経路15に導出されるが、製品供給弁28が閉じているために、その全量が分析経路14に流入して分析ガス圧力調整手段24で圧力が、分析ガス流量調整手段26で流量が、それぞれ所定値に調整されて分析手段25を通る状態となる。   The mixed gas in which the raw material gas and the additive gas are mixed by the gas mixing means 13 is led out to the product gas supply path 15 as a product mixed gas. However, since the product supply valve 28 is closed, the total amount of the mixed gas is analyzed. Then, the analysis gas pressure adjusting means 24 adjusts the pressure, and the analysis gas flow rate adjusting means 26 adjusts the flow rate to a predetermined value.

分析手段25において、製品混合ガス中の特定成分の濃度が分析され、濃度測定値25aが分析手段25から演算手段32に送られるとともに、分析ガス流量調整手段26からは流量設定値26aが、製品流量測定手段27からは流量測定値27a(この時点ではゼロ)がそれぞれ演算手段32に送られる。   In the analyzing means 25, the concentration of the specific component in the product mixed gas is analyzed, and the measured concentration value 25a is sent from the analyzing means 25 to the calculating means 32, and the flow rate set value 26a is sent from the analyzing gas flow rate adjusting means 26 to the product. The flow rate measurement means 27 sends the flow rate measurement value 27a (zero at this time) to the calculation means 32, respectively.

演算手段32では、設定濃度入力手段31からの設定濃度31aと、分析手段25からの濃度測定値25aと、分析ガス流量調整手段26からの流量設定値26a及び製品流量測定手段27からの流量測定値27aの合計流量値とに基づいてフィードバック制御演算が行われ、添加ガス流量調整手段23の添加ガス流量設定値32aを算出する。算出された添加ガス流量設定値32aは、演算手段32から添加ガス流量調整手段23に流量設定指示信号として送信され、この信号に基づいて添加ガス流量調整手段23が作動し、添加ガスの流量が調整されることにより、ガス混合手段13で混合した製品混合ガス中の特定成分の濃度が、設定濃度入力手段31に入力された特定成分濃度に応じた濃度に調整され、所定濃度の特定成分を含む製品混合ガスが得られることになる。   In the calculation means 32, the set concentration 31 a from the set concentration input means 31, the concentration measurement value 25 a from the analysis means 25, the flow rate set value 26 a from the analysis gas flow rate adjustment means 26, and the flow rate measurement from the product flow rate measurement means 27. The feedback control calculation is performed based on the total flow value of the value 27a, and the additive gas flow rate setting value 32a of the additive gas flow rate adjusting means 23 is calculated. The calculated additive gas flow rate setting value 32a is transmitted from the calculation means 32 to the additive gas flow rate adjusting means 23 as a flow rate setting instruction signal. Based on this signal, the additive gas flow rate adjusting means 23 is operated, and the additive gas flow rate is set. By adjusting, the concentration of the specific component in the product mixed gas mixed by the gas mixing unit 13 is adjusted to a concentration according to the specific component concentration input to the set concentration input unit 31, and the specific component having a predetermined concentration is adjusted. A mixed product gas containing is obtained.

ここで、製品供給弁28を開いて混合ガス使用先42への製品混合ガスの供給を開始すると、製品ガス供給経路15から大量の製品混合ガスが流出するのに伴って原料ガス導入経路11からの原料ガスの流入量が急激に増加するめ、演算手段32においては、製品供給弁28を閉じていたときの製品混合ガスの流量、すなわち、分析ガス流量調整手段26の流量設定値に相当する流量と、製品供給弁28を開いたときの製品混合ガスの流量、すなわち、分析ガス流量調整手段26の流量設定値に相当する流量に製品流量測定手段27で測定した流量を加えた合計流量との流量比率が算出され、この流量比率に基づいて前記添加ガス流量設定値32aが補正される。   Here, when the product supply valve 28 is opened and the supply of the product mixed gas to the mixed gas usage destination 42 is started, as a large amount of the product mixed gas flows out from the product gas supply path 15, the raw material gas introduction path 11 In the calculation means 32, the flow rate of the product mixed gas when the product supply valve 28 is closed, that is, the flow rate corresponding to the flow rate setting value of the analysis gas flow rate adjustment means 26 is increased. And the total flow rate obtained by adding the flow rate measured by the product flow rate measuring unit 27 to the flow rate corresponding to the flow rate set value of the analysis gas flow rate adjusting unit 26 when the product supply valve 28 is opened. A flow rate ratio is calculated, and the additive gas flow rate set value 32a is corrected based on the flow rate ratio.

これにより、補正後の添加ガス流量設定値32aに基づいて添加ガス流量調整手段23が作動し、添加ガス導入経路12から導入される添加ガスの流量が、原料ガスの流入量増加に見合った流量に調整され、製品混合ガス中の特定成分の濃度が設定濃度に制御される。したがって、原料ガスの流量が変化しても、製品混合ガス中の特定成分の濃度を設定濃度に高精度で制御することができ、所定の組成の製品混合ガスを安定して供給することができる。   As a result, the additive gas flow rate adjusting means 23 is operated based on the corrected additive gas flow rate setting value 32a, and the flow rate of the additive gas introduced from the additive gas introduction path 12 is a flow rate corresponding to the increase in the inflow amount of the source gas. The concentration of the specific component in the product mixed gas is controlled to the set concentration. Therefore, even if the flow rate of the raw material gas changes, the concentration of the specific component in the product mixed gas can be controlled to the set concentration with high accuracy, and the product mixed gas having a predetermined composition can be stably supplied. .

なお、本形態例では、製品混合ガスの流量を測定する製品混合ガス流量測定手段として、分析ガス流量調整手段26と製品流量測定手段27とを使用し、これらの合計流量を製品混合ガス流量測定手段で測定した流量測定値としているが、ガス混合手段13と分析経路14の分岐部との間に流量計を設置した場合は、この流量計の測定値が製品混合ガスの流量測定値となる。   In this embodiment, the analysis gas flow rate adjusting means 26 and the product flow rate measuring means 27 are used as the product mixed gas flow rate measuring means for measuring the flow rate of the product mixed gas, and these total flow rates are measured as the product mixed gas flow rate. However, if a flow meter is installed between the gas mixing means 13 and the branch part of the analysis path 14, the measured value of the flow meter becomes the flow measurement value of the product mixed gas. .

次に、本発明を、半導体製造装置から排出される排気ガス中のキセノンを精製し、再び半導体製造装置に供給する排気ガス精製装置に適用した一例を図2に示す系統図を参照して説明する。なお、以下の説明において、前記形態例で示した混合ガス製造装置における構成要素と同一の構成要素には、それぞれ同一符号を付して詳細な説明は省略する。   Next, an example in which the present invention is applied to an exhaust gas purifying apparatus that purifies xenon in exhaust gas discharged from a semiconductor manufacturing apparatus and supplies it again to the semiconductor manufacturing apparatus will be described with reference to a system diagram shown in FIG. To do. In the following description, the same components as those in the mixed gas production apparatus shown in the above-described embodiment are assigned the same reference numerals, and detailed description thereof is omitted.

ここに例示する半導体製造装置は、プラズマ励起のための雰囲気ガスとして、クリプトン又はキセノンとアルゴンとを主要ガス成分とする混合ガスを使用するものであって、この雰囲気ガスは、半導体製造装置で消費されることなく全てが排気ガスとして排出されるため、排気ガス精製装置で微量不純物を除去してキセノンやクリプトンを精製することにより、高価なキセノンやクリプトンを再利用するようにしている。しかし、半導体製造装置から排出される排気ガスの組成及び流量は、半導体製造装置の運用状態によって大きく変動するため、排気ガス精製装置から得られる精製混合ガスの組成や流量も変動してしまい、そのまま再利用することは困難であった。   The semiconductor manufacturing apparatus exemplified here uses a mixed gas containing krypton or xenon and argon as main gas components as an atmospheric gas for plasma excitation, and this atmospheric gas is consumed by the semiconductor manufacturing apparatus. Since everything is exhausted as exhaust gas, expensive xenon and krypton are reused by purifying xenon and krypton by removing trace impurities with an exhaust gas purification device. However, since the composition and flow rate of the exhaust gas discharged from the semiconductor manufacturing apparatus largely fluctuate depending on the operation state of the semiconductor manufacturing apparatus, the composition and flow rate of the purified mixed gas obtained from the exhaust gas purifying apparatus also fluctuate. It was difficult to reuse.

このように組成や流量が変動する半導体製造装置からの排気ガスを精製した後の精製混合ガスを原料ガスとし、所定組成、所定流量の製品混合ガスを安定して製造することにより、高価なクリプトンやキセノンの再利用を容易に行うことができる。   In this way, the purified mixed gas after purifying the exhaust gas from the semiconductor manufacturing apparatus whose composition and flow rate fluctuate is used as a raw material gas, and a product mixed gas having a predetermined composition and a predetermined flow rate is stably manufactured, so that expensive krypton And xenon can be easily reused.

図2において、半導体製造装置から排出されたキセノンとアルゴンとを主要ガス成分とする排気ガスは、排気経路51を通って排気ガス精製装置52に導入され、この排気ガス精製装置52で窒素、酸素、水分等の不純物成分が除去され、キセノンとアルゴンとの混合ガスとなった後、原料ガス導入経路11を通り、原料ガスとして混合ガス製造装置に導入される。   In FIG. 2, exhaust gas mainly containing xenon and argon discharged from the semiconductor manufacturing apparatus is introduced into an exhaust gas purification device 52 through an exhaust path 51, and nitrogen and oxygen are exhausted by the exhaust gas purification device 52. After the impurity components such as moisture are removed to form a mixed gas of xenon and argon, the raw material gas is introduced into the mixed gas production apparatus through the raw material gas introduction path 11 as a raw material gas.

運転開始時は、製品供給弁28が閉じられているので、原料ガス圧力調整手段21で圧力調整され、ガス混合手段13を通過した原料ガスは、分析経路14を通り、分析ガス圧力調整手段24で圧力が、分析ガス流量調整手段26で流量が、それぞれ所定値に調整されて分析手段25に導入され、原料ガス中のキセノンの濃度が測定される。分析手段25から排出されたガスは、該ガス中のキセノンを有効利用するため、回収経路53を通って排気ガス精製装置52に回収される。   Since the product supply valve 28 is closed at the start of operation, the pressure of the source gas is adjusted by the source gas pressure adjusting means 21, and the source gas that has passed through the gas mixing means 13 passes through the analysis path 14 and is analyzed by the analysis gas pressure adjusting means 24. The pressure is adjusted to a predetermined value by the analysis gas flow rate adjusting means 26 and introduced into the analysis means 25, and the concentration of xenon in the raw material gas is measured. The gas discharged from the analysis means 25 is recovered by the exhaust gas purification device 52 through the recovery path 53 in order to effectively use xenon in the gas.

分析手段25からのキセノン濃度信号(濃度測定値25a)と、分析ガス流量調整手段26からの流量信号(流量設定値26a)と、設定濃度入力手段31に入力されたキセノン濃度設定信号(設定濃度31a)とが演算手段32に送信され、キセノン濃度信号とキセノン濃度設定信号とでフィードバック制御演算が行われ、制御用出力信号として添加アルゴン流量信号(添加ガス流量設定値32a)が出力される。   A xenon concentration signal (concentration measurement value 25a) from the analysis means 25, a flow signal (flow rate set value 26a) from the analysis gas flow rate adjustment means 26, and a xenon concentration setting signal (set concentration) input to the set concentration input means 31 31a) is transmitted to the calculation means 32, feedback control calculation is performed with the xenon concentration signal and the xenon concentration setting signal, and an added argon flow rate signal (added gas flow rate set value 32a) is output as a control output signal.

一方、添加ガス導入経路12からは、添加ガスとしてアルゴンが導入され、添加ガス圧力調整手段22で圧力が調整され、添加ガス流量調整手段23で流量が調整されて混合手段13に導入される。添加ガス流量調整手段23は、運転開始時には全閉状態となっており、演算手段32からの添加アルゴン流量信号を受けて添加ガスの流量調整、すなわち、アルゴン添加量の調整を行う。   On the other hand, argon is introduced as an additive gas from the additive gas introduction path 12, the pressure is adjusted by the additive gas pressure adjusting means 22, the flow rate is adjusted by the additive gas flow rate adjusting means 23, and introduced into the mixing means 13. The additive gas flow rate adjusting means 23 is in a fully closed state at the start of operation, and receives the additive argon flow rate signal from the computing means 32 to adjust the additive gas flow rate, that is, the argon additive amount.

これにより、その時点での原料ガスの流量及び組成(キセノン濃度)に応じた添加ガスが導入され、ガス混合手段13で原料ガスと添加ガスとが混合することにより、ガス混合手段13からキセノン濃度が調整された混合ガスが製品ガス供給経路15に流出する。この混合ガスは、その全量が分析経路14を通って分析手段25に導入され、該混合ガス中のキセノン濃度が測定される。   Thereby, the additive gas corresponding to the flow rate and composition (xenon concentration) of the raw material gas at that time is introduced, and the raw material gas and the additive gas are mixed by the gas mixing unit 13, whereby the xenon concentration from the gas mixing unit 13. The mixed gas adjusted to flow out into the product gas supply path 15. The total amount of the mixed gas is introduced into the analyzing means 25 through the analysis path 14, and the concentration of xenon in the mixed gas is measured.

そして、キセノン濃度信号とキセノン濃度設定信号とが一致すると、すなわち、ガス混合手段13から導出した混合ガスのキセノン濃度が設定濃度と一致すると製品供給弁28が開き、所定のキセノン濃度となったキセノン・アルゴン混合ガスが製品流量測定手段27で流量を測定された後、製品混合ガスとして半導体製造装置に供給される。   When the xenon concentration signal and the xenon concentration setting signal coincide, that is, when the xenon concentration of the mixed gas derived from the gas mixing unit 13 coincides with the set concentration, the product supply valve 28 opens and the xenon having a predetermined xenon concentration is obtained. After the flow rate of the argon mixed gas is measured by the product flow rate measuring means 27, it is supplied as a product mixed gas to the semiconductor manufacturing apparatus.

このとき、演算手段32では、分析ガス流量調整手段26からの流量設定値26aと、製品流量測定手段27からの流量測定値27aとに基づいて、下記式(1)により添加ガス流量設定値32aを算出する。   At this time, in the calculation means 32, based on the flow rate set value 26a from the analysis gas flow rate adjusting means 26 and the flow rate measured value 27a from the product flow rate measuring means 27, the additive gas flow rate set value 32a is obtained by the following equation (1). Is calculated.

32a=Mv×(26a+27a)/26a・・・(1)
式(1)中の「Mv」は、演算手段32で行われるフィードバック制御演算で得られる濃度補正項であり、「(26a+27a)/26a」は、混合手段13から導出する混合ガスの流量変化率を示す流量補正項である。なお、前記流量補正項は、製品供給弁28が閉じているときを基準としている。このようにして算出された添加ガス流量設定値32aは、添加ガス流量調整手段23に送信され、添加ガス流量設定値32aで設定された流量の添加ガス(アルゴン)が混合手段13に導入される。
32a = Mv × (26a + 27a) / 26a (1)
“Mv” in Equation (1) is a concentration correction term obtained by feedback control calculation performed by the calculation means 32, and “(26a + 27a) / 26a” is the flow rate change rate of the mixed gas derived from the mixing means 13. Is a flow rate correction term. The flow rate correction term is based on when the product supply valve 28 is closed. The additive gas flow rate setting value 32a calculated in this way is transmitted to the additive gas flow rate adjusting means 23, and the additive gas (argon) having the flow rate set by the additive gas flow rate setting value 32a is introduced into the mixing means 13. .

原料ガスの組成及び製品混合ガスの流量は、供給先の半導体製造装置の運用状態によって大きく変化するが、前記濃度補正項によって原料ガスの組成変化に、前記流量補正項によって製品混合ガスの流量変化に、それぞれ対応して一定のキセノン濃度となった製品混合ガスを供給することができる。   The composition of the raw material gas and the flow rate of the product mixed gas vary greatly depending on the operating state of the semiconductor manufacturing apparatus that is the supply destination, but the concentration correction term changes the raw material gas composition, and the flow rate correction term changes the product mixed gas flow rate. In addition, a product mixed gas having a constant xenon concentration can be supplied.

さらに、本例では、ガス混合手段13として、直管13aの中間部から直角に分岐した分岐管13bを有するT字状に形成され、前記直管13aの一方の開口側に前記原料ガスを導入する原料ガス導入部13cが、該直管13aの他方の開口側に前記添加ガスを導入する添加ガス導入部13dが、前記分岐管13bに製品混合ガス導出部13eが、それぞれ設けられているガス混合器を使用している。   Further, in this example, the gas mixing means 13 is formed in a T-shape having a branch pipe 13b branched at a right angle from an intermediate portion of the straight pipe 13a, and the source gas is introduced into one opening side of the straight pipe 13a. A gas in which a raw material gas introduction part 13c is provided, an additive gas introduction part 13d for introducing the additive gas into the other opening side of the straight pipe 13a, and a product mixed gas outlet part 13e in the branch pipe 13b, respectively. A mixer is used.

このような構造のガス混合器を使用することにより、原料ガスと添加ガスとを短時間で効率よく混合することができるので、添加ガス流量調整手段23で流量調整して添加されたアルゴンによるキセノンの濃度変化が分析手段25で測定されるまでの遅延時間を短縮できるので、製品混合ガスの組成を、より高精度に制御することができる。   By using the gas mixer having such a structure, the source gas and the additive gas can be mixed efficiently in a short time. Therefore, the flow rate is adjusted by the additive gas flow rate adjusting means 23 and xenon is added by argon. Since the delay time until the concentration change is measured by the analyzing means 25 can be shortened, the composition of the product mixed gas can be controlled with higher accuracy.

また、本発明は、麻酔用キセノンのリサイクルシステムにも適用することができる。麻酔用キセノンのリサイクルシステムは、麻酔ガスとして酸素濃度約21%のキセノン・酸素混合ガスを患者に供給した後、患者の呼気を回収して再び麻酔ガスとして利用するものであって、呼吸によって放出される二酸化炭素等の不純物を除去するとともに、消費された酸素を添加して酸素濃度を約21%にするものである。   The present invention can also be applied to a xenon recycling system for anesthesia. The xenon recycling system for anesthesia supplies xenon / oxygen mixed gas with an oxygen concentration of about 21% as an anesthetic gas to the patient, collects the patient's exhalation, and uses it again as an anesthetic gas. In addition to removing carbon dioxide and other impurities, the consumed oxygen is added to bring the oxygen concentration to about 21%.

この場合、呼吸により放出される二酸化炭素等の不純物を精製装置で除去したキセノン・酸素混合ガスを原料ガスとして前記混合ガス製造装置に導入し、添加ガスとして酸素を使用するとともに、分析手段25として酸素濃度計を使用することにより、前述のようにして酸素濃度約21%の製品混合ガスを製造することができ、麻酔用のキセノン・酸素混合ガスとして再利用することができる。   In this case, the xenon / oxygen mixed gas from which impurities such as carbon dioxide released by respiration are removed by the refining device is introduced as a raw material gas into the mixed gas production device, and oxygen is used as an additive gas. By using an oxygen concentration meter, a product mixed gas having an oxygen concentration of about 21% can be produced as described above, and can be reused as a xenon / oxygen mixed gas for anesthesia.

供給する麻酔ガスの流量及び酸素消費量は、患者の年齢、性別等によって異なるため、回収するガスの流量及び酸素濃度は一定ではないが、本発明を適用することによって安定した酸素濃度の麻酔ガスを供給できる。   Since the flow rate and oxygen consumption of the anesthetic gas to be supplied vary depending on the age, sex, etc. of the patient, the flow rate and oxygen concentration of the recovered gas are not constant, but the anesthetic gas having a stable oxygen concentration by applying the present invention. Can supply.

なお、本発明は、前述の半導体製造装置の排気ガス精製装置や麻酔用キセノンリサイクルシステムに限らず、一般的なガス混合プロセスにも同様に適用することが可能である。また、前述のような添加ガス圧力調整手段22及び添加ガス流量調整手段23を備えた添加ガス導入経路12を複数経路設けることも可能であり、分析手段25で複数のガス成分を分析して演算処理に利用することも可能である。   The present invention is not limited to the above-described exhaust gas purifying apparatus and xenon recycling system for anesthesia, but can be similarly applied to a general gas mixing process. It is also possible to provide a plurality of additive gas introduction paths 12 including the additive gas pressure adjusting means 22 and the additive gas flow rate adjusting means 23 as described above, and the analysis means 25 analyzes and calculates a plurality of gas components. It can also be used for processing.

本発明の混合ガス製造装置の一形態例を示す系統図である。It is a systematic diagram which shows one example of a mixed gas manufacturing apparatus of this invention. 本発明を半導体製造装置の排気ガス精製装置に適用した一例を示す系統図である。It is a systematic diagram which shows an example which applied this invention to the exhaust-gas purification apparatus of a semiconductor manufacturing apparatus.

符号の説明Explanation of symbols

11…原料ガス導入経路、12…添加ガス導入経路、13…ガス混合手段、13a…直管、13b…分岐管、13c…原料ガス導入部、13d…添加ガス導入部、13e…製品混合ガス導出部、14…分析経路、15…製品ガス供給経路、21…原料ガス圧力調整手段、22…添加ガス圧力調整手段、23…添加ガス流量調整手段、24…分析ガス圧力調整手段、25…分析手段、25a…濃度測定値、26…分析ガス流量調整手段、26a…流量設定値、27…製品流量測定手段、27a…流量測定値、28…製品供給弁、31…設定濃度入力手段、31a…設定濃度、32…演算手段、41…混合ガス発生源、42…混合ガス使用先、51…排気経路、52…排気ガス精製装置、53…回収経路   DESCRIPTION OF SYMBOLS 11 ... Raw material gas introduction path, 12 ... Addition gas introduction path, 13 ... Gas mixing means, 13a ... Straight pipe, 13b ... Branch pipe, 13c ... Raw material gas introduction part, 13d ... Addition gas introduction part, 13e ... Derivation of product mixed gas , 14 ... analysis path, 15 ... product gas supply path, 21 ... raw material gas pressure adjustment means, 22 ... additive gas pressure adjustment means, 23 ... additive gas flow rate adjustment means, 24 ... analysis gas pressure adjustment means, 25 ... analysis means 25a ... measured concentration value, 26 ... analysis gas flow rate adjusting means, 26a ... flow rate set value, 27 ... product flow rate measuring means, 27a ... flow rate measured value, 28 ... product supply valve, 31 ... set concentration input means, 31a ... set Concentration, 32 ... calculation means, 41 ... mixed gas generation source, 42 ... mixed gas use destination, 51 ... exhaust path, 52 ... exhaust gas purifier, 53 ... recovery path

Claims (3)

少なくとも2種類の主要ガス成分を含有し、組成及び流量が経時変化する混合ガスを原料ガスとし、前記主要ガス成分の少なくとも1種類を含むガスを添加ガスとして前記原料ガスに添加し、添加後の混合ガスにおける前記主要ガス成分の少なくとも1種類のガスの濃度をあらかじめ設定された濃度に調整した製品混合ガスを製造する混合ガス製造装置において、前記原料ガスの圧力を設定圧力に調整して流出させる原料ガス圧力調整手段と、前記添加ガスの圧力を設定圧力に調整して流出させる添加ガス圧力調整手段と、前記添加ガスの流量を調整する添加ガス流量調整手段と、設定圧力に調整された前記原料ガスと設定圧力に調整されて流量調整された前記添加ガスとを混合するガス混合手段と、該ガス混合手段で混合した製品混合ガスの一部を取り出して該製品混合ガス中の少なくとも1種類のガスの濃度を測定する分析手段と、前記製品混合ガスの流量を測定する製品混合ガス流量測定手段と、前記製品混合ガスの少なくとも1種類のガスの濃度を設定する設定濃度入力手段と、該設定濃度入力手段に入力された設定濃度と前記分析手段で測定した濃度測定値と前記製品混合ガス流量測定手段で測定した流量測定値の変化率とに基づいて前記添加ガス流量調整手段の添加ガス流量設定値を算出する演算手段とを備えていることを特徴とする混合ガス製造装置。   A mixed gas containing at least two types of main gas components, the composition and flow rate of which changes over time is used as a source gas, and a gas containing at least one type of the main gas components is added to the source gas as an additive gas. In a mixed gas production apparatus for producing a product mixed gas in which the concentration of at least one kind of gas of the main gas component in the mixed gas is adjusted to a preset concentration, the pressure of the raw material gas is adjusted to a set pressure and is discharged. Raw material gas pressure adjusting means, additional gas pressure adjusting means for adjusting and flowing out the pressure of the additive gas, added gas flow rate adjusting means for adjusting the flow rate of the additive gas, and the pressure adjusted to the set pressure Gas mixing means for mixing the source gas and the additive gas whose flow rate is adjusted to a preset pressure, and a product mixed gas mixed by the gas mixing means Analyzing means for taking out a part and measuring the concentration of at least one kind of gas in the product mixed gas, product mixed gas flow rate measuring means for measuring the flow rate of the product mixed gas, and at least one kind of the product mixed gas Set concentration input means for setting the concentration of the gas, set concentration input to the set concentration input means, concentration measurement value measured by the analysis means, and change in flow rate measurement value measured by the product mixed gas flow rate measurement means And a calculating means for calculating an additive gas flow rate setting value of the additive gas flow rate adjusting means based on the rate. 前記ガス混合手段は、直管の中間部から直角に分岐した分岐管を有するT字状に形成され、前記直管の一方の開口側に前記原料ガスを導入する原料ガス導入部が、該直管の他方の開口側に前記添加ガスを導入する添加ガス導入部が、前記分岐管に製品混合ガス導出部が、それぞれ設けられていることを特徴とする請求項1記載の混合ガス製造装置。   The gas mixing means is formed in a T shape having a branch pipe branched at a right angle from an intermediate portion of the straight pipe, and a raw material gas introduction section for introducing the raw material gas into one opening side of the straight pipe is provided with the straight pipe. 2. The mixed gas production apparatus according to claim 1, wherein an additive gas introduction section for introducing the additive gas to the other opening side of the pipe is provided, and a product mixed gas outlet section is provided in the branch pipe. 少なくとも2種類の主要ガス成分を含有し、組成及び流量が経時変化する混合ガスを原料ガスとし、前記主要ガス成分の少なくとも1種類を含むガスを添加ガスとして前記原料ガスに添加し、添加後の混合ガスにおける前記主要ガス成分の少なくとも1種類のガスの濃度をあらかじめ設定された濃度に調整した製品混合ガスを製造する混合ガス製造方法において、前記原料ガスの圧力を設定圧力に調整し、前記添加ガスの圧力を設定圧力に調整するとともに流量を調整し、設定圧力に調整された前記原料ガスと設定圧力に調整されて流量調整された前記添加ガスとを混合して製品混合ガスとし、該製品混合ガスの一部を取り出して該製品混合ガス中の少なくとも1種類のガスの濃度を測定するとともに、前記製品混合ガスの流量を測定し、あらかじめ設定された製品混合ガスの少なくとも1種類のガスの濃度と、製品混合ガス中の少なくとも1種類のガスの濃度測定値と、製品混合ガスの流量測定値の変化率とに基づいて前記添加ガスの流量を調整することを特徴とする混合ガス製造方法。   A mixed gas containing at least two types of main gas components, the composition and flow rate of which changes over time is used as a source gas, and a gas containing at least one type of the main gas components is added to the source gas as an additive gas. In the mixed gas production method for producing a product mixed gas in which the concentration of at least one kind of gas of the main gas component in the mixed gas is adjusted to a preset concentration, the pressure of the raw material gas is adjusted to a set pressure, and the addition The gas pressure is adjusted to a set pressure and the flow rate is adjusted, and the raw material gas adjusted to the set pressure and the additive gas adjusted to the set pressure and the flow rate adjusted are mixed to obtain a product mixed gas, and the product A part of the mixed gas is taken out, the concentration of at least one kind of gas in the product mixed gas is measured, and the flow rate of the product mixed gas is measured. The addition based on the concentration of at least one kind of gas mixed in the product mixture gas, the measured concentration of at least one kind of gas in the product mixed gas, and the rate of change in the measured flow rate of the product mixed gas A method for producing a mixed gas, comprising adjusting a flow rate of a gas.
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