JP2007160582A - Manufacturing method of foamed blow molded product - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a manufacturing method of a foamed blow molded product suitable for manufacturing an air conditioning foam duct made hard to collapse a foamed parison by blowing pressure, not lowering the foaming magnification of the molded product and made hard to cause perforation due to the breaking of foams in a thin-walled part. <P>SOLUTION: In the manufacturing method of the foamed blow molded product wherein a thermoplastic synthetic resin 21 and a foaming agent 23 are charged in an extruder 11 to extrude the foamed parison 27 and air is blown in the foamed parison 27 in a state that the foamed parison 27 is received in a mold 31 to perform blow molding, the foaming agent 23 is charged in the extruder 11 along with the thermoplastic synthetic resin 21 and a thickener 25 and kneaded with the thermoplastic synthetic resin 21 and the thickener 25 in the extruder 11 to extrude the foamed parison 27. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

  The present invention relates to a method for producing a foamed hollow molded article, and more particularly to a method for producing a foamed hollow molded article by blow molding using a foamed parison.

  Conventionally, a foamed hollow molded product is manufactured by putting a thermoplastic synthetic resin and a foaming agent into an extruder, extruding the foamed parison, storing the foamed parison in a mold, and blowing the gas into the foamed parison. To be done.

  However, according to the conventional method for producing a hollow foam molded article, the foaming parison bubbles are crushed by the blowing pressure at the time of blow molding and the foaming ratio is reduced, or the thin part of the molded article causes bubble breakage and holes. There is a problem to do. Furthermore, when an air-conditioning foam duct is formed of a foamed hollow molded product, there is a problem that the sound reduction performance is lowered due to a decrease in foaming ratio.

JP 2000-505752 Gazette JP 2001-18283 A

  This invention has been made in view of the above points, and it is difficult for the foamed parison air bubbles to be crushed by the blowing pressure, the foaming ratio of the molded product does not decrease, and it is difficult to cause perforation due to foam breakage in the thin part, Provided is a method for producing a foamed hollow molded article suitable for producing a foam duct for air conditioning.

  The invention of claim 1 is a foam hollow molding in which a thermoplastic synthetic resin and a foaming agent are put into an extruder to extrude a foam parison, the foam parison is accommodated in a mold, and gas is blown into the foam parison to perform blow molding. In the manufacturing method of the product, the foaming agent is charged into the extruder together with the thermoplastic synthetic resin and the thickener, and the foaming agent is kneaded into the thermoplastic synthetic resin and the thickener in the extruder. Features.

  The invention of claim 2 is characterized in that, in claim 1, the thermoplastic synthetic resin and the thickener have a melt tension of 105 mN to 240 mN at 190 ° C. when both are kneaded.

  A third aspect of the present invention is characterized in that, in the first or second aspect, the thermoplastic synthetic resin is 50 to 90 parts by weight of HDPE and the rest is LLDPE in 100 parts by weight of the thermoplastic synthetic resin.

  The invention of claim 4 is characterized in that, in any one of claims 1 to 3, the thickener is 1 to 5 parts by weight with respect to 100 parts by weight of the thermoplastic synthetic resin.

  According to the present invention, since the foaming parison is extruded by kneading the foaming agent into the thermoplastic synthetic resin and the thickener in the extruder, the foaming is performed by blowing pressure at the time of blow molding using the foamed parison due to the action of the thickening agent. It is difficult for the air bubbles of the parison to be crushed, the foaming ratio of the molded product does not decrease, and it is difficult for the thin-walled portion to perforate due to foam breakage, and a good foamed hollow molded product can be produced. Furthermore, when the obtained foamed hollow molded article is a foam duct for air conditioning, a high sound reduction effect can be obtained due to the high foaming ratio of the tube wall.

  In addition, the thermoplastic synthetic resin and the thickener have a melt tension of 105 mN to 240 mN at 190 ° C. when both are kneaded, so that the foamed parison bubbles are more difficult to break during blow molding, and the molded product It is hard to produce a hole in the thin wall part.

  Furthermore, 50 to 90 parts by weight of HDPE and LLDPE in 100 parts by weight of the thermoplastic synthetic resin and LLDPE prevent the deterioration of the rigidity of the molded product and more effectively prevent bubbles from being crushed by the blow-in pressure. be able to.

  Further, by setting the thickener to 1 to 5 parts by weight with respect to 100 parts by weight of the thermoplastic synthetic resin, the melt tension after kneading the thermoplastic synthetic resin and the thickener is suitable for producing a foamed hollow molded product. The range can be set, and good blow moldability can be obtained.

  Hereinafter, embodiments of the present invention will be described in detail. FIG. 1 is a schematic view of a manufacturing apparatus used in one embodiment of the present invention.

  In the present invention, the thermoplastic synthetic resin 21, the foaming agent 23, and the thickener 25 are put into the extruder 11. The thermoplastic synthetic resin 21, the foaming agent 23, and the thickening agent 25 may be put into the extruder 11 without being mixed in advance, or at least two of the thermoplastic synthetic resin 21, the foaming agent 23, and the thickening agent 25 may be added. You may mix a kind beforehand. Alternatively, the thermoplastic synthetic resin 21 and the thickener 25 may be kneaded in advance and pelletized, and the pellet and the foaming agent may be charged into the extruder 11. In this case, the thickener is easily dispersed uniformly, and the quality stabilizing effect is enhanced.

  In the extruder 11, the thermoplastic synthetic resin 21, the foaming agent 23 and the thickener 25 are kneaded by the screw 13 and heated to melt the thermoplastic synthetic resin 21, and the melt tension (melting tension) of the kneaded product. ) Is increased by the thickener 25. The kneaded material having an increased melt tension is foamed by the foaming agent 23 contained in the kneaded material and extruded from the cross head 15 as a foamed parison 27. The extruded foamed parison 27 is in a state where the thermoplastic synthetic resin 21 is melted. Then, the extruded foam parison 27 is accommodated in a mold 31, the mold 31 is closed to seal the foam parison 27, and from a gas blowing nozzle (not shown) provided at the center of the crosshead 15, A gas such as air is blown into the foamed parison 27 in the mold 31 and the foamed parison 27 is expanded and brought into contact with the inner surface 33 of the mold 31 to form the desired foamed hollow molded product shape. The expanded foamed parison is cooled and solidified to fix the shape, and then the mold 31 is opened to take out the foamed hollow molded product. In addition, the burr | flash etc. are removed as needed with respect to the foaming hollow molded product taken out from the said shaping | molding die 31 after that.

  In addition, the said shaping | molding die 31 makes the inner surface 33 of a shaping | molding die equal to the outer surface shape of a duct, when the foaming hollow molded product made into the objective is a foaming duct for air conditioning, such as a motor vehicle.

  The thermoplastic synthetic resin 21 is not particularly limited as long as it can be blow-molded, and is determined according to the physical properties required for the intended foamed hollow molded article. Examples of the thermoplastic synthetic resin that can be used include polyethylene, polypropylene, polyvinyl chloride resin, polystyrene, and polyethylene terephthalate (PET). In particular, the thermoplastic synthetic resin 21 is preferably 50 to 90 parts by weight of HDPE (high density polyethylene) and 100 parts by weight of thermoplastic synthetic resin 21 with LLDPE (linear low density polyethylene). When the HDPE is less than 50 parts by weight (when the LLDPE exceeds 50 parts by weight), the rigidity of the molded product decreases, while when the HDPE exceeds 90 parts by weight (when the LLDPE is less than 10 parts by weight) The foaming parison bubbles are crushed by the blowing pressure at the time of blow molding, and the foaming ratio is lowered.

  As the foaming agent 23, a chemical foaming agent or a physical foaming agent used in a known method for producing a hollow foam molded article can be used without limitation. Moreover, although the said foaming agent 23 is shown by the pellet form in the figure, it is not restricted to a pellet form. Examples of the chemical foaming agent (decomposable foaming agent) include sodium hydrogen carbonate, sodium citrate, azodicarbonamide, dinitrosopentamethylenetetramine and the like. Examples of physical foaming agents (volatile foaming agents) include propane, normal butane, isobutane, normal pentane, isopentane, normal hexane, isohexane, methyl chloride, carbon dioxide gas, nitrogen gas, and the like. A chemical foaming agent and a physical foaming agent may be used in combination.

  The thickener 25 can be used as long as it increases the melt tension of the kneaded material in the extruder. Specifically, examples of the thickener 25 include an acrylic modified product of polytetrafluoroethylene (PTFE). The addition amount of the thickener 25 is preferably 1 to 5 parts by weight with respect to 100 parts by weight of the thermoplastic synthetic resin 21. If the amount is less than 1 part by weight, the melt tension after kneading the thermoplastic synthetic resin and the thickener is lower than the lower limit of the range suitable for the production of the foamed hollow molded product, in this example, lower than 105 mN at 190 ° C. During molding, the foamed parison bubbles are more likely to break, and holes are easily formed in the thin portion of the molded product. On the other hand, if the thickener exceeds 5 parts by weight, the melt tension after kneading the thermoplastic synthetic resin and the thickener is the upper limit of the range suitable for the production of the foamed hollow molded article, in this example 190 ° C. When it becomes higher than 240 mN, the swell of the parison itself becomes large and the productivity of blow molding decreases.

  In addition, the measurement of the melt tension in this invention was measured with the apparatus shown in FIG. That is, a cylindrical body 41 having an inner diameter of 9.5 mm in which a hole 42 of φ2.0 mm × L20 mm is formed at the bottom is arranged vertically, and a mixture P of a thermoplastic synthetic resin and a thickener is placed in the cylindrical body 41. The mixture P is charged and maintained at 190 ° C., and the mixture P in the cylindrical body 41 is pressed by the pressing plate 43 at a speed of 20 mm / min to be pushed downward from the hole 42 at the bottom of the cylindrical body 41 and the extruded mixture. P1 is rotated in the horizontal direction by reels 44 and 45 and pulled at a speed of 3.1 m / min. The reel 44 that changes the direction in the horizontal direction is connected to a tension measuring device 46. The melt tension was measured by value.

  HDPE (product name: KB148A, manufactured by Nippon Polyethylene Co., Ltd.) and LLDPE (product name: Novatec (registered trademark) UF840, manufactured by Nippon Polyethylene Co., Ltd.) are used as thermoplastic synthetic resins, and polytetrafluoroethylene (PTFE) is used as a thickener. Acrylic modified product (product name: Metabrene A-3000, manufactured by Mitsubishi Rayon Co., Ltd.) was used. A kneaded material was prepared at a weight part ratio of 1 to 14, and the melt tension of the kneaded material was measured by the method shown in FIG. Further, a chemical foaming agent (product name: EE405D, manufactured by Eiwa Kasei Kogyo Co., Ltd.) was used as the foaming agent, and the HDPE, LLDPE, thickener and foaming agent were designated No. 3 to 13 parts by weight were charged into an extruder to form a foamed parison, and then a foamed duct for automobile air conditioning shown in FIG. 3 was blow molded using a duct molding die.

  The air-conditioning foamed duct thus obtained was subjected to a comprehensive judgment by judging duct rigidity, foamed state, presence of holes, and moldability. The determination results are as shown in Table 1. The duct rigidity was determined based on whether or not the duct had sufficient rigidity, and “○” was given to the satisfactory one, “△” was given to the one that was slightly inferior, and “X” was shown to be unsatisfactory. In addition, the foamed state is determined by cutting the molded product to determine whether or not the bubbles on the cut surface are foamed. The case where the bubbles were crushed was designated as “x”. On the other hand, the presence or absence of a hole is determined by observing whether or not a pinhole is generated in the thin corner portion 51 in the air-conditioning foamed duct shown in FIG. “△” indicates that there are many, and “×” indicates that there are many.

  No. in Table 1 From the results of 3 to 8, it can be seen that the foaming state and perforation can be improved by using a thickener. Furthermore, no. From the results of 1 and 2, it can be understood that if the melt tension after kneading the thermoplastic synthetic resin (HDPE and LLDPE) and the thickener is low, it is disadvantageous in the foamed state and perforation. On the other hand, no. As in 9 and 12, when the melt tension after kneading the thermoplastic synthetic resin (HDPE and LLDPE) and the thickener exceeds 240 mN at 190 ° C., the swell of the parison becomes large and the blow productivity decreases. It becomes like this. Furthermore, no. From the results of 2, 5, 8, 11, 13, and 14, it is understood that duct rigidity and foaming state can be improved when HDPE is 50 to 90 parts by weight and the rest is LLDPE in 100 parts by weight of thermoplastic synthetic resin. . No. From the results of 3 to 12, it is understood that the amount of the thickener is preferably 1 to 5 parts by weight.

It is the schematic of the manufacturing apparatus used for one Example of this invention. It is a figure which shows the measuring method of the melt tension in this invention. It is a perspective view which shows one Embodiment of the foaming duct for an air conditioning of the motor vehicle obtained with the manufacturing method of this invention.

Explanation of symbols

DESCRIPTION OF SYMBOLS 11 Extruder 13 Screw 15 Crosshead 21 Thermoplastic synthetic resin 23 Foaming agent 25 Thickener 27 Foam parison 31 Mold

Claims (4)

In the manufacturing method of a foamed hollow molded article in which a thermoplastic synthetic resin and a foaming agent are put into an extruder to extrude a foamed parison, the foamed parison is accommodated in a mold, and gas is blown into the foamed parison to perform blow molding.
The foamed hollow molding characterized in that the foaming agent is charged into the extruder together with the thermoplastic synthetic resin and the thickener, and the foaming agent is kneaded into the thermoplastic synthetic resin and the thickener in the extruder. Product manufacturing method.   2. The method for producing a hollow foam molded article according to claim 1, wherein the thermoplastic synthetic resin and the thickener have a melt tension of 105 mN to 240 mN at 190 ° C. when both are kneaded.   The said thermoplastic synthetic resin is 50-90 weight part of HDPE in 100 weight part of thermoplastic synthetic resins, and the remainder is LLDPE, The manufacturing method of the foaming hollow molded product of Claim 1 or 2 characterized by the above-mentioned. The said thickener is 1-5 weight part with respect to 100 weight part of said thermoplastic synthetic resins, The manufacturing method of the foaming hollow molded article as described in any one of Claim 1 to 3 characterized by the above-mentioned.

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