JP2007160169A - Magnetic separation wastewater treatment system using biological regenerative form magnetic activated carbon - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a wastewater treatment system enabling a wastewater treatment of a high speed and high efficiency by space saving and at low costs. <P>SOLUTION: Magnetic activated carbons to which a magnetism is applied adsorb dissolved organic matter in wastewater, a separation and recovery are carried out by a magnetic separation, and a reproduction and reuse are carried out by a biological treatment. In a continuous magnetic filter system, a rotating type filter belt comprising meshes of a magnetic wire is arranged at a prestage of a superconductive magnet to separate and recover the magnetic activated carbons caught by the magnetic wire at a removal part. A biological regenerative tank of the magnetic activated carbons is provided with a meandering rotating type magnetic belt meandering above and below more than once, and entering and leaving from a water surface of the tank. While the magnetic activated carbon is transported attaching to the magnetic belt, aerobic and anaerobic conditions are made, and the organic matter adsorbed by the magnetic activated carbon is decomposed by organisms attached to the activated carbon. Further, powdery activated carbon can also be used as magnetic activated carbon. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

  The present invention relates to an advanced and high-speed treatment technology for wastewater in which dissolved organic substances and the like in wastewater are adsorbed and removed by magnetic activated carbon that can be regenerated by microorganisms, and magnetic activated carbon is recovered and reused by magnetic separation technology.

  In industrial and domestic wastewater from dyeing factories, food factories, paper factories, semiconductor factories, etc., water pollution-causing substances such as COD-causing substances and BOD-causing substances are in the form of suspended substances, colloidal substances, and dissolved substances. Existing. Such wastewater treatment includes physical treatment methods such as filtration, precipitation, adsorption and magnetic separation, physicochemical treatment methods such as ozone, hydrogen peroxide, and ultraviolet light, activated sludge method, biofilm treatment method. Biological treatment methods such as have been used.

  For example, wastewater treatment by the activated sludge method typically involves the use of dissolved oxygen dissolved in a mixed solution by aeration of a mixed solution containing wastewater in activated sludge containing a high concentration of aerobic microorganisms. This is a process for decomposing pollutants in wastewater (for example, see Patent Document 1). However, wastewater treatment by the activated sludge method requires a large aeration tank and also generates excess sludge.

  Also, for example, in wastewater treatment by magnetic separation, a magnetic filter consisting of magnetic fine wires is installed in the high magnetic field of a superconducting magnet to create a high gradient magnetic field and capture the substance to be separated with a strong magnetic force. Separated. A technique that mainly removes suspended substances and colloidal substances in wastewater by combining the coagulation sedimentation method and this magnetic separation technique has also been proposed (for example, see Patent Document 2). FIG. 8 shows an example of a conventional wastewater treatment system that combines the coagulation sedimentation method and magnetic separation. First, in the flocculation tank 11, a pollutant in the wastewater is entangled with a magnetic substance using a flocculant to form a magnetic floc. Next, the heavy magnetic floc is precipitated and separated in the sedimentation tank 12 and processed in the sludge tank 16. The supernatant water of the settling tank 12 is sent to the superconducting magnetic separator 14 to separate the magnetic floc, and the treated water is drained or recycled.

  On the other hand, there is a social requirement to remove pollutants in wastewater to a higher degree, and to make wastewater or recycled water free from environmental pollution, and even in wastewater treatment by magnetic separation, especially dissolved dissolved in wastewater. There is a need for further improvements in processing capacity for organic matter.

In order to capture dissolved organic matter in wastewater treatment by magnetic separation, for example, use of activated carbon can be considered, but regeneration of activated carbon is necessary. In the conventional activated carbon regeneration treatment, a method of heating (800 ° C.) to thermally decompose the adsorbed material and activating the carbide with steam has been mainly used. The treatment cost was 60 to 70% of that of charcoal, and the treatment cost was high, and the loss of activated carbon due to heat was large.
JP-A-8-257582 Japanese Patent Application No. 10-35872

  An object of the present invention is to provide a wastewater treatment system capable of solving the above problems and performing high-speed and high-efficiency advanced wastewater treatment at a compact and inexpensive cost.

  Another object of the present invention is to increase the treatment performance (sophistication of treatment) of a conventional superconducting magnetic separation device used in a wastewater treatment system.

  Another object of the present invention is to provide a biological regeneration tank that can regenerate activated carbon used in a wastewater treatment system and can be optimally adapted to aerobic and anaerobic organisms without the need for a conventional aeration mechanism. .

  In order to achieve the above object, the present invention provides a wastewater treatment system for performing advanced wastewater treatment by magnetic separation using biologically activated magnetic activated carbon. Specifically, the dissolved activated carbon in the wastewater is collected using magnetic activated carbon that has magnetized activated carbon having adsorption capability, this magnetic activated carbon is isolated in the magnetic separation process, and the recovered activated carbon is regenerated by microorganisms. It is used again in the adsorption process. Incidentally, the magnetic activated carbon is 0.05 g, and it is possible to adsorb almost 100% of the chlorinated compound (concentration of about 0.1 mg / l, 30 ml) in one hour (FIG. 9). It has also been demonstrated that other organic substances (vitamins and peptones) can be adsorbed efficiently.

  The continuous magnetic filter system according to the present invention comprises a magnetic separation device using a superconducting magnet for wastewater treatment and a mesh of magnetic wire, and is disposed at the front stage of the magnetic separation device and at least partially of the magnetic field of the superconducting magnet. A rotary filter belt under the influence, and a removing unit that peels a substance to be separated attached to the rotary filter belt. The magnetic separation device may be a conventional superconducting magnetic separation device, for example, provided with a magnetic filter made of magnetic fine wires in a magnetic field.

  Further, the continuous magnetic filter system according to the present invention has an additional coil for enlarging the magnetic field at the location where the rotary filter belt is located near the end of the superconducting magnet excitation coil on the side where the rotary filter belt is provided. It can also be provided. By this additional coil, the magnetic force exerted on the substance to be separated by the rotary filter belt is strengthened, and the separation ability is improved.

  The magnetic separation device used in the present invention is provided with a suction removal means for removing the substance to be separated attached to the wall surface of the wastewater passage by suction without providing a magnetic filter made of magnetic fine wires in the bore of the superconducting magnet. It can also be. It is mainly effective when the flow rate of wastewater is relatively slow, and the substance to be separated attached to the wall surface of the magnetic field center (substantially the center in the longitudinal direction of the bore) created by the superconducting magnet can be continuously sucked and removed.

  In addition, the magnetic separation device used in the present invention may be configured to include one or more magnetic filters provided with a plurality of suction holes in the bore of the superconducting magnet. The peripheral edge of the suction hole is made of a protruding magnetic material, and the suction hole communicates with the suction removal pipe. The substance to be separated attached to the peripheral edge of the suction hole and the suction hole is continuously passed through the suction removal pipe. Can be removed by suction. Since a high gradient magnetic field is generated at the protruding peripheral edge of the suction hole made of a magnetic material and the magnetic substance to be separated is attracted by a strong magnetic force, it is effective even when the flow rate of waste water is relatively high.

  The biological activated carbon bioregeneration tank according to the present invention has one or more tanks for storing water containing organisms that decompose organic matter in waste water adsorbed on the magnetic activated carbon, and magnetic activated carbon to be regenerated on the magnetic belt. Activated carbon take-in part to be taken in and attached, activated carbon take-out part to peel off and regenerate the regenerated magnetic activated carbon from the magnetic belt, and meandering rotary magnetic belt to meander multiple times in the tank up and down and move in and out from the water surface stored in the tank With. The regeneration of magnetic activated carbon by microorganisms makes the organic matter adsorbed on the activated carbon mineralized by biodegradation, and enables the semi-permanent reuse of activated carbon at low cost and energy saving.

  The tank used in the biological regeneration tank of the magnetic activated carbon according to the present invention can be a single stage or a plurality of stages (a plurality of tanks are arranged in series). In the case of a multi-stage tank, a single annular magnetic belt is used as in the case of the single stage, and each tank is meandered from the first stage tank to the final stage tank, and then the final stage tank. It can be set as the structure which goes out to the exterior of a tank, passes under the tank bottom, and returns to the tank of the first stage. Such a multi-stage tank configuration is particularly effective when one tank cannot completely regenerate magnetic activated carbon, or when a plurality of bacteria that cannot survive in the same environment are used.

  The biological activated carbon regeneration tank according to the present invention may be configured to change the ratio of the time during which the magnetic belt is in water and the time in the air by changing the relative water level in the tank with respect to the magnetic belt. The combination of aerobic organisms and anaerobic organisms used for the regeneration of magnetic activated carbon can be adjusted to optimal aerobic and anaerobic conditions.

  A wastewater treatment system according to the present invention includes an adsorption tank that adsorbs pollutants in wastewater to magnetic activated carbon, at least one superconducting magnetic separation device that magnetically separates the magnetic activated carbon, and at least one biological regeneration tank. The magnetic activated carbon separated and recovered by the superconducting magnetic separator is regenerated in the biological regeneration tank and reused in the adsorption tank. This superconducting magnetic separation device can also be the continuous magnetic filter system described above. Moreover, the magnetic activated carbon to be used is a particle form or a powder form, Preferably it is a powder form.

  Next, the operation of the continuous magnetic filter system of the present invention is as follows. Since at least a part of the rotary filter belt is disposed in the external magnetic field (leakage magnetic field) created by the superconducting magnet, a high gradient magnetic field is generated in the vicinity of the mesh-like magnetic wire constituting the rotary filter belt. Due to the high gradient magnetic field, the activated carbon provided with magnetism that adsorbs the pollutant in the wastewater upstream of the present system, or the magnetic floc that is entangled with the magnetic substance and aggregates the pollutant is captured by the magnetic wire. The rotary filter belt is circulated by a driving roller, and carries the magnetic activated carbon having residual magnetization to the removal unit. In the removing unit, water or air is sprayed onto the rotary filter belt to remove and collect the magnetic activated carbon.

  The effect | action of the biological regeneration tank of the magnetic activated carbon of this invention is demonstrated. The magnetic activated carbon adsorbing the dissolved organic matter in the wastewater is magnetically separated and collected, and is deposited on the magnetic belt at the activated carbon intake part of the biological regeneration tank of the magnetic activated carbon. The magnetic belt meanders up and down and advances alternately in the water and in the air, during which the adsorbed organic matter is decomposed by the organisms attached on the activated carbon. Activated carbon that has been regenerated by decomposing the adsorbed organic matter is peeled off from the magnetic belt at the activated carbon take-out section, removed from the regeneration tank, and reused. Since organisms attached to the magnetic activated carbon exist in water and in the air for a predetermined time, it is possible to create aerobic and anaerobic conditions that optimize the decomposition efficiency of the organisms used.

  Next, the operation of the wastewater treatment system of the present invention will be described. Waste water is stored in a magnetic activated carbon adsorption tank, magnetic activated carbon is added and stirred, and dissolved organic substances in the waste water are adsorbed onto the activated carbon. Next, this waste water is sent to a superconducting magnetic separation device, and the magnetic activated carbon is separated and recovered, and the treated water is reused as waste water or recycled water. The magnetic activated carbon separated and recovered by the superconducting magnetic separator is sent to a biological regeneration tank and regenerated by biological treatment. The regenerated magnetic activated carbon is sent to the adsorption tank and reused.

  As described above, in the continuous magnetic filter system of the present invention, an additional conveyor type magnetic filter device is provided using the external magnetic field (leakage magnetic field) before the conventional superconducting magnetic separation device. Efficiency has improved significantly.

  In addition, the biological regeneration tank of the present invention can perform aerobic treatment and anaerobic treatment simultaneously by moving magnetic activated carbon in the air and water using a magnetic belt. Organic matter can be efficiently mineralized by species (anaerobic and aerobic bacteria). In addition, the biological regeneration tank for magnetic activated carbon is provided independently of the wastewater treatment tank, so that decomposition and growth by microorganisms on the activated carbon can be easily controlled, and surplus sludge can be greatly reduced. In addition, magnetic activated carbon can be regenerated and reused with high efficiency, contributing to lower costs.

  In addition, the wastewater treatment system according to the present invention organically combines adsorption with magnetic activated carbon, magnetic separation with a superconducting magnet, and regeneration of magnetic activated carbon with microorganisms. It is particularly effective for water recycling at dyeing factories, food factories, paper factories, semiconductor factories, etc.

Hereinafter, embodiments of the present invention will be described with reference to FIGS.
FIG. 1 shows a continuous magnetic filter system 20 according to the present invention, in which a conveyor type magnetic filter device 24 is provided in front of a conventional superconducting magnetic separation device 22. The conveyor-type magnetic filter device 24 rotates a rotary filter belt 28 made of a mesh-like magnetic wire by rollers 30 and 32 driven by motors (not shown). For example, a magnetic stainless steel wire can be used as the magnetic wire, and the wire diameter and mesh shape are appropriately designed in consideration of capture efficiency, mechanical strength, and the like. The conveyor-type magnetic filter device 24 includes a removing unit 34 that removes and collects the magnetic activated carbon 36 by spraying water or air. The removal unit 34 is provided in a place where there is no waste water, and preferably in a place where there is almost no external magnetic field (A) created by the superconducting magnet. Although the conveyor-type magnetic filter device 24 is illustrated as being disposed upstream (upstream) of the conventional superconducting magnetic separation device 22, it can also be provided downstream (downstream).

  The superconducting magnetic separation device 22 is provided with a magnetic filter (not shown) in a superconducting magnet 26, and the substance to be separated such as magnetic activated carbon and magnetic floc is magnetically attracted to the magnetic filter and separated from the waste water. To do. This magnetic filter is provided with, for example, a magnetic fine wire for generating a magnetic gradient, and a high gradient magnetic field can be realized particularly near the magnetic fine wire. The magnetic force that attracts the substance to be separated to the magnetic wire is proportional to the product of the strength of magnetization and the magnetic gradient. A strong magnetic field created by a superconducting magnet and a magnetic wire placed in the magnetic field generate strong magnetization and a high gradient magnetic field, resulting in a large magnetic force. Of course, the superconducting magnetic separator 22 may be of any type, and for example, a magnetic separator (Japanese Patent Application No. 2003-288440) that can be continuously processed using a laminated magnetic filter can be used.

  FIG. 2 shows that an additional coil 42 is added to the end of the superconducting magnet 26 on the side where the conveyor type magnetic filter device 24 is provided, and the outside of the conveyor type magnetic filter device 24. A state (B) of increasing the magnetic field is shown. As a result, the magnetic force acting on the magnetic activated carbon is strengthened and the separation ability is increased. The additional coil 42 may be formed by increasing the number of turns of the existing coil 40 at the end on the side where the conveyor type magnetic filter device 24 is provided, or by winding a coil separately from the existing coil 40. Also good. Alternatively, when the periphery of the superconducting magnet 26 is covered with a magnetic shield, the external magnetic field can be strengthened by weakening or eliminating the magnetic shield on the side where the conveyor type magnetic filter device 24 is provided. it can.

  FIG. 3 shows one embodiment of the superconducting magnetic separation device 22 of the present invention. The bore of the superconducting magnet 26 is not provided with a magnetic filter made of a magnetic wire or the like, and the substance to be separated is mainly provided with the strongest magnetic field at the center in the longitudinal direction of the bore. The waste water conduit 46 is pulled by the magnetic force to adhere to the inner wall of the waste water conduit 46. The substance to be separated adhering to the inner wall is removed by continuously sucking and removing by a suction removing means having a pipe or the like connected to a driving device (not shown) such as a pump. When the flow rate of the wastewater in the superconducting magnet 26 is sufficiently slow (for example, 1 cm / second) and the magnetic force of the superconducting magnet 26 acting on the substance to be separated provided with magnetism is sufficiently larger than the force carried by the wastewater. It is particularly effective. Of course, this magnetic separation device can also be used as a single magnetic filter device without the conveyor type magnetic filter device 24.

  FIG. 4 shows another embodiment of the superconducting magnetic separation device 22 of the present invention. 4A is a longitudinal sectional view of the bore portion of the superconducting magnet 26, FIG. 4B is a front view, and FIG. 4C is an enlarged view of a broken line portion C in FIG. 4A. In this configuration, a magnetic filter 47 having a plurality of suction holes 48 is provided in the bore of the superconducting magnet 26, and the suction holes 48 are connected to the suction removal pipe 45 (FIGS. 4A and 4 ( B)). The peripheral edge of the suction hole 48 is made of a protruding magnetic material, and a high gradient magnetic field is generated around the periphery. A strong magnetic force acts on the substance to be separated 36 to which magnetism is imparted by the high gradient magnetic field, and adheres to the periphery and the inside of the suction hole 48. The adhered material to be separated 36 is continuously sucked and removed by a suction removing tube 45 connected to a driving device (not shown) such as a pump. The magnetic filter 47 can be provided in a plurality of stages, and the magnetic separation device 22 can be used as a single magnetic filter device without the conveyor type magnetic filter device 24.

  FIG. 5 schematically shows the configuration of a biological regeneration tank 18 of magnetic activated carbon. The biological regeneration tank 18 includes a magnetic belt 50, a magnetic activated carbon take-in portion 52, a magnetic activated carbon take-out portion 54, and the like. The magnetic belt 50 is formed by, for example, connecting belt-shaped magnet sheets in an annular shape. The magnetic belt 50 snakes up and down so as to enter and exit from the water 58 in the tank a plurality of times by a drive motor 56 and rollers (not shown). In FIG. 5, the magnetic belt rotates 180 degrees a plurality of times in the air and in the liquid and meanders up and down, but the rotation angle can be arbitrarily selected. From the viewpoint of increasing the processing amount, rotation by 180 degrees is preferable. Moreover, although the biological reproduction | regeneration tank 18 of FIG. 5 is an example which consists of one tank, it can also be set as the multistage type structure which has arrange | positioned the several tank in series (not shown). In the case of a multi-stage tank, one common annular magnetic belt is used, and each tank is meandered sequentially from the first tank to the last tank, and from the last tank to the first tank. It can be set as the structure which returns to the tank through the exterior of a tank. The magnetic belt 50 is driven by a driving motor 56 to move in a circulating manner. By adjusting the speed of the drive motor 56, the length of time of the aerobic and anaerobic conditions of the activated carbon can be changed. When the magnetic belt 50 is in the air, the aerobic biological treatment (C) is mainly performed, and when it is in the liquid, the anaerobic biological treatment (D) is mainly performed. Examples of the organism used in the organism regeneration tank 18 include bacteria such as Bacillus genus, Vibrio genus, and Pseudomonas genus. As a basic experiment, when activated carbon saturated with adsorption with a chlorinated compound is immersed in a culture solution of bacteria (genus Pseudomonas) and exposed alternately to anaerobic and aerobic conditions, the adsorption capacity is up to 65% in 24 hours. It was regenerated (Fig. 10).

  First, the magnetic activated carbon 36 recovered by magnetic separation is taken into the magnetic belt 50 of the biological regeneration tank 18 by the activated carbon intake unit 52. The organic matter adsorbed on the magnetic activated carbon 36 is decomposed and regenerated by living organisms adhering to the magnetic activated carbon while the magnetic activated carbon 36 adheres on the magnetic belt 50 and is transported in water and air in the tank. . The regenerated magnetic activated carbon 36 ′ is peeled off from the magnetic belt 50 by the activated carbon take-out section 54 and taken out from the biological regeneration tank 18.

  FIG. 6 shows a method of changing the time ratio of the aerobic condition and the anaerobic condition by adjusting the height position of the magnetic belt 50 up and down in order to optimize the decomposition ability of the aerobic organism and the anaerobic organism to be used. explain. FIG. 6 (A) shows a state in which the magnetic belt 50 is raised with respect to the liquid level 60, and it takes a long time for aerobic conditions. FIG. 6B shows a state in which the magnetic belt 50 is lowered with respect to the liquid surface 60, and the time under anaerobic conditions is long. In FIG. 6, although the magnetic belt 50 is moved up and down, the liquid level may be moved up and down.

  Bacteria dead bodies and incomplete degradation products generated when purifying wastewater by the activated sludge method are called excess sludge. Theoretically, if the rate of microbial self-degradation and the growth rate match, the generation of excess sludge can be prevented. Can do. However, if the wastewater treatment rate is maintained, the activity of microorganisms changes, and surplus sludge is inevitably produced. Removal of excess sludge is one of the problems in biological treatment methods. In the present invention, since the biological treatment tank and the wastewater treatment tank are separated, biological treatment can be performed while devoting to the generation and control of excess sludge.

  FIG. 7 shows a wastewater treatment system according to the present invention, which includes a magnetic activated carbon adsorption tank 10, a superconducting magnetic separation device 14, and a magnetic activated carbon biological regeneration tank 18. A sedimentation tank 12 may be provided between the adsorption tank 10 and the superconducting magnetic separation device 14 to precipitate and separate heavy objects.

  In the operation of the wastewater treatment system, first, in the adsorption tank 10, the dissolved organic matter in the wastewater is adsorbed on the magnetic activated carbon 36 that has been previously magnetized. Next, in the superconducting magnetic separator 14 capable of exerting a strong magnetic force under a high magnetic field with a high gradient, the magnetic activated carbon 36 adsorbing the organic matter is separated and recovered from the waste water. The treated wastewater is discharged or reused as recycled water. The magnetic activated carbon 36 separated and recovered by the superconducting magnetic separation device 14 is sent to the biological regeneration tank 18 of magnetic activated carbon, and the adsorbed organic matter is decomposed and regenerated by the organism. The regenerated magnetic activated carbon 36 ′ is reused in the adsorption tank 10.

  In the wastewater treatment system of the present invention, a pretreatment device may be provided in the front stage of the system in order to make the wastewater suitable for treatment in this system. For example, waste water from a dyeing factory may have a temperature of 60 to 70 ° C. and a turbidity (SS concentration) of 100 to 450 mg / l, but is preferably 40 ° C. or less and 50 mg / l or less by pretreatment. In the pretreatment device, for example, the temperature of the waste water can be lowered by a radiator or a heat exchanger, and suspended matter can be removed by, for example, a coagulating sedimentation tank to reduce turbidity. You may perform ozone treatment with a pre-processing apparatus.

  The activated carbon used in the adsorption tank 10 of magnetic activated carbon is activated carbon made magnetic, and can be manufactured by, for example, (i) imparting magnetism by the ferrite method, (ii) imparting magnetism by collision of magnetite and activated carbon, or the like.

  Conventionally, wastewater treatment with activated carbon has been performed through wastewater, for example, in a column packed with granular activated carbon. Granular activated carbon is used as a mainstream for wastewater treatment because it is not easily washed away and is easily regenerated by heating. On the other hand, powdered activated carbon has the advantages of a large surface area and extremely high adsorption ability of organic matter, but it is easily used with water, and when heated, the pores are blocked and loses its function as activated carbon. I did not come. In one embodiment of the present invention, the powdered activated carbon is magnetized, can be recovered by magnetic separation, and is regenerated at room temperature by microbial activity, so that the powdered activated carbon can be used efficiently. It was.

  In the magnetic activated carbon adsorption tank 10, magnetic activated carbon and waste water are brought into contact with each other to adsorb dissolved organic matter, so that it is desired to increase contact efficiency and adsorption efficiency. When powdered activated carbon is used, the adsorption efficiency is markedly higher than that of granular particles, and the contact efficiency can be increased by finely pulverizing the activated carbon and mixing the suspended aqueous solution into the wastewater with an ejector.

It is explanatory drawing which shows the outline of the continuous magnetic filter system by this invention. It is explanatory drawing which shows the structure which enlarges an external magnetic field in the continuous magnetic filter system by this invention. It is explanatory drawing which shows the structure of an example of the superconducting magnetic separation apparatus by this invention. It is explanatory drawing which shows the structure of another example of the superconducting magnetic separation apparatus by this invention, FIG. 4 (A) is the longitudinal cross-sectional view, FIG.4 (B) is a front view, FIG.4 (C) is FIG. It is expansion explanatory drawing of the broken-line part C in A). It is explanatory drawing which shows the outline of the biological regeneration tank of the magnetic activated carbon by this invention. It is explanatory drawing which shows the method of changing the time ratio of an aerobic condition and an anaerobic condition. It is explanatory drawing which shows the structure of the wastewater treatment system by this invention. It is explanatory drawing which shows the structure of the conventional wastewater treatment system. The measuring method (A) and the measurement result (B) of the adsorption rate of activated carbon with respect to a chlorinated compound (2-chlorophenol, 3-chlorophenol, 3,5-dichlorophenol, 2,4,6-trichlorophenol) are shown. The measurement result of the adsorption rate of activated carbon with respect to a chlorine-type compound (2-chlorophenol, 2,4,6-trichlorophenol) and the reproduction | regeneration rate by bacteria is shown.

Explanation of symbols

DESCRIPTION OF SYMBOLS 10 Adsorption tank of magnetic activated carbon 14 Superconducting magnetic separation device 18 Biological regeneration tank of magnetic activated carbon 20 Continuous magnetic filter system 22 Superconducting magnetic separation device 24 Conveyor type magnetic filter device 26 Superconducting magnet 28 Rotary filter belt 38 Water passage 50 Magnetic Belt 52 Activated carbon intake part 54 Activated carbon extraction part

Claims (9)

A magnetic separator using a superconducting magnet for wastewater treatment;
A rotating filter belt consisting of a mesh of magnetic wire, arranged at the front of the magnetic separation device and at least partially under the influence of the magnetic field of the superconducting magnet;
A continuous magnetic filter system comprising a removal unit that peels off a substance to be separated attached to a rotary filter belt.   2. The continuous magnetic filter according to claim 1, wherein an additional coil for increasing the magnetic field at the location of the rotary filter belt is provided in the vicinity of the end of the superconducting magnet excitation coil on the side where the rotary filter belt is provided. system.   3. The continuous magnetic filter system according to claim 1, wherein the magnetic separation device includes suction removal means for removing a substance to be separated attached to a wall surface of a waste water passage in the bore of the superconducting magnet by suction.   The magnetic separation device includes one or more magnetic filters provided with a plurality of suction holes in the bore of the superconducting magnet, and the periphery of the suction holes is made of a protruding magnetic material to create a high gradient magnetic field. The continuous connection according to claim 1, wherein the suction hole communicates with the suction removal pipe, and the separation target material adhering to the periphery of the suction hole and the suction hole is removed by suction through the suction removal pipe. Magnetic filter system. One or more tanks for storing water containing organisms that decompose organic matter in wastewater adsorbed on magnetic activated carbon;
Activated carbon intake part to take in and adhere magnetic activated carbon to be regenerated on the magnetic belt,
An activated carbon take-off section for separating and taking out the regenerated magnetic activated carbon from the magnetic belt;
A bioregenerative tank of magnetic activated carbon comprising a meandering and rotating magnetic belt that meanders up and down several times in the tank and moves in and out of the water surface stored in the tank.   The biological regeneration tank of magnetic activated carbon according to claim 5, wherein the ratio of the time during which the magnetic belt is in water and the time in which the magnetic belt is in the air can be changed by changing the relative water level in the tank with respect to the magnetic belt. An adsorption tank for adsorbing pollutants in wastewater on magnetic activated carbon;
At least one superconducting magnetic separator for magnetically separating magnetic activated carbon;
A wastewater treatment system comprising at least one biological regeneration tank according to claim 5 or 6,
A wastewater treatment system in which magnetic activated carbon separated and recovered by a superconducting magnetic separator is regenerated in a biological regeneration tank and reused in an adsorption tank.   The wastewater treatment system according to claim 7, wherein the superconducting magnetic separator is the continuous magnetic filter system according to any one of claims 1 to 4.   The wastewater treatment system according to claim 7 or 8, wherein the magnetic activated carbon is powdered magnetic activated carbon.