CN108409024A - A kind of biological adsorption strengthens Magneto separate sewage carbon source concentration recycling system and method - Google Patents

A kind of biological adsorption strengthens Magneto separate sewage carbon source concentration recycling system and method Download PDF

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CN108409024A
CN108409024A CN201710869031.4A CN201710869031A CN108409024A CN 108409024 A CN108409024 A CN 108409024A CN 201710869031 A CN201710869031 A CN 201710869031A CN 108409024 A CN108409024 A CN 108409024A
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magnetic
carbon source
sewage
concentration
coagulation
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王凯军
何秋杭
金正宇
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/48Treatment of water, waste water, or sewage with magnetic or electric fields
    • C02F1/488Treatment of water, waste water, or sewage with magnetic or electric fields for separation of magnetic materials, e.g. magnetic flocculation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/02Biological treatment
    • C02F11/04Anaerobic treatment; Production of methane by such processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/08Multistage treatments, e.g. repetition of the same process step under different conditions
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/12Activated sludge processes

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Water Treatment By Sorption (AREA)

Abstract

The present invention relates to biological adsorptions to strengthen Magneto separate sewage carbon source concentration recycling system and method, belong to water-treatment technology field, the system includes biological adsorption pond, magnetic-coagulation pond, magnetic separating device, magnetic powder recovering device, anaerobic reactor, and the pipeline for connecting each equipment.This method comprises the following steps:Activated sludge is added using biological adsorption pond, realizes effective trapping to dissolved organic matter.Access magnetic-coagulation pond later, adds magnetic kind and high-efficient coagulant aide, so that flco is combined and increases.It recycles the strong magnetic-adsorption of magnetic separating device with the flco that magnetic kind is " core ", realizes carbon source flco high efficient solid and liquid separation, magnetic floc sedimentation enters the realization magnetic kind recycling of magnetic kind recovery system after separation, and concentration carbon source enters anaerobic reactor and realizes the utilization of resources.Biological adsorption and Magneto separate are combined by the present invention, can be efficiently solved magnetic-coagulation carbon source concentration bottleneck problem with Adsorption of Dissolved organic matter, be realized efficient sewage carbon source concentration and recycling.

Description

A kind of biological adsorption strengthens Magneto separate sewage carbon source concentration recycling system and method
Technical field
The invention belongs to water-treatment technology fields, and in particular to a kind of biological adsorption reinforcing Magneto separate sewage carbon source concentration money Source system and method.
Background technology
Under conservation culture theory, changes traditional wastewater processing high energy consumption, high resource consumption disadvantage, sewage is pushed to provide comprehensively Source, the provider that sewage plant is changed into resource and the energy is the important development direction of sewage disposal from now on, with high-efficiency low-carbon, The mode development of high-level recycling is the important channel for realizing Sustainable Water Resources Development target using municipal sewage.Wherein one A important model is the new way sewage recycling tupe using anaerobism as core.However it is dense to be limited to China's organic matter of sewage Spend relatively low, municipal sewage anaerobic pathway resource technology advantage is difficult to play, therefore the efficient pre-concentration in front end of sewage carbon source is Realize the key of carbon source anaerobic pathway high efficient energy sources.
However there are the higher problems of less efficient, cost for current carbon source concentration technique.For the technical problem, this project By coupled biological absorption and super magnetic separation technique, biological adsorption process is acted on and surpassed to effective trapping of dissolved organic matter The separation of solid and liquid characteristic of magnetic separation technique high-efficiency low-carbon is organically combined, to realize the advantage of biochemical route and materialization approach Complementation, and then the contradictory problems of thickening efficiency and concentrated cost in carbon source concentration are solved, research and development more meet sustainable development idea Novel sewage treatment technology, for municipal sewage energy stream high efficient resourcing productivity verification theoretical foundation and technology branch are provided Support.
Include both at home and abroad at present mainly biosorption process, chemical strengthening coagulation method, object using the means of sewage pre-concentration Change reinforcement.Biosorption process be by biology flocculation and adsorption function to realize the enrichment of organic matter, in AB techniques A sections, using under short sludge age microorganism flco suction-operated enrichment sewage in organic matter, then pass through intermediate sedimentation pond Concentration carbon source is obtained in a manner of sludge settling.But biological adsorption technique is due to the presence in intermediate sedimentation pond so that it still has Larger occupation of land, and rejection to organics limited efficacy.Chemical strengthening coagulation method is to make dirt by dosing coagulant and flocculation aid Particulate form and colloidal organic substrate in water are enriched with, but the method has that medicine consumption is high, dissolved organic matter is difficult to be enriched with Disadvantage.Materialization reinforcement includes that high efficient separation technologies, the wherein UF membranes such as UF membrane and Magneto separate are less than using film characteristic aperture Substance to be retained and realize Selective Separation concentrate, but the membrane pollution problem of UF membrane make its processing cost become major limitation Factor;Magneto separate is nucleated to form magnetic floc sedimentation using magnetic kind, strengthens gravity and precipitates separative efficiency, but the enrichment of dissolved organic matter And solid-liquid separation efficiency still has greater room for improvement.Meanwhile the high occupation of land of traditional wastewater factory keeps away problem with neighbour, is provided to soil It is more prominent in source, the higher city of environmental quality requirement, therefore there is an urgent need for the research and development for the sewage disposal technology that efficiently saves land and applications. Therefore efficient land-saving town sewage carbon source concentration technique is the research hotspot of current focus.
Invention content
The purpose of the present invention is to make up that carbon source concentrates that mesophytization approach is less efficient and materialization approach cost is higher asks The needs of high-efficiency low-carbon sewage recycling processing research and development is inscribed and met, it is dense to provide a kind of biological adsorption reinforcing Magneto separate sewage carbon source Contracting recycling system and method, by coupled biological absorption and magnetic separation technique, by biological adsorption process to dissolved organic matter Effective trapping effect and the separation of solid and liquid characteristic of magnetic separation technique high-efficiency low-carbon organically combined, realize biochemical route and object The mutual supplement with each other's advantages of change approach, in conjunction with anaerobic digestion means, research and development more meet the Novel sewage treatment technology of sustainable development idea.
In order to achieve the above object, technical solution provided by the invention is as follows:
A kind of biological adsorption proposed by the present invention strengthens Magneto separate sewage carbon source concentration recycling system and method, dirty for cities and towns Water efficient low-consume recycling treatment, it is characterised in that:
Sewage enters biological adsorption pond and is quickly mixed and reacted with activated sludge, is generated using activated sludge surface extracellular Polymer(EPS)Adsorptivity and flocculability, the organic matter in sewage is effectively enriched with, particulate form in water, colloidal attitude are made Organic pollution and dissolved organic matter can be able to aggregation and form the flocculu shape for being easy to be separated by solid-liquid separation.
Sewage mixed liquor flows into magnetic-coagulation pond later, avoids magnetic kind from efficiently helping using differentiation dosing method is spatially separating It is also easy to produce magnetic kind rendezvous problem under the conditions of solidifying agent.It adds magnetic kind and high-efficient coagulant aide and is mixing slowly lower formation enhanced flocculation, make Biological floe improves floc sedimentation binding force and compactness further combined with increasing and form the magnetic floc sedimentation using magnetic as core, promotees The convenience of carbon source recycling is concentrated after into separation of solid and liquid.
Sewage mixed liquor flows into magnetic separation system, and magnetic separating device is by strong magnetic force rare-earth magnetic disc and the iron-clad for being coated at disk It forming, there is strong magnetic force not have magnetic force that magnetic floc sedimentation is made to be desorbed for adsorbing magnetic floc sedimentation, 1/4 position at 3/4 position in disk, There is collecting tank to collect magnetic floc sedimentation below.The high-intensity magnetic generated using strong magnetic force rare-earth magnetic disc, magnetic flco in water is fast Speed is adsorbed onto on iron-clad, and the magnetic carbon source floc sedimentation being attracted on iron-clad takes the water surface out of with device main axis, when going to magnetic In disk 1/4 not the position of magnetic force when, magnetic floc sedimentation desorption falls into magnetic floc sedimentation collecting tank, then through helix transporting device, in turn It is transported to next unit, to realize the quick separating of magnetic carbon source floc sedimentation and water, has reached the efficient concentration of carbon source in sewage And separation.
Magnetic carbon source floc sedimentation enters magnetic kind recovery system, and Magneto separate magnetic roller is flowed through after being broken up by high speed dispersor, utilizes The high-intensity magnetic field power of magnetic roller screens magnetic kind, to realize that magnetic kind separates and recovers.The magnetic kind sifted out inflow magnetic kind dosing is stirred Case is mixed, then realizes that magnetic kind recycles by magnetic kind throwing device, the concentration carbon source of discharge carries out subsequent Anaerobic Digestion.
The concentration carbon source that above system generates enters CSTR or UASB anaerobic reactors and carries out producing methane through anaerobic fermentation, due to Concentration process hydraulic detention time is extremely short, and inhibits aerobic microbiological process as possible, and takes biological adsorption mode to molten Solution property organic matter is targetedly enriched with, therefore the mineralising of town sewage carbon source can effectively be inhibited to be lost in, and as far as possible More organic carbon sources by various forms in waste water are enriched with, and are realized in concentrate to greatest extent collect carbon source Anaerobic pathway is recycled, and improves the ratio of recyclable carbon source.And since this method is using two kinds of enrichments of absorption and coagulation Means, carbon source do not enter in microbial body, therefore it is possible to prevente effectively from the breaking-wall cell that concentration carbon source anaerobic digestion is encountered is asked Topic, to improve anaerobic gas generation.The biogas of acquisition provides the energy and heat source that system runs well by cogeneration of heat and power in situ.
The first step is that sewage enters biological adsorption pond and quickly mixed and reacted with activated sludge, biological adsorption Hydraulic detention time is 10-30 min in system, and sludge loading reaches 4.0-6.0 kgBOD5/ kgMLSSd, dissolved oxygen 0.5- 1.5 mg/L.In this step, the extracellular polymeric generated using activated sludge surface(EPS)Adsorptivity and flocculability, will Organic matter in sewage is effectively enriched with, and particulate form in water, colloidal attitude organic pollution and dissolved organic matter are enable It is able to aggregation and forms the flocculu shape for being easy to be separated by solid-liquid separation.Biological adsorption method so that dissolved organic matter enters EPS in sewage Adsorbent can be further reduced the content of organics in liquid, and increase the carbon source total amount of separable concentration, be conducive to maximum Change the carbon source recycling realized and completed using anaerobic technology, the means by increasing product output realize the low consumption target of this method.
The second step is that the sewage mixed liquor of biological adsorption system outflow enters magnetic-coagulation system, using being spatially separating Differentiation dosing method adds magnetic kind and high-efficient coagulant aide, so that magnetic kind and high-efficient coagulant aide more uniformly participate in coagulating, Magnetic kind is avoided to be reunited together by high-efficient coagulant aide, without effectively being collided with small flco in sewage, formation contains The magnetic floc sedimentation and high-efficient coagulant aide of " magnetic " core shift to an earlier date consumption problem.Magnetic kind adds 1-1.5 times of a concentration of SS concentration. High-efficient coagulant aide adds a concentration of 30-50 μ g/L, and the hydraulic detention time of magnetic-coagulation agitator tank is 3.5 min, and agitating paddle turns Speed is 70 r/min.In this step, it is wadded a quilt with cotton in the secondary reinforcement for mixing slowly lower formation by adding magnetic kind and high-efficient coagulant aide It is solidifying, make biological floe further combined with increasing and form the magnetic floc sedimentation using magnetic as core, and improve floc sedimentation binding force and closely knit Degree promotes the convenience of concentration carbon source recycling after being separated by solid-liquid separation.
The third step is that the sewage mixed liquor for obtaining the second step is sent into magnetic separation system progress Magneto separate, Magnetic separating device is made of strong magnetic force rare-earth magnetic disc with the iron-clad for being coated at disk, and there is strong magnetic force to be used at 3/4 position in disk The magnetic floc sedimentation of absorption, 1/4 position do not have magnetic force that magnetic floc sedimentation is made to be desorbed, and have collecting tank to collect magnetic floc sedimentation thereunder.It utilizes The high-intensity magnetic that strong magnetic force rare-earth magnetic disc generates on magnetic flco quick adsorption to iron-clad, will be attracted on iron-clad in water Magnetic carbon source floc sedimentation takes the water surface out of with device main axis, when going to the 1/4 not position of magnetic force in disk, magnetic floc sedimentation Desorption falls into magnetic floc sedimentation collecting tank, then through helix transporting device, and then is transported to next unit, to realize magnetic carbon source wadding The quick separating of group and water, has reached the efficient concentration of carbon source and separation in sewage.Iron-clad is adjusted by observing water outlet status Rotating speed increases the time of contact of flow and iron-clad if then should suitably reduce iron-clad rotating speed containing flco in water outlet.Technique can be with Realize the rate of recovery of COD about 70% in town sewage raw water, 90% or more TP removals, 90% or more SS removals, COD in water outlet, TP, SS index can reach national sewage discharge level-one B standard.
The four steps is that the magnetic carbon source floc sedimentation that will be generated in the third step is discharged into magnetic kind recovery system, is passed through High speed dispersor flows through Magneto separate magnetic roller after breaing up, screened magnetic kind using the high-intensity magnetic field power of magnetic roller, to realize magnetic kind Separation and recovery.The magnetic kind sifted out is flowed into magnetic kind dosing agitator tank, then realizes that magnetic kind recycles by magnetic kind throwing device, discharge Concentration carbon source carry out subsequent Anaerobic Digestion.
5th step be the concentration carbon source for generating the four steps be sent into CSTR or UASB anaerobic reactors into Row Anaerobic Digestion since concentration process hydraulic detention time is extremely short, and inhibits aerobic microbiological process as possible, and takes Biological adsorption mode is targetedly enriched with dissolved organic matter, therefore can effectively inhibit town sewage carbon source Mineralising is lost in, and the organic carbon source as much as possible by various forms in waste water is enriched with, to greatest extent receive carbon source Collection realizes that anaerobic pathway is recycled in concentrate, improves the ratio of recyclable carbon source.And since this method uses Absorption and two kinds of enrichment means of coagulation, carbon source do not enter in microbial body, therefore it is possible to prevente effectively from concentration carbon source anaerobic digestion The breaking-wall cell problem encountered, to improve anaerobic gas generation.The biogas of acquisition is normal by cogeneration of heat and power in situ offer system The energy and heat source of operating.
Compared with prior art, the invention has the characteristics that and advantageous effect:
This method develops biochemical route coupling materialization approach and realizes the technique respectively having complementary advantages, and will be directed to enrichment dissolubility has The biological adsorption process of machine object is combined with the magnetic separation technique for rapidly and efficiently detaching pimpled rubber figure's organic matter, by using cheap The activated sludge absorption that is easy to get dissolved organic matter, combined magnetic field effect realize that muddy water rapidly and efficiently detaches, it is dense to solve existing carbon source The contradictory problems of low-carbon high-efficiency in contracting technique reach wastewater efficient low consumption pre-concentration purpose, realize that municipal sewage energy stream is efficient Recycling.
Magnetic kind is added in coagulation system, is formed containing " magnetic " core to make floc sedimentation band be magnetic, therefore magnetic can be utilized Field force is quickly separated by solid-liquid separation, and traditional " biological adsorption-precipitation " is become " magnetic biological adsorption-magnetic disc separation ", is contracted significantly It the short separation of solid and liquid time, improves treatment effeciency, while magnetic disc separation systematic substitution secondary settling tank, greatly reduces equipment occupation of land Area, and the magnetic kind added is recyclable, to realize low-coumption sewage recycling processing system jointly.
Magnetic separating device in magnetic kind recovery system is made of strong magnetic force rare-earth magnetic disc with the iron-clad for being coated at disk, is avoided The sludge residual and equipment loss problem that traditional " disk-scraping article " form generates so that water outlet water stabilization, and do not have to Regular replacement scraping article saves operating cost.
This method organic carbon source as much as possible by various forms in waste water is enriched with, to greatest extent by carbon source It collects in concentrate.Since hydraulic detention time is short, thus in sewage most of organic matter do not occur notable mineralising and into Enter concentrate, improves the ratio of recyclable carbon source.And since this method is using absorption and two kinds of enrichment means of coagulation, carbon source It does not enter in microbial body, therefore it is possible to prevente effectively from the breaking-wall cell problem that carbon source anaerobic digestion is encountered is concentrated, to carry The efficiency of high organic matter of sewage anaerobism production capacity.This method whole process, which realizes sewage, to turn waste into wealth, and obtains product, both uses in this way Water content of organics reaches discharge standard, and organic matter and nutriment in sewage is enable to be able to recycling.
This method is cheap practical, advanced, and flow is simple, takes up an area few, non-secondary pollution, and operation is easy, reliable, has apparent Environmental benefit, Social benefit and economic benefit.
It is described further below in conjunction with the accompanying drawings.
Description of the drawings
Fig. 1 is the flow signal that biological adsorption of the present invention strengthens Magneto separate sewage carbon source concentration recycling system and method Figure;
Fig. 2 is the structural schematic diagram for being spatially separating differentiation dosing method of the embodiment of the present invention.
Specific implementation mode
A kind of biological adsorption proposed by the present invention strengthens Magneto separate sewage carbon source concentration recycling system and method, such as Fig. 1 Shown, which includes biological adsorption pond, magnetic-coagulation pond, magnetic separating device, magnetic powder recovering device, anaerobic reaction Device, and the pipeline for connecting each equipment, connection relation be:Biological adsorption pond and magnetic-coagulation pond share a wall, on partition board Side's opening supplies water, and stream enters magnetic-coagulation pond, magnetic-coagulation pond is connected with magnetic separating device by pipeline, magnetic separating device one end is direct Water outlet, the sludge outlet for being located at the bypass of its device are connected with the sludge import of magnetic powder recovering device, and magnetic powder recovering device sludge goes out Mouth is connected with anaerobic reactor.
Included the following steps using the method for treating water of the system:
1)Sewage enters biological adsorption pond and is quickly mixed and reacted with activated sludge, in biological adsorption system when hydraulic retention Between be 10-30 min, sludge loading reach 4.0-6.0 kgBOD5/ kgMLSS d, dissolved oxygen are 0.5-1.5 mg/L.In this step In, utilize the extracellular polymeric of activated sludge surface generation(EPS)Adsorptivity and flocculability, by sewage organic matter carry out Effectively enrichment enables particulate form in water, colloidal attitude organic pollution and dissolved organic matter to be able to aggregation formation and is easy to solid The flocculu shape of liquid separation.
2)The sewage mixed liquor of biological adsorption system outflow enters magnetic-coagulation system, using being spatially separating the differentiation side of adding Formula adds magnetic kind and high-efficient coagulant aide, it is made effectively to be collided with small flco in sewage, forms the magnetic containing " magnetic " core Property floc sedimentation.Magnetic kind adds 1-1.5 times of a concentration of SS concentration.High-efficient coagulant aide adds a concentration of 30-50 μ g/L, and magnetic-coagulation stirs The hydraulic detention time for mixing case is 3.5 min, and rotating speed of agitator is 70 r/min.
3)The sewage mixed liquor that second step is obtained is sent into magnetic separation system and carries out Magneto separate, utilizes strong magnetic force Rare-Earth Magnetic The high-intensity magnetic that disk generates on magnetic flco quick adsorption to iron-clad, will be fallen into water in disk desorption area's magnetism floc sedimentation desorption Magnetic floc sedimentation collecting tank realizes the quick separating of magnetic carbon source floc sedimentation and water, has reached the efficient concentration of carbon source in sewage and has divided From.
4)The magnetic carbon source floc sedimentation generated in third step is discharged into magnetic kind recovery system, after being broken up by high speed dispersor Magneto separate magnetic roller is flowed through, is screened magnetic kind using the high-intensity magnetic field power of magnetic roller, to realize that magnetic kind separates and recovers.By what is sifted out Magnetic kind flows into magnetic kind dosing agitator tank, then realizes that magnetic kind recycles by magnetic kind throwing device, after the concentration carbon source progress of discharge Continuous Anaerobic Digestion.
5)The concentration carbon source that four steps is generated is sent into CSTR or UASB anaerobic reactors and carries out Anaerobic Digestion, obtains The biogas obtained passes through cogeneration of heat and power in situ and provides the energy and heat source that system runs well.Embodiment is enumerated below to give further Explanation.
The embodiment of the present invention is further illustrated with reference to Fig. 1 and Fig. 2.
Embodiment
Sewage after certain urban wastewater treatment firm fine fack, COD are that 186-394 mg/L, pH 7.21-7.44, TP are 5.37-7.79 a concentration of 86-107 g/L of mg/L, solid suspension SS.
This experiment use operating mode for:Magnetic kind adds 1 times of a concentration of SS concentration, and high-efficient coagulant aide adds a concentration of 30 μ G/L, sludge loading are 5 gCOD/g MLSS d, and rotating speed of agitator is 70 r/min.Test result show that biological adsorption strengthens magnetic It is about 70% to detach COD removal rates.As it can be seen that maximum compared to COD removal rates in common biological adsorption 2-2.5 h processing times 60%, biological adsorption strengthens super Magneto separate sewage carbon source concentration technology larger advantage in terms of carbon source concentrated effect.

Claims (10)

1. a kind of biological adsorption strengthens Magneto separate sewage carbon source concentration recycling system and method, for the sustainable of town sewage Recycling treatment, it is characterised in that:The sewage disposal system includes biological adsorption pond, magnetic-coagulation pond, magnetic separating device, magnetic powder time Receiving apparatus, anaerobic reactor, and the pipeline for connecting each equipment, connection relation be:Biological adsorption pond and magnetic-coagulation pond A wall is shared, partition board upper opening supplies water, and stream is connected with magnetic separating device by pipeline into magnetic-coagulation pond, magnetic-coagulation pond, magnetic divides It is directly discharged from device one end, the sludge outlet for being located at the bypass of its device is connected with the sludge import of magnetic powder recovering device, magnetic powder Retracting device sludge outlet is connected with anaerobic reactor.
2. biological adsorption as described in claim 1 strengthens Magneto separate sewage carbon source concentration recycling system and method, feature It is, activated sludge throwing device is provided in the biological adsorption pond.
3. biological adsorption as described in claim 1 strengthens Magneto separate sewage carbon source concentration recycling system and method, feature It is, this approach includes the following steps:
1)By activated sludge input biological adsorption pond, realizes effective trapping to dissolved organic matter, form small floc sedimentation; 2) Then composite waste enters magnetic-coagulation pond, by adding magnetic kind and high-efficient coagulant aide, particulate form and colloidal attitude in sewage is made to have Machine object is condensed into the suspended matter mixture using magnetic kind as " core ", effect of the carbon source mixture in high-efficient coagulant aide with small floc sedimentation Under further combined with increasing and improve floc sedimentation binding force and compactness;3)Magnetic floc sedimentation mixed liquor enters magnetic separating device, utilizes The strong magnetic-adsorption of magnetic separating device highfield permanent magnet disk acts on, and realizes carbon source flco high efficient solid and liquid separation;4)Magnetism wadding Group enters magnetic kind recovery system, breaks up floc sedimentation through high speed dispersor, recycles magnetic roller to sift out magnetic kind and realizes the recycling of magnetic kind, then leads to It crosses magnetic kind throwing device and realizes that magnetic powder utilizes;5)Sewage coagulation concentration carbon source enters anaerobic reactor and carries out Anaerobic Digestion, To realize carbon source recycling.
4. method as claimed in claim 3, it is characterised in that Magneto separate system makes this method hydraulic detention time extremely short, has Effect inhibits aerobic microbiological process, can effectively inhibit town sewage carbon source carbon caused by bacteria metabolism activity The mineralising in source is lost in, and realizes that anaerobic pathway is recycled in concentrate to greatest extent collect carbon source, improving can Recycle the ratio of carbon source.
5. method as claimed in claim 3, it is characterised in that biological adsorption and magnetic-coagulation are combined by this method, outstanding realizing The aggregation of floating particles state organic matter also realizes dissolved organic matter Adsorption while efficiently separating, and efficiently solves common magnetic Coagulation carbon source concentration dissolved organic matter is difficult to the bottleneck problem being enriched with, and since this method is using absorption and two kinds of richnesses of coagulation Collection means, carbon source do not enter in microbial body, therefore it is possible to prevente effectively from the breaking-wall cell that concentration carbon source anaerobic digestion is encountered Problem, to realize efficient sewage carbon source concentration and recycling.
6. method as claimed in claim 3, it is characterised in that:Hydraulic detention time is 10- in the biological adsorption system 30 min, sludge loading is up to 4.0-6.0 kgBOD5/ kgMLSSd, dissolved oxygen are 0.5-1.5 mg/L.
7. method as claimed in claim 3, it is characterised in that add high-efficient coagulant aide for replacing common coagulants and helping solidifying Agent, such as nano flocculant, because it has many advantages, such as large specific surface area, can be high than table so that dosage is small and flocculating effect is notable.
8. method as claimed in claim 3, it is characterised in that:The step 2)In magnetic kind and high-efficient coagulant aide toss area exist Spatially detached, avoid magnetic kind by high-efficient coagulant aide reunite together, without effectively with small wadding in sewage Body is collided, and the magnetic floc sedimentation containing " magnetic " core is formed, and magnetic kind adds 1-1.5 times of a concentration of SS concentration, high-efficient coagulant aide Add a concentration of 30-50 μ g/L, the hydraulic detention time of magnetic-coagulation agitator tank is 3.5 min.
9. method as claimed in claim 3, it is characterised in that:The step 3)In magnetic separating device by strong magnetic force Rare-Earth Magnetic Disk and the iron-clad for being coated at disk form, and 3/4 position has strong magnetic force for adsorbing magnetic floc sedimentation in disk, and 1/4 position does not have Magnetic force makes magnetic floc sedimentation be desorbed, and has collecting tank to collect magnetic floc sedimentation thereunder.
10. method as claimed in claim 3, it is characterised in that:The step 5)In sewage coagulation concentration carbon source use CSTR or UASB reactors carry out Anaerobic Digestion, on the basis of realizing that substantially saving processing unit takes up an area, to greatest extent Carbon source is collected and carries out anaerobic pathway recovery processing in concentrate, the biogas of acquisition is providing system just by cogeneration of heat and power in situ The energy and heat source often operated.
CN201710869031.4A 2017-09-22 2017-09-22 A kind of biological adsorption strengthens Magneto separate sewage carbon source concentration recycling system and method Pending CN108409024A (en)

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CN109896712A (en) * 2019-04-09 2019-06-18 黑龙江省福林环保科技有限公司 A kind of sewerage integrated treatment process of Green Hospital
CN110467312A (en) * 2019-08-12 2019-11-19 安徽环境科技集团股份有限公司 A kind of recycling treatment process of white carbon black industrial wastewater
CN110627329A (en) * 2019-11-12 2019-12-31 中央民族大学 Carbon source concentration and recycling method for urban domestic sewage
CN113443720A (en) * 2021-07-23 2021-09-28 苏州金螳螂园林绿化景观有限公司 Magnetic suction purification method for landscape closed enclosure water system
CN113636641A (en) * 2021-08-27 2021-11-12 南开大学深圳研究院 Carbon dioxide emission reduction sewage treatment method for converting high carbon source into activated sludge and biomass coupled carbon sequestration to prepare soil conditioner
CN114873819A (en) * 2022-05-27 2022-08-09 安徽理工大学环境友好材料与职业健康研究院(芜湖) Multi-pollutant sewage magnetic treatment system

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