JP2007132730A - Pyrheliometer having photo catalyst layer - Google Patents

Pyrheliometer having photo catalyst layer Download PDF

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JP2007132730A
JP2007132730A JP2005324450A JP2005324450A JP2007132730A JP 2007132730 A JP2007132730 A JP 2007132730A JP 2005324450 A JP2005324450 A JP 2005324450A JP 2005324450 A JP2005324450 A JP 2005324450A JP 2007132730 A JP2007132730 A JP 2007132730A
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pyranometer
sensor
substrate
present
glass dome
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Juichi Hasegawa
壽一 長谷川
Tadashi Kato
加藤  正
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Eko Instruments Trading Co Ltd
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Eko Instruments Trading Co Ltd
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<P>PROBLEM TO BE SOLVED: To provide a pyrheliometer that is less likely to have observation errors generated, even if the pyrheliometer is installed in an outdoor space, or the like over a long term, and that reduces the number of maintenance times. <P>SOLUTION: The pyrheliometer comprises a substrate, a sensor arranged on the substrate, a diffusion plate arranged on the sensor, and a glass dome that is positioned on the diffusion plate and covers the substrate, the sensor, and the diffusion plate. In this case, a photocatalyst, which is hydrophilized according to photoexcitation, is provided on the surface of the glass dome. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は、ガラスドームを備える改良型日射計に係り、より詳細には、前記ガラスドーム上に光触媒層を設けた日射計に関する。   The present invention relates to an improved pyranometer having a glass dome, and more particularly to a pyranometer having a photocatalytic layer provided on the glass dome.

日射計は、その上部に備えるガラスドームを通過した太陽光線が受感部に入射し、その熱エネルギーが電圧に変換される計測器である。この日射計は、太陽光分布とセンサーの分光特性とが整合しない場合には、特に、熱型センサーを利用した場合には、分光誤差や観測誤差が非常に大きくなることが知られている。   The pyranometer is a measuring instrument in which sunlight rays that have passed through a glass dome provided on the top thereof are incident on the sensing part and the thermal energy is converted into a voltage. This pyranometer is known to have very large spectral and observation errors when the solar light distribution and the spectral characteristics of the sensor do not match, particularly when a thermal sensor is used.

分光誤差を解消する目的で、熱型センサーではなく、少なくとも2つの量子型センサーであって、感光波長域が異なるセンサーを利用した日射計が開示されている(例えば、特許文献1参照)。   For the purpose of eliminating spectral errors, a pyranometer using at least two quantum sensors instead of a thermal sensor and having different photosensitive wavelength ranges is disclosed (for example, see Patent Document 1).

しかしながら、日射計は、しばしば、屋外に設置されて観測に多用されている。そのため、常に、雨風に晒され、ガラスドームの表面には汚れが沈着する。この場合、ガラスドームの光透過率が減少し、日射計の感度低下が生じるため、少なくとも2つの量子型センサーを利用しただけでは、日射計の観測誤差の問題を解消することは困難である。   However, pyranometers are often installed outdoors and are often used for observation. Therefore, it is always exposed to rain and wind, and dirt is deposited on the surface of the glass dome. In this case, since the light transmittance of the glass dome is reduced and the sensitivity of the pyranometer is reduced, it is difficult to solve the observation error problem of the pyranometer only by using at least two quantum sensors.

また、気象観測装置に用いられる日射計は、山やビルの屋上など、メンテナンスの難しい場所に設置されることが多い。さらに、観測の自動化や無人化が進展し、日射計のメンテナンスを回数を減らすことが求められている。
特開2002−54627号
In addition, pyranometers used in weather observation devices are often installed in places where maintenance is difficult, such as mountains and rooftops of buildings. In addition, automation and unmanned observations have progressed, and it is required to reduce the number of maintenance of the pyranometer.
JP 2002-54627 A

本発明の課題は、長期間屋外等にて設置しても観測誤差が生じにくい、かつ、メンテナンス回数を減らした日射計を提供することである。   An object of the present invention is to provide a pyranometer that is less likely to cause observation errors even when installed outdoors for a long period of time and that has a reduced number of maintenance.

そこで、本発明者らは、観測誤差が発生しにくい日射計を鋭意検討したところ、日射計が有するガラスドーム上に光触媒層を設けることにより、上記課題を解決するこができるという知見を得て、本発明を完成するに至った。   Therefore, the present inventors diligently studied a pyranometer that is unlikely to cause an observation error, and obtained the knowledge that the above problem can be solved by providing a photocatalyst layer on the glass dome of the pyranometer. The present invention has been completed.

すなわち、本発明では、基板と、前記基板上に配設したセンサーと、前記センサー上に配設した拡散板と、前記拡散板の上に位置し、前記基板、前記センサーおよび前記拡散板を覆うガラスドームと、を備える日射計であって、前記ガラスドームの表面に、つまり、外界と接する表面に、光励起に応じて親水化する光触媒層を設けることを特徴とする、日射計を提供する。   That is, in the present invention, the substrate, the sensor disposed on the substrate, the diffusion plate disposed on the sensor, and the diffusion plate are located on the substrate, covering the substrate, the sensor, and the diffusion plate. A solar radiation meter comprising a glass dome, wherein a photocatalytic layer that becomes hydrophilic in response to photoexcitation is provided on a surface of the glass dome, that is, a surface in contact with the outside.

かかる構成によれば、日射計ガラスドームに付着した汚れが、光触媒の作用によって分解され、その後、雨や風等によって流されるため、日射計の感度低下は発生しにくくなる。   According to such a configuration, the dirt attached to the pyranometer glass dome is decomposed by the action of the photocatalyst, and is then washed away by rain, wind, or the like, so that the sensitivity of the pyranometer is less likely to occur.

本発明に係る日射計の好ましい態様では、前記光触媒層は、TiO2、ZnO、SrTiO3、WO3、Bi23、Fe23、SnO2およびSiO2からなる群から選択される親水性材料を含む。 In a preferred embodiment of the solar radiation meter according to the present invention, the photocatalyst layer is hydrophilic selected from the group consisting of TiO 2 , ZnO, SrTiO 3 , WO 3 , Bi 2 O 3 , Fe 2 O 3 , SnO 2 and SiO 2. Contains sexual materials.

このような光触媒層を利用することにより、ガラスドームの表面に付着した汚れの分解を促進することが可能となる。   By using such a photocatalyst layer, it becomes possible to accelerate the decomposition of dirt adhering to the surface of the glass dome.

本発明に係る日射計の好ましい態様では、前記日射計は、分光日射計、紫外放射計、赤外放射計、シリコンドームを使用した赤外放射計、回転式日照計、直達日射計、太陽電池式日射計、放射収支計、ラディエーションシールド付温湿度計からなる群から選択される。   In a preferred embodiment of the solar radiation meter according to the present invention, the solar radiation meter is a spectroscopic solar radiation meter, an ultraviolet radiometer, an infrared radiometer, an infrared radiometer using a silicon dome, a rotary solarimeter, a direct solar radiation meter, or a solar cell. It is selected from the group consisting of a solar radiation meter, a radiation balance meter, and a temperature and humidity meter with a radiation shield.

本発明によれば、屋外に長期間設置しても、観測誤差の少ない日射計が提供される。また、本発明によれば、無人の観測場所に設置した日射計のメンテナンス回数を低下させることもできる。   ADVANTAGE OF THE INVENTION According to this invention, even if it installs outdoors for a long period of time, the pyranometer with few observation errors is provided. Moreover, according to this invention, the frequency | count of a maintenance of the pyranometer installed in the unmanned observation place can also be reduced.

本発明の実施の形態について、図面を参照しつつ説明する。以下の実施形態は、本発明を説明するための例示であり、本発明をこの実施形態にのみ限定する趣旨ではない。本発明は、その要旨を逸脱しない限り、さまざまな形態で実施することができる。   Embodiments of the present invention will be described with reference to the drawings. The following embodiment is an example for explaining the present invention, and is not intended to limit the present invention only to this embodiment. The present invention can be implemented in various forms without departing from the gist thereof.

図1は、本発明の一の実施態様における日射計の概略断面図を示す。図1に示すように、本発明に係る日射計10は、基板20と、その基板20上に配設されたセンサー30と、そのセンサー30の上に配設されたフィルター40と、そのフィルター40の上に配設された拡散板50と、前記基板20、前記センサー30、前記フィルター40および前記拡散板50を覆うように配設されたガラスドーム60と、そのガラスドームの表面に設けられた光触媒層70と、を備える。   FIG. 1 shows a schematic cross-sectional view of a pyranometer in one embodiment of the present invention. As shown in FIG. 1, the pyranometer 10 according to the present invention includes a substrate 20, a sensor 30 disposed on the substrate 20, a filter 40 disposed on the sensor 30, and the filter 40. A diffusion plate 50 disposed on the glass dome, a glass dome 60 disposed so as to cover the substrate 20, the sensor 30, the filter 40, and the diffusion plate 50, and a surface of the glass dome. A photocatalyst layer 70.

本発明に用いる基板10は、その材質は特に限定されないが、熱による変形等が発生しないガラスやプラスチック等から構成されることが好ましい。   The material of the substrate 10 used in the present invention is not particularly limited, but is preferably composed of glass, plastic, or the like that does not generate deformation due to heat.

本発明に用いるセンサー30は、熱形センサーや、シリコン(Si)センサー、InGaAsやGaAsPなどの量子型センサー等が挙げられる。特に、センサーとしては、光電子素子であり、経時変化が少なく、かつ、電気信号への変換効率の高い量子型のSiダイオードが適する。また、必要に応じて、フィルター40を介して感光波長を選択することもできる。本発明に用いるフィルター40の具体例としては、カットオフフィルターまたは透過する波長範囲を限定するフィルター等が挙げられる。   Examples of the sensor 30 used in the present invention include a thermal sensor, a silicon (Si) sensor, and a quantum type sensor such as InGaAs or GaAsP. In particular, as a sensor, a quantum Si diode that is an optoelectronic element, has little change with time, and has high conversion efficiency into an electric signal is suitable. Further, if necessary, the photosensitive wavelength can be selected via the filter 40. Specific examples of the filter 40 used in the present invention include a cut-off filter or a filter that limits a transmitted wavelength range.

本発明に用いる拡散板50は、太陽光等の光を受光する受光面である。この拡散板の存在により、方位特性(斜入射角特性)を満足させる構造となっている。本発明に用いる拡散板50の材質としては、本発明に係る日射計10としての角度特性を満足させるものであれば特に限定されないが、テフロン(登録商標)製であることが好ましい。   The diffusion plate 50 used in the present invention is a light receiving surface that receives light such as sunlight. Due to the presence of the diffusion plate, the structure satisfies the azimuth characteristics (oblique incident angle characteristics). The material of the diffusing plate 50 used in the present invention is not particularly limited as long as it satisfies the angle characteristics of the pyranometer 10 according to the present invention, but is preferably made of Teflon (registered trademark).

本発明に用いるガラスドーム60は、その表面に、光励起に応じて親水化する光触媒層を設ける。このように、親水化した表面では、付着した汚れは、雨などにより流されて、ガラスドーム60の表面が洗浄されることになる。そのため、長期間屋外に、本発明に係る日射計を設置しても、泥、砂や有機物によりガラスドームの表面が汚れても、ガラスドームに設けられた、光励起に応じて親水化しり光触媒層の作用により、ガラスドーム上の汚れが分解されたり、汚れ自体が流されたりする。   The glass dome 60 used in the present invention is provided on its surface with a photocatalytic layer that becomes hydrophilic in response to photoexcitation. In this way, on the hydrophilic surface, the adhered dirt is washed away by rain or the like, and the surface of the glass dome 60 is cleaned. Therefore, even if the pyrometer according to the present invention is installed outdoors for a long period of time, even if the surface of the glass dome is soiled by mud, sand, or organic matter, the photocatalyst layer is made hydrophilic according to photoexcitation and provided on the glass dome. As a result, the dirt on the glass dome is decomposed or the dirt itself is washed away.

本発明において、必要とされる親水性の程度は、雨などにより供給された水が濡れ拡がる程度であり、概して、接触角(水滴の端部接触角)が10°以下、好ましくは5°以下、より好ましくは3°以下である。   In the present invention, the degree of hydrophilicity required is such that the water supplied by rain or the like spreads out, and generally the contact angle (water droplet end contact angle) is 10 ° or less, preferably 5 ° or less. More preferably, it is 3 ° or less.

本発明による光触媒層70は、TiO2、ZnO、SrTiO3、WO3、Bi23、Fe23、SnO2およびSiO2からなる群から選択される親水性材料を含み、特に、TiO2を含む光触媒層が好ましい。かかる光触媒層は、日射計10に用いるガラスドーム表面に設ける方法は、以下のものに限定されないが、前述のTiO2、ZnO、SrTiO3、WO3、Bi23、Fe23、SnO2、SiO2などの材料を含む光触媒溶液に浸し、ガラスドーム表面に光触媒層を付け、乾燥または加熱しながら乾燥する方法や、前述の材料の蒸着により光触媒層をガラスドーム表面に塗設する方法等がある。 The photocatalytic layer 70 according to the present invention comprises a hydrophilic material selected from the group consisting of TiO 2 , ZnO, SrTiO 3 , WO 3 , Bi 2 O 3 , Fe 2 O 3 , SnO 2 and SiO 2 , in particular TiO A photocatalytic layer containing 2 is preferred. Such photocatalyst layer, a method of providing a glass dome surface for use in the solar radiation meter 10, but are not limited to, TiO 2, ZnO described above, SrTiO 3, WO 3, Bi 2 O 3, Fe 2 O 3, SnO 2 , a method of immersing in a photocatalyst solution containing a material such as SiO 2 and attaching a photocatalyst layer to the surface of the glass dome and drying it while drying or heating, Etc.

図2は、本発明に係る日射計10における演算装置のブロック図である。本発明に係る日射計におけるセンサーからは、多くの場合、電力出力Vとして出力され、本発明にて用いる演算装置にて、常数Kを介して測定量、たとえば、日射強度Gに変換される。すなわち、
G = K*V
と表現される。このKの値は、日射計内または演算装置内で、電気的に処理され、測定量が各々の単位で直接表示または記録される。
FIG. 2 is a block diagram of an arithmetic unit in the pyranometer 10 according to the present invention. In many cases, the sensor in the pyranometer according to the present invention outputs the electric power output V, and is converted into a measured quantity, for example, the solar radiation intensity G through the constant K by the arithmetic unit used in the present invention. That is,
G = K * V
It is expressed. The value of K is electrically processed in the pyranometer or the arithmetic unit, and the measured quantity is directly displayed or recorded in each unit.

図2に示すように、センサー20からの出力電圧は、コネクター80を介して、CPUとメモリから構成される演算装置90に送られ、該装置内にある演算部にて、所定の算出方法に従って、日射強度を算出することができる。なお、図2では、前記演算装置を日射計の外部に設けた態様を例示したが、日射計内部に設けることも可能であることは、当業者には容易に理解できる。必要に応じて、演算装置90にて得られた日射強度の値は、演算装置90に接続された表示手段100にて表示される。本発明で用いられる表示手段1100の具体例としては、以下のものに限定されないが、液晶表示装置等を挙げることができる。   As shown in FIG. 2, the output voltage from the sensor 20 is sent via a connector 80 to an arithmetic device 90 composed of a CPU and a memory, and the arithmetic unit in the device follows a predetermined calculation method. The solar radiation intensity can be calculated. In addition, although the aspect which provided the said arithmetic unit in the exterior of the pyranometer was illustrated in FIG. 2, it can be understood easily by those skilled in the art that it can also be provided in the pyranometer. If necessary, the value of the solar radiation intensity obtained by the computing device 90 is displayed on the display means 100 connected to the computing device 90. Specific examples of the display means 1100 used in the present invention are not limited to the following, but include liquid crystal display devices and the like.

本発明に係る日射計10に用いる光触媒層70を設けたガラスドーム60は、センサー受光面をガラスドームまたはガラスの筒で覆ったものに適用できるほか、分光日射計、紫外放射計、赤外日射計などに適用可能である。また、本発明による光触媒層70を設けたガラスドーム60を備えた日射計の具体例としては、回転式日照計や直達日射計にも適用可能である。さらに、本発明による光触媒層70は、ガラスの筒またはガラスカバーを備えた太陽電池式日射計にも適用可能である。そのほかの適用例としては、シリコンドームを使用した赤外放射計、放射収支計、ラディエーションシールド付温湿度計などの気象観測機器等が挙げられる。   The glass dome 60 provided with the photocatalyst layer 70 used in the solar radiation meter 10 according to the present invention can be applied to a sensor light receiving surface covered with a glass dome or a glass tube, as well as a spectroscopic solar radiation meter, an ultraviolet radiometer, an infrared solar radiation. It can be applied to totals. Moreover, as a specific example of the pyranometer provided with the glass dome 60 provided with the photocatalyst layer 70 according to the present invention, it can also be applied to a rotary irradiometer and a direct solar radiation meter. Furthermore, the photocatalyst layer 70 according to the present invention is also applicable to a solar cell solar radiation meter provided with a glass tube or a glass cover. Other application examples include weather observation equipment such as an infrared radiometer using a silicon dome, a radiation balance meter, and a temperature shield with a radiation shield.

本発明によれば、屋外に長期間設置しても、観測誤差の少ない日射計が提供される。また、本発明によれば、無人の観測場所に設置した日射計のメンテナンス回数を低下させることもできる。   ADVANTAGE OF THE INVENTION According to this invention, even if it installs outdoors for a long period of time, the pyranometer with few observation errors is provided. Moreover, according to this invention, the frequency | count of a maintenance of the pyranometer installed in the unmanned observation place can also be reduced.

図1は、本発明の一の実施態様における日射計の概略断面図を示す。FIG. 1 shows a schematic cross-sectional view of a pyranometer in one embodiment of the present invention. 図2は、本発明に係る日射計10における演算装置のブロック図である。FIG. 2 is a block diagram of an arithmetic unit in the pyranometer 10 according to the present invention.

符号の説明Explanation of symbols

10:本発明に係る日射計、20:基板、30:センサー、40:フィルター、50:拡散板、60:ガラスドーム、70:光触媒層、80:コネクター、90:演算装置、100:表示手段 10: pyranometer according to the present invention, 20: substrate, 30: sensor, 40: filter, 50: diffusion plate, 60: glass dome, 70: photocatalyst layer, 80: connector, 90: arithmetic device, 100: display means

Claims (3)

基板と、
前記基板上に配設したセンサーと、
前記センサー上に配設した拡散板と、
前記拡散板の上に位置し、前記基板、前記センサーおよび前記拡散板を覆うガラスドームと、を備える日射計であって、
前記ガラスドームの表面に、光励起に応じて親水化する光触媒層を設けることを特徴とする、日射計。
A substrate,
A sensor disposed on the substrate;
A diffuser disposed on the sensor;
A pyranometer located on the diffuser plate and comprising a glass dome covering the substrate, the sensor and the diffuser plate,
A photometer, wherein a photocatalytic layer that becomes hydrophilic in response to photoexcitation is provided on the surface of the glass dome.
前記光触媒層は、TiO2、ZnO、SrTiO3、WO3、Bi23、Fe23、SnO2およびSiO2からなる群から選択される親水性材料を含む、請求項1に記載の日射計。 The photocatalyst layer comprises TiO 2, ZnO, SrTiO 3, WO 3, Bi 2 O 3, Fe 2 O 3, the hydrophilic material selected from the group consisting of SnO 2 and SiO 2, of claim 1 Pyranometer. 前記日射計は、分光日射計、紫外放射計、赤外放射計、シリコンドームを使用した赤外放射計、回転式日照計、直達日射計、太陽電池式日射計、放射収支計、ラディエーションシールド付温湿度計からなる群から選択される、請求項1または2に記載の日射計。


The above-mentioned pyranometers are spectrophotometers, ultraviolet radiometers, infrared radiometers, infrared radiometers using silicon domes, rotary solarimeters, direct solar radiation meters, solar cell solar radiation meters, radiation balance meters, and radiation shields. The pyranometer of Claim 1 or 2 selected from the group which consists of a thermo-hygrometer.


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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6023942B1 (en) * 2015-07-15 2016-11-09 英弘精機株式会社 Pyranometer
JP2019086317A (en) * 2017-11-02 2019-06-06 国立大学法人豊橋技術科学大学 Actinometer and cloud behavior predicting system using the same
EP4019917A1 (en) * 2020-12-23 2022-06-29 OTT HydroMet B.V. Pyranometer and method of detecting a soiling on a dome in a pyranometer

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JP7141030B2 (en) 2017-11-02 2022-09-22 国立大学法人豊橋技術科学大学 Pyranometer and cloud behavior prediction system using it
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