JP2007126617A - Agent for preventing petal dropping of artificial flower - Google Patents

Agent for preventing petal dropping of artificial flower Download PDF

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JP2007126617A
JP2007126617A JP2005344609A JP2005344609A JP2007126617A JP 2007126617 A JP2007126617 A JP 2007126617A JP 2005344609 A JP2005344609 A JP 2005344609A JP 2005344609 A JP2005344609 A JP 2005344609A JP 2007126617 A JP2007126617 A JP 2007126617A
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adhesive
glycol
artificial
flower
polyvinyl butyral
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Takahiro Sugawara
孝弘 菅原
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NIPPAN KK
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NIPPAN KK
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Abstract

<P>PROBLEM TO BE SOLVED: To provide an adhesive for preventing petal dropping of artificial flowers using a natural plant, especially, an adhesive applicable even to the central part of a flower center. <P>SOLUTION: The adhesive for adhering artificial flowers made of a natural plant comprises a solution containing (i) a 1-3C lower alcohol, (ii) polyvinyl butyral and (iii) at least one glycol ether, at a weight ratio of (1-99):(99-1). <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は、天然の植物を使用した造花の花びら落下を防止する接着剤の製法及び使用に関する。  The present invention relates to a method for producing and using an adhesive that prevents the fall of petals of artificial flowers using natural plants.

従来、造花の花びら落下防止材としてホットメルトボンドなど、様々な接着方法が開発されているが、代表的なものとして、商品名:グルーガンなどがある。  Conventionally, various adhesion methods such as hot melt bonding have been developed as an artificial flower petal fall prevention material, but a typical product name is a glue gun.

しかしながら、このような溶解型接着ホットメルトボンドは花びら表面の部分には効果があるが、その花芯中心部の維持、形成という性質はなく、いずれも中心部に入れるにもかなりの熟練を要するものであり、初心者にとって極めて困難であることはもとより、ある程度の中級レベルの者や熟練者においても簡単ではなかった。  However, although such a melt-type adhesive hot melt bond is effective on the surface of the petal, there is no property of maintaining and forming the center of the flower core, and both require considerable skill to put in the center. It was difficult for beginners, and it was not easy for some intermediate level or skilled people.

以下、本発明の課題を解決するための手段について説明する。なお、本発明の理解を容易にするために添付図面の参照符号を括弧書きにて付記するが、それにより本発明が図に示めす形態に限定されるものではない。まず請求項1の造花の花びら落下防止において、天然の植物を造花にしたものを接着する接着剤であって、(イ)炭素数1〜3の低級アルコールと(ロ)ポリビニルブチラール(ハ)少なくとも一種類のグリコールエーテルを1〜99:99〜1の重量比率で含有する溶媒からなる事を特徴とする造花の接着剤。(イ)成分としてグリコールエーテルとポリビニルブチラールを併合ずる請求項1〜3いずれか1項の接着剤。(ハ)成分として多価アルコールとポリビニルブチラールを併合ずる請求項1〜3いずれか1項の接着剤。請求項1の溶媒には金属の粉やマイカなどの鉱物を混合した請求項1〜3いずれかの接着剤。前記多価アルコールがエチレングリコール、プロピレングリコール、ジエチレングリコール、ジプロピレングリコール、ブチルジグリコール、グリセリン、チオジエチレングリコール、モノエチレングリコール、ポリエチレングリコール、ポリプロピレングリコール、ポリ(オキシエチレン・オキシプロピレン)グリコール、エチルジエチレングリコール、ポリオキシプロピレントリオール及びポリ(オキシエチレン・オキシプロピレン)トリオールからなる群から選ばれるものである請求項3の接着剤。請求項1の接着剤には適宜に酢酸エチル樹脂、アクリル系樹脂を混合す事が出来る事を特徴とする造花の接着剤これらのグリコールエーテル類群、グリールエーテル類からなる溶液を混合したものを特徴とする溶剤に、アルコール類が含まれ任意に混合できる割合は1対99〜99対1とする事を接着剤を使用する事により花びらが取れるのを防ぐ事ができる。Hereinafter, means for solving the problems of the present invention will be described. In order to facilitate understanding of the present invention, reference numerals in the accompanying drawings are appended in parentheses, but the present invention is not limited to the form shown in the drawings. First, in the prevention of fall of petals of artificial flowers according to claim 1, an adhesive for adhering a natural plant made of artificial flowers, comprising (a) a lower alcohol having 1 to 3 carbon atoms and (b) polyvinyl butyral (c) at least An artificial flower adhesive comprising a solvent containing one kind of glycol ether in a weight ratio of 1 to 99: 99-1. The adhesive according to any one of claims 1 to 3, wherein glycol ether and polyvinyl butyral are combined as component (a). The adhesive according to any one of claims 1 to 3, wherein polyhydric alcohol and polyvinyl butyral are combined as a component (c). The adhesive according to any one of claims 1 to 3, wherein the solvent of claim 1 is mixed with a metal powder or a mineral such as mica. The polyhydric alcohol is ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, butyl diglycol, glycerin, thiodiethylene glycol, monoethylene glycol, polyethylene glycol, polypropylene glycol, poly (oxyethylene / oxypropylene) glycol, ethyl diethylene glycol, poly The adhesive according to claim 3, wherein the adhesive is selected from the group consisting of oxypropylene triol and poly (oxyethylene oxypropylene) triol. The adhesive according to claim 1 is characterized in that an ethyl acetate resin and an acrylic resin can be appropriately mixed, and an artificial flower adhesive characterized by mixing a solution comprising these glycol ethers and glycol ethers. It is possible to prevent petals from being removed by using an adhesive that the solvent contains alcohols and can be mixed arbitrarily at a ratio of 1:99 to 99: 1.

本発明によれば、比較的花びらが散り易い造花の落下防止剤として花本体を形成する花芯において、花の構成部材にこのような接着剤を用いて、これを止着することができる本発明の接着剤は保湿成分を含んでいるのでアルコール及び水分も吸着する為、造花作製時にアルコールが完全に乾かない場合でも十分な接着効果がありアルコールにより花芯部まで浸透する為むしろ造花の出来具合は良くなる。本発明の接着剤は水分を吸収する為、わが国のように湿度が通年変化した場合でも接着剤は水分を吸排出する為に造花と一緒に接着剤も動くような柔軟性があり長期期間にわたり造花の花びらを維持出来る。  According to the present invention, in the flower core that forms the flower main body as an artificial flower fall-preventing agent that is relatively easy to disperse the petals, the book can be fixed using such an adhesive on the flower component. Since the adhesive of the invention contains a moisturizing ingredient, it also adsorbs alcohol and moisture, so even if the alcohol does not dry completely during the production of artificial flowers, it has a sufficient adhesive effect and penetrates to the flower core by alcohol, rather it can produce artificial flowers. The condition gets better. Since the adhesive of the present invention absorbs moisture, even if the humidity changes throughout the year as in Japan, the adhesive is flexible so that the adhesive moves together with artificial flowers to absorb and discharge moisture over a long period of time. Can keep the artificial petals.

一つの実施例として、本発明の接着剤は、ポリビニルプチラール及び酢酸ビニル成物またはポリ成物からなる造花の花びら及び花芯を、接着、花芯を維持形成するための接着剤であって、少なくとも酢酸ビニル樹脂、アクリル系樹脂、ポリ及び着色剤、香料を含んでいる。  As an example, the adhesive of the present invention is an adhesive for maintaining and forming an artificial flower petal and a flower core composed of a polyvinyl petital and a vinyl acetate or a poly composition. , At least a vinyl acetate resin, an acrylic resin, poly, a colorant, and a fragrance.

この酢酸ビニル樹脂とは、接着剤の主要構成要素として含有されるもので、酢酸ビニル基を有するモノマーのビニル重合によって合成される樹脂である。  The vinyl acetate resin is a resin that is contained as a main component of the adhesive and is synthesized by vinyl polymerization of a monomer having a vinyl acetate group.

酢酸ビニル樹脂とは、接着剤の主要構成要素として含有されるもので、酢酸ビニル基を有するモノマーのビニル重合によって合成される樹脂であり、具体的にはポリビニルアルコール、酢酸ビニル樹脂、及び炭素数1〜3のアルコール、グリコールエーテル類からなる2種以上の化合物を共合してなる混合物が挙げられる。  Vinyl acetate resin is a resin that is contained as a main component of an adhesive and is synthesized by vinyl polymerization of a monomer having a vinyl acetate group. Specifically, polyvinyl alcohol, vinyl acetate resin, and carbon number A mixture formed by combining two or more kinds of compounds consisting of 1 to 3 alcohols and glycol ethers.

酢酸ビニル樹脂成分は、分子内に水溶化のために必要な基を有するポリオール、又はこのアリオールとそれ以外のポリオールとの混合ポリオールであるが、物性の設計が容易である等の点から、混合ポリオールが好ましい。  The vinyl acetate resin component is a polyol having a group necessary for water-solubilization in the molecule, or a mixed polyol of this allyol and other polyols, but it is mixed from the viewpoint of easy design of physical properties. Polyols are preferred.

本発明の接着剤は、酢酸ビニル樹脂、香料及び着色剤の他、必要により硬化剤や溶剤を含んでも良いし、更に酸化防止剤、紫外線吸収剤等の添加剤を含んでいてもよい。  The adhesive of the present invention may contain a curing agent and a solvent as necessary in addition to the vinyl acetate resin, the fragrance, and the colorant, and may further contain additives such as an antioxidant and an ultraviolet absorber.

ポリビニルブチラール100cc酢酸ビニル樹脂モノアルマー400ccポリグコールエーテル200ccエチルアルコール300cc染料黄色からなる接着剤を作り造花のガーベラの花びら、花芯へスポイトで10 注いで乾燥させてた。ガーベラの花芯は黄色く染まり、花びらも取れることなく自然な外観を留めたまま、1年以上、実質的に変化無く、美しく保たれた。Polyvinyl butyral 100 cc vinyl acetate resin monoalmer 400 cc polyglycol ether 200 cc ethyl alcohol 300 cc dye An adhesive consisting of yellow was made and poured into an artificial gerbera petal and flower core by pouring 10 times with a dropper and dried. The gerbera flower core was dyed yellow and kept beautiful for more than a year, with virtually no change, while retaining its natural appearance without removing petals.

酢酸エチル樹脂300ccグリコールエーテル100ccエチルアルコール100ccメチルアルコール50ccを混ぜて接着剤をつくり造花の大菊の花芯へ15 スポイトで浸透するように注いだ。造花の大菊は花びらも取れることなく自然な外観を留めたまま、1年以上、実質的に変化無く、美しく保たれた。Ethyl acetate resin 300 cc glycol ether 100 cc Ethyl alcohol 100 cc Methyl alcohol 50 cc was mixed to prepare an adhesive, which was poured into the core of artificial chrysanthemum with 15 drops. The artificial chrysanthemum has kept its natural appearance without removing petals, and has been kept beautiful for over a year without substantial change.

ポリビニルブチラール300 酢酸エチルモノマー200ccエチルアルコール100ccグリコールエーテル150ccエチレングリコール150ccを入れた接着剤をつくり造花のバラの花芯へ10cc注射器で入れた。造花の大菊は花びらも取れることなく自然な外観を留めたまま、1年以上、実質的に変化無く、美しく保たれた。Polyvinyl butyral 300 Ethyl acetate monomer 200 cc Ethyl alcohol 100 cc Glycol ether 150 cc Ethylene glycol 150 cc adhesive was made and put into the rose core of artificial flowers with a 10 cc syringe. The artificial chrysanthemum has kept its natural appearance without removing petals, and has been kept beautiful for over a year without substantial change.

酢酸ビニルエマルション500cc、エチレングリコール100ccグリコールエーテル100ccかならる接着剤をつくり造花のチューリップの花芯へ10cc入れた。造花のチューリップは花びらも取れることなく自然な外観を留めたまま、1年以上、実質的に変化無く、美しく保たれた。An adhesive consisting of 500 cc of vinyl acetate emulsion and 100 cc of ethylene glycol, 100 cc of glycol ether was made, and 10 cc was put into the core of the artificial tulip. Artificial tulips have been kept beautiful with virtually no change for more than a year, keeping their natural appearance without removing petals.

酢酸ビニル樹脂300cc、エチルアルコール500cc、イソプロピルアルコール100cc染料黒からなる接着剤をつくり造花のヒマワリの花芯へ30ccスポイトで入れた。造花のヒマワリの花芯が黒く自然な状態で染まり、花びらも取れることなく自然な外観を留めたまま、1年以上、実質的に変化無く、美しく保たれた。An adhesive consisting of 300 cc of vinyl acetate resin, 500 cc of ethyl alcohol and 100 cc of isopropyl alcohol was made and placed in the sunflower flower core of artificial flowers with a 30 cc dropper. The sunflower core of the artificial flower was dyed in a black and natural state, and it remained beautiful with virtually no change for more than a year, keeping its natural appearance without removing petals.

造花に加工した薔薇の接着においてポリビニルウチラール100cc、メチルアルコール50cc、ポリグリコールエーテル50ccを混合して花のガク部を浸漬した後、薔薇の花芯へスプーンで注いで乾燥させた。In the adhesion of roses processed into artificial flowers, 100 cc of polyvinyl utilal, 50 cc of methyl alcohol, and 50 cc of polyglycol ether were mixed to immerse the flower part of the flower, and then poured into a rose flower core with a spoon and dried.

造花に加工したガーベラにおいて、ポリビニルブチラール100cc、ポリグリコールエーテル30cc、エチルアルコール70cc、染料橙色2グラムを混合したものをガーベラの花芯部分を浸漬させてから筆で花芯部分と花ビラの根元を生花の状態のようにコーティングした。ガーベラは生花の時の様な状態になり生き生きとした状態をその後一年以上保持した。In a gerbera processed into artificial flowers, a mixture of 100 cc of polyvinyl butyral, 30 cc of polyglycol ether, 70 cc of ethyl alcohol, and 2 g of dye orange is immersed in the gerbera's flower core, and then the root of the flower's wick and the leaflet of the flower are dipped in a brush It was coated like a fresh flower. Gerbera became like a fresh flower and kept alive for more than a year thereafter.

造花に加工した薔薇を、ポリビニルブチラール300cc、ポリグリコールエーテル30cc、エチルアルコール30cc、メチルアルコール20cc、染料2グラム、金色のグリッターを混ぜたものを噴霧器により吹きかけた。薔薇は赤と金色のラメに染まりそのまま1年以上美しい姿を維持した。Roses processed into artificial flowers were sprayed with a mixture of 300 cc polyvinyl butyral, 30 cc polyglycol ether, 30 cc ethyl alcohol, 20 cc methyl alcohol, 2 grams dye, and golden glitter. Roses were dyed in red and gold lamé and remained beautiful for over a year.

青色に加工したカーネーションの造花をポリビニルブチラール100cc、ポリグリコールエーテル150cc、メタノール350cc、染料紅梅色5グラムを混合したものを噴霧器に入れて造花に散布した。カーネーションは元の青色と紅梅色が混ざり生花では見ることの出来ない美しい姿になった。その後一年以上経過しても美しい姿を留めた。A carnation artificial flower processed into blue was mixed with 100 cc of polyvinyl butyral, 150 cc of polyglycol ether, 350 cc of methanol, and 5 g of the dye red plum color and placed in a sprayer and sprayed on the artificial flower. The carnation has a beautiful blue color and red plum color that cannot be seen with fresh flowers. It remained beautiful even after more than a year.

本発明の一実施例を示す斜視図  The perspective view which shows one Example of this invention 本発明の他の実施例を示す斜視図  The perspective view which shows the other Example of this invention. 本発明の噴霧を示す斜視図  The perspective view which shows the spray of this invention

符号の説明Explanation of symbols

図1−1.花芯へボンドを注ぐ為のスプーンなどの注ぎ具
図1−2.造花のボンドを注ぐ花芯
図1−3.造花本体
図2−1.造花が入る容器
図2−2.本発明のボンド
図2−3.ボンドに浸ける造花
図3−1.噴霧器
図3−2.造花
Fig. 1-1. Spooning tools such as spoons for pouring bonds to the flower core Figure 1-2. Fig. 1-3. Artificial flower body Figure 2-1. Container for artificial flowers Figure 2-2. Bond of the present invention FIG. 2-3. Artificial flowers immersed in bond Fig. 3-1. Nebulizer Fig. 3-2. Artificial flower

Claims (6)

天然の植物を造花にしたものを接着する接着剤であって、(イ)炭素数1〜3の低級アルコールと(ロ)ポリビニルブチラール(ハ)少なくとも一種類のグリコールエーテルを1〜99:99〜1の重量比率で含有する溶媒からなる事を特徴とする造花の接着剤。  An adhesive for adhering a natural plant made of artificial flowers, comprising (a) a lower alcohol having 1 to 3 carbon atoms and (b) polyvinyl butyral (c) at least one glycol ether in an amount of 1 to 99:99 1. An artificial flower adhesive comprising a solvent contained in a weight ratio of 1. (イ)成分としてグリコールエーテルとポリビニルブチラールを併合ずる請求項1〜3いずれか1項の接着剤。The adhesive according to any one of claims 1 to 3, wherein glycol ether and polyvinyl butyral are combined as component (a). (イ)成分としてグリコールエーテルとポリビニルブチラールを併合ずる請求項1〜3いずれか1項の接着剤。The adhesive according to any one of claims 1 to 3, wherein glycol ether and polyvinyl butyral are combined as component (a). 請求項1の溶媒には金属の粉やマイカなどの鉱物を混合した請求項1〜3いずれかの接着剤。  The adhesive according to any one of claims 1 to 3, wherein the solvent of claim 1 is mixed with a metal powder or a mineral such as mica. 前記多価アルコールがエチレングリコール、プロピレングリコール、ジエチレングリコール、ジプロピレングリコール、ブチルジグリコール、グリセリン、チオジエチレングリコール、モノエチレングリコール、ポリエチレングリコール、ポリプロピレングリコール、ポリ(オキシエチレン・オキシプロピレン)グリコール、エチルジエチレングリコール、ポリオキシプロピレントリオール及びポリ(オキシエチレン・オキシプロピレン)トリオールからなる群から選ばれるものである請求項3の接着剤。  The polyhydric alcohol is ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, butyl diglycol, glycerin, thiodiethylene glycol, monoethylene glycol, polyethylene glycol, polypropylene glycol, poly (oxyethylene / oxypropylene) glycol, ethyl diethylene glycol, poly The adhesive according to claim 3, wherein the adhesive is selected from the group consisting of oxypropylene triol and poly (oxyethylene oxypropylene) triol. 請求項1の接着剤には適宜に酢酸ビニル樹脂、アクリル系樹脂を混合す事が出来る事を特徴とする造花の接着剤。  An adhesive for artificial flowers, wherein a vinyl acetate resin and an acrylic resin can be appropriately mixed with the adhesive of claim 1.
JP2005344609A 2005-10-31 2005-10-31 Agent for preventing petal dropping of artificial flower Pending JP2007126617A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012062592A (en) * 2010-09-15 2012-03-29 Kaori Higashi Preserved flower, bloom control method of the preserved flower, method of producing the preserved flower which has undergone bloom control, and spatula, adhesive and adhesive container used in the methods

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012062592A (en) * 2010-09-15 2012-03-29 Kaori Higashi Preserved flower, bloom control method of the preserved flower, method of producing the preserved flower which has undergone bloom control, and spatula, adhesive and adhesive container used in the methods

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