JP2007103927A - Metalized film capacitor - Google Patents

Metalized film capacitor Download PDF

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JP2007103927A
JP2007103927A JP2006246534A JP2006246534A JP2007103927A JP 2007103927 A JP2007103927 A JP 2007103927A JP 2006246534 A JP2006246534 A JP 2006246534A JP 2006246534 A JP2006246534 A JP 2006246534A JP 2007103927 A JP2007103927 A JP 2007103927A
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film
dielectric film
resin layer
electrode layer
dielectric
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JP4853193B2 (en
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Yukikazu Ochi
幸和 大地
Hiroki Takeoka
宏樹 竹岡
Hiroshi Fujii
浩 藤井
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Panasonic Holdings Corp
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Matsushita Electric Industrial Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a metalized film capacitor capable of suppressing the heat generation even if a high ripple current is caused to flow by providing a resin layer of a material that does not deteriorate dielectric tangent in a dielectric film. <P>SOLUTION: In the metalized film capacitor in which a capacitor element 1 is wound or laminated so that a pair of metal-evaporated electrode layers 3 counters a metalized film 4, which is a dielectric film 2 on one surface or both surfaces of which metal-evaporated electrode layer 3 is formed, via the dielectric film 2, a resin layer 5 is provided between the dielectric film 2 and the metal-evaporated electrode layer 3 and a compound having a vinyl group is used in the resin layer 5. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は、樹脂層を設けた誘電体フィルムを用いた金属化フィルムコンデンサに関するものである。   The present invention relates to a metallized film capacitor using a dielectric film provided with a resin layer.

近年、ハイブリッド自動車のモータ駆動用のインバータシステムに、アルミ電解コンデンサよりも、高耐圧・低損失・温度特性が優れたフィルムコンデンサが用いられるようになってきた。車載用のコンデンサは、寒冷地や高温高湿地でも使用されることから、民生用の電気機器用よりも、高温における耐湿性や広い温度範囲における耐熱衝撃性が求められる。また、高いリプル電流を流しても発熱が小さくなる構造なども求められる。   In recent years, film capacitors having higher withstand voltage, lower loss, and better temperature characteristics than aluminum electrolytic capacitors have been used in inverter systems for driving motors in hybrid vehicles. Since an in-vehicle capacitor is used even in a cold region or a high temperature and high humidity region, it is required to have a moisture resistance at a high temperature and a thermal shock resistance in a wide temperature range as compared with a consumer electric device. Further, there is a demand for a structure that reduces heat generation even when a high ripple current is passed.

特に誘電体となるフィルム表面の状態はフィルムコンデンサの発熱に影響を与える重要な要素である。   In particular, the state of the film surface serving as a dielectric is an important factor affecting the heat generation of the film capacitor.

図1は金属化フィルムコンデンサの斜視図である。図1において、1はコンデンサ素子であり、ポリプロピレン(PP)などからなる誘電体フィルム2の片面にアルミニウムなどの金属蒸着電極層3を形成した金属化フィルム4を一対の金属蒸着電極層3が誘電体フィルム2を介して対向するように巻回したものであり、両端からコンデンサの正極、負極それぞれの極を電気的に引き出すことが出来るように構成されている。   FIG. 1 is a perspective view of a metallized film capacitor. In FIG. 1, reference numeral 1 denotes a capacitor element. A metallized film 4 in which a metal vapor-deposited electrode layer 3 such as aluminum is formed on one side of a dielectric film 2 made of polypropylene (PP) or the like is used as a pair of metal vapor-deposited electrode layers 3. It is wound so as to face each other through the body film 2, and is configured so that the positive and negative electrodes of the capacitor can be electrically drawn out from both ends.

5はアクリレート材料などからなる樹脂層であり、誘電体フィルム2上に塗布することなどによって形成される。   Reference numeral 5 denotes a resin layer made of an acrylate material or the like, which is formed by coating on the dielectric film 2.

硬化や塗布といった作業が容易なアクリレート材料を用いることによって、誘電体フィルム2の耐電圧を高くでき、高耐圧のフィルムコンデンサが実現されてきた。   By using an acrylate material that can be easily cured and applied, the dielectric voltage of the dielectric film 2 can be increased, and a high voltage resistant film capacitor has been realized.

なお、この出願の発明に関連する先行技術文献情報としては、例えば、特許文献1が知られている。
特許第3101682号公報
As prior art document information related to the invention of this application, for example, Patent Document 1 is known.
Japanese Patent No. 3101682

ところが、このような従来の材料、構成においては、電気特性の悪化という問題があった。具体的には高温下での誘電正接が高くなるという問題であって、これはアクリレート材料に含まれるカルボニル基が酸素と炭素からなっており、この酸素は電気的にややマイナス側に、炭素は同じくややプラス側に分極しているため、元来より誘電正接が高く、さらに高温下ではアクリレート材料の分子運動が高くなるのでさらに誘電正接が高くなるというものであった。   However, such conventional materials and structures have a problem of deterioration of electrical characteristics. Specifically, it is a problem that the dielectric loss tangent at high temperature becomes high. This is because the carbonyl group contained in the acrylate material is composed of oxygen and carbon. Similarly, since it is slightly polarized on the positive side, the dielectric loss tangent is higher from the beginning, and at higher temperatures, the molecular motion of the acrylate material is higher, so the dielectric loss tangent is higher.

これにより、コンデンサとしてリプル電流を印加すると発熱するが、その発熱により誘電正接が高くなってさらに発熱するという課題を有していた。   As a result, when a ripple current is applied as a capacitor, heat is generated. However, due to the heat generation, the dielectric loss tangent is increased and further heat is generated.

そこで本発明は、従来の課題を解決するため誘電体フィルムに誘電正接を悪化させない材料による樹脂層を設けることによって高いリプル電流を流しても発熱を抑制できる金属化フィルムコンデンサとすることを目的とする。   Accordingly, the present invention aims to provide a metallized film capacitor capable of suppressing heat generation even when a high ripple current is passed by providing a resin layer made of a material that does not deteriorate the dielectric loss tangent on the dielectric film in order to solve the conventional problems. To do.

前記従来の課題を解決するために、本発明は、誘電体フィルムと金属蒸着電極層の間にビニル基を有する化合物を用いる樹脂層を設けたことを特徴としたものである。   In order to solve the above-mentioned conventional problems, the present invention is characterized in that a resin layer using a compound having a vinyl group is provided between a dielectric film and a metal vapor-deposited electrode layer.

本発明のコンデンサは、コンデンサ素子の誘電体フィルムと金属蒸着電極層の間にビニル基を有する化合物を用いる樹脂層を設けているので、高いリプル電流を流しても誘電正接を悪化させることがなくこれに伴うコンデンサの製品の発熱抑制を期待できるものである。   In the capacitor of the present invention, since a resin layer using a compound having a vinyl group is provided between the dielectric film of the capacitor element and the metal vapor-deposited electrode layer, the dielectric loss tangent is not deteriorated even when a high ripple current is passed. This can be expected to suppress the heat generation of capacitor products.

以下、本発明の実施の形態1について、図を用いて説明する。従来のコンデンサと同一構成の部分については説明を省略する。   Embodiment 1 of the present invention will be described below with reference to the drawings. The description of the same configuration as the conventional capacitor is omitted.

(実施の形態1)
図1において、1はコンデンサ素子であり、ポリプロピレンからなる誘電体フィルム2の片面にアルミニウムの層状の金属蒸着電極層3を形成した金属化フィルム4を一対の金属蒸着電極層3が誘電体フィルム2を介して対向するように巻回したものであり、両端からコンデンサの正極、負極それぞれの極を電気的に引き出すことが出来るように構成されている。
(Embodiment 1)
In FIG. 1, reference numeral 1 denotes a capacitor element. A metallized film 4 in which an aluminum layered metal vapor deposition electrode layer 3 is formed on one side of a dielectric film 2 made of polypropylene is a pair of metal vapor deposition electrode layers 3. It is wound so as to face each other, and is configured so that the positive and negative electrodes of the capacitor can be electrically drawn out from both ends.

5は誘電体フィルム2と層状の金属蒸着電極層3の間に設けられた樹脂層であり、ビニル基を有する化合物を用いたものである。樹脂層5は真空蒸着によっても、塗布などによって形成されてもよいものとする。   Reference numeral 5 denotes a resin layer provided between the dielectric film 2 and the layered metal vapor deposition electrode layer 3, which uses a compound having a vinyl group. The resin layer 5 may be formed by vacuum deposition or coating.

この樹脂層5に用いられる材料は以下の構造式で表されるものである。   The material used for the resin layer 5 is represented by the following structural formula.

Figure 2007103927
Figure 2007103927

Figure 2007103927
Figure 2007103927

このように樹脂層5にビニル基を有する化合物を用いることが本発明における技術的特徴の一つであり、このようにすることによって、誘電体フィルム2にはカルボニル基を含んでいないので、誘電体フィルム2の耐電圧を高くするとともに、誘電正接を悪化させないので、コンデンサ素子の製品の発熱を抑制することができる。   Thus, the use of a compound having a vinyl group in the resin layer 5 is one of the technical features in the present invention. By doing so, the dielectric film 2 does not contain a carbonyl group. Since the withstand voltage of the body film 2 is increased and the dielectric loss tangent is not deteriorated, heat generation of the capacitor element product can be suppressed.

特に上記によって得られる化合物は両端にビニル基を有し、線対称もしくは点対称な構造を有している産業上合成可能な化合物であることが特徴である。これによって構造による分極が抑えられることになり、高温下でも誘電正接がさらに高くなるということがなくなるものである。   In particular, the compound obtained by the above is characterized by being an industrially synthesizeable compound having vinyl groups at both ends and having a line-symmetric or point-symmetric structure. As a result, polarization due to the structure is suppressed, and the dielectric loss tangent is not further increased even at high temperatures.

また、従来であればアクリレート材料は吸湿性が高いものであったので、この材料を使用していないため耐湿性も向上する。   Further, conventionally, since the acrylate material has high hygroscopicity, since this material is not used, the moisture resistance is also improved.

また、本実施の形態においては金属蒸着電極層3としてアルミニウムを用いることとしたが、これは亜鉛、もしくはアルミニウムと亜鉛の合金としてもよいものとする。金属蒸着電極層3としてアルミニウムを用いると抵抗値を高くすることが可能であり、亜鉛を用いると引き出し電極との接合を高めることができ、これらの合金とすることでその両方の
特徴を得ることが可能になるものである。
In the present embodiment, aluminum is used as the metal deposition electrode layer 3, but it may be zinc or an alloy of aluminum and zinc. When aluminum is used as the metal vapor deposition electrode layer 3, the resistance value can be increased, and when zinc is used, the bonding with the extraction electrode can be enhanced, and by using these alloys, both characteristics can be obtained. Is possible.

なお、図1では理解のために誘電体フィルム2、金属蒸着電極層3、樹脂層5のそれぞれの厚み比率を無視しているが、実際において誘電体フィルム2は1〜3μm、金属蒸着電極層3は5〜50nmである。特に樹脂層5は0.01〜2.0μm、好ましくは0.01〜0.5μmとすることによって、誘電体フィルム2の非平坦部を埋めることとなり、誘電体フィルム2の表面粗さを低くするという効果を奏するものである。   In FIG. 1, the thickness ratios of the dielectric film 2, the metal vapor deposition electrode layer 3, and the resin layer 5 are ignored for the sake of understanding, but the dielectric film 2 actually has a thickness of 1 to 3 μm and the metal vapor deposition electrode layer. 3 is 5 to 50 nm. In particular, by setting the resin layer 5 to 0.01 to 2.0 μm, preferably 0.01 to 0.5 μm, the non-flat portion of the dielectric film 2 is filled, and the surface roughness of the dielectric film 2 is reduced. It has the effect of doing.

これによって、ポリプロピレンフィルムなどの表面粗さに応じて、全体の厚みを不必要に厚くすることなく、平坦度を高めることができ、誘電体フィルム2の最薄部分での絶縁破壊を抑え、誘電体フィルム2全体の絶縁耐圧を高めることが可能になるものである。   As a result, the flatness can be increased without unnecessarily increasing the overall thickness according to the surface roughness of the polypropylene film or the like, the dielectric breakdown at the thinnest portion of the dielectric film 2 can be suppressed, and the dielectric It is possible to increase the withstand voltage of the entire body film 2.

これらの値は使用される電圧によって、決められるものであり、本発明における用途であるハイブリッド自動車のモータ駆動用のインバータシステムにおいては高耐電圧が求められている。   These values are determined by the voltage used, and high withstand voltage is required in the inverter system for driving a motor of a hybrid vehicle, which is an application in the present invention.

また、本実施の形態においては誘電体フィルム2の表面に樹脂層5,金属蒸着電極層3の順に形成したが、金属蒸着電極層3の上層にシリコン系オイルやフッ素系オイルなどによるオイル被膜層(図示せず)を設けることによって、金属化フィルムの酸化を防止することができる。特に、オイル被膜層の形成は蒸着機内という同一工程内で実施することが可能になり、より製造コストを抑え、かつ信頼性の高い金属化フィルムコンデンサとすることができるものである。   In the present embodiment, the resin layer 5 and the metal vapor-deposited electrode layer 3 are formed in this order on the surface of the dielectric film 2, but an oil coating layer made of silicon-based oil or fluorine-based oil is formed on the metal vapor-deposited electrode layer 3. By providing (not shown), oxidation of the metallized film can be prevented. In particular, the formation of the oil coating layer can be carried out in the same process, that is, in the vapor deposition machine, and the production cost can be further reduced and a highly reliable metallized film capacitor can be obtained.

なお、本実施の形態における誘電体フィルム2は表面粗さ(Ra)が2nm〜1000nmのものが用いられる。これは特に車載用においては高い耐電圧が求められ、これを実現するために必要な表面粗さである。   In addition, the dielectric film 2 in the present embodiment has a surface roughness (Ra) of 2 nm to 1000 nm. This is a surface roughness required to achieve a high withstand voltage especially for in-vehicle use.

また、本実施の形態における誘電体フィルム2はポリプロピレンとしたが、これに限定されることなく、ポリエチレンテレフタレートやポリエチレンナフタレート、ポリフェニレンサルファイドなどの熱可塑性フィルム、またはこれらのフィルムを主体とする複合熱可塑性フィルムであってもよいものとする。   Moreover, although the dielectric film 2 in this Embodiment was made into polypropylene, it is not limited to this, It is not limited to this, Thermoplastic films, such as a polyethylene terephthalate, a polyethylene naphthalate, polyphenylene sulfide, or the composite heat | fever which mainly uses these films It may be a plastic film.

そして、誘電体フィルム2の組み合わせは上記のフィルムによる同一の組み合わせだけでなく、上記のフィルムから選ばれる任意の組み合わせでもよいものとする。   And the combination of the dielectric film 2 shall not only be the same combination by said film but arbitrary combinations chosen from said film.

さらに、本実施の形態においてコンデンサ素子1は巻回形のものとしたが、積層したものを切断などして構成してもよいものとする。   Furthermore, in the present embodiment, the capacitor element 1 is of a wound type, but it may be configured by cutting a stacked one.

また、本実施の形態において金属化フィルム4は誘電体フィルム2の片面に金属蒸着電極層3を設け、誘電体フィルム2と金属蒸着電極層3の間に樹脂層5を設けているが、これはこの形態に特定されるものではなく、誘電体フィルム2の両面に金属蒸着電極層3を設け、誘電体フィルム2とそれぞれの金属蒸着電極層3の間に樹脂層5を設けても同様の効果を奏するものとする。   Further, in the present embodiment, the metallized film 4 is provided with the metal vapor-deposited electrode layer 3 on one side of the dielectric film 2, and the resin layer 5 is provided between the dielectric film 2 and the metal vapor-deposited electrode layer 3. However, the present invention is not limited to this embodiment. The same applies even if the metal vapor-deposited electrode layer 3 is provided on both surfaces of the dielectric film 2 and the resin layer 5 is provided between the dielectric film 2 and each metal vapor-deposited electrode layer 3. It shall have an effect.

以上のように、本発明にかかる金属化フィルムコンデンサによれば、フィルムコンデンサの発熱を抑制することができるので、ハイブリッド自動車のモータ駆動用のインバータシステムなどに有用である。   As described above, according to the metallized film capacitor of the present invention, heat generation of the film capacitor can be suppressed, which is useful for an inverter system for driving a motor of a hybrid vehicle.

金属化フィルムコンデンサの斜視図Perspective view of metalized film capacitor

符号の説明Explanation of symbols

1 コンデンサ素子
2 誘電体フィルム
3 金属蒸着電極層
4 金属化フィルム
5 樹脂層
DESCRIPTION OF SYMBOLS 1 Capacitor element 2 Dielectric film 3 Metal vapor deposition electrode layer 4 Metallized film 5 Resin layer

Claims (4)

誘電体フィルムの片面または両面に金属蒸着電極層を形成した金属化フィルムを一対の前記金属蒸着電極層が前記誘電体フィルムを介して対向するようにコンデンサ素子を巻回または積層する金属化フィルムコンデンサにおいて、前記誘電体フィルムと前記金属蒸着電極層の間に樹脂層を設け、前記樹脂層にはビニル基を有する化合物を用いることを特徴とする金属化フィルムコンデンサ。 A metallized film capacitor in which a capacitor element is wound or laminated with a metallized film in which a metal vapor-deposited electrode layer is formed on one or both sides of a dielectric film so that the pair of metal vapor-deposited electrode layers face each other with the dielectric film interposed therebetween A metallized film capacitor according to claim 1, wherein a resin layer is provided between the dielectric film and the metal vapor deposition electrode layer, and a compound having a vinyl group is used for the resin layer. 前記金属蒸着電極層にはアルミニウム、亜鉛、もしくはこれらの合金を用いることを特徴とする請求項1に記載の金属化フィルムコンデンサ。 The metallized film capacitor according to claim 1, wherein aluminum, zinc, or an alloy thereof is used for the metal deposition electrode layer. 前記金属化フィルムの金属蒸着電極層の上にオイル被膜層を設けた請求項1に記載の金属化フィルムコンデンサ。 The metallized film capacitor according to claim 1, wherein an oil coating layer is provided on the metal vapor deposition electrode layer of the metallized film. 前記樹脂層の厚みが0.01μm〜2μmである請求項1に記載の金属化フィルムコンデンサ。 The metallized film capacitor according to claim 1, wherein the resin layer has a thickness of 0.01 μm to 2 μm.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009049139A (en) * 2007-08-17 2009-03-05 Nichicon Corp Metallized film capacitor

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JP2001310911A (en) * 2000-04-28 2001-11-06 Sumitomo Seika Chem Co Ltd Dielectric substance forming material and dielectric film
JP2003151849A (en) * 2001-11-15 2003-05-23 Matsushita Electric Ind Co Ltd Capacitor
JP2005029819A (en) * 2003-07-09 2005-02-03 Toray Ind Inc Metal vapor deposition film manufacturing method
JP2005183713A (en) * 2003-12-19 2005-07-07 Matsushita Electric Ind Co Ltd Capacitor and its manufacturing method

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59188110A (en) * 1983-04-08 1984-10-25 株式会社トクヤマ Coated dielectric and method of producing same
JPS59188910A (en) * 1983-04-11 1984-10-26 信越化学工業株式会社 Condenser
JPS61140128A (en) * 1984-12-13 1986-06-27 松下電器産業株式会社 Manufacture of capacitor
JP3101682B2 (en) * 1993-10-04 2000-10-23 プレステック,インコーポレイティド Crosslinked acrylate coating materials useful for forming dielectric and oxygen barriers in capacitors
JP2001310911A (en) * 2000-04-28 2001-11-06 Sumitomo Seika Chem Co Ltd Dielectric substance forming material and dielectric film
JP2003151849A (en) * 2001-11-15 2003-05-23 Matsushita Electric Ind Co Ltd Capacitor
JP2005029819A (en) * 2003-07-09 2005-02-03 Toray Ind Inc Metal vapor deposition film manufacturing method
JP2005183713A (en) * 2003-12-19 2005-07-07 Matsushita Electric Ind Co Ltd Capacitor and its manufacturing method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009049139A (en) * 2007-08-17 2009-03-05 Nichicon Corp Metallized film capacitor

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