JP2007077526A - Backing paper for wall paper - Google Patents

Backing paper for wall paper Download PDF

Info

Publication number
JP2007077526A
JP2007077526A JP2005265227A JP2005265227A JP2007077526A JP 2007077526 A JP2007077526 A JP 2007077526A JP 2005265227 A JP2005265227 A JP 2005265227A JP 2005265227 A JP2005265227 A JP 2005265227A JP 2007077526 A JP2007077526 A JP 2007077526A
Authority
JP
Japan
Prior art keywords
paper
backing paper
wallpaper
backing
fatty acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2005265227A
Other languages
Japanese (ja)
Other versions
JP4766968B2 (en
Inventor
Tomofumi Narishima
倫史 成島
Masato Ougimoto
政人 扇元
Akio Hoshino
明夫 星野
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Paper Industries Co Ltd
Jujo Paper Co Ltd
Original Assignee
Nippon Paper Industries Co Ltd
Jujo Paper Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Paper Industries Co Ltd, Jujo Paper Co Ltd filed Critical Nippon Paper Industries Co Ltd
Priority to JP2005265227A priority Critical patent/JP4766968B2/en
Publication of JP2007077526A publication Critical patent/JP2007077526A/en
Application granted granted Critical
Publication of JP4766968B2 publication Critical patent/JP4766968B2/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Paper (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a backing paper for a wall paper, hardly curling even on applying paste, without forming apertures after pasting, also easy for peeling off at a re-covering time, and showing a uniform backing paper layer remaining on the wall after removal. <P>SOLUTION: This backing paper for the wall paper is to make the wall paper by installing a decoration layer on its one side surface. The backing paper is characterized by having 5-40 mass% content of a thermoplastic synthetic fiber based on the total of the fibers and also containing a fatty acid amine resin and/or fatty acid amide resin. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は壁紙用裏打ち紙に関する。   The present invention relates to a backing paper for wallpaper.

壁紙は、一般住居、ホテル、病院等において室内の美麗化のために、長期間壁に貼付される。壁紙にはビニル壁紙、オレフィン壁紙、織物壁紙、紙壁紙、無機質壁紙等があるが、これらの壁紙は、ビニル層、オレフィン層、織物層、紙層、無機質層等の化粧層と、該化粧層を保持するための裏打ち紙により構成されている。   The wallpaper is affixed to the wall for a long period of time in order to beautify the room in general houses, hotels, hospitals, and the like. The wallpaper includes a vinyl wallpaper, an olefin wallpaper, a fabric wallpaper, a paper wallpaper, an inorganic wallpaper, and the like. These wallpapers include a decorative layer such as a vinyl layer, an olefin layer, a fabric layer, a paper layer, an inorganic layer, and the decorative layer. It is comprised by the backing paper for hold | maintaining.

これらの壁紙は施工時、澱粉や酢酸ビニル樹脂系の水系の糊によって壁に貼合されるが、糊付け工程で裏打ち紙が糊中の水分を吸収するため、壁紙が柔らかくなったり、裏打ち紙が水分増加により伸びたりすることがある。これらが原因となって、壁紙がカールし、壁への貼付作業が困難になったり、貼付後捲れが発生し易くなったりする等の問題が生じた。更に、糊が乾燥すると裏打ち紙が収縮するために、隣接して貼り合せた壁紙同士の繋ぎ目部分に隙間(目開き)が生じ、施工後の意匠性を損なうなどの問題があった。   These wallpapers are glued to the wall with starch or vinyl acetate resin water-based glue during construction, but the backing paper absorbs moisture in the glue during the gluing process, so the wallpaper becomes soft or the backing paper May increase due to increased moisture. For these reasons, the wallpaper is curled, making it difficult to apply to the wall, and causing problems such as the tendency of wrinkling after application. Furthermore, since the backing paper contracts when the glue dries, there is a problem in that a gap (opening) is generated at the joint portion between the adjacently bonded wallpapers, and the design properties after construction are impaired.

また、長期使用後においては、壁紙の張り替えの作業時に壁紙が剥がし易いことと、剥がした後に壁面に残る裏打ち紙の紙層が均一であることが要求される。壁紙の張り替え作業の多くは人手により行われるため、剥がす時の剥離抵抗が大きいと剥がし難くなり、剥がした跡が不均一に壁に残り、下地の修正にかなりの時間を要することになるので、非効率となる。この様なことから剥がす時の剥離抵抗が低く、裏打ち紙層で均一に剥がせる裏打ち紙が望まれていた。   In addition, after long-term use, it is required that the wallpaper is easily peeled off during the wallpaper replacement work, and that the paper layer of the backing paper remaining on the wall surface after the peeling is uniform. Since most of the wallpaper repainting work is done manually, if the peeling resistance when peeling is large, it will be difficult to remove, and the peeled marks will remain unevenly on the wall, so it will take a considerable amount of time to correct the groundwork. It becomes inefficient. For this reason, there has been a demand for a backing paper that has low peeling resistance when peeled and can be peeled uniformly by the backing paper layer.

裏打ち紙の寸法安定性の改善として、水分による伸縮の少ないガラス繊維等の無機系繊維を配合した裏打ち紙(特許文献1、2、3、4、5)、ポリオレフィン、ポリエステル、ポリアミド等の合成繊維を配合した裏打ち紙(特許文献6、7、8、9、10)が開示されている。
しかしながら、ガラス繊維等の無機繊維は自己接着性が無いため、繊維がシートから脱落しやすく作業性が劣る上、抄造時、壁紙加工時、及び壁紙施工時に、繊維の毛羽立ちが生じる。また、ガラス繊維が剛直であることから、皮膚に接触するとチクチクするような刺激が生じ、人に不快感を与えたりするので、無機繊維を配合した裏打ち紙はあまり普及していない。
特公平7−122236号公報 特開平8−100394号公報 特開平8−325997号公報 特公平8−26631号公報 特許第3252265号公報 特開平5−59696号公報 特開平5−59698号公報 特開平5−59699号公報 特開平8−127999号公報 特開2003−3397号公報
Synthetic fibers such as backing paper (Patent Documents 1, 2, 3, 4, 5), polyolefins, polyesters, polyamides, etc. blended with inorganic fibers such as glass fibers that are less stretched by moisture to improve the dimensional stability of the backing paper (Patent Documents 6, 7, 8, 9, and 10) are disclosed.
However, since inorganic fibers such as glass fibers do not have self-adhesive properties, the fibers tend to fall off the sheet, resulting in poor workability, and fiber fluffing occurs during papermaking, wallpaper processing, and wallpaper construction. In addition, since the glass fiber is rigid, when it comes into contact with the skin, a tingling irritation occurs, which causes discomfort to humans. Therefore, backing paper containing inorganic fibers has not been widely used.
Japanese Examined Patent Publication No. 7-122236 JP-A-8-1000039 JP-A-8-325997 Japanese Patent Publication No. 8-26631 Japanese Patent No. 3252265 JP-A-5-59696 JP-A-5-59698 JP-A-5-59699 JP-A-8-127999 JP 2003-3397 A

また、合成樹脂系繊維は抄紙工程では問題ないが、壁紙は一般的に装飾に使用されるため、製造時に、200℃程度の高温で化粧層の塩化ビニルペースト層やオレフィン樹脂層に発泡加工、エンボス加工等の加熱処理を行うので、合成繊維が軟化、融着し、裏打ち紙の紙層間強度が上昇する結果壁紙の剥離強度が高くなり剥離性が損なわれてしまう。   Synthetic resin fibers are not a problem in the papermaking process, but wallpaper is generally used for decoration. During production, foaming is applied to the vinyl chloride paste layer or olefin resin layer of the decorative layer at a high temperature of about 200 ° C. Since heat treatment such as embossing is performed, the synthetic fibers are softened and fused, and the paper interlayer strength of the backing paper is increased. As a result, the peel strength of the wallpaper is increased and the peelability is impaired.

また、壁紙の張替え時に、裏打ち紙の紙層間で軽く均一に剥がし易くするため、例えば、填料を配合して抄紙した紙匹に、バインダーとして澱粉、あるいはポリビニルアルコールを併用した難燃剤水溶液を塗布して難燃処理を施した、軽剥離性ビニル壁紙裏打ち用難燃紙の製造方法が開示されているが(特許文献11)、本発明は難燃紙のみに制限される上、特定の填料と特定のバインダーの塗布が必須となり、製造上に大きな制約を受ける等の欠点があった。
特開平6−73700号公報
In addition, when changing the wallpaper, in order to make it easy to peel lightly and uniformly between the paper layers of the backing paper, for example, a paper or a paper sheet containing a filler is coated with a flame retardant aqueous solution using starch or polyvinyl alcohol in combination as a binder. A method for producing a flame retardant paper for backing a lightly peelable vinyl wallpaper that has been subjected to flame retardant treatment is disclosed (Patent Document 11). However, the present invention is limited to flame retardant paper and a specific filler and The application of a specific binder is indispensable, and there are drawbacks such as severe restrictions on manufacturing.
JP-A-6-73700

また、無機填料とセルロース繊維を主体とした基紙に難燃剤を含浸させて原紙とし、その片面に無機顔料とバインダーを主成分としてなる塗工層を設けることにより、原紙の内部結合強度を100〜200g/15mmとし、かつ塗工層内部結合強度よりも強い強度を有する壁紙用裏打紙が開示されているが(特許文献12)、この裏打ち紙も難燃紙を基紙として使用することが必須となるだけでなく、難燃紙片面に顔料塗工層を設けるなど、製造上に大きな制約を受ける上、用途も難燃紙のみに限定されるため製品化の分野が限定されるという欠点があった。
特開平7−197399号公報
In addition, a base paper mainly composed of an inorganic filler and cellulose fiber is impregnated with a flame retardant to form a base paper, and an internal bond strength of the base paper is set to 100 by providing a coating layer mainly composed of an inorganic pigment and a binder on one side. Although a backing paper for wallpaper having a strength of ˜200 g / 15 mm and stronger than the internal bond strength of the coating layer has been disclosed (Patent Document 12), it is also possible to use a flame retardant paper as a base paper. Not only is it essential, but there is a major limitation in manufacturing such as providing a pigment coating layer on one side of flame retardant paper, and the use is limited to flame retardant paper, so the field of commercialization is limited was there.
Japanese Unexamined Patent Publication No. 7-197399

従って本発明の目的は、施工時に糊を塗付しても壁紙がカールし難いだけでなく、貼付後においては目開きが生じない上、壁紙の張り替え時には剥がし易く、剥がした後の壁に残る裏打ち紙層が均一となる、壁紙用裏打ち紙を提供することにある。   Therefore, the object of the present invention is not only that the wallpaper is not easily curled even if glue is applied at the time of construction, but also does not cause opening after being applied, and is easy to peel off when the wallpaper is replaced, and remains on the wall after peeling. It is an object of the present invention to provide a wallpaper backing paper having a uniform backing paper layer.

本発明者らは上記目的について鋭意検討した結果、抄紙機で製造される壁紙用裏打ち紙における全繊維分中の合成繊維の比率を特定し、特定の脂肪酸系樹脂を含有させた場合には、壁紙の寸法安定性が良好となると同時に剥離性を改善することができることを見出し、本発明を達成するに至った。
即ち本発明は、片面に化粧層を設けて壁紙とするための壁紙用裏打ち紙であって、前記裏打ち紙が、全繊維分中の熱可塑性合成繊維の含有率が5〜40質量%であると共に、脂肪酸アミン樹脂及び/又は脂肪酸アミド樹脂を含有することを特徴とする壁紙用裏打ち紙、及びそれを用いた壁紙である。
As a result of earnestly examining the above object, the present inventors specify the ratio of synthetic fibers in the total fiber content in the backing paper for wallpaper produced by a paper machine, and when a specific fatty acid resin is contained, It has been found that the dimensional stability of the wallpaper becomes good and the peelability can be improved at the same time, and the present invention has been achieved.
That is, the present invention is a wallpaper backing paper for providing a decorative layer on one side to make a wallpaper, wherein the backing paper has a thermoplastic synthetic fiber content of 5 to 40% by mass in the total fiber content. In addition, a backing paper for wallpaper characterized by containing a fatty acid amine resin and / or a fatty acid amide resin, and wallpaper using the same.

また、本発明の裏打ち紙のステキヒトサイズ度は10秒以上で、かつ加熱後の紙層間強度が20〜40N/mであることが好ましい。更に、裏打ち紙表面には水溶性樹脂バインダー及び/又は水分散性樹脂バインダーを主成分とする塗液を少なくとも片面に塗工することが好ましく、坪量は40〜120g/mであることが好ましい。 In addition, it is preferred that the backing paper of the present invention has a Steecht sizing degree of 10 seconds or more and a paper interlayer strength after heating of 20 to 40 N / m. Furthermore, it is preferable to apply a coating liquid mainly composed of a water-soluble resin binder and / or a water-dispersible resin binder on at least one side of the backing paper surface, and the basis weight is 40 to 120 g / m 2. preferable.

本発明の壁紙用裏打紙は、施工時にカールしないので作業性に優れる上、貼付後に目開きが生じないので見栄えを良くすることができる。また、張り替え時には、軽く均一に裏打ち紙の紙層間で剥がせるので、作業者の労力を低減できる上、効率よく作業することができる。   The backing paper for wallpaper of the present invention is excellent in workability because it is not curled at the time of construction, and can be improved in appearance because no openings are formed after application. In addition, since it can be peeled lightly and evenly between the backing paper layers, the labor of the operator can be reduced and the work can be performed efficiently.

本発明の壁紙用裏打ち紙は、全繊維分中の熱可塑性合成繊維の含有率が5〜40質量%である。このように、水分による伸縮の起こり難い熱可塑性合成繊維を使用することにより、吸水による壁紙のカール及び乾燥後の目開きの発生を防止することができる。熱可塑性合成繊維が5質量%未満であると寸法安定性が十分でなく、カールや目開きが発生し易くなる。また、熱可塑性合成繊維の含有率が40質量%を超えると加熱後の紙層間強度が高くなり剥離性が損なわれる。
更に、自己接着性を有しない合成繊維が増加すると、抄紙時に、ウェットプレスパート、ドライヤーパート、サイズプレスロール、カンバス、キャレンダーロール等、裏打ち紙と直接接触する箇所が、合成繊維の脱落や溶融等のために汚れるので好ましくない。
The backing paper for wallpaper of the present invention has a thermoplastic synthetic fiber content of 5 to 40% by mass in the total fiber content. In this way, by using thermoplastic synthetic fibers that do not easily expand and contract due to moisture, it is possible to prevent the wallpaper from curling due to water absorption and the opening after drying. When the thermoplastic synthetic fiber is less than 5% by mass, the dimensional stability is not sufficient, and curling and opening are likely to occur. Moreover, when the content rate of a thermoplastic synthetic fiber exceeds 40 mass%, the paper interlayer strength after a heating will become high and peelability will be impaired.
Furthermore, when the number of synthetic fibers that do not have self-adhesion increases, the parts that come into direct contact with the backing paper, such as wet press parts, dryer parts, size press rolls, canvases, calendar rolls, etc., fall off or melt during paper making. It is not preferable because it becomes dirty due to the like.

本発明で使用する熱可塑性合成繊維の形態としては、繊維の長さが0.5〜20mmであることが好ましい。0.5mm未満であると抄紙性は良好であるが、裏打ち紙の寸法安定性が低下する。繊維の長さが20mmを超えると、繊維の離解や分散等の調製工程時に、配管、パルプ貯蔵槽、抄紙機ストックインレット、脱水ワイヤー等において、合成繊維同士あるいは合成繊維と木材パルプ繊維が絡まり合ってフロックを形成し易くなり、地合の悪化や断紙が起こり易くなる。   As a form of the thermoplastic synthetic fiber used by this invention, it is preferable that the length of a fiber is 0.5-20 mm. If it is less than 0.5 mm, the paper-making property is good, but the dimensional stability of the backing paper is lowered. If the fiber length exceeds 20 mm, synthetic fibers or synthetic fibers and wood pulp fibers are entangled in piping, pulp storage tank, paper machine stock inlet, dewatering wire, etc. during the preparation process such as fiber disaggregation and dispersion. As a result, it becomes easy to form a flock, and the formation is easily deteriorated and the paper is easily cut.

本発明で使用する熱可塑性合成繊維の具体例としては、ポリエチレン、ポリプロピレン等のポリオレフィン系樹脂繊維、ポリエチレンテレフタレート等のポリエステル系樹脂繊維、ナイロン等のポリアミド系樹脂繊維、ポリアクリルニトリル等のアクリル系樹脂繊維、ポリウレタン系樹脂繊維、ポリ塩化ビニル等の含ハロゲン系樹脂繊維が挙げられる。また、上記熱可塑性合成樹脂を共重合させた合成繊維、又は芯鞘構造、海島構造等を有する、2種以上の異なった熱可塑性合成樹脂を一本の繊維中に含有する複合繊維等も使用することができる。これらの合成繊維は単独で使用しても、複数種類混合して使用してもよい。   Specific examples of the thermoplastic synthetic fiber used in the present invention include polyolefin resin fibers such as polyethylene and polypropylene, polyester resin fibers such as polyethylene terephthalate, polyamide resin fibers such as nylon, and acrylic resins such as polyacrylonitrile. Examples thereof include halogen-containing resin fibers such as fibers, polyurethane-based resin fibers, and polyvinyl chloride. Also used are synthetic fibers copolymerized with the above thermoplastic synthetic resins, or composite fibers containing two or more different thermoplastic synthetic resins in a single fiber having a core-sheath structure, a sea-island structure, etc. can do. These synthetic fibers may be used alone or in combination.

本発明の裏打ち紙に含有させる脂肪酸アミン系樹脂及び/又は脂肪酸アミド系樹脂を含有する。前記樹脂は、通常は裏打ち紙全体にほぼ均一に存在させるが、これに限定されるものではない。上記脂肪酸アミン系樹脂としては、高級脂肪酸とポリアルキレンポリアミンとエピクロルヒドリンとの縮合物の4級アンモニウム塩を用いることが好ましい。上記縮合物の4級アンモニウム塩としては、例えば、高級脂肪酸(炭素数8〜24の脂肪酸、例えば、ステアリン酸、パルミチン酸、ラウリン酸、ベヘン酸)、ポリアルキレンアミン(例えば、ジエチレントリアミン、トリエチレンテトラアミン、ジプロピレントリアミン、トリプロピレンテトラアミン、テトラエチレンペンタアミン、1,1−ジエチルエチレントミアミン、1,1−ジメチルエチレントリアミン、1,1−ジエチルエチレンテトラアミン、1,1−ジメチルプロピレントリアミン)、エピクロルヒドリンから重合された樹脂が例示される。高級脂肪酸、ポリアルキレンアミン、及びエピクロルヒドリンのモル比は、それぞれ(1〜3):1:(0.2〜3)の範囲であることが好ましい。   It contains a fatty acid amine resin and / or a fatty acid amide resin to be contained in the backing paper of the present invention. The resin is usually present almost uniformly throughout the backing paper, but is not limited thereto. As the fatty acid amine resin, a quaternary ammonium salt of a condensate of higher fatty acid, polyalkylene polyamine and epichlorohydrin is preferably used. Examples of the quaternary ammonium salt of the condensate include higher fatty acids (fatty acids having 8 to 24 carbon atoms such as stearic acid, palmitic acid, lauric acid, and behenic acid), polyalkylene amines (for example, diethylenetriamine, triethylenetetramine). Amine, dipropylenetriamine, tripropylenetetraamine, tetraethylenepentamine, 1,1-diethylethylenetomiamine, 1,1-dimethylethylenetriamine, 1,1-diethylethylenetetraamine, 1,1-dimethylpropylenetriamine) And a resin polymerized from epichlorohydrin. The molar ratio of the higher fatty acid, polyalkyleneamine, and epichlorohydrin is preferably in the range of (1-3): 1: (0.2-3), respectively.

本明細書においては、高級脂肪酸とポリアルキレンアミンから重合された化合物(高級脂肪酸・ポリアルキレンアミン)や、高級脂肪酸、ポリアルキレンアミン、及びジカルボン酸の3種から合成された化合物(高級脂肪酸・ポリアミノポリアミド)に存在するアミノ基(−NH、−NH−)を、「活性アミノ基」と称する。高級脂肪酸とポリアルキレンポリアミンとエピクロルヒドリンとの縮合反応においては、高級脂肪酸とポリアルキレンアミンの重合の際に生じた活性アミノ基と、エピクロルヒドリンが反応する。この場合、エピクロルヒドリンの添加量は、活性アミノ基に対して0.2〜3モルであることが好ましい。 In the present specification, a compound polymerized from higher fatty acid and polyalkyleneamine (higher fatty acid / polyalkyleneamine) and a compound synthesized from higher fatty acid, polyalkyleneamine and dicarboxylic acid (higher fatty acid / polyaminoamine). Amino groups (—NH 2 , —NH—) present in the polyamide) are referred to as “active amino groups”. In the condensation reaction of a higher fatty acid, a polyalkylene polyamine, and epichlorohydrin, the active amino group produced during the polymerization of the higher fatty acid and the polyalkylene amine reacts with epichlorohydrin. In this case, it is preferable that the addition amount of epichlorohydrin is 0.2-3 mol with respect to an active amino group.

また、脂肪酸アミド樹脂としては、高級脂肪酸・ポリアミノポリアミド・エピクロルヒドリン縮合物の4級アンモニウム塩を用いることが好ましい。上記縮合物の4級アンモニウム塩としては、例えば、高級脂肪酸(炭素数8〜24の脂肪酸、例えば、ラウリン酸、ステアリン酸、オレイン酸、ベヘニン酸)、ポリアルキレンアミン(例えば、ジエチレントリアミン、トリエチレンテトラアミン、テトラエチレンペンタアミン、イミノビスプロピルアミン)、ジカルボン酸(例えば、蓚酸、マロン酸、コハク酸、マレイン酸、フマル酸、グルタル酸、アジピン酸、ピメリン酸、スベリン酸、アゼライン酸、セバシン酸)、及びエピクロルヒドリンから重合された樹脂が例示される。この場合、ポリアルキレンアミンとジカルボン酸が反応することによってポリアミノポリアミドが生成する。高級脂肪酸、ポリアルキレンアミン、ジカルボン酸のモル比は、それぞれ1:(0.2〜0.3):(0.01〜0.5)の範囲であることが好ましい。また、エピクロルヒドリンは、上記と同様、活性アミノ基に対して0.2〜3モル当量を反応させる量だけ含有させることが好ましい。
本発明で使用する脂肪酸アミン系樹脂及び/又は脂肪酸アミド系樹脂における高級脂肪酸部分の炭素数は、8〜24が好ましい。炭素数が8未満では紙層間強度が高くなり、剥離生が悪化する傾向にある。また、炭素数が24を超えると水に対する分散性、乳化性が低下し、樹脂が分離、沈降する傾向がある。
As the fatty acid amide resin, it is preferable to use a quaternary ammonium salt of a higher fatty acid / polyaminopolyamide / epichlorohydrin condensate. Examples of the quaternary ammonium salt of the condensate include higher fatty acids (fatty acids having 8 to 24 carbon atoms, such as lauric acid, stearic acid, oleic acid, and behenic acid), polyalkylene amines (for example, diethylenetriamine, triethylenetetramine). Amines, tetraethylenepentamine, iminobispropylamine), dicarboxylic acids (eg, succinic acid, malonic acid, succinic acid, maleic acid, fumaric acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid) And a resin polymerized from epichlorohydrin. In this case, a polyaminopolyamide is produced by the reaction between the polyalkyleneamine and the dicarboxylic acid. The molar ratio of the higher fatty acid, polyalkyleneamine, and dicarboxylic acid is preferably in the range of 1: (0.2 to 0.3): (0.01 to 0.5), respectively. Moreover, it is preferable to contain epichlorohydrin only by the quantity which makes 0.2-3 molar equivalent react with an active amino group like the above.
The number of carbon atoms of the higher fatty acid moiety in the fatty acid amine resin and / or fatty acid amide resin used in the present invention is preferably 8-24. When the number of carbon atoms is less than 8, the strength between the paper layers becomes high, and the peel strength tends to deteriorate. Moreover, when carbon number exceeds 24, the dispersibility with respect to water and emulsifying property will fall, and there exists a tendency for resin to isolate | separate and settle.

前記脂肪酸アミン系樹脂及び/又は脂肪酸アミド系樹脂の、壁紙用裏打ち紙の繊維分占める含有率は、絶乾質量当り0.005〜2質量%であることが好ましい。前記樹脂の含有率が0.005質量%未満であると十分な剥離性が得られず、また、含有率が2質量%を超えると、裏打ち紙の強度が低下するので好ましくない。   The content of the fatty acid amine-based resin and / or fatty acid amide-based resin in the fiber content of the backing paper for wallpaper is preferably 0.005 to 2% by mass based on the absolute dry mass. If the content of the resin is less than 0.005% by mass, sufficient peelability cannot be obtained, and if the content exceeds 2% by mass, the strength of the backing paper decreases, which is not preferable.

本発明の壁紙用裏打ち紙はステキヒトサイズ度が10秒以上であることが好ましい。ステキヒトサイズ度が10秒未満であると、澱粉糊や酢酸ビニル等の接着剤が裏打ち紙の紙層中に浸み込み易いので、剥離が重くなる傾向となり好ましくない。ステキヒトサイズ度が10秒以上であれば、糊の紙層への浸み込みを抑制し、剥離性を良好に保つことができる。   The backing paper for wallpaper of the present invention preferably has a Steecht size of 10 seconds or more. If the Steecht sizing degree is less than 10 seconds, an adhesive such as starch paste or vinyl acetate tends to penetrate into the paper layer of the backing paper, which is not preferable because peeling tends to be heavy. If the Steecht sizing degree is 10 seconds or more, the penetration of the glue into the paper layer can be suppressed and the peelability can be kept good.

本発明の裏打ち紙には、通常の紙と同様にサイズ剤を使用する。サイズ剤は内添しても外添してもよい。使用するサイズ剤としては、酸性抄きの場合には、ロジン系サイズ剤、ロジン系エマルジョンサイズ剤、アルファカルボキシルメチル飽和脂肪酸等が挙げられ、中性抄きの場合には、中性抄紙用ロジン系サイズ剤、アルキルケテンダイマー、アルケニル無水コハク酸、カチオンポリマー系サイズ剤等が挙げられる。サイズ剤の添加量は特に限定されるものではなく、ステキヒトサイズ度で10秒以上となればよい。例えば、坪量が60g/mの場合、ロジン系サイズ剤を繊維分に対して0.35質量%以上添加することが好ましい。 A sizing agent is used for the backing paper of the present invention in the same manner as ordinary paper. The sizing agent may be added internally or externally. Examples of sizing agents include rosin sizing agents, rosin emulsion sizing agents, and alpha carboxymethyl saturated fatty acids in the case of acidic papermaking. In the case of neutral papermaking, rosin for neutral papermaking. Examples thereof include sizing agents, alkyl ketene dimers, alkenyl succinic anhydrides, and cationic polymer sizing agents. The addition amount of the sizing agent is not particularly limited, and it may be 10 seconds or more in terms of the Stechit sizing degree. For example, when the basis weight is 60 g / m 2 , it is preferable to add 0.35% by mass or more of the rosin-based sizing agent with respect to the fiber content.

本発明の裏打ち紙の後述する化粧層加熱後における紙層間強度は、20〜40N/mであることが好ましい。20N/m未満では紙層間強度が低すぎるため、壁に貼付した後で裏打ち紙層から捲れが生じ易くなるので好ましくない。また、40N/mを超えると紙層間強度が強くなりすぎて、壁から剥がしにくくなること、上層の塩化ビニル層等の化粧層がきれ易くなること等により作業効率が低下するので好ましくない。   It is preferable that the paper interlayer strength of the backing paper of the present invention after heating a decorative layer described later is 20 to 40 N / m. If it is less than 20 N / m, the strength between the paper layers is too low. On the other hand, if it exceeds 40 N / m, the strength between the paper layers becomes too strong, and it is difficult to peel off from the wall, and the decorative layer such as the upper vinyl chloride layer can be easily removed.

本発明は裏打ち紙の表面強度を高めて毛羽立ちを防ぐため、水溶性バインダー及び/又は水分散性樹脂バインダーを主成分とする塗液を、少なくとも化粧層側の表面に塗工することが好ましい。例えば、ビニル壁紙を製造する場合には、裏打ち紙の表面に塩化ビニルペーストを塗布し、塩化ビニルペーストの硬化後、印刷工程に付されて塩化ビニル層が化粧層となる。この場合、裏打ち紙の表面強度が低いと、前記塗工時に紙表面の繊維が毛羽立ち、硬化後に前記毛羽立ち部が壁紙表面で突起状となって印刷不良の原因となる。   In the present invention, in order to increase the surface strength of the backing paper and prevent fluffing, it is preferable to apply at least the surface of the decorative layer side with a coating liquid mainly composed of a water-soluble binder and / or a water-dispersible resin binder. For example, when producing vinyl wallpaper, a vinyl chloride paste is applied to the surface of the backing paper, and after the vinyl chloride paste is cured, it is subjected to a printing process so that the vinyl chloride layer becomes a decorative layer. In this case, if the surface strength of the backing paper is low, the fibers on the paper surface fluff during the coating, and the fluffed portion protrudes on the surface of the wallpaper after curing, causing printing failure.

水溶性バインダーとしては、酸化デンプン及び酵素変成デンプン等の各種変性デンプン、ポリビニルアルコール、カルボキシルメチルセルロース、カゼイン等を適宜使用することができる。
水分散性バインダーとしては、スチレン・ブタジエン共重合体ラテックス、メチルメタアクリレート・ブタジエン共重体ラテックス、アクリル系エマルジョン、酢酸ビニル系エマルジョン等を適宜使用することができる。
この場合、バインダー単独で使用してもよいが、クレー、カオリン、炭酸カルシウム、ニ酸化チタン等の各種顔料と混合して使用することもできる。
バインダーの塗工量は、固形分で0.2〜10g/mとすることが好ましい。0.2g/m未満であると繊維の毛羽立ちが多くなる。また、10g/mを超えるとバインダー層で繊維が全て覆われるので、塩化ビニルペーストと紙層との間でアンカー効果がなくなり、壁から剥がす時に裏打ち紙が紙層間で剥れ難くなる。
As the water-soluble binder, various modified starches such as oxidized starch and enzyme-modified starch, polyvinyl alcohol, carboxymethyl cellulose, casein and the like can be used as appropriate.
As the water-dispersible binder, styrene / butadiene copolymer latex, methyl methacrylate / butadiene copolymer latex, acrylic emulsion, vinyl acetate emulsion and the like can be appropriately used.
In this case, the binder may be used alone, but may be used by mixing with various pigments such as clay, kaolin, calcium carbonate and titanium dioxide.
The coating amount of the binder is preferably 0.2 to 10 g / m 2 in terms of solid content. When the amount is less than 0.2 g / m 2 , the fiber fuzz increases. Further, if it exceeds 10 g / m 2 , all the fibers are covered with the binder layer, so that the anchor effect is lost between the vinyl chloride paste and the paper layer, and the backing paper is difficult to peel off between the paper layers when peeled from the wall.

本発明の裏打ち紙の坪量は、40g/m以上120g/m以下であることが好ましい。坪量が40g/m未満であると強度が低いので、加工時に断紙が発生し易くなる。また、坪量が120g/mを超えると、壁紙に加工した時に硬くなりすぎて施工が困難となる傾向となる。 The basis weight of the backing paper of the present invention is preferably 40 g / m 2 or more and 120 g / m 2 or less. If the basis weight is less than 40 g / m 2 , the strength is low, so that paper breakage is likely to occur during processing. On the other hand, if the basis weight exceeds 120 g / m 2 , it tends to be too hard when processed into wallpaper, making construction difficult.

本発明の裏打ち紙に使用する、前記熱可塑性合成繊維以外の繊維成分としては、針葉樹、広葉樹の化学パルプ、機械パルプ、及び古紙から得られる再生パルプ等の木材系パルプ、靭皮パルプ、リンターパルプ、麻パルプ等の非木材系パルプ等の、天然パルプを使用することができるが、品質やコストの面から木材パルプを使用することが好ましい。
また、品質に影響のない範囲で、定着剤、乾紙紙力剤、湿潤紙力剤、填料、歩留り向上剤、染料、顔料等を内添薬品として使用することができる。さらにサイズプレス等で塗工あるいは含浸させる外添薬品として、表面紙力剤、染料、顔料等を使用することができる。
Examples of fiber components other than the thermoplastic synthetic fibers used in the backing paper of the present invention include soft pulp, hardwood chemical pulp, mechanical pulp, and wood pulp such as recycled pulp obtained from waste paper, bast pulp, linter pulp Natural pulp such as non-wood pulp such as hemp pulp can be used, but wood pulp is preferably used in terms of quality and cost.
Further, fixing agents, dry paper strength agents, wet paper strength agents, fillers, yield improvers, dyes, pigments and the like can be used as internal additives as long as the quality is not affected. Furthermore, surface paper strength agents, dyes, pigments and the like can be used as external chemicals to be applied or impregnated with a size press or the like.

本発明の壁紙は、本発明の裏打ち紙の上層に化粧層を設けることにより得られる。例えば、化粧層としてビニル層を設けたビニル壁紙、オレフィン層を設けたオレフィン壁紙、織物層を設けた織物壁紙、紙層を設けた紙壁紙、無機質層を設けた無機質壁紙等が挙げられる。何れの場合にも、化粧層となる樹脂層を設けた後必要に応じて印刷すると共に、200℃程度に加熱して発泡加工やエンボス加工を行って化粧層とする。   The wallpaper of the present invention can be obtained by providing a decorative layer on the upper layer of the backing paper of the present invention. For example, a vinyl wallpaper provided with a vinyl layer as a decorative layer, an olefin wallpaper provided with an olefin layer, a woven wallpaper provided with a fabric layer, a paper wallpaper provided with a paper layer, an inorganic wallpaper provided with an inorganic layer, and the like. In any case, after providing a resin layer as a decorative layer, printing is performed as necessary, and heating to about 200 ° C. is performed to perform foaming or embossing to obtain a decorative layer.

以下、本発明を実施例によって更に説明するが、本発明はこれによって限定されるものではない。
各実施例及び比較例により得られた壁紙用裏打ち紙について、以下の方法により特性試験を行った。結果をまとめて表1に示す。
EXAMPLES Hereinafter, although an Example demonstrates this invention further, this invention is not limited by this.
About the backing paper for wallpaper obtained by each Example and the comparative example, the characteristic test was done with the following method. The results are summarized in Table 1.

1.水伸び:試験片を23℃、50%R/H雰囲気で調湿し、試験片の抄紙横方向の長さを測定した。試験片を純水に浸漬し、1時間放置した後取り出し、取り出し直後の横方向の長さを測定した。水伸び(%)を以下の式により求めた。
水伸び(%):(水浸漬後長さ−水浸漬前長さ)/水浸漬前長さ×100
2.紙層間強度
(1)常態:23℃、50%R/Hの雰囲気で裏打ち紙両面にセロハンテープを貼り、抄紙方向に15mm幅に切断して試験片とした。測定時に紙層間で剥離するようにカッターで紙層間に切れ目を入れ、JIS P 8113に準じて90度の角度で引張り強さを測定した。
(2)加熱後:試験片を送風乾燥機内において170℃で2分間加熱処理し、その後常態と同様に測定した。
3.ステキヒトサイズ度:JIS P 8122に従った。
1. Water elongation: The test piece was conditioned at 23 ° C. and 50% R / H atmosphere, and the length of the test piece in the horizontal direction of papermaking was measured. The test piece was immersed in pure water, left for 1 hour, then taken out, and the lateral length immediately after taking out was measured. The water elongation (%) was determined by the following formula.
Water elongation (%): (length after water immersion-length before water immersion) / length before water immersion x 100
2. Interlaminar strength of paper (1) Normal state: Cellophane tape was applied to both sides of the backing paper in an atmosphere of 23 ° C. and 50% R / H, and cut into a 15 mm width in the papermaking direction to obtain a test piece. A cut was made between the paper layers with a cutter so as to peel between the paper layers at the time of measurement, and the tensile strength was measured at an angle of 90 degrees according to JIS P8113.
(2) After heating: The test piece was heat-treated at 170 ° C. for 2 minutes in a blow dryer, and then measured in the same manner as in the normal state.
3. Steffith sizing: according to JIS P 8122.

4.施工性、寸法安定性及び剥離性
裏打ち紙の表面に塩化ビニル系樹脂、可塑剤(フタル酸エステル)、炭酸カルシウム、二酸化チタン、ミネラルスピリット等からなる塩化ビニルペーストを、塗工厚が250μmとなるように塗布し、180℃で2分間加熱してゲル化させた。得られたビニル壁紙を、長さ1mで幅95cmにカットして試料とした。
(1)施工性
試料を2枚用意し、裏打ち紙面に、澱粉系のヤヨイ化学製A糊を塗布し、幅2m、長さ1mのベニア板に2枚の壁紙の端が重なるように貼り付け、重なった部分をカッターでカットして繋ぎ目が見えないようした。この作業において、壁紙にカールが発生したか否かにより評価した。
評価
○:カール無し
×:カール有り
(2)寸法安定性
施工後、23℃、50%R/Hの雰囲気で7日間放置して完全に乾燥し、乾燥後の繋ぎ目の箇所に目開きが発生したか否かにより評価した。
評価
○:目開き無し
×:目開き有り
(3)剥離性
壁紙をベニア板から剥がした時の剥がし易さ、及びベニア板に残った裏打ち紙の外観を観察した。
評価
○:剥がしが軽く、均一に剥れる
×:剥がしが重く、均一に剥れない
4). Workability, dimensional stability, and peelability A vinyl chloride paste made of vinyl chloride resin, plasticizer (phthalate ester), calcium carbonate, titanium dioxide, mineral spirit, etc. is applied to the surface of the backing paper to a coating thickness of 250 μm. It was made to gel by heating at 180 ° C. for 2 minutes. The obtained vinyl wallpaper was cut into a length of 1 m and a width of 95 cm to prepare a sample.
(1) Workability Prepare two samples, apply starch-based Yayoi Chemical's A glue on the backing paper, and paste it on a 2m wide and 1m long veneer so that the edges of the two sheets of paper overlap. The overlapping part was cut with a cutter so that the joints could not be seen. In this work, the evaluation was made based on whether or not the wallpaper was curled.
Evaluation
○: No curling ×: Curling (2) Dimensional stability After construction, leave for 7 days in an atmosphere of 23 ° C and 50% R / H for complete drying. Opening occurs at the joints after drying. It was evaluated by whether or not.
Evaluation
○: No opening X: Opening (3) Peelability The ease of peeling when the wallpaper was peeled from the veneer board and the appearance of the backing paper remaining on the veneer board were observed.
Evaluation
○: Light peeling and uniform peeling ×: Heavy peeling and not uniform peeling

晒クラフトパルプのNBKP(カナダ標準ろ水度(CSF)500ml)を55質量%、LBKP(CSF500ml)を30質量%、繊維長5mmの芯鞘繊維(商品名:N−701S、芯:ポリエステル繊維、鞘:ポリエチレン、(株)クラレ製)を15質量%配合したパルプスラリー中に、pHが4.5になるように硫酸バンドを添加した後、サイズ剤としてアルファカルボキシメチル飽和脂肪酸塩(商品名:NSP−S、星光PMC(株)製)を0.15質量%添加した。更に湿潤紙力剤としてポリアミド・エピクロルヒドリン樹脂(商品名:WS−547、星光PMC(株)製)を0.2質量%添加し、次に脂肪酸アミン系樹脂(商品名:N−815、星光PMC(株)製)を0.3質量%添加した。
得られた混合物を使用し、長網抄紙機を用いて抄紙した。なお、工程途中のサイズプレスで、1.5質量%のポリビニルアルコール(商品名:ポバール117、(株)クラレ製)を塗工した。
Bleached kraft pulp NBKP (Canadian standard freeness (CSF) 500 ml) 55% by mass, LBKP (CSF 500 ml) 30% by mass, fiber length 5 mm core sheath fiber (trade name: N-701S, core: polyester fiber, After adding a sulfuric acid band so that pH becomes 4.5 in the pulp slurry which mix | blended 15 mass% of scabbard: Polyethylene and Kuraray Co., Ltd., alpha carboxymethyl saturated fatty acid salt (brand name: 0.15% by mass of NSP-S (manufactured by Seiko PMC) was added. Furthermore, 0.2% by mass of polyamide / epichlorohydrin resin (trade name: WS-547, manufactured by Seiko PMC Co., Ltd.) was added as a wet paper strength agent, and then fatty acid amine resin (trade name: N-815, Seiko PMC). 0.3% by mass) was added.
The obtained mixture was used for paper making using a long paper machine. In addition, 1.5% by mass of polyvinyl alcohol (trade name: Poval 117, manufactured by Kuraray Co., Ltd.) was applied with a size press in the middle of the process.

成紙した裏打ち紙の坪量は65g/m、水伸びは0.5%、紙層間強度は常態が20N/m、加熱後が35N/m、サイズ度は35秒であった。この裏打ち紙に塩化ビニルペーストを塗工した後、180℃で2分間加熱して壁紙とし、この壁紙の施工性、剥離性を評価した。 The basis weight of the formed backing paper was 65 g / m 2 , the water elongation was 0.5%, the paper interlayer strength was 20 N / m in the normal state, 35 N / m after heating, and the sizing degree was 35 seconds. A vinyl chloride paste was applied to the backing paper, and then heated at 180 ° C. for 2 minutes to make a wallpaper. The workability and peelability of this wallpaper were evaluated.

脂肪酸アミン系樹脂N−815の添加量を0.6質量%にしたこと以外は、実施例1と同様にして裏打ち紙を作製し、評価を行った。成紙した裏打ち紙の坪量は65g/m、水伸びは0.48%、紙層間強度は常態が15N/m、加熱後が28N/m、サイズ度は42秒であった。 A backing paper was prepared and evaluated in the same manner as in Example 1 except that the amount of fatty acid amine-based resin N-815 added was 0.6% by mass. The basis weight of the formed backing paper was 65 g / m 2 , the water elongation was 0.48%, the paper interlayer strength was 15 N / m in the normal state, 28 N / m after heating, and the sizing degree was 42 seconds.

脂肪酸アミン系樹脂のN−815の添加量を1.5質量%にしたこと以外は、実施例1と同様にして裏打ち紙を作製し、評価を行った。成紙した裏打ち紙の坪量は65g/m、水伸びは0.45%、紙層間強度は常態が10N/m、加熱後が44N/m、サイズ度は45秒であった。 A backing paper was prepared and evaluated in the same manner as in Example 1 except that the amount of N-815 added to the fatty acid amine resin was 1.5% by mass. The basis weight of the formed backing paper was 65 g / m 2 , the water elongation was 0.45%, the paper interlayer strength was 10 N / m in the normal state, 44 N / m after heating, and the sizing degree was 45 seconds.

木材パルプの配合比は変えずに、芯鞘繊維を8質量%配合したこと以外は、実施例1と同様にして裏打ち紙を作製し、評価を行った。成紙した裏打ち紙の坪量は65g/m、水伸びは0.75%、紙層間強度は常態が20N/m、加熱後が30N/m、サイズ度は40秒であった。 A backing paper was prepared and evaluated in the same manner as in Example 1 except that 8% by mass of the core-sheath fiber was blended without changing the blending ratio of the wood pulp. The basis weight of the printed backing paper was 65 g / m 2 , the water elongation was 0.75%, the paper interlayer strength was 20 N / m in the normal state, 30 N / m after heating, and the sizing degree was 40 seconds.

木材パルプの配合比は変えずに、芯鞘繊維を30質量%配合したこと以外は、実施例1と同様にして裏打ち紙を作製し、評価を行った。成紙した裏打ち紙の坪量は65g/m、水伸びは0.25%、紙層間強度は常態が10N/m、加熱後が35N/m、サイズ度は47秒であった。 A backing paper was prepared and evaluated in the same manner as in Example 1 except that 30% by mass of the core-sheath fiber was blended without changing the blending ratio of the wood pulp. The basis weight of the formed backing paper was 65 g / m 2 , the water elongation was 0.25%, the paper interlayer strength was 10 N / m in the normal state, 35 N / m after heating, and the sizing degree was 47 seconds.

木材パルプの配合比は変えずに、芯鞘繊維を30質量%配合したこと以外は、実施例1と同様にして裏打ち紙を作製し、評価を行った。成紙した裏打ち紙の坪量は65g/m、水伸びは0.25%、紙層間強度は常態が10N/m、加熱後が35N/m、サイズ度は47秒であった。 A backing paper was prepared and evaluated in the same manner as in Example 1 except that 30% by mass of the core-sheath fiber was blended without changing the blending ratio of the wood pulp. Narushi and basis weight of the paper backing had a 65 g / m 2, water elongation of 0.25%, the paper internal bond strength is normal is 10 N / m, the post-heating 35N / m, sizing degree was 47 seconds.

[比較例1]
合成繊維と脂肪酸アミン系樹脂N−815を配合しなかった以外は、実施例1と同様にして裏打ち紙を作製し、評価を行った。結果をまとめて表に示す。成紙した裏打ち紙の坪量は65g/m、水伸びは2.10%、紙層間強度は常態が45N/m、加熱後が50N/m、サイズ度は28秒であった。
[Comparative Example 1]
A backing paper was prepared and evaluated in the same manner as in Example 1 except that the synthetic fiber and the fatty acid amine resin N-815 were not blended. The results are summarized in the table. The basis weight of the formed backing paper was 65 g / m 2 , the water elongation was 2.10%, the paper interlayer strength was 45 N / m in the normal state, 50 N / m after heating, and the sizing degree was 28 seconds.

[比較例2]
脂肪酸アミン系樹脂のN−815を配合しなかった以外は、実施例1と同様にして裏打ち紙を作製し、評価を行った。成紙した裏打ち紙の坪量は65g/m、水伸びは0.55%、紙層間強度は常態が32N/m、加熱後が65N/m、サイズ度は25秒であった。
[Comparative Example 2]
A backing paper was prepared and evaluated in the same manner as in Example 1 except that N-815 of a fatty acid amine resin was not blended. The basis weight of the formed backing paper was 65 g / m 2 , the water elongation was 0.55%, the paper interlayer strength was 32 N / m in the normal state, 65 N / m after heating, and the sizing degree was 25 seconds.

[比較例3]
芯鞘繊維を無配合とし、NBKPを65質量%、LBKPを35質量%としたこと以外は、実施例1と同様にして裏打ち紙を作製し、評価を行った。成紙した裏打ち紙の坪量は65g/m、水伸びは2.50%、紙層間強度は常態が32N/m、加熱後が65N/m、サイズ度は25秒であった。
[Comparative Example 3]
A backing paper was prepared and evaluated in the same manner as in Example 1 except that the core-sheath fiber was not blended, NBKP was 65% by mass, and LBKP was 35% by mass. The basis weight of the formed backing paper was 65 g / m 2 , the water elongation was 2.50%, the paper interlayer strength was 32 N / m in the normal state, 65 N / m after heating, and the sizing degree was 25 seconds.

[比較例4]
脂肪酸アミン系樹脂の添加量N−815をペンタエリスリトール脂肪酸エステル(商品名:KB115、花王(株)製)に変更したこと以外は、実施例1と同様にして裏打ち紙を作製し、評価を行った。成紙した裏打ち紙の坪量は65g/m、水伸びは0.50%、紙層間強度は常態が16N/m、加熱後が30N/m、サイズ度は5秒であった。
[Comparative Example 4]
A backing paper was prepared and evaluated in the same manner as in Example 1 except that the addition amount N-815 of the fatty acid amine-based resin was changed to pentaerythritol fatty acid ester (trade name: KB115, manufactured by Kao Corporation). It was. The basis weight of the formed backing paper was 65 g / m 2 , the water elongation was 0.50%, the paper interlayer strength was 16 N / m in the normal state, 30 N / m after heating, and the sizing degree was 5 seconds.

[比較例5]
芯鞘繊維の配合量を50%、NBKPの配合量を33質量%、LBKPの配合量を17質量%としたこと以外は、実施例1と同様にして裏打ち紙を作製し、評価を行った。成紙した裏打ち紙の坪量は65g/m、水伸びは0.20%、紙層間強度は常態が12N/m、加熱後が80N/m、サイズ度は50秒であった。
[Comparative Example 5]
A backing paper was prepared and evaluated in the same manner as in Example 1 except that the amount of the core-sheath fiber was 50%, the amount of NBKP was 33% by mass, and the amount of LBKP was 17% by mass. . The basis weight of the formed backing paper was 65 g / m 2 , the water elongation was 0.20%, the paper interlayer strength was 12 N / m in the normal state, 80 N / m after heating, and the sizing degree was 50 seconds.

NBKP(CSF500ml)20質量%とLBKP(CSF500ml)30質量%、サーモメカニカルパルプ(CSF250ml)20質量%、ポリエチレン樹脂系の分岐型合成繊維のSWP(商品名:E−400、三井化学(株)製)を30質量%のパルプ配合とし、更に脂肪酸アミド系樹脂(商品名:PT−205、星光PMC(株)製)を0.6質量%配合したこと以外は、実施例1と同様にして裏打ち紙を作製し、評価を行った。成紙した裏打ち紙の坪量は65g/m、水伸びは0.78%、紙層間強度は常態が16N/m、加熱後が32N/m、サイズ度は40秒であった。 NBKP (CSF 500 ml) 20 mass%, LBKP (CSF 500 ml) 30 mass%, thermomechanical pulp (CSF 250 ml) 20 mass%, polyethylene resin-based branched synthetic fiber SWP (trade name: E-400, manufactured by Mitsui Chemicals, Inc.) ) With 30% by mass of pulp, and further with 0.6% by mass of fatty acid amide resin (trade name: PT-205, manufactured by Seiko PMC Co., Ltd.). Paper was prepared and evaluated. The basis weight of the formed backing paper was 65 g / m 2 , the water elongation was 0.78%, the paper interlayer strength was 16 N / m in the normal state, 32 N / m after heating, and the sizing degree was 40 seconds.

[比較例6]
合成繊維を無配合、NBKPの配合量を29質量%、LBKPの配合量を42質量%、TMPの配合量を29質量%としたこと以外は、実施例1と同様にして裏打ち紙を作製し、評価を行った。成紙した裏打ち紙の坪量は65g/m、水伸びは2.30%、紙層間強度は常態が48N/m、加熱後が50N/m、サイズ度は35秒であった。
[Comparative Example 6]
A backing paper was prepared in the same manner as in Example 1 except that no synthetic fiber was used, NBKP was used in an amount of 29 mass%, LBKP was used in an amount of 42 mass%, and TMP was used in an amount of 29 mass%. And evaluated. The basis weight of the formed backing paper was 65 g / m 2 , the water elongation was 2.30%, the paper interlayer strength was 48 N / m in the normal state, 50 N / m after heating, and the sizing degree was 35 seconds.

[比較例7]
脂肪酸アミド系樹脂(商品名:PT−205、星光PMC(株)製)を無添加としたこと以外は、実施例1と同様にして裏打ち紙を作製し、評価を行った。成紙した裏打ち紙の坪量は65g/m、水伸びは0.76%、紙層間強度は常態が22N/m、加熱後が60N/m、サイズ度は45秒であった。
[Comparative Example 7]
A backing paper was prepared and evaluated in the same manner as in Example 1 except that no fatty acid amide resin (trade name: PT-205, manufactured by Seiko PMC Co., Ltd.) was added. The basis weight of the printed backing paper was 65 g / m 2 , the water elongation was 0.76%, the paper interlayer strength was 22 N / m in the normal state, 60 N / m after heating, and the sizing degree was 45 seconds.

[比較例8]
合成繊維SWP E−400を無配合とし、NBKPの配合量を29質量%、LBKPの配合量を42質量%、TMPの配合量を29質量%としたこと以外は、実施例1と同様にして裏打ち紙を作製し、評価を行った。成紙した裏打ち紙の坪量は65g/m、水伸びは2.10%、紙層間強度は常態が25N/m、加熱後が30N/m、サイズ度は45秒であった。
[Comparative Example 8]
Except that the synthetic fiber SWP E-400 was not blended, the blending amount of NBKP was 29 mass%, the blending amount of LBKP was 42 mass%, and the blending amount of TMP was 29 mass%, the same as in Example 1. A backing paper was prepared and evaluated. The basis weight of the formed backing paper was 65 g / m 2 , the water elongation was 2.10%, the paper interlayer strength was 25 N / m in the normal state, 30 N / m after heating, and the sizing degree was 45 seconds.

表1に示されるように、合成繊維、及び脂肪酸アミン系樹脂を含有する実施例1〜7の裏打ち紙は、施工時にカール及び目開き等の発生がなく良好であった。更に、剥離性についても、紙層間で均一に軽く剥れ、良好な結果であった。これに対して、合成繊維、及び脂肪酸アミン系樹脂を含有しない比較例1〜5の裏打ち紙は、カール及び目開きの防止と剥離性を両立することができなかった。   As shown in Table 1, the backing papers of Examples 1 to 7 containing a synthetic fiber and a fatty acid amine-based resin were good without curling and opening during construction. In addition, the peelability was also light and uniform between the paper layers, which was a good result. On the other hand, the backing papers of Comparative Examples 1 to 5 containing no synthetic fiber and fatty acid amine-based resin were unable to achieve both curling and opening prevention and peelability.

本発明の裏打ち紙の上層にビニル層、オレフィン層、織物層、紙層、無機質層等の化粧層を設けて得られた壁紙は、長期間、壁に貼付しておくことができるので、一般住居、ホテル、病院等において室内の美麗化のために利用する価値がある。
Since the wallpaper obtained by providing a decorative layer such as a vinyl layer, an olefin layer, a fabric layer, a paper layer, an inorganic layer on the upper layer of the backing paper of the present invention can be affixed to the wall for a long time, It is worth using for the beautiful interior in residences, hotels, hospitals, etc.

Claims (5)

片面に化粧層を設けて壁紙とするための壁紙用裏打ち紙であって、前記裏打ち紙が、全繊維分中の熱可塑性合成繊維の含有率が5〜40質量%であると共に、脂肪酸アミン樹脂及び/又は脂肪酸アミド樹脂を含有することを特徴とする壁紙用裏打ち紙。   A wallpaper backing paper for providing a decorative layer on one side as a wallpaper, wherein the backing paper has a thermoplastic synthetic fiber content of 5 to 40 mass% in the total fiber content, and a fatty acid amine resin And / or a wallpaper backing paper characterized by containing a fatty acid amide resin. ステキヒトサイズ度が10秒以上で、かつ加熱後の紙層間強度が20〜40N/mである請求項1に記載された壁紙用裏打ち紙。   The backing paper for wallpaper according to claim 1, wherein the sizing degree is 10 seconds or more, and the strength between paper layers after heating is 20 to 40 N / m. 水溶性樹脂バインダー及び/又は水分散性樹脂バインダーを含有する塗工液が少なくとも片面に塗布されている、請求項1又は2に記載された壁紙用裏打ち紙。   The backing paper for wallpaper according to claim 1 or 2, wherein a coating liquid containing a water-soluble resin binder and / or a water-dispersible resin binder is applied on at least one side. 坪量が40g/m以上120g/m以下である、請求項1〜3の何れかに記載された壁紙用裏打ち紙。 Basis weight of 40 g / m 2 or more 120 g / m 2 or less, wallpaper backing paper according to any of claims 1 to 3. 請求項1〜4の何れかに記載された壁紙用裏打ち紙表面に化粧層を設けてなることを特徴とする壁紙。
A wallpaper comprising a decorative layer on the surface of the backing paper for wallpaper according to any one of claims 1 to 4.
JP2005265227A 2005-09-13 2005-09-13 Wallpaper backing paper Expired - Fee Related JP4766968B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2005265227A JP4766968B2 (en) 2005-09-13 2005-09-13 Wallpaper backing paper

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2005265227A JP4766968B2 (en) 2005-09-13 2005-09-13 Wallpaper backing paper

Publications (2)

Publication Number Publication Date
JP2007077526A true JP2007077526A (en) 2007-03-29
JP4766968B2 JP4766968B2 (en) 2011-09-07

Family

ID=37938121

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2005265227A Expired - Fee Related JP4766968B2 (en) 2005-09-13 2005-09-13 Wallpaper backing paper

Country Status (1)

Country Link
JP (1) JP4766968B2 (en)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008261069A (en) * 2007-04-11 2008-10-30 Dainippon Printing Co Ltd Foamed wall paper
JP2009019293A (en) * 2007-07-10 2009-01-29 Asahipen Corp Adhesive wallpaper
JP2009194341A (en) * 2008-02-18 2009-08-27 Hokuetsu Paper Mills Ltd Electromagnetic wave suppressing paper
JP2009242982A (en) * 2008-03-31 2009-10-22 Nippon Paper Industries Co Ltd Backing paper for wallpaper
JP2009263852A (en) * 2008-03-31 2009-11-12 Nippon Paper Industries Co Ltd Backing paper for wallpaper
JP2010116631A (en) * 2008-11-11 2010-05-27 Okamoto Ind Inc Wallpaper
JP5455102B1 (en) * 2012-12-03 2014-03-26 星光Pmc株式会社 Paperboard manufacturing method
WO2014087550A1 (en) * 2012-12-03 2014-06-12 星光Pmc株式会社 Method for manufacturing paperboard
JP2015066898A (en) * 2013-09-30 2015-04-13 大日本印刷株式会社 Laminated sheet and foamed laminated sheet
JP2015180784A (en) * 2014-03-03 2015-10-15 王子ホールディングス株式会社 backing paper for wallpaper
JP2016132846A (en) * 2015-01-22 2016-07-25 三菱製紙株式会社 Nonwoven fabric for wall paper lining
JP2016141922A (en) * 2015-02-05 2016-08-08 三菱製紙株式会社 Wall paper-backing nonwoven fabric
JP2016151066A (en) * 2015-02-16 2016-08-22 王子ホールディングス株式会社 Backing paper for wallpaper

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7336827B2 (en) * 2017-03-02 2023-09-01 凸版印刷株式会社 wallpaper

Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04361699A (en) * 1991-06-04 1992-12-15 Oji Paper Co Ltd Production of flameproof paper for backing of vinyl wallpaper
JPH0559696A (en) * 1991-08-30 1993-03-09 Oji Paper Co Ltd Production of flame-retardant paper for backing polyvinyl chloride-based wall paper
JPH08325997A (en) * 1995-06-02 1996-12-10 New Oji Paper Co Ltd Inorganic paper for lining non-vinyl chloride wall paper
JP2000273792A (en) * 1999-03-25 2000-10-03 Nicca Chemical Co Ltd Opacifying agent for paper, production of opacity- improving paper and opacity-improving paper
JP3252265B2 (en) * 1993-03-09 2002-02-04 新富士製紙株式会社 Flame retardant wallpaper, manufacturing method of fusuma paper
JP2003003397A (en) * 2001-06-22 2003-01-08 Komei Seishi Kk Two-layered foamed paper and method for producing the same
JP2003013397A (en) * 2001-06-26 2003-01-15 Lintec Corp Body paper for wallpaper
JP2004124270A (en) * 2002-09-30 2004-04-22 Nippon Paper Industries Co Ltd Paper for wallpaper
JP2004169219A (en) * 2002-11-20 2004-06-17 Kuraray Co Ltd Wall paper
JP2004292990A (en) * 2003-03-27 2004-10-21 Nippon Paper Industries Co Ltd Wallpaper
JP2005023501A (en) * 2003-07-03 2005-01-27 Nippon Paper Industries Co Ltd Upper layer paper of wallpaper
JP2005029920A (en) * 2003-07-11 2005-02-03 Kohjin Co Ltd Decorative sheet
JP2005082894A (en) * 2003-09-04 2005-03-31 Nippon Paper Industries Co Ltd Wallpaper
JP2005314861A (en) * 2004-03-30 2005-11-10 Nippon Paper Industries Co Ltd Backing paper for wall paper

Patent Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04361699A (en) * 1991-06-04 1992-12-15 Oji Paper Co Ltd Production of flameproof paper for backing of vinyl wallpaper
JPH0559696A (en) * 1991-08-30 1993-03-09 Oji Paper Co Ltd Production of flame-retardant paper for backing polyvinyl chloride-based wall paper
JP3252265B2 (en) * 1993-03-09 2002-02-04 新富士製紙株式会社 Flame retardant wallpaper, manufacturing method of fusuma paper
JPH08325997A (en) * 1995-06-02 1996-12-10 New Oji Paper Co Ltd Inorganic paper for lining non-vinyl chloride wall paper
JP2000273792A (en) * 1999-03-25 2000-10-03 Nicca Chemical Co Ltd Opacifying agent for paper, production of opacity- improving paper and opacity-improving paper
JP2003003397A (en) * 2001-06-22 2003-01-08 Komei Seishi Kk Two-layered foamed paper and method for producing the same
JP2003013397A (en) * 2001-06-26 2003-01-15 Lintec Corp Body paper for wallpaper
JP2004124270A (en) * 2002-09-30 2004-04-22 Nippon Paper Industries Co Ltd Paper for wallpaper
JP2004169219A (en) * 2002-11-20 2004-06-17 Kuraray Co Ltd Wall paper
JP2004292990A (en) * 2003-03-27 2004-10-21 Nippon Paper Industries Co Ltd Wallpaper
JP2005023501A (en) * 2003-07-03 2005-01-27 Nippon Paper Industries Co Ltd Upper layer paper of wallpaper
JP2005029920A (en) * 2003-07-11 2005-02-03 Kohjin Co Ltd Decorative sheet
JP2005082894A (en) * 2003-09-04 2005-03-31 Nippon Paper Industries Co Ltd Wallpaper
JP2005314861A (en) * 2004-03-30 2005-11-10 Nippon Paper Industries Co Ltd Backing paper for wall paper

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008261069A (en) * 2007-04-11 2008-10-30 Dainippon Printing Co Ltd Foamed wall paper
JP2009019293A (en) * 2007-07-10 2009-01-29 Asahipen Corp Adhesive wallpaper
JP2009194341A (en) * 2008-02-18 2009-08-27 Hokuetsu Paper Mills Ltd Electromagnetic wave suppressing paper
JP2009242982A (en) * 2008-03-31 2009-10-22 Nippon Paper Industries Co Ltd Backing paper for wallpaper
JP2009263852A (en) * 2008-03-31 2009-11-12 Nippon Paper Industries Co Ltd Backing paper for wallpaper
JP2010116631A (en) * 2008-11-11 2010-05-27 Okamoto Ind Inc Wallpaper
JP5455102B1 (en) * 2012-12-03 2014-03-26 星光Pmc株式会社 Paperboard manufacturing method
WO2014087550A1 (en) * 2012-12-03 2014-06-12 星光Pmc株式会社 Method for manufacturing paperboard
CN104011293A (en) * 2012-12-03 2014-08-27 星光Pmc株式会社 Method For Manufacturing Paperboard
JP2015066898A (en) * 2013-09-30 2015-04-13 大日本印刷株式会社 Laminated sheet and foamed laminated sheet
JP2015180784A (en) * 2014-03-03 2015-10-15 王子ホールディングス株式会社 backing paper for wallpaper
JP2016132846A (en) * 2015-01-22 2016-07-25 三菱製紙株式会社 Nonwoven fabric for wall paper lining
JP2016141922A (en) * 2015-02-05 2016-08-08 三菱製紙株式会社 Wall paper-backing nonwoven fabric
JP2016151066A (en) * 2015-02-16 2016-08-22 王子ホールディングス株式会社 Backing paper for wallpaper

Also Published As

Publication number Publication date
JP4766968B2 (en) 2011-09-07

Similar Documents

Publication Publication Date Title
JP4766968B2 (en) Wallpaper backing paper
JP5669077B2 (en) Wallpaper backing paper
JP2011208323A (en) Backing paper for wallpaper and wallpaper using the same
JP2005314861A (en) Backing paper for wall paper
JP4358601B2 (en) Paperboard
JP2011074509A (en) Backing paper for wallpaper
JP3484109B2 (en) Wallpaper base paper
JP2010236143A (en) Backing paper for wallpaper
JP2018003218A (en) Unwoven fabric, manufacturing method therefor and wall paper using the unwoven fabric
JP5454296B2 (en) Decorative board paper
JP2006257629A (en) Wallpaper-backing paper
JP6655446B2 (en) Acrylic paint paper
JP3974283B2 (en) Vinyl wallpaper base paper
JP6052069B2 (en) Transpiration paper and method for producing the same
JP2008088579A (en) Processed paper
JP2005023501A (en) Upper layer paper of wallpaper
JP2010196216A (en) Backing paper for wallpaper
JP2023006206A (en) sheet
JP2011157642A (en) Lining paper for wallpaper
JP2013002015A (en) Backing paper for wallpaper
JP2017179645A (en) Wet type nonwoven fabric and manufacturing method therefor
JP4428679B2 (en) Base paper for decorative sheet
JP2019077957A (en) Backing paper for wallpaper
JP6586839B2 (en) Crimp postcard base paper
JPH10273896A (en) Backing paper for wall paper

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20080702

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20101020

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20101203

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20110201

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20110610

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20110614

R150 Certificate of patent or registration of utility model

Free format text: JAPANESE INTERMEDIATE CODE: R150

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20140624

Year of fee payment: 3

LAPS Cancellation because of no payment of annual fees