JP2006348618A - Thermal insulating material and its application method - Google Patents

Thermal insulating material and its application method Download PDF

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JP2006348618A
JP2006348618A JP2005177194A JP2005177194A JP2006348618A JP 2006348618 A JP2006348618 A JP 2006348618A JP 2005177194 A JP2005177194 A JP 2005177194A JP 2005177194 A JP2005177194 A JP 2005177194A JP 2006348618 A JP2006348618 A JP 2006348618A
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insulating material
heat insulating
thermal insulating
wall
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Hiroshi Kawate
浩 川手
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02—Macromolecular compounds
    • C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/06—Acrylates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20—Resistance against chemical, physical or biological attack
    • C04B2111/28—Fire resistance, i.e. materials resistant to accidental fires or high temperatures
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/91—Use of waste materials as fillers for mortars or concrete

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  • Ceramic Engineering (AREA)
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a thermal insulating material having a waterproofing effect and adhesion property. <P>SOLUTION: The thermal insulating material exhibits a thermal insulating effect, the waterproofing effect and a heat insolation effect by applying a thermal insulating material obtained by mixing a hollow bead such as a ceramic bead, a fly-ash and a plastic bead or the like with an acrylic resin or the like as a binder on an external wall such as a building or the like, and it can be used as an adhesive. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は、防水効果、接着効果を有する断熱材に関する。   The present invention relates to a heat insulating material having a waterproof effect and an adhesive effect.

従来、建物の屋根や外壁、内装その他の構造体に断熱材が用いられている（例えば、特許文献１、特許文献２、特許文献３。）。外壁等に断熱材を使用することにより、その外壁の内外間の熱の移動を制限することができる。   Conventionally, heat insulating materials have been used for building roofs, outer walls, interiors, and other structures (for example, Patent Document 1, Patent Document 2, and Patent Document 3). By using a heat insulating material for the outer wall or the like, heat transfer between the inside and outside of the outer wall can be limited.

図２は、従来における建物の壁の断熱について説明する図である。図２（ａ）は、内断熱の様子を示す。室内側壁面は、内装下地１０であり、その内側に断熱材１５が備え付けてある。屋外側壁面にはコンクリート（ＡＬＣ）１４等が設けられ、そのコンクリート（ＡＬＣ）１４壁面にタイル１２がモルタルまたはタイル用接着剤１１で、貼り付けられている。また、断熱材１５とコンクリート１４の間には、防水シートが設けられている。   FIG. 2 is a diagram for explaining heat insulation of a conventional building wall. FIG. 2A shows the state of internal heat insulation. The indoor side wall surface is an interior base 10, and a heat insulating material 15 is provided inside thereof. Concrete (ALC) 14 or the like is provided on the outdoor side wall surface, and tiles 12 are attached to the concrete (ALC) 14 wall surface with mortar or tile adhesive 11. Further, a waterproof sheet is provided between the heat insulating material 15 and the concrete 14.

図２（ｂ）は、外断熱の様子を示す。この場合には、コンクリート（ＡＬＣ）１４の屋外側に断熱材１５が備え付けてある。さらに、断熱材の屋外側には、アンカー２１によって、タイル下地パネル２０が支持され、そのタイル下地パネル２０にタイル１２がモルタルまたはタイル用接着剤１１で、貼り付けられている。また、断熱材１５とコンクリート１４の間には、防水シートが設けられている。
特開２００４−２５７９１号公報 特開２００５−８９５７９号公報 特開平１１−８０５９９号公報 FIG.2 (b) shows the state of external heat insulation. In this case, a heat insulating material 15 is provided on the outdoor side of the concrete (ALC) 14. Further, the tile base panel 20 is supported by the anchor 21 on the outdoor side of the heat insulating material, and the tile 12 is attached to the tile base panel 20 with the mortar or the tile adhesive 11. A waterproof sheet is provided between the heat insulating material 15 and the concrete 14.
JP 2004-25791 A JP 2005-89579 A Japanese Patent Laid-Open No. 11-80599

上述のように、従来内断熱であろうとも、外断熱であろうとも、防水シート１３、接着剤１１、断熱材１５が必要であり、高コスト、長期の工期、及び環境への高負荷であった。   As described above, the waterproof sheet 13, the adhesive 11, and the heat insulating material 15 are necessary regardless of whether the heat insulation is internal heat insulation or external heat insulation, and the cost is high, the construction period is long, and the environment is highly loaded. there were.

上記の課題に鑑み、本発明では、簡易かつ低廉な断熱材、及びその塗布方法を提供する。   In view of the above problems, the present invention provides a simple and inexpensive heat insulating material and a coating method thereof.

本発明は、中空ビーズと、アクリル系樹脂とを混合させて構成される。この中空ビーズは、セラミックビーズ、フライアッシュ、またはプラスチックビーズであり、このアクリル系樹脂は、スチレンアクリル酸アルキルエステル共重合物エマルジョンである。   The present invention is configured by mixing hollow beads and an acrylic resin. The hollow beads are ceramic beads, fly ash, or plastic beads, and the acrylic resin is a styrene acrylic acid alkyl ester copolymer emulsion.

本発明は、さらに、上記の断熱材を建築物の外壁に塗布することにより、断熱効果、防水効果、遮熱効果を発揮することができる。また、本発明は、さらに、上記の記載の断熱材を建築物の外壁に塗布した後、該塗布した断熱材の上から所定の建築部材を貼り付けることにより、接着材としても機能する。   Furthermore, this invention can exhibit the heat insulation effect, the waterproof effect, and the heat-shielding effect by apply | coating said heat insulating material to the outer wall of a building. Furthermore, the present invention further functions as an adhesive by applying the above-described heat insulating material to the outer wall of the building and then sticking a predetermined building member on the applied heat insulating material.

本発明の断熱材を用いることにより、簡易かつ低廉に外壁等に防水処理を兼ねた断熱処理を行うことができる。また、接着剤としても機能する。したがって、保温、遮熱、美観、遮音、結露防止、防カビ、クラック補修、準防水等の用途で用いることができる。   By using the heat insulating material of the present invention, it is possible to easily and inexpensively perform heat insulating treatment that also serves as waterproof treatment on the outer wall or the like. It also functions as an adhesive. Therefore, it can be used in applications such as heat insulation, heat insulation, aesthetics, sound insulation, prevention of dew condensation, mold prevention, crack repair, and semi-waterproofing.

本発明は、セラミックビーズ、フライアッシュ（すす、灰など、燃焼廃ガス中に含まれる固体の粒子状物質。集じん灰およびボイラ、ガス冷却室、再燃焼室で補集されたばいじんを総称したものをいう。）、プラスチックビーズ等の中空ビーズと、バインダー（結合材）としてアクリル系樹脂等を混ぜて得られる断熱材である。   The present invention is a generic term for solid particulate matter contained in combustion waste gas, such as ceramic beads and fly ash (soot, ash, etc .. Dust collection ash and boiler, gas cooling chamber, and recombustion chamber. It is a heat insulating material obtained by mixing hollow beads such as plastic beads and acrylic resin as a binder (binding material).

この本発明にかかる断熱材は、防水効果と断熱効果が一体になることにより、屋上の防水・断熱を同時に達成することができる。これにより、施工の簡略化が実現され、コストの低減につながり、その結果、地球環境においてＣＯ2の削減につながる。 The heat insulating material according to the present invention can achieve waterproof and heat insulation on the roof at the same time by integrating the waterproof effect and the heat insulating effect. As a result, the construction is simplified, leading to cost reduction, and as a result, reducing CO 2 in the global environment.

また、この本発明にかかる断熱材を用いることにより、建物におけるタイル貼・石貼において、断熱効果のある材料と接着剤とが一体である時、タイル・石貼の施工を行うと同時に外断熱の外壁ができる。これにより、施工の簡略化が実現され、コストの低減に繋がり、その結果、地球環境においてＣＯ2の削減につながる。 In addition, by using the heat insulating material according to the present invention, when the material having a heat insulating effect and the adhesive are integrated in the tile sticking / stone sticking in the building, the tile / stone sticking is performed at the same time as the external heat insulation. The outer wall is made. This simplifies construction and leads to cost reduction, and as a result, reduces CO 2 in the global environment.

図１は、本発明にかかる断熱材を外壁に使用した様子を示す。断熱材１は、断熱材であるのと同時に、防水材、接着材でもある、３役を兼ね備えた組成物である。すわなち、コンクリート（ＡＬＣ）１４の外壁側表面に接着材として、本発明にかかる断熱材１を塗布してタイル１２を貼り付けることができる。その結果、外壁側と内壁側との境に断熱材１が存在しているので、断熱効果及び防水効果を発揮する。   FIG. 1 shows a state in which a heat insulating material according to the present invention is used for an outer wall. The heat insulating material 1 is a composition having three roles, which is a heat insulating material and also a waterproof material and an adhesive. In other words, the heat insulating material 1 according to the present invention can be applied as an adhesive to the outer wall side surface of the concrete (ALC) 14 and the tile 12 can be attached. As a result, since the heat insulating material 1 exists at the boundary between the outer wall side and the inner wall side, a heat insulating effect and a waterproof effect are exhibited.

したがって、図２で説明した防水シート１３、接着剤１１、断熱材１５をそれぞれ別々に独立して設ける必要がないため、省スペース、低コスト、短工期化を図ることができる。   Therefore, since it is not necessary to provide the waterproof sheet 13, the adhesive 11, and the heat insulating material 15 described in FIG. 2 separately and independently, space saving, low cost, and a short construction period can be achieved.

＜本発明にかかる断熱材の製造方法＞
表１に示す成分を混合し、均一になるまで攪拌した。このとき、攪拌しやすいように、場合によっては加熱により所定の温度で攪拌してもよい。 <The manufacturing method of the heat insulating material concerning this invention>
The components shown in Table 1 were mixed and stirred until uniform. At this time, in order to facilitate stirring, depending on circumstances, stirring may be performed at a predetermined temperature by heating.

Figure 2006348618
Figure 2006348618

表１において、スチレンアクリルエステル重合体として、スチレンアクリル酸アルキルエステル共重合物エマルジョンを用いた。また、無機化合物として、マイクロセラミックビーズ（株式会社キューマック製）、またはエクスパンセルマイクロフェアー（塩化ビニール化合物）を用いた。エクスパンセルマイクロフェアーは、加熱する温度に応じてその径を例えば約２０〜約５０μｍの範囲で変化させることができる。   In Table 1, a styrene acrylic acid alkyl ester copolymer emulsion was used as the styrene acrylic ester polymer. Further, as the inorganic compound, micro ceramic beads (manufactured by Kyumak Co., Ltd.) or expand cell micro sphere (vinyl chloride compound) were used. The expander microsphere can be changed in diameter in the range of, for example, about 20 to about 50 μm depending on the heating temperature.

このようにして、本発明にかかる断熱材を得ることができる。   Thus, the heat insulating material concerning this invention can be obtained.

本実施例では、実施例１で製造した断熱材（以下、試料Ｓという）の塗膜について、日射反射率を求めた。その得られた日射反射率を表２に示す。   In this example, the solar reflectance was determined for the coating film of the heat insulating material (hereinafter referred to as sample S) manufactured in Example 1. The obtained solar reflectance is shown in Table 2.

Figure 2006348618
Figure 2006348618

これより、０．６ｍｍ厚の試料Ｓの膜で、特に近赤外領域で隠ぺい率試験紙の白地上と黒地上での反射率に差異が認められた。すなわち、黒地上の反射率が低下している。このことは、試料Ｓの０．６ｍｍ膜厚では近赤外領域の光は透過しており、素地の黒地に吸収されていることを意味している。   Accordingly, in the film of the sample S having a thickness of 0.6 mm, a difference was observed in the reflectance between the white ground and the black ground of the concealment rate test paper particularly in the near infrared region. That is, the reflectance on the black ground is reduced. This means that the light in the near infrared region is transmitted when the film thickness of the sample S is 0.6 mm, and is absorbed by the black background.

本実施例では、試料Ｓの塗膜について、熱伝導率を測定し、遮熱効果の程度を確認する。表３は、試料Ｓの熱伝導率の測定結果を示す。   In this example, the thermal conductivity of the coating film of sample S is measured to confirm the degree of the heat shielding effect. Table 3 shows the measurement results of the thermal conductivity of Sample S.

Figure 2006348618
Figure 2006348618

「漆喰」の熱伝導率が「０．６」、熱伝導率が「石膏プラスター」が「０．５」、熱伝導率が「石膏ボード」が「０．７１〜０．１」であるのに対し、試料Ｓは表３より「０．１２１（Ｋｃａｌ／ｈ・ｍ・℃）」である。したがって、この試料Ｓの熱伝導率は比較的低い部類の塗装材料と言える。   The thermal conductivity of “Stucco” is “0.6”, the thermal conductivity is “Gypsum plaster” is “0.5”, and the thermal conductivity is “Gypsum board” is “0.71-0.1” On the other hand, the sample S is “0.121 (Kcal / h · m · ° C.)” from Table 3. Therefore, it can be said that this sample S is a coating material of a relatively low thermal conductivity.

亜鉛めっき銅板及びコンクリート板に対する試料Ｓの接着強度を評価した。その結果を表４に示す。   The adhesive strength of sample S to galvanized copper plate and concrete plate was evaluated. The results are shown in Table 4.

Figure 2006348618
Figure 2006348618

そうすると、試料Ｓの接着強度は、対鋼板１．７Ｎ／ｍｍ2、対コンクリート１．５Ｎ／ｍｍ2である（ＪＩＳ規格は、０．５Ｎ／ｍｍ2以上である）。このことから、この試料Ｓは、ＪＩＳ規格を十分に満足する接着強度を有する。 Then, the adhesive strength of the sample S vs. steel 1.7 N / mm 2, a pair of concrete 1.5N / mm 2 (JIS standard is 0.5 N / mm 2 or higher). Therefore, this sample S has an adhesive strength that sufficiently satisfies the JIS standard.

＜実施例２，３，４の効果＞
上記実施例１，２より、本発明にかかる断熱材の断熱効果の有効性を確認することができた。また、当該断熱材の熱伝導率は０．１２（Ｋｃａｌ／ｈｍ℃）である（塗膜０．６ｍｍの場合）。それに対して、コンクリートの熱伝導率１．４０、石膏の熱伝導率０．５、保温レンガの熱伝導率０．１２である。 <Effects of Examples 2, 3, and 4>
From Examples 1 and 2, the effectiveness of the heat insulating effect of the heat insulating material according to the present invention could be confirmed. Moreover, the heat conductivity of the said heat insulating material is 0.12 (Kcal / hm degreeC) (when the coating film is 0.6 mm). On the other hand, the thermal conductivity of concrete is 1.40, the thermal conductivity of gypsum is 0.5, and the thermal conductivity of thermal insulation bricks is 0.12.

また、当該断熱材の接着強度は、対鋼板１．７Ｎ／ｍｍ2、対コンクリート１．５Ｎ／ｍｍ2である（ＪＩＳ規格は、０．５Ｎ／ｍｍ2以上である）。また、当該断熱材の日光反射卒は９０％以上であり、紫外線を含む太陽光の９０％以上を反射させ、建物など構造物の劣化を防止することができる。 The adhesive strength of the insulation, versus steel 1.7 N / mm 2, a pair of concrete 1.5N / mm 2 (JIS standard is 0.5 N / mm 2 or higher). Moreover, the sunlight reflection degree of the said heat insulating material is 90% or more, 90% or more of sunlight containing an ultraviolet-ray is reflected, and deterioration of structures, such as a building, can be prevented.

この断熱材は、さらに以下の効果も有している。当該断熱材は優れた弾力性を有するので、より亀裂の出来にくい衝撃、振動に強い壁に仕上がる。また塗膜を劣化させるあらゆる障害に対して驚異的に対抗し、抜群の耐久性を発揮することができる。   This heat insulating material also has the following effects. Since the heat insulating material has excellent elasticity, it is finished in a wall that is more resistant to shock and vibration, which is harder to crack. Moreover, it can counteract any obstacle that deteriorates the coating film, and can exhibit outstanding durability.

また、当該断熱材を壁に０．９ｍｍ厚塗布すると屋根・天井・壁を通過する音が約１０デシベル低下し、静かな環境が確保できる。また、当該断熱材は環境にやさしい水溶性で、シックハウス症候群の原因物質を含まない。また、当該断熱材の塗布膜は３層〜４層（０．６ｍｍ〜０．９ｍｍ）の塗膜形成し、水の侵入を防ぐことができる。   Moreover, when the heat insulating material is applied to the wall by a thickness of 0.9 mm, the sound passing through the roof, ceiling, and wall is reduced by about 10 decibels, and a quiet environment can be secured. Moreover, the said heat insulating material is environmentally friendly water-soluble, and does not contain the causative substance of sick house syndrome. Moreover, the coating film of the said heat insulating material can form the coating film of 3 layers-4 layers (0.6 mm-0.9 mm), and can prevent the penetration | invasion of water.

また、コンクリート・鉄・鉄板・木など幅広い塗装適正を持っている。また、刷毛ローラー・吹付け・鏝など幅広い塗装デザインにも対応することができる。また、コンクリートなど幅広い塗装適正の他、カラートタンの塗り替え、油性、アクリル系、ウレタン系等の旧塗膜に対しても優れた密着力を発揮することができる。当該断熱材は、保温、遮熱、美観、遮音、結露防止、防カビ、クラック補修、準防水等の用途で用いることができる。   In addition, it has a wide range of painting suitability for concrete, iron, iron plate, wood, etc. It can also handle a wide range of paint designs such as brush rollers, spraying, and wrinkles. Moreover, in addition to a wide range of coating suitability such as concrete, it can exhibit excellent adhesion to old paint films such as repainting of color tones, oiliness, acrylics and urethanes. The said heat insulating material can be used for uses, such as heat insulation, heat insulation, aesthetics, sound insulation, dew condensation prevention, mold prevention, crack repair, semi-waterproofness.

当該断熱材の施工対象は、たとえば、工場、一般倉庫、保冷倉庫、研究所、学校、集会所、体育館等大きな建物の屋根の外装及び内装であったり、冷凍コンテナ、ドライコンテナ、保冷車、穀物サイロ、冷凍冷蔵倉庫、貯蔵タンク、畜産舎、車両内外装、プラントの配管（ＬＰガス・蒸気）であったり、鉄、コンクリート、発泡コンクリート、木材、瓦、スレート、サイデング、レンガ、タイル、アルミ、ステンレス、ブロック、石膏ボード等であってもよい。また、様々な色の顔料を混ぜることで塗料として用いることもできる。   The target of construction of the insulation is, for example, the exterior and interior of the roofs of large buildings such as factories, general warehouses, cold storage warehouses, laboratories, schools, meeting places, gymnasiums, frozen containers, dry containers, cold cars, grains Silos, frozen / refrigerated warehouses, storage tanks, livestock buildings, interior / exterior of vehicles, plant piping (LP gas / steam), iron, concrete, foamed concrete, wood, tile, slate, siding, brick, tile, aluminum, It may be stainless steel, block, gypsum board or the like. It can also be used as a paint by mixing pigments of various colors.

本発明にかかる断熱材を外壁に使用した様子を示す。A mode that the heat insulating material concerning this invention was used for the outer wall is shown. 従来における建物の壁の断熱を説明する図である。It is a figure explaining the heat insulation of the wall of the conventional building.

符号の説明Explanation of symbols

１ 断熱材
１０ 内装下地
１１ モルタルまたはタイル用接着剤
１２ タイル
１３ 防水シート
１４ コンクリート（ＡＬＣ）
１５ 断熱材


DESCRIPTION OF SYMBOLS 1 Heat insulating material 10 Interior base material 11 Adhesive for mortar or tile 12 Tile 13 Waterproof sheet 14 Concrete (ALC)
15 Insulation


Claims (4)

中空ビーズと、アクリル系樹脂とを混合させて構成されることを特徴とする断熱材。   A heat insulating material comprising a mixture of hollow beads and acrylic resin. 前記中空ビーズは、セラミックビーズ、フライアッシュ、またはプラスチックビーズであり、
前記アクリル系樹脂は、スチレンアクリル酸アルキルエステル共重合物エマルジョンである
ことを特徴とする請求項１に記載の断熱材。 The hollow beads are ceramic beads, fly ash, or plastic beads,
The heat insulating material according to claim 1, wherein the acrylic resin is a styrene acrylic acid alkyl ester copolymer emulsion. 請求項１に記載の断熱材を建築物の外壁に塗布する断熱材を防水材として用いる施工方法。   The construction method using the heat insulating material which apply | coats the heat insulating material of Claim 1 to the outer wall of a building as a waterproofing material. 請求項１に記載の断熱材を建築物の外壁に塗布した後、該塗布した断熱材の上から所定の建築部材を貼り付ける断熱材の接着方法。



A method for bonding a heat insulating material, comprising: applying a heat insulating material according to claim 1 to an outer wall of a building; and attaching a predetermined building member on the applied heat insulating material.



JP2005177194A 2005-06-17 2005-06-17 Thermal insulating material and its application method Withdrawn JP2006348618A (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008063530A (en) * 2006-09-11 2008-03-21 Shimizu Corp Unevenness-modifying material
CN101880501A (en) * 2010-07-09 2010-11-10 重庆航利实业有限责任公司 Nano ZnO/SiO2 sol modified self-cleaning silicone-acrylic exterior wall insulating mould coating
KR101219531B1 (en) * 2012-08-22 2013-01-09 (주)실리칼플로어 Method for repair and infrared heat reflective and waterproof of building's wall
CN104513573A (en) * 2014-12-11 2015-04-15 青岛佰众化工技术有限公司 Novel thin layer thermal insulating paint
JP2015537058A (en) * 2012-09-25 2015-12-24 ユナイテッド・ステイツ・ジプサム・カンパニー Bonding compounds, wall assemblies, and related methods and products
CN109021662A (en) * 2018-06-18 2018-12-18 滁州华海中谊工业炉有限公司 A kind of insulating moulding coating for vacuum furnace outer wall
CN109439086A (en) * 2018-09-28 2019-03-08 河南寰球航空装备科技有限公司 A kind of water-fast exterior coating of good combination property and preparation method thereof
CN115433496A (en) * 2021-12-23 2022-12-06 安徽润航环保材料有限公司 Preparation method of anti-fouling external wall latex paint

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008063530A (en) * 2006-09-11 2008-03-21 Shimizu Corp Unevenness-modifying material
CN101880501A (en) * 2010-07-09 2010-11-10 重庆航利实业有限责任公司 Nano ZnO/SiO2 sol modified self-cleaning silicone-acrylic exterior wall insulating mould coating
KR101219531B1 (en) * 2012-08-22 2013-01-09 (주)실리칼플로어 Method for repair and infrared heat reflective and waterproof of building's wall
JP2015537058A (en) * 2012-09-25 2015-12-24 ユナイテッド・ステイツ・ジプサム・カンパニー Bonding compounds, wall assemblies, and related methods and products
CN104513573A (en) * 2014-12-11 2015-04-15 青岛佰众化工技术有限公司 Novel thin layer thermal insulating paint
CN109021662A (en) * 2018-06-18 2018-12-18 滁州华海中谊工业炉有限公司 A kind of insulating moulding coating for vacuum furnace outer wall
CN109439086A (en) * 2018-09-28 2019-03-08 河南寰球航空装备科技有限公司 A kind of water-fast exterior coating of good combination property and preparation method thereof
CN115433496A (en) * 2021-12-23 2022-12-06 安徽润航环保材料有限公司 Preparation method of anti-fouling external wall latex paint

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