JP2006348429A - Respirator-treating composition - Google Patents
Respirator-treating composition Download PDFInfo
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- JP2006348429A JP2006348429A JP2005176983A JP2005176983A JP2006348429A JP 2006348429 A JP2006348429 A JP 2006348429A JP 2005176983 A JP2005176983 A JP 2005176983A JP 2005176983 A JP2005176983 A JP 2005176983A JP 2006348429 A JP2006348429 A JP 2006348429A
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- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
本発明は、空気中浮遊粒子に対する防御性を高めるためのマスク処理用組成物、および該組成物をスプレー容器に充填してなる空気中浮遊粒子に対する防御性を高めるためのマスク処理用スプレー剤に関する。本発明はまた、該組成物または該スプレー剤を使用することを特徴とする空気中浮遊粒子に対する防御性を高めるためのマスクの処理方法に関する。 The present invention relates to a mask treatment composition for enhancing protection against airborne particles, and a mask treatment spray for enhancing protection against airborne particles obtained by filling the composition with a spray container. . The present invention also relates to a method for treating a mask for enhancing protection against airborne particles, characterized by using the composition or the spray.
日本人がスギなどの花粉によっていわゆる花粉症を患う割合は、人口の10〜15%程度であると言われており、花粉症は、今日では、日本人における現代病であるとも考えられている。花粉症は、これに患ったものでないとわからない目の痒み、鼻詰まりなどの不快症状を発現する。また、ダニの死骸や糞、カビの胞子等のハウスダストに対するアレルギー症状も、今日大きな問題とされている。 It is said that the proportion of Japanese people suffering from so-called hay fever by cedar pollen is about 10-15% of the population, and hay fever is now considered to be a modern disease in the Japanese. . Hay fever develops unpleasant symptoms such as itchy eyes and nasal congestion that cannot be confirmed without suffering from this. In addition, allergic symptoms to house dust such as mite carcasses, feces and mold spores are also regarded as a major problem today.
こうした花粉症やハウスダストに対するアレルギー症状等の対策の一つとして、マスクの使用が有効であることが知られており、花粉やハウスダスト、粉塵、ウィルスといった空気中浮遊粒子の鼻口内への侵入を、効果的に抑制するための対策を施した種々のマスクがこれまでに開示されている。例えば、細かくした粒子炭を和紙製の小袋に入れ、マスクに装着したもの(例えば、特許文献1参照)や、マスクを構成する繊維に繊維状高吸水性ポリマーを使用して、マスク内の高い湿潤状態を保つことによって浮遊物を吸着し、鼻口内への侵入を防止するもの(例えば、特許文献2参照)、また、化学的に正電荷を持つ官能基を有する繊維をマスクに用いることで、花粉を吸着し、鼻口内への侵入を防止するもの(例えば、特許文献3参照)などが知られている。 As one of the countermeasures against such hay fever and allergic symptoms to house dust, it is known that the use of a mask is effective, and the entry of airborne particles such as pollen, house dust, dust, and viruses into the nostril Various masks with countermeasures for effectively suppressing the above have been disclosed so far. For example, fine carbon charcoal is put in a sachet made of Japanese paper and attached to a mask (see, for example, Patent Document 1), or a fibrous superabsorbent polymer is used for fibers constituting the mask. By using a fiber that has a functional group having a positively charged functional group that adsorbs suspended matter by keeping it moist and prevents entry into the nostril (see, for example, Patent Document 2), or a fiber having a chemically positively charged functional group. Those that adsorb pollen and prevent entry into the nostril are known (for example, see Patent Document 3).
しかし、前者のようにマスクに小袋を装着するものは、マスクの厚みが増し、通気性を妨げたり、フィット感がなくなるなど、使用感に優れないという問題点があった。また、後二者は、マスクを構成する繊維そのものに特徴を有するものであるため、マスクの製造時にそれぞれに特有な繊維を必要とするものであった。これらはいずれも、マスクの製造時において、空気中浮遊粒子に対する防御性を高める機能を付与するものであり、既に手持ちのマスクの防御性を、後から容易に高めることの出来るものではなかった。 However, the former, in which a sachet is attached to the mask, has a problem in that it is not excellent in usability, such as an increase in the thickness of the mask, obstructing air permeability, and loss of fit. Further, since the latter two are characterized by the fibers themselves constituting the mask, they have to have unique fibers at the time of manufacturing the mask. All of them impart a function of enhancing the protection against airborne particles at the time of manufacturing the mask, and the protection of the mask already on hand cannot be easily improved later.
本発明は、前記従来技術に鑑みてなされたものであり、安全性が高く、使用感に優れ、通気性を妨げず、且つ既存のマスク、例えば安価に入手可能な使い捨てマスク等の、空気中浮遊粒子に対する防御性を容易に高めることの出来るマスク処理用組成物および該組成物のスプレー剤を提供することを課題とする。 The present invention has been made in view of the above-described prior art, and has high safety, excellent usability, does not hinder air permeability, and does not interfere with air permeability. It is an object of the present invention to provide a composition for mask treatment that can easily enhance the protection against airborne particles and a spray agent of the composition.
即ち、本発明は、
[1] ノニオン系界面活性剤および/または多価アルコールを含有してなる、空気中浮遊粒子に対する防御性を高めるためのマスク処理用組成物;
[2] 更に、水および/または低級アルコールを含有してなる[1]記載のマスク処理用組成物;
[3] 更に、オルガノポリシロキサンを含有してなる[1]または[2]記載のマスク処理用組成物;
[4] 更に、植物精油を含有してなる[1]〜[3]いずれか記載のマスク処理用組成物;
[5] 空気中浮遊粒子が花粉、ハウスダスト、粉塵、ウィルスである[1]〜[4]いずれか記載のマスク処理用組成物;
[6] [1]〜[5]いずれか記載のマスク処理用組成物をスプレー容器に充填してなる、空気中浮遊粒子に対する防御性を高めるためのマスク処理用スプレー剤;ならびに
[7] [1]〜[5]いずれか記載のマスク処理用組成物または[6]記載のマスク処理用スプレー剤を使用することを特徴とする、空気中浮遊粒子に対する防御性を高めるためのマスクの処理方法
に関する。
That is, the present invention
[1] A composition for mask treatment for enhancing the protection against airborne particles, comprising a nonionic surfactant and / or a polyhydric alcohol;
[2] The mask processing composition according to [1], further comprising water and / or a lower alcohol;
[3] The mask processing composition according to [1] or [2], further comprising an organopolysiloxane;
[4] The mask treatment composition according to any one of [1] to [3], further comprising plant essential oil;
[5] The mask treatment composition according to any one of [1] to [4], wherein the airborne particles are pollen, house dust, dust, and virus;
[6] A mask treatment spray for enhancing the protection against airborne particles, which is formed by filling a spray container with the mask treatment composition according to any one of [1] to [5]; and
[7] A mask treatment composition according to any one of [1] to [5] or a mask treatment spray according to [6], which is used to enhance protection against airborne particles. The present invention relates to a mask processing method.
本発明の、空気中浮遊粒子に対する防御性を高めるためのマスク処理用組成物および該組成物のスプレー剤は、安全性が高く、使用感に優れ、通気性を妨げず、且つ既存のマスク、例えば安価に入手可能な使い捨てマスク等の空気中浮遊粒子に対する防御性を容易に高めることが出来る、という効果を奏する。 The composition for mask treatment for enhancing the protection against airborne particles and the spray agent of the composition of the present invention have high safety, excellent usability, do not hinder breathability, and are existing masks, For example, there is an effect that the protection against airborne particles such as a disposable mask that can be obtained at low cost can be easily enhanced.
本発明の、空気中浮遊粒子に対する防御性を高めるためのマスク処理用組成物(本明細書中において、本発明の組成物と称することがある)は、ノニオン系界面活性剤および/または多価アルコールを含有してなることを特徴とする。本発明の組成物は、これらの成分を含有することから、マスクに塗布することにより該マスクの空気中浮遊粒子の透過抑制効果を高めることができ、すなわち該マスクの空気中浮遊粒子に対する防御性を高めることができるものである。ノニオン系界面活性剤および多価アルコールは、それぞれタック性を有することから、これらに空気中浮遊粒子がトラップされることによって、本発明のような空気中浮遊粒子の透過抑制効果が得られると考えられる。 The composition for mask treatment for enhancing the protection against airborne particles according to the present invention (sometimes referred to herein as the composition of the present invention) is a nonionic surfactant and / or a polyvalent surfactant. It is characterized by containing alcohol. Since the composition of the present invention contains these components, it can enhance the permeation suppression effect of airborne particles in the mask by applying to the mask, that is, the mask has a protective property against airborne particles. Can be increased. Since the nonionic surfactant and the polyhydric alcohol each have tackiness, it is thought that the permeation suppression effect of airborne particles as in the present invention can be obtained by trapping airborne particles on them. It is done.
また本発明の組成物は、既存のマスクに塗布するだけで効果を奏するため、容易に使用することができ、また、該マスクの通気性を妨げず、使用感を損なうことがない。更に、ノニオン系界面活性剤および多価アルコールは安全性が高いことが一般に知られており、本発明の組成物は安全性に優れたものであるといえる。 In addition, the composition of the present invention can be used easily because it is effective only by being applied to an existing mask, does not impair the breathability of the mask, and does not impair the feeling of use. Furthermore, it is generally known that nonionic surfactants and polyhydric alcohols have high safety, and it can be said that the composition of the present invention is excellent in safety.
本発明において、空気中浮遊粒子としては、例えば、花粉、ハウスダスト、粉塵、ウィルス等が挙げられる。また、ハウスダストとしては、例えばダニの死骸や糞、カビの胞子、ペットの体毛等が挙げられる。通常、花粉の粒子径が10〜100μm程度、ハウスダストの粒子径が1〜500μm程度、粉塵が0.1〜30μm程度、ウィルスが0.02〜0.2μm程度である事から、本発明の組成物は、粒子径が0.02〜500μm程度である空気中浮遊粒子に対するマスクの防御性を高める効果に優れていると考えられる。したがって、本発明の組成物は、これらの空気中浮遊粒子に対するマスクの防御性を高め、花粉症やハウスダストに対するアレルギーの症状を緩和できるという利点を有する。 In the present invention, examples of airborne particles include pollen, house dust, dust, and viruses. Examples of house dust include mite carcasses and feces, mold spores, and pet hair. Usually, the particle size of pollen is about 10 to 100 μm, the particle size of house dust is about 1 to 500 μm, dust is about 0.1 to 30 μm, and virus is about 0.02 to 0.2 μm. The composition is considered to be excellent in the effect of enhancing the mask's protection against airborne particles having a particle size of about 0.02 to 500 μm. Therefore, the composition of this invention has the advantage that the protective property of the mask with respect to these airborne particles can be improved, and the symptom of the allergy to hay fever and house dust can be relieved.
本発明に使用されるノニオン系界面活性剤としては、例えば、脂肪酸アルカノールアミド、ポリオキシアルキレンアルキルエーテル、ソルビタン脂肪酸エステル、ポリオキシエチレンアルキルフェニルエーテル、アルキルグリコシド、ショ糖脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、ポリオキシエチレン脂肪酸エステル、エチレングリコール脂肪酸エステル、フッ素系ノニオン系界面活性剤等が挙げられるが、かかる例示のみに限定されるものではない。安全性の観点からは、化粧品原料、食品添加物等に利用されるものが好ましく、また、空気中浮遊粒子のトラップ効果(タック性)、相溶性の観点から、脂肪酸アルカノールアミドがより好ましい。 Nonionic surfactants used in the present invention include, for example, fatty acid alkanolamides, polyoxyalkylene alkyl ethers, sorbitan fatty acid esters, polyoxyethylene alkyl phenyl ethers, alkyl glycosides, sucrose fatty acid esters, polyoxyethylene sorbitan fatty acids. Examples include esters, polyoxyethylene fatty acid esters, ethylene glycol fatty acid esters, and fluorine-based nonionic surfactants, but are not limited to such examples. From the viewpoint of safety, those used for cosmetic raw materials, food additives and the like are preferable, and fatty acid alkanolamides are more preferable from the viewpoint of trapping effect (tackiness) of airborne particles and compatibility.
脂肪酸アルカノールアミドの具体例としては、例えば、ヤシ油脂肪酸ジエタノールアミド、ラウリン酸ジエタノールアミド、ステアリン酸ジエタノールアミド、ラウリン酸モノエタノールアミド、ラウリン酸モノイソプロパノールアミド、ステアリン酸モノエタノールアミド、オレイン酸モノエタノールアミドなどが挙げられる。また、これらのノニオン系界面活性剤は、それぞれ単独で使用してもよく、2種以上を組み合わせて使用してもよい。 Specific examples of the fatty acid alkanolamide include, for example, coconut oil fatty acid diethanolamide, lauric acid diethanolamide, stearic acid diethanolamide, lauric acid monoethanolamide, lauric acid monoisopropanolamide, stearic acid monoethanolamide, oleic acid monoethanolamide. Etc. Moreover, these nonionic surfactants may be used alone or in combination of two or more.
本発明の組成物におけるノニオン系界面活性剤の含有量としては、空気中浮遊粒子の透過抑制効果を高める観点および使用感の観点から、組成物中、0.01〜10重量%が好ましく、0.01〜5重量%がより好ましい。 The content of the nonionic surfactant in the composition of the present invention is preferably 0.01 to 10% by weight in the composition from the viewpoint of enhancing the permeation suppressing effect of airborne particles and the feeling of use. More preferably, the content is 0.01 to 5% by weight.
本発明に使用される多価アルコールとしては、グリセリン、ソルビトール、ショ糖等が挙げられるが、かかる例示のみに限定されるものではない。 Examples of the polyhydric alcohol used in the present invention include glycerin, sorbitol, sucrose, and the like, but are not limited to such examples.
本発明の組成物における多価アルコールの含有量としては、空気中浮遊粒子の透過抑制効果を高める観点および使用感の観点から、組成物中0.01〜10重量%が好ましく、0.01〜5重量%がより好ましい。 The content of the polyhydric alcohol in the composition of the present invention is preferably 0.01 to 10% by weight in the composition from the viewpoint of enhancing the permeation suppressing effect of airborne particles and the feeling of use. 5% by weight is more preferred.
また、本発明の組成物は、上記のようなノニオン系界面活性剤または多価アルコールのいずれかのみを含有していてもよく、また、両者ともを含有していてもよい。両者ともを含有する場合は、ノニオン系界面活性剤および多価アルコールの合計含有量が、組成物中、0.01〜10重量%であることが好ましく、0.01〜5重量%であることがより好ましい。 Moreover, the composition of the present invention may contain only one of the nonionic surfactant or the polyhydric alcohol as described above, or may contain both. When both are contained, the total content of the nonionic surfactant and the polyhydric alcohol is preferably 0.01 to 10% by weight and preferably 0.01 to 5% by weight in the composition. Is more preferable.
本発明に使用される水としては、例えば、精製水が挙げられる。また、本発明に使用される低級アルコールとしては、安全性、使用性等の観点から、炭素数が2〜7であることが好ましく、2〜4であることがより好ましく、2であることが更に好ましい。従って、低級アルコールの中では、エタノールが好適である。 Examples of water used in the present invention include purified water. In addition, the lower alcohol used in the present invention preferably has 2 to 7 carbon atoms, more preferably 2 to 4 carbon atoms, and 2 in view of safety, usability, and the like. Further preferred. Therefore, ethanol is preferred among the lower alcohols.
本発明の組成物は、水または低級アルコールいずれかのみを含有していてもよく、また、両者ともを含有していてもよい。乾燥性および使用性を高める観点、ならびに引火性を低減させるとともに刺激性を和らげる観点から、両者ともを含有することが好ましく、その場合、水:低級アルコール=40:60〜100:0であることが好ましい。 The composition of the present invention may contain only water or a lower alcohol, or may contain both. It is preferable to contain both from the viewpoints of improving dryability and usability, and reducing flammability and reducing irritation, in which case water: lower alcohol = 40: 60 to 100: 0. Is preferred.
本発明の組成物における水および/または低級アルコールの合計含有量は、通常、ノニオン系界面活性剤および/または多価アルコール、ならびに、任意にオルガノポリシロキサン、植物精油およびその他の添加剤が所望の濃度となるように含有された、組成物の残部であることが好ましい。 The total content of water and / or lower alcohol in the composition of the present invention is usually desired as nonionic surfactants and / or polyhydric alcohols, and optionally organopolysiloxanes, plant essential oils and other additives. It is preferable that it is the balance of the composition contained so that it may become a density | concentration.
また、本発明の組成物には、マスクへの空気中浮遊粒子の付着を防ぎ、該マスクの空気中浮遊粒子に対する防御性を更に高める観点から、オルガノポリシロキサンが含有されていることが好ましい。ノニオン系界面活性剤および/または多価アルコールによる空気中浮遊粒子の透過抑制効果に、オルガノポリシロキサンによる空気中浮遊粒子の付着防止効果が加わることにより、マスクの空気中浮遊粒子に対する防御性は著しく高まることが期待される。 In addition, the composition of the present invention preferably contains an organopolysiloxane from the viewpoint of preventing airborne particles from adhering to the mask and further enhancing the protection of the mask against airborne particles. The protective effect against airborne particles of the mask is remarkably added by the anti-permeation effect of airborne particles by organopolysiloxane in addition to the permeation suppression effect of airborne particles by nonionic surfactant and / or polyhydric alcohol. Expected to increase.
本発明にいうオルガノポリシロキサンとは、ケイ素と酸素とが結合した有機化合物の総称を意味する。本発明に使用されるオルガノポリシロキサンとしては、シリコーンオイル、オルガノシリケート等が挙げられるが、かかる例示に限定されるものではない。これらの中では、空気中浮遊粒子の付着防止性の観点から、オルガノシリケートが好ましい。 The organopolysiloxane referred to in the present invention is a general term for organic compounds in which silicon and oxygen are bonded. Examples of the organopolysiloxane used in the present invention include silicone oil and organosilicate, but are not limited to such examples. Among these, organosilicate is preferable from the viewpoint of preventing adhesion of airborne particles.
本発明の組成物におけるオルガノポリシロキサンの含有量は、マスクへの空気中浮遊粒子の付着防止性および使用性の観点から、ケイ酸含量に換算して、好ましくは0.01〜2重量%、より好ましくは0.03〜1.5重量%、更に好ましくは0.05〜1重量%である。 The content of the organopolysiloxane in the composition of the present invention is preferably 0.01 to 2% by weight in terms of the silicic acid content from the viewpoint of preventing adhesion of airborne particles to the mask and usability. More preferably, it is 0.03-1.5 weight%, More preferably, it is 0.05-1 weight%.
本発明の組成物には、爽快感を向上させる観点、および、くしゃみ、鼻水、鼻づまり等の、花粉症やハウスダストに対するアレルギーの各種症状を緩和する観点から、植物精油が含有されていることが好ましい。本発明に使用される植物精油としては、例えばミント、ラベンダー、ユーカリ等のハーブの精油が例示されるが、これらに限定されるものではなく、清涼感のある香りもしくはリラックス効果のある香り等を有するものが好ましい。 The composition of the present invention contains plant essential oils from the viewpoint of improving refreshment and alleviating various symptoms of allergies to hay fever and house dust such as sneezing, runny nose and stuffy nose. Is preferred. Examples of the plant essential oil used in the present invention include essential oils of herbs such as mint, lavender and eucalyptus, but are not limited to these, and include a refreshing scent or a relaxing scent. What has is preferable.
また、本発明の組成物には、例えば、乳化剤、界面活性剤、粘度調整剤、乳白剤、安定剤、防腐剤、金属イオン封鎖剤、キレート化剤、透明剤、着色剤、有機溶剤、油分、色素、殺菌剤、抗菌剤、防汚剤、保湿剤、美容成分消臭剤、アレルゲン失活剤、アレルゲン除去剤、帯電防止剤、pH調整剤等の添加剤を所望により含有されていてもよい。これらの添加剤の含有量は、その種類や目的によって異なるため一概には決定することができないが、本発明の所望の効果を阻害しない範囲内で含有させることができる。 The composition of the present invention includes, for example, emulsifiers, surfactants, viscosity modifiers, opacifiers, stabilizers, preservatives, sequestering agents, chelating agents, clearing agents, colorants, organic solvents, oil components. , Pigments, bactericides, antibacterial agents, antifouling agents, moisturizers, beauty ingredient deodorants, allergen deactivators, allergen removers, antistatic agents, pH adjusters, and other additives as desired Good. The content of these additives varies depending on the type and purpose and cannot be determined unconditionally, but can be contained within a range that does not impair the desired effect of the present invention.
本発明の組成物は、ノニオン系界面活性剤および/または多価アルコール、水および/または低級アルコール、ならびに所望により、オルガノポリシロキサン、植物精油、その他の添加剤を、上記のような所望の濃度で混合することによって容易に調製することができる。 The composition of the present invention comprises nonionic surfactants and / or polyhydric alcohols, water and / or lower alcohols, and optionally organopolysiloxanes, plant essential oils, and other additives in desired concentrations as described above. Can be easily prepared.
本発明の組成物は、スプレー容器に充填することにより空気中浮遊粒子に対する防御性を高めるためのマスク処理用スプレー剤(本明細書中において、本発明のスプレー剤と称する場合がある)として使用することが好ましい。スプレー剤としてマスクに噴霧して使用することで、より容易に、マスクに均一に組成物を塗布することができ、またスプレー容器に充填することにより、容易に携帯して持ち運びができるようになり、所望の場所で手軽に使用できるという利点がある。 The composition of the present invention is used as a spray for mask treatment (in this specification, sometimes referred to as the spray of the present invention) for enhancing the protection against airborne particles by filling a spray container. It is preferable to do. By spraying on a mask as a spray agent, the composition can be evenly applied to the mask more easily, and by filling the spray container, it can be easily carried and carried. There is an advantage that it can be used easily at a desired place.
本発明に使用されるスプレー容器の種類には特に限定は無いが、使用時の簡便性の観点から、例えば、トリガー式スプレー容器、ポンプ式スプレー容器、蓄圧式スプレー容器などが好ましい。スプレー容器の内容量は、特に限定はされないが、使用性や携帯性の観点からは、3〜200mL程度が好ましく、5〜100mL程度がより好ましい。 Although there is no limitation in particular in the kind of spray container used for this invention, a trigger type spray container, a pump type spray container, a pressure accumulation type spray container etc. are preferable from a viewpoint of the simplicity at the time of use. The internal volume of the spray container is not particularly limited, but is preferably about 3 to 200 mL, more preferably about 5 to 100 mL from the viewpoint of usability and portability.
本発明の空気中浮遊粒子に対する防御性を高めるためのマスク処理用組成物または空気中浮遊粒子に対する防御性を高めるためのマスク処理用スプレー剤を適用し得るマスクの種類には特に限定はなく、例えば市販の使い捨てマスク等に好ましく適用することができる。通気性のあるマスクであればいずれも好ましく適用することができ、例えば、ガーゼ等の織布、不織布、紙(パルプ紙、レーヨン繊維紙)等からなるマスクが例示される。マスクを構成する繊維としては、例えば、ポリプロピレン、ポリエチレン、ナイロン、ポリウレタン、綿、ポリエステル、ポリエチレンテレフタレート、ポリアミド、ポリオレフィン、アセテート、キュプラ、レーヨン等が例示される。本発明の組成物またはスプレー剤は、市販の使い捨てマスク等の、容易に入手可能で、安価なマスクの空気中浮遊粒子に対する防御性を、所望により容易に高めることができることが出来るという利点を有する。 There is no particular limitation on the type of mask to which the mask treatment composition for enhancing the protection against airborne particles of the present invention or the mask treatment spray for enhancing the protection against airborne particles can be applied, For example, it can be preferably applied to a commercially available disposable mask. Any breathable mask can be preferably applied. For example, a mask made of woven fabric such as gauze, non-woven fabric, paper (pulp paper, rayon fiber paper) or the like is exemplified. Examples of the fibers constituting the mask include polypropylene, polyethylene, nylon, polyurethane, cotton, polyester, polyethylene terephthalate, polyamide, polyolefin, acetate, cupra, and rayon. The composition or spray of the present invention has the advantage that the protection against airborne particles of a readily available and inexpensive mask, such as a commercially available disposable mask, can be easily increased as desired. .
本発明の組成物またはスプレー剤は、例えば、外出前などに、マスクに軽く塗布または噴霧するだけで、マスクを処理することができ、また、塗布後または噴霧後には、速やかに乾燥させることができる。 The composition or spray of the present invention can be treated by simply applying or spraying the mask lightly, for example, before going out, and can be dried quickly after application or after spraying. it can.
また、本発明の組成物またはスプレー剤のマスクへの適用量は、マスクの種類等によって異なるため一概には決定されないが、好ましくは0.5〜50mL/m2程度、より好ましくは5〜30mL/m2程度である。 The amount of the composition of the present invention or the spray applied to the mask varies depending on the type of the mask and the like, but is not generally determined, but is preferably about 0.5 to 50 mL / m 2 , more preferably 5 to 30 mL. / M 2 or so.
実施例1 各種マスク処理用組成物の調製
ヤシ油脂肪酸ジエタノールアミド(ノニオン系界面活性剤)を0.5重量%、1.0重量%、3.0重量%、5.0重量%含有する水溶液をそれぞれ調製し、マスク処理用組成物を得た。同様に、ポリオキシアルキレンアルキルエーテル(ノニオン系界面活性剤)、ショ糖脂肪酸エステル(ノニオン系界面活性剤)、ポリオキシエチレンソルビタン脂肪酸エステル(ノニオン系界面活性剤)、グリセリン(多価アルコール)、ソルビトール(多価アルコール)についても、それぞれ各濃度の水溶液を調製し、各種マスク処理用組成物を得た。
Example 1 Preparation of various mask treatment compositions Aqueous solutions containing coconut oil fatty acid diethanolamide (nonionic surfactant) at 0.5 wt%, 1.0 wt%, 3.0 wt% and 5.0 wt% Were prepared to obtain a mask treatment composition. Similarly, polyoxyalkylene alkyl ether (nonionic surfactant), sucrose fatty acid ester (nonionic surfactant), polyoxyethylene sorbitan fatty acid ester (nonionic surfactant), glycerin (polyhydric alcohol), sorbitol For (polyhydric alcohol), aqueous solutions of various concentrations were prepared, and various mask processing compositions were obtained.
試験例1 花粉透過抑制効果試験
実施例1で得られた各種マスク処理用組成物の花粉透過抑制効果を、市販の使い捨てマスクを用いて以下の通りに試験した。結果を表1に示す。
Test Example 1 Pollen Permeation Suppression Effect Test The pollen permeation suppression effect of the various mask processing compositions obtained in Example 1 was tested as follows using a commercially available disposable mask. The results are shown in Table 1.
[花粉透過抑制効果試験]
市販の使い捨てマスク 20×20cmあたりに、各種マスク処理用組成物0.3mLをそれぞれ均一に塗布し、乾燥させたものを準備した。また対照として、水のみを塗布し、乾燥させたマスクを同様に準備した。図1に示されるような吸引濾過装置のホルダー部に処理後のマスクを装着し、上からスギ花粉0.1gをマスク全体に均一にまいた。10L/minの流量で、マスクの下方から3分間吸引し、吸引後のマスク重量を測定した。下記式によって、各マスク処理用組成物の花粉透過抑制率を求めた。
花粉透過抑制率(%)=(C−A)/B×100
(A:マスクの重量、B:マスク上にまいたスギ花粉重量、C:吸引後のマスク重量)
[Pollen permeation suppression test]
Each of the commercially available disposable masks 20 × 20 cm was uniformly coated with 0.3 mL of various mask processing compositions and dried. As a control, a mask coated with only water and dried was similarly prepared. The processed mask was attached to the holder of the suction filtration apparatus as shown in FIG. 1, and 0.1 g of cedar pollen was evenly spread over the entire mask from above. At a flow rate of 10 L / min, suction was performed from below the mask for 3 minutes, and the weight of the mask after suction was measured. The pollen permeation | transmission suppression rate of each composition for mask processing was calculated | required by the following formula.
Pollen permeation inhibition rate (%) = (C−A) / B × 100
(A: weight of mask, B: weight of cedar pollen scattered on the mask, C: weight of mask after suction)
表1に示されるように、ノニオン系界面活性剤または多価アルコールを含む各種マスク処理用組成物で処理をしたマスクは、水のみで処理をしたマスクよりも花粉の透過をより抑制し、その透過抑制率はノニオン系界面活性剤または多価アルコールの濃度に依存して高くなる傾向にあることが明らかになった。 As shown in Table 1, the mask treated with various mask treatment compositions containing a nonionic surfactant or a polyhydric alcohol suppresses pollen permeation more than a mask treated with water alone. It has been clarified that the permeation suppression rate tends to increase depending on the concentration of nonionic surfactant or polyhydric alcohol.
本発明のマスク処理用組成物は、マスクの空気中浮遊粒子に対する防御性を高めるために好適に使用することができる。したがって、本発明のマスク処理用組成物は、例えば、花粉に対する防御性向上用マスク処理剤、ハウスダストに対する防御性向上用マスク処理剤等として使用することができる。また、本発明のマスク処理用組成物は、スプレー容器に充填することにより、空気中浮遊粒子に対する防御性向上用スプレー製品として使用することができる。 The composition for mask treatment of the present invention can be suitably used for enhancing the protection of the mask against airborne particles. Therefore, the composition for mask treatment of the present invention can be used as, for example, a mask treatment agent for improving protection against pollen, a mask treatment agent for improving protection against house dust, and the like. Moreover, the composition for mask treatment of this invention can be used as a spray product for improving the protection against airborne particles by filling a spray container.
1:ホルダー部
2:流量計
3:吸引ポンプ
4:市販の使い捨てマスク
1: Holder part 2: Flow meter 3: Suction pump 4: Commercially available disposable mask
Claims (7)
A mask processing method for improving the protection against airborne particles, characterized by using the mask processing composition according to any one of claims 1 to 5 or the mask processing spray according to claim 6.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011063523A (en) * | 2009-09-15 | 2011-03-31 | Kobayashi Pharmaceutical Co Ltd | Degerming/bactericidal composition for mask |
JP2017075413A (en) * | 2015-10-13 | 2017-04-20 | グンゼ株式会社 | Fiber treatment agent and fiber product with natural derivation essential oil |
WO2022255487A1 (en) * | 2021-06-04 | 2022-12-08 | 株式会社 資生堂 | Composition for treating mask |
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KR20210014643A (en) | 2018-06-01 | 2021-02-09 | 에스테 가부시키가이샤 | Formulation for mask application |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH11246383A (en) * | 1998-02-27 | 1999-09-14 | Osamu Hashiguchi | Essential oil liquid which can be sprayed or applied |
JP2002128680A (en) * | 2000-10-17 | 2002-05-09 | Lion Corp | House dust treatment agent and method for deactivating house dust |
JP2004346467A (en) * | 2003-05-26 | 2004-12-09 | Sakai Ovex Co Ltd | Pollen-preventive fabric |
JP2005218613A (en) * | 2004-02-05 | 2005-08-18 | Iwao Hishida | Sanitary mask |
JP2006187508A (en) * | 2005-01-07 | 2006-07-20 | Iwao Hishida | Mask |
-
2005
- 2005-06-16 JP JP2005176983A patent/JP5072198B2/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH11246383A (en) * | 1998-02-27 | 1999-09-14 | Osamu Hashiguchi | Essential oil liquid which can be sprayed or applied |
JP2002128680A (en) * | 2000-10-17 | 2002-05-09 | Lion Corp | House dust treatment agent and method for deactivating house dust |
JP2004346467A (en) * | 2003-05-26 | 2004-12-09 | Sakai Ovex Co Ltd | Pollen-preventive fabric |
JP2005218613A (en) * | 2004-02-05 | 2005-08-18 | Iwao Hishida | Sanitary mask |
JP2006187508A (en) * | 2005-01-07 | 2006-07-20 | Iwao Hishida | Mask |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011063523A (en) * | 2009-09-15 | 2011-03-31 | Kobayashi Pharmaceutical Co Ltd | Degerming/bactericidal composition for mask |
JP2017075413A (en) * | 2015-10-13 | 2017-04-20 | グンゼ株式会社 | Fiber treatment agent and fiber product with natural derivation essential oil |
WO2022255487A1 (en) * | 2021-06-04 | 2022-12-08 | 株式会社 資生堂 | Composition for treating mask |
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