JP2006328108A - Anti-allergic composition - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide an anti-allergic composition, especially the anti-allergic composition enabling a fiber or a fiber product to be finished without causing discoloration; and to provide the fiber or the fiber product having anti-allergic properties. <P>SOLUTION: The anti-allergic composition contains at least one kind of a compound represented by general formula 1 (wherein, R1 is a 12-18C alkyl group; R2 is an alkyl group having 10C or less; R3 is a methyl group or [CH2CH2O]nH (n=1 or 2); Xm- is a counter ion; and m is a valence of a counter ion). The allergenicity of the allergen such as mite and tick, and pollen can be reduced by the anti-allergic composition and a composition obtained by further adding a cationic resin to the anti-allergic composition, and the function for reducing the allergenicity can be imparted to the fiber or the fiber product such as a carpet, a Tatami mat, beddings, a curtain, clothing, a stuffed toy, a mask, a filter material and a dust-collecting bag for a vacuum cleaner without causing the discoloration by the composition. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

The present invention relates to an anti-allergen composition for reducing the allergenicity of allergens such as mites and pollen, or for imparting a function of reducing allergenicity to fibers or textile products, and processes these anti-allergen compositions Related to the finished fiber or textile product.

  Allergic diseases such as asthma and atopic dermatitis have been plagued by many people for many years. Typical causes of these allergic diseases are ticks, pet hair, pollen, and molds that inhabit indoors. Currently, pharmacotherapy is mainly applied to treat allergic patients, but on the other hand, removing allergens that cause allergies from the patient's own living environment also protects patients from allergen exposure directly. This is a reasonable means. Such symptom improvement by allergen removal has been reported not only in Japan but also in Europe and the United States.

  Textile products in the house, such as tatami mats, carpets, bedding, and curtains, often serve as a hotbed for mite growth, causing allergies to grow and causing problems. There are various types of ticks, such as clams and mites. Among them, Dermatophagoides farinae and Dermatophagoides pteronyssinus are regarded as important causes of mite allergy. These mites are not only mite allergens, but also mite dead bodies and feces are very strong allergens. Mold is likely to occur in humid places and becomes an allergen when inhaled into the lungs. Examples of plant allergens include pollen of various plants, and it is known that pollen such as cedar, cypress, ragweed, green frog, zelkova, mugwort, and hurghaya causes allergies.

  Decorative items made of fibers such as tatami mats, carpets, bedding, curtains, and stuffed animals also have the problem of becoming a source of allergens because of the possibility of tick breeding. The mask is used to prevent inhalation of cedar and other pollen, but the pollen adhering to the mask does not lose its allergenicity, so there is a risk of absorption by scattering again. . A vacuum cleaner is an effective method for removing allergens, but a large amount of allergens contained in the sucked garbage is only stored in the dust bag, and there is a risk that the allergen will re-scatter when the dust bag is discarded. It is done.

  Examples of methods for removing allergens that do not use chemicals include suction with a vacuum cleaner, removal with an air cleaner, and use of a high-density bedding cover. However, there is a limit to the amount of allergens that can be removed only by suction with a vacuum cleaner, and air cleaners remove only allergens that fly in the air. Further, these methods are not always satisfactory, such as the allergen removal from the inside, but not the allergen removal from the outside, in the high density cover of the bedding.

  Various proposals have also been made regarding drugs for reducing or eliminating allergenicity of allergen substances. For example, (Patent Document 1) uses tannic acid as an allergen inactivator, and (Patent Document 2) uses tea extract, hydroxyapatite, epicatechin, epigallocatechin, epicatechin gallate, epigallo. Methods have been proposed in which catechin gallate, gallic acid and esters of gallic acid and alcohols having 1 to 4 carbon atoms are used as allergen inactivating agents. However, these allergen reducing agents have a problem that they are colored or discolored with time when they are attached to fibers or textiles. Therefore, it is difficult to use for spraying on fibers and fiber products, and further, it becomes a problem when processed into fibers and fiber products. As an allergen-reduced fiber, (Patent Document 3) proposes a compound in which an aromatic hydroxy compound is chemically bonded or fixed to a fiber, but the effect of reducing is not sufficient. In addition, (Patent Document 4) proposes a method of processing various plant extract oils into fibers, but these plant extracts volatilize with time, so that they have poor durability and processed into fibers. In some cases, the oil content may deteriorate over time due to oxidation and discoloration.

JP 61-44821 JP-A-6-279273 JP2003-96670A JP-A-10-53532

  An anti-allergen composition that does not change color and reduces the allergenicity of allergens such as mites and pollen, or imparts a function of reducing allergenicity to fibers or textiles, and these anti-allergen compositions It is an object of the present invention to provide a fiber or a fiber product obtained by processing the fiber.

（式中Ｒ１は炭素数１０以上１８以下のアルキル基、Ｒ２は炭素数１０以下のアルキル基、Ｒ３はメチル基または［ＣＨ２ＣＨ２Ｏ］ｎＨ（ｎ＝１または２）、Ｘｍ−は対イオンを示し、ｍは対イオンの価数を示す。）に示す化合物がアレルゲンと反応しアレルゲン性を低減化させる効果を有することを見出し、さらに繊維または繊維製品に加工することによって抗アレルゲン繊維または抗アレルゲン繊維製品を提供できることを見出し本発明に至った。またこれらの抗アレルゲン組成物にカチオン性樹脂を併用することによって耐洗濯性が向上することを見出し本発明に至った。すなわち本発明は、一般式１

（式中Ｒ１は炭素数１０以上１８以下のアルキル基、Ｒ２は炭素数１０以下のアルキル基、Ｒ３はメチル基または［ＣＨ２ＣＨ２Ｏ］ｎＨ（ｎ＝１または２）、Ｘｍ−は対イオンを示し、ｍは対イオンの価数を示す。）に示す化合物の少なくとも一種類を含有することを特徴とする抗アレルゲン組成物および、さらにカチオン性樹脂を含有させた上記抗アレルゲン組成物である。またこれらの抗アレルゲン組成物を加工した繊維または繊維製品である。 In order to solve such a problem, the present inventors have intensively studied and found that the general formula 1

(Wherein R1 is an alkyl group having 10 to 18 carbon atoms, R2 is an alkyl group having 10 or less carbon atoms, R3 is a methyl group or [CH2CH2O] nH (n = 1 or 2), Xm- represents a counter ion, m represents the valence of the counter ion.) It has been found that the compound represented by (2) reacts with the allergen and has an effect of reducing the allergenicity, and is further processed into a fiber or a fiber product, thereby producing an anti-allergen fiber or an anti-allergen fiber product. The present invention was found. In addition, the present inventors have found that the washing resistance is improved by using a cationic resin in combination with these anti-allergen compositions, and have reached the present invention. That is, the present invention relates to the general formula 1

(Wherein R1 is an alkyl group having 10 to 18 carbon atoms, R2 is an alkyl group having 10 or less carbon atoms, R3 is a methyl group or [CH2CH2O] nH (n = 1 or 2), Xm- represents a counter ion, m represents the valence of the counter ion.) An anti-allergen composition characterized in that it contains at least one of the compounds shown in the above), and the anti-allergen composition further containing a cationic resin. The anti-allergen composition is a processed fiber or fiber product.

  By using said composition, the allergenicity of allergens, such as a tick and pollen, can be reduced. Furthermore, the fiber or fiber product which provided the function to reduce allergenicity by processing into a fiber or fiber product can be provided.

（式中Ｒ１は炭素数１０以上１８以下のアルキル基、Ｒ２は炭素数１０以下のアルキル基、Ｒ３はメチル基または［ＣＨ２ＣＨ２Ｏ］ｎＨ（ｎ＝１または２）、Ｘｍ−は対イオンを示し、ｍは対イオンの価数を示す。）に示す化合物で、対イオンはフッ素イオン、塩素イオン、臭素イオン、ヨウ素イオン、炭酸イオン、リン酸イオン、硫酸イオン等の無機イオン、あるいは酢酸イオン、プロピオン酸イオン等の有機酸イオンいずれでも差し支えないが、塩素イオンが好ましい。本発明に用いられる化合物としては、例えば塩化ジデシルジメチルアンモニウム（Ｒ１：Ｃ１０Ｈ２１、Ｒ２：Ｃ１０Ｈ２１、Ｒ３：ＣＨ３、Ｘ：Ｃｌ、ｍ＝１）、塩化ステアリルトリメチルアンモニウム（Ｒ１：Ｃ１８Ｈ３７、Ｒ２：ＣＨ３、Ｒ３：ＣＨ３、Ｘ：Ｃｌ、ｍ＝１）、塩化セチルトリメチルアンモニウム（Ｒ１：Ｃ１６Ｈ３３、Ｒ２：ＣＨ３、Ｒ３：ＣＨ３、Ｘ：Ｃｌ、ｍ＝１）、ジデシルメチルジオキシエチルアンモニウムプロピオネート（Ｒ１：Ｃ１０Ｈ２１、Ｒ２：Ｃ１０Ｈ２１、Ｒ３：ＣＨ２ＣＨ２ＯＣＨ２ＣＨ２ＯＨ、ｎ＝２、Ｘ：Ｃ２Ｈ５ＣＯＯ、ｍ＝１）等が挙げられる。抗アレルゲン組成物中のこれらの成分の含有率は、散布剤として使用する場合０．０１〜３０重量％が好ましく、０．１〜１０重量％がより好ましい。繊維または繊維製品への加工剤の場合には０．０１〜７０重量％が好ましく、０．１〜５０重量％がより好ましい。 The anti-allergen component in the anti-allergen composition of the present invention has the general formula 1

(Wherein R1 is an alkyl group having 10 to 18 carbon atoms, R2 is an alkyl group having 10 or less carbon atoms, R3 is a methyl group or [CH2CH2O] nH (n = 1 or 2), Xm- represents a counter ion, m represents a valence of a counter ion.) The counter ion is an inorganic ion such as a fluorine ion, a chlorine ion, a bromine ion, an iodine ion, a carbonate ion, a phosphate ion or a sulfate ion, or an acetate ion or propion. Any organic acid ions such as acid ions can be used, but chlorine ions are preferred. Examples of the compound used in the present invention include didecyldimethylammonium chloride (R1: C10H21, R2: C10H21, R3: CH3, X: Cl, m = 1), stearyltrimethylammonium chloride (R1: C18H37, R2: CH3, R3: CH3, X: Cl, m = 1), cetyltrimethylammonium chloride (R1: C16H33, R2: CH3, R3: CH3, X: Cl, m = 1), didecylmethyldioxyethylammonium propionate ( R1: C10H21, R2: C10H21, R3: CH2CH2OCH2CH2OH, n = 2, X: C2H5COO, m = 1). The content of these components in the anti-allergen composition is preferably 0.01 to 30% by weight, more preferably 0.1 to 10% by weight when used as a spraying agent. In the case of a processing agent for fibers or fiber products, the content is preferably 0.01 to 70% by weight, more preferably 0.1 to 50% by weight.

  As long as the dosage form of the anti-allergen composition of the present invention can be processed in an environment in which the allergen is present, or can be processed into fibers and fiber products, any form such as liquid, powder, paste, etc. The dosage form may be used, but the liquid form is easy to handle and effective. In order to carry out such a preparation, a solvent suitable for dissolving or dispersing the compound represented by the general formula 1 can be used alone or as a mixed solvent of two or more kinds. The solvent is not particularly limited, but for example, water, methyl alcohol, ethyl alcohol, isopropyl alcohol, benzyl alcohol, acetic acid, acetone, dimethylformamide, dimethylacetamide, dimethyl sulfoxide, ethylene glycol, propylene glycol, diethylene glycol, triethylene glycol, dipropylene Polar solvents such as glycol, hexylene glycol, polyethylene glycol, glycerin, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, diethylene glycol monoethyl ether acetate, γ-butyrolactone, sulfolane , Jime Use nonpolar solvents such as lunaphthalene, dodecylbenzene, liquid paraffin, isophorone, kerosene, dibutyl adipate, diethyl phthalate, diethylene glycol monobutyl ether acetate, propylene carbonate, coconut oil, rapeseed oil, cottonseed oil, castor oil, soybean oil, etc. be able to. Usually, polar solvents such as water, alcohols and glycol ethers are used.

  When the anti-allergen composition of the present invention is used for the purpose of removing allergens from indoor dust mites, the anti-allergen effect can be further maintained by processing simultaneously with the acaricide. The acaricide used is not particularly limited as long as it has a lethal and repellent effect on indoor dust mites. For example, benzyl alcohol, benzyl benzoate, phenyl salicylate, cinnamaldehyde, hyssop oil, carrot seed oil In addition, pyrethroid compounds such as natural pyrethrin, phenothrin, and permethrin, organophosphorus compounds such as fenitrothion, malathion, fenthion, and diazinon, dicophore, chlorbenzilate, hexityazox, tebufenpyrad, pyridaben, etc. it can.

  The anti-allergen composition of the present invention may be worried about the growth of mold or fungi. Therefore, it is possible to use a fungicide or an antibacterial agent at the same time. The type of the fungicide or antibacterial agent is not particularly limited as long as it has a fungicide or antibacterial effect. For example, 5-chloro-N-methylisothiazolone, methylenebisthiocyanate, 2-bromo-2-nitropropane-1 , 3-diol, glutaraldehyde, iodopropynyl butyl carbamate, zinc salt of pyridinethiol-N-oxide, 1,2-benzisothiazolone, 1,2-dibromo-2,4-dicyanobutane, chlorhexidine gluconate, 2-isopropyl -5-methylphenol, 3-methyl-4-isopropylphenol, orthophenylphenol, methyl paraoxybenzoate, ethyl paraoxybenzoate, propyl paraoxybenzoate, butyl paraoxybenzoate, parachlorometaxylenol, parachlorometacres , Polylysine, benzalkonium chloride, didecyldimethylammonium chloride, Nn-butylbenzisothiazolone, N-octylisothiazolone, 2- (4-thiazolyl) benzimidazole, methyl 2-benzimidazolylcarbamate, tetrachloroiso Phthalonitrile, diiodomethyl paratolyl sulfone, parachlorophenyl-3-iodopropargyl formal, 2,3,5,6-tetrachloro-4- (methylsulfonyl) pyridine, fatty acid glycerin ester, hinokitiol and the like can be used. .

  The usage form of the anti-allergen composition of the present invention can be in a convenient form such as an aqueous solution, spray, aerosol, paste, powder, etc., but is not particularly limited. Compositions that may come into contact with people in the environment, such as detergents, soaps, shampoos, textile processing agents, softeners, deodorants, fungicides, disinfectants, insecticides, paints, adhesives, etc. It is also possible to reduce allergens in the environment by adding to the material, materials that may come into contact with people in the environment, such as building materials such as wood, concrete, metal, stone, glass, rubber, paper It is also possible to reduce allergens in the environment by processing into molded articles made of resin or plastic. When used as a spray, it is preferable to add a water-soluble resin in order to prevent powdering after drying. Such a water-soluble resin is not particularly limited, and examples thereof include polyvinyl alcohol, polyacrylic acid (salt), polyethylene glycol, and polyvinyl pyrrolidone.

  The anti-allergen composition of the present invention can be further improved in washing resistance by processing into a fiber or fiber product in combination with a binder. Nonionic and cationic resins can be used as the binder, but it is preferable to use a cationic resin in combination. Although the cationic resin is not particularly limited, for example, polyacrylic acid ester, polymethacrylic acid ester or a copolymer thereof having a cationic quaternary ammonium base in the side chain, an amino group or quaternary ammonium base in the side chain. Modified silicone resin having Examples of methacrylic acid or acrylic acid ester monomers having a cationic quaternary ammonium base used in polyacrylic acid esters, polymethacrylic acid esters or copolymers thereof include 2-methacryloyloxyethyltrimethylammonium chloride, chloride Examples thereof include 2-methacryloyloxyethyltriethylammonium chloride, 2-acryloyloxyethyltrimethylammonium chloride, and 2-acryloyloxyethyltriethylammonium chloride. Two or more of these may be used in combination. Examples of acrylic acid or methacrylic acid alkyl ester monomers for obtaining a copolymer include methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, and the like. It doesn't matter. The polymerization can be performed using ammonium persulfate or the like, and the molecular weight is preferably 20000 or more. An example of the modified silicone resin having an amino group in the side chain is an amino-modified silicone resin, and the amino group may be any one of the first to third grades. When these binders are blended in the anti-allergen composition, the content is preferably 70% by weight or less, and more preferably 50% by weight or less.

  There are various types of fibers that can be used to process the anti-allergen composition of the present invention, and examples thereof include nylon, cotton, polyester, wool, and the like, and a composite fiber using two or more of these fibers. There is no problem. A method for processing the anti-allergen composition of the present invention into a fiber or a fiber product is not particularly limited, and immersion treatment, spray treatment, exhaustion processing, and the like can be performed. The concentration used is 0.1-5.0% o. w. f, more preferably 0.5 to 2.0% o. w. f.

  In formulating the anti-allergen composition of the present invention, in addition to the above-mentioned solvent, anti-mite agent, anti-bacterial agent, binder, chelating agent, anti-rust agent, thickener, perfume, scale inhibitor, as necessary, Surfactants, pH adjusters, antifoaming agents, antistatic agents, softening agents, and the like can be added.

  The method of using the anti-allergen composition of the present invention includes spraying agents for treating objects in the environment such as carpets, tatami mats, bedding, and curtains contaminated with allergens, and these objects have anti-allergen functions. The processing agent for giving it can be considered. It is also possible to obtain textiles and textiles that reduce allergens in the environment by processing into textiles such as clothing, stuffed animals, masks, filter materials, and vacuum cleaner dust bags. The environment of the present invention refers to bedding such as carpets, tatami mats, floors, floor covers, futons, sofas, stuffed animals, clothes, curtains, etc. that are in direct contact with people, such as clothes, closets, etc. The space of the place where the house is stored or the living space in the house. There is an advantage that coloring of an object hardly occurs by the application or processing of the present invention.

  By using the composition of the present invention and the fiber or fiber product of the present invention, allergens derived from mites in house dust, pet hair and epithelium such as dogs and cats, cockroaches, feathers, fungi allergens, and plant allergens It can be reduced and various allergens can be substantially eliminated. Therefore, the present invention works particularly effectively when the allergen in the environment is a mite allergen or a plant allergen in house dust.

The present invention will be described in more detail with reference to examples and test examples, but the present invention is not limited thereto.
(Anti-allergen composition example)
The following composition shown in Table 1 was sufficiently stirred to obtain a uniform solution. Table 2 shows the groups in the general formula 1 of each compound. In addition, all the mixture ratios shown in the table are% by weight.

＊：東レ・ダウコーニング社製

*: Toray Dow Corning

(Test Example 1) Measurement of mite allergen reducing effect of anti-allergen composition Examples 1 to 4 for mite allergen Derf2 of about 2 μg / 1 mL {phosphate buffer (pH 7.2)} contained in standard house dust. Was reacted with 0.15 mL. About these samples, the mite allergen reduction effect was measured by the sandwich method of the Derf2 enzyme immunoassay (ELISA). First, 100 μL of Derf2 monoclonal antibody 15E11 diluted to 2 μg / mL with phosphate buffer (pH 7.4, containing 0.1 wt% NaN 3) per well of F16 MAXISORP NUNC-IMMUNO MODULE plate (manufactured by NUNC) Added and sensitized for more than 1 day at 4 ° C. After the sensitization, the solution is discarded, and a blocking reagent {1 wt% bovine serum albumin + phosphate buffer (pH 7.2, containing 0.1 wt% NaN3)} is added in an amount of 100 μL per well, at 37 ° C. for 60 minutes. Reacted. After the reaction, the plate was washed with a phosphate buffer (pH 7.2, containing 0.1 wt% polyoxyethylene (20) sorbitan monolaurate). Next, 100 μL of the extract obtained by reacting the mite allergen and the above composition was added dropwise per well and reacted at 37 ° C. for 60 minutes. After the reaction, the plate was washed with a phosphate buffer (pH 7.2, containing 0.1 wt% polyoxyethylene (20) sorbitan monolaurate). The peroxidase-labeled Derf2 monoclonal antibody was dissolved in distilled water at 200 μg / mL, and was dissolved in phosphate buffer {pH 7.2, 1% by weight bovine serum albumin and 0.1% by weight polyoxyethylene (20) sorbitan monolaurate. The solution diluted 1000-fold with “containing” was added at 100 μL per well. After reacting at 37 ° C. for 60 minutes, the plate was first washed with a phosphate buffer (pH 7.2, containing 0.1 wt% polyoxyethylene (20) sorbitan monolaurate) and then with distilled water. 100 μL per well of orthomolten phenylenediamine dihydrochloride (26 mg Table, manufactured by SIGMA CHEMICAL CO.) And 13 μL of hydrogen peroxide was added to 13 mL of 0.1 mol / L phosphate buffer (pH 6.2). And allowed to react at 37 ° C. for 5 minutes. Immediately thereafter, 50 μL of 2 mol / L H 2 SO 4 was added to stop the reaction, and the absorbance (OD 490 nm) was measured with a spectrophotometer for microplate (manufactured by Bio-Rad Laboratories Inc.). The results are shown in Table 3.

(Test Example 2)
Measurement of effect of reducing mite allergen by processed fiber product 5% aqueous solution of tannic acid (corresponding to Japanese Patent Laid-Open No. Sho 61-44821) was applied to cotton broad cloth (white) as Example 5 or Comparative Example by 2.0% o. w. The film was immersed in f at 25 ° C. for 20 minutes, treated at a squeezing rate of 100%, and dried at 105 ° C. Allergen reduction tests were conducted on the fabrics that had been washed 10 times as they were. The washing method is a household washing machine, using “JAFET detergent” (textile product new function evaluation council) as a detergent, adding 40 ml to 30 liters of warm water at 40 ° C., washing for 5 minutes, rinsing for 2 minutes Was performed twice and then dehydrated. This operation was repeated 10 times. 0.005 g of standard house dust is adhered to the fabric before and after washing (5 cm x 5 cm), and after 1 hour, it is put into a plastic bag with a chuck and extracted with 10 ml of skim milk-containing phosphate buffer (pH 7.2). did. About these samples after centrifugation, the mite allergen reduction effect was measured by the sandwich method of the Derf2 enzyme immunoassay (ELISA). First, 100 μL of Derf2 monoclonal antibody 15E11 diluted to 2 μg / mL with phosphate buffer (pH 7.4, containing 0.1 wt% NaN 3) per well of F16 MAXISORP NUNC-IMMUNO MODULE plate (manufactured by NUNC) Added and sensitized for more than 1 day at 4 ° C. After the sensitization, the solution is discarded, and a blocking reagent {1 wt% bovine serum albumin + phosphate buffer (pH 7.2, containing 0.1 wt% NaN3)} is added in an amount of 100 μL per well, at 37 ° C. for 60 minutes. Reacted. After the reaction, the plate was washed with a phosphate buffer (pH 7.2, containing 0.1 wt% polyoxyethylene (20) sorbitan monolaurate). Next, 100 μL of the extract obtained by reacting the mite allergen and the above composition was added dropwise per well and reacted at 37 ° C. for 60 minutes. After the reaction, the plate was washed with a phosphate buffer (pH 7.2, containing 0.1 wt% polyoxyethylene (20) sorbitan monolaurate). The peroxidase-labeled Derf2 monoclonal antibody was dissolved in distilled water at 200 μg / mL, and was dissolved in phosphate buffer {pH 7.2, 1% by weight bovine serum albumin and 0.1% by weight polyoxyethylene (20) sorbitan monolaurate. The solution diluted 1000-fold with “containing” was added at 100 μL per well. After reacting at 37 ° C. for 60 minutes, the plate was first washed with a phosphate buffer (pH 7.2, containing 0.1 wt% polyoxyethylene (20) sorbitan monolaurate) and then with distilled water. 100 μL per well of orthomolten phenylenediamine dihydrochloride (26 mg Table, manufactured by SIGMA CHEMICAL CO.) And 13 μL of hydrogen peroxide was added to 13 mL of 0.1 mol / L phosphate buffer (pH 6.2). And allowed to react at 37 ° C. for 5 minutes. Immediately thereafter, 50 μL of 2 mol / L H 2 SO 4 was added to stop the reaction, and the absorbance (OD 490 nm) was measured with a spectrophotometer for microplate (manufactured by Bio-Rad Laboratories Inc.). In addition, the appearance was observed to confirm the presence or absence of discoloration. The results are shown in Table 4.

According to the present invention, the allergenicity of allergens such as mites and pollen can be reduced, and an anti-allergen composition that does not change color for imparting a function of reducing the allergenicity to fibers or textiles, And a fiber or a fiber product capable of reducing allergens.

Claims (4)

General formula 1

(Wherein R1 is an alkyl group having 10 to 18 carbon atoms, R2 is an alkyl group having 10 or less carbon atoms, R3 is a methyl group or [CH2CH2O] nH (n = 1 or 2), Xm- represents a counter ion, m represents the valence of a counter ion). General formula 1

(Wherein R1 is an alkyl group having 10 to 18 carbon atoms, R2 is an alkyl group having 10 or less carbon atoms, R3 is a methyl group or [CH2CH2O] nH (n = 1 or 2), Xm- represents a counter ion, 2. The antiallergen composition according to claim 1, wherein m represents a valence of a counter ion, and contains a cationic resin. General formula 1

(Wherein R1 is an alkyl group having 10 to 18 carbon atoms, R2 is an alkyl group having 10 or less carbon atoms, R3 is a methyl group or [CH2CH2O] nH (n = 1 or 2), Xm- represents a counter ion, The anti-allergen composition according to claim 2, wherein the compounding ratio of the compound represented by (m represents a valence of a counter ion) is 0.01% or more and 30% or less, and the cationic resin is 70% or less. . A fiber or a fiber product obtained by processing the anti-allergen composition according to claim 1.