JP2006305518A - Method and apparatus for dewatering sludge - Google Patents
Method and apparatus for dewatering sludge Download PDFInfo
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- JP2006305518A JP2006305518A JP2005134016A JP2005134016A JP2006305518A JP 2006305518 A JP2006305518 A JP 2006305518A JP 2005134016 A JP2005134016 A JP 2005134016A JP 2005134016 A JP2005134016 A JP 2005134016A JP 2006305518 A JP2006305518 A JP 2006305518A
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- QHVBLSNVXDSMEB-UHFFFAOYSA-N 2-(diethylamino)ethyl prop-2-enoate Chemical compound CCN(CC)CCOC(=O)C=C QHVBLSNVXDSMEB-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/10—Biological treatment of water, waste water, or sewage
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- Aeration Devices For Treatment Of Activated Polluted Sludge (AREA)
- Treatment Of Sludge (AREA)
- Filtration Of Liquid (AREA)
Abstract
Description
本発明は、下水処理施設、し尿処理施設その他排水処理施設から発生する汚泥の脱水処理方法及び装置に関する。 The present invention relates to a method and apparatus for dewatering sludge generated from sewage treatment facilities, human waste treatment facilities and other wastewater treatment facilities.
一般に、排水処理、し尿処理、下水処理などの活性汚泥処理工程から発生する汚泥は、場合によっては濃縮後、高分子凝集剤の添加により凝集させ、機械脱水処理により脱水される。近年、各種製造工場における生産品目の多様化や居住民の生活様式の多様化により、工場排水や家庭排水などの下水の性状が変化したことに起因して、活性汚泥処理工程から発生する汚泥は凝集し難くなっており、脱水処理後の汚泥の含水率が低下し難くなっている。 In general, sludge generated from an activated sludge treatment process such as wastewater treatment, human waste treatment, sewage treatment, or the like is sometimes condensed and then agglomerated by addition of a polymer flocculant and dehydrated by mechanical dehydration treatment. In recent years, sludge generated from the activated sludge treatment process due to changes in the quality of sewage such as factory wastewater and household wastewater due to diversification of production items at various manufacturing plants and lifestyles of residents Aggregation is difficult, and the water content of the sludge after dehydration is difficult to decrease.
特に、下水処理にオキシデーションディッチ処理法を採用した場合に発生する汚泥は、混合生汚泥、標準活性汚泥、消化汚泥などに比較して、脱水性が非常に悪い。これは、オキシデーションディッチ処理法が、機械撹拌と散気とを同時に行う処理法であることから、他の処理法に比較して、曝気時間が長期化するので被処理水の硝化・脱窒が進行して、凝集の核となる汚泥中の繊維分が分解消費されてしまうためであると考えられる。
同様にし尿処理施設から発生する汚泥も、生物処理前段に設けられているスクリーンにより殆どの夾雑物が除去され、発生する汚泥には繊維分が少なくなるため、汚泥脱水処理により汚泥の含水率を低下させることが難しい。
In particular, the sludge generated when the oxidation ditch treatment method is used for sewage treatment is very poor in dehydration compared with mixed raw sludge, standard activated sludge, digested sludge and the like. This is because the oxidation ditch treatment method is a treatment method in which mechanical agitation and aeration are performed simultaneously, and the aeration time is prolonged compared to other treatment methods. This is considered to be because the fiber content in the sludge that becomes the core of aggregation is decomposed and consumed.
Similarly, most of the sludge generated from the urine treatment facility is removed by the screen provided before the biological treatment, and the generated sludge has less fiber content. It is difficult to reduce.
一方、廃棄物の再利用の観点から汚泥のコンポスト化が推進されている。コンポスト化処理に供する場合、含水率が高すぎるとべたついて供給装置からの定量供給が困難となるので対象汚泥の含水率は極力低下させておく必要がある。また、コンポスト化においては、脱水処理用薬剤等は微生物で分解されるものでなければならない。 On the other hand, composting of sludge is promoted from the viewpoint of recycling waste. In the case of composting treatment, if the water content is too high, it becomes sticky and it becomes difficult to quantitatively supply from the supply device, so it is necessary to reduce the water content of the target sludge as much as possible. In composting, dehydration chemicals and the like must be decomposed by microorganisms.
これまで、汚泥の含水率を低下させる手段として汚泥に繊維状物またはおが屑や籾殻等の植物素材を混合した後、高分子凝集剤を添加し脱水する方法が提案されている(特開昭56-198200号公報及び特開昭60-25595号公報)。しかしながら、汚泥に繊維状物を混合する方法では、繊維状物の汚泥への定量添加や繊維状物の親水性が不十分な場合には汚泥中での開繊が困難で、汚泥へ均一に混合することができず、そのため安定した処理ができない場合がある。また、繊維状物の中には微生物で分解され難いものもあり、コンポスト化には不向きな場合もある。一方、おが屑や籾殻等の植物素材を混合する方法は、汚泥固形物に対する添加量が一般に10〜100%程度であり、脱水可能な凝集フロックを生成させるのに高分子凝集剤添加量が増大する傾向があり、汚泥処理コストの上昇が避けられない。また、植物の種類によっては撥水性を有するため汚泥へ馴染ませることが難しい場合もある。 Until now, as a means for reducing the moisture content of sludge, there has been proposed a method in which a fibrous material or a plant material such as sawdust or rice husk is mixed with sludge, and then a polymer flocculant is added to dehydrate (JP-A-56). -198200 and JP-A-60-25595). However, in the method of mixing the fibrous material with the sludge, if the quantitative addition of the fibrous material to the sludge or the hydrophilicity of the fibrous material is insufficient, it is difficult to open the fiber in the sludge, and evenly into the sludge. In some cases, mixing cannot be performed, and thus stable processing cannot be performed. Also, some fibrous materials are difficult to be decomposed by microorganisms and may not be suitable for composting. On the other hand, in the method of mixing plant materials such as sawdust and rice husk, the amount added to the sludge solids is generally about 10 to 100%, and the amount of the polymer flocculant added is increased to generate a dewaterable aggregated floc. There is a tendency to increase the sludge treatment cost. Moreover, since it has water repellency depending on the kind of plant, it may be difficult to adjust to sludge.
また、特に下水処理施設から発生する汚泥に関しては硫化水素やメチルメルカプタン等の悪臭物質が発生し易く、脱水処理施設付近や脱水ケーキの貯留や搬送時の作業環境が問題になっている。そのため脱水処理時に鉄化合物や亜鉛化合物等の金属化合物あるいは次亜塩素酸塩等の消臭剤が汚泥に添加されることが行われているが、これらの消臭剤は脱水汚泥をコンポストやセメント原料として使用する際に障害となる場合があり、用途に制限がある。 In particular, sludge generated from sewage treatment facilities is likely to generate malodorous substances such as hydrogen sulfide and methyl mercaptan, and there is a problem in the vicinity of the dehydration treatment facility and the working environment during storage and transport of the dehydrated cake. For this reason, metal compounds such as iron compounds and zinc compounds or deodorizers such as hypochlorite are added to the sludge during the dehydration process. These deodorizers are used as compost or cement. When used as a raw material, it may be an obstacle, and there is a limitation in use.
また、難脱水性汚泥を機械的に脱水させる方法として、特に近年、スクリュープレス脱水機が中規模下水処理場において採用されつつある。しかしながら、難脱水性汚泥を対象としているために、高分子凝集剤による調質が不十分であると強固な凝集フロックが形成されず、脱水ケーキ含水率が低下せず、固形物回収率も低下するので、安定した運転が難しい。その対策として無機凝集剤で調質した後、高分子凝集剤で凝集させる方法も採用されているが、この場合には、高分子凝集剤の添加量が多くなり、処理費用が増加し、汚泥の性状変動に対応した調質条件を調整しなければならず、かえって運転が煩雑になる場合もある。 Moreover, as a method of mechanically dewatering hardly dewatering sludge, a screw press dewatering machine has been adopted in a medium-scale sewage treatment plant in recent years. However, because it is intended for difficult-to-dewater sludge, if the refining with the polymer flocculant is insufficient, a strong flocs flocs will not be formed, the water content of the dehydrated cake will not decrease, and the solids recovery rate will also decrease Therefore, stable driving is difficult. As a countermeasure, a method of tempering with an inorganic flocculant and then flocculating with a polymer flocculant is also employed, but in this case, the amount of the polymer flocculant added is increased, the treatment cost increases, and sludge The tempering conditions corresponding to the fluctuations in the properties must be adjusted, and the operation may be complicated.
本発明は、上述の問題を解決することができる汚泥脱水処理方法を提供することを目的とする。特に、難脱水性の汚泥から、低含水率で臭気発生の少ない脱水ケーキを安定して形成することができる汚泥脱水処理方法を提供することを目的とする。 An object of this invention is to provide the sludge dehydration processing method which can solve the above-mentioned problem. In particular, an object of the present invention is to provide a sludge dewatering method that can stably form a dehydrated cake with low moisture content and low odor generation from hardly dewatered sludge.
上記課題を解決するべく鋭意研究の結果、本発明者らは、笹の葉及び/又は竹の葉の粉砕物を利用することによって、難脱水性の汚泥から、低含水率で臭気発生の少ない脱水ケーキを安定して形成することができることを知見して、本発明をなすに至った。 As a result of earnest research to solve the above-mentioned problems, the present inventors have used pulverized material of bamboo leaves and / or bamboo leaves to generate low odor and low odor from hardly dewatering sludge. Knowing that a dehydrated cake can be formed stably, the present invention has been made.
具体的には、本発明によれば、汚泥に笹の葉及び/又は竹の葉の粉砕物を混合させて混合汚泥を形成する工程と、得られた混合汚泥に高分子凝集剤を添加して凝集フロックを形成させる工程と、得られた凝集フロックを機械脱水する工程と、を含む汚泥脱水処理方法が提供される。 Specifically, according to the present invention, a step of mixing sludge with bamboo leaf and / or bamboo leaf pulverized material to form mixed sludge, and adding a polymer flocculant to the obtained mixed sludge. Thus, there is provided a sludge dewatering method including a step of forming agglomerated floc and a step of mechanically dewatering the obtained agglomerated floc.
本発明の脱水処理対象となる汚泥は、一般の排水処理、し尿処理、下水処理における活性汚泥処理工程から発生する汚泥であれは種類を問わないが、特にオキシデーションディッチ法から発生する余剰汚泥やし尿処理施設から発生する汚泥は、凝集性が不良で、脱水汚泥の含水率が低下し難いことから、本発明の効果が最も発揮できる。 The sludge to be subjected to the dehydration treatment of the present invention is not limited to the type of sludge generated from the activated sludge treatment process in general wastewater treatment, human waste treatment, and sewage treatment, but surplus sludge generated from the oxidation ditch method in particular. Since the sludge generated from the human waste treatment facility has poor cohesiveness and the water content of the dewatered sludge is difficult to decrease, the effect of the present invention can be exhibited most.
本発明において用いる笹の葉及び/又は竹の葉の粉砕物としては、ミヤコザサ、チマキザサ、チュウゴクザサ、カムロザサ、クマザサ、オカメザサ等の葉の他、オロシマチク、ホテイチク、モウソウチク、シホウチク、クロチク、トウチク、ナリヒラダケ、ヤダケ、マダケ等の葉の粉砕物を挙げることができる。これらのうち最も好ましいのはクマザサの葉の粉砕物である。これらに含まれる繊維分は強固であるので、これらを取り込んだ凝集フロックの強度が高分子凝集剤のみを使用する場合に比較して大きくなり、脱水機内で圧搾される際に抵抗が大きくなることで、脱水しやすくなるのみならず、汚泥の臭気抑制効果もある。このような効果は他の植物系粉砕物では得ることができない。 As pulverized products of bamboo leaves and / or bamboo leaves used in the present invention, in addition to leaves such as Miyakozasa, Chimakazasa, Chugokusa, Kamurozasa, Kumazasa, Okamesa, etc. Mention may be made of pulverized leaves such as mushrooms and mushrooms. The most preferable of these is a ground product of Kumazasa leaves. Since the fibers contained in these are strong, the strength of the flocs that incorporate them increases compared to the case where only the polymer flocculant is used, and the resistance increases when squeezed in the dehydrator. In addition to being easy to dehydrate, it also has an effect of suppressing the odor of sludge. Such an effect cannot be obtained with other plant-based pulverized products.
粉砕物は、葉をそのまま粉砕したものでも、あるいは乾燥させてから粉砕したものでもよい。粉砕方法としては、公知の粉砕方法を用いることができる。
また、ササエキス製造時に発生する残渣等も使用可能である。このような残渣等を利用する場合には、特に最近の健康食品ブームに乗って、クマザサ抽出エキスの製造が盛んであるが、抽出物残渣が多量に発生することによる廃棄物処理問題を解決することもできる。
The pulverized product may be obtained by pulverizing leaves as they are or by pulverizing them after drying. As the pulverization method, a known pulverization method can be used.
Moreover, the residue etc. which generate | occur | produce at the time of Sasa extract manufacture can also be used. In the case of using such residues, etc., especially on the recent health food boom, the production of Kumazasa extract is thriving, but it solves the waste disposal problem caused by the large amount of extract residue You can also.
本発明において、汚泥に添加する笹の葉及び/又は竹の葉の粉砕物の形状は、1〜30mm、好ましくは2〜10mm程度の長さ寸法としておくことが汚泥への添加、混合また脱水時の作業性から好ましい。 In the present invention, the shape of the pulverized bamboo leaf and / or bamboo leaf added to the sludge is 1 to 30 mm, preferably about 2 to 10 mm in length. Addition to sludge, mixing or dehydration It is preferable from the workability of time.
また、笹の葉及び/又は竹の葉の粉砕物は、乾燥物、含水物いずれも使用可能であるが抽出物残渣の場合のような含水物は汚泥への供給を安定させるために含水率を一定としておくことが好ましい。好ましい含水率の範囲は、60%以下である。含水率があまり高すぎると、べたついて供給装置からの定量供給が困難になる。 In addition, the crushed material of bamboo leaves and / or bamboo leaves can be either dried or hydrated, but the hydrated material as in the case of the extract residue has a moisture content to stabilize the supply to the sludge. Is preferably constant. A preferable moisture content range is 60% or less. If the water content is too high, it becomes sticky and it becomes difficult to supply a fixed amount from the supply device.
本発明の方法において汚泥に対する笹の葉及び/又は竹の葉の粉砕物の混合割合は、各汚泥の濃度により変動し得るが、汚泥中のSS分に対して、一般的には0.1〜20重量%、好ましくは1〜10重量%とすることが好ましい。0.1重量%未満では含水率低減効果が無く、20重量%を超えるとそれ以上の含水率低減効果は無くなり、またケーキ発生量も増加するので経済的に好ましくない。 In the method of the present invention, the mixing ratio of the pulverized material of bamboo leaves and / or bamboo leaves to sludge can vary depending on the concentration of each sludge, but is generally 0.1 for the SS content in the sludge. -20% by weight, preferably 1-10% by weight. If it is less than 0.1% by weight, there is no effect of reducing the moisture content, and if it exceeds 20% by weight, the effect of further reducing the moisture content is lost, and the amount of cake generated increases, which is economically undesirable.
また本発明において、笹の葉及び/又は竹の葉の粉砕物には、汚泥処理に一般的に使用されている消泡剤や消臭剤を予め含浸させておいてもよい。また、他の天然繊維の粉砕物等も混合して使用しても良い。 In the present invention, the pulverized product of bamboo leaf and / or bamboo leaf may be impregnated in advance with a defoaming agent or deodorant generally used for sludge treatment. Further, other natural fiber pulverized products may also be used in combination.
本発明においては、笹の葉及び/又は竹の葉の粉砕物を混合させた汚泥混合物に、高分子凝集剤を添加する。高分子凝集剤の添加により、凝集の核となる笹の葉及び/又は竹の葉の粉砕物の周囲に汚泥が凝集して、凝集フロックを形成する。また、繊維分が脱水機内で圧搾される際の抵抗となり、脱水しやすくなる。 In the present invention, a polymer flocculant is added to a sludge mixture obtained by mixing pulverized material of bamboo leaves and / or bamboo leaves. By the addition of the polymer flocculant, sludge is aggregated around the pulverized material of bamboo leaves and / or bamboo leaves which are the core of aggregation, forming aggregated flocs. Moreover, it becomes resistance at the time of a fiber part being squeezed within a dehydrator, and becomes easy to dehydrate.
本発明において用いられる高分子凝集剤としては、アニオン系高分子凝集剤、ノニオン系高分子凝集剤及びカチオン系高分子凝集剤を好ましく挙げることができ、特にカチオン系高分子凝集剤及び両性高分子凝集剤が好ましい。 Preferred examples of the polymer flocculant used in the present invention include anionic polymer flocculants, nonionic polymer flocculants, and cationic polymer flocculants, and in particular, cationic polymer flocculants and amphoteric polymers. Flocculants are preferred.
カチオン系高分子凝集剤としては、カチオン性モノマーを必須成分として有し、カチオン性モノマーの共重合体又はカチオン性モノマーとノニオン性モノマーとの共重合体からなるカチオン系高分子凝集剤、及び分子内にアミジン単位を有するカチオン系高分子凝集剤を好ましく用いることができる。カチオン性モノマーとしては、ジメチルアミノエチルアクリレート、ジメチルアミノエチルメタクリレート、ジエチルアミノエチルアクリレート、ジエチルアミノエチルメタクリレートもしくはこれらの中和塩、4級塩及びこれらの組み合わせなどを好ましく挙げることができる。ノニオン性モノマーとしては、アクリルアミド、メタクリルアミド、メタアクリロニトリル、酢酸ビニル等及びこれらの組み合わせを好ましく挙げることができる。本発明において用いることができるカチオン性モノマーとノニオン性モノマーとの共重合体からなるカチオン系高分子凝集剤としては、例えば、ジメチルアミノエチルアクリレート及び/又はジメチルアミノエチルメタクリレートの塩化メチル4級化物/アクリルアミド共重合体、を好ましく挙げることができる。また、本発明において用いることができる分子内にアミジン単位を有するカチオン系高分子凝集剤としては、例えば、N−ビニルホルムアミド/アクリロニトリル共重合体のアミジン化物を好ましく挙げることができる。 As the cationic polymer flocculant, a cationic polymer flocculant having a cationic monomer as an essential component and comprising a copolymer of a cationic monomer or a copolymer of a cationic monomer and a nonionic monomer, and a molecule A cationic polymer flocculant having an amidine unit therein can be preferably used. Preferred examples of the cationic monomer include dimethylaminoethyl acrylate, dimethylaminoethyl methacrylate, diethylaminoethyl acrylate, diethylaminoethyl methacrylate, neutralized salts, quaternary salts thereof, and combinations thereof. Preferred examples of the nonionic monomer include acrylamide, methacrylamide, methacrylonitrile, vinyl acetate, and combinations thereof. Examples of the cationic polymer flocculant composed of a copolymer of a cationic monomer and a nonionic monomer that can be used in the present invention include dimethylaminoethyl acrylate and / or methyl chloride quaternized product of dimethylaminoethyl methacrylate / An acrylamide copolymer can be preferably mentioned. Moreover, as a cationic high molecular flocculant which has an amidine unit in the molecule | numerator which can be used in this invention, the amidine thing of an N-vinylformamide / acrylonitrile copolymer can be mentioned preferably, for example.
両性高分子凝集剤としては、カチオン性モノマー単位、アニオン性モノマー単位及びノニオン性モノマー単位の共重合体を好ましく用いることができる。本発明において用いることができる両性高分子凝集剤としては、例えば、ジメチルアミノエチルアクリレート及び/又はジメチルアミノエチルメタクリレートの塩化メチル4級化物/アクリルアミド/アクリル酸共重合体を好ましく挙げることができる。 As the amphoteric polymer flocculant, a copolymer of a cationic monomer unit, an anionic monomer unit and a nonionic monomer unit can be preferably used. Preferred examples of the amphoteric polymer flocculant that can be used in the present invention include dimethylaminoethyl acrylate and / or dimethylaminoethyl methacrylate methyl chloride quaternized / acrylamide / acrylic acid copolymer.
アニオン系高分子凝集剤としては、ポリアクリルアミド部分加水分解物、アニオン性モノマーの共重合体、アニオン性モノマーとノニオン性モノマーとの共重合体を好ましく挙げることができる。アニオン性モノマーとしては、アクリル酸、メタクリル酸、イタコン酸、マレイン酸、フマル酸、ビニルスルホン酸、アリルスルホン酸、メタリルスルホン酸、スチレンスルホン酸、2−アリルアミドエタンスルホン酸、2−アクリルアミド−2−メチルプロパンスルホン酸、2−メタクリルアミドエタンスルホン酸、2−メタクリルアミド−2−メチルプロパンスルホン酸、2−アクリロイルオキシエタンスルホン酸、3−アクリロイルオキシプロパンスルホン酸、4−アクリロイルオキシブタンスルホン酸、2−メタクリロイルオキシエタンスルホン酸、3−メタクリロイルオキシプロパンスルホン酸、4−メタクリロイルオキシブタンスルホ酸、及びこれらのアルカリ金属、アルカリ土類金属などの金属塩又はアンモニウム塩を好ましく挙げることができる。アニオン性モノマーとノニオン性モノマーとの共重合体としては、アクリルアミド・アクリル酸共重合体、アクリルアミド・2−アクリルアミド−2−メチルプロパンスルホン酸共重合体を好ましく挙げることができる。 Preferable examples of the anionic polymer flocculant include a polyacrylamide partial hydrolyzate, a copolymer of an anionic monomer, and a copolymer of an anionic monomer and a nonionic monomer. As an anionic monomer, acrylic acid, methacrylic acid, itaconic acid, maleic acid, fumaric acid, vinyl sulfonic acid, allyl sulfonic acid, methallyl sulfonic acid, styrene sulfonic acid, 2-allylamide ethane sulfonic acid, 2-acrylamide- 2-methylpropanesulfonic acid, 2-methacrylamideamidoethanesulfonic acid, 2-methacrylamide-2-methylpropanesulfonic acid, 2-acryloyloxyethanesulfonic acid, 3-acryloyloxypropanesulfonic acid, 4-acryloyloxybutanesulfonic acid 2-methacryloyloxyethanesulfonic acid, 3-methacryloyloxypropanesulfonic acid, 4-methacryloyloxybutanesulfonic acid, and metal salts or ammonium salts of these alkali metals and alkaline earth metals are preferred. It can be mentioned. Preferable examples of the copolymer of the anionic monomer and the nonionic monomer include acrylamide / acrylic acid copolymer and acrylamide / 2-acrylamido-2-methylpropanesulfonic acid copolymer.
ノニオン系高分子凝集剤としては、ノニオン性モノマーの重合体又は共重合体を好ましく用いることができ、例えばアクリルアミド、メタクリルアミド、メタアクリロニトリル、酢酸ビニル等及びこれらの組み合わせを用いることができ、より好ましくはポリアクリルアミドを用いることができる。 As the nonionic polymer flocculant, a polymer or copolymer of a nonionic monomer can be preferably used. For example, acrylamide, methacrylamide, methacrylonitrile, vinyl acetate and the like, and combinations thereof can be used, and more preferably. Can be polyacrylamide.
本発明の高分子凝集剤の添加工程においては、上述のカチオン系高分子凝集剤を添加した後に、さらに上述のアニオン系高分子凝集剤を添加する二剤法を用いることもできる。
さらに、本発明においては、高分子凝集剤を添加する前に、混合した汚泥に無機凝集剤及び/又は有機高分子凝結剤を添加することもできる。無機凝集剤としては、硫酸バンド、ポリ塩化アルミニウム(PAC)、ポリ硫酸第2鉄(ポリ鉄)、塩化第2鉄及びこれらの混合物を好ましく用いることができる。有機高分子凝結剤としては、縮合系ポリアミン、ジシアンジアミド・ホルマリン縮合物、ポリエチレンイミン、ポリビニルイミダリン、ポリビニルピリジン、ジアリルアミン塩・二酸化硫黄共重合体、ポリジメチルジアリルアンモニウム塩、ポリジメチルジアリルアンモニウム塩・二酸化硫黄共重合体、ポリジメチルジアリルアンモニウム塩・アクリルアミド共重合体、ポリジメチルアジアリルアンモニウム塩・ジアリルアミン塩酸塩誘導体共重合体、アクリルアミン塩共重合体などを好ましく用いることができる。縮合系ポリアミンとしては、例えば、アルキレンジクロライドとアルキレンポリアミンとの縮合物、アニリンとホルマリンの縮合物、アルキレンジアミンとエピクロルヒドリンとの縮合物、アンモニアとエピクロルヒドリンとの縮合物などを好ましく挙げることができる。エピクロルヒドリンと縮合するアルキレンジアミンとしては、ジメチルアミン、ジエチルアミン、メチルプロピルアミン、メチルブチルアミン、ジブチルアミンなどを好ましく挙げることができる。
In the step of adding the polymer flocculant of the present invention, a two-agent method in which the above-mentioned anionic polymer flocculant is further added after the aforementioned cationic polymer flocculant can be added.
Furthermore, in this invention, before adding a polymer flocculent, an inorganic flocculant and / or an organic polymer coagulant can also be added to the mixed sludge. As the inorganic flocculant, a sulfuric acid band, polyaluminum chloride (PAC), polyferric sulfate (polyiron), ferric chloride and a mixture thereof can be preferably used. Organic polymer coagulants include condensed polyamines, dicyandiamide / formalin condensates, polyethyleneimine, polyvinylimidazoline, polyvinylpyridine, diallylamine salts / sulfur dioxide copolymers, polydimethyldiallylammonium salts, polydimethyldiallylammonium salts / dioxides Sulfur copolymers, polydimethyldiallylammonium salt / acrylamide copolymers, polydimethylasialylammonium salt / diallylamine hydrochloride derivative copolymers, acrylamine salt copolymers and the like can be preferably used. Preferred examples of the condensed polyamine include a condensate of alkylene dichloride and alkylene polyamine, a condensate of aniline and formalin, a condensate of alkylene diamine and epichlorohydrin, a condensate of ammonia and epichlorohydrin, and the like. Preferred examples of the alkylene diamine that condenses with epichlorohydrin include dimethylamine, diethylamine, methylpropylamine, methylbutylamine, and dibutylamine.
本発明の方法において、汚泥に笹の葉及び/又は竹の葉の粉砕物を添加するには、汚泥貯留槽がある場合には汚泥貯留槽に添加し、汚泥貯留槽がない場合には濃縮層から汚泥含有被処理物を引き抜いて脱水機に至るまでの配管中のいずれかのポイントにて添加することができる。 In the method of the present invention, in order to add the pulverized material of bamboo leaves and / or bamboo leaves to the sludge, if there is a sludge storage tank, add it to the sludge storage tank, and if there is no sludge storage tank, concentrate It can be added at any point in the piping from the sludge containing workpiece to the dehydrator.
本発明の方法において、笹の葉及び/又は竹の葉の粉砕物と混合された汚泥に高分子凝集剤を添加して形成した凝集フロックを機械的に脱水するには、通常の加圧脱水機、真空脱水機、ベルトプレス脱水機、遠心脱水機、スクリュープレス脱水機を利用することができる。 In the method of the present invention, in order to mechanically dehydrate the flocs formed by adding a polymer flocculant to sludge mixed with the pulverized material of bamboo leaves and / or bamboo leaves, the usual pressure dehydration is used. A machine, a vacuum dehydrator, a belt press dehydrator, a centrifugal dehydrator, or a screw press dehydrator can be used.
また、本発明によれば、汚泥に笹の葉及び/又は竹の葉の粉砕物を混合させて混合汚泥を形成する混合汚泥形成槽と、得られた混合汚泥に高分子凝集剤を添加して凝集フロックを形成させる凝集フロック形成槽と、得られた凝集フロックを機械脱水する脱水機と、を含む汚泥脱水処理装置が提供される。 Further, according to the present invention, a mixed sludge forming tank that forms sludge by mixing bamboo leaf and / or bamboo leaf pulverized material with sludge, and a polymer flocculant is added to the obtained mixed sludge. There is provided a sludge dewatering apparatus including a coagulation floc forming tank that forms coagulation floc and a dehydrator that mechanically dehydrates the obtained coagulation floc.
図1は、本発明の汚泥脱水処理方法を実施するための汚泥脱水処理装置の一実施形態の概略説明図である。図1に示す装置は、混合汚泥形成槽10と、凝集フロック形成槽20と、脱水機30と、を含む。混合汚泥形成槽10には、機械的撹拌装置11が装備されており、汚泥と笹の葉及び/又は竹の葉の粉砕物とを十分に混合する。混合汚泥形成槽10と凝集フロック形成槽20とは、混合汚泥形成槽10にて形成された汚泥と笹の葉及び/又は竹の葉の粉砕物との混合物を供給するライン13で接続されている。凝集フロック形成槽20には、高分子凝集剤溶解槽25にて調製された高分子凝集剤を供給するライン27も接続されている。凝集フロック形成槽20と脱水機30とは、凝集フロックを脱水機に供給するライン28で接続されている。脱水機30には、脱水ケーキ取り出し口31と分離液排出ライン32とが設けられている。
FIG. 1 is a schematic explanatory diagram of an embodiment of a sludge dewatering treatment apparatus for carrying out the sludge dewatering treatment method of the present invention. The apparatus shown in FIG. 1 includes a mixed sludge forming tank 10, an agglomerated floc forming tank 20, and a dehydrator 30. The mixed sludge formation tank 10 is equipped with a
混合汚泥形成槽10では、下水処理場などから得られる汚泥と、笹の葉及び/又は竹の葉の粉砕物とが供給されて、機械的撹拌装置11により混合され笹の葉及び/又は竹の葉の粉砕物との混合物を形成する。この混合物は、ライン13を介して凝集フロック形成槽20に送られる。凝集フロック形成槽20には、高分子凝集剤溶解槽25にて調製された高分子凝集剤がライン27を介して供給される。混合物及び高分子凝集剤は凝集フロック形成槽20にて一緒に混合されて、凝集フロックを形成する。凝集フロックは、ライン28を介して脱水機30に送られ、機械的脱水処理されて、脱水ケーキと分離液とに分けられる。
In the mixed sludge formation tank 10, sludge obtained from a sewage treatment plant and the like and pulverized material of bamboo leaves and / or bamboo leaves are supplied and mixed by a
図1に示す装置では、前記笹の葉及び/又は竹の葉の粉砕物を混合した後、前記高分子凝集剤を添加する前に、前記汚泥に無機凝集剤及び/又は有機高分子凝結剤を添加する助剤供給装置40をさらに含む。助剤供給装置40は、混合汚泥形成槽10と接続するライン41を介して混合汚泥形成槽10に助剤を供給するように構成されていても、あるいは、ライン13と接続するライン42を介して形成された混合汚泥に助剤を供給するように構成されていてもよい。
In the apparatus shown in FIG. 1, the inorganic flocculant and / or organic polymer coagulant is added to the sludge after mixing the pulverized material of bamboo leaves and / or bamboo leaves and before adding the polymer flocculant. It further includes an auxiliary agent supply device 40 for adding the above. The auxiliary agent supply device 40 may be configured to supply the auxiliary agent to the mixed sludge forming tank 10 via a
本発明によれば、汚泥に笹の葉及び/又は竹の葉の粉砕物を混合した後に高分子凝集剤を添加し、機械脱水処理することで、笹の葉及び/又は竹の葉の粉砕物が凝集の核として作用し高分子凝集剤の作用により速やかに汚泥を凝集させ、その後の機械脱水処理に供することができるので、特にオキシデーションディッチ処理された難脱水性の汚泥であっても十分に脱水処理を行うことができる。 According to the present invention, after mixing the pulverized material of bamboo leaves and / or bamboo leaves with sludge, the polymer flocculant is added, and mechanical dehydration treatment is performed, whereby the leaves of bamboo leaves and / or bamboo leaves are pulverized. Since the substance acts as a core of aggregation and sludge can be quickly aggregated by the action of the polymer flocculant and can be used for the subsequent mechanical dehydration treatment, Dehydration can be sufficiently performed.
また、笹の葉及び/又は竹の葉の粉砕物を用いることにより、従来方法による消臭剤を用いることなく、脱臭効果も良好である。また、笹の葉及び/又は竹の葉の粉砕物は微生物分解されるので、コンポスト化処理に供することもできる。 Moreover, the deodorizing effect is favorable by using the ground material of a bamboo leaf and / or bamboo leaf, without using the deodorizer by a conventional method. Moreover, since the pulverized product of bamboo leaves and / or bamboo leaves is decomposed by microorganisms, it can be subjected to a composting treatment.
さらに、スクリュープレス脱水機を利用する場合にも、高分子凝集剤を多量に添加したり、調質条件を調製することなく、安定した運転が可能である。 Furthermore, even when a screw press dehydrator is used, stable operation is possible without adding a large amount of a polymer flocculant or preparing tempering conditions.
以下、実施例により本発明を詳細に説明するが、本発明はこれらの実施例に限定されるものではない。
本実施例に用いた高分子凝集剤の組成を下記表1に示す。使用時には、蒸留水で0.2重量%水溶液となるように調製した。
EXAMPLES Hereinafter, although an Example demonstrates this invention in detail, this invention is not limited to these Examples.
The composition of the polymer flocculant used in this example is shown in Table 1 below. At the time of use, it prepared so that it might become a 0.2 weight% aqueous solution with distilled water.
(1) 脱水ケーキ20gを臭気測定用袋(容量:700ml)に入れ、ゴム栓で密栓する。
(2) 脱水ケーキ入りの臭気測定用袋内に、ゴム栓にシリンジを刺して600mlの無臭空気を注入する。
(3) シリンジを外した脱水ケーキ入りの臭気測定用袋を30℃の恒温槽に保管し、消臭剤添加後から所定時間毎(12時間)に北川式検知管で硫化水素、メチルメルカプタンを測定する。
(1) Put 20 g of dehydrated cake in an odor measurement bag (capacity: 700 ml) and seal with a rubber stopper.
(2) Inject a 600ml odorless air into the bag for odor measurement with dehydrated cake by inserting a syringe into a rubber stopper.
(3) Store the odor measurement bag with dehydrated cake with the syringe removed in a 30 ° C thermostatic bath, and add hydrogen sulfide and methyl mercaptan at the Kitagawa-type detector tube every predetermined time (12 hours) after adding the deodorant. taking measurement.
[実施例1]
オキシデーションディッチ方式下水処理場から発生する表2に示す性状の余剰汚泥スラリーにモウソウチクの葉の乾燥物の粉砕物(大きさは概ね5〜10mm)を汚泥中SSに対して2wt%添加して、汚泥スラリーを調製した。
[Example 1]
Add 2wt% of dried mulberry leaves (size is approximately 5-10mm) to SS in sludge to surplus sludge slurry with properties shown in Table 2 generated from oxidation ditch sewage treatment plant. A sludge slurry was prepared.
[実施例2〜3、比較例1〜2]
実施例2〜3は、モウソウチクの葉の乾燥物の粉砕物の添加量を表3に記載したように変更した以外は実施例1と同様に試験を行った。比較例1は、モウソウチクの葉の乾燥物の粉砕物を添加しなかった対照実験であり、比較例2は、モウソウチクの葉に替えて桜の木の木屑(大きさは概ね5〜15mm)を添加した対照実験である。結果を表3に併記する。
[Examples 2-3, Comparative Examples 1-2]
Examples 2 to 3 were tested in the same manner as in Example 1 except that the amount of pulverized dried product of Moso bamboo leaves was changed as described in Table 3. Comparative Example 1 is a control experiment in which the pulverized product of Moso bamboo leaves was not added, and Comparative Example 2 was the addition of Moso bamboo leaves to add cherry wood chips (approximately 5 to 15 mm in size). Control experiment. The results are also shown in Table 3.
し尿処理施設から発生する表4に示す性状の余剰汚泥と凝集沈澱汚泥の混合汚泥スラリーに、クマザサの葉の乾燥物の粉砕物(大きさは概ね5〜20mm、含水率5%)をSSに対して1wt%添加して汚泥スラリーを調製した。次に高分子凝集剤bを使用して実施例1と同様に脱水試験を行った。結果を表5に記載する。
In the mixed sludge slurry of surplus sludge and coagulated sediment sludge having the characteristics shown in Table 4 generated from the human waste treatment facility, the dried product of Kumazasa leaves (size is approximately 5 to 20 mm, water content 5%) is changed to SS. On the other hand, sludge slurry was prepared by adding 1 wt%. Next, a dehydration test was conducted in the same manner as in Example 1 using the polymer flocculent b. The results are listed in Table 5.
実施例5〜6は、クマザサの葉の乾燥物の粉砕物及び凝集剤の添加量を表5に記載したように変更した以外は実施例1と同様に試験を行った。比較例3は、クマザサの葉の乾燥物の粉砕物を添加しなかった場合の対照実験であり、比較例4は、クマザサの葉に替えて、籾殻の粉砕物(大きさは概ね3〜10mm)を使用した場合の対照実験である。結果を表5に併記する。
Examples 5 to 6 were tested in the same manner as in Example 1 except that the amount of added crushed material and flocculant of the dried leaves of Kumazasa was changed as described in Table 5. Comparative Example 3 is a control experiment in the case where the pulverized product of dried kumazasa leaves was not added, and Comparative Example 4 was a crushed material of rice husks (size was approximately 3 to 10 mm) instead of kumazasa leaves. ) Is a control experiment. The results are also shown in Table 5.
オキシデーションディッチ方式下水処理場から発生した表6に示す性状の余剰汚泥スラリーに、クマザサ抽出物製造工程で排出される残渣の粉砕物(大きさは概ね10〜20mm、含水率9%)をSSに対して3wt%添加して汚泥スラリーを調製した。
The surplus sludge slurry with the properties shown in Table 6 generated from the oxidation ditch sewage treatment plant is crushed by residue (size is approximately 10-20mm, moisture content 9%) discharged in the Kumazasa extract manufacturing process. A sludge slurry was prepared by adding 3 wt% to the slurry.
[実施例8〜12、比較例5〜6]
実施例8〜12は、クマザサ抽出物残渣の粉砕物の添加量を表7に記載したように変更した以外は、実施例7と同様に試験を行った。比較例5及び6はクマザサ抽出物残渣を添加しなかった場合の対照実験である。結果を表7に併記する。
[Examples 8 to 12, Comparative Examples 5 to 6]
Examples 8 to 12 were tested in the same manner as in Example 7 except that the amount of crushed extract of Kumazasa extract residue was changed as described in Table 7. Comparative Examples 5 and 6 are control experiments in the case where the Kumazasa extract residue was not added. The results are also shown in Table 7.
10:混合汚泥形成槽
20:凝集フロック形成槽
30:脱水機
40:助剤供給装置
10: Mixed sludge formation tank 20: Coagulation floc formation tank 30: Dehydrator 40: Auxiliary supply device
Claims (11)
得られた混合汚泥に高分子凝集剤を添加して凝集フロックを形成させる工程と、
得られた凝集フロックを機械脱水する工程と、
を含む汚泥脱水処理方法。 Mixing sludge with bamboo leaf and / or bamboo leaf pulverized material to form mixed sludge;
Adding a polymer flocculant to the resulting mixed sludge to form a floc floc;
Mechanical dehydration of the obtained floc floc,
Sludge dewatering treatment method.
得られた混合汚泥に高分子凝集剤を添加して凝集フロックを形成させる工凝集フロック形成槽と、
得られた凝集フロックを機械脱水する脱水機と、
を含む汚泥脱水処理装置。 A mixed sludge forming tank for mixing sludge with bamboo leaf and / or bamboo leaf pulverized material to form mixed sludge;
An agglomeration floc forming tank for adding a polymer flocculant to the obtained mixed sludge to form an agglomerated floc;
A dehydrator for mechanically dewatering the obtained flocculent flock;
Including sludge dewatering equipment.
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