JP2006299494A5 - - Google Patents
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- JP2006299494A5 JP2006299494A5 JP2005153053A JP2005153053A JP2006299494A5 JP 2006299494 A5 JP2006299494 A5 JP 2006299494A5 JP 2005153053 A JP2005153053 A JP 2005153053A JP 2005153053 A JP2005153053 A JP 2005153053A JP 2006299494 A5 JP2006299494 A5 JP 2006299494A5
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- 229920000728 polyester Polymers 0.000 description 25
- 239000003795 chemical substances by application Substances 0.000 description 21
- 229920001400 block copolymer Polymers 0.000 description 14
- 238000002844 melting Methods 0.000 description 13
- 239000002202 Polyethylene glycol Substances 0.000 description 12
- 229920001223 polyethylene glycol Polymers 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 239000006185 dispersion Substances 0.000 description 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 10
- 238000005406 washing Methods 0.000 description 10
- 239000004744 fabric Substances 0.000 description 9
- 239000000835 fiber Substances 0.000 description 9
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 8
- 239000004721 Polyphenylene oxide Substances 0.000 description 7
- 239000004480 active ingredient Substances 0.000 description 7
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 7
- 229920000570 polyether Polymers 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 6
- 125000003118 aryl group Chemical group 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- QQVIHTHCMHWDBS-UHFFFAOYSA-N Isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 230000035699 permeability Effects 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 239000012209 synthetic fiber Substances 0.000 description 4
- 229920002994 synthetic fiber Polymers 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- WOZVHXUHUFLZGK-UHFFFAOYSA-N Dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene (PE) Substances 0.000 description 2
- 230000003373 anti-fouling Effects 0.000 description 2
- 239000002216 antistatic agent Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 230000000379 polymerizing Effects 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- VNGOYPQMJFJDLV-UHFFFAOYSA-N dimethyl benzene-1,3-dicarboxylate Chemical compound COC(=O)C1=CC=CC(C(=O)OC)=C1 VNGOYPQMJFJDLV-UHFFFAOYSA-N 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 239000011528 polyamide (building material) Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 238000005429 turbidity Methods 0.000 description 1
Description
次の条件Ａ，Ｂのすべてを充たすポリエステル・ポリエーテルブロック共重合体を主体とする合成繊維、フィルム等の被処理物に用いる高分子処理剤。
Ａ．酸成分としてテレフタル酸もしくはテレフタル酸とイソフタル酸、グリコール成分としてエチレングリコールとを重合させたポリエステルと片末端がメチル基またはエチル基で置換されたポリエチレグリコールとのポリエステル・ポリエーテルブロック共重合体であって、
Ｂ．上記Ａのポリエステル・ポリエーテルブロック共重合体は
Ｂ−１ 分子量が５０００〜１５０００
Ｂ−２ 片末端がメチル基またはエチル基で置換されたポリエチレグリコールと上記芳香族ポリエステルとのモル比が１：１．５以上であり、
Ｂ−３ 結晶融点（差動走査熱量計で測定して、セカンドスキャンの吸熱ピークを融点とする）が５０℃〜９０℃の性質を持つ。A polymer treating agent used for an object to be treated such as a synthetic fiber or a film mainly composed of a polyester / polyether block copolymer satisfying all of the following conditions A and B.
A. This is a polyester / polyether block copolymer of polyester obtained by polymerizing terephthalic acid or terephthalic acid and isophthalic acid as an acid component, and polyethylene glycol having one end substituted with a methyl group or an ethyl group. And
B. The polyester / polyether block copolymer of A is B-1 having a molecular weight of 5000 to 15000.
B-2 The molar ratio of polyethylene glycol having one end substituted with a methyl group or an ethyl group and the aromatic polyester is 1: 1.5 or more,
B-3 The crystal melting point (measured with a differential scanning calorimeter and the second scan endothermic peak is the melting point) has a property of 50 ° C to 90 ° C.
請求項１に記載の高分子処理剤で処理された被処理品。 An article to be treated treated with the polymer treating agent according to claim 1.
被処理品がポリエステル繊維を主体とする繊維製品である請求項２記載の被処理品。 The article to be treated according to claim 2, wherein the article to be treated is a fiber product mainly composed of polyester fibers.
本発明は、主としてポリエステルのような合成繊維、フィルム等に耐久性のある帯電防止性、吸収性、再汚染防止性、汚れ防止性、等を与えるポリエステル系処理剤及び該処理剤で処理された被処理品に関する。 The present invention is mainly treated with a polyester-based treatment agent that imparts durable antistatic properties, absorption properties, anti-recontamination properties, antifouling properties, etc. to synthetic fibers such as polyester, films, etc., and the treatment agents. It relates to processed products.
従来から芳香族ポリエステルとポリアルキレングリコールとのブロック共重合体を用いた帯電防止剤、特にポリエステル系合成繊維を主体とする繊維製品用の帯電防止剤は知られており、帯電防止性の向上に効果を挙げている（例えば、特許文献１、特許文献２、特許文献３）。 Conventionally, antistatic agents using block copolymers of aromatic polyesters and polyalkylene glycols, especially antistatic agents for textile products mainly composed of polyester-based synthetic fibers, have been known to improve antistatic properties. The effect is mentioned (for example, patent document 1, patent document 2, patent document 3).
上記各特許文献１〜３に記載のポリエステル処理剤は水分散液としてポリエステル系合成繊維製品を処理するものであるが、耐洗濯性等の耐久性が不足しているのが難点である。
本発明は、上記処理剤の耐洗濯性の向上はもちろん、フィルム、シートにも耐久性のある吸収性、再汚染防止性、汚れ防止性をも付与することを目的とする。The polyester treating agents described in the above Patent Documents 1 to 3 treat polyester synthetic fiber products as an aqueous dispersion, but are disadvantageous in lack of durability such as washing resistance.
The object of the present invention is to provide not only the washing resistance of the treatment agent to be improved, but also to impart durable absorbability, recontamination prevention property, and antifouling property to films and sheets.
即ち、本発明は、酸成分としてテレフタル酸、もしくはテレフタル酸とイソフタル酸、グリコール成分としてエチレングリコールからなるポリエステルと片末端がメチル基またはエチル基で置換されたポリエチレングリコールとのブロック共重合体であって、分子量が５，０００〜１５，０００、結晶融点（差動走査熱量計で測定して、セカンドスキャンの吸熱ピークを融点とする）が５０℃〜９０℃のものを主体とするポリエステル−ポリエチレングリコール系ブロック共重合体を処理剤として使用することによって耐久性のある帯電防止性等を付与するものである。上記酸成分における、イソフタル酸成分の使用量は、テレフタル酸を含む全酸成分重量に対して５〜１０重量％程度使用することが好ましい。 That is, the present invention is a block copolymer of terephthalic acid as an acid component, or polyester comprising terephthalic acid and isophthalic acid and ethylene glycol as a glycol component, and polyethylene glycol having one end substituted with a methyl group or an ethyl group. Polyester-polyethylene mainly having a molecular weight of 5,000 to 15,000 and a crystalline melting point (measured with a differential scanning calorimeter and having a second scan endothermic peak as a melting point) of 50 ° C. to 90 ° C. The use of a glycol block copolymer as a treating agent imparts durable antistatic properties and the like. The amount of the isophthalic acid component used in the acid component is preferably about 5 to 10% by weight based on the total acid component weight including terephthalic acid.
特に、本発明のポリエステル−ポリエーテルブロック共重合体の結晶融点は、ポリエステルの種類、分子量、ポリエチレグリコールの種類、分子量、両者の重合形態、重合比率等の要素が複雑に組み合わされ、複雑に絡み合うことによって、もたらされるものであり、本発明は、この結晶融点と加工効果とを把握し、その融点を得るために、上記ブロック共重合体の各要素を研究、究明して本発明に到達したものである。 In particular, the crystalline melting point of the polyester-polyether block copolymer of the present invention is intricately entangled by a complex combination of factors such as polyester type, molecular weight, polyethylene glycol type, molecular weight, polymerization form of both, and polymerization ratio. The present invention has ascertained the crystal melting point and the processing effect, and in order to obtain the melting point, researched and investigated each element of the block copolymer to arrive at the present invention. Is.
処理剤の結晶融点を５０℃〜９０℃に調整することによって、処理剤の有効成分が繊維等の被処理品に吸着され、ヒートセットされることにより、この有効成分と被処理品とが融合し、接着性が向上して耐洗濯性等の耐久性が増加する。
結晶融点が低いと、分子量の場合と同様に処理剤と被処理品との接着性が弱く、耐洗濯性等の耐久性が劣る。また結晶融点が９０°以上を示す結晶性の重合体では、水への分散が悪くなって、多量の界面活性剤を使用することになり、前述したように繊維等の被処理品への接着が悪くなり、耐洗濯性等の耐久性が低下する。By adjusting the crystal melting point of the treating agent to 50 ° C. to 90 ° C., the active ingredient of the treating agent is adsorbed to the article to be treated such as fiber and heat set, so that this active ingredient and the article to be treated are fused. However, the adhesiveness is improved, and durability such as washing resistance is increased.
When the crystal melting point is low, the adhesion between the treatment agent and the article to be treated is weak as in the case of the molecular weight, and durability such as washing resistance is poor. In addition, in the case of a crystalline polymer having a crystal melting point of 90 ° or more, the dispersion in water becomes poor, and a large amount of surfactant is used. Deteriorates and durability such as washing resistance decreases.
また、処理剤の分子量が５，０００以下になると繊維製品等の被処理品に処理剤を付着することはできるが付着力が弱く、耐久性が劣る。また分子量が１５，０００以上になると水分散性が悪くなって、これを分散させるために多量の界面活性剤を必要とし、水分散物の放置安定性も悪く、容易にゲル化する欠点がある。また界面活性剤の大量使用によってポリエステル系加工剤と繊維等との接着性が阻害され、耐洗濯性等の耐久性が低下する。 In addition, when the molecular weight of the treatment agent is 5,000 or less, the treatment agent can be attached to an article to be treated such as a textile product, but the adhesion is weak and the durability is poor. Further, when the molecular weight is 15,000 or more, the water dispersibility is deteriorated, and a large amount of a surfactant is required to disperse this, and the standing stability of the aqueous dispersion is also poor, and there is a drawback that gelation easily occurs. . In addition, the use of a large amount of a surfactant hinders the adhesion between the polyester-based processing agent and the fibers, and the durability such as washing resistance is lowered.
本発明の処理剤は、片末端がメチル基またはエチル基で置換されているポリエチレングリコールを使用するものであるから、当然に少なくとも一方の末端、もしくは両末端が上記メチル基またはエチル基で封鎖されたポリエステル−ポリエーテルブロック共重合体を主体とするポリマーである。 Since the treatment agent of the present invention uses polyethylene glycol in which one end is substituted with a methyl group or an ethyl group, naturally at least one end or both ends are blocked with the above methyl group or ethyl group. It is a polymer mainly composed of a polyester-polyether block copolymer.
従来のこの種の処理剤は芳香族ポリエステルのモル数が、ポリエチレングリコールのモル数よりも大きいブロック共重合体を使用していたため、末端に芳香族基を有するものが多かった。本発明の処理剤は、末端にメチル基またはエチル基を結合したポリエチレングリコールと芳香族ポリエステルとが重合したポリマーであるために、末端がメチル基またはエチル基であることが多く、従来の処理剤と異なっている。
なお、上記ではブロック共重合体は、片末端置換ポリエチレングリコールと芳香族ポリエステルとのモル比が１：１．５以上であるということが必要である。Since this type of conventional treating agent uses a block copolymer in which the number of moles of aromatic polyester is larger than the number of moles of polyethylene glycol, many of them have an aromatic group at the terminal. Since the treatment agent of the present invention is a polymer obtained by polymerizing polyethylene glycol having a methyl group or an ethyl group bonded to the terminal and an aromatic polyester, the terminal is often a methyl group or an ethyl group. Is different.
In the above, the block copolymer needs to have a molar ratio of the one-end substituted polyethylene glycol and the aromatic polyester of 1: 1.5 or more.
本発明の処理剤は、必要に応じて乳化剤を加えて水中で攪拌し、通常４〜１５重量％の水分散液に調整して使用する。実際の加工では、この処理剤を被処理品に対して５〜１５重量％になるように適用する。被処理品はその後、結晶融点以上の温度で熱処理する。 The treating agent of the present invention is used by adding an emulsifier if necessary, stirring in water, and adjusting to a water dispersion of usually 4 to 15% by weight. In actual processing, this treatment agent is applied so as to be 5 to 15% by weight based on the article to be treated. The article to be treated is then heat-treated at a temperature above the crystalline melting point.
本発明の処理剤を適用する被処理品としては、ポリエステル、ポリアミド、ポリエチレン、ポリプロピレンのようなプラスチック製品、特に、ポリエステルを主体とする繊維製品、フィルム、シートが含まれ、その中でもポリエステル繊維を主体とする繊維製品が好ましい。 The products to be treated to which the treatment agent of the present invention is applied include plastic products such as polyester, polyamide, polyethylene, and polypropylene, particularly fiber products, films, and sheets mainly composed of polyester. A textile product is preferred.
本発明のポリエステル−ポリエーテルブロック共重合体は、従来のものよりも水分散性が良好であり、分散に際して多量の界面活性剤を使用する必要がないため、界面活性剤による耐洗濯性等の耐久性の低下が防止できる。 The polyester-polyether block copolymer of the present invention has better water dispersibility than conventional ones, and it is not necessary to use a large amount of surfactant for dispersion. It is possible to prevent a decrease in durability.
また、このブロック共重合体は被処理品への吸尽加工中の加温状態での曇点現象が起こらず、分子状分散の状態で被処理物に吸着される。その結果、繊維上に均一に有効成分が吸着でき、ナノオーダーの分子状吸着が可能となり、有効成分との融合、特に被処理品がポリエステルの場合には両者の共晶化が理想的に起こり、その皮膜は耐洗濯性等の耐久性に大きく影響を与える良好な接着性を示し、いわゆるナノミクロンオーダーの加工が達成される。 In addition, the block copolymer does not cause a cloud point phenomenon in a heated state during exhaustion processing to the article to be treated, and is adsorbed on the article to be treated in a molecular dispersion state. As a result, the active ingredient can be adsorbed uniformly on the fiber, and nano-order molecular adsorption is possible. Fusion with the active ingredient, especially when the product to be processed is polyester, ideally eutecticization of both occurs. The film exhibits good adhesion that greatly affects the durability such as washing resistance, and so-called nano-micron order processing is achieved.
次に実施例について、本発明を説明するが、実施例中の各種特性の測定は次表の方法で行った。
テレフタル酸、イソフタル酸、エチレングリコール、片末端をメチル基で置換したポリエチレングリコールとを重合後第２表の成分比率になるように混合し、触媒を少量添加して、常圧で１９０℃、１８０分間反応させてほぼ理論量のメタノールを留去して、エステル交換反応を完了させた。次いで、これに少量の触媒を添加して、これを５ｍｍＨｇの減圧下で２６０℃、２０分間、更に０．１ｍｍＨｇで３０分間反応させて共重合体を得た。第２表に重合体の成分重量比率と特性を示した。
第２表の実施例１の欄における成分比率の共重合体を水中に分散させ、約１０重量％の水分散液を得た。
次にポリエステルタフタ布を上記に示した１０％の水分散液をタフタ重量の７％になるように採取して、生地と処理液の比（以下浴比と略す）１：３０に調整して、処理浴を調製した。処理温度下では処理液は無色透明であり、処理成分は完全に液中で分散されていた。ポリエステルとポリエチレングリコールとの共重合体の分散液で一般に見られるような処理温度での曇点現象は認められず、成分の液中での凝集は観察されなかった。加工剤のポリエステル繊維への吸尽後は常法にしたがって還元洗浄処理をおこない、その後１８０℃、１分間の加熱処理をした。
この帯電防止加工布の摩擦帯電圧と水浸透性は第３表に示すように洗濯前、洗濯２０分後ともに良好な結果を示した。
なお、本実施例の加工布、及び後述する比較例１の加工布との摩擦帯電圧及び水浸透性の結果は第３表のとおりである。The copolymer of the component ratio in the column of Example 1 of Table 2 was dispersed in water to obtain an aqueous dispersion of about 10% by weight.
Next, the polyester taffeta cloth was collected so that the 10% aqueous dispersion shown above was 7% of the taffeta weight, and the ratio of the dough to the treatment liquid (hereinafter abbreviated as bath ratio) was adjusted to 1:30. A treatment bath was prepared. Under the treatment temperature, the treatment liquid was colorless and transparent, and the treatment components were completely dispersed in the liquid. The cloud point phenomenon at the treatment temperature generally observed in a dispersion of a copolymer of polyester and polyethylene glycol was not observed, and aggregation of the components in the liquid was not observed. After exhaustion of the processing agent to the polyester fiber, reduction cleaning treatment was performed according to a conventional method, and then heat treatment was performed at 180 ° C. for 1 minute.
As shown in Table 3, the friction band voltage and water permeability of this antistatic fabric showed good results both before and 20 minutes after washing.
Table 3 shows the results of the friction band voltage and water permeability of the work cloth of this example and the work cloth of Comparative Example 1 described later.
第２表の実施例２の欄に示したようにメチルテレフタレートと、メチルイソフタレートと、エチレングリコールと分子量２５００の片末端にメチル基を有するポリエチレングリコールとが重合後夫々の残基が２００部、２０部、６０部、７２０部になるように混合し、その後は製造例に示したように重合反応をして、結晶性白色樹脂を得た。樹脂の融点は５２℃であった。この樹脂を２００℃で再溶融して４０℃の湯に溶融物を滴下して樹脂成分が１０％になるように分散液を得た。
この液を使用して、実施例１と同条件下でポリエステル加工糸織物を帯電防止加工をした。得られた加工織物の家庭洗濯２０回後の摩擦帯電圧は３５０ボルト、水浸透性は１秒以下であった。また加工布の人工汚れ液による再汚染防止性は糸加工布に比べはるかに良好であった。As shown in the column of Example 2 in Table 2, methyl terephthalate, methyl isophthalate, ethylene glycol, and polyethylene glycol having a molecular weight of 2500 at one end are polymerized and each residue is 200 parts, It mixed so that it might become 20 parts, 60 parts, and 720 parts, and it superposed | polymerized as shown to the manufacture example after that, and obtained crystalline white resin. The melting point of the resin was 52 ° C. This resin was remelted at 200 ° C., and the melt was dropped into hot water at 40 ° C. to obtain a dispersion so that the resin component was 10%.
Using this solution, the polyester processed yarn fabric was subjected to antistatic treatment under the same conditions as in Example 1. After 20 home washings of the obtained processed fabric, the frictional band voltage was 350 volts and the water permeability was 1 second or less. Moreover, the anti-recontamination property of the processed cloth by the artificial soil solution was much better than that of the yarn processed cloth.
ジメチルテレフタレートとジメチルイソテレフタレートと、エチレングリコールと平均分子量３０００の片末端にフェニル基を有するポリエチレングリコールとが重合後それぞれの残基が１７０部、４０部、７１０部、４０部になるように混合し、触媒を少量添加して、実施例１と同じ条件で重合をした。
得られた樹脂はロウ石状の不透明な塊状の樹脂であった。その結晶融点は４０℃、平均分子量は７６００であった。実施例２のようにこの樹脂を１５０℃で溶融して、湯中に滴下して乳白色の分散液を得た。この処理液を使用して、実施例１と同じ条件でタフタに処理した。７０℃付近から処理液は濁りを増して、曇点現象を起こした。
有効成分が繊維に吸尽された後は処理液が透明になった。加工されたタフタは有効成分が微粒子状のまま吸着されていることを示す。
加工布の摩擦帯電圧と水浸透性を測定した。実施例１の表に併せて第３表に示した。これから、この加工剤の性能、特に２０回洗濯後の性能は劣る結果を示す。
これは有効成分が吸尽浴中で、凝集して、分子の集合状態のまま繊維上に吸着されたために、その集合体が洗濯で脱落して、摩擦帯電圧が高くなり耐洗濯性が劣る結果となった。Dimethyl terephthalate, dimethyl isoterephthalate, ethylene glycol and polyethylene glycol having an average molecular weight of 3000 and having a phenyl group at one end are polymerized and mixed so that the respective residues are 170 parts, 40 parts, 710 parts and 40 parts. A small amount of catalyst was added, and polymerization was carried out under the same conditions as in Example 1.
The obtained resin was a wax-like opaque massive resin. The crystal melting point was 40 ° C. and the average molecular weight was 7600. As in Example 2, the resin was melted at 150 ° C. and dropped into hot water to obtain a milky white dispersion. Using this treatment solution, taffeta was treated under the same conditions as in Example 1. From around 70 ° C., the treatment liquid increased in turbidity and caused a cloud point phenomenon.
The treatment liquid became transparent after the active ingredient was exhausted by the fibers. The processed taffeta shows that the active ingredient is adsorbed in the form of fine particles.
The friction band voltage and water permeability of the work cloth were measured. The results are shown in Table 3 together with the table in Example 1. From this, the performance of this processing agent, particularly the performance after 20 washes, shows inferior results.
This is because the active ingredient aggregates in the exhaust bath and is adsorbed onto the fiber in the molecular aggregate state, so that the aggregate falls off by washing, the frictional voltage becomes high, and the washing resistance is inferior. As a result.
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| JP4942670B2 (en) * | 2008-01-17 | 2012-05-30 | 日華化学株式会社 | Fiber treatment agent and method for producing functional fiber product |
| JP2012107346A (en) * | 2010-11-15 | 2012-06-07 | Gunze Ltd | Method for applying stain-proof function to polyester fiber product |
| JP6377437B2 (en) | 2014-07-22 | 2018-08-22 | 株式会社Adeka | Antistatic agent, antistatic agent composition, antistatic resin composition and molded article |
| JP6566647B2 (en) * | 2015-01-26 | 2019-08-28 | 株式会社Adeka | Antistatic resin composition and container and packaging material using the same |
| JP6566643B2 (en) * | 2015-01-19 | 2019-08-28 | 株式会社Adeka | Containers and packaging materials |
| US10053536B2 (en) | 2015-01-19 | 2018-08-21 | Adeka Corporation | Antistatic resin composition, and container and packaging material which use same |
| WO2020202642A1 (en) * | 2019-03-29 | 2020-10-08 | 株式会社Adeka | Antistatic agent, antistatic composition comprising same, antistatic resin composition comprising same, and molded article thereof |
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| JPS5346960B2 (en) * | 1974-08-21 | 1978-12-18 | ||
| JPS61291622A (en) * | 1985-06-18 | 1986-12-22 | Toyobo Co Ltd | Textile-finishing agent of polyester base |
| JPH0730512B2 (en) * | 1985-08-22 | 1995-04-05 | ザ、プロクタ−、エンド、ギヤンブル、カンパニ− | Articles and methods for treating fabrics |
| US4711730A (en) * | 1986-04-15 | 1987-12-08 | The Procter & Gamble Company | Capped 1,2-propylene terephthalate-polyoxyethylene terephthalate polyesters useful as soil release agents |
| US5474691A (en) * | 1994-07-26 | 1995-12-12 | The Procter & Gamble Company | Dryer-added fabric treatment article of manufacture containing antioxidant and sunscreen compounds for sun fade protection of fabrics |
| JP3487424B2 (en) * | 2000-04-28 | 2004-01-19 | 東洋紡績株式会社 | Hydrophilic polyester fiber, hydrophilic nonwoven fabric and method for producing the same |
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