JP2006259122A - Image forming apparatus - Google Patents

Image forming apparatus Download PDF

Info

Publication number
JP2006259122A
JP2006259122A JP2005075252A JP2005075252A JP2006259122A JP 2006259122 A JP2006259122 A JP 2006259122A JP 2005075252 A JP2005075252 A JP 2005075252A JP 2005075252 A JP2005075252 A JP 2005075252A JP 2006259122 A JP2006259122 A JP 2006259122A
Authority
JP
Japan
Prior art keywords
image
toner
transfer
carrier
developer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2005075252A
Other languages
Japanese (ja)
Inventor
Hajime Koyama
小山一
Katsuhiro Echigo
越後勝博
Takahiro Tamiya
田宮孝弘
Hisashi Kikuchi
菊地尚志
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ricoh Co Ltd
Original Assignee
Ricoh Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ricoh Co Ltd filed Critical Ricoh Co Ltd
Priority to JP2005075252A priority Critical patent/JP2006259122A/en
Publication of JP2006259122A publication Critical patent/JP2006259122A/en
Pending legal-status Critical Current

Links

Images

Landscapes

  • Developing For Electrophotography (AREA)
  • Electrostatic Charge, Transfer And Separation In Electrography (AREA)
  • Developing Agents For Electrophotography (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To easily and effectively suppress failures, such as transfer dust, dot image reproduction failure, toner scattering, and reverse transfer of a previous process transfer toner to an image carrier, by preventing the transfer of the toner in slight gaps on upstream and downstream of a transfer nip at the time of transfer without depending on a surface potential distribution (toner sensible image pattern) of an image carrier in developing. <P>SOLUTION: The image forming apparatus equipped with a photoreceptor, a developing roller for carrying and conveying a developer, and a means for transferring the toner image formed on the photoreceptor by an electric field to a transfer material, in which the development is performed under the conditions of satisfying the relation ä¾Q2¾-¾Q1¾}/¾Q1¾ ≥-0.3, when Q1 denotes the average charge quantity of the toner in the developer carried on the developing roller just before passing through the counter area between the developing roller and the photoreceptor in a state where a potential difference between the surface of the developing roller and the surface of the photoreceptor is almost 0 V and Q2 denotes the average charge quantity of the surface toner image of the transfer material right after the electric field transfer to the surface for the next transfer material from the photoreceptor. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本発明は、白黒、モノカラーあるいはフルカラーの電子写真複写機、ファクシミリ、プリンタ等として用いられ、電子写真方式あるいは静電記録方式等により形成された潜像担持体上のトナーを記録紙等の転写材に転写電界を付与して転写することにより画像を得る画像形成装置に関するものである。より詳しくは、潜像担持体上に形成されたトナー像を、直接記録媒体に転写する直接転写方式、及び中間転写体に一次転写した後に記録媒体に二次転写する中間転写方式の画像形成装置、更には、潜像担持体上に形成された複数のトナー像を直接記録媒体上に複数回重ね合わせて転写することによってカラー画像を得る直接転写方式、及び中間転写体上に複数回重ね合わせて中間転写した後、記録媒体に一括転写することによってカラー画像を得る中間転写方式のカラー画像形成装置に関わっている。   The present invention is used for black and white, mono-color or full-color electrophotographic copying machines, facsimiles, printers, etc., and transfers toner on a latent image carrier formed by an electrophotographic system or electrostatic recording system to recording paper or the like. The present invention relates to an image forming apparatus that obtains an image by transferring a material by applying a transfer electric field. More specifically, an image forming apparatus of a direct transfer method in which a toner image formed on a latent image carrier is directly transferred to a recording medium, and an intermediate transfer method in which the toner image is primarily transferred to an intermediate transfer member and then secondarily transferred to the recording medium. Furthermore, a direct transfer system that obtains a color image by superimposing and transferring a plurality of toner images formed on a latent image carrier onto a recording medium a plurality of times, and superimposing a plurality of times on an intermediate transfer member. The present invention relates to an intermediate transfer type color image forming apparatus that obtains a color image by batch transfer to a recording medium after intermediate transfer.

特開2004−062140号公報JP 2004-062140 A 特開平10−010886号公報JP-A-10-010886 特開平05−100534号公報Japanese Patent Laid-Open No. 05-100534 特開2003−084504号公報JP 2003-084504 A 特開2003−241518号公報JP 2003-241518 A 特開2002−357939号公報JP 2002-357939 A

電子写真方式等を利用した画像形成装置においては、感光体等の潜像担持体(あるいは像担持体)上に原稿画像や画像情報に応じた露光を行って静電潜像を形成し、この静電潜像を現像手段のトナーにより現像して顕像化した後、そのトナー像を記録紙等の転写材上に転写し、定着して画像を形成する。この場合における現像方法としては、現在、現像剤としてトナーと磁性キャリアとからなる二成分系現像剤を用いる二成分系現像方式や、キャリアを用いない一成分系現像剤を用いる一成分系現像方式等が知られているが、より高画質や高速が要求される場合には二成分系現像方式が好適に用いられている。そして、二成分系現像方式では、二成分系現像剤が、現像剤担持体上で現像磁気ブラシと呼ばれる穂立ちを形成するが、この現像磁気ブラシが、現像工程において現像担持体に接触する所謂接触現像と、接触しないまま現像が行われる所謂非接触現像が知られている。通常、高画質や高濃度が求められる場合には、前者の接触現像が用いられることが多い。   In an image forming apparatus using an electrophotographic method or the like, an electrostatic latent image is formed on a latent image carrier (or image carrier) such as a photoconductor by performing exposure according to a document image or image information. The electrostatic latent image is developed with the toner of the developing means to be visualized, and then the toner image is transferred onto a transfer material such as recording paper and fixed to form an image. As a developing method in this case, currently, a two-component developing method using a two-component developer composed of a toner and a magnetic carrier as a developer, or a one-component developing method using a one-component developer that does not use a carrier. However, when higher image quality and higher speed are required, a two-component development system is preferably used. In the two-component development system, the two-component developer forms a spike called a developing magnetic brush on the developer carrying member, and this developing magnetic brush is in contact with the developing carrier in the developing process. Contact development and so-called non-contact development in which development is performed without contact are known. Usually, when high image quality and high density are required, the former contact development is often used.

従来の画像形成プロセスでは、現像電流や、環境に応じて予め求めてあるデータに基づいて、転写電流を制御したり、前後の工程色トナーの帯電量の序列を制約する等、機構や方式が複雑になっている。その割には現像剤の経時的な、あるいは環境による変化で制御の信頼性が損なわれる可能性が高い。   In the conventional image forming process, there are mechanisms and methods such as controlling the transfer current based on the development current and data obtained in advance according to the environment, and limiting the order of charge amounts of the process color toners before and after. It is complicated. On the other hand, there is a high possibility that the reliability of the control will be lost due to changes in the developer over time or due to environmental changes.

また転写電界を付与して像担持体から中間転写体や記録媒体等の転写材へトナー像を転写する際にトナーチリという現象(以下、転写チリという)が発生する場合があることが知られている。転写チリとは、像担持体から転写材へトナー像を転写する際に、像担持体上に形成されたトナー像(可視像)が本来転写されるべき位置に転写されず、その周辺に拡散して転写されてしまい、結果として画像がぼけてしまう現象であり、特に細線部分での画像のシャープさを損なわせるものである。画像重ねする際に顕著で、3色、4色と重ね合わせるときには、この転写チリの現象は一層発生し易くなり、画像自体も粒状性が悪くなり、ザラザラとした画像になるという問題がある。   It is also known that a phenomenon called toner dust (hereinafter referred to as transfer dust) may occur when a toner image is transferred from an image carrier to a transfer material such as an intermediate transfer member or a recording medium by applying a transfer electric field. Yes. Transfer dust means that when a toner image is transferred from an image carrier to a transfer material, the toner image (visible image) formed on the image carrier is not transferred to a position where it should originally be transferred, but around it. This is a phenomenon in which the image is blurred and transferred, resulting in blurring of the image, and particularly the sharpness of the image at the thin line portion is impaired. This phenomenon is conspicuous when superimposing images, and when superimposing three or four colors, the phenomenon of transfer dust is more likely to occur, and there is a problem that the image itself has poor graininess and becomes a rough image.

2色以上のトナーでカラー画像を形成するにあたって、転写チリ現象の発生を防止し、画像の粒状性(ザラツキ)の改善を図るために、特許文献1では、像担持体上の潜像を現像して顕像化する現像手段を備え、現像手段として、現像剤の色が異なる2つ以上の二成分現像方式の現像器を具備する現像装置を備えた画像形成装置において、現像装置と、現像剤担持体で担持・搬送する二成分現像剤の搬送量や層厚を規制するドクターブレードを有し、現像装置の各現像器中のトナーの帯電量Qが、作像順毎に、Q1<Q2<Q3<Q4と高くなる構成が提案されている。   In forming a color image with two or more colors of toner, Patent Document 1 develops a latent image on an image carrier in order to prevent the occurrence of a transfer dust phenomenon and to improve the graininess (roughness) of the image. In the image forming apparatus, the developing device includes a developing device that includes two or more two-component developing type developing devices having different developer colors as the developing device. A doctor blade that regulates the transport amount and layer thickness of the two-component developer carried and transported by the agent carrier, and the toner charge amount Q in each developing device of the developing device is Q1 < A configuration in which Q2 <Q3 <Q4 is high is proposed.

転写不良等による異常画像の発生を伴うことなく、感光体上のトナー像を中間転写ベルト上に転写する際の転写チリの発生を防止するために、特許文献2では、中間転写ベルトと感光体との間の転写ニップ部よりも中間転写ベルト移動方向の上流側に、中間転写ベルトの転写面に向けてトナーの帯電極性と同極性の電荷を付与するスコロトロン帯電器を設けることが提案されている。   In order to prevent generation of transfer dust when a toner image on a photoconductor is transferred onto an intermediate transfer belt without causing an abnormal image due to transfer failure or the like, Patent Document 2 discloses an intermediate transfer belt and a photoconductor. It has been proposed to provide a scorotron charger that applies a charge of the same polarity as the toner charge polarity toward the transfer surface of the intermediate transfer belt, upstream of the transfer nip portion between the toner and the intermediate transfer belt. Yes.

また温度や湿度の環境変化に左右されずに的確な転写条件のもとで良好に転写を行うために、特許文献3では、現像スリーブと現像バイアス電源の間に現像電流測定回路を接続し、現像電流測定回路と転写電源との間に転写制御回路を接続し、そして該転写制御回路に、温度及び湿度の変化に対する現像電流と適正転写電流との関係を表すデータを記憶させ、上記現像電流測定回路によって検知した現像電流に基づいて最適な転写電流を選択し転写電源を制御するように設定することが提案されている。   In Patent Document 3, a developing current measuring circuit is connected between the developing sleeve and the developing bias power source in order to perform good transfer under an accurate transfer condition without being influenced by environmental changes in temperature and humidity. A transfer control circuit is connected between the development current measuring circuit and the transfer power source, and data representing the relationship between the development current and the appropriate transfer current with respect to changes in temperature and humidity is stored in the transfer control circuit. It has been proposed to select an optimum transfer current based on the development current detected by the measurement circuit and to set the transfer power source to be controlled.

現像剤担持体上に担持されたトナーの帯電電荷量の変化を抑制して、残像現象を抑制し、均一な濃度の画像を形成するために、特許文献4では、現像ローラと感光体ドラムの表面との電位差が0Vであるときの、現像ローラと感光体ドラムとの対向領域通過直後のトナーの平均帯電電荷量をQ1、現像ローラに現像バイアスが印加され、感光体ドラムの表面電位が非画像部電位であるときの、現像ローラと感光体ドラムとの対向領域通過直後のトナーの平均帯電電荷量をQ2とした場合に、|Q2|−|Q1|/|Q1|≦±0.45の関係を満足する条件下で現像を行うことが提案されている。   In Patent Document 4, in order to suppress a change in the charged charge amount of the toner carried on the developer carrying member, to suppress an afterimage phenomenon, and to form an image having a uniform density, Patent Document 4 describes a development roller and a photosensitive drum. When the potential difference from the surface is 0 V, the average charged charge amount of the toner immediately after passing through the facing region between the developing roller and the photosensitive drum is Q1, the developing bias is applied to the developing roller, and the surface potential of the photosensitive drum is not | Q2 | − | Q1 | / | Q1 | ≦ ± 0.45, where Q2 is the average charge amount of the toner immediately after passing through the facing region between the developing roller and the photosensitive drum when the potential is the image portion. It has been proposed to perform development under conditions that satisfy this relationship.

更には、横ラインの細り・後端白抜け・孤立ドット画像の抜け・ハーフトーン画像のざらつき感悪化を発生させず、またスキャベンジ効果、エッジ効果をも低減させるために、特許文献5では、小径(φ30以下)の潜像担持体に対して磁気ブラシ搬送する小径(φ16mm以下)の現像剤担持体を有し、所定の複数のパラメータを設定することが開示され、また像担持体へのトナーの逆転写による画像劣化を防止するために、特許文献6では、各感光体のうちの、一次転写直前の画像形成に関与しない感光体の表面と中間転写ベルト上のトナーとの間で放電が生じないように感光体の表面電位と、一次転写電界による中間転写ベルトの表面電位との電位差を制御することが開示されている。   Furthermore, in order to reduce the narrowing of the horizontal line, the trailing edge blank, the missing of the isolated dot image, and the rough feeling of the halftone image, and to reduce the scavenging effect and the edge effect, Patent Document 5 discloses a small diameter. Disclosed is a developer carrier having a small diameter (φ16 mm or less) that conveys a magnetic brush to a latent image carrier (φ30 or less), and setting a plurality of predetermined parameters, and toner for the image carrier In order to prevent image deterioration due to reverse transfer of toner, in Patent Document 6, discharge is generated between the surface of the photoconductor that does not participate in image formation immediately before the primary transfer and the toner on the intermediate transfer belt. It is disclosed that the potential difference between the surface potential of the photoreceptor and the surface potential of the intermediate transfer belt due to the primary transfer electric field is controlled so as not to occur.

本発明は、以上のような従来技術を背景として、転写時における転写ニップ上流、及び下流の微少空隙でのトナー転移を、現像時の像担持体(感光体)の表面電位分布(トナー顕像パターン)によらず防止して、転写チリ、ドット画像再現不良、トナー飛散、前工程転写トナーの像担持体への逆転写等の不具合を容易、且つ効果的に抑制することを課題とするものである。   In the present invention, against the background of the above-described conventional technology, toner transfer in a fine gap at the upstream and downstream of the transfer nip during transfer is performed with respect to the surface potential distribution (toner visible image) of the image carrier (photoreceptor) during development. The problem is to easily and effectively suppress defects such as transfer dust, poor dot image reproduction, toner scattering, and reverse transfer of toner transferred from the previous process to the image carrier. It is.

上記課題は、本発明にしたがって、像担持体(感光体)と、現像剤(一成分系現像剤又はトナーと磁性キャリアからなる二成分現像剤)を担持し搬送する現像剤担持体(現像ローラ;二成分現像剤使用の場合は、固定又は回転する磁石を内蔵した現像スリーブ)と、像担持体上に形成されたトナー像を転写材に電界転写する手段とを備えた画像形成装置において、上記現像剤担持体の表面と上記像担持体の表面との電位差が殆ど0Vであるときの、現像剤担持体と像担持体との対向領域を通過する直前の現像剤担持体に担持されている現像剤中トナーの平均帯電量をQ1、像担持体から次の転写材(直接転写方式では紙等の最終転写材、間接転写方式では中間転写体)表面に電界転写した直後の上記転写材の表面トナー像の平均帯電量をQ2とした場合に、
{│Q2│−│Q1│}/│Q1│≧−0.3
の関係を満足する条件下で現像することで、解決される。本発明の狙いは、現像剤中のトナーの平均帯電量と、後工程である、現像や転写の際のトナーの平均帯電量の差(低下量)を少なくすることにある。転写前途中のコロナチャージャ電荷付与等、何らかのトナー帯電嵩上げ処理工程を経由する場合もあり、その場合には一次転写体(中間転写体)での「トナー像の平均帯電量」と二次転写体(最終転写材)での「トナー像の平均帯電量」を同時に問題にすることもある。
According to the present invention, there is provided a developer carrier (developing roller) that carries and conveys an image carrier (photoconductor) and a developer (one-component developer or a two-component developer composed of toner and a magnetic carrier) according to the present invention. A developing sleeve incorporating a fixed or rotating magnet in the case of using a two-component developer), and means for electric field transfer of a toner image formed on the image carrier to a transfer material; When the potential difference between the surface of the developer carrier and the surface of the image carrier is almost 0 V, it is carried on the developer carrier just before passing through the opposing area between the developer carrier and the image carrier. The average charge amount of the toner in the developer is Q1, and the transfer material immediately after electric field transfer from the image carrier to the surface of the next transfer material (final transfer material such as paper in the direct transfer system, intermediate transfer body in the indirect transfer system) The average charge amount of the surface toner image is Q2 If it is,
{│Q2│-│Q1│} /│Q1│≧-0.3
This problem can be solved by developing under the condition satisfying the above relationship. The aim of the present invention is to reduce the difference (reduction amount) between the average charge amount of the toner in the developer and the average charge amount of the toner at the time of development or transfer, which is a subsequent step. In some cases, the toner charge is increased in some way, such as corona charger charge in the middle of transfer, and in that case, the “average charge amount of the toner image” on the primary transfer body (intermediate transfer body) and the secondary transfer body The “average charge amount of the toner image” in the (final transfer material) may be a problem at the same time.

ここで、│Q1│、│Q2│はトナー帯電量の絶対値を表し、トナー体積平均粒径が5〜12μm程度の場合は、Q1が負極性の場合は−15〜−50μC/gが好適であり、Q2は−10.5〜−60μC/gが好適である。現像工程に到達する前のトナーに付与する帯電量を適正レベルにして、転写ニップ前後の空隙部電界で転移する低帯電トナーの比率が増加する不具合を防止でき、転写ニップ前後空隙で像担持体から転写材への転写チリの主因である転移現象を防止できる。│Q1│が15μC/gに満たないと、現像に関わるトナー中に正規極性と逆の極性(上記例では+極性)に帯電したトナーの比率が過分になり、現像部からのトナー飛散等で機内を汚染したり、現像工程では像担持体の地肌部汚れが多くなる等の不具合がある。また│Q1│が50μC/gを超える場合は、現像工程で像担持体の高濃度画像部に十分量のトナーを現像でき難くなる。   Here, | Q1 | and | Q2 | represent absolute values of the toner charge amount. When the toner volume average particle diameter is about 5 to 12 μm, −15 to −50 μC / g is preferable when Q1 is negative. And Q2 is preferably −10.5 to −60 μC / g. The amount of charge applied to the toner before reaching the development process is set to an appropriate level, and the problem of an increase in the ratio of low-charged toner that is transferred by the gap electric field before and after the transfer nip can be prevented. The transfer phenomenon that is the main cause of transfer dust from the toner to the transfer material can be prevented. If | Q1 | is less than 15 μC / g, the ratio of the toner charged to the polarity opposite to the normal polarity (+ polarity in the above example) in the toner related to the development becomes excessive, and the toner is scattered from the developing unit. There are problems such as contaminating the inside of the machine and increasing the amount of background stains on the image carrier in the development process. If | Q1 | exceeds 50 μC / g, it becomes difficult to develop a sufficient amount of toner on the high-density image portion of the image carrier in the development step.

│Q2│が10.5μC/gに満たない場合は、転写に関わる像担持体上トナー中に非常に低い正規極性帯電のトナー(弱帯電トナー)比率が多く、像担持体と転写材間に間隙があり且つ弱い転写電界が作用しても、該弱帯電トナーが像担持体から離れて転写材に転移し易いトナー比率が多かったことになり、転写後の転写材上画像周辺部にトナーが散乱してしまう「転写チリ」の度合いが酷い。また│Q2│が60μC/gを超えている場合は、転写電界強度を強く(本発明例では高々転写材に加える転写バイアス電圧は1.5kVで済むが、例えば2.0kVの高電圧の転写バイアスを印加)した場合等で、転写後の転写材上高濃度部画像で90%以上の十分な転写率の画像が得られ難くなっている。更に、該高電圧を転写バイアスで用いた場合は、転写ニップ前後の空隙で放電が起き易く、該放電で像担持体上の低濃度部画像や低面積率画像(点や線等)に付着しているトナー(高濃度のベタ部画像のトナーより平均帯電量は低め)は極性が反転する割合が増え、転写し難くなったり(転写ヌケ)、一旦転写材に転写した画像が、再び像担持体に転移してしまう逆転写現象が起き易い。   If | Q2 | is less than 10.5 μC / g, the toner on the image carrier involved in the transfer has a very low ratio of normal polarity charged toner (weakly charged toner), and there is a gap between the image carrier and the transfer material. Even if there is a gap and a weak transfer electric field is applied, there is a large proportion of the toner that the weakly charged toner is likely to move away from the image carrier and transfer to the transfer material. The degree of “transfer dust” that scatters is severe. When | Q2 | exceeds 60 μC / g, the transfer electric field strength is high (in the example of the present invention, the transfer bias voltage applied to the transfer material is 1.5 kV at most, but a transfer voltage of, for example, 2.0 kV is high. When a bias is applied), it is difficult to obtain an image with a sufficient transfer rate of 90% or more in the high density portion image on the transfer material after transfer. Furthermore, when the high voltage is used as a transfer bias, discharge easily occurs in the gap before and after the transfer nip, and the discharge adheres to a low density portion image or a low area ratio image (dots, lines, etc.) on the image carrier. Toner (the average charge amount is lower than the toner of the solid image with high density) has a higher rate of polarity reversal, making it difficult to transfer (transfer failure), and the image once transferred to the transfer material is re-imaged. The reverse transfer phenomenon that is transferred to the carrier tends to occur.

上記課題は、また本発明にしたがって、像担持体と、現像剤担持体と、像担持体上に形成されたトナー像を転写材に電界転写する手段とを備えた画像形成装置において、上記現像剤担持体の表面と上記像担持体の表面との電位差が0Vであるときの、現像剤担持体と像担持体との対向領域を通過する直前の現像剤中トナーの平均帯電量をQ1、像担持体から次の転写材表面に電界転写する直前の上記像担持体の表面トナー像の平均帯電量をQ3とした場合に、
{│Q3│−│Q1│}/│Q1│≧−0.3
の関係を満足する条件下で現像することで、解決される。これは、転写直前のトナー帯電レベルを、トナー帯電量の減衰を抑えたり、像担持体上の画像を乱さない、コロナチャージャ等、何らかの帯電電荷付加によって、所定レベル電荷に保つものである。
According to the present invention, there is provided an image forming apparatus comprising: an image carrier; a developer carrier; and a means for transferring an electric field of a toner image formed on the image carrier to a transfer material. When the potential difference between the surface of the agent carrier and the surface of the image carrier is 0 V, the average charge amount of the toner in the developer immediately before passing through the opposing region between the developer carrier and the image carrier is Q1, When the average charge amount of the surface toner image of the image carrier immediately before electric field transfer from the image carrier to the surface of the next transfer material is Q3,
{│Q3│-│Q1│} /│Q1│≧-0.3
This problem can be solved by developing under the condition satisfying the above relationship. This is to maintain the toner charge level immediately before transfer at a predetermined level charge by adding some charge charge such as a corona charger that suppresses the attenuation of the toner charge amount and does not disturb the image on the image carrier.

ここで、│Q1│、│Q3│はトナー帯電量の絶対値を表し、トナー体積平均粒径が5〜12μm程度の場合は、Q1が負極性の場合は−15〜−50μC/gが好適であり、Q3は−10.5〜−60μC/gが好適である。現像工程に到達する前に帯電量を十分付与したトナーに関し、転写工程に到達する途中工程で弱い転写電界で転移する低帯電トナーの比率が増加する不具合を、トナーの体積抵抗率を高めて(本発明例では、3gトナーに6トン/5cmの加重を掛けて厚さ約2mmのトナーペレットに成型し、厚み方向に1kVの電圧を印加した時の、1分後測定抵抗で1012Ω・cm以上)トナー保持電荷の減衰を抑えたり、転写前に、負極性コロナ帯電等で、トナー電荷量を増やすことによって、転写時に弱帯電トナー比率を過分にしないようにすることで、転写ニップ前後空隙で像担持体から転写材に転写チリの主因である転移現象を防止できる。 Here, | Q1 | and | Q3 | represent the absolute value of the toner charge amount. When the toner volume average particle diameter is about 5 to 12 μm, −15 to −50 μC / g is preferable when Q1 is negative. Q3 is preferably −10.5 to −60 μC / g. Regarding the toner with sufficient charge amount before reaching the development step, the problem of increasing the ratio of low-charged toner that is transferred by a weak transfer electric field in the middle step of reaching the transfer step is increased by increasing the volume resistivity of the toner ( In the present invention, 3 g of toner was applied with a weight of 6 tons / 5 cm 2 to be molded into a toner pellet having a thickness of about 2 mm, and a resistance of 10 12 Ω was measured after 1 minute when a voltage of 1 kV was applied in the thickness direction. (Cm or more) By suppressing the attenuation of the toner holding charge or increasing the toner charge amount by negative corona charging before transfer, the weakly charged toner ratio is prevented from becoming excessive during transfer. The front-rear gap can prevent the transfer phenomenon that is the main cause of transfer dust from the image carrier to the transfer material.

│Q1│については既述したとおりである。│Q3│が10.5μC/gに満たない場合は、転写に関わる像担持体上トナー中に非常に低い正規極性帯電のトナー(弱帯電トナー)比率が多く、像担持体と転写材間に間隙があり且つ弱い転写電界が作用しても、該弱帯電トナーが像担持体から離れて転写材に転移し易いトナー比率が多く、転写後の転写材上画像周辺部にトナーが散乱してしまう「転写チリ」の度合いが酷くなる。また│Q3│が60μC/gを超えている場合は、転写電界強度を強く(本発明例では高々転写材に加える転写バイアス電圧は、1.5kVで済むが、例えば2.0kVの高電圧の転写バイアスを印加)する必要があり、転写後の転写材上高濃度部画像で90%以上の十分な転写率の画像が得られ難くなる。更に、該高電圧を転写バイアスで用いるため、転写ニップ前後の空隙で放電が起き易く、該放電で像担持体上の低濃度部画像や低面積率画像(点や線等)に付着しているトナー(高濃度のベタ部画像のトナーより平均帯電量は低め)は極性が反転する割合が増え、転写し難くなったり(転写ヌケ)、一旦転写材に転写した画像が、再び感光体に転移してしまう逆転写現象が起き易くなる。   | Q1 | is as described above. When | Q3 | is less than 10.5 μC / g, the toner on the image carrier involved in transfer has a very low ratio of normal polarity charged toner (weakly charged toner), and between the image carrier and the transfer material. Even if there is a gap and a weak transfer electric field acts, the ratio of the toner with which the weakly charged toner is likely to move away from the image carrier and transfer to the transfer material is large, and the toner is scattered around the image on the transfer material after transfer. The degree of “transfer dust” becomes severe. When | Q3 | exceeds 60 μC / g, the transfer electric field strength is high (in the example of the present invention, the transfer bias voltage applied to the transfer material is 1.5 kV at most, but for example, a high voltage of 2.0 kV is sufficient. It is necessary to apply a transfer bias), and it is difficult to obtain an image with a sufficient transfer rate of 90% or more in the high density portion image on the transfer material after transfer. Further, since the high voltage is used as a transfer bias, discharge easily occurs in the gap before and after the transfer nip, and the discharge adheres to a low density portion image or a low area ratio image (dots, lines, etc.) on the image carrier. The toner (which has a lower average charge than the toner of the high density solid image) has a higher polarity reversal rate, making it difficult to transfer (transfer failure), and the image once transferred to the transfer material is again transferred to the photoreceptor. The reverse transfer phenomenon that causes transfer is likely to occur.

上記課題は、また本発明にしたがって、像担持体と、現像剤担持体と、像担持体上に形成されたトナー像を転写材に電界転写する手段とを備えた画像形成装置において、上記現像剤担持体の表面と上記像担持体の表面との電位差が0Vであるときの、現像剤担持体と像担持体との対向領域を通過する直前の現像剤中トナーの平均帯電量をQ1、現像剤担持体に現像バイアスが印加され、像担持体表面の電位が画像部電位であるときの、現像剤担持体と像担持体との対向領域を通過した直後の像担持体表面の画像部に現像されたトナーの平均帯電量をQ4とした場合に、
{│Q4│−│Q1│}/│Q1│≧−0.3
の関係を満足する条件下で現像することで、解決される。これは、現像工程でのトナー帯電量の変化を抑えることを特徴とするものである。
According to the present invention, there is provided an image forming apparatus comprising: an image carrier; a developer carrier; and a means for transferring an electric field of a toner image formed on the image carrier to a transfer material. When the potential difference between the surface of the agent carrier and the surface of the image carrier is 0 V, the average charge amount of the toner in the developer immediately before passing through the opposing region between the developer carrier and the image carrier is Q1, When a developing bias is applied to the developer carrying member and the potential on the surface of the image carrying member is the image portion potential, the image portion on the surface of the image carrying member immediately after passing through the opposing region between the developer carrying member and the image carrying member. When the average charge amount of the developed toner is Q4,
{│Q4│-│Q1│} /│Q1│≧-0.3
This problem can be solved by developing under the condition satisfying the above relationship. This is characterized in that a change in the toner charge amount in the developing process is suppressed.

ここで、│Q1│、│Q4│はトナー帯電量の絶対値を表し、トナー体積平均粒径が5〜12μm程度の場合は、Q1が負極性の場合は−15〜−50μC/gが好適であり、Q4は−10.5〜−60μC/gが好適である。現像工程に到達する前に帯電量を十分付与したトナーに関し、現像・転写工程に到達する途中工程で弱い転写電界で転移する低帯電トナーの比率が増加する不具合を、現像時に像担持体に対しトナーが摩擦帯電系列上正規な極性側に位置するようにしたり、トナーの体積抵抗率の上限を抑えて(本発明例では、3gトナーに6トン/5cmの加重を掛けて厚さ約2mmのトナーペレットに成型し、厚み方向に1kVの電圧を印加した時の、1分後測定抵抗で1015Ω・cm以下)トナーに現像電界の直流成分によって電荷注入し易くしたり、2成分現像の現像電界に交番電界を重畳することによりトナーを振動させて、キャリアとの摩擦帯電量を増加させることで、転写工程前に転写前の予備コロナ帯電処理等の補助手段なしで、転写時に弱帯電トナー比率を過分にしないようにすることができ、転写ニップ前後空隙で感光体から転写材に転写チリの主因である転移現象を防止できる。尚、上記注入電荷に関しては、放電もし易いことから、トナーの体積抵抗率下限を既述のように1012Ω・cm以上にすることが望ましい。 Here, | Q1 | and | Q4 | represent absolute values of the toner charge amount. When the toner volume average particle diameter is about 5 to 12 μm, −15 to −50 μC / g is preferable when Q1 is negative. Q4 is preferably −10.5 to −60 μC / g. Regarding the toner that has been given enough charge before reaching the development process, there is a problem that the ratio of low-charged toner that is transferred by a weak transfer electric field increases during the development / transfer process. The toner is positioned on the normal polarity side in the triboelectric charge series, or the upper limit of the volume resistivity of the toner is suppressed (in the example of the present invention, a thickness of about 2 mm by applying a weight of 6 tons / 5 cm 2 to 3 g toner) When a voltage of 1 kV is applied in the thickness direction, the measured resistance is 10 15 Ω · cm or less after 1 minute. The toner is vibrated by superimposing an alternating electric field on the development electric field of the toner to increase the amount of frictional charge with the carrier, thereby transferring without auxiliary means such as a preliminary corona charging process before the transfer before the transfer process. The weakly charged toner ratio can prevent the excessive, the transition phenomenon is a major cause of transfer dust to the transfer material from the photosensitive member at the transfer nip before and after the gap can be prevented. The injected charge is easy to discharge, so the lower limit of the volume resistivity of the toner is desirably 10 12 Ω · cm or more as described above.

│Q1│については既述したとおりである。│Q4│が10.5μC/gに満たない場合は、転写に関わる像担持体上トナー中に非常に低い正規極性帯電のトナー(弱帯電トナー)比率が多く、像担持体と転写材間に間隙があり且つ弱い転写電界が作用しても、該弱帯電トナーが像担持体から離れて転写材に転移し易いトナー比率が多く、転写後の転写材上画像周辺部にトナーが散乱してしまう「転写チリ」の度合いが酷くなる。また│Q3│が60μC/gを超えている場合は、転写電界強度を強く(本発明例では高々転写材に加える転写バイアス電圧は、1.5kVで済むが、例えば2.0kVの高電圧の転写バイアスを印加)する必要があり、転写後の転写材上高濃度部画像で90%以上の十分な転写率の画像が得られ難くなる。更に、該高電圧を転写バイアスで用いるため、転写ニップ前後の空隙で放電が起き易く、該放電で感光体上の低濃度部画像や低面積率画像(点や線等)に付着しているトナー(高濃度のベタ部画像のトナーより平均帯電量は低め)は極性が反転する割合が増え、転写し難くなったり(転写ヌケ)、一旦転写材に転写した画像が、再び感光体に転移してしまう逆転写現象が起き易くなる。   | Q1 | is as described above. When | Q4 | is less than 10.5 μC / g, the toner on the image carrier involved in the transfer has a very low ratio of normal polarity charged toner (weakly charged toner), and there is a gap between the image carrier and the transfer material. Even if there is a gap and a weak transfer electric field acts, the ratio of the toner with which the weakly charged toner is likely to move away from the image carrier and transfer to the transfer material is large, and the toner is scattered around the image on the transfer material after transfer. The degree of “transfer dust” becomes severe. When | Q3 | exceeds 60 μC / g, the transfer electric field strength is high (in the example of the present invention, the transfer bias voltage applied to the transfer material is 1.5 kV at most, but for example, a high voltage of 2.0 kV is sufficient. It is necessary to apply a transfer bias), and it is difficult to obtain an image with a sufficient transfer rate of 90% or more in the high density portion image on the transfer material after transfer. Furthermore, since the high voltage is used as a transfer bias, discharge easily occurs in the gap before and after the transfer nip, and the discharge adheres to the low density portion image and the low area ratio image (dots, lines, etc.) on the photoconductor. Toner (average charge is lower than that of high-density solid image toner) increases the rate of polarity reversal, making it difficult to transfer (transfer failure), and the image once transferred to the transfer material is transferred to the photoreceptor again The reverse transfer phenomenon that occurs is likely to occur.

現像工程と転写工程の間に像担持体表面上トナー像に該トナーの正規極性と同極性の電荷を付与する手段を設けていれば、好適である。転写電界で転移する低帯電トナーの比率が増加する不具合を、該トナーの正規極性と同極性(例えばトナーの正規帯電極性が負の場合は負極性)の帯電で、トナー電荷量を増やすことによって、転写時に弱帯電トナー比率を過分にしないようにすることで、転写ニップ前後空隙で像担持体から転写材に転写チリの主因たる転移現象を防止できる。   It is preferable to provide means for applying a charge having the same polarity as the normal polarity of the toner to the toner image on the surface of the image carrier between the development process and the transfer process. By increasing the toner charge amount by charging the toner with the same polarity as the normal polarity of the toner (for example, negative polarity when the normal charge polarity of the toner is negative) By preventing the weakly charged toner ratio from becoming excessive during transfer, it is possible to prevent a transfer phenomenon mainly caused by transfer dust from the image carrier to the transfer material in the gap before and after the transfer nip.

像担持体表面の現像前地肌部電位をVD、画像部電位をVL、現像バイアス電圧をVBとすると0<|VD|−|VB|<|VD−VL|<400Vを満たす直流現像電界条件で現像すれば、現像剤担持体と像担持体間の電位差が小さく、現像領域でトナーの正規極性電荷を低減させる放電現象を防止でき、転写前に像担持体表面上トナー像に電荷付与処理を施すことなく、転写ニップ前後空隙で像担持体と転写材の転写チリを発生させる転移現象を防止できる。   Under the condition of a DC developing electric field satisfying 0 <| VD | − | VB | <| VD−VL | <400 V, where VD is the background potential before development on the surface of the image bearing member, VL is the image portion potential, and VB is the developing bias voltage. If developed, the potential difference between the developer carrier and the image carrier is small, and it is possible to prevent a discharge phenomenon that reduces the normal polarity charge of the toner in the development area, and to charge the toner image on the surface of the image carrier before transfer. Without applying, it is possible to prevent a transfer phenomenon that generates transfer dust between the image carrier and the transfer material in the gap before and after the transfer nip.

1成分現像の場合は現像剤担持体芯金と表層間の抵抗を10Ω以下(測定条件は電圧印加電極を一方は現像剤担持体芯金、他方は金属板、又は導電性テープ。他方、電極と現像剤担持体は現像ニップ相当面積で接触。印加電圧は200〜400V)に抑えることが好適である。2成分現像では、現像ギャップを0.2〜1mmに保ち、キャリアの抵抗を1014Ω・cm(100回タッピング充填。測定電極ギャップ2mm。印加電圧1kV)以下にすることが好適である。 In the case of one-component development, the resistance between the developer carrier core and the surface layer is 10 8 Ω or less (measurement conditions are a voltage application electrode, one developer carrier core, the other is a metal plate, or conductive tape. The electrode and the developer carrying member are in contact with each other in an area corresponding to the developing nip, and the applied voltage is preferably suppressed to 200 to 400 V). In the two-component development, it is preferable to keep the development gap at 0.2 to 1 mm and the carrier resistance to 10 14 Ω · cm (100 times tapping filling. Measurement electrode gap 2 mm; applied voltage 1 kV) or less.

トナーの比誘電率を2.5〜4、体積固有抵抗を1010〜1015Ω・cmとすれば、現像装置内で主に摩擦帯電電荷を付与されたトナーは、体積固有抵抗1015Ω・cm以下の場合、現像電界で静電誘導や電荷注入現象による帯電電荷増大効果が働き易く、且つ該帯電電荷増大効果で付与された電荷は該トナー電荷の放電時定数(抵抗と比誘電率の積に比例)が大きいので、転写工程まで保持し易く、転写工程でも有効に働き、像担持体非画像部対向による静電誘導や電荷注入による帯電電荷量の変化が起き難く、転写ニップ前後空隙で像担持体と転写材の転写チリを発生させる転移現象を防止できる。より好ましいトナーの比誘電率は2.5〜3、体積固有抵抗は1010〜1012Ω・cmである。 If the relative dielectric constant of the toner is 2.5 to 4 and the volume specific resistance is 10 10 to 10 15 Ω · cm, the toner to which the triboelectric charge is mainly applied in the developing device has a volume specific resistance of 10 15 Ω. When the thickness is less than or equal to cm, the effect of increasing the charged charge due to electrostatic induction or charge injection phenomenon is likely to work in the developing electric field, and the charge given by the charged charge increasing effect is the discharge time constant of the toner charge (resistance and relative dielectric constant) Is easy to hold up to the transfer process, works effectively in the transfer process, is less likely to change the amount of charged charge due to electrostatic induction or charge injection due to the non-image part facing the image carrier, and before and after the transfer nip It is possible to prevent a transition phenomenon that generates transfer dust between the image carrier and the transfer material in the gap. More preferably, the relative dielectric constant of the toner is 2.5 to 3, and the volume resistivity is 10 10 to 10 12 Ω · cm.

現像バイアスとして像担持体の画像部表面電位より高めと低めのレベルを現像領域内で少なくとも1周期以上繰り返す態様の交番電圧を用いれば、現像装置内で主に摩擦帯電電荷を付与されたトナーに対し、現像電界でトナー振動が起こり易く現像電界中でも摩擦帯電電荷増大効果が働き易く、且つ該帯電電荷増大効果で付与された電荷は該トナー電荷の放電時定数(抵抗と比誘電率の積に比例)が大きい場合に、転写工程まで保持し易いので、転写工程でも有効に働き像担持体非画像部対向による静電誘導や電荷注入による帯電電荷量の変化が起き難く、転写ニップ前後空隙で像担持体と転写材の転写チリを発生させる転移現象を防止できる。交番電圧の現像時の周波数は1KHz〜10KHz、該電圧の最大値と最小値の差は500V〜100Vが好適である。   If an alternating voltage having a mode in which a level higher and lower than the surface potential of the image portion of the image carrier is repeated for at least one cycle in the developing region is used as the developing bias, the toner which is mainly given triboelectric charge in the developing device is used. On the other hand, toner vibration easily occurs in the developing electric field, and the effect of increasing the triboelectric charge tends to work even in the developing electric field, and the charge applied by the effect of increasing the charged charge is the discharge time constant of the toner charge (the product of resistance and relative dielectric constant). When the (proportional) is large, it is easy to hold up to the transfer process, so it works effectively even in the transfer process, and electrostatic charge induced by the non-image part facing the image carrier and change in the charge amount due to charge injection hardly occur. It is possible to prevent a transfer phenomenon that generates transfer dust between the image carrier and the transfer material. The frequency at the time of development of the alternating voltage is preferably 1 KHz to 10 KHz, and the difference between the maximum value and the minimum value of the voltage is preferably 500 V to 100 V.

トナーをクリーニング回収する専用のクリーニング手段を備えなくとも、転写工程でトナーの帯電量が適正な範囲(本発明例では絶対値で10.5〜60μC/g)に維持でき、高効率転写で転写残トナーが非常に少なく、残像及び像担持体表面のトナーフィルミングを防止できる。   Even without a dedicated cleaning means for cleaning and collecting the toner, the charge amount of the toner can be maintained in an appropriate range (10.5 to 60 μC / g in absolute value in the example of the present invention) in the transfer process, and transfer is performed with high efficiency transfer. The residual toner is very small, and the residual image and toner filming on the surface of the image carrier can be prevented.

請求項1に記載の発明によれば、現像工程に到達する前に帯電量を十分付与したトナーに関し、弱い転写電界で転移する低帯電トナーの比率が増加する不具合を防止でき、転写ニップ前後空隙で像担持体と転写材の転写チリを発生させる転移現象を防止できる。   According to the first aspect of the present invention, it is possible to prevent a problem that the ratio of the low-charged toner that is transferred by a weak transfer electric field is increased with respect to the toner that has been sufficiently charged before reaching the developing process, and the gap before and after the transfer nip. Therefore, it is possible to prevent a transfer phenomenon that generates transfer dust between the image carrier and the transfer material.

請求項2に記載の発明によれば、現像工程に到達する前に帯電量を十分付与したトナーに関し、転写工程に到達する途中工程で弱い転写電界で転移する低帯電トナーの比率が増加する不具合を防止でき、転写ニップ前後空隙で像担持体と転写材の転写チリを発生させる転移現象を防止できる。   According to the second aspect of the present invention, with respect to the toner that has been sufficiently charged before reaching the developing step, the ratio of the low-charged toner that is transferred by a weak transfer electric field in the middle of the transfer step is increased. And a transfer phenomenon that generates transfer dust between the image carrier and the transfer material in the gap before and after the transfer nip.

請求項3に記載の発明によれば、現像工程に到達する前に帯電量を十分付与したトナーに関し、現像工程で弱い転写電界で転移する低帯電トナーの比率が増加する不具合を防止でき、転写前に像担持体表面上トナー像に電荷付与処理を施すことなく、転写ニップ前後空隙で像担持体と転写材の転写チリを発生させる転移現象を防止できる。   According to the third aspect of the present invention, it is possible to prevent an increase in the ratio of the low-charged toner that is transferred by a weak transfer electric field in the developing process, with respect to the toner that has been sufficiently charged before reaching the developing process. A transfer phenomenon that generates transfer dust between the image carrier and the transfer material in the gap before and after the transfer nip can be prevented without performing a charge imparting process on the toner image on the surface of the image carrier before.

請求項4に記載の発明によれば、現像工程に到達する前に帯電量を十分付与したトナーに関し、現像工程で弱い転写電界で転移する低帯電トナーの比率が増加しても、転写前に像担持体表面上トナー像に電荷付与処理を施すことによって、トナー像の低帯電トナーの比率を低減でき、転写ニップ前後空隙で像担持体と転写材の転写チリを発生させる転移現象を防止できる。転写電界で転移する低帯電トナーの比率が増加する不具合を、コロナ帯電等で、像担持体表面トナーの正規極性と同極性(トナーの正規帯電極性が負の場合には負極性)の電荷を付与して、トナー電荷量を増し、転写時に弱帯電トナー比率を過分にしないようにし、転写ニップ前後空隙で像担持体から転写材に転写チリの主因である転移現象を防止する。0.5〜10kHzで最大〜最小間電位差VP−Pが高々5kV程度の交流成分を含み、直流成分がトナーの正規極性側に偏ったコロナ帯電電荷を用いて、トナー電荷を過不足なく増やしてもよい。 According to the fourth aspect of the present invention, even if the ratio of the low-charged toner that is transferred by a weak transfer electric field in the development process is increased with respect to the toner that has been sufficiently charged before reaching the development process, before the transfer. By applying a charge imparting process to the toner image on the surface of the image carrier, the ratio of low-charged toner in the toner image can be reduced, and the transfer phenomenon that generates transfer dust between the image carrier and the transfer material in the gap before and after the transfer nip can be prevented. . The problem of an increase in the ratio of low-charged toner that is transferred by the transfer electric field is due to corona charging, etc., with a charge of the same polarity as the normal polarity of the toner on the image carrier surface (negative polarity when the normal charge polarity of the toner is negative) The toner charge amount is increased so that the ratio of the weakly charged toner is not excessive at the time of transfer, and the transfer phenomenon, which is the main cause of transfer dust from the image carrier to the transfer material, is prevented in the gap before and after the transfer nip. Comprises at most AC component of about 5kV maximum-minimum potential difference V P-P in 0.5~10KHz, using a corona charger charges the direct current component is biased to the normal polarity of the toner, increasing the toner charge without excess or deficiency May be.

請求項5に記載の発明によれば、現像材担持体と像担持体の間の差が小さいので、現像領域でトナーの正規極性電荷を低減させる放電現象を防止でき、転写前に像担持体表面上トナー像に電荷付与処理を施すことなく、転写ニップ前後空隙で像担持体と転写材の転写チリを発生させる転移現象を防止できる。好適条件例として、VDの絶対値が600V以下、VLの絶対値が50〜300V、VDとVLの差の絶対値が400V未満の組み合わせ条件が挙げられる。   According to the fifth aspect of the present invention, since the difference between the developer carrier and the image carrier is small, it is possible to prevent a discharge phenomenon that reduces the normal polarity charge of the toner in the development region, and the image carrier before transfer. A transfer phenomenon that generates transfer dust between the image carrier and the transfer material in the gap before and after the transfer nip can be prevented without applying a charge imparting process to the toner image on the surface. Examples of suitable conditions include combination conditions in which the absolute value of VD is 600 V or less, the absolute value of VL is 50 to 300 V, and the absolute value of the difference between VD and VL is less than 400 V.

請求項6に記載の発明によれば、現像装置内で主に摩擦帯電電荷を付与されたトナーが1015Ω・cm以下の場合、現像電界で静電誘導や電荷注入現象による帯電電荷増大効果が働きやすく、且つ該帯電電荷増大効果で付与された電荷は該トナー電荷の放電時定数(抵抗と比誘電率の積に比例)が大きいので、転写工程まで保持しやすいので、転写工程でも有効に働き像担持体非画像部対向による静電誘導や電荷注入による帯電電荷量の変化が起き難く、転写ニップ前後空隙で像担持体と転写材の転写チリを発生させる転移現象を防止できる。より好ましいトナーの比誘電率は2.5〜3、体積固有抵抗は1010〜1012Ω・cmである。またトナー帯電量の平均値の絶対値としては20〜40μC/g、トナーの体積平均粒径は4〜10μmが好適である。 According to the sixth aspect of the present invention, when the toner mainly imparted with triboelectric charge in the developing device is 10 15 Ω · cm or less, the effect of increasing the charged charge by electrostatic induction or charge injection phenomenon in the developing electric field. And the charge imparted by the effect of increasing the charged charge has a large discharge time constant (proportional to the product of resistance and relative dielectric constant) of the toner charge, so that it is easy to hold up to the transfer process, so it is also effective in the transfer process. Therefore, the electrostatic induction due to the non-image portion facing the image carrier and the change in the amount of charged charge due to the charge injection hardly occur, and the transfer phenomenon that generates transfer dust between the image carrier and the transfer material in the gap before and after the transfer nip can be prevented. More preferably, the relative dielectric constant of the toner is 2.5 to 3, and the volume resistivity is 10 10 to 10 12 Ω · cm. Further, the absolute value of the average toner charge amount is preferably 20 to 40 μC / g, and the toner volume average particle size is preferably 4 to 10 μm.

請求項7に記載の発明によれば、現像装置内で主に摩擦帯電電荷を付与されたトナーに対し、現像電界でトナー振動が起こりやすく現像電界中でも摩擦帯電電荷増大効果が働きやすく、且つ該帯電電荷増大効果で付与された電荷は該トナー電荷の放電時定数(抵抗と比誘電率の積に比例)が大きいので、転写工程まで保持しやすいので、転写工程でも有効に働き像担持体非画像部対向による静電誘導や電荷注入による帯電電荷量の変化が起き難く、転写ニップ前後空隙で像担持体と転写材の転写チリを発生させる転移現象を防止できる。交番電圧の現像時の周波数は1KHz〜10KHz、該電圧の最大値と最小値の差は500V〜100Vが好適である。   According to the seventh aspect of the present invention, the toner which is mainly given the triboelectric charge in the developing device is likely to vibrate in the developing electric field, and the triboelectric charge increasing effect is apt to work in the developing electric field. The charge imparted by the effect of increasing the charged charge has a large discharge time constant (proportional to the product of resistance and relative dielectric constant) of the toner charge, so that it can be easily held up to the transfer process, and thus works effectively in the transfer process. Changes in the amount of charged charge due to electrostatic induction due to the image portion facing or charge injection are unlikely to occur, and a transition phenomenon that generates transfer dust between the image carrier and the transfer material in the gap before and after the transfer nip can be prevented. The frequency at the time of development of the alternating voltage is preferably 1 KHz to 10 KHz, and the difference between the maximum value and the minimum value of the voltage is preferably 500 V to 100 V.

請求項8に記載の発明によれば、高効率転写で転写残トナーが非常に少ないので、残像及び像担持体表面のトナーフィルミングを防止できる。少なくとも現像手段の一つ(できれば黒色トナー使用現像手段)にクリーニング機能をもたせ、像担持体上の転写残トナーを回収させて、専用クリーニング手段を持たせずに像担持体のトナーフィルミングや残像画像の発生を防止すると、省スペース化やコストダウンに好適である。本発明では、転写で、トナー帯電電荷量分布が好適で、転写率が高めに維持できるので、転写残トナーの量が少なく、現像でクリーニングを兼ねる形態でも、転写残トナーによる残像を防止できる。   According to the eighth aspect of the present invention, since there is very little transfer residual toner with high-efficiency transfer, it is possible to prevent the residual image and toner filming on the surface of the image carrier. At least one of the developing means (preferably using black toner) is provided with a cleaning function to collect the transfer residual toner on the image carrier, so that the toner filming and afterimage of the image carrier without the dedicated cleaning means are provided. Preventing image generation is suitable for space saving and cost reduction. In the present invention, the toner charge charge amount distribution is suitable for transfer and the transfer rate can be maintained high, so that the residual image due to the transfer residual toner can be prevented even in a mode in which the amount of transfer residual toner is small and development also serves as cleaning.

本発明の詳細を、図に示された例に基づいて以下に説明する。
図1は、本発明を適用した画像形成装置であるカラーレーザープリンタ(以下、プリンタという)の概略構成を示すものである。図1において、矢印の方向に回転する像担持体としてのドラム状感光体1の周囲には、感光体クリーニングユニット2、感光体を1一様帯電する帯電手段としての帯電器4、画像情報に応じて感光体1に光を照射する露光手段としての露光ユニット5、感光体上の静電潜像を現像する現像手段6,7,8,9、中間転写ベルト10等が配置されている。感光体上にトナー像を形成するトナー像形成手段は、上記帯電器4、露光ユニット5、現像手段6,7,8,9等により構成されている。
The details of the present invention will be described below based on the example shown in the drawings.
FIG. 1 shows a schematic configuration of a color laser printer (hereinafter referred to as a printer) which is an image forming apparatus to which the present invention is applied. In FIG. 1, around a drum-shaped photoreceptor 1 as an image carrier rotating in the direction of an arrow, there are a photoreceptor cleaning unit 2, a charger 4 as a charging means for uniformly charging the photoreceptor, and image information. Correspondingly, an exposure unit 5 as exposure means for irradiating the photosensitive member 1 with light, developing means 6, 7, 8, 9 for developing an electrostatic latent image on the photosensitive member, an intermediate transfer belt 10 and the like are arranged. The toner image forming means for forming a toner image on the photoreceptor is constituted by the charger 4, the exposure unit 5, the developing means 6, 7, 8, 9 and the like.

現像手段は、イエロー現像器6、マゼンタ現像器7、シアン現像器8、ブラック現像器9の4個の現像器から構成される。フルカラー画像形成時はイエロー現像器6、マゼンタ現像器7、シアン現像器8、ブラック現像器9の順でトナー像(可視像)を形成し、各色のトナー像が中間転写ベルト10に順次重ね転写されることでフルカラー画像が形成される。トナー像が中間転写ベルト10に転写された後の感光体1の表面は、感光体クリーニングユニット2のブレード3でクリーニングされる。   The developing means includes four developing units, a yellow developing unit 6, a magenta developing unit 7, a cyan developing unit 8, and a black developing unit 9. When forming a full-color image, a toner image (visible image) is formed in the order of the yellow developing device 6, the magenta developing device 7, the cyan developing device 8, and the black developing device 9, and the toner images of the respective colors are sequentially superimposed on the intermediate transfer belt 10. A full color image is formed by the transfer. The surface of the photoreceptor 1 after the toner image is transferred to the intermediate transfer belt 10 is cleaned by the blade 3 of the photoreceptor cleaning unit 2.

中間転写ベルト10は、駆動ローラ13、一次転写バイアスローラ11、および従動ローラ12a,12bにより張架されており、不図示の駆動モータによって駆動されるようになっている。上記一次転写バイアスローラ11の圧接力は、圧接バネ30により調節されている。中間転写ベルト10は、PVDF(フッ化ビニルデン)、ETFE(エチレン−四フッ化エチレン共重合体)、PI(ポリイミド)、PC(ポリカーボネート)等にカーボンブラック等の導電性材料を分散させて電気抵抗を調整した混合・合成材料を2種類以上組み合わせることで使用でき、その体積抵抗率が10〜1015Ωcmの範囲にすると、感光体上トナー像を中間転写ベルトの表面に転写(一次転写)する際に転写チリが発生する不具合がでにくい。 The intermediate transfer belt 10 is stretched by a drive roller 13, a primary transfer bias roller 11, and driven rollers 12a and 12b, and is driven by a drive motor (not shown). The pressure contact force of the primary transfer bias roller 11 is adjusted by a pressure contact spring 30. The intermediate transfer belt 10 has an electrical resistance by dispersing a conductive material such as carbon black in PVDF (vinylidene fluoride), ETFE (ethylene-tetrafluoroethylene copolymer), PI (polyimide), PC (polycarbonate), or the like. Can be used by combining two or more types of mixed / synthetic materials with adjusted volume, and when the volume resistivity is in the range of 10 7 to 10 15 Ωcm, the toner image on the photoreceptor is transferred to the surface of the intermediate transfer belt (primary transfer). It is difficult to cause defects that cause transfer dust when

図2に示す例は、感光体1’がエンドレスベルト、現像が1成分現像方式を採用した例である。中間転写ベルト10の抵抗特性や材料・構成については、図1の例と同様である。   The example shown in FIG. 2 is an example in which the photoreceptor 1 ′ employs an endless belt and development uses a one-component development system. The resistance characteristics, material, and configuration of the intermediate transfer belt 10 are the same as in the example of FIG.

ここで、一次転写バイアスローラ11による圧接によって生じる感光体1と中間転写ベルト10との当接圧は、5×10−4Mpa以上、5×10−2Mpa以下であるのが望ましい。この範囲内であると、圧接力不足による転写性の悪化、及び過圧接によるトナーの凝集を防ぐことができ、転写効率を向上させ、中抜け画像の発生を防止することができる。 Here, the contact pressure between the photoreceptor 1 and the intermediate transfer belt 10 caused by the pressure contact by the primary transfer bias roller 11 is preferably 5 × 10 −4 Mpa or more and 5 × 10 −2 Mpa or less. Within this range, transferability deterioration due to insufficient pressure contact force and toner aggregation due to overpressure contact can be prevented, transfer efficiency can be improved, and occurrence of void images can be prevented.

中間転写ベルトの表面が弾性を有し、好ましくは表面マイクロ硬度をマイクロゴム硬度計(例えば、高分子計器社製:MD−1)による測定で30度〜70度の範囲にすることで、一次転写の転写ニップでトナー像部分に転写圧力が集中するのを防止でき、一次転写時のトナー像と像担持体の間の非静電気的付着力上昇を防止でき、一次転写の転写ヌケを防止できる。更に、転写材、記録媒体たる転写紙の表面性にかかわらず、白抜け、中抜け、文字つぶれ、色ずれ等が発生しない転写を行うことができ、高品質なフルカラー画像を印字することができる。   The surface of the intermediate transfer belt has elasticity, and preferably the surface micro hardness is adjusted to a range of 30 to 70 degrees as measured by a micro rubber hardness meter (for example, MD-1 manufactured by Kobunshi Keiki Co., Ltd.) It is possible to prevent the transfer pressure from concentrating on the toner image portion at the transfer nip of the transfer, to prevent a non-electrostatic adhesive force increase between the toner image and the image carrier during the primary transfer, and to prevent the primary transfer from being lost. . Furthermore, regardless of the surface properties of the transfer material and the transfer paper as the recording medium, it is possible to perform transfer without occurrence of white spots, voids, character collapse, color misregistration, etc., and high quality full color images can be printed. .

また、中間転写ベルトが厚み方向に圧縮性を有した弾性層を備える構成とし、好ましくは表面マイクロ硬度をマイクロゴム硬度計(例えば、高分子計器社製:MD−1)による測定で30度〜70度の範囲にすることでも、一次転写の転写ニップでトナー像部分に転写圧力が集中するのを防止でき、一次転写時のトナー像と像担持体の間の非静電気的付着力上昇を防止でき、一次転写の転写ヌケの防止余裕度を向上できる。   In addition, the intermediate transfer belt is provided with an elastic layer having compressibility in the thickness direction, and preferably the surface micro hardness is 30 degrees as measured by a micro rubber hardness meter (for example, MD-1 manufactured by Kobunshi Keiki Co., Ltd.). Even within the range of 70 degrees, it is possible to prevent the transfer pressure from being concentrated on the toner image portion at the transfer nip of the primary transfer, and to prevent a non-electrostatic adhesion increase between the toner image and the image carrier during the primary transfer. In addition, it is possible to improve the degree of prevention of the transfer failure in the primary transfer.

また、感光体表面の保護層にシリコーンオイルSH200(東レ・ダウコーニング・シリコーン社製)を少し(0.1〜1.0部程度)存在させたり、ステアリン酸亜鉛等の潤滑剤を感光体表面に塗布する等で、中間転写ベルトのオイラ−ベルト法で測定した静止摩擦係数μが感光体の静止摩擦係数μ以上より相対的に大きくなる(μ≧μ)ようにすると、一次転写時のトナー像と像担持体の間の非静電気的付着力上昇を抑制でき、一次転写の転写ヌケの防止余裕度を向上できる。 In addition, a small amount (about 0.1 to 1.0 part) of silicone oil SH200 (manufactured by Toray Dow Corning Silicone) is present in the protective layer on the surface of the photoreceptor, or a lubricant such as zinc stearate is added to the surface of the photoreceptor. When the static friction coefficient μ 1 measured by the Euler-belt method of the intermediate transfer belt is relatively larger than the static friction coefficient μ 2 or more of the photosensitive member (μ 1 ≧ μ 2 ). The increase in non-electrostatic adhesion between the toner image and the image carrier during transfer can be suppressed, and the prevention margin for primary transfer loss can be improved.

重合トナー等の球形に近いトナーで、平均円形度0.90〜0.99のトナーを使用し、トナー像と感光体の非静電気的付着力上昇を抑制すると、一次転写電界強度を抑制でき、一次転写の転写ヌケの防止余裕度を向上できる。母体トナー中に、定着部でオイル塗布の必要がないようにワックス等の離型剤を含ませたトナーを使用し、トナー表面に若干ではあるが離型剤が存在する状態にして、トナー像と感光体の非静電気的付着力上昇を抑制すると、一次転写電界強度を抑制でき、一次転写の転写ヌケの防止余裕度を向上できる。母体トナーに疎水性の無機微粒子を外添し、より好ましくはシリカ(SiO)を外添して、トナーの流動性を良くし、トナー像と感光体の非静電気的付着力上昇を抑制すると、一次転写電界強度を抑制でき、一次転写の転写ヌケの防止余裕度を向上できる。シリカはシランカップリング剤、シリコーンオイル等によって表面を疎水化処理したものが更に好ましい。 By using a toner with an average circularity of 0.90 to 0.99, which is close to a spherical toner such as a polymerized toner, and suppressing the increase in non-electrostatic adhesion between the toner image and the photoreceptor, the primary transfer electric field strength can be suppressed, It is possible to improve the degree of prevention of primary transfer transfer leakage. In the base toner, a toner containing a release agent such as wax is used so that it is not necessary to apply oil at the fixing portion, and the toner image is made in a state where there is a slight release agent on the toner surface. If the increase in non-electrostatic adhesion force between the photosensitive member and the photosensitive member is suppressed, the primary transfer electric field strength can be suppressed, and the degree of prevention of transfer failure during primary transfer can be improved. When hydrophobic inorganic fine particles are externally added to the base toner, and more preferably silica (SiO 2 ) is externally added to improve the fluidity of the toner and suppress the increase in non-electrostatic adhesion between the toner image and the photoreceptor. In addition, the primary transfer electric field strength can be suppressed, and the prevention margin for the transfer failure in the primary transfer can be improved. Silica is more preferably hydrophobized on the surface with a silane coupling agent, silicone oil or the like.

また中間転写ベルト10の表面には、必要に応じて離型層をコートしてもよい。このコートに用いる材料としては、ETFE、PTFE(ポリ四フッ化エチレン)、PVDF、PEA(パーフルオロアルコキシフッ素樹脂)、FEP(四フッ化エチレン−六フッ化プロピレン共重合体)、PVF(フッ化ビニル)等のフッ素樹脂が使用できるが、これらに限定されない。   Further, the surface of the intermediate transfer belt 10 may be coated with a release layer as necessary. Materials used for this coating include ETFE, PTFE (polytetrafluoroethylene), PVDF, PEA (perfluoroalkoxy fluororesin), FEP (tetrafluoroethylene-hexafluoropropylene copolymer), PVF (fluorinated). A fluororesin such as vinyl) can be used, but is not limited thereto.

次に、静止摩擦係数の測定を上記オイラー法による行う場合について説明する。先ず、紙片(TYPE6200、A4T目:株式会社リコー製)を297mm×30mmに切り、両端に糸を付けて測定紙片を作成する。紙片の特性は秤量:71.7g/m2、厚さ:89μm、密度:0.81g/cm、平滑度:表;40s、裏;37s、体積抵抗:1.2E+11Ω・cm、摩擦係数:表/裏;(ゴム付きオモリ)tanθで、縦;0.64、横;0.65である。測定紙片をテーブルの一端に支持部材を用いて支持された感光体ドラム1にのせて、一方の糸に0.98N(100g重)の重りを結び付け、他方の糸にはデジタルプッシュプルゲージを結び付ける。この状態でデジタルプッシュプルゲージによって糸を介して測定紙片を引っ張り、測定紙片が動き出した時のデジタルプッシュプルゲージの値を読む。この時の値をF(N)とすると、静止摩擦係数μは、
μ=(2/π)×〔ln(F/0.98)〕
で求められる。
Next, the case where the static friction coefficient is measured by the Euler method will be described. First, a piece of paper (TYPE 6200, A4T: manufactured by Ricoh Co., Ltd.) is cut into 297 mm × 30 mm, and yarns are attached to both ends to create a measurement piece. The properties of the paper piece are: Weighing: 71.7 g / m 2, Thickness: 89 μm, Density: 0.81 g / cm 3 , Smoothness: Table: 40 s, Back: 37 s, Volume resistance: 1.2E + 11 Ω · cm, Friction coefficient: Table / Back; (Body with rubber) Tan θ, length: 0.64, width: 0.65. A piece of measurement paper is placed on the photosensitive drum 1 supported at one end of the table by using a support member, and a weight of 0.98 N (100 g weight) is tied to one thread, and a digital push-pull gauge is tied to the other thread. . In this state, the measurement paper piece is pulled through the thread by the digital push-pull gauge, and the value of the digital push-pull gauge when the measurement paper piece starts to move is read. If the value at this time is F (N), the coefficient of static friction μ is
μ = (2 / π) × [ln (F / 0.98)]
Is required.

中間転写ベルト10の製造方法としては、注型法や遠心成型法等がある。表面粗さRzを小さくする場合には、ベルトの表面に対応する型側の表面粗さRzを小さくすることで、該ベルトの表面粗さRzの値を調節することが可能である。尚、必要に応じて、ベルト表面を研磨して調節してもよい。   Examples of the method for manufacturing the intermediate transfer belt 10 include a casting method and a centrifugal molding method. When reducing the surface roughness Rz, it is possible to adjust the value of the surface roughness Rz of the belt by reducing the surface roughness Rz on the mold side corresponding to the surface of the belt. Note that the belt surface may be polished and adjusted as necessary.

中間転写ベルト10に接離可能なベルトクリーニングユニット19は、クリーニングブレード18、およびクリーニングブレード18を中間転写ベルト10に対して接離させる接離機構26等で構成されており、1色目のイエロー画像を一次転写したあとの、2、3、4色目を一次転写している間は、上記接離機構26によって中間転写ベルト10の表面から離間させられる。上記接離機構26は、クリーニングブレード18が感光体1の表面に当接するようにクリーニングユニット19を付勢する不図示の付勢手段と、クリーニングユニット19の揺動する底面部に当接した状態で後述の制御部200で回転駆動される偏心カムを用いて構成されている。   The belt cleaning unit 19 that can contact and separate from the intermediate transfer belt 10 includes a cleaning blade 18 and a contact / separation mechanism 26 that contacts and separates the cleaning blade 18 from the intermediate transfer belt 10, and the first color yellow image. During the primary transfer of the second, third, and fourth colors after the primary transfer, the contact / separation mechanism 26 separates the surface from the surface of the intermediate transfer belt 10. The contact / separation mechanism 26 is in contact with a biasing means (not shown) that biases the cleaning unit 19 so that the cleaning blade 18 is in contact with the surface of the photosensitive member 1 and a bottom surface of the cleaning unit 19 that swings. Thus, an eccentric cam that is rotationally driven by a control unit 200 described later is used.

また、中間転写ベルト10の外周面の幅方向端部にはベルト位置検出マーク23が設けられており、マークセンサ24によって上記マーク23が検出されたタイミングで各色の画像形成プロセスを開始することにより、各色画像の正確な色重ねが可能となる。本技術では、中間転写ベルトの回動方向の伸縮歪みや変化が無いので色ずれ防止に有効である。   Further, a belt position detection mark 23 is provided at an end portion in the width direction of the outer peripheral surface of the intermediate transfer belt 10. By starting the image forming process for each color at the timing when the mark 23 is detected by the mark sensor 24. Thus, accurate color superposition of each color image becomes possible. This technique is effective in preventing color misregistration because there is no stretching distortion or change in the rotation direction of the intermediate transfer belt.

二次転写ユニット15は、二次転写バイアスローラ14、および該二次転写バイアスローラ14を中間転写ベルト10に対して接離させる接離機構16等で構成されている。接離機構16は、二次転写バイアスローラ14が中間転写ベルト10から離間するように二次転写ユニット15を付勢する付勢手段としてのバネ部材と、二次転写ユニット15の揺動する底面部に当接した状態で後述する制御部200により回転駆動される偏心カムとを用いて構成されている。二次転写バイアスローラ14はSUS等の金属製芯金上に、導電性材料によって10〜1010Ωの抵抗値に調整されたウレタン等の弾性体を被覆することで構成されている。なお、二次転写バイアスローラ14の抵抗値測定は、導電性の金属製板に二次転写バイアスローラ14を設置し、芯金両端部に片側4.9N(両側で合計9.8N)の荷重を掛けた状態にて、芯金と金属製板との間に1000Vの電圧を印加したときに流れる電流値から算出した。 The secondary transfer unit 15 includes a secondary transfer bias roller 14 and a contact / separation mechanism 16 that contacts and separates the secondary transfer bias roller 14 from the intermediate transfer belt 10. The contact / separation mechanism 16 includes a spring member as a biasing unit that biases the secondary transfer unit 15 so that the secondary transfer bias roller 14 is separated from the intermediate transfer belt 10, and a bottom surface on which the secondary transfer unit 15 swings. It is comprised using the eccentric cam rotated by the control part 200 mentioned later in the state contact | abutted to the part. The secondary transfer bias roller 14 is configured by coating a metal core such as SUS with an elastic body such as urethane adjusted to a resistance value of 10 6 to 10 10 Ω with a conductive material. The resistance value of the secondary transfer bias roller 14 is measured by installing the secondary transfer bias roller 14 on a conductive metal plate and applying a load of 4.9 N on one side (total of 9.8 N on both sides) to both ends of the core metal. In the state which applied, it computed from the electric current value which flows when a voltage of 1000V is applied between a metal core and a metal plate.

二次転写バイアスローラ14は、不図示の駆動ギヤによって駆動力が与えられており、その周速は中間転写ベルト10の周速に対して、略同一となるよう調整されている。この二次転写バイアスローラ14は、通常中間転写ベルト10の表面から離間しているが、中間転写ベルト10の表面に形成された4色の重ね画像を転写紙22に一括転写するときにタイミングを取って接離機構16で押圧され、二次転写バイアス印加手段としての高圧電源100により、二次転写バイアスローラ14に二次転写バイアスを印加することにより、中間転写ベルト10から転写紙22への転写を行う。   The secondary transfer bias roller 14 is given a driving force by a driving gear (not shown), and its peripheral speed is adjusted to be substantially the same as the peripheral speed of the intermediate transfer belt 10. The secondary transfer bias roller 14 is usually separated from the surface of the intermediate transfer belt 10, but the timing when the four-color superimposed images formed on the surface of the intermediate transfer belt 10 are collectively transferred to the transfer paper 22. Then, it is pressed by the contact / separation mechanism 16 and a secondary transfer bias is applied to the secondary transfer bias roller 14 by a high-voltage power source 100 as a secondary transfer bias applying means, whereby the intermediate transfer belt 10 is transferred to the transfer paper 22. Transcription.

上記構成のプリンタにおいて、上記転写紙22は給紙ローラ25、レジストローラ21によって、中間転写ベルト10上の4色重ね画像の先端部が二次転写位置に到達するタイミングに合わせて給紙される。転写紙22に転写された4色重ね画像は定着手段17で定着された後、排紙される。   In the printer having the above-described configuration, the transfer paper 22 is fed by the paper feed roller 25 and the registration roller 21 at the timing when the leading end of the four-color superimposed image on the intermediate transfer belt 10 reaches the secondary transfer position. . The four-color superimposed image transferred to the transfer paper 22 is fixed by the fixing unit 17 and then discharged.

上記プリンタにおいて使用されるトナーは、体積平均粒径が4〜10μmの範囲であることが望ましい。トナーの粒径を上記範囲のように小径化することで、トナー飛散を防止し、かつ、高解像度での画像形成が可能となるとともに、トナー小径化による、現像時の地汚れ、トナーの流動性の悪化及びトナー凝集を防止し、中抜け画像の発生を効果的に防止できる。   The toner used in the printer preferably has a volume average particle size in the range of 4 to 10 μm. By reducing the particle size of the toner within the above range, toner scattering can be prevented and high-resolution image formation can be achieved. Deterioration of toner and toner aggregation can be prevented, and the occurrence of a void image can be effectively prevented.

上記トナーに使用される結着樹脂としては、従来からトナー用結着樹脂として使用されてきたものは全てが適用可能である。具体的には、ポリオール樹脂、スチレンアクリル共重合体、ポリスチレン、ポリクロロスチレン、ポリビニルトルエン等のスチレン及びその置換体の単重合体、スチレン/p−クロロスチレン共重合体、また、スチレン/プロピレン共重合体、スチレン/ビニルトルエン共重合体、スチレン/ビニルナフタレン共重合体、スチレン/アクリル酸メチル共重合体、スチレン/アクリル酸エチル共重合体、スチレン/アクリル酸ブチル共重合体、スチレン/アクリル酸オクチル共重合体、スチレン/メタクリル酸メチル共重合体、スチレン/メタクリル酸エチル共重合体、スチレン/メタクリル酸ブチル共重合体、スチレン/α−クロルメタクリル酸メチル共重合体、スチレン/アクリロニトリル共重合体、スチレン/ビニルエチルエーテル共重合体、スチレン/ビニルメチルケトン共重合体、スチレン/ブタジエン共重合体、スチレン/イソプレン共重合体、スチレン/アクリロニトリル/インデン共重合体、スチレン/マレイン酸共重合体、スチレン/マレイン酸エステル共重合体等のスチレン系共重合体、更には、ポリメチルメタクリレート、ポリブチルメタクリレート、ポリ塩化ビニル、ポリ酢酸ビニル、ポリエチレン、ポリプロピレン、ポリエステル、ポリビニルブチルブチラール、ポリアクリル酸樹脂、ロジン、変性ロジン、テルペン樹脂、フェノール樹脂、脂肪族又は脂環族炭化水素樹脂、芳香族系石油樹脂、塩素化パラフィン、パラフィンワックス等が使用可能であり、これらは単独であるいは2種以上を混合して使用される。   As the binder resin used for the toner, all those conventionally used as a binder resin for toner can be applied. Specifically, polyol resins, styrene acrylic copolymers, styrene such as polystyrene, polychlorostyrene, polyvinyltoluene, and the like, homopolymers of styrene / p-chlorostyrene copolymers, and styrene / propylene copolymers. Polymer, styrene / vinyl toluene copolymer, styrene / vinyl naphthalene copolymer, styrene / methyl acrylate copolymer, styrene / ethyl acrylate copolymer, styrene / butyl acrylate copolymer, styrene / acrylic acid Octyl copolymer, styrene / methyl methacrylate copolymer, styrene / ethyl methacrylate copolymer, styrene / butyl methacrylate copolymer, styrene / α-chloromethyl methacrylate copolymer, styrene / acrylonitrile copolymer , Styrene / vinyl ethyl ether copolymer Styrene / vinyl methyl ketone copolymer, styrene / butadiene copolymer, styrene / isoprene copolymer, styrene / acrylonitrile / indene copolymer, styrene / maleic acid copolymer, styrene / maleic acid ester copolymer Styrene-based copolymers such as polymethyl methacrylate, polybutyl methacrylate, polyvinyl chloride, polyvinyl acetate, polyethylene, polypropylene, polyester, polyvinyl butyl butyral, polyacrylic acid resin, rosin, modified rosin, terpene resin, Phenol resin, aliphatic or alicyclic hydrocarbon resin, aromatic petroleum resin, chlorinated paraffin, paraffin wax and the like can be used, and these are used alone or in admixture of two or more.

上記トナーに使用される着色剤としては、従来からトナー用着色剤として使用されてきた染料及び顔料全てを適用可能である。具体的には、カーボンブラック、ニグロシン染料、鉄黒、ナフトールイエローS、ハンザイエロー(10G、5G、G)、カドミユウムイエロー、黄色酸化鉄、黄土、黄鉛、チタン黄、オイルイエロー、ハンザイエロー、(GR、A、RN、R)、ピグメントイエローL、ベンジジンイエロー(G、GR)、パーマネントイエロー(NCG)、バルカンファストイエロー(5G、R)、タートラジンレーキ、キノリンイエローレーキ、アンスラゲンイエローBGL、イソインドリノンイエロー、ベンガラ、鉛丹、鉛朱、カドミユウムレッド、カドミユウムマーキュリレッド、アンチモン朱、パーマネントレッド4R、パラレッド、ファイヤーレッド、パラクロルオルトニトロアニリンレッド、リソールファストスカーレットG、ブリリアントファストスカーレット、ブリリアントカーミンBS、パーマネントレッド(E2R、F4R、FRL、FRLL、F4RH)、ファストスカーレットVD、ベルカンファストルビンB、ブリリアントスカーレットG、リソールルビンGX、パーマネントレッドF5R、ブリリアントカーミン6B、ピグメントスカーレット3B、ボルドー5B、トルイジンマリーン、パーマネントボルドーF2K、ヘリオボルドーBL、ボルドー10B、ボンマリーンライト、ボンマリーンメジアム、エオシンレーキ、ローダミンレーキB、ローダミンレーキY、アリザリンレーキ、チオインジゴレットB、チオインジゴマルーン、オイルレッド、キナクリドンレッド、ピラゾロンレッド、クロームバーミリオン、ベンジジンオレンジ、ペリノンオレンジ、オイルオレンジ、コバルトブルー、セルリアンブルー、アルカリブルーレーキ、ピーコックブルーレーキ、ビクトリアブルーレーキ、無金属フタロシアニンブルー、フタロシアニンブルー、ファストスカイブルー、インダンスレンブルー(RS、BC)、インジゴ、群青、紺青、アントラキノンブルー、ファストバイオレットB、メチルバイオレットレーキ、コバルト紫、マンガン紫、ジオキサジンバイオレット、アントラキノンバイオレット、クロムグリーン、ジンクグリーン、酸化クロム、ピリジアンエメラルドグリーン、ピグメントグリーンB、ナフトールグリーンB、グリーンゴールド、アシッドグリーンレーキ、マラカイトグリーンレーキ、フタロシアニングリーン、アントラキノングリーン、酸化チタン、亜鉛華、リトボン及びそれらの混合物等を使用することが可能である。尚、上記着色剤の使用量は、一般に、バインダー樹脂100重量部に対して、0.1〜50重量部である。   As the colorant used in the toner, all dyes and pigments that have been conventionally used as toner colorants can be applied. Specifically, carbon black, nigrosine dye, iron black, naphthol yellow S, Hansa yellow (10G, 5G, G), cadmium yellow, yellow iron oxide, ocher, yellow lead, titanium yellow, oil yellow, Hansa yellow, (GR, A, RN, R), Pigment Yellow L, Benzidine Yellow (G, GR), Permanent Yellow (NCG), Vulcan Fast Yellow (5G, R), Tartrazine Lake, Quinoline Yellow Lake, Anslagen Yellow BGL, Isoindolinone yellow, Bengala, red lead, lead red, cadmium red, cadmium mercury red, antimony red, permanent red 4R, para red, fire red, parachlor ortho nitroaniline red, risor fast scarlet G, brilliant Fast Scarlet, Brilliant Carmine BS, Permanent Red (E2R, F4R, FRL, FRLL, F4RH), Fast Scarlet VD, Belkan Fast Rubin B, Brilliant Scarlet G, Resol Rubin GX, Permanent Red F5R, Brilliant Carmine 6B, Pigment Scarlet 3B Bordeaux 5B, Toluidine Marine, Permanent Bordeaux F2K, Helio Bordeaux BL, Bordeaux 10B, Bon Marine Light, Bon Marine Medium, Eosin Lake, Rhodamine Lake B, Rhodamine Lake Y, Alizarin Lake, Thioindigolet B, Thioindigo Maroon, Oil Red, quinacridone red, pyrazolone red, chrome vermilion, benzidine orange, perinone orange, orange Le Orange, Cobalt Blue, Cerulean Blue, Alkaline Blue Lake, Peacock Blue Lake, Victoria Blue Lake, Metal-Free Phthalocyanine Blue, Phthalocyanine Blue, Fast Sky Blue, Indanthrene Blue (RS, BC), Indigo, Ultraviolet, Bituminous, Anthraquinone Blue, Fast Violet B, Methyl Violet Lake, Cobalt Purple, Manganese Purple, Dioxazine Violet, Anthraquinone Violet, Chrome Green, Zinc Green, Chrome Oxide, Pyridian Emerald Green, Pigment Green B, Naphthol Green B, Green Gold, Acid Green Lake, Malachite Green Lake, Phthalocyanine Green, Anthraquinone Green, Titanium Oxide, Zinc Hana, Litobon and it It is possible to use a mixture of these. In addition, generally the usage-amount of the said coloring agent is 0.1-50 weight part with respect to 100 weight part of binder resin.

本例では、4色のトナーを使用するが、3色や2色あるいは単色又は5色以上のトナーを用いてもかまわない。また使用する色の種類も、どのような色であってもかまわないが、フルカラーを再現できる色を選択するのが好ましい。特に、上述のように、トナーの色が、黒、イエロー、シアン、マゼンタの4色であると、現像の回数が少なくてすみ、かつ比較的広い色調範囲をカバーできるので好適である。   In this example, four colors of toner are used, but toner of three colors, two colors, single color, or five colors or more may be used. The type of color used may be any color, but it is preferable to select a color that can reproduce a full color. In particular, as described above, it is preferable that the toner colors are black, yellow, cyan, and magenta because the number of developments can be reduced and a relatively wide color tone range can be covered.

また上記トナーには、必要に応じて、帯電制御剤を含有させてもよい。この帯電制御剤としては、公知のものが全て使用できる。具体的には、ニグロシン系染料、トリフェニルメタン系染料、クロム含有金属錯体染料、モリブデン酸キレート顔料、ローダミン系染料、アルコキシ系アミン、4級アンモニウム塩(フッ素変性4級アンモニウム塩を含む)、アルキルアミド、燐の単体または化合物、タングステンの単体または化合物、フッ素系活性剤、サリチル酸金属塩、サリチル酸誘導体の金属塩等を使用することが可能である。   The toner may contain a charge control agent as necessary. Any known charge control agent can be used. Specifically, nigrosine dyes, triphenylmethane dyes, chromium-containing metal complex dyes, molybdate chelate pigments, rhodamine dyes, alkoxy amines, quaternary ammonium salts (including fluorine-modified quaternary ammonium salts), alkyls Amides, phosphorus simple substances or compounds, tungsten simple substances or compounds, fluorine-based activators, salicylic acid metal salts, metal salts of salicylic acid derivatives, and the like can be used.

上記帯電制御剤の使用量は、バインダー樹脂の種類、必要に応じて使用される添加剤の有無、分散方法を含めたトナー製造方法等によって決定されるもので、一義的に限定されるものではないが、好ましくは、バインダー樹脂100重量部に対して0.1〜10重量部の範囲で用いられる。更に好ましくは、2〜5重量部の範囲がよい。ここで、0.1重量部未満の場合には、トナーの負帯電が不足し実用的でない。また10重量部を越える場合には、トナーの帯電性が高すぎて、キャリアや現像スリーブ等との静電吸引力が増大し、スペントやフィルミング等によって画像濃度の低下を招く。尚、必要に応じて、複数の帯電制御剤を併用してもよい。   The amount of the charge control agent used is determined by the type of binder resin, the presence or absence of additives used as necessary, the toner production method including the dispersion method, etc. However, it is preferably used in the range of 0.1 to 10 parts by weight with respect to 100 parts by weight of the binder resin. More preferably, the range of 2 to 5 parts by weight is good. Here, when the amount is less than 0.1 parts by weight, the toner is insufficiently charged and is not practical. On the other hand, when the amount exceeds 10 parts by weight, the chargeability of the toner is too high, and the electrostatic attraction force with the carrier, the developing sleeve or the like increases, and the image density is lowered due to spent or filming. If necessary, a plurality of charge control agents may be used in combination.

本例のプリンタでは、トナー単独で現像剤となって静電潜像を顕像化する所謂1成分現像法で現像してもよいし、トナーとキャリアを混合してなる2成分現像剤を用いて静電潜像を顕像化する2成分現像法で現像してもよい。2成分現像法を用いる場合、使用キャリアとしては、鉄粉、フェライト、ガラスビーズ等、従来と同様のものを使用することができる。また、これらキャリアは、樹脂を被覆したものであってもよく、この樹脂としては、ポリフッ化炭素、ポリ塩化ビニル、ポリ塩化ビニリデン、フェノール樹脂、ポリビニルアセタール、シリコーン樹脂等を使用することができる。いずれにしても、トナーとキャリアとの混合割合は、一般にキャリア100重量部に対して、トナー0.5〜6.0重量部程度が適当である。   In the printer of this example, development may be performed by a so-called one-component development method in which an electrostatic latent image is visualized by using toner alone as a developer, or a two-component developer obtained by mixing toner and a carrier is used. Then, development may be performed by a two-component development method for visualizing the electrostatic latent image. When the two-component development method is used, the same carrier as conventional ones such as iron powder, ferrite, and glass beads can be used. These carriers may be those coated with a resin, and as this resin, polyfluorinated carbon, polyvinyl chloride, polyvinylidene chloride, phenol resin, polyvinyl acetal, silicone resin and the like can be used. In any case, the mixing ratio of the toner and the carrier is generally about 0.5 to 6.0 parts by weight with respect to 100 parts by weight of the carrier.

また上記トナーには、必要に応じて、添加剤を混合させてもよい。この添加剤としては、疎水性シリカ、疎水性酸化チタン、疎水性酸化アルミニウム等の無機微粒子からなる流動性付与剤、ケーキング防止剤、四フッ化エチレン樹脂やステアリン酸亜鉛等の滑剤、カーボンブラックや酸化スズ等の導電性付与剤、酸化セリウムや炭化ケイ素等の研磨剤、低分子量ポレオレフィン等の定着助剤等を用いることができる。これらは、単独あるいは2種以上混合して使用される。これら添加剤の添加量は、トナー100重量部に対して0.1〜5重量部が望ましい。   The toner may be mixed with an additive as necessary. Examples of the additives include fluidity imparting agents composed of inorganic fine particles such as hydrophobic silica, hydrophobic titanium oxide, and hydrophobic aluminum oxide, anti-caking agents, lubricants such as ethylene tetrafluoride resin and zinc stearate, carbon black, Conductivity imparting agents such as tin oxide, abrasives such as cerium oxide and silicon carbide, fixing aids such as low molecular weight polyolefins, and the like can be used. These may be used alone or in combination of two or more. The addition amount of these additives is desirably 0.1 to 5 parts by weight with respect to 100 parts by weight of the toner.

上記トナーを製造するにあたっては、上述したような構成材料をヘンシェルミキサー等の混合機にて混合した後、連続混練機あるいはロールニーダー等の混練機にて加熱混練し、混練物を冷却固化後、粉砕分級して所望の平均粒径を得る方法が好ましい。この他の製造方法としては、噴霧乾燥法、重合法、マイクロカプセル法等がある。そして、こうして得られたトナーを、必要に応じて所望の添加剤とヘンシェルミキサー等の混合機にて十分に混合することで、トナーを製造することができる。   In producing the toner, after mixing the constituent materials as described above in a mixer such as a Henschel mixer, the mixture is heated and kneaded in a kneader such as a continuous kneader or a roll kneader, and the kneaded product is cooled and solidified. A method of obtaining a desired average particle size by pulverization and classification is preferred. As other production methods, there are a spray drying method, a polymerization method, a microcapsule method and the like. The toner thus obtained can be sufficiently mixed with a desired additive with a mixer such as a Henschel mixer, if necessary, to produce a toner.

本例のトナーは、各色共通の材料としては、バインダー樹脂としてポリエステル系樹脂を使用し、帯電制御剤としてサリチル酸亜鉛誘導体を使用する。このサリチル酸亜鉛誘導体は、ポリエステル系樹脂100重量部に対して、4重量部の比率で含有されている。その他、各色トナーには、それぞれ着色剤が含有されており、上記ポリエステル系樹脂100重量部に対して、ブラックトナーではカーボンブラックが5重量部、イエロートナーではジスアゾ系イエロー顔料(C.I.PIGMENTYELLOW17)が5重量部、シアントナーでは、銅フタロシアニンブルー顔料(C.I.PIGMENTBLUE15)が4重量部、マゼンタトナーではキナクドリン系マゼンタ顔料(C.I.PIGMENTRED184)が4重量部の比率で含有している。   The toner of this example uses a polyester resin as a binder resin and a zinc salicylate derivative as a charge control agent as a material common to each color. This zinc salicylate derivative is contained in a ratio of 4 parts by weight to 100 parts by weight of the polyester resin. In addition, each color toner contains a colorant, and for 100 parts by weight of the polyester resin, 5 parts by weight of carbon black is used for black toner, and disazo yellow pigment (CI PIGMENTYELLOW17 for yellow toner). ) Is 5 parts by weight, cyan toner contains 4 parts by weight of copper phthalocyanine blue pigment (CI PIGMENTBLUE 15), and magenta toner contains quinacdrine magenta pigment (CI PIMGENTRED 184) at a ratio of 4 parts by weight. Yes.

以下、本発明の実施例と比較例において画像形成を行った画像評価について説明する。画像評価は、転写率と転写チリ画像に絞って比較評価した。表1が比較評価した結果の主な内容である。   Hereinafter, image evaluation in which image formation was performed in Examples and Comparative Examples of the present invention will be described. The image evaluation was made by comparing the transfer rate and the transferred dust image. Table 1 shows the main contents of the comparative evaluation results.

Figure 2006259122
Figure 2006259122

実施例1、2共に、従来例より転写率が高く、且つ転写チリが非常に少なくなっている。図3〜図5は表1で比較した例の帯電量分布の推移を比較したもので、ホソカワミクロン製のE-SPARTアナライザーで測定した値を示した。図3が実施例1に相当し、図4が実施例2に相当し、図5が従来例に相当する。   In both Examples 1 and 2, the transfer rate is higher than that of the conventional example, and transfer dust is very small. FIGS. 3 to 5 show changes in the charge amount distribution of the examples compared in Table 1, and show values measured by an E-SPART analyzer manufactured by Hosokawa Micron. 3 corresponds to the first embodiment, FIG. 4 corresponds to the second embodiment, and FIG. 5 corresponds to the conventional example.

ところで、弾性層を有する中間転写ベルトにおいて、弾性層単層で構成する場合には、ベルト駆動時に伸びが発生してしまい、色ずれ等の原因となるため、伸び防止層を設けるのが好ましい。伸び防止層は中間転写ベルトに積層したり、弾性層単層中に弾性材料と混在する形態で伸び防止層と弾性層が同一となる構成とする等がよい。更に適宜硬度がより高いがより薄い表面コート層を設けて表面の経時変化を防止してもよい。   By the way, when the intermediate transfer belt having an elastic layer is formed of a single elastic layer, it is preferable that an elongation preventing layer is provided because elongation occurs when the belt is driven, causing color misregistration and the like. The elongation preventing layer may be laminated on the intermediate transfer belt, or may be configured such that the elongation preventing layer and the elastic layer are the same in a form of being mixed with an elastic material in a single elastic layer. Further, a surface coating layer having a higher hardness but a thinner surface may be provided to prevent the surface from changing with time.

上記伸び防止層としては、PI(ポリイミド)、PC(ポリカーボネート)、PET(ポリエチレンテレフタレート)等の樹脂や、繊維を用いた芯体層で構成もよい。この芯体層に用いる繊維としては、綿、絹、麻等の天然繊維、キチン繊維、アルギン酸繊維等の再生繊維、アセテート繊維等の半合成繊維、ポリエステル繊維、ナイロン繊維、アクリル繊維、ポリオレフィン繊維、ポリウレタン繊維、ポリアセタール繊維、アラミド繊維等の合成繊維、炭素繊維、ガラス繊維等の無機繊維等を用いることができる。本例では、太さ100μmのアラミド繊維を織布形状にして用いた。上記弾性層に用いる材料としては、スチレン−ブタジエンゴム、ハイスチレンゴム、ブタジエンゴム、イソプレンゴム、エチレン−プロピレン共重合体、ニトリルブタジエンゴム、クロロプレンゴム、ブチルゴム、シリコーンゴム、フッ素ゴム、ニトリルゴム、ウレタンゴム、アクリルゴム、エピクロロヒドリンゴム、ノルボルネンゴム等が挙げられる。本例では、硬度60度(JIS−A)のニトリルブタジエンゴムを用いた。なお、上記弾性層の厚みは500μmとした。上記表面コート層に用いる材料としては、スチレン−ブタジエンゴム、ハイスチレンゴム、ブタジエンゴム、イソプレンゴム、エチレン−プロピレン共重合体、ニトリルブタジエンゴム、クロロプレンゴム、ブチルゴム、シリコーンゴム、フッ素ゴム、ニトリルゴム、ウレタンゴム、アクリルゴム、エピクロロヒドリンゴム、ノルボルネンゴムおよび熱可塑性エラストマー等が挙げられる。本例では、ポリウレタンにフッ素樹脂を配合したものを塗工したものを用いた。なお、塗工厚みは数μmから数十μm(好ましくは1〜10μm)であった。   The elongation preventing layer may be constituted by a core body layer using a resin such as PI (polyimide), PC (polycarbonate), PET (polyethylene terephthalate), or fibers. As fibers used for the core layer, natural fibers such as cotton, silk and hemp, recycled fibers such as chitin fibers and alginic acid fibers, semi-synthetic fibers such as acetate fibers, polyester fibers, nylon fibers, acrylic fibers, polyolefin fibers, Synthetic fibers such as polyurethane fibers, polyacetal fibers and aramid fibers, inorganic fibers such as carbon fibers and glass fibers, and the like can be used. In this example, an aramid fiber having a thickness of 100 μm was used in the form of a woven fabric. Materials used for the elastic layer include styrene-butadiene rubber, high styrene rubber, butadiene rubber, isoprene rubber, ethylene-propylene copolymer, nitrile butadiene rubber, chloroprene rubber, butyl rubber, silicone rubber, fluorine rubber, nitrile rubber, urethane. Examples thereof include rubber, acrylic rubber, epichlorohydrin rubber and norbornene rubber. In this example, a nitrile butadiene rubber having a hardness of 60 degrees (JIS-A) was used. The thickness of the elastic layer was 500 μm. As the material used for the surface coat layer, styrene-butadiene rubber, high styrene rubber, butadiene rubber, isoprene rubber, ethylene-propylene copolymer, nitrile butadiene rubber, chloroprene rubber, butyl rubber, silicone rubber, fluorine rubber, nitrile rubber, Examples thereof include urethane rubber, acrylic rubber, epichlorohydrin rubber, norbornene rubber, and thermoplastic elastomer. In this example, polyurethane coated with a fluororesin was used. The coating thickness was several μm to several tens of μm (preferably 1 to 10 μm).

尚、上記の実施の形態は、本発明の理解を容易にするために記載したものであって、本発明を限定するものではない。例えば、本実施の形態では、像担持体として感光体ドラムを用いて説明したが、本発明はこれに限定されるものではなく、感光体ベルト等、全ての像担持体に適用可能である。また、図1の態様では、感光体ドラムは1本の形態であるが、黒、イエロー、シアン、マゼンタ色別に専用の感光体ドラムを用いる所謂4連タンデム型のフルカラー画像形成システム形態でも適用可能である。また、本実施の形態では、一次転写手段として転写ローラを用いたが、回転型転写ブラシ等の回転型接触転写方式はもちろんのこと、転写ブラシ、転写ブレード、転写プレート等の接触転写方式を用いた画像形成装置であれば本発明を適用可能である。   In addition, said embodiment was described in order to make an understanding of this invention easy, Comprising: This invention is not limited. For example, in the present embodiment, the photosensitive drum is used as the image carrier. However, the present invention is not limited to this and can be applied to all image carriers such as a photosensitive belt. In the embodiment of FIG. 1, the photosensitive drum is in a single form, but it can also be applied to a so-called quadruple tandem full-color image forming system form using dedicated photosensitive drums for black, yellow, cyan, and magenta colors. It is. In this embodiment, the transfer roller is used as the primary transfer unit. However, a contact transfer system such as a transfer brush, a transfer blade, and a transfer plate is used as well as a rotary contact transfer system such as a rotary transfer brush. The present invention can be applied to any image forming apparatus.

本発明に係る画像形成装置の概略構成図である。1 is a schematic configuration diagram of an image forming apparatus according to the present invention. 本発明に係る別の画像形成装置の概略構成図である。It is a schematic block diagram of another image forming apparatus which concerns on this invention. 画像評価を行った際の帯電量分布の推移での実施例1における結果を示すグラフである。It is a graph which shows the result in Example 1 in transition of charge amount distribution at the time of image evaluation. 画像評価を行った際の帯電量分布の推移での実施例2における結果を示すグラフである。It is a graph which shows the result in Example 2 in transition of the charge amount distribution at the time of image evaluation. 画像評価を行った際の帯電量分布の推移での従来例における結果を示すグラフである。It is a graph which shows the result in a prior art example in transition of charge amount distribution at the time of image evaluation.

符号の説明Explanation of symbols

1 感光体
2 クリーニングユニット
4 帯電器
5 露光ユニット
6,7,8,9 現像手段
10 中間転写ベルト
11 一次転写バイアスローラ
12 従動ローラ
13 駆動ローラ
14 二次転写バイアスローラ
15 二次転写ユニット
16 接離機構
17 定着手段
18 クリーニングブレード
19 ベルトクリーニングユニット
21 レジストローラ
22 転写紙
23 ベルト位置検出マーク
24 マークセンサ
25 給紙ローラ
26 接離機構
30 圧接バネ
DESCRIPTION OF SYMBOLS 1 Photoconductor 2 Cleaning unit 4 Charger 5 Exposure unit 6, 7, 8, 9 Developing means 10 Intermediate transfer belt 11 Primary transfer bias roller 12 Driven roller 13 Drive roller 14 Secondary transfer bias roller 15 Secondary transfer unit 16 Contact / separation Mechanism 17 Fixing means 18 Cleaning blade 19 Belt cleaning unit 21 Registration roller 22 Transfer paper 23 Belt position detection mark 24 Mark sensor 25 Paper feed roller 26 Contact / separation mechanism 30 Pressure contact spring

Claims (8)

像担持体と、現像剤担持体と、像担持体上に形成されたトナー像を転写材に電界転写する手段とを備えた画像形成装置において、
上記現像剤担持体の表面と上記像担持体の表面との電位差が0Vであるときの、現像剤担持体と像担持体との対向領域を通過する直前の現像剤中トナーの平均帯電量をQ1、像担持体から次の転写材の表面に電界転写した直後の転写材表面トナー像の平均帯電量をQ2とした場合に、
{│Q2│−│Q1│}/│Q1│≧−0.3
の関係を満足する条件下で現像することを特徴とする画像形成装置。
In an image forming apparatus comprising an image carrier, a developer carrier, and means for transferring an electric field of a toner image formed on the image carrier to a transfer material,
When the potential difference between the surface of the developer carrier and the surface of the image carrier is 0 V, the average charge amount of the toner in the developer immediately before passing through the opposing region between the developer carrier and the image carrier Q1, when the average charge amount of the transfer material surface toner image immediately after the electric field transfer from the image carrier to the surface of the next transfer material is Q2,
{│Q2│-│Q1│} /│Q1│≧-0.3
The image forming apparatus is developed under a condition that satisfies the above relationship.
像担持体と、現像剤担持体と、像担持体上に形成されたトナー像を転写材に電界転写する手段とを備えた画像形成装置において、
上記現像剤担持体の表面と上記像担持体の表面との電位差が0Vであるときの、現像剤担持体と像担持体との対向領域を通過する直前の現像剤中トナーの平均帯電量をQ1、像担持体から次の転写材の表面に電界転写する直前の像担持体表面トナー像の平均帯電量をQ3とした場合に、
{│Q3│−│Q1│}/│Q1│≧−0.3
の関係を満足する条件下で現像することを特徴とする画像形成装置。
In an image forming apparatus comprising an image carrier, a developer carrier, and means for transferring an electric field of a toner image formed on the image carrier to a transfer material,
When the potential difference between the surface of the developer carrier and the surface of the image carrier is 0 V, the average charge amount of the toner in the developer immediately before passing through the opposing region between the developer carrier and the image carrier Q1, when the average charge amount of the image carrier surface toner image immediately before the electric field transfer from the image carrier to the surface of the next transfer material is Q3,
{│Q3│-│Q1│} /│Q1│≧-0.3
The image forming apparatus is developed under a condition that satisfies the above relationship.
像担持体と、現像剤担持体と、像担持体上に形成されたトナー像を転写材に電界転写する手段とを備えた画像形成装置において、
上記現像剤担持体の表面と上記像担持体の表面との電位差が0Vであるときの、現像剤担持体と像担持体との対向領域を通過する直前の現像剤中トナーの平均帯電量をQ1、現像剤担持体に現像バイアスが印加され、像担持体表面の電位が画像部電位であるときの、現像剤担持体と像担持体との対向領域を通過した直後の像担持体表面の画像部に現像されたトナーの平均帯電量をQ4とした場合に、
{│Q4│−│Q1│}/│Q1│≧−0.3
の関係を満足する条件下で現像することを特徴とする画像形成装置。
In an image forming apparatus comprising an image carrier, a developer carrier, and means for transferring an electric field of a toner image formed on the image carrier to a transfer material,
When the potential difference between the surface of the developer carrier and the surface of the image carrier is 0 V, the average charge amount of the toner in the developer immediately before passing through the opposing region between the developer carrier and the image carrier Q1, when a developing bias is applied to the developer carrying member and the potential on the surface of the image carrying member is the image portion potential, the surface of the image carrying member immediately after passing through the opposing region between the developer carrying member and the image carrying member. When the average charge amount of the toner developed on the image portion is Q4,
{│Q4│-│Q1│} /│Q1│≧-0.3
The image forming apparatus is developed under a condition that satisfies the above relationship.
現像工程と転写工程の間に、像担持体表面トナー像に該トナーの正規極性と同極性の電荷を付与する手段を設けたことを特徴とする請求項1に記載の画像形成装置。   2. The image forming apparatus according to claim 1, wherein means for applying a charge having the same polarity as the normal polarity of the toner is provided to the toner image on the surface of the image carrier between the development step and the transfer step. 像担持体表面の現像前地肌部電位をVD、画像部電位をVL、現像バイアス電圧をVBとすると0<|VD|−|VB|<|VD−VL|<400Vを満たす直流現像電界条件で現像することを特徴とする請求項1に記載の画像形成装置。   Under the condition of a DC developing electric field satisfying 0 <| VD | − | VB | <| VD−VL | <400 V, where VD is the background potential before development on the surface of the image bearing member, VL is the image portion potential, and VB is the developing bias voltage. The image forming apparatus according to claim 1, wherein development is performed. トナーの比誘電率を2.5〜4、体積固有抵抗を1010〜1015Ω・cmとしたことを特徴とする請求項1に記載の画像形成装置。 The image forming apparatus according to claim 1, wherein the toner has a relative dielectric constant of 2.5 to 4 and a volume resistivity of 10 10 to 10 15 Ω · cm. 現像バイアスとして像担持体の画像部表面電位より高めと低めのレベルを現像領域内で少なくとも1周期以上繰り返す態様の交番電圧を用いることを特徴とする請求項6に記載の画像形成装置。   7. The image forming apparatus according to claim 6, wherein an alternating voltage having a mode in which a level higher and lower than the image portion surface potential of the image carrier is repeated at least one period in the developing region is used as the developing bias. トナーをクリーニング回収する専用のクリーニング手段を備えないことを特徴とする請求項1に記載の画像形成装置。   The image forming apparatus according to claim 1, wherein a dedicated cleaning unit that cleans and collects toner is not provided.
JP2005075252A 2005-03-16 2005-03-16 Image forming apparatus Pending JP2006259122A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2005075252A JP2006259122A (en) 2005-03-16 2005-03-16 Image forming apparatus

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2005075252A JP2006259122A (en) 2005-03-16 2005-03-16 Image forming apparatus

Publications (1)

Publication Number Publication Date
JP2006259122A true JP2006259122A (en) 2006-09-28

Family

ID=37098481

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2005075252A Pending JP2006259122A (en) 2005-03-16 2005-03-16 Image forming apparatus

Country Status (1)

Country Link
JP (1) JP2006259122A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010055019A (en) * 2008-08-29 2010-03-11 Sanyo Chem Ind Ltd Toner composition
JP2010217642A (en) * 2009-03-18 2010-09-30 Ricoh Co Ltd Electrophotographic toner, method of manufacturing the same and process cartridge
JP2015184595A (en) * 2014-03-25 2015-10-22 富士ゼロックス株式会社 Photoluminescent toner, electrostatic charge image developer, developer cartridge, process cartridge, image forming apparatus, and image forming method
JP2017219756A (en) * 2016-06-09 2017-12-14 株式会社リコー Image forming apparatus

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11190926A (en) * 1997-12-26 1999-07-13 Canon Inc Image forming device
JP2003084504A (en) * 2001-07-06 2003-03-19 Ricoh Co Ltd Method and device for developing, image forming apparatus and process cartridge
JP2003316133A (en) * 2002-04-22 2003-11-06 Canon Inc Image forming method and image forming device
JP2004069860A (en) * 2002-08-02 2004-03-04 Canon Inc Image forming apparatus

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11190926A (en) * 1997-12-26 1999-07-13 Canon Inc Image forming device
JP2003084504A (en) * 2001-07-06 2003-03-19 Ricoh Co Ltd Method and device for developing, image forming apparatus and process cartridge
JP2003316133A (en) * 2002-04-22 2003-11-06 Canon Inc Image forming method and image forming device
JP2004069860A (en) * 2002-08-02 2004-03-04 Canon Inc Image forming apparatus

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010055019A (en) * 2008-08-29 2010-03-11 Sanyo Chem Ind Ltd Toner composition
JP2010217642A (en) * 2009-03-18 2010-09-30 Ricoh Co Ltd Electrophotographic toner, method of manufacturing the same and process cartridge
JP2015184595A (en) * 2014-03-25 2015-10-22 富士ゼロックス株式会社 Photoluminescent toner, electrostatic charge image developer, developer cartridge, process cartridge, image forming apparatus, and image forming method
JP2017219756A (en) * 2016-06-09 2017-12-14 株式会社リコー Image forming apparatus

Similar Documents

Publication Publication Date Title
JP2006313307A (en) Image forming apparatus
JP2003280331A (en) Image forming apparatus
JP2006259122A (en) Image forming apparatus
JP2007127889A (en) Image forming apparatus
JP4627251B2 (en) Image forming apparatus
JP2001235946A (en) Image forming device
JP5090627B2 (en) Image forming apparatus
JP4671392B2 (en) Full-color image forming method, full-color image forming apparatus, and full-color toner
JP2008122619A (en) Image forming apparatus
US20100074659A1 (en) Image forming method and apparatus
JP2004302250A (en) Image forming apparatus
JP2003131444A (en) Image forming apparatus
US7362990B2 (en) Image forming apparatus
JP2002055516A (en) Image forming device
US20060159493A1 (en) Image forming apparatus
JP2006251753A (en) Multi-color image forming apparatus
US7486901B2 (en) Image forming apparatus and image forming method
JP2005181800A (en) Color image forming apparatus and method for forming color image
JP3652425B2 (en) Toner manufacturing method and electrophotographic apparatus
JPH08211741A (en) Image forming device and process cartridge
JP2006072389A (en) Image forming apparatus
JPH09134074A (en) Method and device for forming image and process cartridge
JP4032643B2 (en) Image forming apparatus
JP2006071846A (en) Development processing device
JPH09325515A (en) Developing device

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20070619

A977 Report on retrieval

Effective date: 20091202

Free format text: JAPANESE INTERMEDIATE CODE: A971007

A131 Notification of reasons for refusal

Effective date: 20091215

Free format text: JAPANESE INTERMEDIATE CODE: A131

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20100406