JP2006249179A - Liquid crystal composition and liquid crystal display element - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a liquid crystal composition which has a low viscosity and high reliability, when a threshold voltage is constant. <P>SOLUTION: This nematic liquid crystal composition comprises 15 to 35 mass% of a compound of formula (I) and 25 to 50 mass% of a compound of formula (II). <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

  The present invention relates to a nematic liquid crystal composition useful as an electro-optical liquid crystal display material and a liquid crystal display element using the same.

  Since the advent of LCDs as calculator displays, LCDs have been developed and used in the same way as computers to support the expansion of display capacity from TN-LCDs (twisted nematic liquid crystal displays) to STN-LCDs. I have done it. STN-LCD was developed by Scheffer et al [SID '85 Digest, 120 Mitsugu (1985)] or Kinukawa et al [SID '86 Digest, 122 Mitsumi (1986)]. Widespread use in information processing displays.

  In recent years, as a required characteristic in a liquid crystal display device, in particular, an STN-LCD, a high response speed and high reliability are demanded at the same threshold voltage. In order to increase the response speed of the liquid crystal display device, a low-viscosity liquid crystal composition is required. For the purpose of reducing the viscosity while maintaining the threshold voltage, a compound having a high dielectric constant is used. The proportion of small compounds must be increased. However, a compound having a large dielectric constant is generally unreliable, and an increase in current value often occurs in a long-time heating test, so that there is a limit to the use of a compound having a large dielectric constant. Therefore, development of a liquid crystal composition having low viscosity and high reliability while maintaining the threshold voltage has been demanded.

  On the other hand, a compound having a cyanobenzene skeleton, which is an essential component of the present invention, is already known, and there is a description that the current value can be improved (see Patent Document 1). However, it is suggested that the liquid crystal composition described in the cited document widely uses a compound having a monofluorocyanobenzene skeleton and further having an ester bond. Therefore, in current liquid crystal compositions that require higher reliability, the increase in current value during heating cannot be said to be sufficiently low, and the development of more reliable liquid crystal compositions has been demanded.

JP 2002-173680 A (pages 18, 19)

  An object of the present invention is to provide a liquid crystal composition having low viscosity and high reliability when the threshold voltage is constant.

  The inventors of the present invention have conducted extensive studies to solve the above problems, and as a result, by using a specific liquid crystal compound as a constituent member, it is possible to ensure low viscosity and high reliability when the threshold voltage is constant. The headline has been completed. The present invention relates to the general formula (I)

(式中、R¹は炭素原子数1〜16のアルキル基、炭素原子数1〜16のアルコキシル基、炭素原子数2〜16のアルケニル基又は炭素原子数3〜16のアルケニルオキシ基を表す。)で表される化合物を1種又は2種以上含有し該化合物の含有率が15〜35質量％の範囲であり、一般式(II)

(Wherein R ¹ represents an alkyl group having ^{1 to} 16 carbon atoms, an alkoxyl group having 1 to 16 carbon atoms, an alkenyl group having 2 to 16 carbon atoms, or an alkenyloxy group having 3 to 16 carbon atoms). 1 or 2 or more compounds, and the content of the compound is in the range of 15 to 35% by mass, and the general formula (II)

(In the formula, R ² represents an alkyl group having 1 to 16 carbon atoms, an alkoxyl group having 1 to 16 carbon atoms, an alkenyl group having 2 to 16 carbon atoms, or an alkenyloxy group having 3 to 16 carbon atoms, A and B are each independently 1,4-phenylene group, 3-fluoro-1,4-phenylene, 2,3-difluoro-1,4-phenylene, 3,5-difluoro-1,4-phenylene, Represents a trans-1,4-cyclohexylene group, a pyridine-2,5-diyl group or a pyrimidine-2,5-diyl group, l represents 0, 1 or 2, and X ¹ represents a hydrogen atom or a fluorine atom. 1) or two or more compounds represented by formula (III), wherein the content of the compound is in the range of 25 to 50% by mass, and the general formula (III)

(In the formula, R ³ represents an alkyl group having 1 to 16 carbon atoms, an alkoxyl group having 1 to 16 carbon atoms, an alkenyl group having 2 to 16 carbon atoms, or an alkenyloxy group having 3 to 16 carbon atoms, C ¹ , C ² and C ³ are each independently 1,4-phenylene group, 2-methyl-1,4-phenylene, 3-fluoro-1,4-phenylene, 3,5-difluoro-1,4 Represents a -phenylene or pyrimidine-1,4-diyl group, and K ² and K ³ are each independently a single bond, —CH ₂ CH ₂ —, — (CH ₂ ) ₄ —, —OCH ₂ —, —CH _2. O—, —COO—, —OCO— or —C≡C—, wherein R ⁸ is an alkyl group having 1 to 16 carbon atoms, an alkoxyl group having 1 to 16 carbon atoms, or an alkenyl having 2 to 16 carbon atoms. A group or an alkenyloxy group having 3 to 16 carbon atoms, p represents 0, 1 or 2), and the content is 35 to 60% by mass. Nematic characterized by being It provides crystal composition, a liquid crystal display element as a constituent member of the liquid crystal composition together.

  The liquid crystal composition of the present invention has low viscosity and high reliability when the threshold voltage is constant. Therefore, the present invention has an excellent effect in reducing the viscosity and increasing the reliability in a twisted nematic (TN) or super twisted nematic (STN) liquid crystal display element comprising the liquid crystal composition as a constituent member. The liquid crystal composition of the present invention is useful as a twisted nematic (TN) or super twisted nematic (STN) liquid crystal display element.

  Although the liquid-crystal composition of this invention contains 15-35 mass% of compounds represented by general formula (I), it is preferable to contain 15-30 mass%, and it is more preferable to contain 15-25 mass%.

In the general formula (I), R ¹ is an alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms, or an alkenyloxy group having 2 to 10 carbon atoms. Are more preferable, an alkyl group having 1 to 8 carbon atoms, an alkoxy group having 1 to 8 carbon atoms, an alkenyl group having 2 to 8 carbon atoms, or an alkenyloxy group having 2 to 8 carbon atoms is more preferable. An alkyl group having 1 to 5 carbon atoms, an alkoxy group having 1 to 5 carbon atoms, an alkenyl group having 2 to 5 carbon atoms, or an alkenyloxy group having 2 to 5 carbon atoms is particularly preferable.

Although the liquid-crystal composition of this invention contains 25-50 mass% of compounds represented by general formula (II), it is preferable to contain 25-45 mass%.
In the general formula (II), R ² is an alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms, or an alkenyl having 2 to 10 carbon atoms. An oxy group is preferable, an alkyl group having 1 to 8 carbon atoms, an alkoxy group having 1 to 8 carbon atoms, an alkenyl group having 2 to 8 carbon atoms, or an alkenyloxy group is more preferable, and an alkyl having 1 to 5 carbon atoms. A group, an alkoxy group having 1 to 5 carbon atoms, an alkenyl group having 2 to 5 carbon atoms or an alkenyloxy group having 2 to 5 carbon atoms is particularly preferable.
Specifically, the compound represented by the general formula (II) is represented by the following general formula (II-a) to general formula (II-h).

(Wherein R ⁶ represents an alkyl group having 1 to 16 carbon atoms, an alkoxyl group having 1 to 16 carbon atoms, an alkenyl group having 2 to 16 carbon atoms, or an alkenyloxy group having 3 to 16 carbon atoms). And a compound selected from the group of compounds represented by formula (II-a), formula (II-b), formula (II-c) or formula (II-f) Is more preferable.

Although the liquid-crystal composition of this invention contains 35-60 mass% of compounds represented by general formula (III), it is more preferable to contain 35-55 mass%.
In the general formula (III), R ² is an alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms, or an alkenyloxy group having 2 to 10 carbon atoms. Are more preferable, an alkyl group having 1 to 8 carbon atoms, an alkoxy group having 1 to 8 carbon atoms, an alkenyl group having 2 to 8 carbon atoms, or an alkenyloxy group having 2 to 8 carbon atoms is more preferable. An alkyl group having 1 to 5 carbon atoms, an alkoxy group having 1 to 5 carbon atoms, an alkenyl group having 2 to 5 carbon atoms, or an alkenyloxy group having 2 to 5 carbon atoms is particularly preferable.
The compounds represented by the general formula (III) are specifically the following general formulas (III-a) to (III-u)

Wherein R ⁴ and R ⁵ are each independently an alkyl group having 1 to 16 carbon atoms, an alkoxyl group having 1 to 16 carbon atoms, an alkenyl group having 2 to 16 carbon atoms, or 3 to 16 carbon atoms. And a compound selected from the group of compounds represented by formula (III-a), formula (III-c), formula (III-d), formula (III- g), a compound represented by formula (III-h), formula (III-j), formula (III-l), formula (III-q) or formula (III-u) is more preferred. .

  As mentioned above, 1 type or 2 types or more of compounds represented by general formula (I) are contained, the content rate of this compound is the range of 15-35 mass%, general formula (II-a)-general formula ( II-h) containing from 1 to 8 compounds selected from the group consisting of compounds having a content of 25 to 50% by mass, represented by the general formula (III-a) to general formula (III-u) A liquid crystal composition containing 1 to 30 compounds selected from the group consisting of) is in the range of 35 to 60% by mass.

  In the liquid crystal composition of the present invention, when the reliability is particularly important, the general formula (IV)

(Wherein R ⁴ represents an alkyl group having 1 to 16 carbon atoms, an alkoxyl group having 1 to 16 carbon atoms, an alkenyl group having 2 to 16 carbon atoms, or an alkenyloxy group having 3 to 16 carbon atoms, D and E are each independently 1,4-phenylene group, 3-fluoro-1,4-phenylene, 2,3-difluoro-1,4-phenylene, 3,5-difluoro-1,4-phenylene or A trans-1,4-cyclohexylene group, m represents 0, 1 or 2, K ¹ represents a single bond or —CH ₂ CH ₂ —, and X ⁶ represents a hydrogen atom or a fluorine atom. It is preferable to further contain the represented compound.

In the case of containing the general formula (IV), the content is preferably 5 to 20% by mass, and more preferably 5 to 10% by mass.
In the general formula (IV), R ⁴ is preferably an alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms, or an alkenyloxy group having 2 to 10 carbon atoms, An alkyl group having 1 to 8 carbon atoms, an alkoxy group having 1 to 8 carbon atoms, an alkenyl group having 2 to 8 carbon atoms, or an alkenyloxy group having 2 to 8 carbon atoms is more preferable, and 1 to 5 carbon atoms. Are particularly preferred, an alkoxy group having 1 to 5 carbon atoms, an alkenyl group having 2 to 5 carbon atoms, or an alkenyloxy group having 2 to 5 carbon atoms.
Specific examples of the compound represented by the general formula (IV) include the following general formula (IV-a) to general formula (IV-d):

Wherein R ⁷ represents an alkyl group having 1 to 16 carbon atoms, an alkoxyl group having 1 to 16 carbon atoms, an alkenyl group having 2 to 16 carbon atoms, or an alkenyloxy group having 3 to 16 carbon atoms. A compound selected from the group of compounds represented by formula (IV) is preferred, and a compound represented by formula (IV-a), formula (IV-c) or formula (IV-d) is more preferred.

  From the above, when reliability is particularly emphasized, the compound represented by the general formula (I) is contained in one or more kinds, the content of the compound is in the range of 15 to 35% by mass, 1 to 8 compounds selected from the group consisting of the formula (II-a) to the general formula (II-h) are contained, the content of the compound is in the range of 25 to 45% by mass, and the general formula (III -a) to 1 to 30 compounds selected from the group consisting of the general formula (III-u), the content of the compound is in the range of 35 to 55% by mass, and the general formula (IV-a) It is preferable that 1 to 8 compounds selected from the group consisting of the general formula (IV-d) are contained, and the content of the compound-containing compound is 5 to 20% by mass.

  Furthermore, 1 type or 2 types or more of compounds represented by general formula (I) are contained, the content rate of this compound is the range of 15-35 mass%, general formula (II-a), general formula (II -b), containing 1 to 30 compounds selected from the group consisting of compounds represented by general formula (II-c) and general formula (II-f), the content of the compound being 25 to 45 mass % Of the general formula (III-a), general formula (III-c), general formula (III-d), general formula (III-g), general formula (III-h), general formula (III -j), general formula (III-l), general formula (III-m), general formula (III-n), general formula (III-o), general formula (III-p), general formula (III-q ) And a compound represented by the general formula (III-u), and the content of the compound is in the range of 35 to 55% by mass selected from the group consisting of the compounds represented by the general formula (IV). -a), 1 to 8 selected from the group consisting of compounds represented by general formula (IV-c) and general formula (IV-d) It is more preferable content of the compound containing compound is is 5-20 wt%.

  The liquid crystal composition of the present invention may contain a normal nematic liquid crystal, a smectic liquid crystal, a cholesteric liquid crystal, a dichroic dye, and the like in addition to the above compounds. Further, a chiral agent may be added to prevent the reverse twist domain of TN-LCD or to induce the helical structure of STN-LCD. As the chiral agent, commercially available products can be used. Examples thereof include cholesteryl nonanoate (CN), S-811, R-811, CB-15, and C-15 manufactured by Merck. It is known that the induced helical pitch becomes longer and shorter as the temperature rises, but one of these may be used alone or in combination of two or more, or both may be used in combination of one or more. good. For example, in TN-LCD, STN-LCD, and TFT-LCD, the quotient d / p between the thickness d between the substrates and the induced spiral pitch p can be selected from the range of 0.001 to 24, but the range of 0.01 to 12 The range of 0.1 to 2 is more preferable, the range of 0.1 to 1.5 is more preferable, the range of 0.1 to 1 is still more preferable, and the range of 0.1 to 0.8 is particularly preferable.

The liquid crystal composition of the present invention has a viscosity η of preferably 25.0 mPs · s or less and more preferably 23.0 mPs · s or less when the threshold voltage Vth when the display element is configured is about 1.4V. The rate of increase I ₁₄₄₀ / I ₀ is preferably 100.0 or less, and more preferably 80.0 or less.

When the threshold voltage Vth is about 1.3 V, the viscosity η is preferably 34.0 mPs · s or less, and more preferably 28.0 mPs · s or less. The rate of increase I ₁₄₄₀ / I ₀ is preferably 130.0 or less, and more preferably 95.0 or less.

When the threshold voltage Vth is about 1.2 V, the viscosity η is preferably 40.0 mPs · s or less, and more preferably 37.0 mPs · s or less. The increase rate I ₁₄₄₀ / I ₀ of the current value is preferably 85.0 or less, and more preferably 15.0 or less.

  The nematic liquid crystal composition is useful for TN-LCD, STN-LCD, OCB-LCD, polymer dispersion type liquid crystal display element, phase change type cholesteric liquid crystal display element, but is particularly useful for TN-LCD and STN-LCD. is there. Further, it can be used for a transmissive or reflective liquid crystal display element.

  In the TN liquid crystal display element of the present invention, the twist angle can be selected in the range of 80 ° to 130 °, preferably 85 ° to 110 °, depending on the purpose. Further, the STN liquid crystal display element of the present invention can select a twist angle in the range of 180 ° to 270 ° according to the purpose, and is preferably 220 ° to 260 °.

EXAMPLES Hereinafter, although an Example and a comparative example are given and this invention is further explained in full detail, this invention is not limited to these Examples. Further, “%” in the compositions of the following examples and comparative examples means “mass%”.
In the examples, the measured characteristics are as follows.
T _NI : Nematic phase-isotropic liquid phase transition temperature (° C)
Δn: birefringence (20 ° C. and 589 nm)
Vth: threshold voltage (V) (25 ° C)
I ₀ : Use a TN panel with an electrode area of 0.64 cm ² and a cell thickness of 8.3 μm
Current value after standing for 0 hours at 80 ℃ (μA / cm ² )
I ₁₄₄₀ : TN panel with electrode area of 0.64cm ² and cell thickness of 8.3μm is used.
Current value after leaving for 1440 hours at 80 ℃ (μA / cm ² )
I ₁₄₄₀ / I ₀ : Rate of increase in current value The following abbreviations are used in the description of the compound.
-Terminal n (number): -C _n H _{2n + 1} ndm-: C _n H _{2n + 1} -CH = CH- (CH ₂ ) _m-1-
-T-: -C≡C- -ndm:-(C _n H _{2n + 1} -CH = CH- (CH ₂ ) _m-1 )
-F: -F -On: -OC _n H _{2n + 1}
-VO-: -COO- -CN: -C≡N
-Z-: -CH = NN = CH- -CF ₂ O-: -CF ₂ -O-

例えば、以下に示すように略号を用いる。

For example, abbreviations are used as shown below.

(Example 1 and Comparative Examples 1 and 2)
Liquid crystal composition No. 1 (Example 1), liquid crystal composition M1 (Comparative Example 1), and liquid crystal composition M2 (Comparative Example 2) were prepared and their physical properties are shown in Table 1.
The value and rate of increase of I ₁₄₄₀ / I ₀ compared this time vary depending on the alignment film, the sealing agent, etc. that are in contact with the liquid crystal. Therefore, in order to compare the physical property values, it is necessary to perform the relative comparison by aligning the physical property values such as Tni, Δn, Vth, etc. almost equally by using the same panels for the examples and comparative examples. .
In Example 1, Comparative Example 1 and Comparative Example 2, the threshold voltages are set to around 1.4 V, and the physical property values such as Tni and Δn are set to be approximately equal for fair comparison.

As shown in Table 1, the liquid crystal composition of Example 1 significantly suppressed the rate of increase I ₁₄₄₀ / I ₀ of the current value compared to Comparative Example 1. Further, the viscosity η is greatly reduced as compared with Comparative Example 2. Therefore, it is clear that the liquid crystal composition of the present invention has a small viscosity η and a small increase rate I ₁₄₄₀ / I _{0 of} the current value.

(Example 2 and Comparative Examples 3 to 4)
A liquid crystal composition No. 2 (Example 2), a liquid crystal composition M3 (Comparative Example 3), and a liquid crystal composition M4 (Comparative Example 4) were prepared.
In Example 2, Comparative Example 3 and Comparative Example 4, the threshold voltages are set to around 1.3 V, and the physical property values such as Tni and Δn are set to be approximately equal for fair comparison.

As shown in Table 2, the liquid crystal composition of Example 2 significantly suppresses the increase rate I ₁₄₄₀ / I ₀ of the current value as compared with Comparative Example 3. In addition, the viscosity η is greatly reduced as compared with Comparative Example 4. Therefore, it is clear that the liquid crystal composition of Example 2 also has a small viscosity η and a small current value increase rate I ₁₄₄₀ / I ₀ .

(Example 3 and Comparative Examples 5 to 6)
Liquid crystal composition No. 3 (Example 3), liquid crystal composition M5 (Comparative Example 5), and liquid crystal composition M6 (Comparative Example 6) were prepared, and their physical properties are shown in Table 3.
In Example 3, Comparative Example 5 and Comparative Example 6, the threshold voltages are set to around 1.2 V, and the physical property values such as Tni and Δn are set to be approximately equal for fair comparison.

As shown in Table 3, the liquid crystal composition of Example 3 significantly suppresses the increase in current value I ₁₄₄₀ / I ₀ as compared with Comparative Example 5. In addition, the viscosity η is significantly reduced as compared with Comparative Example 6. Therefore, it is clear that the liquid crystal composition of Example 3 also has a small viscosity η and a small increase rate I ₁₄₄₀ / I _{0 of} the current value.

Claims (10)

Formula (I)

(Wherein R ¹ represents an alkyl group having ^{1 to} 16 carbon atoms, an alkoxyl group having 1 to 16 carbon atoms, an alkenyl group having 2 to 16 carbon atoms, or an alkenyloxy group having 3 to 16 carbon atoms). 1 or 2 or more compounds, and the content of the compound is in the range of 15 to 35% by mass, and the general formula (II)

(In the formula, R ² represents an alkyl group having 1 to 16 carbon atoms, an alkoxyl group having 1 to 16 carbon atoms, an alkenyl group having 2 to 16 carbon atoms, or an alkenyloxy group having 3 to 16 carbon atoms, A and B are each independently 1,4-phenylene group, 3-fluoro-1,4-phenylene, 2,3-difluoro-1,4-phenylene, 3,5-difluoro-1,4-phenylene, Represents a trans-1,4-cyclohexylene group, a pyridine-2,5-diyl group or a pyrimidine-2,5-diyl group, l represents 0, 1 or 2, and X ¹ represents a hydrogen atom or a fluorine atom. 1) or two or more compounds represented by formula (III), wherein the content of the compound is in the range of 25 to 50% by mass, and the general formula (III)

(In the formula, R ³ represents an alkyl group having 1 to 16 carbon atoms, an alkoxyl group having 1 to 16 carbon atoms, an alkenyl group having 2 to 16 carbon atoms, or an alkenyloxy group having 3 to 16 carbon atoms, C ¹ , C ² and C ³ are each independently 1,4-phenylene group, 2-methyl-1,4-phenylene, 3-fluoro-1,4-phenylene, 3,5-difluoro-1,4 Represents a -phenylene or pyrimidine-1,4-diyl group, and K ² and K ³ are each independently a single bond, —CH ₂ CH ₂ —, — (CH ₂ ) ₄ —, —OCH ₂ —, —CH _2. O—, —COO—, —OCO— or —C≡C—, wherein R ⁸ is an alkyl group having 1 to 16 carbon atoms, an alkoxyl group having 1 to 16 carbon atoms, or an alkenyl having 2 to 16 carbon atoms A group or an alkenyloxy group having 3 to 16 carbon atoms, p represents 0, 1 or 2), and the content is 35 to 60% by mass. Nematic characterized by being Crystal composition. Formula (IV)

(Wherein R ⁴ represents an alkyl group having 1 to 16 carbon atoms, an alkoxyl group having 1 to 16 carbon atoms, an alkenyl group having 2 to 16 carbon atoms, or an alkenyloxy group having 3 to 16 carbon atoms, D and E are each independently 1,4-phenylene group, 3-fluoro-1,4-phenylene, 2,3-difluoro-1,4-phenylene, 3,5-difluoro-1,4-phenylene or Represents a trans-1,4-cyclohexylene group, m represents 0, 1 or 2, K ¹ represents a single bond or —CH ₂ CH ₂ —, and X ⁶ represents a hydrogen atom or a fluorine atom. 1 type or 2 or more types of the compound represented, The content rate of this compound is 5-20 mass%, This content rate of the compound represented by general formula (II) is 25-45 mass%, 2. The liquid crystal composition according to claim 1, wherein the content of the compound represented by the general formula (III) is 35 to 55% by mass. As a compound of general formula (II), the following general formula (II-a) to general formula (II-h)

(Wherein R ⁶ represents an alkyl group having 1 to 16 carbon atoms, an alkoxyl group having 1 to 16 carbon atoms, an alkenyl group having 2 to 16 carbon atoms, or an alkenyloxy group having 3 to 16 carbon atoms). 3. The liquid crystal composition according to claim 1 or 2, comprising one or more compounds selected from the group consisting of compounds represented by: As a compound of general formula (III), the following general formula (III-a) to general formula (III-u)

Wherein R ⁴ and R ⁵ are each independently an alkyl group having 1 to 16 carbon atoms, an alkoxyl group having 1 to 16 carbon atoms, an alkenyl group having 2 to 16 carbon atoms, or 3 to 16 carbon atoms. 4. The liquid crystal composition according to claim 1, 2 or 3, comprising one or more compounds selected from the group consisting of compounds represented by: 1 to 8 compounds selected from the group consisting of general formula (II-a) to general formula (II-h) are contained, and the content of the compound is in the range of 25 to 50% by mass. 5. The liquid crystal composition according to claim 4, comprising from 1 to 30 compounds selected from the group consisting of III-a) to general formula (III-u), wherein the content of the compound is in the range of 35 to 60% by mass. object. As a compound of general formula (IV), the following general formula (IV-a) to general formula (IV-d)

Wherein R ⁷ represents an alkyl group having 1 to 16 carbon atoms, an alkoxyl group having 1 to 16 carbon atoms, an alkenyl group having 2 to 16 carbon atoms, or an alkenyloxy group having 3 to 16 carbon atoms. 5. The liquid crystal compound according to claim 2, comprising one or more compounds selected from the group consisting of compounds represented by formula (1): , Containing 1 to 8 compounds selected from the group consisting of general formula (II-a) to general formula (II-h), the content of the compound being in the range of 25 to 45% by mass, (III-a) to 1 to 30 compounds selected from the group consisting of the general formula (III-u), the content of the compound is in the range of 35 to 55% by mass, and the general formula (IV- 7. The liquid crystal composition according to claim 6, wherein the liquid crystal composition comprises 1 to 8 compounds selected from the group consisting of a) to general formula (IV-d), and the content of the compound-containing compound is 5 to 20% by mass. 1 to 30 compounds selected from the group consisting of compounds represented by formula (II-a), formula (II-b), formula (II-c) and formula (II-f) And the content of the compound is in the range of 25 to 45% by mass, the general formula (III-a), the general formula (III-c), the general formula (III-d), the general formula (III-g), General formula (III-h), general formula (III-j), general formula (III-l), general formula (III-m), general formula (III-n), general formula (III-o), general formula (III-p), 1 to 30 compounds selected from the group consisting of compounds represented by general formula (III-q) and general formula (III-u), wherein the content of the compound is 35 to 1 to 8 compounds selected from the group consisting of compounds represented by general formula (IV-a), general formula (IV-c) and general formula (IV-d) 7. The liquid crystal composition according to claim 6, wherein the content of the compound is 5 to 20% by mass. A liquid crystal display device using the liquid crystal composition according to claim 1. A super twisted nematic (STN) liquid crystal display element using the liquid crystal composition according to claim 1.