JP2006239627A - System for treatment of organic waste water containing nitrogen - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a system for treatment of organic waste water containing nitrogen, which can be made compact by rationalizing the system, is high in a nitrogen removal efficiency and can surely remove nitrogen. <P>SOLUTION: This system is provided with: a suspended sludge-used biological treatment apparatus 11 for biologically treating organic waste water 20 containing nitrogen with activated sludge of a suspended state; a membrane separation apparatus 12 for subjecting the biologically treated liquid to be discharged from the suspended sludge-used biological treatment apparatus to membrane separation to obtain a separated liquid and separated sludge; and an anaerobic microbe fixed bed apparatus 13 for biologically treating the separated liquid by the action of a microbe fixed on a support under an anaerobic condition. A step of removing a nitrogen component contained in the separated liquid is carried out mainly in the anaerobic microbe fixed bed apparatus 13. A submerged membrane separation system is suitably adopted in the membrane separation apparatus 12 so that an oxygen-containing diffusion gas is removed and a nitrification step is also carried out in the membrane separation apparatus 12. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

  The present invention relates to the treatment of organic wastewater containing pollutants such as nitrogen, and more particularly to a nitrogen-containing organic wastewater treatment system mainly composed of biological treatment that decomposes and removes nitrogen by the action of microorganisms.

In organic wastewater such as human waste, septic tank sludge, and industrial wastewater, the environment such as SS (floating matter), nitrogen, phosphorus, BOD (biochemical oxygen demand), COD (chemical oxygen demand) Contaminating substances that adversely affect the human body are included, and various methods for removing these have been developed and put into practical use.
The treatment of organic waste water is mainly performed by removing SS by solid-liquid separation, oxidative decomposition of BOD and COD, removal of inorganic nutrient salts such as phosphorus and nitrogen compounds, and treatment of sludge solids alone or in combination.
As shown in FIG. 6, the conventional general organic wastewater treatment system first receives the accepted organic wastewater in the pretreatment facility 50 to remove impurities and then puts it into the biological treatment device 51. Then, BOD, TN (nitrogen), etc. are mainly processed and separated into a separated liquid and separated sludge by a solid-liquid separation facility 52 such as sedimentation separation, and the separated liquid is separated by an advanced treatment facility 53. After performing treatments such as coagulation separation and activated carbon treatment to remove TP (phosphorus), COD, and chromaticity components, they were discharged out of the system. On the other hand, the separated sludge has been subjected to incineration, composting, and the like in the sludge treatment facility 54.

In such a treatment system, the following biological treatment facilities having main functions are available. (I) An anaerobic digestion, activated sludge method (aeration tank), basically a treatment method that does not consider the removal of TN (nitrogen), (II) active as a nitrification denitrification treatment For example, a treatment system that performs nitrogen removal.
However, in facilities that use the biological treatment method (I), TN (total nitrogen) remains in the treatment liquid, but when adding a nitrogen removal function due to stricter regulations, Modification to the system is necessary, and large-scale construction such as expansion of the water tank and modification in the tank is required. In addition, in facilities that use the biological treatment method (II), the properties of wastewater discharged due to changes in the lifestyle of residents change, making it difficult to operate and manage biological treatment equipment, and nitrogen is contained in the treatment liquid. There are cases that remain. This is because the SS concentration tends to decrease in, for example, human waste, septic tank sludge, etc., and it becomes difficult to keep the BOD / N ratio at the time of nitrification and denitrification, and the denitrification efficiency decreases.

Generally, when the nitrogen component in wastewater is removed by the biological treatment method of (II), NH ₄ —N (ammonia nitrogen), Org-N (organic nitrogen) in wastewater is converted to NO ₂ —N (nitrous acid). Nitrogen) and NO ₃ —N (nitric nitrogen) and a denitrification step that converts NO ₂ —N and NO ₃ —N to N ₂ gas in the presence of an organic carbon source. Nitrogen treatment is performed.
A technique for removing nitrogen from wastewater through these processes has been proposed and put into practical use in, for example, Patent Document 1 (Japanese Patent Laid-Open No. 7-308687). Patent Document 1 discloses a first biological reaction tank for biologically treating wastewater under anaerobic conditions, and a second biological treatment for treating water transferred from the first biological reaction tank under aerobic conditions. And a biological reaction tank, wherein the nitrification step is performed by aeration of treated water in the second biological reaction tank, and the denitrification step is performed by the fixed bed holding the cells in the first biological reaction tank. Is disclosed.

Thus, the biological fixed bed is suitable for the denitrification process in the denitrification process for the following reasons. When a fixed bed is used in the nitrification process, nitrifying bacteria are more dependent on the environment such as temperature and pH than denitrifying bacteria, and the activity of the nitrifying bacteria decreases depending on the conditions, and the cells are detached from the fixed bed. As a result, the processing performance may be hindered. Therefore, when a fixed bed is used in the denitrification process, a relatively stable treatment performance can be maintained.
However, in the apparatus of Patent Document 1, the nitrification process and the denitrification process in the denitrification process are performed in a balanced manner, and all nitrogen components of ammonia nitrogen, nitrite nitrogen, and nitrate nitrogen are removed to a satisfactory level. Thus, it is very difficult to perform proper operation control, and there is a high possibility that any nitrogen component remains in the treated water.

Further, in solid-liquid separation after biological treatment, an apparatus that employs a membrane separation apparatus that is immersed in a liquid such as a hollow fiber membrane is disclosed in Patent Document 2 (Japanese Patent Laid-Open No. 8-57269). When the device is applied to wastewater treatment, even if the removal performance of TN is satisfied in biological treatment, aeration is performed as membrane surface cleaning, so that the bacterial cells in the sludge are disassembled and nitrogen is released from the bacterial cells. It is considered that nitrogen elutes and nitrogen remains in the treated water.
Furthermore, among nitrogen remaining in biological treatment, ammonia nitrogen can be efficiently decomposed by electrolysis (see Patent Document 3) after solid-liquid separation, but nitrite nitrogen or nitrate nitrogen In this case, it is very difficult to disassemble and remove.
Further, when removing nitrite nitrogen and nitrate nitrogen by the electrolytic method, a large amount of electric power is required and the performance is limited, so that the nitrogen removal rate is lowered.

JP-A-7-308687 JP-A-8-57269 JP 2004-202484 A

Thus, it has been difficult to efficiently remove all nitrogen components such as ammonia nitrogen, nitrate nitrogen, and nitrite nitrogen in the nitrogen removal treatment in the conventional wastewater treatment system. Further, when trying to increase the nitrogen removal efficiency, there is a problem that the apparatus becomes complicated and the system becomes large.
Therefore, in view of the above-mentioned problems of the prior art, the present invention can be made compact by making it a streamlined system, has high nitrogen removal efficiency, and can contain nitrogen reliably. The purpose is to provide a wastewater treatment system.

Therefore, in order to solve this problem, the present invention provides:
Floating sludge-type biological treatment equipment that biologically treats nitrogen-containing organic wastewater with suspended activated sludge, and a membrane that separates biological treatment liquid discharged from the floating sludge-type biological treatment equipment to obtain a separated liquid and separated sludge A separation apparatus, and an anaerobic biological fixed bed apparatus that biologically treats the separation liquid by the action of microorganisms immobilized on a support under anaerobic conditions,
In the floating sludge type biological treatment apparatus, a nitrification step of nitrogen component contained mainly in the organic waste water is mainly performed, and in the anaerobic biological fixed bed apparatus, nitrogen component mainly contained in the separation liquid. The denitrification process is performed.

The present invention mainly employs a nitrification step of converting ammonia nitrogen from nitrogen components into nitrite nitrogen (NO ₂ -N) and nitrate nitrogen (NO ₃ -N) in the floating sludge biological treatment apparatus. The denitrification step of converting the nitrate nitrogen and nitrite nitrogen into nitrogen gas is mainly performed in the anaerobic fixed bed apparatus at the latter stage.
In the biological treatment in the prior art, it has been difficult to perform proper operation control so that the nitrification step and the denitrification step in the denitrification treatment are performed in a balanced manner and nitrogen is removed to a satisfactory level. In the floating sludge type biological treatment device, while aeration removes organic matter, partially nitrifies nitrogen, removes nitrogen by denitrification, the nitrification process is dominant with respect to nitrogen removal, and the form of residual nitrogen is nitrous acid. Since the treatment mainly includes basic nitrogen and nitrate nitrogen is performed, the operation can be performed relatively easily by adjusting the amount of aeration air by ORP, pH monitoring and the like in the tank.

In addition, since the nitrification process is performed at the center of gravity in the floating sludge biological treatment apparatus, the apparatus can be miniaturized, and in the denitrification process, the fixed bed is more nitrogenous than the floating sludge process. Although the volumetric load can be increased, since the separation liquid after membrane separation is processed, there is less concern about blockage due to SS, and a support having a high specific area such as anthracite can be adopted. Can be miniaturized. Therefore, the system as a whole can be made much more compact. Furthermore, since an aerobic fixed bed is not installed in the anaerobic organism fixed bed apparatus, there is little risk of sudden bacterial cell separation, and there is no need to install a new solid-liquid separation facility after the fixed bed.
Further, since the membrane separation device is provided as the solid-liquid separation means, the MLSS concentration of the floating sludge type biological treatment device can be increased, the treatment efficiency can be improved, and the low concentration SS separation solution. Therefore, the treatment efficiency in the anaerobic organism fixed bed can be expected to be improved.

In addition, the membrane separation device is provided below the membrane unit, a membrane unit immersed in the biological treatment liquid, a liquid collecting means for collecting the separation liquid through the membrane unit, and the biological unit A submerged membrane separation apparatus having an aeration means for introducing and aeration of an aeration gas containing oxygen into the treatment liquid.
Thus, by adopting the submerged membrane separation apparatus, stable solid-liquid separation can be achieved at a low running cost.
In the present invention, a part of oxygen contained in the aeration gas is dissolved in the treatment liquid, and ammonia nitrogen remaining in the treatment liquid is converted into nitrate nitrogen and nitrite nitrogen by the dissolved oxygen. A nitrification process is performed. This nitrification step can be suitably performed by adjusting the aeration intensity by the aeration means. Thereby, a nitrification process is suitably performed in the treatment liquid, and a permeate containing almost no ammoniacal nitrogen is obtained.
On the other hand, the aeration means also has a membrane surface cleaning function by bubbles for stabilizing the cake layer deposited on the membrane surface. However, the cells themselves are disassembled by this aeration, and the nitrogen component is eluted again in the liquid. There is a case. However, in the present invention, since the anaerobic biological fixed bed apparatus is installed in the subsequent stage of the membrane separation apparatus, the generated nitrogen component can be reliably treated.

In addition, a biological sludge treatment system that biologically treats nitrogen-containing organic wastewater with suspended activated sludge, and a biological treatment liquid discharged from the sludge biotreatment apparatus are separated into membranes to separate the separated liquid and the separated sludge. A membrane separation device to obtain,
The membrane separation apparatus is provided below the membrane unit, a membrane unit immersed in the biological treatment solution, a liquid collecting means for collecting the separation solution through the membrane unit, and the biological treatment solution An aeration means for introducing and aeration of an aeration gas containing oxygen therein,
In the floating sludge type biological treatment apparatus, the nitrification step of the nitrogen component contained in the organic waste water is mainly performed, and in the membrane separation device, the nitrification step of the nitrogen component contained in the biological treatment liquid. The aeration intensity by the aeration means is set so that the aeration is performed. In the present invention, the same effect as described above can be obtained.

Furthermore, a second membrane separation device for reverse osmosis membrane separation or electrodialysis separation of the separation liquid obtained by the membrane separation device is provided, and the concentrated liquid obtained by the second membrane separation device is anaerobic. It is supplied to a biological fixed bed apparatus.
Thereby, the amount of water flowing into the anaerobic organism fixed bed apparatus can be reduced, and the apparatus can be made compact.
Furthermore, an electrolytic denitrification apparatus for removing a nitrogen component by electrolysis is provided between the membrane separation apparatus and the anaerobic biological fixed bed apparatus.
This is because ammonia nitrogen is mainly removed by the electrolysis, so that ammonia nitrogen can be reliably removed even when ammonia nitrogen remains after membrane separation. Further, even when a part of ammonia nitrogen is converted into nitrous acid and nitrate nitrogen in the electrolytic denitrification apparatus, these can be surely removed by the anaerobic fixed bed apparatus in the subsequent stage.

  As described above, according to the present invention, in the nitrogen-containing organic wastewater treatment mainly composed of biological treatment, the floating sludge type biological treatment device, the anaerobic biological fixed bed, and the membrane separation device are optimally combined. A stable processing system can be provided and the entire system can be made compact.

Hereinafter, exemplary embodiments of the present invention will be described in detail with reference to the drawings. However, the dimensions, materials, shapes, relative arrangements, and the like of the components described in this embodiment are not intended to limit the scope of the present invention unless otherwise specified, but are merely illustrative examples. Not too much.
The organic wastewater to be treated in this embodiment is wastewater containing nitrogen such as human waste, septic tank sludge, and factory wastewater.
FIG. 1 is a configuration diagram showing an outline of an organic wastewater treatment system according to Embodiment 1 of the present invention, FIG. 2 is an explanatory diagram showing an example of a membrane separation apparatus according to this embodiment, and FIG. 3 is a membrane separation apparatus of FIG. 4 is a perspective view showing a configuration of a membrane unit included in FIG. 4, FIG. 4 is a configuration diagram showing an outline of an organic wastewater treatment system according to Embodiment 2 of the present invention, and FIG. 5 of an organic wastewater treatment system according to Embodiment 3 of the present invention. It is a block diagram which shows an outline.

  As shown in FIG. 1, the organic wastewater treatment system according to the first embodiment includes a pretreatment facility 10 into which organic wastewater 20 is introduced in order from the upstream side of the treatment process, and an organic property after the pretreatment. Anaerobic biological immobilization into which the floating sludge biological treatment apparatus 11 into which the waste water 20 is introduced, the membrane separation apparatus 12 into which the biological treatment liquid after the biological treatment is introduced, and the separation liquid 21 obtained by membrane separation are introduced. The membrane separation device 12 includes a floor device 13, an advanced treatment facility 14 into which the treatment liquid obtained in the biological fixed bed device is introduced, and a sludge treatment facility 14 into which the separated sludge 22 is introduced. At least a part of the sludge 22 separated in step 1 is returned to the biological treatment facility 11.

Examples of the pretreatment facility 10 include a screen for removing impurities contained in the organic wastewater 20, a precipitation tank, and the like.
The floating sludge biological treatment apparatus 11 is an apparatus that has at least an aeration tank and mainly performs a nitrification step of a nitrogen component contained in the pretreated organic wastewater, and preferably a nitrification step of the contained nitrogen The aeration tank that performs the denitrification process and the denitrification tank that performs the denitrification process are configured so that the treatment in the aeration tank becomes dominant by combining one or more. In the aeration tank, the wastewater stored in the tank is aerated, and ammonia nitrogen (NH ₄ -N) contained in the wastewater is converted into nitrite by the decomposition action of microorganisms such as nitrite bacteria and nitrate bacteria. nitrogen _(NO 2 -N), is oxidized to nitrate nitrogen _(NO 3 -N). On the other hand, in the denitrification tank, the nitrite nitrogen and nitrate nitrogen contained in the wastewater are reduced to nitrogen gas (N ₂ ) by the action of microorganisms by aeration of the treatment liquid in the presence of a hydrogen donor. Is done. At this time, a carbon source such as methanol or acetic acid may be supplied as the hydrogen donor as necessary.

The membrane separation device 12 is a device that includes a membrane unit such as a UF membrane (ultrafiltration) or an MF membrane (microfiltration), for example, and separates biologically treated water into a separated liquid and separated sludge.
An example of a specific apparatus configuration of the membrane separation apparatus 12 is shown in FIGS.
As shown in FIG. 2, the membrane separation device 12 includes a membrane raw water tank 30 for storing a biological treatment liquid, a membrane unit 31 immersed in the treatment liquid in the membrane raw water tank 30, and a suction pump 33. A permeate feed pipe 32 that sucks the processing liquid in the tank through the membrane unit 31 and an aeration pipe 34 disposed below the membrane unit 31 are configured. The membrane separation device 12 is operated such that the membrane permeation flux has a membrane area of 0.5 m ³ / m ² · day or less, and the membrane suction pressure is about −0.02 MPa or less. Is preferred.
As shown in FIG. 3, the membrane unit 31 includes a flat membrane module 35 in which a microporous membrane element 38 is bonded to a mesh steel material 37 held by a frame 36, and the membrane module A plurality of layers 35 are arranged in layers at predetermined intervals by spacers 39. A space formed by the spacer 39 becomes a flow path for the processing liquid. Inside the membrane module 35, a flow path for the permeate that has passed through the membrane element 38 is formed, and the permeate is collected in a permeate collection tube 40 to pass through the permeate feed pipe 32. It is sent to the latter device through.

The biological treatment liquid supplied into the membrane raw water tank 30 is sucked through the membrane unit 31 by the transmembrane differential pressure generated by depressurizing the permeate side with the suction pump 33. A separation liquid which is filtered when passing through 31 to remove SS, microorganisms and the like is obtained. At this time, a diffused gas is ejected from a diffuser tube 34 provided below the membrane unit 31 to aerate the processing liquid. The aeration gas is a gas containing oxygen, preferably air. In the membrane raw water tank 30, a part of oxygen contained in the aeration gas is dissolved in the treatment liquid, and ammonia nitrogen remaining in the treatment liquid is converted into nitrite nitrogen and nitrate nitrogen by the dissolved oxygen. A nitrification process is performed. This nitrification step can be suitably performed by adjusting the amount of aeration gas supplied (aeration intensity) through the aeration tube 34. As a preferable condition at this time, the aeration intensity (the amount of air supplied per 1 m ^{3 of} water tank) is preferably ⁴ to 5 Nm ³ / hour. Thereby, a nitrification process is suitably performed in the treatment liquid, and a permeate containing almost no ammoniacal nitrogen is obtained. At the same time, aeration by the diffusing tube 34 also has a function of appropriately maintaining the thickness of the cake layer deposited on the surface of the membrane element 38 of the membrane unit 31. This maintains the surface flow rate of the membrane element 38 due to aeration and prevents the cake layer from becoming too thick and blocking the membrane.

Furthermore, as a preferable configuration of the membrane unit 35, the membrane unit 35 is installed at the bottom of the membrane raw water tank 30. At this time, the arrangement position of the membrane unit 35 is preferably a position with a water depth of about 4 to 5 m. Thereby, since the transmembrane pressure difference increases, suction can be performed with high efficiency, and the suction power of the pump can be reduced. Further, the membrane unit 35 may be arranged in a plurality of stages in the vertical direction.
The air diffuser 34 is preferably disposed about 500 mm above the bottom of the membrane raw water tank. By providing the air diffuser 34 at the tank bottom in this way, the air diffused gas is easily dissolved in the processing liquid, and the nitrification process is promoted. The

The anaerobic organism fixed bed apparatus 13 includes a treatment tank maintained under anaerobic conditions and a support that is accommodated in the treatment tank and supports microorganisms, and adheres to the support surface to form a film. It is a well-known apparatus that performs treatment with microorganisms that have grown rapidly. For example, a configuration in which a plurality of honeycomb-like plate-like supports are arranged in parallel in the tank, or a structure in which a granular packed bed filled with a granular support such as anthracite is arranged in the tank, and the like can be mentioned. Since this separation liquid does not contain SS, it is preferable to reduce the size of the apparatus by adopting a granular packed bed having a small risk of clogging and a higher specific area. In the present embodiment, the anaerobic organism fixed bed apparatus 13 mainly performs a denitrification step of the separation liquid, and converts nitrate nitrogen and nitrite nitrogen into nitrogen gas by the action of microorganisms.
The sludge treatment facility 14 is a facility for performing dehydration, drying, incineration, composting, and the like of the separated sludge 22.
Examples of the advanced processing equipment 15 include a coagulation separator, an activated carbon adsorption tower, and the like.

About the processing equipment which has the above composition, the operation is explained with a processing method.
First, the organic waste water 20 is introduced into the pretreatment facility 10, and after pretreatment such as removal of contaminants is performed in the pretreatment facility 10, the organic wastewater 20 is supplied to the floating sludge type biological treatment device 11. Inside, the biological treatment liquid 21 is obtained by removing SS, BOD, nitrogen components and the like in the waste by the decomposition action of microorganisms. In the biological treatment apparatus 11, as the removal of the nitrogen component, a treatment that predominates the nitrification step is performed, and ammonia nitrogen in the treatment liquid is converted into nitrite nitrogen and nitrate nitrogen, and ammonia nitrogen is contained in the treatment liquid. Hardly remains.

And this biological treatment liquid is introduce | transduced into the membrane separator 12, and the separation sludge 22 containing SS, microorganisms, etc. in this membrane separator 12 and the separation liquid containing nitrate nitrogen and nitrite nitrogen with low SS concentration In addition, the nitrification step is performed in the membrane separation device 12 to convert ammonia nitrogen remaining in the treatment liquid into nitrate nitrogen and nitrite nitrogen.
The separation liquid 21 containing nitrate nitrogen and nitrite nitrogen is introduced into the anaerobic biological fixed bed apparatus 13, and a carbon source is appropriately supplied in the biological fixed bed apparatus 13 to mainly perform a denitrification step. Nitrate nitrogen and nitrite nitrogen are separated as nitrogen gas and rendered harmless.
The treatment liquid from which the nitrogen component has been removed by the anaerobic organism fixed bed apparatus 13 is purified by the advanced treatment facility 15 and then discharged as treated water. In the anaerobic organism fixed bed apparatus 13, stable treatment is possible by regularly backwashing with air, post-treatment water or the like. The backwash wastewater generated at this time may be returned to the membrane separation device 13 or its upstream side.
On the other hand, at least a part of the separated sludge 22 is returned to the floating sludge-type biological treatment apparatus 11 as return sludge 23, and the other sludge is incinerated and composted in the sludge treatment facility 14.

As described above, in this example, the organic wastewater is subjected to floating sludge type biological treatment that predominates the nitrification process, and then the biological treatment liquid is separated into membranes and separated mainly in the anaerobic biological fixed bed. It was set as the structure which performs the denitrification process of a liquid. In this way, in the nitrogen removal process, the nitrification process and the denitrification process are separated and the treatment is performed at the apparatus and position where each reaction is most efficiently performed, so the nitrogen component can be efficiently removed, In addition, the apparatus and system can be made compact. Furthermore, since the nitrification process is dominant in the floating sludge biological treatment, the operation in the biological treatment apparatus becomes easy.
In addition, since the membrane separation device is installed, the treatment target in the latter anaerobic organism fixed bed is a separation liquid having a very low SS concentration, so that the treatment efficiency is improved and the floating sludge biological treatment is performed. The MLSS concentration of the apparatus can be increased, and the processing efficiency here can be improved.
Furthermore, since the membrane separation device is a submerged membrane separation device, it is possible to convert ammonia nitrogen remaining without being treated by floating sludge biological treatment into nitrate nitrogen and nitrite nitrogen. Yes, an improvement in nitrogen removal rate can be expected.
In addition, by providing the anaerobic organism fixed bed apparatus, nitrogen eluted by aeration of the treatment liquid can be reliably removed by the submerged membrane separation apparatus.
As described above, according to the present embodiment, in the nitrogen-containing organic wastewater treatment mainly composed of biological treatment, the floating sludge-type biological treatment device, the anaerobic biological fixed bed, and the membrane separation device are optimally combined. Thus, it is possible to provide a stable processing system.

FIG. 4 shows a schematic configuration of an organic wastewater treatment system according to the second embodiment. Hereinafter, in the second embodiment and the third embodiment, detailed description of the configuration substantially similar to that of the first embodiment will be omitted.
In the second embodiment, in addition to the configuration of the treatment system of the first embodiment, a reverse osmosis membrane device 16 is provided between the membrane separation device 12 and the anaerobic biological fixed bed device 13, and the reverse osmosis membrane device 16. The concentrated liquid concentrated in (1) is introduced into the anaerobic organism fixed bed apparatus 13, and the separation liquid 24 is discharged as treated water or introduced into the advanced treatment facility 15.
The reverse osmosis membrane device 16 is a well-known device, thereby concentrating nitrite nitrogen and nitrate nitrogen contained in the treatment liquid, and adding a concentrated solution containing these in high concentration to the anaerobic organism fixed bed device 13. Process.
As an alternative to the reverse osmosis membrane device 16, an electrodialysis device may be used.
According to this embodiment, since the amount of water flowing into the anaerobic organism fixed bed apparatus 13 can be reduced, the apparatus can be made compact.

FIG. 5 shows a schematic configuration of an organic wastewater treatment system according to the third embodiment.
In the third embodiment, in addition to the configuration of the treatment system of the first embodiment, an electrolytic denitrification device 17 is provided between the membrane separation device 12 and the anaerobic biological fixed bed device 13.
In the electrolytic denitrogenator 17, electrolysis of the separation liquid 21 mainly produces a hypochlorous acid-based strong oxidizing substance such as hypochlorous acid, and ammonia contained in the separating liquid by the strong oxidizing substance. Nitrogen is decomposed and removed. Examples of the electrolysis that can be applied to this embodiment include direct current electrolysis, ozone electrolysis, catalytic electrolysis, pulse electrolysis, mesh, electrolysis using a granular electrode, and the like.
As described above, according to this embodiment, even when ammonia nitrogen is mixed into the residual nitrogen after solid-liquid separation, the ammonia nitrogen can be reliably removed by providing the electrolytic denitrification device 17. Further, even when a part of ammonia nitrogen is converted into nitrous acid and nitrate nitrogen by the electrolytic denitrification device 17, these can be reliably removed by the anaerobic fixed bed device 13 at the subsequent stage.

  Since the present invention can be reduced in size and space-saving and can be denitrified with high efficiency, organic sewerage treatment, human waste treatment, septic tank sludge treatment, livestock wastewater treatment, fishery processing wastewater treatment, It can be effectively applied to both cleaning wastewater treatment and factory wastewater treatment.

It is a block diagram which shows the outline of the organic wastewater treatment system which concerns on Example 1 of this invention. It is explanatory drawing which shows an example of the membrane separator which concerns on a present Example. It is a perspective view which shows the structure of the membrane unit with which the membrane separator of FIG. 2 is provided. It is a block diagram which shows the outline of the organic wastewater treatment system which concerns on Example 2 of this invention. It is a block diagram which shows the outline of the organic wastewater treatment system which concerns on Example 3 of this invention. It is a block diagram of the conventional organic wastewater treatment system.

Explanation of symbols

DESCRIPTION OF SYMBOLS 10 Pretreatment equipment 11 Floating sludge type biological treatment equipment 12 Membrane separator 13 Anaerobic organism fixed bed equipment 14 Sludge treatment equipment 15 Advanced treatment equipment 16 Reverse osmosis membrane equipment 17 Electrodenitrification equipment 30 Membrane raw water tank 31 Membrane unit 33 Suction pump 34 Diffuser 35 Membrane module 38 Membrane element

Claims (5)

Floating sludge-type biological treatment equipment that biologically treats nitrogen-containing organic wastewater with suspended activated sludge, and a membrane that separates biological treatment liquid discharged from the floating sludge-type biological treatment equipment to obtain a separated liquid and separated sludge A separation apparatus, and an anaerobic biological fixed bed apparatus that biologically treats the separation liquid by the action of microorganisms immobilized on a support under anaerobic conditions,
In the floating sludge type biological treatment apparatus, a nitrification step of nitrogen component contained mainly in the organic waste water is mainly performed, and in the anaerobic biological fixed bed apparatus, nitrogen component mainly contained in the separation liquid. A nitrogen-containing organic wastewater treatment system characterized in that a denitrification step is performed.   The membrane separation apparatus is provided below the membrane unit, a membrane unit immersed in the biological treatment solution, a liquid collecting means for collecting the separation solution through the membrane unit, and the biological treatment solution The nitrogen-containing organic wastewater treatment system according to claim 1, wherein the nitrogen-containing organic wastewater treatment system has an aeration means for introducing and aeration by introducing an aeration gas containing oxygen. Floating sludge-type biological treatment equipment that biologically treats nitrogen-containing organic wastewater with suspended activated sludge, and a membrane that separates biological treatment liquid discharged from the floating sludge-type biological treatment equipment to obtain a separated liquid and separated sludge A separation device,
The membrane separation apparatus is provided below the membrane unit, a membrane unit immersed in the biological treatment solution, a liquid collecting means for collecting the separation solution through the membrane unit, and the biological treatment solution An aeration means for introducing and aeration of an aeration gas containing oxygen therein,
In the floating sludge type biological treatment apparatus, the nitrification step of the nitrogen component contained in the organic waste water is mainly performed, and in the membrane separation device, the nitrification step of the nitrogen component contained in the biological treatment liquid. The nitrogen-containing organic wastewater treatment system is characterized in that the aeration intensity by the aeration means is set so as to be performed.   Provided with a second membrane separation device for reverse osmosis membrane separation or electrodialysis separation of the separation liquid obtained by the membrane separation device, and the concentrated solution obtained by the second membrane separation device is immobilized on an anaerobic organism The nitrogen-containing organic wastewater treatment system according to claim 1 or 3, wherein the system is supplied to a floor apparatus. 5. The nitrogen-containing organic wastewater treatment system according to claim 1, wherein an electrolytic denitrification device for removing a nitrogen component by electrolysis is provided between the membrane separation device and the anaerobic biological fixed bed device. .

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