JP2006239354A - Method and apparatus for generating carbonated spring with sterilization function - Google Patents

Method and apparatus for generating carbonated spring with sterilization function Download PDF

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JP2006239354A
JP2006239354A JP2005099645A JP2005099645A JP2006239354A JP 2006239354 A JP2006239354 A JP 2006239354A JP 2005099645 A JP2005099645 A JP 2005099645A JP 2005099645 A JP2005099645 A JP 2005099645A JP 2006239354 A JP2006239354 A JP 2006239354A
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water
pressure vessel
bathtub
footbath
aqueous solution
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Tatsuo Okazaki
龍夫 岡崎
Yoshinori Ota
好紀 太田
Hiroshi Teranishi
洋 寺西
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Veeta Inc
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a clean bathtub kept at appropriate temperature for 24 hours, capable of generating high-concentration carbonated spring when desired, and saving energy and noise by circulating bathtub water through a bypass conduit with the reduced frequency of rotation of a pump when the carbonated spring is not generated. <P>SOLUTION: Water in a bathtub or foot bathtub is sprayed/fed to a pressure vessel 12 filled with carbon dioxide with pressure by a pump 3 and carbon dioxide is efficiently dissolved in water to generate carbonated spring, which is returned to the bathtub or foot bathtub. By this circulation of water and periodical addition of a disinfectant such as aqueous sodium hypochlorite solution or aqueous sodium chlorite solution in the middle of the circulation conduit, the disinfectant, which is originally alkaline, becomes slightly acidic together with water in the bathtub or foot bathtub by the effect of carbon dioxide, so that a sufficient sterilization effect can be achieved even if the concentration of the disinfectant is low. In addition, a simple filter 2 and a heater 4 can be attached to the circulation conduit. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本発明は、浴槽や足浴槽の温水を過熱、保温、ろ過などを行う循環管路において、炭酸ガスを溶け込ませて前記浴槽水や足浴槽水中の炭酸ガス溶存濃度を高め、極めて高濃度の人工炭酸泉を生成する技術に関するものである。  The present invention provides an extremely high concentration artificial water in a circulation pipe for overheating, keeping warm, and filtering hot water in a bathtub or a foot tub by dissolving carbon dioxide to increase the dissolved concentration of carbon dioxide in the bathtub water or foot tub water. It relates to the technology for producing carbonated springs.

本発明は炭酸ガスを充填した圧力容器内に浴槽水や足浴槽水を噴射および/又は散水して、浴槽水や足浴槽水中の溶存炭酸ガス濃度を高めて、天然の炭酸泉と同等かそれ以上の治療効果を有する人工炭酸泉を生成することができる技術に関するものである。  The present invention jets and / or sprinkles bathtub water or footbath water into a pressure vessel filled with carbon dioxide gas to increase the concentration of dissolved carbon dioxide in the bathtub water or footbath water, and is equivalent to or higher than natural carbonated springs. It is related with the technique which can produce | generate the artificial carbonated spring which has the therapeutic effect of this.

また、特に家庭用の24時間風呂や足浴装置に適した人口炭酸泉装置の技術に関するもので、高濃度の炭酸濃度を実現すると共に、浴槽や足浴槽の温水の効果的な殺菌方法も併せ持つ方法および装置に関するものである。  In addition, the present invention relates to a technology of artificial carbonated spring apparatus particularly suitable for home 24 hour baths and foot bath devices, and a method for realizing a high concentration of carbon dioxide and also having an effective sterilization method for hot water in bathtubs and foot baths. It relates to the device.

従来から、さまざまな名称の家庭用炭酸泉浴用剤の投入により得られる炭酸泉が知られているが、これらは重炭酸ナトリウムに有機酸を混合して加熱水中で炭酸ガスを生成させるものであった。また、炭酸ガス入り飲料の生成技術としては、古くから冷却した水の中に炭酸ガスを吹き込む形の高濃度炭酸水生成方法が知られていた。
また、炭酸水生成方法で別の生成方法としては炭酸ガス空間に散水して炭酸ガスを溶け込ませ、飲料用の炭酸水を生成する方法などが知られていた。
Conventionally, carbonated springs obtained by introducing various names of household carbonated spring bath agents are known, but these were made by mixing an organic acid with sodium bicarbonate to generate carbon dioxide gas in heated water. As a technique for producing a carbon dioxide-containing beverage, a high-concentration carbonated water production method in which carbon dioxide gas is blown into cooled water has been known for a long time.
As another method for generating carbonated water, there has been known a method of generating carbonated water for beverages by sprinkling water into a carbon dioxide space and dissolving the carbon dioxide.

人体の皮膚は、冷水に触れたときに体温の低下を防ぐために毛細血管の収縮が起こり、皮膚近傍での血流が減少する。これに対して、適度な温度の炭酸ガス含有加熱水に肌が接すると、皮膚の下に炭酸ガスが浸透して酸素欠乏状態になり、この酸素欠乏状態の信号を受けた毛細血管は大量の血液を流せるように毛細血管の入口を開き、この結果、皮膚近傍の血流が増大し、皮膚の紅潮現象となって現れる。このメカニズムが、炭酸含有加熱水の浴用効果と考えられている。ここに、温泉として適温である40〜42℃程度の温度での炭酸ガスの飽和溶存濃度は約1000ppmである。  When the human skin is exposed to cold water, capillary contraction occurs to prevent a decrease in body temperature, and blood flow near the skin decreases. In contrast, when the skin comes into contact with heated water containing carbon dioxide at an appropriate temperature, carbon dioxide penetrates under the skin and becomes oxygen-deficient, and a large amount of capillaries that receive this oxygen-deficient signal The entrance of the capillary is opened so that blood can flow. As a result, the blood flow in the vicinity of the skin increases and appears as a flushing phenomenon of the skin. This mechanism is considered to be a bathing effect of carbonated heated water. Here, the saturated dissolved concentration of carbon dioxide at a temperature of about 40 to 42 ° C., which is a suitable temperature for hot springs, is about 1000 ppm.

炭酸泉は、保温効果に優れた皮膚に優しい温泉として世界的に知られている。このことだけでなく、高濃度の炭酸含有加熱水は治療効果があると認識され始めている。例えば、糖尿病患者に多く見られるように、例えば足のキズが悪化して壊死状態になり、このため足の切断手術が必要になる事例が世界的に増加しているが、このような事例に対して高濃度炭酸含有加熱水に入浴する治療方法が効果的であると考えられている。  Carbonated springs are known around the world as skin-friendly hot springs with excellent heat retention. Not only this, but high concentration carbonated heating water is beginning to be recognized as having a therapeutic effect. For example, as is often seen in diabetics, for example, there is an increasing number of cases in which the wound in the foot worsens and becomes necrotic, which necessitates amputation of the foot. On the other hand, it is thought that the treatment method bathed in the heating water containing high concentration carbonic acid is effective.

日本特開平7−313855号は、ガス透過性中空糸を使った炭酸泉生成装置を提案している。この炭酸泉生成装置は、中空糸を収容した炭酸ガス溶解器と浴槽とが循環管路で連結され、ポンプで浴槽から汲み上げた温水を炭酸ガス溶解器の中に供給し、炭酸ガス溶解器で炭酸ガスを溶解させて高濃度の炭酸泉を生成して、これを浴槽に供給するようになっている。  Japanese Unexamined Patent Publication No. 7-313855 proposes a carbonated spring production apparatus using a gas permeable hollow fiber. In this carbonated spring production apparatus, a carbon dioxide gas dissolver containing a hollow fiber and a bathtub are connected by a circulation pipe, hot water pumped from the bathtub by a pump is supplied into the carbon dioxide gas dissolver, and the carbon dioxide gas dissolver is used for carbonation. Gas is dissolved to produce a high-concentration carbonated spring, and this is supplied to the bathtub.

また、この炭酸泉生成装置は、浴槽内に設置した濃度センサーを有し、この濃度センサーで浴槽内の炭酸泉の炭酸ガス濃度を検知して、炭酸ガス溶解器に供給する炭酸ガスの流量を制御することを提案している。この炭酸泉生成装置は、温水に含まれる汚濁物によって中空糸の機能が阻害され易いという問題があり、初期性能を維持するには高頻度のメンテナンスが必要となるという欠点がある。Moreover, this carbonated spring production | generation apparatus has the density | concentration sensor installed in the bathtub, detects the carbon dioxide gas density | concentration of the carbonated spring in a bathtub with this density | concentration sensor, and controls the flow volume of the carbon dioxide gas supplied to a carbon dioxide gas dissolver. Propose that. This carbonated spring production apparatus has a problem that the function of the hollow fiber is likely to be hindered by the contaminants contained in the hot water, and has a drawback that frequent maintenance is required to maintain the initial performance.

特開平11−192421号公報は他の形式の炭酸泉生成装置を提案している。この炭酸泉生成装置は、圧力タンク内に温水を収容し、この圧力タンク内で、圧力下で炭酸ガスをバブリングすることにより温水に炭酸ガスを溶解させて炭酸泉を生成し、所定時間が経過したら炭酸泉を後段のガス分離器に送って大気圧まで減圧すると共に炭酸泉から出た炭酸ガスを回収し、所定時間が経過したら、炭酸泉をガス分離器から浴槽に供給するようになっている。  JP-A-11-192421 proposes another type of carbonated spring generating apparatus. This carbonated spring production device stores warm water in a pressure tank, and generates carbon dioxide by dissolving carbon dioxide in warm water by bubbling carbon dioxide gas under pressure in the pressure tank. Is sent to a subsequent gas separator to reduce the pressure to atmospheric pressure and collect carbon dioxide gas from the carbonated spring. When a predetermined time has elapsed, the carbonated spring is supplied from the gas separator to the bathtub.

この特開平11−192421号公報に開示の炭酸泉生成装置はいわゆるバッチ式であり、圧力タンクに所定量の温水を投入した後に炭酸泉を生成する工程を実行し、次いで、この圧力タンクから炭酸泉を取り出して圧力タンクを空にし、その後、空の圧力タンクの中に温水を供給して、再び炭酸泉を生成する工程を実行するというものであり、このことから、炭酸泉を連続的に生成することができない。  The carbonated spring generating device disclosed in Japanese Patent Application Laid-Open No. 11-192421 is a so-called batch type, which performs a step of generating carbonated spring after charging a predetermined amount of hot water into the pressure tank, and then removes the carbonated spring from the pressure tank. The pressure tank is emptied, then hot water is supplied into the empty pressure tank, and the process of generating carbonated springs again is executed. From this, the carbonated springs cannot be generated continuously. .

特開平6−269483号公報は他の形式の炭酸泉生成装置を提案している。この炭酸泉生成装置は、浴槽から温水を取り出す管路に炭酸ガスを供給して温水と炭酸ガスとを合流させた後にポンプの吸い込み口からポンプ内に入れ、このポンプで炭酸ガスと温水とを混合させて炭酸ガスを温水に溶解させて炭酸泉を生成し、ポンプから送り出される炭酸泉をタンクに供給して、このタンクで未溶解の炭酸ガスを回収した後にタンクの底から炭酸泉を浴槽に戻す構成を採用している。  Japanese Patent Application Laid-Open No. 6-269483 proposes another type of carbonated spring generating apparatus. This carbonated spring generator supplies carbon dioxide to a pipe that takes hot water out of the bathtub, merges the hot water and carbon dioxide, and then enters the pump through the suction port of the pump. This pump mixes the carbon dioxide and hot water. The carbonated gas is dissolved in warm water to produce a carbonated spring, the carbonated spring sent from the pump is supplied to the tank, the undissolved carbon dioxide gas is recovered in this tank, and then the carbonated spring is returned to the bathtub from the bottom of the tank. Adopted.

また、この炭酸泉生成装置は、タンクと浴槽との間の配管に絞りが設けられ、タンク内の炭酸ガスの増加に伴ってタンク内の炭酸泉の水位が低下すると電磁弁を開いてタンクから炭酸ガスを排出し、タンク内の炭酸泉の水位が増加すると電磁弁を閉じる制御が行われる。In addition, this carbonated spring generating device is provided with a throttle in the pipe between the tank and the bathtub, and opens the electromagnetic valve when the carbonated water level in the tank decreases as the carbon dioxide gas in the tank increases. When the water level of the carbonated spring in the tank increases, the solenoid valve is closed.

この特開平6−269483号公報に開示の炭酸泉生成装置は、ポンプの攪拌作用により炭酸ガスを温水に溶解させることを主眼にしており、汎用のポンプを採用したときには、これにより生成できる炭酸泉の溶存炭酸ガス濃度を高濃度にすることは難しい。すなわち、高濃度の炭酸泉を生成しようとしたら、ポンプの上流で大量の炭酸ガスを温水と合流させる必要があるが、この結果、ポンプは大量の気体を吸い込むことになるため、汎用のポンプでは本来のポンプ作用が阻害される。  The carbonated spring production device disclosed in Japanese Patent Laid-Open No. 6-269383 is mainly intended to dissolve carbon dioxide gas in warm water by the stirring action of the pump. When a general-purpose pump is adopted, the carbonated spring that can be produced thereby is dissolved. It is difficult to increase the carbon dioxide concentration. That is, if a high concentration carbonated spring is to be produced, a large amount of carbon dioxide gas needs to be combined with warm water upstream of the pump. As a result, the pump sucks a large amount of gas. The pumping action of is inhibited.

また、人工炭酸泉装置ではないが、家庭用の24時間風呂があり、この24時間風呂においては、一時期大問題になったレジオネラ菌の繁殖を抑制するために、無隔膜電解槽で次亜塩素酸ナトリウム水溶液を生成して、循環浴槽水に添加したり、活性炭や特殊フィルターによる濾過、さらには熱湯殺菌などの複数の濾過および殺菌機能を付加した物がある。  Moreover, although it is not an artificial carbonated spring device, there is a 24-hour bath for home use. In this 24-hour bath, hypochlorous acid is used in a non-diaphragm electrolytic cell in order to suppress the growth of Legionella bacteria, which has been a major problem for some time. There is a product in which an aqueous sodium solution is generated and added to circulating bath water, or filtered with activated carbon or a special filter, and further added with a plurality of filtration and sterilization functions such as hot water sterilization.

発明が解決しようとする課題Problems to be solved by the invention

一般に、浴槽水や足浴槽水は髪の毛や湯垢などが多く、中空糸により炭酸ガスを溶解する方法においては、この湯垢やヌルが中空糸壁面や入り口に溜まり、目詰まりを起こし、初期の性能を維持するためには、複数の濾過器が必要であると共に、頻繁にメンテナンスを行う必要があった。  In general, bath water and foot bath water have a lot of hair and scales, and in the method of dissolving carbon dioxide with hollow fibers, the scales and nulls accumulate on the hollow fiber wall surface and entrance, causing clogging and improving the initial performance. In order to maintain, a plurality of filters are required, and maintenance has to be performed frequently.

また、タンクに溜めた浴槽水や足浴槽水に炭酸ガスをバブリングして、炭酸ガスを溶解する場合は、バッチ式であったり炭酸ガスを回収/再バブリングするための循環システムが必要であるため、装置が大型化して家庭用の装置として使用するには無理があった。  Also, when carbon dioxide is bubbled into the bathtub water or foot bath water stored in the tank to dissolve the carbon dioxide gas, a batch system or a circulation system for collecting / re-bubbling the carbon dioxide gas is required. However, the device has become large and cannot be used as a home device.

ポンプの吸入側に炭酸ガスを注入して炭酸ガスと浴槽水あるいは足浴槽水に炭酸ガスを溶解する方法においては、炭酸ガスの溶解量を増やそうとすると、炭酸ガスを多量に注入するため、ポンプ内の気相が多くなり、ポンプ自体が機能しなくなるため、高濃度の炭酸泉を生成することが難しく、さらに余分な炭酸ガスを回収しないと、炭酸ガスの消費が多くなりすぎることと、浴槽に多量の炭酸ガスが送られると、入浴者が炭酸ガス中毒を起こす危険性があった。  In the method of injecting carbon dioxide into the suction side of the pump and dissolving the carbon dioxide in the water and bath water or foot bath water, the pump injects a large amount of carbon dioxide when trying to increase the amount of carbon dioxide dissolved. Since the gas phase in the inside increases and the pump itself does not function, it is difficult to produce a high concentration carbonated spring, and unless excessive carbon dioxide is recovered, the consumption of carbon dioxide will be excessive, and the bathtub will When a large amount of carbon dioxide gas was sent, there was a risk that the bather would cause carbon dioxide poisoning.

さらに、一般的な24時間風呂における殺菌システムは、何重ものフィルターや熱湯殺菌装置を設けるなど、装置のコストが増すと共に、消耗品が多くなり使用者に大きな負担となる。  Furthermore, a general 24-hour bath sterilization system is provided with many filters and hot water sterilization devices, which increases the cost of the device and increases the number of consumables, which places a heavy burden on the user.

また、装置内に無隔膜電解槽を設け、電気分解により次亜塩素酸ナトリウム水溶液を生成して、その水溶液を循環される浴槽水に添加して殺菌効果を持たせている物もあるが、次亜塩素酸ナトリウム水溶液はpHが中性領域ではあまり殺菌力が強くないため、ある程度濃度を上げる必要がある。  In addition, there is a thing in which a non-diaphragm electrolytic cell is provided in the apparatus, a sodium hypochlorite aqueous solution is generated by electrolysis, and the aqueous solution is added to the circulated bath water to have a sterilizing effect. The aqueous sodium hypochlorite solution has a high bactericidal activity when the pH is in a neutral range, so it is necessary to increase the concentration to some extent.

厚生労働省の指導では、浴槽内の塩素濃度が0.2〜0.4ppmであることを指針としているが、入浴者数や頻度により塩素濃度が下がる可能性があるので、どうしても濃度を1.0ppm弱の高めに設定することになり、塩素臭が強くなり不快感を覚えることになり、安全と快適の狭間で苦難を強いられているのが現状である。  The guidance of the Ministry of Health, Labor and Welfare is that the chlorine concentration in the bathtub is 0.2 to 0.4 ppm, but the chlorine concentration may decrease depending on the number of bathers and the frequency, so the concentration should be 1.0 ppm. The current situation is that it is set to be slightly weaker, the odor of chlorine becomes stronger, and uncomfortable feeling is felt, and hardship is forced between safety and comfort.

課題を解決するための手段Means for solving the problem

本発明の1つは、浴槽水や足浴槽水をポンプにより炭酸ガスが充填された圧力容器に送水し、送水された浴槽水や足浴槽水を圧力容器内に噴射や散水して炭酸ガスを溶解したのち、再び浴槽や足浴槽に戻す循環システムを形成し、圧力容器内に炭酸ガスを供給すると共に、圧力容器内の炭酸ガスが浴槽に逃げないように、噴射や散水された浴槽水や足浴槽水を圧力容器の底部に所定の水位で貯留するようになされている。  One of the present invention supplies water from a bathtub or footbath to a pressure vessel filled with carbon dioxide gas by a pump, and jets or sprinkles the supplied bathtub water or footbath water into the pressure vessel. After melting, a circulation system is formed to return to the bathtub or foot tub again, and carbon dioxide is supplied into the pressure vessel, and in order to prevent the carbon dioxide in the pressure vessel from escaping to the bathtub, Footbath water is stored at a predetermined water level at the bottom of the pressure vessel.

そして、その循環管路の途中で、次亜塩素酸ナトリウム水溶液や亜塩素酸ナトリウム水溶液を添加するか、循環管路から浴槽水や足浴槽水の一部を取り出し、塩化ナトリウムや岩塩あるいは硫化水素を含有する岩塩で電解物質を溶かして、無隔膜電解槽を用いて次亜塩素酸ナトリウム水溶液を生成して再び循環管路の浴槽水や足浴槽水に添加するものである。  Then, in the middle of the circulation line, add sodium hypochlorite aqueous solution or sodium chlorite aqueous solution, or take out part of bathtub water or footbath water from the circulation line, and add sodium chloride, rock salt or hydrogen sulfide. An electrolytic substance is dissolved with a rock salt containing water, a sodium hypochlorite aqueous solution is generated using a non-diaphragm electrolytic bath, and added again to the bath water and foot bath water of the circulation pipe.

添加された次亜塩素酸ナトリウム水溶液や亜塩素酸ナトリウム水溶液は浴槽水や足浴槽水に溶解させた炭酸ガスの作用で浴槽水や足浴槽水と共に弱酸性となり、中性あるいは弱アルカリ性の場合に比べて、はるかに強い殺菌力を持つと共に塩素臭も軽減され、快適で安全なばかりではなく、天然の炭酸泉がもつ本来の効果も期待できる人工炭酸泉を提供できる方法および装置を提案する。  The added sodium hypochlorite aqueous solution and sodium chlorite aqueous solution become weakly acidic with the bath water and footbath water due to the action of carbon dioxide dissolved in the bath water and footbath water. In comparison, the present invention proposes a method and apparatus that can provide an artificial carbonated spring that has not only a much stronger bactericidal power but also reduced chlorine odor, and is not only comfortable and safe, but also expected to have the original effects of a natural carbonated spring.

本発明の2つ目は、浴槽水や足浴槽水をポンプで24時間循環して、必要なときに炭酸ガスを溶解する方法および装置において、循環管路に濾過器やヒーター4を持ち、さらに次亜塩素酸ナトリウム水溶液や亜塩素酸ナトリウム水溶液を添加する機構を持つもので、必要なときに炭酸ガスを溶解して浴槽水や足浴槽水の炭酸ガス濃度を1000ppm程度に上げる機能を持つと共に、定期的に循環管路の浴槽水や足浴槽水に次亜塩素酸ナトリウム水溶液や亜塩素酸ナトリウム水溶液を添加し、その時に必ず循環管路の浴槽水や足浴槽水に炭酸ガスを溶解して、浴槽水や足浴槽水を弱酸性にすることにより、殺菌力を高める方法および装置を提案する。  The second of the present invention is a method and apparatus for circulating bath water or foot bath water with a pump for 24 hours to dissolve carbon dioxide gas when necessary, and having a filter and a heater 4 in the circulation line, It has a mechanism to add sodium hypochlorite aqueous solution and sodium chlorite aqueous solution, and has the function to dissolve carbon dioxide gas when necessary and raise the carbon dioxide concentration of bathtub water and footbath water to about 1000 ppm Periodically, add sodium hypochlorite aqueous solution or sodium chlorite aqueous solution to the bath water or foot bath water of the circulation pipeline, and at that time, always dissolve carbon dioxide in the bath water or foot bath water of the circulation pipeline Then, the method and apparatus which raise sterilization power by making bathtub water and foot bathtub water weakly acidic are proposed.

本発明の3つ目は、浴槽水や足浴槽水をポンプで24時間循環して、必要な時に炭酸ガスを溶解する方法および装置において、循環管路に濾過器やヒーターを持ち、炭酸ガスを溶解して浴槽水や足浴槽水の炭酸ガス濃度を1000ppm程度に上げる機能を持つと共に、循環管路に圧力容器を迂回する管路を有し、通常は圧力容器への送水を減らし、大半を迂回管路を介して循環し、炭酸ガス濃度を高める場合と、殺菌を行う場合のみ迂回管路を閉鎖して、循環管路の浴槽水や足浴槽水を圧力容器に送水し、さらに、迂回管路に送水しているときは、ポンプの回転数を落として、消費電力や騒音を軽減する方法および装置を提案している。  The third aspect of the present invention is a method and device for circulating bath water or foot bath water with a pump for 24 hours to dissolve carbon dioxide gas when necessary. It has a function to dissolve and raise the carbon dioxide concentration of bathtub water and foot tub water to about 1000 ppm, and it has a pipe line that bypasses the pressure vessel in the circulation pipe, usually reducing the water supply to the pressure vessel, most of it Circulate through the bypass pipe to increase the carbon dioxide concentration and close the bypass pipe only when sterilization is performed, and the bathtub water and foot tub water in the circulation pipe are sent to the pressure vessel. We propose a method and device that reduces power consumption and noise by reducing the number of revolutions of the pump when water is delivered to the pipeline.

図1〜11を用いて、本発明の実施例を説明する。
図1は、本発明の代表的な実施例であり、浴槽1内にフィルター2を有し(もちろん浴槽外で、ポンプ3の手前に設けても良い)、フィルター2の下流に浴槽1から浴槽水を吸い上げるポンプ3を有し、ポンプ3により浴槽1から吸い上げられた浴槽水は、フィルター2で濾過された後、ポンプ3下流のヒーター4で加温される。
An embodiment of the present invention will be described with reference to FIGS.
FIG. 1 shows a typical embodiment of the present invention, which has a filter 2 in the bathtub 1 (of course, it may be provided outside the bathtub and before the pump 3). The bathtub water sucked up from the bathtub 1 by the pump 3 is sucked up from the bathtub 1 and filtered by the filter 2 and then heated by the heater 4 downstream of the pump 3.

そして、ヒーター4下流の分岐部5で、3つの管路101,102,103に分岐送水される。管路102に送水された浴槽水は電動開閉バルブ43が開放されると、岩塩などが入った電解質添加部6で電解質を溶解し、無隔膜電解槽7に送水される。  Then, the water is branched and fed to the three pipe lines 101, 102, and 103 at the branch portion 5 downstream of the heater 4. When the electric opening / closing valve 43 is opened, the bathtub water fed to the pipe line 102 dissolves the electrolyte in the electrolyte addition unit 6 containing rock salt or the like, and is fed to the non-diaphragm electrolytic cell 7.

さらに、無隔膜電解槽7で電気分解されて次亜塩素酸ナトリウム水溶液となり、管路110を介して添加部8で浴槽から吸い上げられた浴槽水に合流する。このとき、無隔膜電解槽7を流れる流量が多いと、電解効率が低下するため、管路110には絞り47が設けられ、電解流量を適正な流量に制限する。  Further, it is electrolyzed in the non-diaphragm electrolytic cell 7 to become a sodium hypochlorite aqueous solution, and merges with the bath water sucked up from the bathtub by the addition unit 8 through the conduit 110. At this time, if the flow rate flowing through the diaphragmless electrolytic cell 7 is large, the electrolysis efficiency is lowered. Therefore, a throttle 47 is provided in the pipe line 110 to limit the electrolytic flow rate to an appropriate flow rate.

一方、管路101に送水された浴槽水は逆止弁49を通って、圧力容器12上部の空間9に送水され、噴射孔10から炭酸ガスが充填された空間11に噴射され、炭酸ガスを溶解して炭酸泉となる。この時、噴射孔10からの噴射流は、少なくとも2つの噴射孔10からの噴射がお互いに衝突するようにされていると、噴射された浴槽水が空間11内で細かい水滴となり、炭酸ガスの溶解が容易に出来て、さらに良い。また、噴射孔10は単なる穴になっているが、噴射された噴射流を霧状にする噴霧ノズルであっても良い。  On the other hand, the bathtub water sent to the pipe line 101 passes through the check valve 49, is sent to the space 9 above the pressure vessel 12, and is injected from the injection hole 10 into the space 11 filled with carbon dioxide gas. Dissolves to become carbonated spring. At this time, the jet flow from the injection hole 10 is such that when the injection from at least two injection holes 10 collides with each other, the injected bath water becomes fine water droplets in the space 11, and the carbon dioxide gas It is easier to dissolve and even better. Moreover, although the injection hole 10 is a mere hole, the spray nozzle which makes the injected injection flow into a mist form may be sufficient.

また、炭酸ガスは、炭酸ガスボンベ19から手動バルブ20を介して、減圧弁21および22で減圧されたのち圧力容器12内の空間11に大気圧以上の所定の圧力で供給される。  The carbon dioxide gas is decompressed by the decompression valves 21 and 22 from the carbon dioxide gas cylinder 19 through the manual valve 20 and then supplied to the space 11 in the pressure vessel 12 at a predetermined pressure equal to or higher than atmospheric pressure.

圧力容器12内で炭酸ガスを含有した浴槽水は、炭酸泉となり圧力容器12の底部に貯留し、排水管路106に設けられた絞り27を介して、合流部28を通って排水管路108により浴槽に戻される。  The bathtub water containing carbon dioxide gas in the pressure vessel 12 becomes a carbonated spring and is stored at the bottom of the pressure vessel 12, and through the constriction 27 provided in the drainage pipe 106, through the junction 28, and by the drainage pipe 108. Returned to the bathtub.

管路103に送水された浴槽水は電動開閉バルブ29が開放されると、合流部28で圧力容器12からの排水に合流して排水管路108を通って浴槽に戻る。
逆止弁49は、ポンプ3が停止した場合や、電動開閉バルブ29が開放されて浴槽水が管路103に送水されたときに管路101内の圧力が低下することにより、圧力容器12内の炭酸ガスが管路101を逆流するのを防止する。
When the electric opening / closing valve 29 is opened, the bathtub water sent to the pipe 103 joins the drainage from the pressure vessel 12 at the junction 28 and returns to the bathtub through the drain pipe 108.
The check valve 49 is provided in the pressure vessel 12 when the pump 3 is stopped or when the electric on-off valve 29 is opened and the bath water is supplied to the pipe 103 so that the pressure in the pipe 101 decreases. The carbon dioxide gas is prevented from flowing back through the pipe 101.

次に、準備動作について説明する。
まず、電動開閉バルブ23、29、43を閉じ、電動開閉バルブ25を開放する。管路102と103の電動開閉バルブ43と29を閉じた状態で、ポンプにより送水された浴槽水は全てが管路101に送水され、さらに、圧力容器12の空間9に送られ、噴射孔10から空間11に噴射送水され、圧力容器12の下部に貯留する。
Next, the preparation operation will be described.
First, the electric opening / closing valves 23, 29, 43 are closed, and the electric opening / closing valve 25 is opened. In the state where the electric open / close valves 43 and 29 of the pipe lines 102 and 103 are closed, all of the bathtub water fed by the pump is fed to the pipe line 101 and further sent to the space 9 of the pressure vessel 12, and the injection hole 10 Is injected into the space 11 and stored in the lower part of the pressure vessel 12.

ここで、排水管路106に設けられた絞り27により、空間11の圧力が大気圧のときは、噴射孔10から空間11に噴射送水される浴槽水よりも圧力容器から排出される浴槽水が少なくなり、空間11の圧力が所定の圧力以上になると、噴射孔10から空間11に噴射送水される浴槽水よりも圧力容器から排出される浴槽水が多くなるようになされている。  Here, when the pressure of the space 11 is atmospheric pressure by the throttle 27 provided in the drain pipe 106, the bathtub water discharged from the pressure vessel is more than the bathtub water jetted and fed from the injection hole 10 to the space 11. When the pressure in the space 11 becomes equal to or higher than the predetermined pressure, the amount of bathtub water discharged from the pressure vessel is larger than the amount of bathtub water sprayed and fed from the injection hole 10 to the space 11.

これにより、圧力容器内の炭酸泉の水位が上昇すると共に、フロート13が上昇し、空間11内の空気は管路105を通って、合流部26を介して排水管路108に送られ、圧力容器12から排出される炭酸泉に混ざり浴槽1内に排出される。フロート13にはマグネット14が取り付けられており、このマグネット14により、圧力容器12の側面に設けられたリミットスイッチ15、16,17,18が順番に反応する。  As a result, the water level of the carbonated spring in the pressure vessel rises, the float 13 rises, and the air in the space 11 passes through the pipe line 105 and is sent to the drainage pipe line 108 via the merging portion 26. 12 is mixed with the carbonated spring discharged from the tub 12 and discharged into the bathtub 1. A magnet 14 is attached to the float 13, and the limit switch 15, 16, 17, 18 provided on the side surface of the pressure vessel 12 reacts in order by the magnet 14.

最も高い位置のリミットスイッチ18が反応したら、電動開閉バルブ25を閉鎖すると共に、電動開閉バルブ29を開放し、ポンプ3により送水される浴槽水を管路103を通して浴槽に戻す循環運転にすると共に、ポンプの回転数を下げて、初期動作が完了したことを表示する。このとき、ポンプの回転数を下げても、管路105の抵抗が少ないため、ポンプのよる循環水量は減少せず、場合によっては、全量を圧力容器12に送水しているときよりも増大する。そして、消費電力および騒音ともに軽減される。この一連の動作により、空間11内の空気が完全に排出された状態となる。  When the limit switch 18 at the highest position reacts, the electric opening / closing valve 25 is closed, the electric opening / closing valve 29 is opened, and the bathtub water fed by the pump 3 is returned to the bathtub through the conduit 103, and the circulation operation is performed. Decrease the pump speed and display that the initial operation is complete. At this time, even if the number of revolutions of the pump is reduced, the resistance of the pipe 105 is small, so the amount of circulating water by the pump does not decrease, and in some cases, the total amount increases compared to when the water is fed to the pressure vessel 12 . Both power consumption and noise are reduced. By this series of operations, the air in the space 11 is completely exhausted.

この時、圧力容器への炭酸ガスの供給は行われていないが、ポンプ3により送水される浴槽水の一部は管路101を介して、圧力容器12にも送水されており、圧力容器内に浴槽水が淀むことが無いようになされている。  At this time, carbon dioxide gas is not supplied to the pressure vessel, but part of the bath water supplied by the pump 3 is also supplied to the pressure vessel 12 via the pipe 101, There is no tub water in the bathroom.

次に、高濃度の炭酸泉を生成する動作を説明する。
炭酸泉の生成ボタン(図示せず)が押されると、ポンプの回転数を所定の回転に上げると共に、電動開閉バルブ29を閉鎖して、ポンプ3から送水される浴槽水の全てを圧力容器12へ送水する。さらに、リミットスイッチ18が反応していない場合は、電動開閉バルブ25を開放しリミットスイッチ18が反応するまで待ち、電動開閉バルブ25を閉鎖すると共に、電動開閉バルブ23を開放して炭酸ガスボンベ19より炭酸ガスを圧力容器12内の空間11へ大気圧以上の所定の圧力で供給する。これにより、空間11内の気体は、ほぼ炭酸ガスだけになる。
Next, the operation | movement which produces | generates a high concentration carbonated spring is demonstrated.
When a carbonated spring generation button (not shown) is pressed, the rotational speed of the pump is increased to a predetermined value, and the electric on-off valve 29 is closed, and all of the bathtub water fed from the pump 3 is sent to the pressure vessel 12. Send water. Further, when the limit switch 18 is not responding, the electric opening / closing valve 25 is opened and waits until the limit switch 18 reacts. Carbon dioxide gas is supplied to the space 11 in the pressure vessel 12 at a predetermined pressure equal to or higher than atmospheric pressure. Thereby, the gas in the space 11 is substantially only carbon dioxide.

圧力容器12内の水位は、供給された炭酸ガスの圧力により徐々に下がり、それに伴いフロート13も下降して、リミットスイッチ17、16の順に反応する。リミットスイッチ16が反応したら、電動開閉バルブ23を閉鎖して炭酸ガスの供給を止める。すると、噴射孔10から噴射された浴槽水が空間11内の炭酸ガスを溶解して空間11内の圧力が徐々に下がり、水位は再び上昇する。リミットスイッチ17が反応したら、再び電動開閉バルブ23を開放して炭酸ガスを供給する。すると、再び水位が下降し始める。  The water level in the pressure vessel 12 is gradually lowered by the pressure of the supplied carbon dioxide gas, and the float 13 is also lowered accordingly, and reacts in the order of the limit switches 17 and 16. When the limit switch 16 reacts, the electric open / close valve 23 is closed to stop the supply of carbon dioxide gas. Then, the bathtub water injected from the injection hole 10 dissolves the carbon dioxide gas in the space 11, the pressure in the space 11 gradually decreases, and the water level increases again. When the limit switch 17 reacts, the electric open / close valve 23 is opened again to supply carbon dioxide gas. Then, the water level begins to fall again.

これらの動作により、圧力容器12内の水位はリミットスイッチ16と17の間に保たれ、生成された炭酸泉は排水管路106および108を通って浴槽に戻される。  By these operations, the water level in the pressure vessel 12 is maintained between the limit switches 16 and 17, and the generated carbonated spring is returned to the bathtub through the drain lines 106 and 108.

浴槽水はポンプ3により再び吸引され、炭酸ガスを溶解した後に浴槽に戻され、この繰り返しにより浴槽水全体の炭酸ガス濃度が上昇し、高濃度の炭酸泉となる。  The bath water is sucked again by the pump 3 and dissolved in the carbon dioxide, and then returned to the bath. By repeating this, the concentration of carbon dioxide in the whole bath water rises and becomes a high concentration carbonated spring.

次に、高濃度の炭酸泉を生成する場合のもう一つの動作について説明する。
この場合は、ポンプ3により全ての浴槽水が圧力容器12に送水されていて、圧力容器12に炭酸ガスが圧力供給されている状態でも、排水管路106に設けられた絞り27により、噴射孔10から噴射される浴槽水が圧力容器12から排水される浴槽水よりも多くなるようになされている。
Next, another operation for generating a high-concentration carbonated spring will be described.
In this case, even if all the bathtub water is sent to the pressure vessel 12 by the pump 3 and the carbon dioxide gas is supplied to the pressure vessel 12 by pressure, the nozzle 27 is provided by the throttle 27 provided in the drain pipe 106. The bathtub water sprayed from 10 becomes larger than the bathtub water drained from the pressure vessel 12.

炭酸泉の生成ボタン(図示せず)が押されると、ポンプの回転数を所定の回転に上げる。そして、リミットスイッチ18が反応していない場合は、電動開閉バルブ25を開放し、リミットスイッチ18が反応するまで待ち、電動開閉バルブ25を閉鎖すると共に電動開閉バルブ23を開放して炭酸ガスボンベ19より炭酸ガスを圧力容器12内の空間11へ大気圧以上の所定の圧力で供給するとともに、電動開閉バルブ29を適度に開放して、管路103へも送水する。  When a carbonated spring generation button (not shown) is pressed, the pump speed is increased to a predetermined value. If the limit switch 18 is not responding, the electric open / close valve 25 is opened, waits until the limit switch 18 reacts, the electric open / close valve 25 is closed, and the electric open / close valve 23 is opened from the carbon dioxide cylinder 19. Carbon dioxide gas is supplied to the space 11 in the pressure vessel 12 at a predetermined pressure equal to or higher than atmospheric pressure, and the electric open / close valve 29 is appropriately opened to supply water to the pipe 103.

すると、圧力容器12へ送水される浴槽水の水量が減少するので、圧力容器12内の水位は徐々に下がり、それに伴いフロート13も下降して、リミットスイッチ17、16の順に反応する。リミットスイッチ16が反応したら、電動開閉バルブ29を閉鎖してポンプ3により送水される浴槽水を全て圧力容器12に送水する。すると、圧力容器12に送水される浴槽水の水量が増加し水位は再び上昇する。リミットスイッチ17が反応したら、再び電動開閉バルブ29を適度に開放して浴槽水を管路103にも送水する。すると、再び水位が下降し始める。  Then, since the amount of bathtub water sent to the pressure vessel 12 is reduced, the water level in the pressure vessel 12 is gradually lowered, and the float 13 is also lowered accordingly, and reacts in the order of the limit switches 17 and 16. When the limit switch 16 reacts, the electric open / close valve 29 is closed and all the bathtub water supplied by the pump 3 is supplied to the pressure vessel 12. As a result, the amount of bathtub water fed to the pressure vessel 12 increases and the water level rises again. When the limit switch 17 reacts, the electric on-off valve 29 is appropriately opened again to send the bath water to the pipe 103. Then, the water level begins to fall again.

これらの動作により、圧力容器12内の水位はリミットスイッチ16と17な間に保たれ、生成された炭酸泉は排水管路106および108を通って浴槽に戻される。  By these operations, the water level in the pressure vessel 12 is maintained between the limit switches 16 and 17, and the generated carbonated spring is returned to the bathtub through the drain lines 106 and 108.

浴槽水はポンプ3により吸引され、炭酸ガスを溶解した後に浴槽に戻され、この繰り返しにより浴槽水全体の炭酸ガス濃度が上昇し、高濃度の炭酸泉となる。  The bathtub water is sucked by the pump 3 and is returned to the bathtub after dissolving the carbon dioxide gas. By repeating this, the carbon dioxide gas concentration of the whole bathtub water rises and becomes a high concentration carbonated spring.

また、上記2つの動作における高濃度炭酸泉生成状態においては、常に所定の時間だけ電動開閉バルブ43を開放して、次亜塩素酸ナトリウム水溶液を生成して浴槽水に添加して、浴槽水の殺菌を行うと良い。  Further, in the high-concentration carbonated spring generation state in the above two operations, the electric on-off valve 43 is always opened for a predetermined time to generate a sodium hypochlorite aqueous solution and add it to the bath water to sterilize the bath water. Good to do.

これとは別に、浴槽水の殺菌状態を維持するために、所定の時間間隔で以下に記載する殺菌運転を行う。すなわち、ポンプの回転数を所定の回転に上げると共に、電動開閉バルブ29を閉鎖して、ポンプ3から送水される浴槽水の全てを圧力容器12へ送水する。さらに、リミットスイッチ18が反応していない場合は、電動開閉バルブ25を開放して、リミットスイッチ18が反応するまで待ち、電動開閉バルブ25を閉鎖すると共に、電動開閉バルブ23と43を開放して、炭酸ガスボンベ19より炭酸ガスを圧力容器12内の空間11へ大気圧以上の所定の圧力で供給すると共に、浴槽水の一部を管路102へ送り無隔膜電解槽で次亜塩素酸ナトリウム水溶液を生成して、添加部8により浴槽水に添加する。  Separately, in order to maintain the sterilized state of the bath water, the sterilization operation described below is performed at predetermined time intervals. That is, while increasing the rotation speed of the pump to a predetermined rotation, the electric on-off valve 29 is closed, and all the bath water supplied from the pump 3 is supplied to the pressure vessel 12. Further, when the limit switch 18 is not responding, the electric opening / closing valve 25 is opened, waits until the limit switch 18 reacts, the electric opening / closing valve 25 is closed, and the electric opening / closing valves 23 and 43 are opened. In addition, carbon dioxide gas is supplied from the carbon dioxide gas cylinder 19 to the space 11 in the pressure vessel 12 at a predetermined pressure equal to or higher than atmospheric pressure, and a part of the bath water is sent to the conduit 102 and the sodium hypochlorite aqueous solution in the diaphragm electrolyzer. Is added to the bath water by the addition unit 8.

次亜塩素酸ナトリウム水溶液が添加された浴槽水はポンプ3により圧力容器12に送られ、炭酸ガスが添加されて弱酸性になり、殺菌効果を増強されて再び浴槽に戻される。また、この時、圧力容器12内の水位維持は前記2つの方法いずれかで行う。  The bath water to which the sodium hypochlorite aqueous solution has been added is sent to the pressure vessel 12 by the pump 3, and becomes carbonic acid by being added with carbon dioxide gas. The bactericidal effect is enhanced and the bath water is returned to the bath again. At this time, the water level in the pressure vessel 12 is maintained by either of the two methods.

この場合、高濃度炭酸泉を生成することが目的ではなく、浴槽水を弱酸性にすることが目的なので、所定の時間経過後に、ポンプの回転数を下げると共に、電動開閉バルブ23を閉鎖して炭酸ガスの供給を止め、電動開閉バルブ29を開放して浴槽水の大半を管路103に送る循環動作に戻す。  In this case, the purpose is not to produce a high-concentration carbonated spring but to make the bath water weakly acidic. Therefore, after a predetermined time has elapsed, the pump speed is lowered and the electric on-off valve 23 is closed to close the carbonated water. The supply of gas is stopped, and the electric on-off valve 29 is opened to return to the circulation operation in which most of the bath water is sent to the pipe 103.

ただし、電動開閉バルブ43は開放状態を保ち、次亜塩素酸ナトリウム水溶液の添加は続ける。そして、さらに所定の時間が経過したのち電動開閉バルブ43を閉鎖して次亜塩素酸ナトリウム水溶液の生成と添加を停止する。  However, the electric on-off valve 43 is kept open and the addition of the sodium hypochlorite aqueous solution is continued. Then, after a predetermined time has passed, the electric on-off valve 43 is closed to stop the generation and addition of the sodium hypochlorite aqueous solution.

もちろん、必要に応じて、前記次亜塩素酸ナトリウム水溶液の添加を行っている間は常に炭酸泉の生成を行っても良いし、間欠的に炭酸泉の生成を行っても良い。この殺菌運転により、浴槽水は常に殺菌されてクリーンな状態を保つことが出来る。  Of course, if necessary, the carbonated spring may be generated while the sodium hypochlorite aqueous solution is added, or the carbonated spring may be intermittently generated. By this sterilization operation, the bathtub water is always sterilized and can be kept clean.

次に図2は、図1における管路103がない場合の簡易型の実施例である。
この場合、無隔膜電解槽7に接続される管路202に設けられている電動開閉バルブ43が閉鎖している時は、ポンプ3により送水された浴槽水は全て圧力容器12に送られる。
Next, FIG. 2 is a simplified embodiment in the case where the pipe 103 in FIG. 1 is not provided.
In this case, when the electric on-off valve 43 provided in the pipe line 202 connected to the non-diaphragm electrolytic cell 7 is closed, all the bath water fed by the pump 3 is sent to the pressure vessel 12.

無隔膜電解槽における次亜塩素酸ナトリウム水溶液の生成、圧力容器12への炭酸ガスの供給、圧力容器12内への噴射孔10を介した噴射動作については基本的に図1で説明した内容と同じである。  The generation of the sodium hypochlorite aqueous solution in the diaphragmless electrolytic cell, the supply of carbon dioxide gas to the pressure vessel 12, and the injection operation through the injection hole 10 into the pressure vessel 12 are basically the same as those described in FIG. The same.

次に、準備動作について説明する。
まず、電動開閉バルブ23、43を閉じ、電装開閉バルブ25を開放する。管路102の電動開閉バルブ43を閉じた状態で、ポンプにより送水された浴槽水は全て管路101に送水され、さらに、圧力容器12の空間9に送られ、噴射孔10から空間11に噴射送水され、圧力容器12の下部に貯留する。
Next, the preparation operation will be described.
First, the electric on-off valves 23 and 43 are closed, and the electric equipment on-off valve 25 is opened. In the state where the electric opening / closing valve 43 of the pipe line 102 is closed, all the bathtub water fed by the pump is fed to the pipe line 101 and further sent to the space 9 of the pressure vessel 12 and injected into the space 11 from the injection hole 10. Water is fed and stored in the lower part of the pressure vessel 12.

ここで、排水管路106に設けられた絞り27により、空間11の圧力が大気圧のときは、噴射孔10から空間11に噴射送水される浴槽水よりも圧力容器から排出される浴槽水が少なくなり、空間11の圧力が所定の圧力以上になると、噴射孔10から空間11に噴射送水される浴槽水よりも圧力容器から排出される浴槽水が多くなるようになされている。  Here, when the pressure of the space 11 is atmospheric pressure by the throttle 27 provided in the drain pipe 106, the bathtub water discharged from the pressure vessel is more than the bathtub water jetted and fed from the injection hole 10 to the space 11. When the pressure in the space 11 becomes equal to or higher than the predetermined pressure, the amount of bathtub water discharged from the pressure vessel is larger than the amount of bathtub water sprayed and fed from the injection hole 10 to the space 11.

これにより、圧力容器内の炭酸泉の水位が上昇すると共に、フロート13が上昇し、空間11内の空気は管路105を通って、合流部26を介して排水管路108に送られ、圧力容器12から排出される炭酸泉に混ざり浴槽1内に排出される。フロート13にはマグネット14が取り付けられており、このマグネット14により、圧力容器12の側面に設けられたリミットスイッチ15、16,17,18が順番に反応する。これにより、空間11内の空気が完全に排出された状態となる。リミットスイッチ18が反応したら、電動開閉バルブ25を閉鎖し、初期動作を完了したことを表示する。  As a result, the water level of the carbonated spring in the pressure vessel rises, the float 13 rises, and the air in the space 11 passes through the pipe line 105 and is sent to the drainage pipe line 108 via the merging portion 26. 12 is mixed with the carbonated spring discharged from the tub 12 and discharged into the bathtub 1. A magnet 14 is attached to the float 13, and the limit switch 15, 16, 17, 18 provided on the side surface of the pressure vessel 12 reacts in order by the magnet 14. As a result, the air in the space 11 is completely exhausted. When the limit switch 18 reacts, the electric open / close valve 25 is closed to indicate that the initial operation has been completed.

次に、高濃度の炭酸泉を生成する動作を説明する。
炭酸泉の生成ボタン(図示せず)が押されると、リミットスイッチ18が反応していない場合は、電動開閉バルブ25を開放して、リミットスイッチ18が反応するまで待ち、電動開閉バルブ25を閉鎖すると共に、電動開閉バルブ23を開放して炭酸ガスボンベ19より炭酸ガスを圧力容器12内の空間11へ大気圧以上の所定の圧力で供給する。これにより、空間11内の気体は、ほぼ炭酸ガスだけになる。
Next, the operation | movement which produces | generates a high concentration carbonated spring is demonstrated.
When a carbonated spring generation button (not shown) is pressed, if the limit switch 18 is not responding, the electric open / close valve 25 is opened, waits until the limit switch 18 reacts, and the electric open / close valve 25 is closed. At the same time, the electric open / close valve 23 is opened, and carbon dioxide is supplied from the carbon dioxide cylinder 19 to the space 11 in the pressure vessel 12 at a predetermined pressure equal to or higher than atmospheric pressure. Thereby, the gas in the space 11 is substantially only carbon dioxide.

圧力容器12内の水位は、供給された炭酸ガスの圧力により徐々に下がり、それに伴いフロート13も下降して、リミットスイッチ17、16の順に反応する。リミットスイッチ16が反応したら、電動開閉バルブ23を閉鎖して炭酸ガスの供給を止める。すると、噴射孔10から噴射された浴槽水が空間11内の炭酸ガスを溶解して空間11の圧力が徐々に下がり、水位は再び上昇する。リミットスイッチ17が反応したら、再び電動開閉バルブ23を開放して炭酸ガスを供給する。すると、再び水位が下降し始める。  The water level in the pressure vessel 12 is gradually lowered by the pressure of the supplied carbon dioxide gas, and the float 13 is also lowered accordingly, and reacts in the order of the limit switches 17 and 16. When the limit switch 16 reacts, the electric open / close valve 23 is closed to stop the supply of carbon dioxide gas. Then, the bathtub water injected from the injection hole 10 dissolves the carbon dioxide gas in the space 11, the pressure in the space 11 gradually decreases, and the water level increases again. When the limit switch 17 reacts, the electric open / close valve 23 is opened again to supply carbon dioxide gas. Then, the water level begins to fall again.

これらの動作により、圧力容器12内の水位はリミットスイッチ16と17な間に保たれ、生成された炭酸泉は排水管路106および108を通って浴槽に戻される。  By these operations, the water level in the pressure vessel 12 is maintained between the limit switches 16 and 17, and the generated carbonated spring is returned to the bathtub through the drain lines 106 and 108.

浴槽水はポンプ3により再び吸引され、炭酸ガスを溶解した後に浴槽に戻され、この繰り返しにより浴槽温水全体の炭酸ガス濃度が上昇し、高濃度の炭酸泉となる。  The bath water is sucked again by the pump 3 and is returned to the bath after dissolving the carbon dioxide gas. By repeating this, the carbon dioxide gas concentration in the whole bath hot water rises to become a high-concentration carbonated spring.

また、上記の動作における高濃度炭酸泉生成状態においては、常に所定の時間だけ電動開閉バルブ43を開放して、次亜塩素酸ナトリウム水溶液を生成して浴槽水に添加して、浴槽水の殺菌を行うと良い。  Moreover, in the state of high concentration carbonated spring generation in the above operation, the electric on-off valve 43 is always opened for a predetermined time, and a sodium hypochlorite aqueous solution is generated and added to the bath water to sterilize the bath water. Good to do.

これとは別に、浴槽水の殺菌状態を維持するために、所定の時間間隔で以下に記載する殺菌運転を行う。すなわち、リミットスイッチ18が反応していない場合は、電動開閉バルブ25を開放して、リミットスイッチ18が反応するまで待ち、電動開閉バルブ25を閉鎖すると共に、電動開閉バルブ23と43を開放して、炭酸ガスボンベ19より炭酸ガスを圧力容器12内の空間11へ大気圧以上の所定の圧力で供給すると共に、浴槽水の一部を管路102へ送り無隔膜電解槽で次亜塩素酸ナトリウム水溶液を生成して、添加部8により浴槽水に添加する。
次亜塩素酸ナトリウム水溶液が添加された浴槽水はポンプ3により圧力容器12に送られ、炭酸ガスが添加されて弱酸性になり、殺菌効果を増強されて再び浴槽に戻される。
Separately, in order to maintain the sterilized state of the bath water, the sterilization operation described below is performed at predetermined time intervals. That is, when the limit switch 18 is not responding, the electric opening / closing valve 25 is opened, waiting until the limit switch 18 reacts, the electric opening / closing valve 25 is closed, and the electric opening / closing valves 23 and 43 are opened. In addition, carbon dioxide gas is supplied from the carbon dioxide gas cylinder 19 to the space 11 in the pressure vessel 12 at a predetermined pressure equal to or higher than atmospheric pressure, and a part of the bath water is sent to the conduit 102 and the sodium hypochlorite aqueous solution in the diaphragm electrolyzer. Is added to the bath water by the addition unit 8.
The bath water to which the sodium hypochlorite aqueous solution has been added is sent to the pressure vessel 12 by the pump 3, and becomes carbonic acid by being added with carbon dioxide gas. The bactericidal effect is enhanced and the bath water is returned to the bath again.

この場合、高濃度炭酸泉を生成することが目的ではなく、浴槽水を弱酸性にすることが目的なので、所定の時間経過後に、電動開閉バルブ23を閉鎖して炭酸ガスの供給を止める。  In this case, the purpose is not to produce a high-concentration carbonated spring, but to make the bath water weakly acidic. Therefore, after a predetermined time has elapsed, the electric on-off valve 23 is closed to stop the supply of carbon dioxide gas.

ただし、電動開閉バルブ43は開放状態を保ち、次亜塩素酸ナトリウム水溶液の添加は続ける。そして、所定の時間が経過したのち電動開閉バルブ43を閉鎖して次亜塩素酸ナトリウム水溶液の生成と添加を停止する。  However, the electric on-off valve 43 is kept open and the addition of the sodium hypochlorite aqueous solution is continued. Then, after a predetermined time has elapsed, the electric on-off valve 43 is closed to stop the generation and addition of the sodium hypochlorite aqueous solution.

もちろん、必要に応じて、前記次亜塩素酸ナトリウム水溶液の添加を行っている間は常に炭酸ガスの供給を行っても良いし、完結的に炭酸泉の生成を行っても良い。この殺菌運転により、浴槽の温水は常に殺菌されてクリーン状態を保つことが出来る。  Of course, if necessary, the carbon dioxide gas may be always supplied during the addition of the sodium hypochlorite aqueous solution, or the carbonated spring may be completely generated. By this sterilization operation, the hot water in the bathtub is always sterilized and can be kept clean.

以下は図1および図2の実施例に共通の事項である。
炭酸泉生成運転時に圧力容器12内の水位が上がり、リミットスイッチ18が反応すると、供給される炭酸ガスの圧力が不足しているとして、炭酸ガス供給不足の警告を表示する機能も有している。
The following items are common to the embodiments of FIGS.
If the water level in the pressure vessel 12 rises during the carbonated spring generation operation and the limit switch 18 reacts, it also has a function of displaying a carbon dioxide supply shortage warning that the pressure of the supplied carbon dioxide gas is insufficient.

また、フロート13の底部に弾性体45を有し、万が一圧力容器12内の水位が下降してフロートが圧力容器12の最下部まで下がっても、弾性体45により圧力容器底部の排水口46を閉鎖し、圧力容器12内の炭酸ガスが浴槽1に排出するのを防ぐ。  In addition, an elastic body 45 is provided at the bottom of the float 13, and even if the water level in the pressure vessel 12 drops and the float falls to the bottom of the pressure vessel 12, the elastic body 45 allows the drain 46 at the bottom of the pressure vessel to be opened. It closes and prevents the carbon dioxide gas in the pressure vessel 12 from being discharged into the bathtub 1.

また、前記無隔膜電解槽で次亜塩素酸ナトリウム水溶液を生成している状態で、電解電流を検知し、その電流が所定の電流地よりも低い場合は、電解質の溶解が少ない、すなわち、電解質が電解質添加部内に無いことを表示する機能も有している。  Further, in the state where the sodium hypochlorite aqueous solution is generated in the diaphragmless electrolytic cell, the electrolytic current is detected, and when the current is lower than a predetermined current location, the electrolyte is less dissolved, that is, the electrolyte There is also a function of displaying that there is no electrolyte added portion.

さらに、前記無隔膜電解槽の電極に印加される極性を定期的に入れ換えることにより、電極のセルフクリーニングを行う機能も有している。また、電解質として、硫化水素を含有する岩塩などを用いると、炭酸ガスのみならず、硫化ガスが僅かに溶けた炭酸泉を生成することができ、さらに入浴効果が増すことも期待できる。  Furthermore, it has a function of performing self-cleaning of the electrode by periodically changing the polarity applied to the electrode of the diaphragm membrane electrolytic cell. Further, when rock salt containing hydrogen sulfide is used as the electrolyte, not only carbon dioxide gas but also carbonate spring in which sulfide gas is slightly dissolved can be generated, and further, the bathing effect can be expected to increase.

さらに、管路102を電動開閉バルブ43の手前で2つに分岐し、電動開閉バルブ43を持たない管路を電解質添加部と無隔膜電解槽7の間に接続し、電動開閉バルブ43が閉鎖しているときは、電解質添加部6への送水を遮断し、無隔膜電解槽へは、常時送水されている状態を維持して、無隔膜電解槽に定期的に電圧を印加してその電流値によりポンプにより浴槽水が送水されているかどうかをチェックする送水検知機能を持たせても良い。  Further, the pipe line 102 is branched into two before the electric opening / closing valve 43, and a pipe line not having the electric opening / closing valve 43 is connected between the electrolyte addition part and the diaphragm electrolyzer 7, so that the electric opening / closing valve 43 is closed. When the water is flowing, the water supply to the electrolyte addition unit 6 is shut off, the state where the water is always supplied to the diaphragm electrolyzer is maintained, and the current is applied to the diaphragm electrolyzer periodically by applying a voltage. You may give the water supply detection function which checks whether the bathtub water is being pumped by the value by the pump.

図1および2で挙げた高濃度炭酸泉を生成する動作の他に、電動開閉バルブ23を開放状態に保ち、管路103を有する場合は電動開閉バルブ29を閉鎖状態に保ち、リミットスイッチ17が反応したらポンプ3を停止し、リミットスイッチ16が反応したらポンプ3を運転して送水再開して圧力容器12内の水位をリミットスイッチ16と17の間に保っても良いが、ポンプの運転/停止が頻繁となるため、あまり好ましい方法ではない。  In addition to the operation of generating the high-concentration carbonated spring shown in FIGS. 1 and 2, the electric open / close valve 23 is kept open, and when the pipe 103 is provided, the electric open / close valve 29 is kept closed, and the limit switch 17 reacts. Then, the pump 3 is stopped, and when the limit switch 16 reacts, the pump 3 is operated to resume water supply and the water level in the pressure vessel 12 may be maintained between the limit switches 16 and 17, but the pump operation / stop is Because it becomes frequent, it is not a preferable method.

次に、図3〜8を用いて次亜塩素酸ナトリウム水溶液添加のいくつかの方法について説明する。図3〜8は図1と次亜塩素酸ナトリウム水溶液の添加方法が異なるだけで、その他の動作に関しては図1で説明した動作と同じである。また、図2に示すように、管路103を省略した簡易型でも良い。  Next, several methods for adding a sodium hypochlorite aqueous solution will be described with reference to FIGS. 3 to 8 differ from FIG. 1 only in the method of adding the sodium hypochlorite aqueous solution, and the other operations are the same as those described in FIG. Further, as shown in FIG. 2, a simplified type in which the pipe 103 is omitted may be used.

図3においては、次亜塩素酸ナトリウム水溶液を貯留したタンク30を有し、タンク30からポンプ31により次亜塩素酸ナトリウム水溶液を管路111を介して吸引し、ポンプ3により送水された浴槽水にポンプ31の圧力を利用して添加部32を介して次亜塩素酸ナトリウムス水溶液を添加する実施例を示す。  In FIG. 3, a tank 30 storing a sodium hypochlorite aqueous solution is provided, and the sodium hypochlorite aqueous solution is sucked from the tank 30 by a pump 31 through a pipe line 111, and bath water is supplied by the pump 3. An embodiment in which the sodium hypochlorite aqueous solution is added through the adding section 32 using the pressure of the pump 31 is shown.

ここでは、分岐部48の上流で添加しているが、圧力容器12の直前や圧力容器12の排水管路106や108において添加しても良い。  Here, it is added upstream of the branch 48, but it may be added immediately before the pressure vessel 12 or in the drain pipes 106 and 108 of the pressure vessel 12.

図4は、次亜塩素酸ナトリウム水溶液をスプレー缶のような圧力容器44に加圧剤とともに充填し、その圧力を利用して添加する実施例を示す。  FIG. 4 shows an embodiment in which a sodium hypochlorite aqueous solution is filled in a pressure vessel 44 such as a spray can together with a pressurizing agent and added using the pressure.

圧力容器44は管路111と添加部32を介して管路101と接続されており、管路111には電動開閉バルブ33が設けられている。電動開閉バルブ33を開放すると、圧力容器44の圧力により、次亜塩素酸ナトリウム水溶液が添加部32を介してポンプ3により送水された浴槽水に添加される。  The pressure vessel 44 is connected to the pipe line 101 via the pipe line 111 and the addition unit 32, and the electric line valve 111 is provided with the electric opening / closing valve 33. When the electric opening / closing valve 33 is opened, the sodium hypochlorite aqueous solution is added to the bath water fed by the pump 3 through the addition section 32 by the pressure of the pressure vessel 44.

ここでは、分岐部48の上流で添加しているが、圧力容器12の直前や圧力容器12の排水管路106や108において添加しても良い。  Here, it is added upstream of the branch 48, but it may be added immediately before the pressure vessel 12 or in the drain pipes 106 and 108 of the pressure vessel 12.

図5は、次亜塩素酸ナトリウム水溶液の添加をポンプ3の上流側の負圧を利用して行う実施例を示す。  FIG. 5 shows an embodiment in which the sodium hypochlorite aqueous solution is added using the negative pressure upstream of the pump 3.

すなわち、次亜塩素酸ナトリウム水溶液が貯留したタンク30とポンプ3の上流の添加部35が電動開閉バルブ34を有する管路111でつながれており、ポンプ上流側は負圧になっているため、電動開閉バルブ34を開放すると、次亜塩素酸ナトリウム水溶液がタンク30から吸い上げられて、添加部35を介して次亜塩素酸ナトリウム水溶液が添加される。  That is, the tank 30 in which the sodium hypochlorite aqueous solution is stored and the addition portion 35 upstream of the pump 3 are connected by the pipe line 111 having the electric opening / closing valve 34, and the pump upstream side has a negative pressure. When the opening / closing valve 34 is opened, the sodium hypochlorite aqueous solution is sucked up from the tank 30, and the sodium hypochlorite aqueous solution is added via the adding unit 35.

図6は、循環管路の途中に直接無隔膜電解槽を設けた実施例を示す。すなわち、ヒーター4の直後に電解質添加部6を設け、その下流に無隔膜電解槽7を設置して、送水される浴槽水全量に電解質を添加して直接電気分解して次亜塩素酸ナトリウム水溶液を含む温水にする方法である。  FIG. 6 shows an embodiment in which a diaphragm electrolyzer is provided directly in the middle of the circulation line. That is, an electrolyte addition unit 6 is provided immediately after the heater 4, a non-diaphragm electrolytic tank 7 is installed downstream thereof, the electrolyte is added directly to the total amount of bath water to be fed, and directly electrolyzed to obtain an aqueous sodium hypochlorite solution. It is a method to make warm water containing.

もちろん、電解質添加部6と無隔膜電解槽7を圧力容器12の直前や圧力容器12の排水管路106や108において添加しても良い。  Of course, the electrolyte addition unit 6 and the diaphragm electrolyzer 7 may be added immediately before the pressure vessel 12 or in the drain lines 106 and 108 of the pressure vessel 12.

図7は無隔膜電解槽7で生成した次亜塩素酸ナトリウム水溶液を圧力容器12の排水管路108に添加する実施例を示す。  FIG. 7 shows an embodiment in which the aqueous sodium hypochlorite solution generated in the diaphragm membrane electrolytic cell 7 is added to the drain line 108 of the pressure vessel 12.

ヒーター4下流の分岐部41で分岐された浴槽水は管路112を通って、電解質添加部6で電解質を添加された後、無隔膜電解槽7で次亜塩素酸ナトリウム水溶液となり、添加部36を介して排水管路108の炭酸泉に添加される。  The bathtub water branched at the branching portion 41 downstream of the heater 4 passes through the pipe line 112 and is added with an electrolyte at the electrolyte addition unit 6, and then becomes a sodium hypochlorite aqueous solution in the diaphragm membrane electrolytic cell 7. Is added to the carbonated spring of the drain pipe 108.

図8は水道水や井水を供給して無隔膜電解槽7で次亜塩素酸ナトリウム水溶液を生成する実施例を示す。  FIG. 8 shows an embodiment in which tap water or well water is supplied to produce a sodium hypochlorite aqueous solution in the diaphragmless electrolytic cell 7.

浴槽水ではなく、水道水や井水を電動開閉バルブ40を有する管路114から供給し、電解質添加部6で電解質を添加した後、無隔膜電解槽7で次亜塩素酸ナトリウム水溶液を生成し、管路115に設けられた添加部42を介して、ポンプ3により送水される浴槽水に添加する。  After supplying tap water and well water from the pipe line 114 having the electric opening / closing valve 40 instead of the bath water, and adding the electrolyte in the electrolyte addition section 6, an aqueous sodium hypochlorite solution is generated in the diaphragm membrane electrolytic cell 7. Then, the water is added to the bath water fed by the pump 3 through the adding portion 42 provided in the pipe line 115.

この場合も、圧力容器12の直前や圧力容器12の排水管路106や108において添加しても良い。  Also in this case, it may be added immediately before the pressure vessel 12 or in the drain pipes 106 and 108 of the pressure vessel 12.

次に図9〜10を用いて、高濃度炭酸泉生成動作における圧力容器12内の水位をリミットスイッチ16と17の間に維持する動作に関して、別の動作を説明する。  Next, another operation will be described with respect to the operation of maintaining the water level in the pressure vessel 12 between the limit switches 16 and 17 in the high-concentration carbonated spring generating operation with reference to FIGS.

図9においては、圧力容器12の上流の管路101に電動開閉バルブ37を有しており、さらに、ポンプ3はポンプ出口圧力が所定の圧力を超えると自動的にポンプ3からの送水がポンプ3の入口側に戻るリリーフ機能を有し(図示せず)、炭酸ガスを供給する電動開閉バルブ23は開放状態、管路103の電動開閉バルブは閉鎖状態を維持し、圧力容器12内の水位が変動してリミットスイッチ17が反応すると、電動開閉バルブ37を閉鎖して圧力容器への送水を遮断し、リミットスイッチ16が反応すると、電動開閉バルブ37を開放して、送水を再開する動作である。  In FIG. 9, an electric on-off valve 37 is provided in the pipe line 101 upstream of the pressure vessel 12, and the pump 3 automatically pumps water from the pump 3 when the pump outlet pressure exceeds a predetermined pressure. 3 has a relief function for returning to the inlet side (not shown), the electric open / close valve 23 for supplying carbon dioxide gas is maintained in an open state, the electric open / close valve in the conduit 103 is maintained in a closed state, and the water level in the pressure vessel 12 is maintained. When the limit switch 17 reacts with the fluctuation, the electric open / close valve 37 is closed to shut off the water supply to the pressure vessel, and when the limit switch 16 reacts, the electric open / close valve 37 is opened to restart the water supply. is there.

図10は、圧力容器12の給水側と排水側の管路に設けられた電動式流量調整バルブにより圧力容器に供給される水量、あるいは、排水される水量を調整して、圧力容器12内の水位を維持する実施例である。  FIG. 10 is a diagram illustrating the adjustment of the amount of water supplied to the pressure vessel or the amount of water to be drained by an electric flow rate adjusting valve provided on the water supply side and drainage side pipes of the pressure vessel 12. This is an example of maintaining the water level.

ポンプ3の直後に電動式流量調整バルブ38を有し、排水管路108には電動式流量調整バルブ39を有し、圧力容器のリミットスイッチ17が反応すると、電動式流量調整バルブ38を絞って送水量を減らすか電動式流量調整バルブ39を開いて排水量を増やし、リミットスイッチ16が反応したら、電動式開閉バルブ38を開いて送水量を増やすか電動式流量調整バルブ29を絞って排水量を減らすことにより圧力容器12内の水位を維持する動作である。  An electric flow rate adjusting valve 38 is provided immediately after the pump 3. An electric flow rate adjusting valve 39 is provided in the drain line 108. When the limit switch 17 of the pressure vessel reacts, the electric flow rate adjusting valve 38 is throttled. If the amount of water supply is reduced or the electric flow control valve 39 is opened to increase the amount of drainage, and the limit switch 16 reacts, the electric on-off valve 38 is opened to increase the amount of water supply or the electric flow rate adjustment valve 29 is throttled to reduce the amount of drainage. This is the operation of maintaining the water level in the pressure vessel 12.

この場合、可能であれば、電動式流量調整バルブ38および39はどちらか1つであっても良い。  In this case, if possible, either one of the electric flow rate adjusting valves 38 and 39 may be provided.

最後に図11は圧力容器12からの排水管路と管路103が合流せず、別々に浴槽と接続されている実施例を示す。この場合は、絞り27は管路108の末端で、浴槽への出口部に設けても良い。  Finally, FIG. 11 shows an embodiment in which the drainage pipe from the pressure vessel 12 and the pipe 103 do not merge and are separately connected to the bathtub. In this case, the throttle 27 may be provided at the end of the pipe 108 at the outlet to the bathtub.

上述の全ての実施例では、次亜塩素酸ナトリム水溶液を例にしているが、もちろん、亜塩素酸ナトリウム水溶液でも良い。  In all the embodiments described above, sodium hypochlorite aqueous solution is taken as an example, but of course, sodium chlorite aqueous solution may be used.

さらに、上述の全ての実施例では、圧力容器12内の水位の検出が、マグネット14を有したフロート13とリミットスイッチ15〜18により行われているが、液面を直接検出できるセンサーなどの、その他の検出器を用いてもかまわない。  Furthermore, in all the embodiments described above, the detection of the water level in the pressure vessel 12 is performed by the float 13 having the magnet 14 and the limit switches 15 to 18, but the sensor or the like that can directly detect the liquid level, Other detectors may be used.

上述の全ての実施例では、浴槽1を例に挙げて説明しているが、浴槽は足浴槽でも、その他の温水を貯留する容器でもかまわない。
また、上述の添加部8,32,35,36,42には必要に応じて、逆流防止バルブを設置する。
In all the above-described embodiments, the bathtub 1 is described as an example, but the bathtub may be a foot bathtub or a container for storing other hot water.
In addition, a backflow prevention valve is installed in the above-described addition portions 8, 32, 35, 36, and 42 as necessary.

発明の効果The invention's effect

本発明により、浴槽水のような、ある意味汚れた温水であっても、目詰まりを起こすことなく循環させて炭酸ガスを溶解させることができ、手軽に高濃度の炭酸泉を生成することが出来き、メンテナンスも容易で、長期間初期の性能を保つことが出来る。  According to the present invention, even hot water that is dirty in a sense, such as bath water, can be circulated without causing clogging to dissolve carbon dioxide gas, and a high-concentration carbonated spring can be easily produced. Maintenance is easy and the initial performance can be maintained for a long time.

また、次亜塩素酸ナトリウム水溶液や亜塩素酸水溶液は、それ自体がアルカリ性であり、殺菌力があまり強くないため多量に入れなければ十分な効果が得られなかったが、本発明のように、炭酸ガスを溶解した温水と共に使用すると、弱酸性の次亜塩素酸水溶液あるいは亜塩素酸水溶液となり、低濃度でも十分な殺菌効果が得られ、不快な塩素臭もほとんど無くなる。  In addition, the sodium hypochlorite aqueous solution and the chlorous acid aqueous solution are alkaline per se, and the bactericidal power is not so strong, so a sufficient effect cannot be obtained unless it is added in a large amount. When used with warm water in which carbon dioxide gas is dissolved, a weakly acidic hypochlorous acid aqueous solution or chlorous acid aqueous solution is obtained, and a sufficient bactericidal effect can be obtained even at a low concentration, and there is almost no unpleasant chlorine odor.

そして、24時間風呂のようなヒーターとフィルターを介して循環濾過しながら浴槽水を保温する場合においても、温水が強力な次亜塩素酸や亜塩素酸により常に殺菌されているため、フィルターや管路における菌の繁殖も防止され、熱湯によるフィルターや管路の殺菌、あるいは、幾重ものフィルターを使用して頻繁にフィルターを交換する必要もなくなる。  And even when the bath water is kept warm while being circulated and filtered through a heater and a filter such as a 24-hour bath, since the hot water is always sterilized by strong hypochlorous acid or chlorous acid, Propagation of bacteria in the road is also prevented, and it is not necessary to sterilize the filter or pipe with hot water, or to change the filter frequently using multiple filters.

さらに、高濃度炭酸泉を生成する時以外は、迂回管路を介して循環することにより、ポンプの吐出圧を低くしても十分な循環が出来るため、ポンプの回転数を下げ、省エネおよび省音運転をすることができる。  In addition, except when generating high-concentration carbonated springs, circulation through a bypass line allows sufficient circulation even if the pump discharge pressure is lowered. You can drive.

したがって、本発明により、一般家庭においても24時間保温されたクリーンな風呂を、欲しいときにいつでも簡単に高濃度炭酸泉にすることができるようになり、高齢化とストレスが進む現代社会に不可欠な商品を安価に提供できるようになる。  Therefore, according to the present invention, a clean bath that has been kept warm for 24 hours even in ordinary homes can be easily converted to a high-concentration carbonated spring whenever necessary, and is an indispensable product for the modern society where aging and stress are advancing. Can be provided at low cost.

本発明の代表的な実施例を示すShown is a representative embodiment of the present invention. 図1における簡易的な実施例を示す1 shows a simple embodiment in FIG. 次亜塩素酸ナトリウム水溶液をポンプで添加する実施例を示すAn example of adding a sodium hypochlorite aqueous solution with a pump is shown. 次亜塩素酸ナトリウム水溶液を圧力容器で添加する実施例を示すAn example of adding an aqueous sodium hypochlorite solution in a pressure vessel is shown. 次亜塩素酸ナトリウム水溶液をポンプ上流の負圧を利用して添加する実施例を示すExample of adding sodium hypochlorite aqueous solution using negative pressure upstream of pump ポンプ送水される浴槽水の全量を無隔膜電解する実施例を示すAn example of performing diaphragmless electrolysis of the whole amount of bathtub water to be pumped is shown. 無隔膜電解水を排水管路に添加する実施例を示すAn example of adding non-diaphragm electrolyzed water to a drain line is shown. 水道水や井水を無隔膜電解槽で電解して添加する実施例を示すAn example is shown in which tap water and well water are electrolyzed in a diaphragm membrane electrolytic cell and added. 圧力容器の水位維持を送水を遮断して行う実施例を示すAn example is shown in which the water level is maintained in the pressure vessel by shutting off the water supply. 圧力容器の水位維持を循環管路の流量を制御して行う実施例を示すAn embodiment is shown in which the water level of the pressure vessel is maintained by controlling the flow rate of the circulation line. 圧力容器からの排水とバイパス管路の排水を別々に浴槽に戻す実施例を示すAn example is shown in which drainage from the pressure vessel and drainage from the bypass line are returned separately to the bathtub.

符号の説明Explanation of symbols

1 浴槽 、2 フィルター 、3 ポンプ
4 ヒーター 、5 分岐部 、6 電解質添加部
7 無隔膜電解槽 、8 添加部 、9 空間 、10 噴射孔
11 空間 、12 圧力容器 、13 フロート
14 マグネット 、15 リミットスイッチ 、16 リミットスイッチ
17 リミットスイッチ 、18 リミットスイッチ
19 炭酸ガスボンベ 、20 手動バルブ 、21 減圧弁
22 減圧弁 、23 電動開閉バルブ 、24 逆止弁
25 電動開閉バルブ 、26 合流部 、27 絞り
28 合流部 、29 電動開閉バルブ 、30 タンク
31 ポンプ 、32 添加部 、33 電動開閉バルブ
34 電動開閉バルブ 、35 添加部 、36 添加部
37 電動開閉バルブ 、38 電動式流量調整バルブ
39 電動式流量調整バルブ 、40 電動開閉バルブ
41 分岐部 、42 添加部 、43 電動開閉バルブ
44 圧力容器 、45 弾性体 、46 排水口
47 絞り 、48 分岐部 、49 逆止弁
101〜105:管路 、106 排水管路 、107 管路
108 排水管路 、109〜115 管路
DESCRIPTION OF SYMBOLS 1 Bathtub, 2 Filter, 3 Pump 4 Heater, 5 Branch part, 6 Electrolyte addition part 7 Non-membrane electrolyzer, 8 Addition part, 9 space, 10 Injection hole 11 Space, 12 Pressure vessel, 13 Float 14 Magnet, 15 Limit switch 16 limit switch 17 limit switch 18 limit switch 19 carbon dioxide gas cylinder 20 manual valve 21 pressure reducing valve 22 pressure reducing valve 23 electric open / close valve 24 check valve 25 electric open / close valve 26 merge part 27 throttle 28 merge part 29 Electric open / close valve, 30 Tank 31 Pump, 32 Addition part, 33 Electric open / close valve 34 Electric open / close valve, 35 Addition part, 36 Addition part 37 Electric open / close valve, 38 Electric flow adjustment valve 39 Electric flow adjustment valve, 40 Electric Open / close valve 41 Branching section 42 Adding section 43 Electric Off valve 44 pressure vessel 45 the elastic body, the diaphragm 46 drain opening 47, 48 branch unit, 49 a check valve 101 to 105: pipe, 106 drain line, 107 line 108 drain line, 109-115 conduit

Claims (39)

浴槽水や足浴槽水に炭酸ガスを溶解して炭酸泉を生成する工程を有し、ポンプにより浴槽や足浴槽から前記炭酸ガス溶解工程に浴槽水や足浴槽水を送水し、炭酸ガスを溶解した後、再び浴槽や足浴槽に戻す循環工程を有し、該炭酸ガス溶解工程が圧力容器に炭酸ガスを大気圧以上の所定の圧力で供給する工程を有し、浴槽水や足浴槽水を炭酸ガスが充填された圧力容器内に噴射および/または散水する工程を有し、該圧力容器から浴槽水や足浴槽水を排水する排水工程を有し、圧力容器内に噴射および/または散水された浴槽水や足浴槽水が圧力容器底部に所定の範囲の水位で貯留する水位維持工程を有し、該炭酸ガス溶解工程の前工程において浴槽水や足浴槽水に次亜塩素酸ナトリウム水溶液あるいは亜塩素酸水溶液を添加する工程を有するか、あるいは、該炭酸ガス溶解工程の後工程において該炭酸泉に次亜塩素酸ナトリウム水溶液あるいは亜塩素酸水溶液を添加する工程を有することを特徴とする炭酸泉生成方法  It has a step of generating carbon dioxide spring by dissolving carbon dioxide in bathtub water or foot bath water, and pumping bathtub water or foot bath water from the bathtub or foot tub to the carbon dioxide dissolving step by a pump to dissolve carbon dioxide After that, there is a circulation step for returning to the bathtub or footbath again, and the carbon dioxide gas dissolving step has a step of supplying carbon dioxide gas to the pressure vessel at a predetermined pressure equal to or higher than atmospheric pressure. A step of spraying and / or sprinkling water into a pressure vessel filled with gas, a step of draining bath water and footbath water from the pressure vessel, and spraying and / or sprinkling water into the pressure vessel There is a water level maintaining step in which bath water or foot bath water is stored at a predetermined range of water level at the bottom of the pressure vessel, and in the previous step of the carbon dioxide dissolving step, sodium hypochlorite aqueous solution or It has a process to add chloric acid aqueous solution Or, alternatively, carbonated spring generation method characterized by comprising the step of adding an aqueous sodium hypochlorite solution or chlorite solution to the carbonate spring in the process after the carbon dioxide gas dissolving step 前記圧力容器内に貯留する浴槽水や足浴槽水を所定の範囲の水位にする水位維持工程が、前記圧力容器底部近傍に排水管路を持ち、該圧力容器内の圧力が所定の値以下のときは排水管路からの排水量よりも該圧力容器への浴槽水や足浴槽水の噴射および/または散水による供給量が多く、該圧力容器内の圧力が所定の圧力を超えると、噴射および/または散水による供給量よりも排水量が多くなる流量調整工程を排水工程に有し、少なくとも該圧力容器内の上下2点の水位を検知する検知手段を有し、上部検知手段が水位を検知すると炭酸ガスの供給を開始し、下部検知手段が水位を検知すると炭酸ガスの供給を停止する炭酸ガス供給調整手段であることを特徴とする請求項1に記載の炭酸泉生成方法  The water level maintaining step of setting the bathtub water or footbath water stored in the pressure vessel to a predetermined range of water level has a drain line near the bottom of the pressure vessel, and the pressure in the pressure vessel is not more than a predetermined value. When the amount of water supplied from and / or water sprayed to the pressure vessel is greater than the amount of water discharged from the drain pipe, and the pressure in the pressure vessel exceeds a predetermined pressure, Alternatively, the drainage process has a flow rate adjustment process in which the amount of drainage is greater than the supply amount by watering, and has at least detection means for detecting the water levels at the upper and lower two points in the pressure vessel. 2. The carbonated spring production method according to claim 1, wherein the supply of carbon dioxide is started when gas supply is started and when the lower detection means detects the water level, the supply of carbon dioxide gas is stopped. 前記圧力容器内に貯留する浴槽水や足浴槽水を所定の範囲の水位にする水位維持工程が、前記圧力容器底部近傍に排水管路を持ち、常に排水管路からの排水量が該圧力容器への浴槽水や足浴槽水の供給量よりも少ない排水工程を有し、少なくとも該圧力容器内の2点の水位を検知する検知手段を有し、上部検知手段が水位を検知すると前記圧力容器への浴槽水や足浴槽水の供給を停止し、下部検知手段が水位を検知すると再び供給を開始する工程であることを特徴とする請求項1に記載の炭酸泉生成方法  The water level maintaining step of bringing the bathtub water and footbath water stored in the pressure vessel into a predetermined range has a drain pipe near the bottom of the pressure vessel, and the amount of drainage from the drain pipe always flows to the pressure vessel. The drainage process is less than the supply amount of the bathtub water or footbath water, and has at least two detection means for detecting the water level in the pressure vessel. When the upper detection means detects the water level, the pressure vessel 2. The carbonated spring production method according to claim 1, wherein the supply of the bathtub water and the footbath water is stopped and the supply is started again when the lower detection means detects the water level. 前記圧力容器上部に開閉自在の排気手段を有し、排気手段を開放すると共に、該圧力容器内に浴槽水や足浴槽水を送水して、前記圧力容器内を浴槽水や足浴槽水で満たすことにより、圧力容器内の空気を排出することを特徴とする請求項1〜3のいずれか1項に記載の炭酸泉生成方法  The pressure vessel has an openable / closable exhaust means, and the exhaust means is opened, and bath water or footbath water is fed into the pressure vessel to fill the pressure vessel with bath water or footbath water. The air in a pressure vessel is discharged by this, The carbonated spring production | generation method of any one of Claims 1-3 characterized by the above-mentioned. 前記圧力容器内に水位を検知する検知手段を少なくとも1つ有し、圧力容器内に炭酸ガスを圧力供給している状態で、該水位検知手段が水位を検知した場合、炭酸ガスの供給が不足していると判断することを特徴とする請求項1〜4のいずれか1項に記載の炭酸泉生成方法  The pressure vessel has at least one detecting means for detecting the water level, and when the water level detecting means detects the water level in a state where the carbon dioxide gas is pressure-supplied in the pressure vessel, the supply of the carbon dioxide gas is insufficient. It is judged that it is carrying out, The carbonated spring production | generation method of any one of Claims 1-4 characterized by the above-mentioned. 前記次亜塩素酸ナトリウム水溶液や亜塩素酸ナトリウム水溶液を添加する工程が、次亜塩素酸ナトリウム水溶液や亜塩素酸ナトリウム水溶液が貯留したタンクからポンプで次亜塩素酸ナトリウム水溶液や亜塩素酸ナトリウム水溶液を吸い上げる工程を有し、該ポンプの圧力により次亜塩素酸ナトリウム水溶液や亜塩素酸ナトリウム水溶液を浴槽水や足浴槽水中に添加する添加工程であることを特徴とする請求項1〜5のいずれか1項に記載の炭酸泉生成方法  The step of adding the sodium hypochlorite aqueous solution or the sodium chlorite aqueous solution is a sodium hypochlorite aqueous solution or a sodium chlorite aqueous solution by a pump from a tank in which the sodium hypochlorite aqueous solution or the sodium chlorite aqueous solution is stored. 6. The method according to claim 1, further comprising adding a sodium hypochlorite aqueous solution or a sodium chlorite aqueous solution to bath water or foot bath water by the pressure of the pump. The carbonated spring production method according to claim 1 前記次亜塩素酸ナトリウム水溶液や亜塩素酸ナトリウム水溶液を添加する工程が、カセットボンベなどの圧力容器に加圧剤と共に封入された次亜塩素酸ナトリウム水溶液や亜塩素酸ナトリウム水溶液を、途中に電動式開閉バルブを有する管路を介して浴槽水や足浴槽水に添加する工程であることを特徴とする請求項1〜5のいずれか1項に記載の炭酸泉生成方法  The step of adding the sodium hypochlorite aqueous solution or the sodium chlorite aqueous solution is performed by electrically driving a sodium hypochlorite aqueous solution or a sodium chlorite aqueous solution sealed together with a pressure agent in a pressure vessel such as a cassette cylinder. The method for producing carbonated spring according to any one of claims 1 to 5, wherein the method is a step of adding to bathtub water or footbath water via a pipe line having an open / close valve. 前記次亜塩素酸ナトリウム水溶液や亜塩素酸ナトリウム水溶液を添加する工程が、前記浴槽水や足浴槽水を送水するポンプ上流の負圧を利用して亜塩素酸ナトリウム水溶液や亜塩素酸ナトリウム水溶液をタンクから吸い上げて浴槽水や足浴槽水に添加する工程であることを特徴とする請求項1〜5のいずれか1項に記載の炭酸泉生成方法  The step of adding the sodium hypochlorite aqueous solution or the sodium chlorite aqueous solution uses the negative pressure upstream of the pump for feeding the bath water or footbath water to the sodium chlorite aqueous solution or the sodium chlorite aqueous solution. It is the process of sucking up from a tank and adding to bathtub water or footbath water, The carbonated spring production | generation method of any one of Claims 1-5 characterized by the above-mentioned. 前記次亜塩素酸ナトリウム水溶液を添加する工程が、水道水や井水に塩化物溶液を含む電解促進剤を添加した後に、無隔膜電解槽で電気分解して次亜塩素酸ナトリウム水溶液を生成する工程を有し、該工程で生成された次亜塩素酸ナトリウム水溶液を循環工程のいずれかの位置で浴槽水や足浴槽水中に添加する添加工程であるか、浴槽水や足浴槽水をポンプの下流で2つの管路に分岐する分岐工程を有し、その分岐された一方の管路の浴槽水や足浴槽水に前記電解促進剤を添加した後に、無隔膜電解槽で電気分解して次亜塩素酸ナトリウムを生成する工程を有し、該工程で生成された次亜塩素酸ナトリウム水溶液を循環工程のいずれかの位置で浴槽水や足浴槽水中に添加する添加工程を有することを特徴とする請求項1〜5のいずれか1項に記載の炭酸泉生成方法  In the step of adding the sodium hypochlorite aqueous solution, an electrolysis accelerator containing a chloride solution is added to tap water or well water, and then electrolyzed in a non-diaphragm electrolyzer to generate a sodium hypochlorite aqueous solution. A step of adding an aqueous sodium hypochlorite solution generated in the step to the bath water or footbath water at any position in the circulation step, or adding the bath water or footbath water to the pump It has a branching process that branches into two pipes downstream, and after the electrolysis promoter is added to the bathtub water or footbath water of one of the branched pipes, A step of producing sodium chlorite, and an addition step of adding the aqueous sodium hypochlorite solution produced in the step to bath water or foot bath water at any position in the circulation step, In any one of claims 1 to 5 Carbonated spring generation method of mounting 前記次亜塩素酸ナトリウム水溶液を添加する工程が、循環管路の一部に浴槽水や足浴槽水に前記電解促進剤を添加した後に、無隔膜電解槽で電気分解して次亜塩素酸ナトリウムを生成する工程を有することを特徴とする請求項1〜5のいずれか1項に記載の炭酸泉生成方法  The step of adding the aqueous sodium hypochlorite solution comprises adding the electrolysis promoter to bathtub water or footbath water in a part of the circulation line, and then electrolyzing the sodium hypochlorite in a non-diaphragm electrolytic cell. The method for producing carbonated spring according to any one of claims 1 to 5, further comprising: 前記無隔膜電解槽の各電極間を流れる電流を検地する検知手段を有し、前記電解促進剤がなくなった場合に起きる電流値の変化から、電解促進剤が無くなった事を検知する手段を有する請求項9あるいは10に記載の炭酸泉生成方法  It has a detecting means for detecting the current flowing between the electrodes of the diaphragm electrolyzer, and has a means for detecting that the electrolysis promoter is lost from a change in current value that occurs when the electrolysis promoter is lost. The carbonated spring production | generation method of Claim 9 or 10 前記電解促進剤が硫化水素を含有した岩塩であることを特徴とする請求項9〜11のいずれか1項に記載の炭酸泉生成方法  The method for producing carbonated spring according to any one of claims 9 to 11, wherein the electrolysis promoter is a rock salt containing hydrogen sulfide. 前記無隔膜電解槽の各電極の極性を、所定の時間間隔ごとに入れ替えて電圧を印加することを特徴とする請求項9〜12のいずれか1項に記載の炭酸泉生成方法  The method of producing carbonated springs according to any one of claims 9 to 12, wherein a voltage is applied by switching the polarity of each electrode of the non-diaphragm electrolytic cell at predetermined time intervals. 前記無隔膜電解槽の各電極間を流れる電流を検地する検知手段を有し、該無隔膜電解槽内に水道水や井水あるいは浴槽水や足浴槽水が供給されている時と供給されていない時の各電極間を流れる電流の変化を検知し、水道水や井水あるいは浴槽水や足浴槽水の供給が無いことを検知することを特徴とする請求項9〜13のいずれか1項に記載の炭酸泉生成方法  It has a detecting means for detecting the current flowing between the electrodes of the diaphragm electrolyzer, and is supplied when tap water, well water, bath water or foot bath water is supplied into the diaphragm electrolyzer. The change of the electric current which flows between each electrode when there is no is detected, and it detects that there is no supply of tap water, well water, bathtub water, or footbath water, The any one of Claims 9-13 characterized by the above-mentioned. Carbonate spring generation method as described in 浴槽水や足浴槽水をポンプにより浴槽や足浴槽から前記圧力容器に送水し、炭酸ガスを溶解した後、再び浴槽や足浴槽に戻す循環工程の一部に、浴槽水や足浴槽水を加温する工程を有し、および/または、前記循環工程の一部で前記ポンプの上流側にごみや湯垢を除去する濾過工程を有することを特徴とする請求項1〜14のいずれか1項に記載の炭酸泉生成方法  Bathtub water or footbath water is pumped from the bathtub or footbath to the pressure vessel to dissolve the carbon dioxide gas, and then added to the part of the circulation process to return to the bathtub or footbath again. The method according to any one of claims 1 to 14, further comprising a filtration step of removing dust and scale on the upstream side of the pump in a part of the circulation step. The carbonated spring generation method described 浴槽水や足浴槽水をポンプにより浴槽や足浴槽から前記圧力容器に送水し、炭酸ガスを溶解した後、再び浴槽や足浴槽に戻す循環工程において、前記ポンプの下流で少なくとも2つ以上の管路に分岐する分岐工程を有し、分岐工程下流の一方の管路に圧力容器を有し、他方の管路に電動開閉バルブあるいは電動式流量調整バルブなどの流量調整手段を有するか、あるいは、前記分岐工程に各管路への流量を調整できる流量調整手段を有することにより、それぞれの管路を流れる量を調整する流量調整工程を有し、圧力容器からの排水管路と前記圧力管路を有さない管路から別々に浴槽や足浴槽に送水するか、該圧力容器の下流で圧力管路からの排水管路と前記圧力管路を有さない管路を合流して浴槽や足浴槽に送水することを特徴とする請求項1〜15のいずれか1項に記載の炭酸泉生成方法  At least two or more pipes downstream of the pump in a circulation process in which bathtub water or footbath water is pumped from the bathtub or footbath to the pressure vessel, carbon dioxide is dissolved, and then returned to the bathtub or footbath. Having a branching process that branches into a path, having a pressure vessel in one pipeline downstream of the branching process, and having a flow rate adjusting means such as an electric open / close valve or an electrical flow rate regulating valve in the other pipeline, or By having a flow rate adjusting means capable of adjusting the flow rate to each pipeline in the branching step, it has a flow rate adjusting step for adjusting the amount of flow through each pipeline, and the drain pipeline from the pressure vessel and the pressure pipeline Water is separately sent from a pipeline not having a pressure line to a bathtub or foot tub, or a drain line from the pressure line and a line not having the pressure line are joined downstream of the pressure vessel to Claiming water to the bathtub Carbonated spring producing method according to any one of 1 to 15 前記分岐工程下流の圧力容器を有さない管路への送水を行う場合、ポンプの回転数を落として消費電力および騒音を軽減することを特徴とする請求項16に記載の炭酸泉生成方法  17. The carbonated spring production method according to claim 16, wherein when water is supplied to a pipe having no pressure vessel downstream of the branching step, the number of rotations of the pump is reduced to reduce power consumption and noise. 浴槽水や足浴槽水をポンプにより浴槽や足浴槽から前記圧力容器に送水し、炭酸ガスを溶解した後、再び浴槽や足浴槽に戻す循環工程において、前記ポンプの下流で少なくとも2つ以上の管路に分岐する分岐工程を有し、分岐工程下流の一方の管路に圧力容器を有し、他方の管路に電動開閉バルブあるいは電動式流量調整バルブなどの流量調整手段を有するか、あるいは、前記分岐工程に各管路への流量を調整できる流量調整手段を有し、通常は前記電動開閉バルブを開放するか、電動式流量調整バルブや分岐工程の流量調整手段により圧力容器を有さない管路への送水を行い、次亜塩素酸ナトリウム水溶液あるいは亜塩素酸水溶液を添加する場合には、所定の時間だけ前記電動開閉バルブを閉じるか、所定の時間だけ前記電動式流量調整バルブや分岐工程の流量調整手段により浴槽水や足浴槽水を全て圧力容器へ送水し、前記次亜塩素酸ナトリウム水溶液あるいは亜塩素酸水溶液の添加を、所定の時間間隔あるいは決められた時間に所定の時間だけ行う事を特徴とする請求項16あるいは17いずれか1項に記載の炭酸泉生成方法  At least two or more pipes downstream of the pump in a circulation process in which bathtub water or footbath water is pumped to the pressure vessel from the bathtub or footbath and the carbon dioxide is dissolved and then returned to the bathtub or footbath again Having a branching process that branches into a path, having a pressure vessel in one pipeline downstream of the branching process, and having a flow rate adjusting means such as an electric open / close valve or an electrical flow rate regulating valve in the other pipeline, or It has a flow rate adjustment means that can adjust the flow rate to each pipe line in the branching process, and usually the electric on-off valve is opened or there is no pressure vessel by the electric flow rate adjustment valve or the flow rate adjustment means of the branching process. When water is supplied to the pipeline and an aqueous sodium hypochlorite solution or aqueous chlorous acid solution is added, the electric open / close valve is closed for a predetermined time or the electric flow control valve is supplied for a predetermined time. The bath water and foot bath water are all sent to the pressure vessel by the flow rate adjusting means in the buoy and branching process, and the addition of the sodium hypochlorite aqueous solution or the aqueous chlorous acid aqueous solution is performed at a predetermined time interval or at a predetermined time. The method for producing carbonated spring according to any one of claims 16 and 17, wherein the method is performed only for 圧力容器内に貯留する浴槽水や足浴槽水を所定の範囲の水位にする水位維持工程が、浴槽水や足浴槽水を送水するポンプの下流で少なくとも2つ以上の管路に分岐する分岐工程を有し、分岐工程下流の一方の管路に圧力容器を有し、他方の管路に電動開閉バルブあるいは電動式流量調整バルブなどの流量調整手段を有するか、あるいは、前記分岐工程に各管路への流量を調整できる流量調整手段を有することにより、それぞれの管路を流れる量を調整する流量調整工程を有し、少なくとも該圧力容器内の2点の水位を検知する検知手段を有し、上部検知手段が水位を検知すると、前記電動開閉バルブを開放するか、あるいは電動式流量調整バルブや分岐工程の流量調整手段により圧力容器への送水を少なくし、下部検知手段が水位を検知すると、前記電動開閉バルブを閉鎖するか、あるいは電動式流量調整バルブや分岐工程の流量調整手段により圧力容器への送水を増やす工程であることを特徴とする請求項16〜18いずれか1項に記載の炭酸泉生成方法  A branching step in which the water level maintaining step of making the bathtub water or footbath water stored in the pressure vessel into a predetermined range of water branches into at least two or more pipelines downstream of the pump that feeds the bathtub water or footbath water A pressure vessel in one of the pipes downstream of the branching process, and a flow rate adjusting means such as an electric open / close valve or an electric flow control valve in the other pipe, or each pipe in the branching process. By having a flow rate adjusting means capable of adjusting the flow rate to the channel, it has a flow rate adjusting step for adjusting the amount of flow through each pipe line, and has at least a detecting means for detecting the two water levels in the pressure vessel When the upper detection means detects the water level, the electric open / close valve is opened, or the water supply to the pressure vessel is reduced by the electric flow adjustment valve or the flow adjustment means in the branching process, and the lower detection means detects the water level. The process according to any one of claims 16 to 18, wherein the electric open / close valve is closed, or the water supply to the pressure vessel is increased by an electric flow rate adjusting valve or a flow rate adjusting means in a branching step. Of carbonated spring 浴槽水や足浴槽水に炭酸ガスを溶解して炭酸泉を生成する機構を有し、浴槽水や足浴槽水を浴槽や足浴槽から前記炭酸ガス溶解機構に送水するポンプを有し、炭酸ガスを溶解した浴槽水や足浴槽水を再び浴槽や足浴槽に戻す管路を有する循環管路を有し、前記炭酸ガス溶解機構が、炭酸ガスが充填された圧力容器を有し、該圧力容器に炭酸ガスを大気圧以上の所定の圧力で供給する管路を有し、浴槽水や足浴槽水を炭酸ガスが充填された圧力容器内に噴射および/または散水する機構を有し、該圧力容器内に噴射および/または散水された浴槽水や足浴槽水を排出する排出管路を有し、圧力容器内に噴射および/または散水された浴槽水や足浴槽水が圧力容器底部に所定の範囲の水位で貯留する水位維持機構を有し、該圧力容器の上流において浴槽水や足浴槽水に次亜塩素酸ナトリウム水溶液あるいは亜塩素酸水溶液を添加する機構を有するか、あるいは、該圧力容器の下流において炭酸泉に次亜塩素酸ナトリウム水溶液あるいは亜塩素酸水溶液を添加する機構を有することを特徴とする炭酸泉生成装置  It has a mechanism that generates carbon dioxide spring by dissolving carbon dioxide in bathtub water and footbath water, and has a pump that feeds bathtub water and footbath water from the bathtub and footbath to the carbon dioxide dissolution mechanism. A circulation line having a conduit for returning the dissolved bathtub water and footbath water to the bathtub and footbath again, and the carbon dioxide gas dissolution mechanism has a pressure vessel filled with carbon dioxide gas. A pressure line having a pipe for supplying carbon dioxide gas at a predetermined pressure equal to or higher than atmospheric pressure, and jetting and / or sprinkling bathtub water and footbath water into a pressure container filled with carbon dioxide gas; There is a discharge pipe that discharges the bathtub water and footbath water sprayed and / or sprinkled inside, and the bathtub water and footbath water sprayed and / or sprinkled into the pressure container has a predetermined range at the bottom of the pressure container A water level maintaining mechanism for storing at a water level of It has a mechanism for adding sodium hypochlorite aqueous solution or chlorous acid aqueous solution to bathtub water or footbath water, or sodium hypochlorite aqueous solution or chlorous acid aqueous solution is added to carbonated spring downstream of the pressure vessel Carbon dioxide spring generating apparatus characterized by having a mechanism 前記圧力容器内に貯留する浴槽水や足浴槽水を所定の範囲の水位にする水位維持機構が、前記圧力容器底部近傍に排水管路を有し、該圧力容器内の圧力が所定の値以下のときは排水管路からの排水量よりも該圧力容器への浴槽水や足浴槽水の噴射および/または散水による供給量が多く、該圧力容器内の圧力が所定の圧力を超えると、噴射および/または散水による供給量よりも排水量が多くなる絞りまたは流量調整機構を排水管路に有し、圧力容器への炭酸ガス供給管路に電動開閉バルブを有し、少なくとも該圧力容器内の上下2点の水位を検知する検知機構を有し、上部検知機構が水位を検知すると前記電動開閉バルブを開放して炭酸ガスの供給を開始し、下部検知手段が水位を検出すると前記電動開閉バルブを閉鎖して炭酸ガスの供給を停止する炭酸ガス供給調整機構であることを特徴とする請求項20に記載の炭酸泉生成装置  The water level maintaining mechanism for setting the bathtub water and footbath water stored in the pressure vessel to a predetermined range of water level has a drain pipe line near the bottom of the pressure vessel, and the pressure in the pressure vessel is below a predetermined value. In this case, the amount of water supplied from the water and / or water from the pressure vessel is larger than the amount of water discharged from the drain pipe, and when the pressure in the pressure vessel exceeds a predetermined pressure, The drainage pipe has a throttling or flow rate adjusting mechanism that increases the amount of drainage more than the amount supplied by watering, and an electric open / close valve in the carbon dioxide supply pipe to the pressure vessel. It has a detection mechanism that detects the water level at the point. When the upper detection mechanism detects the water level, it opens the electric open / close valve to start supplying carbon dioxide, and when the lower detection means detects the water level, the electric open / close valve is closed. And supply carbon dioxide Carbonated spring producing apparatus according to claim 20, characterized in that a carbon dioxide gas supply control mechanism to stop 前記圧力容器内に貯留する浴槽水や足浴槽水を所定の範囲の水位にする水位維持機構が、前記圧力容器底部近傍に排水管路を有し、常に排水管路からの排水量が該圧力容器への浴槽水や足浴槽水の供給量よりも少なくできる絞りあるいは流量調整バルブを排水管路に有し、少なくとも該圧力容器内の2点の水位を検知する検知機構を有し、ポンプの出口側圧力が所定の圧力を超えると自動的に送水をポンプの入り口側に戻すリリーフ機構を具備したポンプを有し、該ポンプの下流に電動開閉バルブを有し、上部検知機構が水位を検知すると前記電動開閉バルブを閉鎖して浴槽水や足浴槽水の供給を停止し、下部検知手段が水位を検知すると前記電動開閉バルブを開放して再び供給を開始する機構であることを特徴とする請求項20に記載の炭酸泉生成装置  The water level maintaining mechanism that makes the bathtub water and footbath water stored in the pressure vessel have a predetermined level of water has a drain pipe near the bottom of the pressure vessel, and the amount of drainage from the drain pipe is always the pressure vessel. The drain pipe has a throttle or flow rate adjustment valve that can reduce the amount of bathtub water or foot tub water supplied to the outlet, and has a detection mechanism that detects at least two water levels in the pressure vessel. When the pump has a relief mechanism that automatically returns the water supply to the inlet side of the pump when the side pressure exceeds a predetermined pressure, and has an electric open / close valve downstream of the pump, the upper detection mechanism detects the water level. The electric open / close valve is closed to stop the supply of bath water or foot bath water, and when the lower detection means detects the water level, the electric open / close valve is opened to start supplying again. Item 20 Charcoal Izumi generating device 前記圧力容器内に貯留する浴槽水や足浴槽水を所定の範囲の水位にする水位維持機構が、前記浴槽水や足浴槽水を供給するポンプを有し、前記圧力容器底部近傍に排水管路を有し、常に排水管路からの排水量が該圧力容器への浴槽水や足浴槽水の供給量よりも少なくできる絞りあるいは流量調整機構を排水管路に有し、少なくとも該圧力容器内の2点の水位を検知する検知機構を有し、上部検知機構が水位を検知すると前記ポンプを停止して浴槽水や足浴槽水の供給を停止し、下部検知手段が水位を検知すると前記ポンプを起動して再び供給を開始する機構であることを特徴とする請求項20に記載の炭酸泉生成装置  A water level maintaining mechanism for setting the bathtub water and footbath water stored in the pressure vessel to a predetermined range of water has a pump for supplying the bathtub water and footbath water, and a drain pipe near the bottom of the pressure vessel The drainage pipe has a throttling or flow rate adjusting mechanism that can always reduce the amount of drainage from the drainage pipe to the supply amount of bathtub water or footbath water to the pressure vessel, and at least 2 in the pressure vessel. It has a detection mechanism that detects the water level at the point. When the upper detection mechanism detects the water level, it stops the pump and stops the supply of bath water and footbath water, and when the lower detection means detects the water level, it starts the pump. 21. The carbonated spring generating apparatus according to claim 20, wherein the mechanism is a mechanism for starting supply again. 前記圧力容器内に貯留する浴槽水や足浴槽水を所定の範囲の水位にする水位維持機構が、排水管路および/または浴槽水や足浴槽水の供給管路に電動流量調整バルブを有した機構であることを特徴とする請求項20に記載の炭酸泉生成装置  The water level maintenance mechanism for setting the bathtub water and footbath water stored in the pressure vessel to a predetermined level has an electric flow control valve in the drainage pipe and / or the bathtub water and footbath water supply pipe The carbonated spring generating device according to claim 20, wherein the carbonated spring generating device is a mechanism. 前記圧力容器上部に電動開閉バルブを有する排気管路を有し、該圧力容器が浴槽水や足浴槽水で満たされたことを検知する水位センサーなどの検知機構を有することを特徴とする請求項20〜24のいずれか1項に記載の炭酸泉生成装置  The exhaust pipe having an electric on-off valve at the upper part of the pressure vessel, and having a detection mechanism such as a water level sensor for detecting that the pressure vessel is filled with bathtub water or footbath water. The carbonated spring production | generation apparatus of any one of 20-24 前記圧力容器内の水位を検知する前記検知機構を少なくとも1つ有し、炭酸ガス供給管路に電動開閉バルブを有し、該バルブが開放している状態で前記水位検知機構が水位を検知した場合、炭酸ガスの供給が不足していると判断し、警告を出力することを特徴とする請求項20〜25のいずれか1項に記載の炭酸泉生成装置  It has at least one detection mechanism for detecting the water level in the pressure vessel, and has an electric open / close valve in the carbon dioxide gas supply line, and the water level detection mechanism detects the water level with the valve open. In the case, it is determined that the supply of carbon dioxide gas is insufficient, and a warning is output, and the carbonated spring generating device according to any one of claims 20 to 25 前記次亜塩素酸ナトリウム水溶液や亜塩素酸ナトリウム水溶液を添加する機構が、次亜塩素酸ナトリウム水溶液や亜塩素酸ナトリウム水溶液が貯留したタンクを有し、該タンクから次亜塩素酸ナトリウム水溶液や亜塩素酸ナトリウム水溶液を吸い上げるポンプを有し、循環管路のいずれかの位置に浴槽水や足浴槽水中に次亜塩素酸ナトリウム水溶液や亜塩素酸ナトリウム水溶液を添加する添加部を有し、該添加部には逆流防止機構を有し、前記タンクと前記ポンプおよび前記添加部をつなぐ管路有する機構であることを特徴とする請求項20〜26のいずれか1項に記載の炭酸泉生成装置  The mechanism for adding the sodium hypochlorite aqueous solution or the sodium chlorite aqueous solution has a tank in which the sodium hypochlorite aqueous solution or the sodium chlorite aqueous solution is stored, from which the sodium hypochlorite aqueous solution or the sodium hypochlorite aqueous solution is stored. It has a pump for sucking up sodium chlorate aqueous solution, and has an addition part for adding sodium hypochlorite aqueous solution or sodium chlorite aqueous solution to bath water or foot bath water at any position of the circulation pipe, and the addition 27. The carbonated spring generating device according to claim 20, wherein the part has a backflow prevention mechanism, and is a mechanism having a pipe line connecting the tank, the pump, and the adding part. 前記次亜塩素酸ナトリウム水溶液や亜塩素酸ナトリウム水溶液を添加する機構が、次亜塩素酸ナトリウム水溶液や亜塩素酸ナトリウム水溶液が圧力容器に加圧剤と共に封入されたカセットボンベを有し、該カセットボンベと浴槽水や足浴槽水を送水する管路をつなぐ管路を有し、該管路の途中に電動式開閉バルブを有し、該管路と浴槽水や足浴槽水を送水する管路の接合部に逆流防止機構を有する添加部を有する機構であることを特徴とする請求項20〜26のいずれか1項に記載の炭酸泉生成装置  The mechanism for adding the sodium hypochlorite aqueous solution or the sodium chlorite aqueous solution has a cassette cylinder in which the sodium hypochlorite aqueous solution or the sodium chlorite aqueous solution is sealed together with a pressurizing agent in a pressure vessel. A pipeline that connects a cylinder and a pipeline that feeds bathtub water and footbath water, and that has an electric open / close valve in the middle of the pipeline, and that feeds the pipeline, bathtub water, and footbath water 27. The carbonated spring production device according to claim 20, wherein the joining portion is a mechanism having an addition portion having a backflow prevention mechanism. 前記次亜塩素酸ナトリウム水溶液や亜塩素酸ナトリウム水溶液を添加する機構程が、次亜塩素酸ナトリウム水溶液や亜塩素酸ナトリウム水溶液が貯留したタンクを有し、該タンクと前記浴槽水や足浴槽水を送水するポンプ上流の管路をつなぐ管路を有し、該管路に電動開閉バルブを有し、該管路とポンプ上流の管路の接合部に逆流防止機構を有する添加部を有する機構であることを特徴とする請求項20〜26のいずれか1項に記載の炭酸泉生成装置  The mechanism for adding the sodium hypochlorite aqueous solution or the sodium chlorite aqueous solution has a tank in which the sodium hypochlorite aqueous solution or the sodium chlorite aqueous solution is stored. A mechanism that has a pipe line that connects a pipe upstream of the pump for supplying water, has an electric on-off valve in the pipe, and has an addition part that has a backflow prevention mechanism at the joint between the pipe and the pipe upstream of the pump 27. The carbonated spring generating device according to any one of claims 20 to 26, wherein 前記次亜塩素酸ナトリウム水溶液を添加する機構が、浴槽水や足浴槽水を送水するポンプ下流で2つの管路に分岐する分岐部を有し、その分岐された一方の管路の浴槽水や足浴槽水に塩化物溶液を含む電解促進剤を添加する添加部を有し、その下流に前記電解促進剤を添加した浴槽水や足浴槽水を電気分解する無隔膜電解槽を有し、該無隔膜電解槽からの排水管路が前記ポンプの上流側の管路あるいは圧力容器の排水管路に接続されていることを特徴とする請求項20〜26のいずれか1項に記載の炭酸泉生成装置  The mechanism for adding the aqueous sodium hypochlorite solution has a branching portion that branches into two pipes downstream of a pump for feeding bathtub water or footbath water, and the bathtub water in one of the branched pipes It has an addition part for adding an electrolysis promoter containing a chloride solution to footbath water, and has a diaphragm electrolyzer that electrolyzes the bath water and footbath water to which the electrolysis promoter is added downstream, The carbonated spring production according to any one of claims 20 to 26, wherein a drainage pipe from the diaphragm electrolyzer is connected to a pipe upstream of the pump or a drainage pipe of a pressure vessel. apparatus 前記水酸化ナトリウム水溶液を添加する機構が、水道水や井水に塩化物溶液を含む電解促進剤を添加する添加部を有し、その下流に電解促進剤を添加した水道水や井水を電気分解する無隔膜電解槽を有し、該無隔膜電解槽からの排水管路が前記循環管路のいずれかの位置に接続されていることを特徴とする請求項20〜26のいずれか1項に記載の炭酸泉生成装置  The mechanism for adding the sodium hydroxide aqueous solution has an addition section for adding an electrolysis promoter containing a chloride solution to tap water or well water, and the tap water or well water to which the electrolysis promoter is added downstream is electrically connected. 27. A diaphragm electrolyzer that decomposes, and a drain pipe from the diaphragm electrolyzer is connected to any position of the circulation pipe. Carbonate spring generator as described in 前記次亜塩素酸ナトリウム水溶液を添加する機構が、浴槽水や足浴槽水を送水するポンプ下流に塩化物溶液を含む電解促進剤を添加する添加部を有し、その下流に前記電解促進剤を添加した浴槽水や足浴槽水を電気分解する無隔膜電解槽を有することを特徴とする請求項20〜26のいずれか1項に記載の炭酸泉生成装置  The mechanism for adding the sodium hypochlorite aqueous solution has an addition portion for adding an electrolysis promoter containing a chloride solution downstream of a pump for feeding bath water or footbath water, and the electrolysis promoter is placed downstream thereof. 27. A carbonated spring generator according to claim 20, further comprising a diaphragm electrolyzer that electrolyzes the added bath water or foot bath water. 前記無隔膜電解槽の電極間を流れる電流を検地する検知手段を有し、該電流が所定の値よりも低くなると警告を表示することを特徴とする請求項30〜32に記載の炭酸泉生成方法  33. A carbonated spring production method according to claim 30, further comprising a detecting means for detecting a current flowing between the electrodes of the non-diaphragm electrolytic cell, and displaying a warning when the current becomes lower than a predetermined value. 前記電解促進剤が硫化水素を含有した岩塩であることを特徴とする請求項30〜33のいずれか1項に記載の炭酸泉生成装置  34. The carbonated spring generator according to any one of claims 30 to 33, wherein the electrolysis promoter is a rock salt containing hydrogen sulfide. 前記無隔膜電解槽の各電極に印加する電圧の極性を所定の時間間隔ごとに入れ替える機構を有することを特徴とする請求項30〜34のいずれか1項に記載の炭酸泉生成装置  35. The carbonated spring generating device according to any one of claims 30 to 34, further comprising a mechanism for switching a polarity of a voltage applied to each electrode of the non-diaphragm electrolytic cell at predetermined time intervals. 浴槽水や足浴槽水を浴槽や足浴槽から前記圧力容器に送水して炭酸ガスを溶解した浴槽水や足浴槽水を再び浴槽や足浴槽に戻す管路を有する循環管路の一部に、浴槽水や足浴槽水を加温する機構を有し、および/または、前記循環管路の一部で前記ポンプの上流側にごみや湯垢を除去するフィルターを有することを特徴とする請求項20〜35のいずれか1項に記載の炭酸泉生成装置  In a part of the circulation pipeline having a pipeline for returning bathtub water or foot tub water from the bathtub or foot tub to the pressure vessel to dissolve the carbon dioxide gas and returning the water to the bathtub or foot tub again, 21. A mechanism for warming bath water or foot bath water, and / or a filter for removing dust and scales upstream of the pump in a part of the circulation pipe. The carbonated spring production | generation apparatus of any one of -35 浴槽水や足浴槽水をポンプにより浴槽や足浴槽から前記圧力容器に送水し、炭酸ガスを溶解した後、再び浴槽や足浴槽に戻す循環管路において、前記ポンプの下流で少なくとも2つ以上の管路に分岐する分岐部を有し、分岐部下流の一方の管路に圧力容器を有し、他方の管路に電動開閉バルブあるいは電動式流量調整バルブを有するか、あるいは、前記分岐部に各管路への流量を調整できる流量調整バルブを有し、圧力容器からの排水管路ともう一方の管路から別々に浴槽や足浴槽に送水するか、前記圧力容器の下流で圧力管路からの排水管路ともう一方の管路を合流する合流部を介して浴槽や足浴槽に送水することを特徴とする請求項20〜36のいずれか1項に記載の炭酸泉生成装置  At least two or more downstream of the pump in the circulation line which pumps bathtub water or footbath water from the bathtub or footbath to the pressure vessel by the pump, dissolves carbon dioxide, and returns to the bathtub or footbath again Has a branching part that branches into a pipe line, has a pressure vessel in one pipe line downstream of the branching part, and has an electric on-off valve or an electric flow control valve in the other pipe line, or in the branch part It has a flow rate adjustment valve that can adjust the flow rate to each pipe line, and separately supplies water from the drain pipe line and the other pipe line to the bathtub or foot tub, or the pressure pipe line downstream of the pressure vessel 37. The carbonated spring generating device according to any one of claims 20 to 36, wherein water is supplied to a bathtub or a foot tub through a joining portion that joins a drain pipe from the other pipe and the other pipe. 浴槽水や足浴槽水をポンプにより浴槽や足浴槽から前記圧力容器に送水し、炭酸ガスを溶解した後、再び浴槽や足浴槽に戻す循環管路において、前記ポンプの下流で少なくとも2つ以上の管路に分岐する分岐部を有し、分岐部下流の一方の管路に圧力容器を有し、他方の管路に電動開閉バルブあるいは電動式流量調整バルブを有するか、あるいは、前記分岐部に各管路への流量を調整できる電動式流量調整バルブを有し、通常は前記電動開閉バルブを開放するか、電動式流量調整バルブにより圧力容器を有さない循環管路への送水を行い、次亜塩素酸ナトリウム水溶液あるいは亜塩素酸水溶液を添加する場合には、所定の時間だけ前記電動開閉バルブを閉じるか、所定の時間だけ前記電動式流量調整バルブにより浴槽水や足浴槽水を全て圧力容器へ送水し、前記次亜塩素酸ナトリウム水溶液あるいは亜塩素酸水溶液の添加を、所定の時間間隔あるいは決められた時間に所定の時間だけ行う事を特徴とする請求項37に記載の炭酸泉生成方法  At least two or more downstream of the pump in the circulation line which pumps bathtub water or footbath water from the bathtub or footbath to the pressure vessel by the pump, dissolves carbon dioxide, and returns to the bathtub or footbath again Has a branching part that branches into a pipe line, has a pressure vessel in one pipe line downstream of the branching part, and has an electric on-off valve or an electric flow control valve in the other pipe line, or in the branch part It has an electric flow rate adjustment valve that can adjust the flow rate to each pipe line, and normally opens the electric open / close valve or supplies water to the circulation line that does not have a pressure vessel by the electric flow rate adjustment valve, When adding sodium hypochlorite aqueous solution or chlorous acid aqueous solution, the electric on-off valve is closed for a predetermined time, or all the bath water and footbath water are pressurized by the electric flow control valve for a predetermined time. And water to the vessel, carbonated spring producing method according to claim 37, wherein the addition of sodium hypochlorite aqueous solution or chlorite aqueous solution, characterized in that performing a predetermined time at a predetermined time interval or determined time 圧力容器内に貯留する浴槽水や足浴槽水を所定の範囲の水位にする水位維持機構程が、浴槽水や足浴槽水を送水するポンプの下流で少なくとも2つ以上の管路に分岐する分岐部を有し、分岐部下流の一方の管路に圧力容器を有し、他方の管路に電動開閉バルブあるいは電動式流量調整バルブを有するか、あるいは、前記分岐部に各管路への流量を調整できる電動式流量調整バルブを有し、少なくとも該圧力容器内の2点の水位を検知する検知手段を有し、上部検知手段が水位を検知すると、前記電動開閉バルブを開放するか、前記電動式流量調整バルブにより圧力容器への送水を少なくし、下部検知手段が水位を検知すると、前記電動開閉バルブを閉鎖するか、前記電動式流量調整バルブにより圧力容器への送水を増やすことを特徴とする請求項37あるいは38のいずれか1項に記載の炭酸泉生成方法  The water level maintenance mechanism that makes the bathtub water or footbath water stored in the pressure vessel a predetermined level of water branches into at least two pipelines downstream of the pump that feeds the bathtub water or footbath water. A pressure vessel in one of the pipes downstream of the branch part, and an electric open / close valve or an electric flow control valve in the other pipe, or a flow rate to each pipe line in the branch part An electric flow rate adjusting valve that can adjust the water level, and has at least two detecting means for detecting the water level in the pressure vessel. When the upper detecting means detects the water level, the electric opening / closing valve is opened, or The water flow to the pressure vessel is reduced by the electric flow rate adjusting valve, and when the lower detection means detects the water level, the electric opening / closing valve is closed or the water flow to the pressure vessel is increased by the electric flow rate adjusting valve. Beg Carbonated spring producing method according to any one of claim 37 or 38
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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010110608A (en) * 2008-11-10 2010-05-20 Toyohiko Urakawa Continuous temperature raising method of natural high concentration carbonated mineral spring
JP2011240218A (en) * 2010-05-14 2011-12-01 Dainippon Screen Mfg Co Ltd Fine bubble generating device and method
JP2013158635A (en) * 2012-02-02 2013-08-19 Viita Kk Method and apparatus which regulate concentration of dissolved carbon dioxide in water within pressure vessel
JP2013215543A (en) * 2012-04-11 2013-10-24 Viita Kk Carbonated spring generating method and apparatus
JP2014171485A (en) * 2013-03-06 2014-09-22 Tokyo Gas Co Ltd Artificial carbonated spring system
KR20180020600A (en) * 2016-08-19 2018-02-28 협우 이 Bathtub system of providing carbonated water
CN110385078A (en) * 2018-04-23 2019-10-29 陈云涛 A kind of bull bubble subacidity multifunctional disinfectant generating means

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010110608A (en) * 2008-11-10 2010-05-20 Toyohiko Urakawa Continuous temperature raising method of natural high concentration carbonated mineral spring
JP4466781B2 (en) * 2008-11-10 2010-05-26 豊彦 浦川 Continuous heating method for high concentration natural carbonated springs
JP2011240218A (en) * 2010-05-14 2011-12-01 Dainippon Screen Mfg Co Ltd Fine bubble generating device and method
JP2013158635A (en) * 2012-02-02 2013-08-19 Viita Kk Method and apparatus which regulate concentration of dissolved carbon dioxide in water within pressure vessel
JP2013215543A (en) * 2012-04-11 2013-10-24 Viita Kk Carbonated spring generating method and apparatus
JP2014171485A (en) * 2013-03-06 2014-09-22 Tokyo Gas Co Ltd Artificial carbonated spring system
KR20180020600A (en) * 2016-08-19 2018-02-28 협우 이 Bathtub system of providing carbonated water
KR101854628B1 (en) 2016-08-19 2018-06-14 협우 이 Bathtub system of providing carbonated water
CN110385078A (en) * 2018-04-23 2019-10-29 陈云涛 A kind of bull bubble subacidity multifunctional disinfectant generating means

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