JP2006233364A - Nonwoven fabric - Google Patents
Nonwoven fabric Download PDFInfo
- Publication number
- JP2006233364A JP2006233364A JP2005050007A JP2005050007A JP2006233364A JP 2006233364 A JP2006233364 A JP 2006233364A JP 2005050007 A JP2005050007 A JP 2005050007A JP 2005050007 A JP2005050007 A JP 2005050007A JP 2006233364 A JP2006233364 A JP 2006233364A
- Authority
- JP
- Japan
- Prior art keywords
- nonwoven fabric
- layer
- fibers
- fiber
- fineness
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004745 nonwoven fabric Substances 0.000 title claims abstract description 164
- 239000000835 fiber Substances 0.000 claims abstract description 100
- 238000000034 method Methods 0.000 claims abstract description 26
- 230000006835 compression Effects 0.000 claims abstract description 15
- 238000007906 compression Methods 0.000 claims abstract description 15
- 230000003746 surface roughness Effects 0.000 claims abstract description 11
- 238000005452 bending Methods 0.000 claims description 22
- 230000002745 absorbent Effects 0.000 claims description 16
- 239000002250 absorbent Substances 0.000 claims description 16
- 239000000463 material Substances 0.000 claims description 13
- 239000000470 constituent Substances 0.000 claims description 10
- 239000004744 fabric Substances 0.000 abstract description 2
- 229920005989 resin Polymers 0.000 description 23
- 239000011347 resin Substances 0.000 description 23
- 238000003490 calendering Methods 0.000 description 16
- 206010016322 Feeling abnormal Diseases 0.000 description 13
- 238000012360 testing method Methods 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 12
- 238000004519 manufacturing process Methods 0.000 description 11
- 238000011156 evaluation Methods 0.000 description 7
- 230000004927 fusion Effects 0.000 description 7
- 238000012545 processing Methods 0.000 description 7
- 238000005259 measurement Methods 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 238000000691 measurement method Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 229920001875 Ebonite Polymers 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 238000001000 micrograph Methods 0.000 description 2
- 238000012805 post-processing Methods 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 238000011144 upstream manufacturing Methods 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229920006311 Urethane elastomer Polymers 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- -1 polyethylene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000007779 soft material Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
- Absorbent Articles And Supports Therefor (AREA)
- Nonwoven Fabrics (AREA)
- Treatment Of Fiber Materials (AREA)
Abstract
Description
本発明は不織布に関する。 The present invention relates to a nonwoven fabric.
不織布の肌触りを判断する場合には、不織布を握ってみたり、軽く引っ張ったり、さすったり、或いは曲げたりするといった様々な力を不織布に与えることで、その不織布が伸びたり、皺ができたり、曲がったりするといった変形との関係を調べるのが通常である。不織布の肌触りは、これら様々な観点から総合的に判断される。 When judging the touch of the nonwoven fabric, the nonwoven fabric can be stretched or wrinkled by applying various forces to the nonwoven fabric, such as trying to grasp the nonwoven fabric, pulling it lightly, touching it, or bending it. It is usual to examine the relationship with deformation such as bending. The touch of the nonwoven fabric is comprehensively judged from these various viewpoints.
不織布の肌触りの判断要素の一つである表面平滑性に関し、この特性を高めることを目的として、上下２層構造を有し、上層に含まれる繊維として下層に含まれる繊維よりも細いものを用いた不織布が提案されている（特許文献１参照）。この不織布は、疎水性繊維を主材としてなる上層と下層とを有し、上層が表面平滑であって下層よりも細繊度の繊維で高密度に構成されているケミカルボンド不織布である。不織布においては、繊維どうしの交点がバインダによって結合されている。その結果、この不織布は、布としてのしなやかさ乃至ドレープ性に欠ける。またバインダ特有のべたつき感がある。従ってこの不織布の総合的な肌触りは良好なものとは言えない。 With regard to surface smoothness, which is one of the factors that determine the touch of nonwoven fabrics, for the purpose of enhancing this property, the upper and lower layers are used, and the fibers contained in the upper layer are thinner than those contained in the lower layer. The nonwoven fabric which has been proposed is proposed (refer patent document 1). This non-woven fabric is a chemical bond non-woven fabric having an upper layer and a lower layer mainly composed of hydrophobic fibers, the upper layer having a smooth surface and a higher density of finer fibers than the lower layer. In the nonwoven fabric, the intersections of the fibers are connected by a binder. As a result, this nonwoven fabric lacks flexibility or drapeability as a fabric. There is also a sticky feeling peculiar to the binder. Therefore, it cannot be said that the overall feel of this nonwoven fabric is good.
従って本発明の目的は、前述した従来技術が有する種々の欠点を解消し得る不織布を提供することにある。 Accordingly, an object of the present invention is to provide a non-woven fabric that can eliminate the various drawbacks of the above-described prior art.
本発明は、一方の表面を含む第１層と、他方の表面を含む第２層とを有し、第２層の密度が第１層の密度よりも低くなっている、エアスルー法によって製造された不織布であって、
少なくとも第１層に含まれる繊維はその横断面が扁平になっており、該繊維はその横断面の長軸方向が前記不織布の平面方向に概ね配向しており、
第１層側の表面は、その表面粗さの平均偏差ＳＭＤが２．５μｍ以下で且つ摩擦係数の平均偏差ＭＭＤが０．００８未満であり、
前記不織布の圧縮特性の線形性ＬＣが０．３以下で且つ曲げ剛性Ｂが０．０３ｃＮ・ｃｍ2／ｃｍ以下である不織布を提供することにより前記目的を達成したものである。
The present invention is manufactured by an air-through method, which has a first layer including one surface and a second layer including the other surface, and the density of the second layer is lower than the density of the first layer. Non-woven fabric,
The fibers included in at least the first layer have a flat cross section, and the fibers have a major axis direction of the cross section substantially oriented in the plane direction of the nonwoven fabric,
The surface on the first layer side has an average deviation SMD of the surface roughness of 2.5 μm or less and an average deviation MMD of the friction coefficient of less than 0.008,
The object is achieved by providing a nonwoven fabric having a linearity LC of compression characteristics of the nonwoven fabric of 0.3 or less and a bending rigidity B of 0.03 cN · cm 2 / cm or less.
また本発明は、前記の不織布を備え、該不織布における第１層側の表面が使用者の肌に接するように配されている吸収性物品であって、第１層の坪量が５〜１５ｇ／ｍ2、第２層の坪量が５〜４５ｇ／ｍ2で、不織布全体の坪量が１０〜５０ｇ／ｍ2である吸収性物品を提供するものである。 Moreover, this invention is an absorbent article provided with the said nonwoven fabric, and is distribute | arranged so that the surface of the 1st layer side in this nonwoven fabric may contact user's skin, Comprising: The basic weight of 1st layer is 5-15g / m 2, in which the basis weight of the second layer in 5~45g / m 2, the basis weight of the entire nonwoven fabric is to provide an absorbent article which is 10 to 50 g / m 2.
本発明の不織布は、表面粗さが低くなめらかであり、ドレープ性を有ししなやかであり、更に厚み方向への圧縮回復性が高くふんわり感を有するものである。従って本発明の不織布は、総合的な肌触りが非常に良好なものである。 The nonwoven fabric of the present invention has a smooth and low surface roughness, has a draping property, is flexible, has a high compression recovery property in the thickness direction, and has a soft feeling. Therefore, the nonwoven fabric of the present invention has a very good overall touch.
以下本発明を、その好ましい実施形態に基づき説明する。本発明の不織布はエアスルー法によって製造されたものである。エアスルー法は、カードウエブなどの繊維ウエブを、通気性のネットやドラムの上に載置し、熱風を吹き付けることで構成繊維の交点を熱融着させて不織布化する方法である。エアスルー法を採用することで、他の製造方法、例えば従来技術の項で述べたケミカルボンド法等で不織布を製造する場合に比較して、生産性良く肌触りの良好な不織布を得ることができる。本発明の不織布は、その一方の表面を含む第１層と、他方の表面を含む第２層とを有している多層構造のものである。この多層構造は、２層に限られず、第１層と第２層との間に１層以上の別の層が介在配置されている３層以上の構造であってもよい。 Hereinafter, the present invention will be described based on preferred embodiments thereof. The nonwoven fabric of this invention is manufactured by the air through method. The air-through method is a method in which a fiber web such as a card web is placed on a breathable net or drum, and hot air is blown to heat-bond intersections of constituent fibers to form a nonwoven fabric. By adopting the air-through method, it is possible to obtain a non-woven fabric with good productivity and good touch as compared with the case of producing a non-woven fabric by other production methods such as the chemical bond method described in the section of the prior art. The nonwoven fabric of the present invention has a multilayer structure having a first layer including one surface and a second layer including the other surface. This multilayer structure is not limited to two layers, and may be a structure of three or more layers in which one or more other layers are interposed between the first layer and the second layer.
本発明の不織布は、肌触りの主要な判断要素である（イ）なめらかさ、（ロ）しなやかさ及び（ハ）ふんわり感を兼ね備えていることによって特徴付けられる。これら３つの特性を兼ね備えた本発明の不織布は、非常に良好な肌触りを有するものとなる。 The non-woven fabric of the present invention is characterized by having (i) smoothness, (b) suppleness and (c) soft feeling, which are the main judgment factors of the touch. The nonwoven fabric of the present invention having these three characteristics has a very good touch.
まず不織布のなめらかさについて説明する。なめらかさは、本発明の不織布における第１層によって主として発現する特性である。第１層に含まれる不織布はその横断面が扁平になっている。この扁平形状が不織布になめらかさを付与する一因となっている。この観点から、第１層に含まれる繊維は、横断面の扁平率（長軸長／短軸長）が１．２以上、とりわけ１．３以上の値となる扁平形状であることが好ましい。第１層に含まれる繊維は、その全長に亘って横断面が扁平になっていることが好ましいが、それに限定されず、全長のうちの７０％以上、特に８０％以上の部分における横断面が扁平になっていれば、所望のなめらかさが付与される。特に、繊維どうしの結合点間の部分において横断面が扁平になっていることが好ましい。 First, the smoothness of the nonwoven fabric will be described. The smoothness is a characteristic mainly expressed by the first layer in the nonwoven fabric of the present invention. The nonwoven fabric contained in the first layer has a flat cross section. This flat shape contributes to the smoothness of the nonwoven fabric. From this point of view, it is preferable that the fibers included in the first layer have a flat shape in which the cross-sectional flatness (major axis length / minor axis length) is 1.2 or more, particularly 1.3 or more. The fibers included in the first layer preferably have a flat cross section over the entire length, but are not limited thereto, and the cross section in the portion of 70% or more, particularly 80% or more of the total length is not limited thereto. If it is flat, desired smoothness is provided. In particular, it is preferable that the cross section is flat in the portion between the bonding points of the fibers.
第１層に含まれる繊維は、そのすべてが扁平な繊維であることが望ましいが、それに限定されない。第１層の縦断面を電子顕微鏡で拡大して、繊維の横断面形状を観察した場合に、本数基準で７０％以上の繊維が扁平な形状であれば、所望のなめらかさが付与される。 The fibers included in the first layer are preferably all flat fibers, but are not limited thereto. When the longitudinal cross section of the first layer is enlarged with an electron microscope and the cross-sectional shape of the fiber is observed, if the fiber has a flat shape of 70% or more on the basis of the number, the desired smoothness is given.
横断面が扁平な繊維としては、異形口金を用いて紡糸された、横断面が扁平な繊維や、紡糸時の横断面は扁平ではないが、不織布製造後の後加工によって扁平に加工された繊維を用いることができる。後述する理由から明らかなように、本発明においては後者の繊維を用いることが好ましい。 The fiber with a flat cross section is a fiber that is spun using a deformed die and has a flat cross section, or a fiber that has been flattened by post-processing after manufacturing a nonwoven fabric, although the cross section at the time of spinning is not flat. Can be used. As will be apparent from the reason described later, the latter fiber is preferably used in the present invention.
不織布になめらかさを付与するためには、第１層に含まれる前述の横断面が扁平な繊維は、その横断面の長軸方向が不織布の平面方向に概ね配向していることも重要である。繊維の横断面の長軸方向と、不織布の平面方向とのなす角度が大きくなりすぎると、なめらかな感触を与えづらい。この観点から、第１層の表面及びその近傍に位置する繊維ほど、その横断面の長軸方向が不織布の平面方向に配向していることが好ましい。概ね配向しているとは、第１層の縦断面を電子顕微鏡で拡大して、扁平な繊維の長軸方向を観察したときに、本数基準で７０％以上の繊維の長軸方向が、不織布の平面方向と±３０度以内の角度をなしていることをいう。 In order to impart smoothness to the nonwoven fabric, it is also important that the long-axis direction of the cross-section of the above-mentioned fibers included in the first layer is generally oriented in the plane direction of the nonwoven fabric. . If the angle formed between the major axis direction of the cross section of the fiber and the plane direction of the nonwoven fabric is too large, it is difficult to give a smooth feel. From this viewpoint, it is preferable that the longer axis direction of the cross section is oriented in the plane direction of the nonwoven fabric as the fiber is located on the surface of the first layer and in the vicinity thereof. When the longitudinal section of the first layer is enlarged with an electron microscope and the major axis direction of flat fibers is observed, the major axis direction of 70% or more of the fibers on the basis of the number is non-woven fabric. The angle is within ± 30 degrees with the plane direction.
第１層に含まれる繊維における横断面の長軸方向を不織布の平面方向に配向させるためには、後述するように、不織布製造後の後工程であるカレンダー加工において繊維を扁平に加工すると同時に横断面の長軸方向を不織布の平面方向に配向させることが簡便であり好ましい。 In order to orient the major axis direction of the cross section of the fibers contained in the first layer in the plane direction of the nonwoven fabric, as will be described later, the fibers are processed flatly in calendering, which is a subsequent process after manufacturing the nonwoven fabric. It is convenient and preferable to orient the major axis direction of the surface in the plane direction of the nonwoven fabric.
不織布に一層良好ななめらかさを付与する観点から、第１層に含まれる繊維は細繊度のものであることが好ましい。細繊度の繊維によって第１層の表面が緻密になるからである。この観点から、第１層に含まれる繊維は、その繊度が０．０５〜２．０ｄｔｅｘ、特に０．０５〜１．５ｄｔｅｘであることが好ましい。繊度は次の方法で測定される。不織布の縦断面を電子顕微鏡で拡大し、繊維の横断面を観察する。１０カ所の位置での標準的な太さの繊維の横断面積を測定する。その値と樹脂の密度から繊度を算出する。その平均値をもって繊度とする。 From the viewpoint of imparting better smoothness to the nonwoven fabric, it is preferable that the fibers contained in the first layer have fineness. This is because the surface of the first layer becomes dense due to fine fibers. From this viewpoint, it is preferable that the fineness of the fibers contained in the first layer is 0.05 to 2.0 dtex, particularly 0.05 to 1.5 dtex. The fineness is measured by the following method. The longitudinal section of the nonwoven fabric is enlarged with an electron microscope, and the cross section of the fiber is observed. The cross-sectional area of a standard thickness fiber at 10 locations is measured. The fineness is calculated from the value and the density of the resin. The average value is used as the fineness.
不織布の表面をなめらかなものにするためには、表面における繊維の毛羽立ちが少ないことも重要である。繊維の毛羽立ちを少なくするためには、繊維どうしを確実に結合させて、繊維の自由末端が繊維の表面に存在しないようにすることが重要である。先に述べた通り、本発明の不織布はエアスルー法によって製造されるから、繊維どうしを確実に結合させるためには、融着しやすい繊維を用いることが有利である。この観点から、第１層に含まれる繊維は、熱可塑性樹脂を原料とする熱融着性繊維であることが好ましく、特に芯鞘型やサイド・バイ・サイド型などの複合繊維からなる熱融着性繊維であることが好ましい。 In order to make the surface of the nonwoven fabric smooth, it is also important that there is little fiber fluffing on the surface. In order to reduce fiber fluff, it is important to ensure that the fibers are bonded together so that the free ends of the fibers are not present on the surface of the fibers. As described above, since the nonwoven fabric of the present invention is produced by the air-through method, it is advantageous to use fibers that are easily fused in order to reliably bond the fibers together. From this point of view, the fiber contained in the first layer is preferably a heat-fusible fiber made of a thermoplastic resin as a raw material, and in particular, a heat-melting fiber composed of a composite fiber such as a core-sheath type or a side-by-side type. It is preferably an adhesive fiber.
第１層が以上の構成を有することで、不織布における第１層側の表面は、その表面粗さの平均偏差（以下ＳＭＤという）が２．５μｍ以下、好ましくは２．３μｍ以下という極めて低い値となる。ＳＭＤの下限値に特に制限はなく０に近ければ近いほど好ましいが、下限値が１．０μｍ、特に０．５μｍ程度に低くなれば、不織布に十分ななめらかさが付与される。 When the first layer has the above configuration, the surface on the first layer side of the nonwoven fabric has an extremely low value of an average deviation of surface roughness (hereinafter referred to as SMD) of 2.5 μm or less, preferably 2.3 μm or less. It becomes. The lower limit of SMD is not particularly limited and is preferably closer to 0. However, if the lower limit is as low as 1.0 μm, particularly about 0.5 μm, sufficient smoothness is imparted to the nonwoven fabric.
また不織布における第１層側の表面は、その摩擦係数の平均偏差（以下ＭＭＤという）が０．００８未満、好ましくは０．００６以下という極めて低い値となる。ＭＭＤの下限値に特に制限はなく０に近ければ近いほど好ましいが、下限値が０．００４、特に０．００３程度に低くなれば、不織布に十分ななめらかさが付与される。 Further, the surface on the first layer side of the nonwoven fabric has an extremely low value of an average deviation in friction coefficient (hereinafter referred to as MMD) of less than 0.008, preferably 0.006 or less. Although there is no restriction | limiting in particular in the lower limit of MMD, and it is so preferable that it is near 0, when a lower limit becomes low to about 0.004, especially about 0.003, sufficient smoothness is provided to a nonwoven fabric.
ＳＭＤ及びＭＭＤは以下の書籍に記載の方法に従い、カトーテック株式会社製のＫＥＳＦＢ４−ＡＵＴＯ−Ａ（商品名）を用いて測定される。具体的には以下の方法で測定される。
川端季雄著、「風合い評価の標準化と解析」、第２版、社団法人日本繊維機会学会 風合い計量と規格化研究委員会、昭和５５年７月１０日発行
SMD and MMD are measured using KESFB4-AUTO-A (trade name) manufactured by Kato Tech Co., Ltd. according to the method described in the following books. Specifically, it is measured by the following method.
Kakio Kawabata, “Standardization and analysis of texture evaluation”, 2nd edition, Japan Textile Opportunity Society, Texture Measurement and Standardization Research Committee, published on July 10, 1980
〔表面粗さの平均偏差ＳＭＤの測定法〕
２０ｃｍ×２０ｃｍの試験片を準備し、平滑な金属平面の試験台に取りつける。接触子を９．８ｃＮ（誤差±０．４９ｃＮ以内）で試験片に圧着する。試験片を０．１ｃｍ／ｓｅｃの一定速度で水平に２ｃｍ移動させる。試験片には１９．６ｃＮ／ｃｍの一軸張力が与えられる。接触子は、０．５ｍｍ径のピアノ線を幅５ｍｍでＵ字状に曲げたものからなり、９．８ｃＮで試験片を圧着する。接触子は、ばねで圧着される。ばねの定数は２４．５ｃＮ／ｍｍ（誤差±０．９８ｃＮ／ｍｍ以内）とし、共振周波数は表面接触から離れた状態で３０Ｈｚ以上とする。表面粗さの平均偏差の測定値はＳＭＤ値で表される。この測定をＭＤ及びＣＤともに行い、下記式（１）から平均値を出し、これを表面粗さの平均偏差ＳＭＤとする。
表面粗さの平均偏差ＳＭＤ＝｛(SMDMD 2＋SMDCD 2)／２｝1/2 （１）
[Measurement method of average deviation SMD of surface roughness]
A test piece of 20 cm × 20 cm is prepared and attached to a smooth metal flat test bench. The contact is pressed against the test piece with 9.8 cN (within ± 0.49 cN error). The specimen is moved 2 cm horizontally at a constant speed of 0.1 cm / sec. The specimen is given a uniaxial tension of 19.6 cN / cm. The contact consists of a 0.5 mm diameter piano wire bent in a U shape with a width of 5 mm, and a test piece is crimped at 9.8 cN. The contact is crimped with a spring. The spring constant is 24.5 cN / mm (within an error of ± 0.98 cN / mm), and the resonance frequency is 30 Hz or more in a state away from the surface contact. The measured value of the average deviation of the surface roughness is represented by the SMD value. This measurement is performed for both MD and CD, and an average value is obtained from the following formula (1), which is defined as an average deviation SMD of the surface roughness.
Average deviation of surface roughness SMD = {(SMD MD 2 + SMD CD 2 ) / 2} 1/2 (1)
〔摩擦係数の平均偏差ＭＭＤの測定法〕
２０ｃｍ×２０ｃｍの試験片を準備し、平滑な金属平面の試験台に取りつける。接触子を４９ｃＮの力で接触面を試験片に圧着し、試験片を０．１ｃｍ／ｓｅｃの一定速度で水平に２ｃｍ移動させる。試験片には１９．６ｃＮ／ｃｍの一軸張力が与えられる。接触子は、表面粗さの測定に用いた接触子と同じ０．５ｍｍ径のピアノ線を２０本並べ幅１０ｍｍでＵ字状に曲げたもので、重錘によって４９ｃＮの力で接触面を試験片に圧着させている。摩擦係数の平均偏差の測定値はＭＭＤ値で表される。この測定をＭＤ及びＣＤともに行い、下記式（２）から平均値を出し、これを摩擦係数の平均偏差ＭＭＤとする。
摩擦係数の平均偏差ＭＭＤ＝｛(MMDMD 2＋MMDCD 2)／２｝1/2 （２）
[Measuring method of mean deviation MMD of friction coefficient]
A test piece of 20 cm × 20 cm is prepared and attached to a smooth metal flat test bench. The contact surface is pressure-bonded to the test piece with a force of 49 cN, and the test piece is moved horizontally by 2 cm at a constant speed of 0.1 cm / sec. The specimen is given a uniaxial tension of 19.6 cN / cm. The contact was made by arranging 20 piano wires with the same diameter of 0.5 mm as the contact used for measuring the surface roughness and bending it into a U shape with a width of 10 mm. The contact surface was tested with a force of 49 cN using a weight. Crimped to a piece. The measured value of the average deviation of the friction coefficient is expressed as an MMD value. This measurement is performed for both MD and CD, and an average value is obtained from the following formula (2), which is defined as an average deviation MMD of the friction coefficient.
Mean deviation of friction coefficient MMD = {(MMD MD 2 + MMD CD 2 ) / 2} 1/2 (2)
次に不織布のしなやかさについて説明する。不織布の表面がなめらかであってもドレープ性が低くしなやかでない場合は、紙様の硬い感触を呈し、風合いが良好とならない。不織布のしなやかさの程度を表す尺度として当該技術分野においては曲げ剛性（以下Ｂともいう）が用いられる。本発明の不織布は、その曲げ剛性Ｂが０．０３ｃＮ・ｃｍ2／ｃｍ以下という低いものであり、好ましくは０．０２５ｃＮ・ｃｍ2／ｃｍ以下である。曲げ剛性Ｂが０．０３ｃＮ・ｃｍ2／ｃｍ超となると、不織布に十分なしなやかさが付与されず、総合的な肌触りを良好にすることができない。曲げ剛性Ｂの下限値に特に制限はなく０に近ければ近いほど好ましいが、下限値が０．０１５、特に０．０１程度に低くなれば、不織布に十分なしなやかさが付与される。 Next, the flexibility of the nonwoven fabric will be described. Even if the surface of the nonwoven fabric is smooth, if the drapeability is not low and flexible, it gives a paper-like hard feel and the texture is not good. In the technical field, bending stiffness (hereinafter also referred to as B) is used as a scale representing the degree of flexibility of a nonwoven fabric. The nonwoven fabric of the present invention has a low flexural rigidity B of 0.03 cN · cm 2 / cm or less, preferably 0.025 cN · cm 2 / cm or less. When the bending rigidity B exceeds 0.03 cN · cm 2 / cm, the nonwoven fabric is not given sufficient flexibility and the overall feel cannot be improved. The lower limit of the bending rigidity B is not particularly limited and is preferably closer to 0. However, if the lower limit is as low as 0.015, particularly about 0.01, the nonwoven fabric is sufficiently flexible.
曲げ剛性Ｂを前記の値以下とするためには、例えば不織布を揉む等の操作を行い、不織布の全体構造を変形させる（例えば繊維どうしの結合点を一部変形ないし破壊する）ことが有利である。具体的には、後述するように、不織布製造後の後工程であるカレンダー加工によって不織布の全体構造を変形させることが有利である。本発明において曲げ剛性Ｂとは、純曲げ試験機（カトーテック株式会社製のＫＥＳＦＢ２−ＡＵＴＯ−Ａ）を用いて測定された値をいう。曲げ剛性Ｂは、前述の「風合い評価の標準化と解析」に記載の方法に従い測定される。具体的には以下の方法で測定される。 In order to make the bending rigidity B equal to or less than the above value, it is advantageous to deform the entire structure of the nonwoven fabric (for example, partially deform or break the bonding point between the fibers) by, for example, sandwiching the nonwoven fabric. is there. Specifically, as will be described later, it is advantageous to deform the entire structure of the nonwoven fabric by calendering, which is a post-process after the production of the nonwoven fabric. In the present invention, the bending rigidity B refers to a value measured using a pure bending tester (KESFB2-AUTO-A manufactured by Kato Tech Co., Ltd.). The bending stiffness B is measured according to the method described in “Standardization and analysis of texture evaluation” described above. Specifically, it is measured by the following method.
〔曲げ剛性Ｂの測定法〕
２０ｃｍ×２０ｃｍの試験片を準備し、試験台に取りつけ、１ｃｍの間隔のチャックに試験片を把持する。試験片に対して、曲率Ｋ＝−２．５〜＋２．５ｃｍ-1の範囲で、等速度曲率の純曲げを行う。変形速度は０．５０ｃｍ-1／ｓｅｃで、１サイクル変形を行う。曲げ剛性値Ｂは、前述の「風合い評価の標準化と解析」の記載では、曲率０．５〜１．５及び−０．５〜−１．５間の曲げモーメントの傾斜より算出しているが、不織布の測定では、この曲率間で屈曲が起きるケースがあり、正確な数値が表されにくい。そこで、本発明における曲げ剛性Ｂは、０〜最大曲げモーメント値及び０〜最小曲げモーメント値における傾斜より算出する。この測定をＭＤ及びＣＤともに行い、下記式（３）から平均値を出し、これを曲げ剛性Ｂとする
曲げ剛性Ｂ＝｛(ＢMD 2＋ＢCD 2)／２｝1/2 （３）
[Measurement method of bending stiffness B]
A test piece of 20 cm × 20 cm is prepared, mounted on a test stand, and the test piece is gripped by a chuck having a 1 cm interval. The specimen is subjected to pure bending with a constant velocity curvature in the range of curvature K = −2.5 to +2.5 cm −1 . The deformation rate is 0.50 cm −1 / sec, and one cycle deformation is performed. The bending stiffness value B is calculated from the inclination of the bending moment between the curvatures of 0.5 to 1.5 and −0.5 to −1.5 in the description of “Standardization and analysis of texture evaluation” described above. In the measurement of non-woven fabrics, there are cases where bending occurs between these curvatures, and accurate numerical values are difficult to represent. Therefore, the bending stiffness B in the present invention is calculated from the inclination at 0 to the maximum bending moment value and 0 to the minimum bending moment value. This measurement is performed for both MD and CD, and an average value is obtained from the following formula (3), and this is set as the bending rigidity B. Bending rigidity B = {(B MD 2 + B CD 2 ) / 2} 1/2 (3)
次に不織布のふんわり感について説明する。ふんわり感とは、不織布をその厚み方向にどの程度圧縮できるかということや、圧縮を解放したときにどの程度厚みが回復するかによって知覚されるものである。ところで、不織布のなめらかさに関して先に述べた通り、第１層は比較的細繊度の繊維が緻密に含まれていることが好ましい。つまり密度が高くなっていることが好ましい。その結果、第１層のみでは、不織布は厚み方向に十分に圧縮しにくく、また圧縮を解放しても厚みが回復しにくい。そこで本発明の不織布においては、第１層よりも密度の低い第２層を用い、第２層によって不織布にふんわり感を付与している。この場合、第２層の密度が第１層の密度よりも１０〜８０％、特に２０〜６０％小さいと、ふんわり感の付与に効果的である。それぞれの層の密度に関しては、第１層の密度は０．０１〜０．１ｇ／ｃｍ3、特に０．０２〜０．０５ｇ／ｃｍ3であることが、不織布になめらかさを付与する観点から好ましい。一方、第２層の密度は０．００５〜０．０４ｇ／ｃｍ3、特に０．０１〜０．０３ｇ／ｃｍ3であることが、不織布にふんわり感を付与する観点から好ましい。 Next, the soft feeling of the nonwoven fabric will be described. The soft feeling is perceived by how much the nonwoven fabric can be compressed in the thickness direction, and by how much the thickness recovers when the compression is released. By the way, as mentioned above regarding the smoothness of a nonwoven fabric, it is preferable that the 1st layer contains the fiber of comparatively fineness densely. That is, the density is preferably high. As a result, with the first layer alone, the nonwoven fabric is not easily compressed in the thickness direction, and the thickness is difficult to recover even when the compression is released. Therefore, in the nonwoven fabric of the present invention, the second layer having a density lower than that of the first layer is used, and the second layer gives a soft feeling to the nonwoven fabric. In this case, if the density of the second layer is 10 to 80%, particularly 20 to 60% smaller than the density of the first layer, it is effective for imparting a soft feeling. Regarding the density of each layer, the density of the first layer is 0.01 to 0.1 g / cm 3 , particularly 0.02 to 0.05 g / cm 3 , from the viewpoint of imparting smoothness to the nonwoven fabric. preferable. On the other hand, the density of the second layer is preferably 0.005 to 0.04 g / cm 3 , particularly 0.01 to 0.03 g / cm 3 , from the viewpoint of imparting a soft feeling to the nonwoven fabric.
第２層によって不織布にふんわり感を付与するために、第２層に含まれる繊維は、圧縮に対してへたりの少ないものであることが好ましい。圧縮に対するへたりを小さくするためには、太繊度の繊維を用いることが有利である。この観点から、第２層に含まれる繊維は、その繊度が１．５〜５．０ｄｔｅｘ、特に１．７〜３．０ｄｔｅｘであることが好ましい。繊度がこの範囲内であれば、第２層の繊維の粗さが第１層側に影響を及ぼしにくくなり、第１層側の表面の表面粗さの平均偏差ＳＭＤ及び摩擦係数の平均偏差ＭＭＤが小さくなって、不織布のなめらかさが良好になる。また、第２層に含まれる繊維の繊度が第１層に含まれる繊維の繊度よりも大きいことも好ましい。この場合、第２層に含まれる繊維の繊度が、第１層に含まれる繊維の繊度よりも２０〜２００％、特に４０〜１５０％大きいと、ふんわり感の付与に効果的である。 In order to give a soft feeling to the nonwoven fabric by the second layer, it is preferable that the fibers contained in the second layer have little slack against compression. In order to reduce the sag with respect to compression, it is advantageous to use fibers having a large fineness. From this viewpoint, the fineness of the fibers contained in the second layer is preferably 1.5 to 5.0 dtex, particularly 1.7 to 3.0 dtex. If the fineness is within this range, the roughness of the fibers of the second layer is less likely to affect the first layer side, the average deviation SMD of the surface roughness of the surface of the first layer side and the average deviation MMD of the friction coefficient. Becomes smaller, and the smoothness of the nonwoven fabric becomes better. It is also preferred that the fineness of the fibers contained in the second layer is greater than the fineness of the fibers contained in the first layer. In this case, if the fineness of the fibers contained in the second layer is 20 to 200%, particularly 40 to 150% greater than the fineness of the fibers contained in the first layer, it is effective for imparting a soft feeling.
第２層が低密度であることに加えて、厚みが大きいこともふんわり感の向上の点から有利である。この観点から、第２層の厚みは０．３〜１．２ｍｍ、特に０．４〜０．８ｍｍであることが好ましい。一方、第１層の厚みは、第２層の厚みより小さいことが、なめらかさの向上の観点から好ましく、具体的には０．０５〜０．５ｍｍ、特に０．１〜０．３ｍｍであることが好ましい。不織布の全体の厚みは、０．５〜１．５ｍｍ、特に０．５〜１．０ｍｍであることが好ましい。 In addition to the low density of the second layer, a large thickness is also advantageous in terms of improving the soft feeling. From this viewpoint, the thickness of the second layer is preferably 0.3 to 1.2 mm, particularly 0.4 to 0.8 mm. On the other hand, the thickness of the first layer is preferably smaller than the thickness of the second layer from the viewpoint of improving smoothness, specifically 0.05 to 0.5 mm, particularly 0.1 to 0.3 mm. It is preferable. The total thickness of the nonwoven fabric is preferably 0.5 to 1.5 mm, particularly preferably 0.5 to 1.0 mm.
第２層が以上の構成を有することで、不織布の圧縮特性の線形性（以下ＬＣともいう）は０．３以下、好ましくは０．２５以下という極めて低い値となる。ＬＣが０．３超になると不織布に十分なふんわり感が付与されず、総合的な肌触りを良好にすることができない。ＬＣの下限値に特に制限はなく０に近ければ近いほど好ましいが、下限値が０．２、特に０．１５程度に低くなれば、不織布に十分なふんわり感が付与される。本発明においてＬＣとは、カトーテック株式会社製のＫＥＳＦＢ３−ＡＵＴＯ−Ａを用いて測定された値をいう。ＬＣは、前述の「風合い評価の標準化と解析」に記載の方法に従い測定される。具体的には以下の方法で測定される。 When the second layer has the above-described configuration, the linearity (hereinafter also referred to as LC) of the compression characteristics of the nonwoven fabric is an extremely low value of 0.3 or less, preferably 0.25 or less. When the LC exceeds 0.3, the nonwoven fabric is not given a sufficient soft feeling, and the overall feel cannot be improved. The lower limit of LC is not particularly limited and is preferably closer to 0. However, when the lower limit is as low as 0.2, particularly about 0.15, the nonwoven fabric is sufficiently soft. In the present invention, LC refers to a value measured using KESFB3-AUTO-A manufactured by Kato Tech Co., Ltd. LC is measured according to the method described in “Standardization and analysis of texture evaluation” described above. Specifically, it is measured by the following method.
〔圧縮特性の線形性ＬＣの測定法〕
２０ｃｍ×２０ｃｍの試験片を準備し、試験台に取りつける。その試験片を面積２ｃｍ2の円形平面をもつ鋼板間で圧縮する。圧縮速度は２０μｍ／ｓｅｃ、圧縮最大荷重は４．９ｋＰａとする。回復過程も同一速度で測定を行う。圧縮特性の線形性はＬＣ値で表される。ＬＣ値は下記式（４）で定義される。
[Measurement method of linearity LC of compression characteristics]
A test piece of 20 cm × 20 cm is prepared and attached to a test bench. The specimen is compressed between steel plates having a circular plane with an area of 2 cm 2 . The compression speed is 20 μm / sec, and the maximum compression load is 4.9 kPa. The recovery process is also measured at the same rate. The linearity of the compression characteristic is represented by an LC value. The LC value is defined by the following formula (4).
第１層及び第２層の坪量は、肌触りの向上の観点からは臨界的なものとはならず、不織布の具体的な用途に応じて適宜定め得るものである。不織布の坪量についても同様である。本発明の不織布を例えば使い捨ておむつや生理用ナプキン等の吸収性物品の構成材料として用いる場合には、第１層の坪量は５〜１５ｇ／ｍ2、特に７〜１２ｇ／ｍ2であることが好ましい。第２層の坪量は５〜４５ｇ／ｍ2、特に７〜２５ｇ／ｍ2であることが好ましい。不織布全体の坪量は１０〜６０ｇ／ｍ2、特に１５〜４０ｇ／ｍ2であることが好ましい。この場合、不織布の引張強度は流れ方向（ＭＤ）において１０〜１００Ｎ／５０ｍｍ、特に２０〜７０Ｎ／５０ｍｍであることが好ましく、幅方向（ＣＤ）において４〜１５Ｎ／５０ｍｍ、特に５〜１２Ｎ／５０ｍｍであることが好ましい。引張強度は、引張試験機を用い、チャック間距離１５０ｍｍ、引張速度３００ｍｍ／ｍｉｎの条件で測定される。 The basis weights of the first layer and the second layer are not critical from the viewpoint of improving the touch and can be appropriately determined according to the specific use of the nonwoven fabric. The same applies to the basis weight of the nonwoven fabric. When the nonwoven fabric of the present invention is used as a constituent material of absorbent articles such as disposable diapers and sanitary napkins, the basis weight of the first layer is 5 to 15 g / m 2 , particularly 7 to 12 g / m 2. Is preferred. The basis weight of the second layer is preferably 5 to 45 g / m 2 , particularly 7 to 25 g / m 2 . The basis weight of the entire nonwoven fabric is preferably 10 to 60 g / m 2 , particularly preferably 15 to 40 g / m 2 . In this case, the tensile strength of the nonwoven fabric is preferably 10 to 100 N / 50 mm, particularly 20 to 70 N / 50 mm in the flow direction (MD), and 4 to 15 N / 50 mm, particularly 5 to 12 N / 50 mm in the width direction (CD). It is preferable that The tensile strength is measured using a tensile tester under conditions of a distance between chucks of 150 mm and a tensile speed of 300 mm / min.
特に本発明の不織布を、吸収性物品の最外面の構成材として用いる場合には、第１層の坪量は５〜１５ｇ／ｍ2、特に７〜１２ｇ／ｍ2であることが好ましい。第２層の坪量は５〜２５ｇ／ｍ2、特に７〜２０ｇ／ｍ2であることが好ましい。不織布全体の坪量は１０〜４０ｇ／ｍ2、特に１５〜３０ｇ／ｍ2であることが好ましい。 In particular, when the nonwoven fabric of the present invention is used as a constituent material of the outermost surface of the absorbent article, the basis weight of the first layer is preferably 5 to 15 g / m 2 , particularly 7 to 12 g / m 2 . The basis weight of the second layer is preferably 5 to 25 g / m 2 , particularly 7 to 20 g / m 2 . The basis weight of the whole nonwoven fabric is preferably 10 to 40 g / m 2 , particularly preferably 15 to 30 g / m 2 .
第１層及び第２層の構成繊維に特に制限はなく、不織布の具体的な用途に応じて適切な素材の繊維が用いられる。本発明の不織布がエアスルー法によって製造されることに鑑みれば、各層に含まれる繊維は熱融着性繊維であることが好ましい。また、不織布に所望の機能を付与することを目的として、熱融着性繊維に加えて少量の非融着性繊維、例えばレーヨンやコットン、パルプ等を第１層及び／又は第２層に配合してもよい。また、本来的には熱融着性を有しているものの、本発明の不織布の製造過程における熱融着処理温度では熱融着性を発現しない繊維、例えばポリエステル系繊維やポリアミド系繊維等を第１層及び／又は第２層に配合してもよい。繊維の繊維長にも特に制限はないが、エアスルー法の原料となるウエブの形成性の観点から３８〜６０ｍｍ程度の短繊維を用いることが好ましい。 There is no restriction | limiting in particular in the constituent fiber of a 1st layer and a 2nd layer, The fiber of a suitable raw material is used according to the specific use of a nonwoven fabric. In view of the fact that the nonwoven fabric of the present invention is produced by the air-through method, the fibers contained in each layer are preferably heat-fusible fibers. In addition to the heat-fusible fiber, a small amount of non-fusible fiber such as rayon, cotton, pulp, etc. is blended in the first layer and / or the second layer in order to give the nonwoven fabric a desired function. May be. In addition, fibers that have inherently heat fusion properties but do not exhibit heat fusion properties at the heat fusion treatment temperature in the production process of the nonwoven fabric of the present invention, such as polyester fibers and polyamide fibers, etc. You may mix | blend with a 1st layer and / or a 2nd layer. Although there is no restriction | limiting in particular also in the fiber length of a fiber, It is preferable to use a short fiber about 38-60 mm from a viewpoint of the formability of the web used as the raw material of an air through method.
次に本発明の不織布の好適な製造方法を、図１を参照しながら説明する。図１には本発明の不織布を製造するために用いられる好適な装置の模式図が示されている。図１に示す装置１０は、ウエブ形成部２０、熱融着部３０及びカレンダー部４０を備えている。 Next, the suitable manufacturing method of the nonwoven fabric of this invention is demonstrated, referring FIG. FIG. 1 shows a schematic view of a suitable apparatus used for producing the nonwoven fabric of the present invention. The apparatus 10 shown in FIG. 1 includes a web forming unit 20, a heat fusion unit 30, and a calendar unit 40.
ウエブ形成部２０には第１及び第２カード機２１，２２が設置されている。第１カード機２１は、第１層の形成用の第１ウエブを製造するためのものである。第２カード機２２は、第２層の形成用の第２ウエブを製造するためのものである。原料繊維の供給部（図示せず）から各カード機２１，２２に原料繊維が供給され繊維がカーディングされる。これによって第１ウエブ１１及び第２ウエブ１２が形成される。第２ウエブ１２は、第１ウエブ１１上に重ね合わされる。これによって両ウエブの重ね合わせウエブ１３が形成される。 The web forming unit 20 is provided with first and second card machines 21 and 22. The 1st card machine 21 is for manufacturing the 1st web for formation of the 1st layer. The second card machine 22 is for producing a second web for forming the second layer. The raw fiber is supplied from the raw fiber supply unit (not shown) to each of the card machines 21 and 22, and the fiber is carded. As a result, the first web 11 and the second web 12 are formed. The second web 12 is overlaid on the first web 11. Thereby, an overlapping web 13 of both webs is formed.
ウエブ１３は、ワイヤーメッシュ等のネットのような通気性材料からなる無端縁ベルト３１によって搬送されて熱融着部３０へ導入される。熱融着部３０においては、無端縁ベルト３１上を搬送されるウエブ１３に対向する位置に、熱風の吹き付けブロア３２が設置されている。無端縁ベルト３１を挟んでブロア３２と対向する位置にはサクションボックス３３が設置されている。ウエブ１３がブロア３２の下を通過するときに、所定温度に加熱された熱風がウエブ１３を貫通し、そのときに付与される熱によってウエブに含まれている熱融着性繊維が軟化ないし溶融し、繊維どうしの交点が結合する。これによってエアスルー不織布１４が得られる。ウエブ１３を貫通した熱風はサクションボックス３３によって回収される。 The web 13 is conveyed by an endless belt 31 made of a breathable material such as a net such as a wire mesh, and is introduced into the heat fusion part 30. In the heat fusion part 30, the blower 32 of a hot air is installed in the position facing the web 13 conveyed on the endless belt 31. As shown in FIG. A suction box 33 is installed at a position facing the blower 32 with the endless belt 31 in between. When the web 13 passes under the blower 32, hot air heated to a predetermined temperature passes through the web 13, and the heat-fusible fiber contained in the web is softened or melted by the heat applied at that time. And the intersection of the fibers joins. Thereby, the air-through nonwoven fabric 14 is obtained. Hot air passing through the web 13 is collected by a suction box 33.
熱風の吹き付け温度は、ウエブ１３に含まれている熱融着性繊維の構成樹脂の融点やウエブ１３の搬送速度及び坪量等に応じて適宜決定される。熱融着成分の樹脂がポリエチレンである場合、熱風の温度は１２０〜１５０℃、特に１３０〜１４５℃であることが、繊維どうしの交点を確実に結合し得る点から好ましい。同様の理由により、熱風の吹き付け時間は５〜３０秒、特に５〜２０秒であることが好ましい。 The blowing temperature of the hot air is appropriately determined according to the melting point of the constituent resin of the heat-fusible fiber contained in the web 13, the conveyance speed of the web 13, the basis weight, and the like. When the resin of the heat fusion component is polyethylene, it is preferable that the temperature of the hot air is 120 to 150 ° C., particularly 130 to 145 ° C. from the viewpoint that the intersections of the fibers can be reliably bonded. For the same reason, the hot air blowing time is preferably 5 to 30 seconds, particularly 5 to 20 seconds.
ウエブ１３へ熱風を吹き付けるときには、ウエブ１３における第１ウエブ１１の側がベルト３１に対向し、第２ウエブ１２の側から熱風が吹き付けられる。その結果、第１ウエブ１１の側がベルト３１に押し付けられて、毛羽立ちが抑えられ平坦な表面となる。このことは、得られる不織布における第１層側の表面をなめらかにし得る点から有利である。 When hot air is blown to the web 13, the first web 11 side of the web 13 faces the belt 31, and hot air is blown from the second web 12 side. As a result, the side of the first web 11 is pressed against the belt 31, and fuzz is suppressed and a flat surface is obtained. This is advantageous in that the surface of the first layer side in the obtained nonwoven fabric can be smoothed.
このようにして得られた不織布１４は、後工程であるカレンダー部４０へ導入される。カレンダー部４０において不織布１４は多段カレンダー加工に付される。カレンダー部４０は、金属製のカレンダーロール４１並びに第１及び第２樹脂ロール４２，４３を備えている。各樹脂ロール４２，４３はカレンダーロール４１に接するように対向して配置されている。各ロール４１，４２，４３は垂直型に配置されている。不織布１４の搬送方向に関して、第１樹脂ロール４１が上流側に配置され、第２樹脂ロール４３が下流側に配置されている。 The nonwoven fabric 14 obtained in this way is introduced into the calendar unit 40 which is a subsequent process. In the calendar part 40, the nonwoven fabric 14 is subjected to multistage calendaring. The calendar unit 40 includes a metal calendar roll 41 and first and second resin rolls 42 and 43. The resin rolls 42 and 43 are arranged to face each other so as to contact the calendar roll 41. Each roll 41,42,43 is arrange | positioned at the vertical type. With respect to the conveyance direction of the nonwoven fabric 14, the first resin roll 41 is disposed on the upstream side, and the second resin roll 43 is disposed on the downstream side.
不織布１４は先ず上流側に配置された第１樹脂ロール４２とカレンダーロール４１との間に導入されて一段目のカレンダー加工に付される。このとき、第１層側がカレンダーロールに対向するように不織布１４を導入する。カレンダー加工によってカレンダーロール４１に対向している第１層側が挟圧されて第１層に含まれる繊維が変形して扁平になる。また第１層は挟圧により高密度化される。更に、挟圧によって不織布１４に「揉み」の作用が加わり、繊維どうしの結合点の一部が変形ないし破壊されて、不織布１４がしなやかになる。第１樹脂ロール４２に対向している第２層に含まれる繊維は、樹脂ロール４２が軟質な材料からなるので挟圧力を受けにくく変形しづらくなっている。また高密度化しづらくなっている。扁平に変形した第１層に含まれる繊維は、その横断面における長軸方向が、不織布１４の平面方向に配向する。 The nonwoven fabric 14 is first introduced between the first resin roll 42 and the calendar roll 41 arranged on the upstream side, and is subjected to the first-stage calendar processing. At this time, the nonwoven fabric 14 is introduced so that the first layer side faces the calendar roll. The first layer side facing the calendar roll 41 is clamped by calendar processing, and the fibers contained in the first layer are deformed and flattened. The first layer is densified by the clamping pressure. Furthermore, the “stagnation” action is applied to the nonwoven fabric 14 by the pinching pressure, and a part of the bonding point between the fibers is deformed or destroyed, and the nonwoven fabric 14 becomes supple. The fibers contained in the second layer facing the first resin roll 42 are difficult to be subjected to pinching pressure and difficult to deform because the resin roll 42 is made of a soft material. Moreover, it is difficult to increase the density. As for the fiber contained in the 1st layer deform | transformed flatly, the major axis direction in the cross section orientates in the plane direction of the nonwoven fabric 14. FIG.
一段目のカレンダー加工における線圧は、５０〜７００Ｎ／ｃｍ、特に１００〜３００Ｎ／ｃｍであることが、生産性の高いライン速度を保ちつつ、第１層に含まれる繊維を扁平に変形させやすくできる点から好ましい。カレンダーロール４１及び／又は樹脂ロールは、所定温度に加熱して用いてもよく、或いは非加熱状態で用いてもよい。好ましくはカレンダーロール４１及び樹脂ロール４２，４３の何れも非加熱状態で用いられ、カレンダー加工は室温条件下で行われる。カレンダーロール４１は鏡面加工された平滑なものであってもよく、或いは梨地等の微細な凹凸が施されたものであってもよい。樹脂ロール４２としては、例えば硬質ゴム、シリコンゴム、ウレタンゴム、ＮＢＲ、ＥＰＤＭ等の樹脂から構成されるものを用いることができる。これらの樹脂はそのＤ硬度（ＪＩＳ Ｋ６２５３）が４０〜１００度、特に７０〜９５度であることが好ましい。 The linear pressure in the first stage calendering is 50 to 700 N / cm, particularly 100 to 300 N / cm, and it is easy to deform the fibers contained in the first layer flatly while maintaining a high productivity line speed. It is preferable from the point which can be performed. The calendar roll 41 and / or the resin roll may be used after being heated to a predetermined temperature, or may be used in an unheated state. Preferably, both the calender roll 41 and the resin rolls 42 and 43 are used in an unheated state, and the calendering is performed at room temperature. The calendar roll 41 may be a mirror-finished smooth one or may be provided with fine irregularities such as a satin finish. As the resin roll 42, for example, a resin roll made of a resin such as hard rubber, silicon rubber, urethane rubber, NBR, EPDM or the like can be used. These resins preferably have a D hardness (JIS K6253) of 40 to 100 degrees, particularly 70 to 95 degrees.
次いで不織布は、下流側に配置された第２樹脂ロール４３とカレンダーロール４１との間に導入されて二段目のカレンダー加工に付される。このときも、第１層側がカレンダーロール４１に対向するように不織布１４を導入する。二段目のカレンダー加工によって、カレンダーロール４１に対向している第１層側が更に挟圧されて第１層に含まれる繊維が一層変形して扁平の度合いが大きくなる。また第１層は挟圧により一層高密度化される。更に、扁平に変形した第１層に含まれる繊維は、その横断面における長軸方向が、不織布１４の平面方向に一層配向するようになる。また、不織布１４に「揉み」の作用が加わり、しなやかさが一層向上する。 Next, the nonwoven fabric is introduced between the second resin roll 43 and the calender roll 41 arranged on the downstream side, and subjected to the second stage calendering. Also at this time, the nonwoven fabric 14 is introduced so that the first layer side faces the calendar roll 41. By the second-stage calendering, the first layer facing the calender roll 41 is further pinched, and the fibers contained in the first layer are further deformed to increase the degree of flatness. The first layer is further densified by the clamping pressure. Further, the fibers contained in the first layer deformed into a flat shape have the major axis direction in the cross section thereof further oriented in the plane direction of the nonwoven fabric 14. In addition, the “non-woven fabric” 14 is added with the effect of “stagnation”, and the flexibility is further improved.
二段目のカレンダー加工における線圧は、一段目のカレンダー加工における線圧に関して前述した範囲内から選択されることが好ましい。特に、二段目のカレンダー加工における線圧は、前述した範囲内において、一段目のカレンダー加工における線圧よりも低めにすることが、第２層側が挟圧によって高密度化されにくく、それによってＬＣが低くなり、十分なふんわり感を付与し得る点から好ましい。具体的には２０〜２００Ｎ／ｃｍ、特に２０〜１５０Ｎ／ｃｍであることが好ましい。第２樹脂ロール４３としては、第１樹脂ロール４２のＤ硬度に関して前述した範囲と同様の範囲のＤ硬度を有する材質のものを用いることが好ましい。 The linear pressure in the second stage calendering is preferably selected from the range described above with respect to the linear pressure in the first stage calendering. In particular, the linear pressure in the second-stage calendering should be lower than the linear pressure in the first-stage calendering within the above-described range. It is preferable from the viewpoint that LC becomes low and a sufficient soft feeling can be imparted. Specifically, it is preferably 20 to 200 N / cm, particularly 20 to 150 N / cm. As the second resin roll 43, it is preferable to use a material having a D hardness in a range similar to the range described above with respect to the D hardness of the first resin roll 42.
このように本製造方法は、カレンダー加工を多段で行う点に特徴の一つを有している。本発明者らの検討の結果、カレンダー加工を一段で行った場合には、カレンダー条件を過酷にしても繊維を十分に扁平に変形させることができない。また扁平に変形できたとしても、扁平な繊維の長軸方向を不織布の平面方向に確実に配向させることができない。 Thus, this manufacturing method has one of the features in that calendar processing is performed in multiple stages. As a result of the study by the present inventors, when calendering is performed in one step, the fiber cannot be sufficiently flattened even if the calendering conditions are severe. Even if it can be deformed flat, the long axis direction of the flat fiber cannot be reliably oriented in the plane direction of the nonwoven fabric.
カレンダー加工の終了後には、必要に応じ種々の後加工を不織布１４に施してもよい。例えば不織布１４を、後述するように吸収性物品の表面材として用いる場合には、各種の親水化剤を用いた親水化処理を施すことができる。 After the calendering is finished, various post-processing may be performed on the nonwoven fabric 14 as necessary. For example, when using the nonwoven fabric 14 as a surface material of an absorbent article as will be described later, a hydrophilic treatment using various hydrophilizing agents can be performed.
このようにして目的とする不織布が得られる。得られた不織布は、例えば使い捨ておむつや生理用ナプキン等の吸収性物品の構成材料、シート状パック化粧材、清拭シート用基材、含浸シート用基材等として好適に用いられる。特に本発明の不織布は、第１層側が平坦でなめらかなことから、該不織布を吸収性物品の構成材料として用いる場合には、該不織布の第１層側が、使用者の肌に接するように配されることが好ましい。不織布が使用者の肌に接するように配される具体的な使用形態としては、不織布を液透過性の表面材として用いる形態や、吸収性物品の最外面の構成材として用いる形態などが挙げられるが、これらの形態に限られない。不織布を吸収性物品の最外面の構成材として用いる場合には、吸収性物品の端縁部及び／又は側縁部で該不織布を表面材側に折り返して用いることが多いので、不織布の第１層側が吸収性物品の外方を向くように該不織布を配することで、折り返された部分における第１層の側が、使用者の肌に接するようになる。 In this way, the intended nonwoven fabric is obtained. The obtained non-woven fabric is suitably used as a constituent material of absorbent articles such as disposable diapers and sanitary napkins, sheet-shaped pack cosmetics, substrates for wiping sheets, substrates for impregnated sheets, and the like. In particular, since the nonwoven fabric of the present invention is smooth and flat on the first layer side, when the nonwoven fabric is used as a constituent material of an absorbent article, it is arranged so that the first layer side of the nonwoven fabric is in contact with the user's skin. It is preferred that Specific usage forms in which the non-woven fabric is placed in contact with the user's skin include forms using the non-woven fabric as a liquid-permeable surface material, forms using the outermost constituent material of the absorbent article, and the like. However, it is not limited to these forms. When the nonwoven fabric is used as a constituent material of the outermost surface of the absorbent article, the nonwoven fabric is often used by folding it back to the surface material side at the edge and / or side edge of the absorbent article. By arranging the nonwoven fabric so that the layer side faces the outside of the absorbent article, the side of the first layer in the folded portion comes into contact with the user's skin.
以上、本発明の不織布をその好ましい実施形態について説明したが、本発明は前記実施形態に制限されない。例えば第１層に含まれている繊維に加えて、第２層に含まれている繊維もその横断面が扁平になっていてもよい。 As mentioned above, although the nonwoven fabric of this invention was demonstrated about the preferable embodiment, this invention is not restrict | limited to the said embodiment. For example, in addition to the fibers contained in the first layer, the fibers contained in the second layer may have a flat cross section.
また前記実施形態の製造方法においては、カレンダー加工は二段であったが、これに代えて三段以上のカレンダー加工を行ってもよい。また全体的に、カレンダー加工は、室温条件下、線圧２０〜７００Ｎ／ｃｍで、金属製のカレンダーロール及びＤ硬度（ＪＩＳ Ｋ６２５３）が４０〜１００度の樹脂ロールを用いて行うことが好ましい。 Moreover, in the manufacturing method of the said embodiment, although the calendar process was two steps, it may replace with this and may perform the calendar process of three steps or more. Moreover, generally, it is preferable to perform calendering using a metal calender roll and a resin roll having a D hardness (JIS K6253) of 40 to 100 degrees at room temperature under a linear pressure of 20 to 700 N / cm.
以下、実施例により本発明を更に詳細に説明する。しかし本発明の範囲はかかる実施例に制限されない。 Hereinafter, the present invention will be described in more detail with reference to examples. However, the scope of the present invention is not limited to such examples.
〔実施例１〜６〕
図１に示す装置を用いて不織布を製造した。表１に示す組成の短繊維を、同表に示す坪量となるようにカーディングして第１及び第２ウエブを形成した。第１ウエブ上に第２ウエブを重ね合わせ、表１に示す条件でエアスルー加工し不織布を得た。このとき第１ウエブがベルトに対向し、第２ウエブの側から熱風が吹き付けられるようにした。得られた不織布を室温下で二段のカレンダー加工に付した。加工条件は表１に示す通りであった。カレンダーロールは、微粒面柄３５０番の模様が施された金属ロールであった。第１及び第２樹脂ロールは、Ｄ硬度９０度の硬質ゴムロールであった。
[Examples 1 to 6]
The nonwoven fabric was manufactured using the apparatus shown in FIG. The short fibers having the composition shown in Table 1 were carded so as to have the basis weight shown in the same table to form the first and second webs. The second web was overlaid on the first web and air-through processed under the conditions shown in Table 1 to obtain a nonwoven fabric. At this time, the first web was opposed to the belt, and hot air was blown from the second web side. The obtained nonwoven fabric was subjected to a two-step calendar process at room temperature. Processing conditions were as shown in Table 1. The calendar roll was a metal roll provided with a pattern having a fine surface pattern of 350. The first and second resin rolls were hard rubber rolls having a D hardness of 90 degrees.
〔比較例１〕
表１に示す条件で不織布を得た。本比較例ではカレンダー加工を施していない。
[Comparative Example 1]
Nonwoven fabrics were obtained under the conditions shown in Table 1. In this comparative example, calendar processing is not performed.
〔比較例２及び３〕
表１に示す条件で不織布を得た。本比較例では第１層のみを用い、第２層は用いていない。
[Comparative Examples 2 and 3]
Nonwoven fabrics were obtained under the conditions shown in Table 1. In this comparative example, only the first layer is used, and the second layer is not used.
〔比較例４〕
エアスルー加工に代えてヒートロール加工によって不織布を製造する以外は実施例１と同様にして不織布を得た。ロールの加熱温度は１３５℃であった。
[Comparative Example 4]
A nonwoven fabric was obtained in the same manner as in Example 1 except that the nonwoven fabric was produced by heat roll processing instead of air-through processing. The heating temperature of the roll was 135 ° C.
〔比較例５〕
スパンボンド法により得られた不織布について、実施例１と同条件でカレンダー加工を施した。
[Comparative Example 5]
The nonwoven fabric obtained by the spunbond method was calendered under the same conditions as in Example 1.
〔比較例６〕
表１に示す条件で不織布を得た。
[Comparative Example 6]
Nonwoven fabrics were obtained under the conditions shown in Table 1.
〔評価〕
実施例及び比較例で得られた不織布の坪量及び厚み並びに第１層及び第２層の坪量及び密度を表２に示す。また不織布の縦断面を電子顕微鏡で拡大して、第１層に含まれる繊維の横断面形状を観察し扁平度を求めた。その結果を表２に示す。更に不織布の第１層側のＳＭＤ及びＭＭＤ並びに不織布の圧縮剛さＬＣ、曲げ剛性Ｂ及び引張強度を測定した。その結果を表２に示す。更に、実施例１で得られた不織布の第１層側の表面及び不織布の縦断面の電子顕微鏡像を図２及び図３にそれぞれ示す。また比較例１で得られた不織布の第１層側の表面の電子顕微鏡像を図４に示す。
[Evaluation]
Table 2 shows the basis weight and thickness of the nonwoven fabric obtained in Examples and Comparative Examples, and the basis weight and density of the first layer and the second layer. Moreover, the longitudinal cross-section of the nonwoven fabric was expanded with an electron microscope, and the cross-sectional shape of the fiber contained in the first layer was observed to obtain the flatness. The results are shown in Table 2. Further, SMD and MMD on the first layer side of the nonwoven fabric, and compression stiffness LC, bending stiffness B and tensile strength of the nonwoven fabric were measured. The results are shown in Table 2. Furthermore, the electron microscope image of the surface by the side of the 1st layer of the nonwoven fabric obtained in Example 1 and the longitudinal cross-section of a nonwoven fabric is shown in FIG.2 and FIG.3, respectively. Moreover, the electron microscope image of the surface by the side of the 1st layer of the nonwoven fabric obtained by the comparative example 1 is shown in FIG.
更に、不織布の肌触りを、やわらかさ及びなめらかさの観点から官能評価した。評価は、１０人のパネラーを対象として以下の５段階で行った。結果は１０人の平均点で表３に示した。
・やわらかさに関して
「やわらかくて、肌触りがよい。」
５：そう思う
４：ややそう思う
３：どちらともいえない
２：あまりそう思わない
１：そう思わない
・なめらかさに関して
「なめらかで、肌触りがよい」
５：そう思う
４：ややそう思う
３：どちらともいえない
２：あまりそう思わない
１：そう思わない
Furthermore, the touch of the nonwoven fabric was subjected to sensory evaluation from the viewpoints of softness and smoothness. The evaluation was performed on the following five stages for 10 panelists. The results are shown in Table 3 with an average score of 10 people.
・ Softness “Soft and soft to the touch.”
5: I think so 4: Somewhat like 3: I can't say it either 2: I don't think so much 1: I don't think so · About smoothness “Smooth and soft to the touch”
5: I think so 4: Somewhat like 3: I can't say either 2: I don't think so much 1: I don't think so
表１及び表２に示す結果から明らかなように、各実施例で得られた不織布は、その第１層側の表面のＳＭＤ及びＭＭＤ値が低く、なめらかであることが判る。また、曲げ剛性値が低く、しなやかであることが判る。更に圧縮剛さが低く、ふんわり感が高いことが判る。更に、十分な強度を有していることも判る。また、表３に示す結果から明らかなように、各実施例で得られた不織布は、比較例の不織布に比較してやわらかで且つなめらかなものであることが判る。 As is clear from the results shown in Tables 1 and 2, the nonwoven fabric obtained in each example has a low SMD and MMD value on the surface on the first layer side, and is found to be smooth. It can also be seen that the flexural rigidity value is low and supple. Further, it can be seen that the compression stiffness is low and the soft feeling is high. Furthermore, it turns out that it has sufficient intensity | strength. Further, as is apparent from the results shown in Table 3, it can be seen that the nonwoven fabric obtained in each example is softer and smoother than the nonwoven fabric of the comparative example.
また、図２及び図３から明らかなように、実施例１で得られた不織布は、その第１層に含まれる繊維が扁平になっており、該繊維はその横断面に長軸方向が不織布の平面方向に概ね配向していることが判る。これに対して比較例１の不織布は、その第１層に含まれる繊維が円形であることが判る。なお図には示していないが、実施例１以外の実施例で得られた不織布についても、第１層に含まれる繊維が扁平になっており、該繊維はその横断面に長軸方向が不織布の平面方向に概ね配向していることを確認した。 Further, as apparent from FIGS. 2 and 3, the nonwoven fabric obtained in Example 1 has a flat fiber in the first layer, and the fiber has a long-axis direction in the transverse cross section of the nonwoven fabric. It can be seen that they are generally oriented in the plane direction. In contrast, in the nonwoven fabric of Comparative Example 1, it can be seen that the fibers contained in the first layer are circular. Although not shown in the drawings, the fibers contained in the first layer of the nonwoven fabric obtained in the examples other than Example 1 are flat, and the fibers have a long axis direction in the transverse cross section of the nonwoven fabric. It was confirmed that the film was generally oriented in the plane direction.
１０ 製造装置
１１ 第１ウエブ
１２ 第２ウエブ
１３ ウエブ
１４ 不織布
２０ ウエブ形成部
３０ 熱融着部
４０ カレンダー部
４１ カレンダーロール
４２ 第１樹脂ロール
４３ 第２樹脂ロール
DESCRIPTION OF SYMBOLS 10 Manufacturing apparatus 11 1st web 12 2nd web 13 Web 14 Nonwoven fabric 20 Web formation part 30 Heat-sealing part 40 Calender part 41 Calendar roll 42 1st resin roll 43 2nd resin roll
Claims (7)
少なくとも第１層に含まれる繊維はその横断面が扁平になっており、該繊維はその横断面の長軸方向が前記不織布の平面方向に概ね配向しており、
第１層側の表面は、その表面粗さの平均偏差ＳＭＤが２．５μｍ以下で且つ摩擦係数の平均偏差ＭＭＤが０．００８未満であり、
前記不織布の圧縮特性の線形性ＬＣが０．３以下で且つ曲げ剛性Ｂが０．０３ｃＮ・ｃｍ2／ｃｍ以下である不織布。 A nonwoven fabric produced by an air-through method, having a first layer including one surface and a second layer including the other surface, wherein the density of the second layer is lower than the density of the first layer. And
The fibers included in at least the first layer have a flat cross section, and the fibers have a major axis direction of the cross section substantially oriented in the plane direction of the nonwoven fabric,
The surface on the first layer side has an average deviation SMD of the surface roughness of 2.5 μm or less and an average deviation MMD of the friction coefficient of less than 0.008,
A nonwoven fabric in which the linearity LC of compression characteristics of the nonwoven fabric is 0.3 or less and the bending rigidity B is 0.03 cN · cm 2 / cm or less.
The absorbent article according to claim 5, wherein the nonwoven fabric is used as a constituent material of the outermost surface of the absorbent article.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2005050007A JP4683957B2 (en) | 2005-02-25 | 2005-02-25 | Non-woven |
| TW095105077A TW200643247A (en) | 2005-02-25 | 2006-02-15 | Nonwoven fabric |
| CN 200610009535 CN1824867B (en) | 2005-02-25 | 2006-02-24 | Non-weaving fabric and producing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2005050007A JP4683957B2 (en) | 2005-02-25 | 2005-02-25 | Non-woven |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2006233364A true JP2006233364A (en) | 2006-09-07 |
| JP4683957B2 JP4683957B2 (en) | 2011-05-18 |
Family
ID=36935693
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2005050007A Active JP4683957B2 (en) | 2005-02-25 | 2005-02-25 | Non-woven |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP4683957B2 (en) |
| CN (1) | CN1824867B (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013530025A (en) * | 2011-05-30 | 2013-07-25 | ザ プロクター アンド ギャンブル カンパニー | Method for evaluating the tackiness of the outer surface of an absorbent article |
| CN103603139A (en) * | 2013-12-12 | 2014-02-26 | 潍坊志和无纺布有限公司 | Heat bonding non-woven fabric and preparation method thereof |
| WO2015182441A1 (en) * | 2014-05-30 | 2015-12-03 | 花王株式会社 | Disposable diaper |
| WO2016103741A1 (en) * | 2014-12-26 | 2016-06-30 | ユニ・チャーム株式会社 | Disposable cosmetic pad |
| JP2017214470A (en) * | 2016-05-31 | 2017-12-07 | 東レ株式会社 | Moisture-permeable waterproof film |
| JP2018154317A (en) * | 2017-03-21 | 2018-10-04 | 日本バイリーン株式会社 | Interior surface material and manufacturing method thereof |
| WO2018225512A1 (en) * | 2017-06-05 | 2018-12-13 | 東洋紡株式会社 | Nonwoven fabric |
| KR20190025915A (en) * | 2016-07-07 | 2019-03-12 | 가부시키가이샤 타이키 | cosmetics |
| JP2019148043A (en) * | 2018-02-28 | 2019-09-05 | 東レ株式会社 | Spunbonded nonwoven fabric |
| CN111212939A (en) * | 2017-10-17 | 2020-05-29 | 东丽株式会社 | Spun-bonded non-woven fabric |
| WO2023286140A1 (en) * | 2021-07-12 | 2023-01-19 | 花王株式会社 | Nonwoven fabric production method, nonwoven fabric produced by same, and absorbent article comprising said nonwoven fabric as constituent member |
| JP7549995B2 (en) | 2020-08-31 | 2024-09-12 | 日本製紙クレシア株式会社 | Absorbent articles |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5610786B2 (en) * | 2010-02-17 | 2014-10-22 | 大王製紙株式会社 | Industrial wipes |
| US20120175074A1 (en) * | 2010-10-21 | 2012-07-12 | Eastman Chemical Company | Nonwoven article with ribbon fibers |
| US9273417B2 (en) | 2010-10-21 | 2016-03-01 | Eastman Chemical Company | Wet-Laid process to produce a bound nonwoven article |
| US8840757B2 (en) | 2012-01-31 | 2014-09-23 | Eastman Chemical Company | Processes to produce short cut microfibers |
| US9617685B2 (en) | 2013-04-19 | 2017-04-11 | Eastman Chemical Company | Process for making paper and nonwoven articles comprising synthetic microfiber binders |
| CN103485073B (en) * | 2013-09-30 | 2015-12-23 | 中国科学院长春应用化学研究所 | Automotive trim panel the sandwich layer system of processing of natural-fiber composite material felt and technique |
| JP5753883B2 (en) * | 2013-10-18 | 2015-07-22 | ユニ・チャーム株式会社 | Manufacturing apparatus and manufacturing method of sheet-like member related to absorbent article |
| US9605126B2 (en) | 2013-12-17 | 2017-03-28 | Eastman Chemical Company | Ultrafiltration process for the recovery of concentrated sulfopolyester dispersion |
| US9598802B2 (en) | 2013-12-17 | 2017-03-21 | Eastman Chemical Company | Ultrafiltration process for producing a sulfopolyester concentrate |
| JP6359292B2 (en) * | 2014-02-28 | 2018-07-18 | 花王株式会社 | Absorber manufacturing method |
| JP6587608B2 (en) * | 2014-03-31 | 2019-10-09 | ダイワボウホールディングス株式会社 | Non-woven fabric for skin impregnated skin coating sheet and method for producing the same |
| JP6906915B2 (en) * | 2015-09-29 | 2021-07-21 | 日東電工株式会社 | Layered article |
| CN110325155B (en) * | 2017-02-27 | 2022-07-29 | 宝洁公司 | Wearable article with characteristic material properties |
| CN107237046A (en) * | 2017-07-26 | 2017-10-10 | 唐新雄 | The process units of the free non-woven fabrics of lint |
| CN109718012A (en) * | 2017-10-27 | 2019-05-07 | 捷恩智株式会社 | Absorbent commodity |
| JP7271150B2 (en) * | 2018-11-30 | 2023-05-11 | ユニ・チャーム株式会社 | absorbent article |
| JP7113863B2 (en) * | 2020-03-27 | 2022-08-05 | ユニ・チャーム株式会社 | mask |
Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55158367A (en) * | 1979-05-26 | 1980-12-09 | Uni Charm Corp | Nonwoven fabric and method |
| JPH02175958A (en) * | 1988-09-06 | 1990-07-09 | Kao Corp | Surface material for absorbing article |
| JPH10273884A (en) * | 1997-03-27 | 1998-10-13 | Chisso Corp | Composite nonwoven cloth and absorbing material using the same |
| JPH11206811A (en) * | 1998-01-29 | 1999-08-03 | Mitsui Chem Inc | Surface material of absorbing artice |
| JP2003147670A (en) * | 2001-11-06 | 2003-05-21 | Du Pont Toray Co Ltd | Stretchable nonwoven fabric and method for producing the same |
| JP2003235896A (en) * | 2002-02-15 | 2003-08-26 | Daio Paper Corp | Absorptive article having nonwoven fabric and method of manufacturing the same |
| JP2003265528A (en) * | 2002-03-15 | 2003-09-24 | Daio Paper Corp | Disposable paper diaper |
| JP2003319970A (en) * | 2002-04-30 | 2003-11-11 | Asahi Kasei Corp | Disposable sanitary material |
| JP2004166832A (en) * | 2002-11-18 | 2004-06-17 | Kao Corp | Absorbent article |
| JP2004249079A (en) * | 2002-12-27 | 2004-09-09 | Uni Charm Corp | Pants type disposable diaper |
| JP2005000428A (en) * | 2003-06-12 | 2005-01-06 | Daio Paper Corp | Disposable diaper |
-
2005
- 2005-02-25 JP JP2005050007A patent/JP4683957B2/en active Active
-
2006
- 2006-02-24 CN CN 200610009535 patent/CN1824867B/en not_active Expired - Fee Related
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55158367A (en) * | 1979-05-26 | 1980-12-09 | Uni Charm Corp | Nonwoven fabric and method |
| JPH02175958A (en) * | 1988-09-06 | 1990-07-09 | Kao Corp | Surface material for absorbing article |
| JPH10273884A (en) * | 1997-03-27 | 1998-10-13 | Chisso Corp | Composite nonwoven cloth and absorbing material using the same |
| JPH11206811A (en) * | 1998-01-29 | 1999-08-03 | Mitsui Chem Inc | Surface material of absorbing artice |
| JP2003147670A (en) * | 2001-11-06 | 2003-05-21 | Du Pont Toray Co Ltd | Stretchable nonwoven fabric and method for producing the same |
| JP2003235896A (en) * | 2002-02-15 | 2003-08-26 | Daio Paper Corp | Absorptive article having nonwoven fabric and method of manufacturing the same |
| JP2003265528A (en) * | 2002-03-15 | 2003-09-24 | Daio Paper Corp | Disposable paper diaper |
| JP2003319970A (en) * | 2002-04-30 | 2003-11-11 | Asahi Kasei Corp | Disposable sanitary material |
| JP2004166832A (en) * | 2002-11-18 | 2004-06-17 | Kao Corp | Absorbent article |
| JP2004249079A (en) * | 2002-12-27 | 2004-09-09 | Uni Charm Corp | Pants type disposable diaper |
| JP2005000428A (en) * | 2003-06-12 | 2005-01-06 | Daio Paper Corp | Disposable diaper |
Cited By (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013530025A (en) * | 2011-05-30 | 2013-07-25 | ザ プロクター アンド ギャンブル カンパニー | Method for evaluating the tackiness of the outer surface of an absorbent article |
| CN103603139A (en) * | 2013-12-12 | 2014-02-26 | 潍坊志和无纺布有限公司 | Heat bonding non-woven fabric and preparation method thereof |
| RU2680241C2 (en) * | 2014-05-30 | 2019-02-18 | Као Корпорейшн | Disposable diaper |
| WO2015182441A1 (en) * | 2014-05-30 | 2015-12-03 | 花王株式会社 | Disposable diaper |
| JP2016005545A (en) * | 2014-05-30 | 2016-01-14 | 花王株式会社 | Disposable diaper |
| WO2016103741A1 (en) * | 2014-12-26 | 2016-06-30 | ユニ・チャーム株式会社 | Disposable cosmetic pad |
| JP2016123833A (en) * | 2014-12-26 | 2016-07-11 | ユニ・チャーム株式会社 | Disposable cosmetic pad |
| JP2017214470A (en) * | 2016-05-31 | 2017-12-07 | 東レ株式会社 | Moisture-permeable waterproof film |
| CN109475215B (en) * | 2016-07-07 | 2021-11-23 | 株式会社黛怡茜 | Cosmetic preparation |
| KR20190025915A (en) * | 2016-07-07 | 2019-03-12 | 가부시키가이샤 타이키 | cosmetics |
| CN109475215A (en) * | 2016-07-07 | 2019-03-15 | 株式会社黛怡茜 | Cosmetics |
| US11363873B2 (en) | 2016-07-07 | 2022-06-21 | Taiki Corp., Ltd. | Cosmetic |
| EP3482652A4 (en) * | 2016-07-07 | 2020-03-04 | Taiki Corp., Ltd. | Cosmetic |
| EP3744213A1 (en) * | 2016-07-07 | 2020-12-02 | Taiki Corp., Ltd. | Cosmetic |
| KR102208742B1 (en) * | 2016-07-07 | 2021-01-28 | 가부시키가이샤 타이키 | cosmetics |
| JP2018154317A (en) * | 2017-03-21 | 2018-10-04 | 日本バイリーン株式会社 | Interior surface material and manufacturing method thereof |
| JPWO2018225512A1 (en) * | 2017-06-05 | 2020-04-02 | 東洋紡株式会社 | Non-woven |
| WO2018225512A1 (en) * | 2017-06-05 | 2018-12-13 | 東洋紡株式会社 | Nonwoven fabric |
| CN111212939A (en) * | 2017-10-17 | 2020-05-29 | 东丽株式会社 | Spun-bonded non-woven fabric |
| JP7040122B2 (en) | 2018-02-28 | 2022-03-23 | 東レ株式会社 | Spunbond non-woven fabric |
| JP2019148043A (en) * | 2018-02-28 | 2019-09-05 | 東レ株式会社 | Spunbonded nonwoven fabric |
| JP7549995B2 (en) | 2020-08-31 | 2024-09-12 | 日本製紙クレシア株式会社 | Absorbent articles |
| WO2023286140A1 (en) * | 2021-07-12 | 2023-01-19 | 花王株式会社 | Nonwoven fabric production method, nonwoven fabric produced by same, and absorbent article comprising said nonwoven fabric as constituent member |
| JP7271801B1 (en) * | 2021-07-12 | 2023-05-11 | 花王株式会社 | Method for producing nonwoven fabric, method for producing absorbent article containing nonwoven fabric produced by this as a constituent member |
Also Published As
| Publication number | Publication date |
|---|---|
| JP4683957B2 (en) | 2011-05-18 |
| CN1824867B (en) | 2012-01-04 |
| CN1824867A (en) | 2006-08-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP4683957B2 (en) | Non-woven | |
| JP4683959B2 (en) | Nonwoven manufacturing method | |
| JP4744920B2 (en) | Fiber sheet processing method | |
| JP4043943B2 (en) | Flexible nonwoven fabric with wear resistance | |
| US20140127460A1 (en) | Article(s) with soft nonwoven web | |
| US20140127461A1 (en) | Article(s) with soft nonwoven web | |
| JP5374142B2 (en) | Non-woven | |
| JP2001516291A (en) | Elastic cloth stretchable in the cross direction laminated by hot spot bonding | |
| JP4566142B2 (en) | Non-woven | |
| EP2898129B1 (en) | Nonwoven webs with enhanced softness and process for forming such webs | |
| TW202023501A (en) | Air-through nonwoven fabric for absorbent article | |
| TWI359887B (en) | ||
| JP7320974B2 (en) | Nonwoven product manufacturing method and nonwoven fabric | |
| JP6946023B2 (en) | Manufacturing method of stretchable non-woven fabric sheet and stretchable non-woven fabric sheet | |
| TWI363819B (en) | ||
| JP7271801B1 (en) | Method for producing nonwoven fabric, method for producing absorbent article containing nonwoven fabric produced by this as a constituent member | |
| JP4646760B2 (en) | Method for producing elastic nonwoven fabric | |
| JP2023515837A (en) | layered nonwoven | |
| JP7096110B2 (en) | Manufacturing method of uneven non-woven fabric for absorbent articles | |
| JP5936846B2 (en) | Skin patch base fabric | |
| CN115175648B (en) | Nonwoven fabric for absorbent article and absorbent article provided with same | |
| JP2023547228A (en) | Non-woven fabrics containing filament layers | |
| JP2023066700A (en) | Nonwoven fabric and production method thereof | |
| JP2022187164A (en) | Nonwoven fabric, manufacturing method thereof, and absorbent article | |
| WO2023013790A1 (en) | Nonwoven fabric for hygiene and method for producing same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20080215 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20101021 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20101102 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20101224 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20110208 |
|
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20110208 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20140218 Year of fee payment: 3 |
|
| R151 | Written notification of patent or utility model registration |
Ref document number: 4683957 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R151 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20140218 Year of fee payment: 3 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |