JP2006231309A - Fused substance of carbon and ceramics, pyroligneous acid generated during fusion, its production method and processing method - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To eliminate waste disposal and prevent global pollution, by not disposing of paper industrial waste generated when recycling old paper, but converting the paper industrial waste into porous carbon ceramics usable as raw material of products, and performing complete recycling. <P>SOLUTION: The paper industrial waste generated when recycling old paper is converted into porous carbon ceramics by a vacuum-heating carbonizing furnace or a double-structured vacuum-carbonizing system, better-life articles and various building materials are produced using the porous carbon ceramics as raw materials, to completely recycle the paper industrial waste. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

  The present invention is a residue that is always generated when the paper industry manufactures recycled paper from waste paper. Paper industry waste, which is a complete mixture of organic, inorganic and harmful chemicals, is vacuum-treated after dehydration and drying. The organic matter is carbonized by self-combustion in a high-temperature steamed state, and at the same time, the high temperature is used to turn the inorganic material into ceramics. Contained sheet made from porous structure carbon ceramics by utilizing the moisture absorption adjustment, deodorizing power, adsorption power of carbon dioxide gas, etc., and electromagnetic wave shielding power of porous structure carbon ceramics Bedding aids in shape, living-living products and living-environment-improving products such as for customer transport vehicles, seat-in-place and flat seat and board and antibacterial treatment Board-shaped building materials and interior building materials, inclusion-type sheet shape and flat sheet shape and board shape combined with a fibrous heating face, and board shape with antibacterial treatment heating and heating building materials Interior building materials, board and block-shaped road outer wall building materials and outer wall building materials that grow plants and supply water to plants, board-shaped or spherical water purification materials, water quality filtration materials and purification building materials, soil improvement materials A method of manufacturing civil engineering landscaping materials in the shape of flower pots for afforestation and horticulture that can be changed to different.

Technology background

  Residues that must be generated in the recycle of conventional waste paper are contained as a large amount of harmful drugs, finely shaped organic and inorganic substances are discharged as a complete industrial waste in the paper industry, and the water content is high. Since it is impossible to completely separate the substances, they are completely incinerated at about 900 ° C to 1000 ° C and partly recycled as clay-based incineration ash to be used for commercialization and cement extenders. However, complete recycling is difficult, and most of them are landfilled at the final disposal site.

Problems to be solved by the invention

  Residue generated at the time of conventional waste paper recycling is a mixture of inorganic clay, organic matter, woody and various drugs, organic matter is prone to spoilage, and harmful drugs contained in it are harmful to animals and plants and the global environment. There is no method other than the method of completely extinguishing drugs and organic substances by incineration and disposing them as incineration ash, and incineration ash has a narrow range of use when considering recycling, and there is no method other than final landfill disposal in the soil There has been a problem of causing global environmental pollution.

  The present invention is a paper-making waste that has been used only to completely incinerate all effective materials from chemicals and other harmful materials contained in waste paper, and to eliminate all harmful materials and other effective materials to make them non-polluting waste. By changing the incineration method to make porous structure carbon ceramics that makes use of the characteristics of papermaking waste, it is changed into raw material materials for a wide variety of products, and the use of raw materials and commercialization of building materials and living environment improvement products, etc. are complete The purpose is to recycle.

Means for solving the problem

  In order to achieve the above-mentioned object, the porous structure carbon ceramics of the present invention is obtained by repeating hot air and stirring on a paper industry waste in which organic wood and inorganic clay are mixed in a fine state together with chemicals. Reduce the moisture causing unburned material to a complete dry state, put the vacuum high-temperature carbonization furnace or paper industry waste into a vacuum-heated steaming charcoal furnace or a double-structure vacuum carbonization system, and make a vacuum By continuing to apply high heat from 300 ° C. to 900 ° C. from the outside, carbonization proceeds while aggregating gaseous harmful gases including chemicals. When carbonization is further advanced, tar-based substances and chemicals contained in paper industry wastes become gaseous smoke, and the gas generated is rapidly cooled to extract the pyroligneous liquor and extract the pyroligneous liquor. The remaining harmful substances are re-burned again at a high temperature of 1000 ° C. or more, completely polluted and released to the atmosphere. In the process of carbonization, organic matter self-combusts and carbonizes while generating high temperature, so the inorganic clay is heated to become porous ceramics, and the structure is fine porous. This is a porous structure carbon ceramic in which fine holes and carbon are mixed in a fine form, and has deodorizing power, moisture absorption power, adsorbing power of volatile substances and carbon dioxide gas, electromagnetic wave shielding power, and capillary action.

  The porous structure carbon ceramic is formed into a single grid by forming a porous structure carbon ceramic into a granular shape by applying a paste surface to the back surface of a triple structure nonwoven fabric having high airtightness and air permeability, and applying pressure with heating high frequency. 3g to 4g, and heated and pressed to produce a belt-like continuous sheet in which a sachet containing porous structure carbon ceramics is joined together in a seat sheet of a train car, aircraft, car, etc. Built-in seat-type seat for customer transport vehicles built in, and with a continuous belt-like sheet containing porous carbon ceramics as the inner material, soft hairs and breathable static electricity on the outside A sheet-shaped living environment improvement product of porous structure carbon ceramics, which is installed between a sheet and a futon or bed mat, by sewing a bag-like cover with a cloth that does not wake up, is deodorizing, moisture absorbing, Thermal insulation and breathability Excellent, has a function to release the far-infrared, it is intended to prepare the bed in a healthy environment.

  Using the inner material of the encapsulated sheet-shaped living environment improvement product manufactured from the above porous structure carbon ceramics, the thickness is reduced, and one or two layers are stacked, roof, ceiling, wall, Installed under the surface under the floor to take advantage of the functions of porous structure carbon ceramics such as deodorization, moisture absorption, heat retention, air permeability, electromagnetic wave shielding, etc., deodorization of bad odors, elimination of volatile components in the air, air purification It is a sheet-shaped building material containing porous structure carbon ceramics that shields moisture and functions and shields electromagnetic waves, and wallpaper is applied to the surface of one side of the sheet-type building material containing envelope. It is a seat-type interior building material with a handle that can be used as a substitute for.

  Also, porous structure carbon ceramics finely pulverized into fine particles, incombustible chemical fibers or carbon fibers cut to 2 to 5 cm, glass fibers and emulsion chemical resins are mixed to form a flat sheet. It is sandwiched between non-flammable nonwoven fabrics from both sides, and the moisture content is removed by heating and drying with hot air, making use of functions such as deodorization, moisture absorption, heat retention, air permeability, and electromagnetic wave shielding of porous structure carbon ceramics. A flat sheet-shaped life-improving product and building material with no irregularities that incorporates porous structure carbon ceramics that deodorize, eliminates volatile components in the air, cleans the air, controls humidity, and shields electromagnetic waves. is there. Furthermore, it can also be used as a substitute for wallpaper and base material by changing the non-woven fabric on one side to a non-woven fabric with a pattern, or by applying makeup on the surface with a breathable cloth, paper, or non-woven fabric with a pattern on one side. It becomes a flat sheet-shaped living environment improvement article and building material with a pattern that can be made.

  Also, 10 to um or larger particulate porous carbon ceramics and glass fiber or fiber thread cut to a length of about 5 mm to 1 mm are mixed with emulsion-based cellular water resin. And further heating at around 300 ° C. to evaporate the contained water. At the time when the water evaporates, fine pores are formed at the joints of the emulsion-based cellular water-based resin, so air flow is good, and the deodorization, moisture absorption, heat retention, air permeability, carbon dioxide gas possessed by the porous structure carbon ceramics It becomes a board-shaped building material of porous structure carbon ceramics that functions to adsorb and decompose and shield electromagnetic waves. Furthermore, the antibacterial ceramic pulverized into ultrafine particles of about 0.01 um or less mixed with a cellular resin and a paint is baked or printed on the surface of the porous structural carbon ceramic board-shaped building material, Since the cellular resin has fine holes when it dries, the surface breathes, has an antibacterial effect that does not generate mold, moss, etc., and is a board of porous structure carbon ceramics with antibacterial treatment printed with a variety of patterns It becomes a shape building material.

  Inner sheet-shaped building material and patterned inner sheet-shaped interior building material manufactured from the above porous structure carbon ceramics, flat sheet-shaped building material, flat sheet-shaped interior building material with pattern, By connecting a fiber heating face to the back and inside of the board-shaped building material and the board-shaped building material with antibacterial treatment, the ceiling wall floor itself becomes a ceiling wall floor with a built-in heating device, and electricity is supplied when necessary. It can be heated with minimal heat generation energy, emits a lot of far-infrared rays, helps to deodorize, adjust humidity, clean air, shield and neutralize electromagnetic waves, and create a healthy residential space. It is a building material with heating and heating and an interior building material having a toe shape, a flat sheet shape and a board shape.

  A glass fiber or fibrous thread cut from 1 cm to 3 cm and an emulsion-based aqueous cellular resin are mixed with 10 to 1 um large and small particulate porous carbon ceramics, and the thickness is about 10 t so that the thickness becomes 5 cm or more. When pressure is pressed, pressure bonded, and fired at about 300 ° C. in a tunnel gama with built-in far-infrared rays to evaporate the water, the bubbles where the water has evaporated become fine holes and water can be circulated. Board or block-shaped road side wall building material is a porous structure with soundproofing and sound absorbing effect against roadway noise, adsorption and decomposition deodorization of vehicle exhaust gas, purification of rainwater, plant growth on roadside wall and water replenishment ability Road side wall building materials and outer wall building materials manufactured from carbon ceramics.

  When porous structure carbon ceramics, diatomaceous earth, and cellular inorganic resin are mixed together and formed into a plate or spherical shape with a pressure of about 5 to 10 tons and heated to around 300 ° C., the moisture of the cellular inorganic resin is evaporated. In order to form pore pores of 20um or more, air or water can be easily passed through, and porous structure carbon ceramics in the form of a porous or spherical water-type purification material and water-type filtration material for water purification, porous with deodorizing power It is a board shape and spherical water quality purification building material of the quality structure carbon ceramics.

  Porous structure carbon ceramics, waste paper melting material and phenolic resin are mixed together, and pressed into a flowerpot shape from about 5t to 10t to form a lightly bonded flowerpot-shaped outer material. It is a planting pot for planting and horticulture in which culture soil mixed with soil, human feces, feces dung, incineration residue of cow dung and diluted wood vinegar is put together with plants. Cultured soil becomes a nutrient source for plants, allowing plants to grow and grow even in poorly conditioned soils and climates, and phenolic resins even if the pots collapse and decompose as plants grow and decompose bacteria It becomes a nutrient source for bacteria when it is changed to urea, and the porous structure carbon ceramics improves the poor soil by becoming a bacterial floorer. Landscaping building materials.

The invention's effect

  Since the present invention is configured as described above, the following effects can be obtained.

  Paper industry waste generated at the time of recycling used paper is mixed with harmful chemicals, organic matter, and inorganic substances in a fine shape, cannot be decomposed and separated, is difficult to recycle, incinerated, and then disposed of in an aerobic state. It is a substance that has no way to promote global environmental pollution. The present invention changes this industrial waste into an effective resource, completely recycles it as a single resource, uses it as a raw material for products, eliminates industrial waste generated at the time of recycling used paper, One cause can be eliminated.

  Clay-like kaolin, which is used for the gloss of printing surfaces and has the function of emitting far-infrared rays, is contained in a large amount in paper industry waste, so that harmful chemicals, organic matter and inorganic matter remain in a fine shape. Carbonization is performed to change to porous structure carbon ceramics. Paper industry waste contains a lot of moisture, so it is easy to cause uneven carbonization, and it is difficult to perform uniform carbonization uniformly. However, repeated hot air and agitation reduce moisture that causes unburned materials. And completely dried, put into a vacuum high-temperature carbonization furnace or a double combustion type carbonization system, and complete vacuum by applying a high heat of about 400 ° C. to 1000 ° C. from the outside in a vacuum.

  At that time, tar-based substances and chemicals contained in paper industry wastes become gaseous smoke, and the generated gas is extracted by rapid cooling of the generated gas. The material is again reburned at a high temperature of 1000 ° C. or more, completely detoxified, and released to the atmosphere. In the process of carbonization, the organic matter self-combusts and generates a high temperature to reduce the volume and carbonize, and the inorganic clay is subjected to the heat of the self-combustion, and the organic and inorganic materials are completely mixed and porous. It becomes a ceramic with a quality structure.

  Its structure is a porous porous carbon ceramic with fine porous pores and carbon mixed in a fine form, so it has carbon deodorization power, moisture absorption power, carbon dioxide gas adsorption power, electromagnetic wave shielding power, Porous ceramics perform the same function and maintain a stable force, and the ceramics that account for 95% of the porous carbon ceramics that do not release the moisture when adsorbing moisture cause capillarity and cause moisture from the carbon. It has the feature of separating. Porous structure carbon ceramics is based on adsorption and decomposition of volatile substances and carbon dioxide in the air, deodorization of bad odors, improvement of living environment and global environment by shielding electromagnetic waves, capillarity phenomenon, water retention, water permeability phenomenon, porous structure Global warming phenomena such as soil improvement and plant growth promotion can be alleviated.

  In order to effectively utilize the adsorption deodorizing power and electromagnetic wave shielding power of porous structure carbon ceramics, it is necessary to maintain air permeability when processing. Adhesive paste is applied to the back of non-woven fabric with high airtightness and air permeability. The air permeability can be maintained by filling the porous non-woven fabric with a porous structure in a triple structure nonwoven fabric that has been applied and crimped, and forming a band-like solid sheet by pressure bonding by high-frequency heating.

  As for the shape of the nonwoven fabric enclosing the porous structure carbon ceramic, one side can be formed into a sachet shape, a semi-conical cylindrical shape, or a hemispherical uneven shape.

  Furthermore, if it is covered with a cloth with a soft touch and installed between a sheet and a futon or a bed mat and used as a bedding aid, the porous structure carbon ceramics deodorizes, absorbs moisture, emits air, and emits far infrared rays. In addition, it eliminates body odor, bad odor and ammonia odor, keeps the bed warm with far-infrared rays, and prevents the sick from rubbing the bed, making the bed a healthy environment.

  A porous silicate mineral with a high absorption rate of ammonia odor is sprayed on and attached to a sheet-like material between the inner materials having a double structure in contact with the waist from the center to the buttocks. By installing the ammonia odor removal sheet encapsulated in the crimping manner, the strong odor and ammonia odor of the excrement of the elderly and sick can be eliminated.

  In addition, a porous structure carbon ceramic sheet containing porous structure carbon ceramics is installed in seat cushions, chairs and other passenger seats such as train cars, airplanes, cars, etc. Fatigue feeling by maintaining the posture, deodorization of bad odors in the vehicle, good air permeability and surface irregularities can stimulate the blood circulation disorder diseases such as wrinkles.

  In addition, the porous structure carbon ceramic sheet containing the porous structure carbon ceramics is thinned and stacked on one or two layers for use in the lower part of the roof, ceiling, wall, floor surface, or porous structure. In order to effectively use the adsorption and deodorizing power of carbon ceramics and the shielding power of electromagnetic waves, the surface is decorated and a porous structure carbon ceramic sheet interior building material with a handle that can be used like interior wallpaper. Thus, it is possible to provide a healthy indoor environment that is easy for people to live by performing adsorption and decomposition of volatile substances and carbon dioxide in the room, deodorization of bad odors, air purification, humidity control function, etc. and shielding of electromagnetic waves.

  Porous structure carbon ceramics finely pulverized into fine particles, incombustible chemical fiber or carbon fiber cut to 5 to 2 cm, mixed with glass fiber and emulsion chemical resin, formed into a flat sheet, incombustible Porous structure carbon ceramics flat sheet construction material sandwiched from both sides with non-woven fabric of the non-woven fabric, taking advantage of the functions of porous structure carbon ceramics such as deodorization, moisture absorption, heat retention, air permeability, electromagnetic wave shielding, etc. Can eliminate odors from volatile components in the air, clean air, control humidity, and shield electromagnetic waves.

  Furthermore, by changing the non-woven fabric on one side to a non-woven fabric with a pattern, or by applying makeup on the surface with a breathable cloth, paper, or non-woven fabric with a pattern on one side, it can be used as a substitute for wallpaper. Since it is close to air and has high air permeability, the function of the porous structure carbon ceramics can be enhanced.

  Porous structure carbon ceramics board building material formed with porous structure carbon ceramics, glass fiber or fibrous yarn, emulsion-based cellular water-based resin is heated at the time of formation and the contained water is evaporated. Since fine pores are made at the joints of water-based foamed water-based resins, the air permeability is high, so deodorization, moisture absorption, heat retention, breathability, adsorption and decomposition of volatile substances and carbon dioxide gas possessed by porous structure carbon ceramics, By shielding electromagnetic waves, etc., it is possible to arrange a healthy indoor environment that is easy for humans to live.

  Furthermore, the cellular resin is finely punctured when it is dried by mixing the cellular resin and paint into antibacterial ceramics pulverized into ultrafine particles and baking or printing on the surface of the porous structure carbon ceramic board building material. Therefore, it is possible to print a wide variety of patterns while breathing on the surface, which eliminates the need to use wallpaper in the room, etc. Higher function can be demonstrated.

  Porous structure carbon ceramics board building materials printed with a wide variety of patterns, porous structure carbon ceramics sheet building materials and interior building materials, porous structure carbon ceramics flat sheet and building materials and interior building materials on the back and inside, By attaching the installation of the fibrous heating surface to the entire surface of the ceiling wall floor surface, it becomes a ceiling wall floor surface with a built-in heating device. When electricity is supplied when necessary, indirect heating can be performed with minimum heat generation energy. Since the fibrous heating face 18 is made of heat-resistant vinyl chloride and is laminated, it does not come into contact with the copper wire even if dew condensation due to moisture in the base material or water vapor enters the inside, and leakage of electricity, etc. There is no occurrence.

  Also, the heating heat generated by the heat generated by the fibrous heating face 18 is not directly heated by the human body, but is indirectly heated to raise the sensible temperature of the human body by warming the air. In combination with the porous carbon ceramic board building material 17, it emits far infrared rays, deodorizing power of indoor malodors, volatile substances, carbon dioxide, etc., moisture absorption, heat retention, air permeability, electromagnetic wave shielding power This makes it possible to create a healthy indoor environment that is easy for humans to live on.

  Porous structure carbon ceramics road side wall building materials and outer wall building materials mixed with porous structure carbon ceramics and mixed with glass fiber or fibrous yarn and emulsion-based aqueous cell resin, and pressure-bonded to a thickness of 5 cm or more, Bubbles where water has evaporated become fine holes, allowing air and water to flow, soundproofing and absorbing effects on roadway noise, adsorption and decomposition and deodorization of vehicle exhaust gases, purification of rainwater, plant growth and water on roadside walls Can relieve the natural environment and global warming.

  In addition, installation of board and block-shaped road side wall building materials to existing concrete road side wall materials, curbs and sidewalk curbs, and concrete is performed by fixing H-shaped steel materials at equal intervals and bobbing in the grooves. -Stable construction can be performed by inserting road and building materials in the shape of blocks and blocks.

  Since this construction maintains air permeability, the air permeability, water infiltration and water retention of the board and block-shaped road side wall building materials can be maintained. As a result, deodorization by adsorption and decomposition of vehicle exhaust gas, inundation and retention of moisture such as rainwater, rainwater purification action by rainwater etc. infiltrating road side wall building materials, and accompanying water replenishment power at the time of drought However, the growth and self-sufficiency of the plant on the side wall of the roadway can be promoted, and a porous structure carbon ceramic roadside wall building material and an outer wall building material having a soundproofing and sound absorbing effect against the noise of the roadway by including many bubbles inside the roadside wall building material can be obtained.

  In addition, water that cannot be retained inside the road side wall building material is purified and submerged in water, collected in the lower gutters, and incinerated and fermented human feces and chicken dung and diluted wood vinegar are contained in the soil inside the planted trees. , Grow into a rooted plant.

  Board-shaped porous structure carbon ceramics water purification material or spherical porous structure carbon ceramics filter medium and deodorizing material, which are formed by pressing porous structure carbon ceramics, diatomaceous earth, and cellular resin into a plate or spherical shape. Porous structure carbon ceramics water purification board building materials and deodorizing porous structure carbon ceramics water purification spherical building materials form pore pores of 20um or more when the water content of the cellular resin is evaporated. Can be easily passed through to purify water.

  Porous structure carbon ceramics and waste paper melting material and phenolic resin are mixed, pressed into a flower pot shape and lightly joined to form an outer material, and soil, culture soil, human feces, manure, Planting and horticultural flower pots that contain plant soil mixed with dilute vinegar mixed with cow and horse manure incineration residues are a source of nutrients for plants and help plants grow and grow even in adverse conditions and climate It is effective as a global greening material and an improved material for oxidized soil.

  In addition, even if the pot collapses and decomposes with the growth of the plant and the decomposition of the bacteria, the phenolic resin changes to urea and becomes a nutrient source for the bacteria, and the porous carbon ceramics are the bacterial floorer. Can improve poor soil.

  The embodiment of the porous structure carbon ceramics thoroughly stirs the paper industry waste in which the organic woody and inorganic clays are mixed with the chemicals in a fine state, and the moisture causing generation of unburned matter is about 20 t. Compressed with a press and reduced in water content into the drying chamber, and while rotating, the hot water and stirring are repeated to reduce the water content to around 20%, and the paper industry waste is heated into a steaming charcoal oven Or put it in the double structure vacuum carbonization method, keep giving high heat from about 700 ° C to 1000 ° C from the outside, maintain the temperature at about 350 ° C to 450 ° C by evacuating the internal state, Carbonize evenly. When carbonization is further advanced, tar-based substances and chemicals contained in paper industry wastes are concentrated in a gaseous smoke so that they do not flow back and absorb into the carbides, and are rapidly cooled to perform pyrolysis. The liquid is extracted, and tar-based gaseous substances and harmful chemical substances remaining after the extraction of the pyroligneous acid liquid are recombusted at a high temperature of 1000 ° C. or more, thereby making them completely pollution-free and releasing them into the atmosphere. In addition, this carbonization is to generate high temperature by burning the organic material while the organic wood and inorganic materials are mixed, and change from inorganic clay to porous ceramics by receiving the heat of the combustion. Makes porous structure carbon ceramics with an internal structure in which fine pores and carbon are mixed in a fine form, and it has deodorizing power, moisture absorption power, carbon dioxide gas adsorption power, electromagnetic wave shielding power, and capillary action. It has a function of restoring and regenerating faster than carbon.

  The embodiment shown in FIG. 1 has a highly airtight and breathable triple-structure nonwoven fabric with a glue surface on the back side and bonded by heating high-frequency pressure bonding. 4g encased, with a belt-like continuous sheet 7 in which small bags are joined together by heating and high-frequency pressure bonding, the bag-like cover is sewn with a cloth 5 that is soft on the outside and does not cause static electricity. It is the external appearance shape of the porous structure carbon ceramics sheet living environment improvement article which has the above-mentioned triple structure and is installed between a sheet and a futon or a bed mat. Figure 1 shows that the inner and outer parts are sewn into three parts 8 so that the inner and outer parts do not slip or twist, and the upper part of the upper body is in contact with the upper part, and the upper part of the center part is in contact with the hips. It is the structure made into the part 3 which touches from a lower thigh to a toe. In particular, the portion 2 in contact from the waist to the buttocks of the central part is a porous silicic acid with a high absorption rate of ammonia odor between the inner materials having a double structure considering that ammonia odor is often generated. It is installed inside so as to sandwich an ammonia odor removing sheet 6 in which a mineral is sprayed on a sheet-like object or adhered or pressure-bonded. This makes it possible to completely eliminate bad odors such as sick odor and ammonia odor, and the outer side is covered with a soft, bristle and breathable cloth 5 that does not cause static electricity. It is excellent in deodorization, moisture absorption, heat retention and breathability, has a function of emitting far-infrared rays, and makes the bed a healthy environment. Further, a laying cloth 4 in which a soft hair and a breathable cloth 5 that does not generate static electricity is extended under the pillow in the upper direction of the portion 1 that is in contact with the upper half of the uppermost part, thereby further stabilizing.

  The embodiment shown in FIGS. 2, 3, and 4 has the structure of the inner material of FIG. 1, and uses non-woven fabrics 8, 12 and 16 having a high airtightness and a breathable triple structure. A surface is applied and heat-fitted with high-frequency pressure, and in the shape of a sachet 6 in FIG. 2, a semi-conical cylindrical shape in FIG. 3, and a hemispherical uneven shape in FIG. Porous structure carbon ceramics 9, 13, and 17 are encapsulated in a filling form, and bonded with a heating high frequency to form a band-like solid sheet. 1 is sewn into the shape shown in FIG. 1, so that the living environment improvement article of the porous structure carbon ceramic sheet shown in FIG. 1 installed between the sheet and the futon or the bed mat can be obtained. If the semicircular cylindrical shape 15 of FIG. 3 and the hemispherical uneven shape 19 of FIG. 4 are incorporated in a seat seat of a train car, an aircraft, a car, etc. as they are, Passenger with a porous sheet of porous carbon ceramics that relieves discomfort, fatigue, etc., deodorizes, absorbs moisture, retains heat, and eliminates bad odors in the vehicle and cleans the air and adjusts humidity. It is a seat for transportation vehicles.

  In the embodiment shown in FIG. 5, the thickness of the strip-shaped joint sheet 20 in the shape of the semiconical cylinder of FIG. 3 and the hemispherical uneven shape of FIG. Installed in the lower part of the surface under the roof, ceiling, wall, floor, taking advantage of the functions of porous structure carbon ceramics such as deodorization, moisture absorption, heat retention, air permeability, electromagnetic shielding, etc. It is a sheet-shaped building material of porous structure carbon ceramics that shields electromagnetic waves from volatile component elimination odor, air purification, humidity control function, and the like. Further, by applying a fabric or paper 21 with good air permeability on one side of FIG. 5 and applying a makeup on the surface, it becomes an enclosed sheet-shaped interior building material that can be used as a substitute for wallpaper.

  The embodiment shown in FIG. 6 is a porous structure carbon ceramic finely pulverized into fine particles, mixed with non-combustible chemical fibers or carbon fibers cut to 2 to 5 cm, glass fibers, and an emulsion-based chemical resin. What is formed in the toroidal shape 22 is sandwiched from both sides with a non-combustible nonwoven fabric 23, bonded by removing the moisture contained by heating and warm air drying, and made into a sheet-shaped building material without unevenness, so that the roof, ceiling, When installed below the surface of walls and floors, it takes advantage of the functions of porous structure carbon ceramics such as deodorization, moisture absorption, heat retention, air permeability, and electromagnetic wave shielding to eliminate bad odors, eliminate odors from volatile components in the air, and air It is a flat sheet-shaped life improvement article and a building material having a flat sheet shape and having a built-in porous structure carbon ceramics for cleaning, humidity control function and electromagnetic wave shielding. In addition, a non-woven fabric 24 having a pattern similar to wallpaper on one side of the non-woven fabric in FIG. 6 or a fabric, paper, or non-woven fabric having a pattern similar to wallpaper on one side of FIG. By applying the above, it becomes a living environment improvement article and a building material having a flat sheet shape with a porous structure with a pattern that can be used as a substitute for wallpaper and a base material.

  The implementation of the board-shaped building material of porous structure carbon ceramics is a glass fiber cut to a length of about 1 mm to 5 mm using particulate porous structure carbon ceramics of various sizes as large as 10 um or more as a main raw material. Incombustible chemical fiber or carbon fiber and emulsion-based water quality chemical resin are mixed, 5t to 10t pressure press or roller pressure press is performed, and the core temperature is further increased in the heating chamber or tunnel heating type kiln. Is heated to around 300 ° C. so that the temperature becomes 170 ° C. to 190 ° C. to evaporate water contained in the resin. At the time when the water contained in this resin evaporates, a fine fine hole is made at the joint of the emulsion-based cellular water-based chemical resin, so that the air flow is good and the deodorization, moisture absorption, Utilizing heat retention and air permeability, it becomes a board-shaped building material of porous structure carbon ceramics that functions to deodorize and decompose malodor, adsorb and decompose carbon dioxide gas, shield electromagnetic waves, and the like.

  In the embodiment shown in FIG. 7, the board-shaped building material 26 made of porous structure carbon ceramics has a black color and poor aesthetic appearance, and it is necessary to stretch a cloth or the like on the surface in a place where decorativeness is required in the interior and exterior. However, since the functionality of the board-shaped building material 26 of the porous structure carbon ceramics is deprived when the entire surface is glued in doing so, the function is inferior, so that it is about 0.01 μm or less. After mixing the antibacterial ceramic pulverized into ultrafine particles of the above and mixing emulsion type water-based water chemical resin and paint, 0.1 mm is formed on the surface of the board-shaped building material 26 of porous structure carbon ceramics at high temperature. When the emulsion-based foam water quality chemical resin has fine holes 14 when it is dried by baking or printing to a thickness of 0.3 mm from the surface, air flow 27 on the surface is good. It has an antibacterial effect that does not cause mold, moss, etc., and makes use of various functions such as deodorization, moisture absorption, heat retention, breathability, carbon dioxide adsorption decomposition, electromagnetic wave shielding, etc. of porous structure carbon ceramics By printing, it becomes a board-shaped building material with a handle of a porous structure carbon ceramic that can improve the aesthetic scenery in a place where the decorativeness of the interior and exterior is required.

  The embodiment shown in FIG. 8 includes a porous sheet-shaped carbon ceramic encapsulated sheet-shaped building material and a patterned encased sheet-shaped interior building material, a flat sheet-shaped building material, and a flat sheet shape with a pattern. Built-in heating device by attaching fiber heating surface 29 on the back and inside of interior building material, board shape building material and board shape building material with antibacterial treatment, to the whole surface of the ceiling wall floor surface It becomes a ceiling wall floor surface, and indirect heating can be performed with a minimum of heat generation energy by simply energizing electricity when necessary. Since the fibrous heat generating face body 29 has carbon fiber entangled with a thin copper wire and is laminated with heat-resistant vinyl chloride from both outer sides, the porous structure carbon ceramic board building material 30 is Condensation due to absorbed moisture or moisture from the base material, water vapor, etc. do not contact the copper wire, and no leakage occurs. Further, the heating heat generated by the heat generated by the fibrous heating surface 29 is not directly heated by the human body, but is heated indirectly to raise the temperature of the human body by warming the air. Combined with the board-shaped building material 30 of carbon ceramic mix, the inclusion-type sheet-shaped building material, and the flat sheet-shaped building material, far infrared rays are emitted, and indoor odors, volatile substances, carbon dioxide, etc. It becomes a heating and heating building material having deodorizing power, moisture absorption, heat retention, air permeability, and electromagnetic wave shielding power.

  The embodiment shown in FIG. 9 includes porous sheet-shaped carbon ceramic inclusion sheet-shaped building material and patterned inclusion sheet-shaped interior building material, flat sheet-shaped building material, and flat sheet shape with a pattern. Internal heating materials, board-shaped building materials, and board-shaped building materials with antibacterial treatment 31 are installed in the shape of several strips of about 20% of the area on the back and inside of the building-shaped building material 31 with antibacterial treatment, and integrated into the heat source. By attaching an energization switching control device 33 that can be connected to each other and making a connection to the heat source separately for each band of the fibrous heating surface body 32, each of the bands of the fibrous heating surface body 32 can be switched between energization, Easily adjust the heat generation area and temperature, power consumption can be adjusted, and indirect heating and far-infrared rays are emitted as in Fig. 8, deodorizing power of indoor odors, volatile substances and carbon dioxide, moisture absorption, heat retention, Heat-generating heating building with air permeability and electromagnetic shielding ability And heating the heating interior building materials and sheet - is an exothermic heating material bets shape.

  In the embodiment shown in FIG. 10, a glass fiber or fiber thread cut into 1 to 3 cm and an emulsion-based aqueous cellular resin are mixed in a porous structural carbon ceramic having a particle size of 10 to 1 μm and a thickness of When the pressure is pressed about 10t so as to be 10cm or more, pressure is applied, and the moisture is evaporated by baking at about 300 ° C with tunnel gama with built-in far infrared rays, It becomes a state and becomes the board and block-shaped road side wall building material 35 which can distribute | circulate water. In addition, the existing concrete road side wall material, the curb of the roadway and the sidewalk, and the construction to be attached to the concrete 37 are performed by fixing the H-shaped steel material 36 at equal intervals, and the board and block in the groove of the H-shaped steel material 36 When stable construction is performed by inserting the shape of the road side wall building material 35, the air permeability is maintained, so that the air permeability, water infiltration and water retention of the board and block shape road side wall building material can be maintained. Deodorization due to water and decomposition, inundation and retention of water such as rain water, rain water etc. purifies the rain water 38 by inundating road side wall building materials, and has the ability to replenish water accordingly, so that plants on the road side wall can be nurtured even during drought It is a porous structure carbon ceramic road side wall building material and outer wall wall building material that has a soundproofing and sound absorbing effect against roadway noise by promoting self-sufficiency and containing many bubbles inside the road side wall building materialIn addition, water that cannot be retained inside the road side wall building material is purified and submerged, collected in the lower side ditch, and by including incinerated and fermented human feces, chicken dung, and diluted wood vinegar in the soil inside the plantation, Grow into a rooted plant.

  The board-shaped or spherical water purification material and water filtering material of porous structure carbon ceramics, the board shape of porous structure carbon ceramics with deodorizing power and the implementation of spherical water purification building materials are porous structure carbon ceramics , Diatomaceous earth and cellular inorganic resin are mixed to form a plate or spherical shape with a pressure of about 5t to 10t, and heated to around 300 ° C so that the core temperature becomes 170 ° C to 190 ° C. When the water content of the resin is evaporated, a fine pore of 20 μm or more is formed. The pores of the cellular inorganic resin after evaporating the water allow air and water to pass through easily, and further to spread the air and water to the fine pores in the porous structure carbon ceramics and diatomaceous earth. Water is a water purification material, a water quality filtration material, and a deodorizing water quality purification building material that decomposes and removes impure substances of water before passing through these fine holes.

  The embodiment shown in FIG. 11 is a mixture of porous structure carbon ceramics, waste paper melting material and a small amount of phenolic resin, which is lightly joined to a flower pot shape 40 by pressing from 5t to 10t. As an outer frame material, 3% to 5% porous structured carbon ceramics, soil, cultured soil, cultured soil 41 in which diluted wood vinegar is mixed with incineration residue of human droppings and cochlea horse droppings, together with plants 42, It is a planting plant with a plant 42 in the center and a garden pot for gardening. This planting and horticultural plant pot is a planting and horticultural plant pot that enables the plant to inhabit and grow even in adverse conditions such as drought and desert 43 and the climate by filling the edge of the pot below the level of the ground surface. Yes, immediately after planting, the culture soil inside the pot grows as a nutrient source of the plant and grows a poor plant, and the pot of the outer frame material retains water and inundates by the fine pores of the porous structure carbon ceramics. Even in soils with little climate, water is supplied to plants with retained water. In addition, even if the pot collapses and decomposes with the growth of the plant and the decomposition of the bacteria, the phenolic resin changes to urea to become a nutrient source for the bacteria, and the porous carbon ceramics are the bacterial flora. It is a civil engineering landscaping material in the shape of a flower pot for planting and horticulture that improves poor soil by becoming-.

      Cross-sectional view and oblique projection showing the shape of a sheet-shaped bedding manufactured from porous structure carbon ceramics       Cross-sectional view and oblique projection showing the shape of a sachet-shaped band-shaped solid sheet manufactured from porous structure carbon ceramics       Cross-sectional view and oblique projection showing the shape of a conical strip-shaped solid sheet manufactured from porous structure carbon ceramics       Cross-sectional view and oblique projection showing the shape of a hemispherical strip-shaped solid sheet manufactured from porous structure carbon ceramics       Cross-sectional view showing sheet-shaped patterned interior building material manufactured from porous structure carbon ceramics       Cross-sectional view showing flat sheet-shaped patterned interior building material manufactured from porous structure carbon ceramics       Cross-sectional view showing a patterned board shaped antibacterial interior building material manufactured from porous structure carbon ceramics       Cross-sectional view showing a patterned board-shaped antibacterial heating heating building material manufactured from porous structure carbon ceramics       Plan view showing a board-shaped antibacterial heating and heating building material with a handle manufactured from porous carbon ceramics       Diagonal projection showing road exterior wall construction material manufactured from porous carbon ceramics and its construction method       Cross-sectional view showing planting and gardening materials for planting and horticulture and their construction methods

Explanation of symbols

DESCRIPTION OF SYMBOLS 1 Part which upper body touches 2 Part which touches from waist to buttocks 3 Part which touches from thigh to toe 4 Laying cloth 5 Cloth which does not cause static electricity with soft hair and air permeability 6 Ammonia odor removal sheet 7, 20 Sheets 8, 12, 16 Triple structure nonwoven fabric 9, 13, 17, 26 Porous structure carbon ceramics 10, 14, 18 Heated high frequency press-bonded portion 21 Fabric or paper with a handle having good air permeability 22 Porous structure carbon Flat sheet shape of ceramics 23 Non-combustible non-woven fabric 24 Cloth, paper, non-woven fabric with good breathability 27 Air flow 28 Various patterns 29, 32 Fibrous heating face body 30, 31 Porous structure carbon Ceramic board-shaped building material 32 Side surface uncoated portion 33 Control device 34 Connection line 35 Board and block-shaped road side wall building material 3 6 H-type steel material 37 Concrete 38 Rain water 39 Drainage port 40 Flower pot-shaped outer material 41 Culture soil 42 Plant 43 Soil under bad conditions

Claims (8)

  When recycled paper is produced from waste paper, paper industry waste mixed with various chemicals, inorganic clay and woody organic matter is converted into organic matter by self-combustion using a vacuum heating steaming carbonization furnace or a double structure vacuum carbonization method. Carbonize, change the inorganic material to porous ceramics, vaporize chemicals, quickly cool and extract the pyroligneous acid liquid, reburn the harmful substances remaining after the pyroligneous acid extraction and completely eliminate it, making it completely pollution-free , Deodorizing, moisture absorption, adsorption power for carbon dioxide gas, etc., porous structure carbon ceramics having electromagnetic wave shielding power, and method for producing wood vinegar liquid.   Adhesive paste is applied to the back surface of a triple-layered air-tight and highly breathable nonwoven fabric to form two continuous layers, filled with the porous structure carbon ceramics according to claim 1, and press-bonded at high frequency with heating. The porous structure carbon ceramic according to claim 1, wherein the sheet is covered with a fabric having a soft touch, is excellent in deodorization, moisture absorption and breathability, has a far-infrared emission, and prepares a bed in a healthy environment. Bedding aids, seat cushions, chairs, etc. installed between the manufactured sheet and the futon or bed mat, and passenger seats for passenger carriages installed in passenger seats such as train cars, aircraft, cars, etc. Included sheet-shaped living-environment-improving products and building-sheet-shaped building materials used on the lower part of the roof, ceiling, wall, and floor surface, and a patterned-included sheet-shaped sheet with a decorative surface. Manufacturing method of interior building materials.   The porous structure carbon ceramic according to claim 1 and non-combustible chemical fiber or carbon fiber, glass fiber and emulsion chemical resin are mixed and formed into a flat sheet shape on both sides with a non-combustible nonwoven fabric. 2. A porous structure carbon as claimed in claim 1, wherein the sheet is made of a sheet-like building material sandwiched between odors, deodorizing bad odor, eliminating volatile components in the air, purifying air, controlling humidity, etc. and shielding electromagnetic waves. Flat sheet-shaped living environment improvement products and building materials manufactured from ceramics, non-woven fabric with a pattern on one side of the nonwoven fabric, or a breathable fabric with a pattern, paper, and a flat sheet with a pattern to which the nonwoven fabric is bonded A manufacturing method for G-shaped interior building materials.   The board-shaped building material manufactured from the porous structure carbon ceramics according to claim 1, which has free entry and exit of air and has deodorization, moisture absorption, adsorption of carbon dioxide gas, etc., and electromagnetic wave shielding ability, and ultrafine powder of antibacterial ceramics In addition to water or paint, it enhances the aesthetic landscape of the surface by baking or printing, and it is a board-shaped building material with antibacterial treatment that does not generate deodorization, moisture absorption, carbon dioxide adsorption, electromagnetic wave shielding neutralization function, mold, moss, etc. Manufacturing method.   The inner sheet-shaped building material according to claim 2 and the inner sheet-shaped interior building material with handle manufactured from the porous structure carbon ceramic according to claim 1, the flat sheet-shaped building material according to claim 3, and A flat sheet-shaped interior building material with a handle, the board-shaped building material according to claim 4 and the board-shaped building material with antibacterial treatment, when a fibrous heat generating face plate is installed and energized, the floor surface of the ceiling wall Becomes a ceiling and floor building material with heating and heating that keeps a constant temperature and interior building material, emits a lot of far infrared rays, helps deodorize, adjust humidity and purify air, and creates a healthy living space by shielding and neutralizing electromagnetic waves A method of manufacturing a building material with heating / heating and an interior building material having an encapsulated sheet shape, a flat sheet shape, and a board shape.   Porous structure carbon ceramics with a thickness of 5cm or more as a board plate or block-shaped road side wall material with heat and pressure resistance, soundproofing, sound absorption, exhaust gas adsorption and decomposition deodorization, A method for producing board and block-shaped road outer wall building materials and outer wall building materials produced from the porous structural carbon ceramics according to claim 1 by growing and supplying water to plants.   A porous structure carbon ceramic according to claim 1, diatomaceous earth, and soil with a cellular inorganic resin, and a board shape having a fine hole of 20 μm or more produced from the porous structure carbon ceramic according to claim 1 A method for producing a spherical water purification phase, a water filter medium, and a deodorizing purification building material.   The porous structure carbon ceramic according to claim 1 is lightly joined with a melting material of used paper and phenolic resin to form an outer material, and is diluted into an incineration residue of soil, culture soil, human feces, feces, and cow dung. Planting and gardening pots mixed with wood vinegar serve as a nutrient source for plants, allowing plants to grow and grow even in poorly conditioned soils. A method of manufacturing civil engineering landscaping materials in the shape of flower pots for planting and horticulture that can be changed.

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