JP2006220376A - Hot repairing method of lining castable refractory of refining vessel such as electric furnace - Google Patents

Hot repairing method of lining castable refractory of refining vessel such as electric furnace Download PDF

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JP2006220376A
JP2006220376A JP2005035279A JP2005035279A JP2006220376A JP 2006220376 A JP2006220376 A JP 2006220376A JP 2005035279 A JP2005035279 A JP 2005035279A JP 2005035279 A JP2005035279 A JP 2005035279A JP 2006220376 A JP2006220376 A JP 2006220376A
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refractory
refining vessel
castable refractory
refining
repair
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Kazuhiro Hashizume
一弘 橋爪
Kazuya Kodama
和哉 児玉
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Sanyo Special Steel Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a method for repairing a castable refractory of a refining vessel such as an electric furnace or a ladle refining furnace, whereby spalling of the repaired castable refractory is dissolved and no rebound loss is produced when repairing it. <P>SOLUTION: The castable refractory in which an amount of kneaded moisture is set to 5-10% is extruded by a cylinder spindle 18 from the tip of the cylinder spindle pipe of a hydraulic cylinder in a compression molding repairing machine disposed in the refining vessel by a swing type support arm 13 to be compression molded at the defective repair part 9 of the castable refractory lining of the refining vessel 1 kept in a high temperature state after tapping molten steel, in order to repair in a hot state the defective part of the castable refractory of the refining vessel such as an electric furnace for manufacturing steel or the ladle. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

この発明は製鋼用の電気炉あるいは取鍋精錬炉などの精錬容器に内張りされている不定形耐火物の補修に関し、特に高温状態にある精錬容器への熱間での不定形耐火物による補修に関する。   The present invention relates to repair of an irregular refractory lined in a refining vessel such as an electric furnace for steel making or a ladle smelting furnace, and more particularly to repairing a hot smelting vessel with an irregular refractory. .

従来から、製鋼用の電気炉あるいは取鍋精錬炉などの精錬容器1には、MgO系やAl23系の耐火物が内張りされて用いられている。ところで、この精錬容器1の使用により発生するこれらの耐火物の溶損部やスポーリングによる欠損部の補修には、図4に示すように、精錬直後のまだ高温状態(この状態を本明細書では「熱間」という。)にある精錬容器1に内張りされた耐火レンガ4上の不定形耐火物5と同材質の不定形耐火物粉末を水やバインダーと混練して混練物とし、をスウィング式支持アーム13で保持した不定形耐火物容器21の噴霧ノズル22から、圧縮空気管23で送給の圧縮エアーにより、不定形耐火物5の欠損補修部9に上記の混練物を吹付けて補修する方法が一般的に採用されている。例えば、ノズル付き耐火物供給ホースを旋回アーム上の摺動及び回転機構付き台車に取り付け、遠隔操作で行う方法がある(例えば、特許文献1参照。)。 Conventionally, MgO-based or Al 2 O 3 -based refractories are lined in a refining vessel 1 such as an electric furnace for steel making or a ladle refining furnace. By the way, as shown in FIG. 4, in repairing the refractory melted part and spalling part generated by the use of the refining vessel 1, a high temperature state immediately after refining (this state is described in this specification). In this case, it is called “Hot”.) The amorphous refractory powder of the same material as the amorphous refractory 5 on the refractory brick 4 lined in the smelting vessel 1 is kneaded with water or a binder to form a kneaded mixture. The above-mentioned kneaded material is sprayed from the spray nozzle 22 of the irregular refractory container 21 held by the support arm 13 to the defect repairing portion 9 of the irregular refractory 5 by the compressed air supplied by the compressed air pipe 23. A repair method is generally adopted. For example, there is a method in which a refractory supply hose with a nozzle is attached to a carriage with a sliding and rotating mechanism on a swivel arm and is operated remotely (see, for example, Patent Document 1).

しかし、このような従来の不定形耐火物の吹付けによる補修方法では、得られた耐火物のスポーリングの問題や、吹付け時のリバウンドロスによる歩留低下の問題、あるいは多大な補修時間を要する問題などの種々の問題があった。例えば、高温状態にある電気炉の補修を熱間で行うための吹付け耐火物材の概略を説明すると、吹付け耐火物材は表1に示す化学組成を含有する不定形耐火物材が一般的に使用される。なお、図3は本発明に用いる一般的な電気炉の炉体内のライニングの構成を模式的に示す断面図で、同図において精錬容器1は鉄皮2に耐火煉瓦4が内張りされ、さらに不定形耐火物4で内張りされ、さらに溶鋼8より上方の鉄皮2は水冷パネル3で冷却されている。精錬容器1は蓋6を有し、電極7が炉内に装着されている。また、図2及び図4の精錬容器1は水冷パネル3を一部省略して図示している。   However, in the conventional repair method by spraying the irregular refractory, the problem of spalling of the obtained refractory, the problem of yield reduction due to rebound loss at the time of spray, or a large repair time is required. There were various problems such as necessary problems. For example, the outline of a sprayed refractory material for hot repair of an electric furnace in a high temperature state will be described. The sprayed refractory material is generally an amorphous refractory material containing the chemical composition shown in Table 1. Used. FIG. 3 is a cross-sectional view schematically showing the configuration of the lining in a general electric furnace used in the present invention. In FIG. 3, the smelting vessel 1 has a refractory brick 4 lined on an iron shell 2 and is further not suitable. Lined with a regular refractory 4, the iron skin 2 above the molten steel 8 is cooled by a water-cooled panel 3. The refining vessel 1 has a lid 6 and an electrode 7 is mounted in the furnace. Further, the refining vessel 1 of FIGS. 2 and 4 is shown with a part of the water cooling panel 3 omitted.

Figure 2006220376
Figure 2006220376

さらに、この吹付け不定形耐火物材は表2に示す粒度分布を有する耐火物微粉末からなり、この耐火物微粉末を水と混練比5〜30%で混練した混練状態の不定形耐火物からなる。そしてこの不定形耐火物の水との混練状態の吹付け耐火物材を圧縮エアーにより熱間で電気炉内の耐火物の欠損補修部9の部分に吹付けて補修している。   Further, the sprayed amorphous refractory material is composed of a refractory fine powder having a particle size distribution shown in Table 2, and the refractory fine powder is kneaded with water at a kneading ratio of 5 to 30% in an unshaped refractory. Consists of. Then, the sprayed refractory material kneaded with water of the irregular refractory is sprayed onto the portion of the refractory defect repairing portion 9 in the electric furnace with hot air for repair.

Figure 2006220376
Figure 2006220376

ところで、この従来の吹付け耐火物材の混練状況は一般には不均一であった。さらに、この従来の補修方法は吹付けにより補修するため、熱間での吹付け時のリバウンドロスが大きく、約60〜80%程度の歩留となっている。このため粉塵の飛散も多く、周辺の作業環境は良くない問題があった。   By the way, generally the kneading | mixing condition of this conventional spraying refractory material was uneven. Further, since this conventional repair method is repaired by spraying, the rebound loss during hot spraying is large, and the yield is about 60 to 80%. For this reason, there was much dust scattering, and the surrounding work environment was not good.

さらに、上記の熱間で精錬容器へ吹付け耐火物材を吹付けて補修する方法で形成した耐火物は、混練状態の不定形の吹付け材に含有されている水分量が多いため、この不定形耐火物の耐スポーリング性が耐火レンガなどの定形耐火物に比べて非常に悪い問題があった。   Furthermore, since the refractory formed by the method of spraying and repairing the refractory material sprayed onto the smelting vessel with the above-mentioned heat has a large amount of moisture contained in the irregularly shaped spray material in the kneaded state, There was a problem that the spalling resistance of the irregular refractory was much worse than that of the regular refractory such as refractory bricks.

特開昭51−151227号公報Japanese Patent Laid-Open No. 51-151227

本発明が解決しようとする問題は、従来の不定形耐火物をエアーにより吹付けて熱間で補修する方法における耐火物のスポーリングの問題を解消し、さらに熱間での吹付け時のリバウンドロスをなくして歩留り向上を図りうる、電気炉あるいは取鍋精錬炉などの精錬容器の熱間での内張り耐火物の補修方法を提供することである。   The problem to be solved by the present invention is to eliminate the problem of spalling of refractory in the conventional method of repairing hot by spraying an irregular refractory with air, and further rebounding during hot spraying It is an object of the present invention to provide a method for repairing a lining refractory between hot smelting vessels such as an electric furnace or a ladle smelting furnace, which can improve the yield without loss.

上記の課題を解決するための本発明の手段は、第1の発明では、溶鋼を出鋼した状態の高温状態にある製鋼用電気炉又は取鍋などの精錬容器の不定形耐火物の欠損部に、水分混練量を5〜10%とした不定形耐火物を、油圧シリンダーにより押し出して圧縮成形することからなる製鋼用電気炉又は取鍋などの精錬容器の内張り耐火物の欠損部の熱間補修方法である。   Means of the present invention for solving the above-mentioned problem is that, in the first invention, the defect part of the unshaped refractory in the refining vessel such as a steelmaking electric furnace or ladle in a high temperature state where the molten steel is discharged. In addition, the hot portion of the refractory part of the lining refractory of a refining container such as an electric furnace for steel making or ladle, in which an amorphous refractory with a water kneading amount of 5 to 10% is extruded by a hydraulic cylinder and compressed. It is a repair method.

さらに第2の発明では、不定形耐火物の油圧シリンダーによる押し出しは、スウィング式支持アームで精錬容器内に配設した圧縮成形補修機の油圧シリンダーのシリンダー軸パイプの先端から不定形耐火物をシリンダー軸により押し出して圧縮成形することからなる上記の発明の手段における電気炉又は取鍋などの精錬容器の内張り耐火物の欠損部を熱間で補修する方法である。   Furthermore, in the second invention, the extrusion of the irregular refractory by the hydraulic cylinder is performed by inserting the irregular refractory from the tip of the cylinder shaft pipe of the hydraulic cylinder of the compression molding repair machine disposed in the smelting vessel with the swing type support arm. This is a method of hot repairing a defective portion of a refractory lining of a refining vessel such as an electric furnace or ladle in the means of the present invention consisting of compression molding by extruding with a shaft.

本発明の上記の手段の作用について説明すると、第1の発明の手段では、不定形耐火物を水と混練する場合の水の混練比の上限を、従来のエアーによる吹付ける方法の30%から10%へと低くすることができる。このために補修された不定形耐火物の耐スポーリング性が向上することとなる。さらに第2の発明の手段では、この圧縮成形補修機に装着された油圧シリンダーの強力な圧力により不定形耐火物の溶損などの欠損部に不定形耐火物を押し出し圧縮成形するので、不定形耐火物の付着力が向上する。   The operation of the above-mentioned means of the present invention will be described. In the means of the first invention, the upper limit of the water kneading ratio when kneading the amorphous refractory with water is from 30% of the conventional air blowing method. It can be as low as 10%. For this reason, the spalling resistance of the irregular refractory repaired is improved. Furthermore, in the means of the second invention, the amorphous refractory is extruded and compressed into a defective part such as a refractory melt of the amorphous refractory by the strong pressure of the hydraulic cylinder attached to the compression molding repair machine. Improved adhesion of refractories.

本発明は、製鋼用の電気炉や取鍋精錬炉などの精錬容器の内張りされた不定形耐火物の補修において、水分混練比が低く耐スポーリング性に優れた不定形耐火物をシリンダー軸により圧縮成形する補修方法であるので、従来の吹付けによる補修方法で要求される均一な微粉からなる不定形耐火物と異なり、本発明の方法では粗粒や中間粒の微粉より大きい粒度の不定形耐火物も使用可能となり、この結果、電気炉や取鍋から廃却した使用済みの古い耐火物もリサイクルして使用可能できる。さらに本発明の方法ではシリンダーにより押し出して圧縮成形するので、従来の吹付けに比べて不定形耐火物のリバウンドロスが大幅に軽減されて歩留が向上し、さらに補修時間の短縮ができ、補修の生産性が大きく向上するなど、本発明は従来にない優れた効果を奏する。   The present invention relates to repairing an irregular shaped refractory lined in a refining vessel such as an electric furnace for steel making or a ladle refining furnace. Since it is a compression molding repair method, unlike the amorphous refractory consisting of uniform fine powder required by the conventional spraying repair method, the method of the present invention has an irregular shape having a particle size larger than that of coarse particles or intermediate particles. Refractories can also be used, and as a result, used old refractories discarded from electric furnaces and ladles can be recycled and used. Furthermore, since the method of the present invention is extruded by a cylinder and compression-molded, the rebound loss of the irregular refractory is greatly reduced compared to conventional spraying, the yield is improved, and the repair time can be shortened. The present invention has an excellent effect that has not been achieved so far.

本発明における不定形耐火物の熱間での圧縮成形方法を実施するための最良の形態を図面を参照して説明する。本実施の形態における圧縮成形に使用する不定形耐火物の成分組成は、上記の表1に示す吹付け耐火物材の成分組成と同じ成分組成である。ここに再び表3として示す。   The best mode for carrying out the hot compression molding method for an amorphous refractory according to the present invention will be described with reference to the drawings. The component composition of the amorphous refractory used for compression molding in the present embodiment is the same as the component composition of the sprayed refractory material shown in Table 1 above. This is again shown in Table 3.

Figure 2006220376
Figure 2006220376

さらに、表3に示す成分組成から成る不定形耐火物の粒度分布は、上記の表2に示すものと同じであってもよく、またそれより大きな粒度であるふるい目4.76mmを超え20mm以下の粒度のものを骨材として、従来の吹付けによる場合の2%〜30%程度含有して混練することも可能である。このために電気炉や取鍋から廃却した定形耐火物を粉砕して得られた耐火物粒を骨材としてリサイクルすることができる。   Furthermore, the particle size distribution of the irregular refractory material having the composition shown in Table 3 may be the same as that shown in Table 2 above, and is larger than the sieve size of 4.76 mm and 20 mm or less. It is possible to mix and knead the material having a particle size of about 2% to 30% in the case of conventional spraying. For this reason, the refractory particles obtained by pulverizing the regular refractory discarded from the electric furnace or ladle can be recycled as an aggregate.

これらの不定形耐火物粉末に水を例えば8%加え、この水と不定形耐火物粉末を供給管14により、図1に示す熱間圧縮補修機10の混練機15に外部から供給する。この供給された水と不定形耐火物粉末を混練機15により混練する。次いで、混練機15から供給管16を通じて油圧シリンダー17のシリンダー軸18を内装しているシリンダーパイプ19に混練された不定形耐火物5を供給し、精錬容器1内の補修する不定形耐火物5の欠損補修部9に混練した不定形耐火物5をシリンダー軸18により押し出して圧縮成形する。この熱間圧縮成形補修機10のシリンダーによる圧縮成形圧は10〜500t/m2の範囲とする。なお、熱間圧縮補修機10は混練機15及び油圧シリンダー17を水冷ジャケット11の容器からなり、この水冷ジャケット11からなる容器の熱間圧縮補修機10は精錬容器1の上方外部からスウィング式支持アーム13で支持されており、下部にはカウンターウエイト12を有してバランスされている。またシリンダーパイプ19の角度は支点20で上下に変更できる。 For example, 8% of water is added to the amorphous refractory powder, and the water and the amorphous refractory powder are supplied from the outside to the kneading machine 15 of the hot compression repair machine 10 shown in FIG. The supplied water and the irregular refractory powder are kneaded by the kneader 15. Next, the kneaded amorphous refractory 5 is supplied from the kneader 15 to the cylinder pipe 19 that houses the cylinder shaft 18 of the hydraulic cylinder 17 through the supply pipe 16, and the irregular refractory 5 to be repaired in the refining vessel 1 is repaired. The irregular refractory 5 kneaded in the defect repairing portion 9 is extruded by a cylinder shaft 18 and compression molded. The compression molding pressure by the cylinder of the hot compression molding repair machine 10 is in the range of 10 to 500 t / m 2 . The hot compression repair machine 10 comprises a kneading machine 15 and a hydraulic cylinder 17 as a container of a water cooling jacket 11, and the hot compression repair machine 10 for the container comprising the water cooling jacket 11 is supported by a swing type from above and outside the refining container 1. It is supported by an arm 13 and has a counterweight 12 at the bottom to be balanced. The angle of the cylinder pipe 19 can be changed up and down at the fulcrum 20.

従来の吹付けによる方法と異なり、本発明では、図2に示すように、油圧シリンダー17のシリンダー軸18により圧縮成形するので、使用する際の水分混練量は不定形耐火物5の5〜10%程度と従来の吹付けによる場合の5〜30%に比して上限を略1/3と少なくすることができる。また従来の吹付けに使用する不定形耐火物のように不均一でなく、混練機10で充分混練して均一なものとしている。このため、本発明の方法では、圧縮成形時の耐火物のリバウンドロス及び耐スポーリング性は従来の吹付けによる方法に比して大きく改善されている。すなわち、リバウンドロスは従来の吹付けによる場合では約30%あったものが、本発明の方法では約0%に減少し、耐スポーリング性も従来の吹付けの方法に比して約30%改善されている。さらに熱間での補修時間も次の表4に示すように短縮されている。   Unlike the conventional spraying method, in the present invention, as shown in FIG. 2, since the compression molding is performed by the cylinder shaft 18 of the hydraulic cylinder 17, the amount of water kneading when used is 5 to 10 of the amorphous refractory 5. The upper limit can be reduced to about 1/3 as compared to about 5% to 30% in the case of conventional spraying. Further, it is not non-uniform like the conventional refractory used for spraying, but is sufficiently kneaded by the kneader 10 to be uniform. For this reason, in the method of the present invention, the rebound loss and spalling resistance of the refractory during compression molding are greatly improved as compared with the conventional spraying method. That is, the rebound loss is about 30% in the case of the conventional spraying, but is reduced to about 0% in the method of the present invention, and the spalling resistance is also about 30% as compared with the conventional spraying method. It has been improved. Furthermore, the hot repair time is shortened as shown in Table 4 below.

Figure 2006220376
Figure 2006220376

表4に本発明の熱間圧縮成形方法によるものと、従来の熱間吹付け方法によるものとを対比して補修頻度、補修時間、補修量を示す。表4に見られるとおり、本発明の方法によるものは1回の補修時間は従来法と変わらないものの、従来法に比して補修頻度が1/3〜1/5に、1分当たりの補修量も倍以上とすることも可能となり、従って、これらのトータルで補修時間は従来法に比して約6割以上も削減することができた。   Table 4 shows the repair frequency, repair time, and repair amount by comparing the hot compression molding method of the present invention with the conventional hot spraying method. As can be seen in Table 4, although the repair time for one method of the present invention is the same as that of the conventional method, the repair frequency is 1/3 to 1/5 that of the conventional method. Therefore, the total repair time can be reduced by about 60% or more compared with the conventional method.

上記の熱間圧縮成形補修機10についてさらに説明すると、不定形耐火物5を混練する混練機15は約20トンの重量を有し、油圧シリンダー17の加圧力は10〜500MPaである。熱間圧縮成形補修機10はボックスタイプの水冷ジャケット11からなる容器の底部にカウンターウエイト12を装着している。このボックスタイプの水冷ジャケット11からなる容器はスウィング式支持アーム13又は図示しないクレーンにより精錬容器1の上方から支持され、熱間の精錬容器1内に装入されている。次いで精錬容器1内の内張りされた耐火物の欠損補修部9にシリンダー軸パイプ19の先端を当てがい、10〜500MPaのシリンダー圧力で内装のシリンダー軸18により混練物の供給管16から供給された不定形耐火物を欠損補修部9に押し出して圧縮形成する。この場合、水冷ジャケット11からなる熱間圧縮成形補修機10の自重がカウンターウエイト12により増加しているので、圧縮形成のため加圧力は増強されている。   The hot compression molding repair machine 10 will be further described. The kneader 15 for kneading the irregular refractory 5 has a weight of about 20 tons, and the pressure of the hydraulic cylinder 17 is 10 to 500 MPa. The hot compression molding repair machine 10 is equipped with a counterweight 12 at the bottom of a container comprising a box type water cooling jacket 11. A container comprising the box-type water-cooled jacket 11 is supported from above the refining container 1 by a swing type support arm 13 or a crane (not shown), and is inserted into the hot refining container 1. Next, the tip of the cylinder shaft pipe 19 was applied to the refractory defect repairing portion 9 lined in the smelting vessel 1 and supplied from the kneaded product supply pipe 16 by the internal cylinder shaft 18 at a cylinder pressure of 10 to 500 MPa. An unshaped refractory is extruded into the defect repairing part 9 and compressed. In this case, since the weight of the hot compression molding repair machine 10 composed of the water-cooled jacket 11 is increased by the counterweight 12, the pressure is increased for compression formation.

本発明の方法に使用する熱間圧縮成形補修機の模式的断面図である。It is typical sectional drawing of the hot compression molding repair machine used for the method of this invention. 本発明の方法における熱間圧縮成形補修機による精錬容器の補修状況を模式的に示す断面図である。It is sectional drawing which shows typically the repair condition of the smelting container by the hot compression molding repair machine in the method of this invention. 電気炉の炉体内のライニングの構成を模式的に示す断面図である。It is sectional drawing which shows typically the structure of the lining in the furnace body of an electric furnace. 従来の不定形耐火物の吹付けによる精錬容器の補修を示す模式的断面図である。It is typical sectional drawing which shows repair of the refining container by the spraying of the conventional amorphous refractory.

符号の説明Explanation of symbols

1 精錬容器
2 鉄皮
3 水冷パネル
4 耐火レンガ
5 不定形耐火物
6 蓋
7 電極
8 溶鋼
9 欠損補修部
10 熱間圧縮補修機
11 水冷ジャケット
12 カウンターウエイト
13 スウィング式支持アーム
14 供給管
15 混練機
16 供給管
17 油圧シリンダー
18 シリンダー軸
19 シリンダー軸パイプ
20 支点
21 不定形耐火物容器
22 噴霧ノズル
23 加圧空気管
DESCRIPTION OF SYMBOLS 1 Refining container 2 Iron skin 3 Water-cooled panel 4 Refractory brick 5 Indeterminate refractory 6 Lid 7 Electrode 8 Molten steel 9 Defect repair part 10 Hot compression repair machine 11 Water-cooling jacket 12 Counterweight 13 Swing type support arm 14 Supply pipe 15 Kneader 16 Supply Pipe 17 Hydraulic Cylinder 18 Cylinder Shaft 19 Cylinder Shaft Pipe 20 Supporting Point 21 Unshaped Refractory Container 22 Spray Nozzle 23 Pressurized Air Pipe

Claims (2)

出鋼後の高温状態にある精錬容器の不定形耐火物の欠損部に水分混練量を5〜10%とした不定形耐火物を油圧シリンダーにより押し出し圧縮成形することを特徴とする精錬容器の不定形耐火物の欠損部の熱間補修方法。   The irregularity of the refining vessel is characterized by extruding and compressing an irregularly shaped refractory with a water kneading amount of 5 to 10% into a defective portion of the irregularly shaped refractory in the refining vessel in a high-temperature state after steelmaking. Hot repair method for defects in standard refractories. 不定形耐火物の油圧シリンダーによる押し出しはスウィング式支持アームで精錬容器内に配設した圧縮成形補修機の油圧シリンダーのシリンダー軸パイプの先端から不定形耐火物をシリンダー軸により押し出し圧縮成形することを特徴とする請求項1に記載の精錬容器の不定形耐火物の欠損部の熱間補修方法。   Extrusion of irregular refractories by hydraulic cylinders is a compression-type compression arm formed by extruding irregular refractories from the tip of the cylinder shaft pipe of a hydraulic cylinder of a compression molding repair machine placed in a refining vessel with a swing type support arm. The hot repair method of the defect | deletion part of the irregular-shaped refractory of the refining container of Claim 1 characterized by the above-mentioned.
JP2005035279A 2005-02-10 2005-02-10 Hot repairing method of lining castable refractory of refining vessel such as electric furnace Pending JP2006220376A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2005035279A JP2006220376A (en) 2005-02-10 2005-02-10 Hot repairing method of lining castable refractory of refining vessel such as electric furnace

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
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Publications (1)

Publication Number Publication Date
JP2006220376A true JP2006220376A (en) 2006-08-24

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008018601A1 (en) 2006-08-11 2008-02-14 Tosoh Corporation Catalyst composition for polyurethane resin production and method for producing polyurethane resin
CN103542728A (en) * 2013-11-18 2014-01-29 龙南龙钇重稀土科技股份有限公司 Device for repairing furnace lining of smelting furnace
CN106476002A (en) * 2015-08-31 2017-03-08 中冶宝钢技术服务有限公司 The resistance to material of ladle liner disintegrates and uses bridge type mechanical handss and its operational method

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008018601A1 (en) 2006-08-11 2008-02-14 Tosoh Corporation Catalyst composition for polyurethane resin production and method for producing polyurethane resin
CN103542728A (en) * 2013-11-18 2014-01-29 龙南龙钇重稀土科技股份有限公司 Device for repairing furnace lining of smelting furnace
CN106476002A (en) * 2015-08-31 2017-03-08 中冶宝钢技术服务有限公司 The resistance to material of ladle liner disintegrates and uses bridge type mechanical handss and its operational method

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