JP2006206677A - Anionic aqueous dispersion of butyl rubber thermoplastic elastomer and its preparation method - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide an aqueous dispersion of a butyl rubber thermoplastic elastomer with a small particle size, which is excellent in shelf stability and performance and does not cause any discoloring or bleedout of a surfactant when the aqueous dispersion is dried and converted into a solid form, and its preparation method. <P>SOLUTION: The anionic aqueous dispersion of the butyl rubber thermoplastic elastomer is obtained by emulsifying and dispersing the butyl rubber thermoplastic elastomer in the presence of 1-15 pts.wt. anionic surfactant against 100 pts.wt. butyl rubber thermoplastic elastomer. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

The present invention relates to an anionic aqueous dispersion of a butyl rubber thermoplastic elastomer and a method for producing the same.

Various types of thermoplastic elastomers are used in a wide range of industrial fields, taking advantage of the fact that they can be mechanically molded in the same way as plastics while being the same elastic body as rubber. Among these, in particular, a diene thermoplastic elastomer such as SBS (polystyrene-polybutadiene-polystyrene block copolymer) in which butadiene is introduced as a soft segment is softer and has a permanent set when compared with other thermoplastic elastomers. Manufactured for a long time than small. However, these diene-based thermoplastic elastomers have problems such as inferior heat resistance and weather resistance because they have an unsaturated bond in the block portion of polybutadiene. As this improved product, a thermoplastic elastomer of SEBS (polystyrene-poly (ethylene-butadiene) -polystyrene block copolymer) type, in which heat resistance and weather resistance are improved by hydrogenating unsaturated bonds, has been produced. However, since a small amount of unsaturated bonds remain, further improvement may be required.

On the other hand, by introducing isobutylene as a block part, a thermoplastic elastomer such as a SIBS (polystyrene-polyisobutylene-polystyrene) type that does not contain any unsaturated bond in the product has been devised. Since there is no saturated bond, development is progressing as a material excellent not only in heat resistance and weather resistance but also in gas barrier properties and vibration damping properties due to the structure of polyisobutylene as a block portion. Thermoplastic elastomers having these polyisobutylenes as block portions may be classified as butyl rubber-based thermoplastic elastomers in order to distinguish them from SEBS type thermoplastic elastomers. Many of these butyl rubber-based thermoplastic elastomers are used by machine molding such as extrusion molding, but as coating agents for various materials, adhesives, binders, modifiers such as emulsions, fiber convergence agents, etc. When using, provision with an aqueous dispersion is required.
Many studies have been made on aqueous dispersions of thermoplastic elastomers, mainly diene thermoplastic elastomers. Usually, an organic phase obtained by dissolving a diene thermoplastic elastomer in an organic solvent and an emulsifier are dissolved. The aqueous phase is mixed and emulsified using a homomixer, an ultrasonic disperser or the like, and then the organic solvent is removed (see Patent Documents 1 and 2).
On the other hand, an aqueous dispersion of a butyl rubber thermoplastic elastomer is not known, and it is desired to establish an aqueous dispersion of a butyl rubber thermoplastic elastomer having excellent characteristics and a method for producing the same.
Japanese Patent Publication No.55-8020 JP 2003-253134 A

An object of the present invention is a butyl rubber-based thermoplastic elastomer having a small particle size, excellent storage stability, and excellent performance without coloring or surfactant bleeding when the aqueous dispersion is dried to form a solid. An aqueous dispersion of the present invention and a method for producing the same.

The present invention relates to a butyl rubber thermoplastic elastomer obtained by emulsifying and dispersing a butyl rubber thermoplastic elastomer in the presence of an anionic surfactant at a ratio of 1 to 15 parts by weight with respect to 100 parts by weight of the butyl rubber thermoplastic elastomer. The present invention relates to an anionic aqueous dispersion and a method for producing the same.
The present invention is described in detail below.

The butyl rubber-based thermoplastic elastomer used in the present invention is not particularly limited as long as it is a thermoplastic elastomer having polyisobutylene as a block portion. For example, (A) a block portion composed of isobutylene as a main monomer, And (B) various known materials such as a copolymer comprising a block portion composed of an aromatic vinyl compound as a main monomer. Specific examples of the aromatic vinyl compound used here include styrene, o-, m- or p-methylstyrene, α-methylstyrene, and the like. These may be used alone or in combination of two or more.

The content of the isobutylene monomer in the block portion composed of isobutylene as the main monomer and the content of the aromatic vinyl compound in the block portion composed of the aromatic vinyl compound as the main monomer are preferably 60% by weight or more, respectively. 80% by weight or more is more preferable.

Specific examples of such a butyl rubber thermoplastic elastomer include polystyrene-polyisobutylene-polystyrene block copolymer, poly α-methylstyrene-polyisobutylene-polyα-methylstyrene block copolymer, and poly p-methylstyrene- Examples thereof include polyisobutylene-poly p-methylstyrene block copolymers, polystyrene-polyisobutylene block copolymers, and halides thereof. Among these, a polystyrene-polyisobutylene-polystyrene block copolymer is particularly preferably used. These butyl rubber-based thermoplastic elastomers may be used alone or in combination of two or more.

The content ratio of the block portion composed of (A) isobutylene as the main monomer in the above-mentioned butyl rubber-based thermoplastic elastomer is not particularly limited, but usually (A) isobutylene is the main monomer. The block portion is preferably set to 40 to 95% by weight, more preferably 50 to 90% by weight.
The surfactant used in the present invention is not particularly limited as long as it is an anionic surfactant. For example, aliphatic polyoxyalkylene ether sulfate, polyoxyalkylene alkylphenyl ether sulfate, alkylbenzene sulfonate, Alkyl naphthalene sulfonate, alkyl diphenyl sulfonate, α-olefin sulfonate, alkyl sulfate ester salt, naphthalene sulfonate formalin condensate, dialkyl sulfosuccinate, polyoxyethylene alkyl ether acetate, rosinate and fatty acid Examples thereof include fatty acid salts such as sodium and fatty acid potassium. These may be used alone or in admixture of two or more.

Among these anionic surfactants, at least one selected from the group consisting of dialkyl sulfosuccinates, aliphatic polyoxyalkylene ether sulfates, fatty acid salts and alkylbenzene sulfonates is preferable. .

The dialkylsulfosuccinate has the following general formula [I]
YO ₃ SCH (CH ₂ COOR ¹ ) COOR ² [I]
(Wherein Y represents a sodium salt, a potassium salt, an amine salt or an ammonia salt, and R ¹ and R ² may be the same or different and each represents an alkyl group having 5 to 12 carbon atoms or a phenyl group). It is a compound represented.
Specific examples of the dialkylsulfosuccinate include dioctylsulfosuccinate, diethylhexylsulfosuccinate, dialkylphenylsulfosuccinate, didodecylsulfosuccinate and the like. Among them, particularly preferable results are obtained when dioctyl sulfosuccinate is used.

The aliphatic polyoxyalkylene ether sulfate has the general formula [II]
R ³ (AO) _n SO ₃ Y [II]
(In the formula, Y represents a sodium salt, potassium salt, amine salt or ammonia salt, R ³ represents an alkyl group having 5 to 24 carbon atoms or an alkenyl group having 5 to 24 carbon atoms, and n represents an addition mole) the .AO represents an integer of 2 to 50 indicate the _{number, - (- C 2 H 4} O-) n1 - (- C 3 H 6 O-) n2 - (n1 = 0~50, n2 = 0~50, However, an n1 + n2 = 2 to 50, when n1 ≠ 0 and _{n2 ≠ 0, -C 2 H 4} O- and _-C 3 order of the _H 6 O-regardless, in block or at random.) the It is a compound represented by.
Specific examples of the aliphatic polyoxyalkylene ether sulfate include polyoxyalkylene lauryl ether sulfate and polyoxyalkylene oleyl ether sulfate. Examples of the polyoxyalkylene lauryl ether sulfate include sodium polyoxyalkylene lauryl ether sulfate such as sodium polyoxyethylene lauryl ether sulfate and polyoxyalkylene lauryl ether ammonium sulfate such as ammonium polyoxyethylene lauryl ether sulfate. Examples of the polyoxyalkylene oleyl ether sulfate include sodium polyoxyalkylene oleyl ether sulfate such as sodium polyoxyethylene oleyl ether sulfate and sodium polyoxypropylene oleyl ether sulfate, and polyoxyalkylene oleyl ether ammonium sulfate. Among them, polyoxyalkylene lauryl ether sulfate, particularly sodium polyoxyalkylene lauryl ether sulfate is preferable, and particularly preferable results are obtained when sodium polyoxyethylene lauryl ether sulfate is used.

The fatty acid salt has the general formula [III]
R ³ COOM [III]
(Wherein R ³ represents an alkyl group having 5 to 24 carbon atoms or an alkenyl group having 5 to 24 carbon atoms, and M represents a sodium salt, potassium salt, ammonia salt or amine salt). is there.
Specific examples of fatty acid salts include, for example, oleate, stearate, laurate, myristate, palmitate, etc. Among them, oleate was used in particular. In some cases, favorable results are obtained.

The alkylbenzene sulfonate has the general formula [IV]
R ⁴ C ₆ H ₄ SO ₃ M
(Wherein R ⁴ represents an alkyl group having 5 to 24 carbon atoms, and M represents a sodium salt, a potassium salt, an ammonium salt or an amine salt).
Specific examples of alkylbenzene sulfonates include linear alkylbenzene sulfonates, among which linear alkyl (C ₁₀ -C ₁₄ ) benzene sulfonates are preferred, especially dodecyl benzene sulfone. Favorable results are obtained when using acid salts, among them sodium dodecylbenzenesulfonate.

In general, the amount of the anionic surfactant added is preferably set so that the ratio with respect to 100 parts by weight of the butyl rubber-based thermoplastic elastomer is 1 to 15 parts by weight, and is set to be 1 to 7 parts by weight. More preferred. When the ratio of the anionic surfactant is less than 1 part by weight, a stable aqueous dispersion may not be obtained. Conversely, if it exceeds 15 parts by weight, emulsification is facilitated, but it is uneconomical, and various physical properties of the anionic aqueous dispersion of the resulting butyl rubber-based thermoplastic elastomer may be impaired.

In addition to anionic surfactants, nonionic surfactants other than the above anionic surfactants or anionic or nonionic polymer dispersion stabilizers may be used in combination.
Examples of nonionic surface activity include polyoxyethylene alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene sorbitan alkylate, oxyethylene oxypropylene block copolymer, and polyglycerin ester.
On the other hand, examples of the polymer dispersion stabilizer include polyvinyl alcohol, hydroxyethyl cellulose, methyl cellulose, hydroxypropyl cellulose, polyacrylate, polyacrylate salt, sodium alginate and the like.

The anionic aqueous dispersion of the butyl rubber thermoplastic elastomer of the present invention is not particularly limited as long as it is obtained by emulsifying and dispersing a butyl rubber thermoplastic elastomer using an anionic surfactant. For example, as a manufacturing method thereof, (1) an organic phase in which a butyl rubber-based thermoplastic elastomer is dissolved in an organic solvent and an aqueous phase in which an anionic surfactant is dissolved in water are mixed and emulsified, and then the organic solvent is retained. And (2) a method comprising stirring and emulsifying and dispersing a butyl rubber-based thermoplastic elastomer in an aqueous medium under heating in the presence of an anionic surfactant, followed by cooling.

As the method for producing the anionic aqueous dispersion of the butyl rubber thermoplastic elastomer of the present invention, the method (1) is preferably used because the butyl rubber thermoplastic elastomer is easily dissolved in an organic solvent.

In the production method (1) in the present invention, the organic solvent used for preparing the organic phase containing the butyl rubber-based thermoplastic elastomer is not particularly limited, but usually pentane, hexane, heptane, octane. Acyclic aliphatic hydrocarbon organic solvents such as cyclohexane, cycloaliphatic hydrocarbon organic solvents such as cyclohexane, and aromatic hydrocarbon organic solvents such as benzene, toluene and xylene. These organic solvents may be used alone or in combination of two or more. Furthermore, lower alcohols such as methanol, ethanol, isopropyl alcohol, and t-butanol may be used in combination as a dissolution aid.

In preparing the organic phase, the dissolution ratio of the butyl rubber-based thermoplastic elastomer is not particularly limited, but is preferably set so that the solid content concentration in the organic phase is 5 to 50% by weight. The melting temperature is not particularly limited, and it is usually dissolved at a temperature up to 100 ° C.

When preparing an aqueous phase in which an anionic surfactant is dissolved, the surfactant is usually added and dissolved in water. At this time, the addition amount of the surfactant is not particularly limited, but is preferably set so that the concentration in the aqueous phase is 0.1 to 50% by weight.

In the step of mixing and emulsifying an organic phase containing a butyl rubber-based thermoplastic elastomer and an aqueous phase containing a surfactant, the mixing ratio of the organic phase and the aqueous phase is usually that of the aqueous phase relative to 100 parts by weight of the organic phase. The ratio is preferably set to 20 to 500 parts by weight, and more preferably set to 25 to 200 parts by weight. When the proportion of the aqueous phase is less than 20 parts by weight, emulsification may not be possible or the viscosity of the resulting emulsion may be very high. Conversely, if it exceeds 500 parts by weight, emulsification is possible, but productivity is poor and impractical.

The method for mixing and emulsifying the organic phase and the aqueous phase is not particularly limited. For example, a method of stirring and mixing using an emulsifier having an appropriate shearing force, such as a homogenizer or a colloid mill, A method of dispersing and mixing using an ultrasonic disperser or the like can be employed, but a method of stirring and mixing is preferably employed. Moreover, the temperature at the time of emulsification is not particularly limited, but is preferably set in the range of 5 to 70 ° C.

The anionic aqueous dispersion of the butyl rubber thermoplastic elastomer of the present invention can be obtained by distilling off the organic solvent from the emulsion obtained by the above-described emulsification step. In general, the organic solvent can be distilled off according to a usual distillation method in which the emulsion is heated under reduced pressure. The anionic aqueous dispersion of the butyl rubber-based thermoplastic elastomer thus obtained can be concentrated to a desired solid content concentration by an operation such as heat concentration, centrifugal separation or wet separation, if necessary.

In the present invention, the average particle size of the butyl rubber thermoplastic elastomer particles is preferably 0.1 to 3 μm. When the average particle size is less than 0.1 μm, the standing stability of the latex is increased, but the viscosity becomes high and handling may be difficult. On the other hand, if it exceeds 3 μm, the stationary stability of the latex may be lowered. In addition, this average particle diameter can be achieved by appropriately adjusting the stirring and mixing operation in the emulsification step.

The anionic aqueous dispersion of a butyl rubber thermoplastic elastomer of the present invention is obtained by emulsifying and dispersing butyl rubber thermoplastic elastomer particles in an aqueous dispersion medium. The above-mentioned dialkyl sulfosuccinate and aliphatic polyoxy Since an anionic surfactant represented by alkylene ether sulfate, fatty acid salt, alkylbenzene sulfonate and the like is included, anionic property is imparted.

Since the anionic aqueous dispersion of the butyl rubber thermoplastic elastomer of the present invention contains the specific anionic surfactant as described above, the dispersed butyl rubber thermoplastic elastomer particles have a small particle size, and Excellent storage stability, especially static stability.

By drying the anionic aqueous dispersion of the butyl rubber-based thermoplastic elastomer of the present invention, molded articles such as films, films and sheets containing an anionic surfactant and a butyl rubber-based thermoplastic elastomer can be obtained.
The molded article of the butyl rubber thermoplastic elastomer obtained from the anionic aqueous dispersion of the butyl rubber thermoplastic elastomer of the present invention is also one aspect of the present invention.
Although it does not specifically limit as temperature conditions for producing the said molded article, It is preferable to dry at the temperature of 40-200 degreeC.
Since the anionic surfactant is excellent in thermal stability, the molded product of the butyl rubber-based thermoplastic elastomer is not colored due to the anionic surfactant.
Further, since the anionic surfactant is excellent in compatibility with the butyl rubber-based thermoplastic elastomer, almost no bleeding of the anionic surfactant from the molded product of the butyl rubber-based thermoplastic elastomer is observed.
Therefore, this anionic aqueous dispersion of a butyl rubber thermoplastic elastomer can be used as a plastic molding, a coating agent for fibers, paper, films, etc., a gas barrier agent, a raw material for foam rubber, a fiber or glass fiber converging agent, or a hose or tube. It is widely usable as a raw material for belts, gaskets and packing molding materials, and has great industrial value.

According to the present invention, an anionic aqueous dispersion of a butyl rubber-based thermoplastic elastomer having a small particle size and excellent storage stability and a method for producing the same are provided. Since the anionic aqueous dispersion of the butyl rubber thermoplastic elastomer of the present invention has good compatibility between the anionic surfactant and the butyl rubber thermoplastic elastomer, the bleed of the surfactant does not occur when the molded product is dried. In addition, since there is no coloring, a material having excellent heat resistance, weather resistance, gas barrier properties, and vibration damping properties can be provided.

Example 1
30 g of polystyrene-polyisobutylene-polystyrene block copolymer (isobutylene content = 77 wt%) and 170 g of toluene were added to a separable flask having an internal volume of 500 ml, and dissolved by stirring at 50 ° C. for 4 hours. An aqueous solution in which 1.5 g of sodium dioctylsulfosuccinate is dissolved in 100 g of water is added to the obtained toluene solution, and this is used with a homomixer (trade name “TK homomixer M type” manufactured by Tokushu Kaika Co., Ltd.). And stirred for 2 minutes to obtain an emulsion. The rotation speed and temperature during stirring and mixing were set to 12000 rpm and 40 ° C., respectively. The obtained emulsion was heated to 40 to 70 ° C. under reduced pressure of 40 to 90 kPa, and toluene was distilled off. As a result, an anionic aqueous dispersion of polystyrene-polyisobutylene-polystyrene block copolymer was obtained.

Example 2
To a separable flask having an internal volume of 500 ml, 30 g of a polystyrene-polyisobutylene-polystyrene block copolymer (isobutylene content = 77% by weight), 153 g of cyclohexane, and 17 g of isopropyl alcohol were added and dissolved by stirring at 50 ° C. for 4 hours. . An aqueous solution obtained by dissolving 1.5 g of sodium polyoxyalkylene lauryl ether sulfate in 100 g of water was added to the obtained organic solution, and this was added to a homomixer (trade name “TK Homomixer M type” by Tokushu Kika Kogyo Co., Ltd.). The mixture was stirred and mixed for 2 minutes to obtain an emulsion. The rotation speed and temperature during stirring and mixing were set to 12000 rpm and 40 ° C., respectively. The obtained emulsion was heated to 40 to 70 ° C. under reduced pressure of 40 to 90 kPa to distill off cyclohexane and isopropyl alcohol. As a result, an anionic aqueous dispersion of polystyrene-polyisobutylene-polystyrene block copolymer was obtained.

Example 3
30 g of polystyrene-polyisobutylene-polystyrene block copolymer (isobutylene content = 77% by weight) and 170 g of cyclohexane were added to a separable flask having an internal volume of 500 ml, and dissolved by stirring at 50 ° C. for 4 hours. An aqueous solution obtained by dissolving 1.2 g of potassium oleate in 100 g of water was added to the obtained cyclohexane solution, and this was added using a homomixer (trade name “TK Homomixer M type” manufactured by Tokushu Kika Kogyo Co., Ltd.). The mixture was stirred and mixed for 2 minutes to obtain an emulsion. The rotation speed and temperature during stirring and mixing were set to 12,000 rpm and 40 ° C., respectively. The obtained emulsion was heated to 40 to 70 ° C. under a reduced pressure of 40 to 90 kPa, and cyclohexane was distilled off. As a result, an anionic aqueous dispersion of polystyrene-polyisobutylene-polystyrene block copolymer was obtained.

Example 4
To a separable flask having an internal volume of 500 ml, 30 g of a polystyrene-polyisobutylene-polystyrene block copolymer (isobutylene content = 77 wt%), 153 g of heptane and 17 g of isopropyl alcohol were added and dissolved by stirring at 50 ° C. for 4 hours. . An aqueous solution in which 1.5 g of sodium dodecylbenzenesulfonate was dissolved in 100 g of water was added to the obtained organic solution, and this was mixed with a homomixer (trade name “TK Homomixer M type” manufactured by Tokushu Kika Kogyo Co., Ltd.). And stirred for 2 minutes to obtain an emulsion. The rotation speed and temperature during stirring and mixing were set to 12000 rpm and 40 ° C., respectively. The obtained emulsion was heated to 40 to 70 ° C. under a reduced pressure of 40 to 90 kPa to distill off heptane and isopropyl alcohol. As a result, an anionic aqueous dispersion of polystyrene-polyisobutylene-polystyrene block copolymer was obtained.

Comparative Example 1
A nonionic aqueous dispersion of polystyrene-polyisobutylene-polystyrene block copolymer was obtained in the same manner as in Example 1 except that polyoxyethylene lauryl ether was used instead of sodium dioctylsulfosuccinate in Example 1.

Comparative Example 2
A cationic aqueous dispersion of polystyrene-polyisobutylene-polystyrene block copolymer was obtained in the same manner as in Example 1 except that octadecylamine acetate was used instead of sodium dioctylsulfosuccinate in Example 1.

Comparative Example 3
An anionic aqueous dispersion of polystyrene-polyisobutylene-polystyrene block copolymer was obtained in the same manner as in Example 1 except that 6 g of sodium dioctylsulfosuccinate was used in Example 1.

Comparative Example 4
A latex was attempted in the same manner as in Example 1 except that 0.15 g of sodium dioctylsulfosuccinate was used in Example 1, but it became a lump when toluene was distilled off, and no aqueous dispersion was obtained.

Evaluation Regarding the latex obtained in each Example and each Comparative Example, the average particle size, storage stability, and the state of the molded product obtained from the aqueous dispersion were examined according to the following methods. The results are shown in Table 1.
(Average particle diameter) Measurement was performed using a laser diffraction particle size distribution analyzer (trade name “SALD-2000J” manufactured by Shimadzu Corporation).
(Storage stability) 40 g of the aqueous dispersion was put in a 50 ml container, sealed, and left in a temperature environment of 25 ° C. Then, after 3 months, the state of the aqueous dispersion was visually evaluated. The evaluation criteria are as follows.
○: No phase separation ×: Phase separation (colorability) 10 g of an aqueous dispersion was placed in a petri dish having a diameter of 120 mm and dried at 40 ° C. for 12 hours to obtain an aqueous dispersion film. The state of this film was visually evaluated according to the following evaluation criteria.
○: The film is not colored ×: The film is colored
(Surfactant Bleed) Using the above coating, the following method was used.
○: Surfactant is not bleeding from the surface of the film ×: Surfactant is slightly bleeding from the surface of the film

It can be seen from Table 1 that the aqueous dispersion obtained by the present invention is excellent in storage stability, and that the molded product (film) obtained from the aqueous dispersion is free from surfactant bleeding and coloring. On the other hand, according to the methods of Comparative Examples 1 and 2, a nonionic or cationic aqueous dispersion can be obtained, but storage stability, coloring of the composition, and bleeding of the surfactant are observed. Further, a similar aqueous dispersion can be obtained even if anionic surfactant is used in a large amount as in the method of Comparative Example 3, but since the bleeding of the surfactant is observed from the composition, the anionic aqueous dispersion of the present invention is obtained. It is clear that has excellent properties.

According to the present invention, an anionic aqueous dispersion of a butyl rubber-based thermoplastic elastomer having a small particle size and excellent storage stability and a method for producing the same are provided. Since the anionic aqueous dispersion of the butyl rubber thermoplastic elastomer of the present invention has good compatibility between the anionic surfactant and the butyl rubber thermoplastic elastomer, there is no surfactant bleed when dried to form a molded product. Since there is no coloring, a material excellent in heat resistance, weather resistance, gas barrier properties, and vibration damping properties can be provided.

Claims (7)

Anionic aqueous dispersion of butyl rubber thermoplastic elastomer in which butyl rubber thermoplastic elastomer is emulsified and dispersed in the presence of 1 to 15 parts by weight of an anionic surfactant with respect to 100 parts by weight of the butyl rubber thermoplastic elastomer body. The butyl rubber-based thermoplastic elastomer is a copolymer comprising (A) a block composed of isobutylene as a main monomer and (B) a block composed of an aromatic vinyl compound as a main monomer. Anionic aqueous dispersion of butyl rubber thermoplastic elastomer. The anionic aqueous dispersion of a butyl rubber thermoplastic elastomer according to claim 1, wherein the butyl rubber thermoplastic elastomer is a polystyrene-polyisobutylene-polystyrene block copolymer. The anionic surfactant is at least one selected from the group consisting of dialkyl sulfosuccinates, aliphatic polyoxyalkylene ether sulfates, fatty acid salts and alkylbenzene sulfonates. An anionic aqueous dispersion of the butyl rubber-based thermoplastic elastomer described in 1. The anionic aqueous dispersion of a butyl rubber-based thermoplastic elastomer according to any one of claims 1 to 4, wherein an average particle size of the butyl rubber-based thermoplastic elastomer particles in the anionic aqueous dispersion is from 0.1 to 3 µm. . A molded article of a butyl rubber thermoplastic elastomer obtained from the anionic aqueous dispersion of the butyl rubber thermoplastic elastomer according to any one of claims 1 to 5. A butyl rubber thermoplastic elastomer dissolved in an organic solvent and an anionic surfactant dissolved in water are mixed and emulsified, and then the organic solvent is distilled off. A process for producing an anionic aqueous dispersion of a butyl rubber thermoplastic elastomer according to claim 1.