JP2006093159A - Manufacturing method for electrode of excimer lamp - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To inexpensively and surely provide a manufacturing method for an electrode of an excimer lamp for manufacturing an external electrode. <P>SOLUTION: The manufacturing method for an electrode of an excimer lamp which includes a discharge tube 10, consisting of an inner tube 11 and an outer tube formed in a coaxial tubular shape, applies high voltage between an inner electrode 13 inside the inner tube 10 and an external electrode 14 disposed on the external surface of the outer tube 12, and causes a gas to be discharged and emitted being filled in the discharge space 15 between the inner tube 11, and the outer tube 12 is provided. The method comprises a first process of forming an electrode pattern 14c with a conductive substance on a transfer paper 30, of which the surface is applied with starch 31, in advance; a second process of forming a cover coat 17 covering the starch 31 and the electrode pattern 14c; a third process of wetting the transfer paper 3 produced in the second process to paste it on the surface of the outer tube 11; a fourth process of peeling off the transfer paper 3 to remain the electrode pattern 14 together the cover coat 17 on the surface of the outer tube 11; and a fifth proces of calcining the electrode pattern 14c remained in the fourth process and make it into an electrode 14. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

  The present invention relates to a method for manufacturing an excimer lamp (dielectric barrier discharge lamp), and more particularly to a method for manufacturing a net-like outer electrode formed on an outer surface of an outer tube of an excimer lamp.

  Excimer lamps are widely used in ultraviolet exposure apparatuses and the like in the manufacturing process of electronic components such as semiconductor integrated circuits, liquid crystal display panels, and printed circuit boards. Conventional techniques relating to excimer lamps are disclosed in, for example, “High-Brightness Light Irradiation Device” described in Patent Document 1, “Dielectric Barrier Discharge Lamp” described in Patent Document 2, and the like.

  A conventional excimer lamp basically includes a discharge tube composed of a coaxial inner tube and an outer tube, and a high voltage is applied between the inner electrode on the inner surface of the inner tube and the outer electrode on the outer surface of the outer tube. Then, the rare gas sealed in the space between the inner tube and the outer tube is caused to emit light by excimer discharge.

  The outer electrode of a conventional excimer lamp is in close contact with, for example, a perforated metal plate spirally wound around a discharge tube. In such an electrode, loosening at the time of winding, swell of a part of the electrode inevitably occurs, and a gap is generated between the electrode and the surface of the discharge tube.

When discharge occurs in the gap as described above, power is wasted and light emission efficiency is reduced. In addition, even when a seamless mesh electrode braided with metal wires is used, a gap is generated at the intersection of the metal wires, and it is difficult to make the discharge tube and the electrode adhere to each other. In addition, when a thick electrode such as a metal wire is used, it becomes a barrier against the radiation beam having an angle, and the luminous efficiency is lowered.
JP 2000-223078 Japanese Patent Laid-Open No. 2001-23577

  In order to solve such a problem, in an excimer lamp, an electrode is formed by bringing a metal thin film into close contact with a discharge tube. The metal thin film is formed by printing, plating, vapor deposition, sputtering technique, or the like. Among these techniques, the vapor deposition and sputtering techniques are complicated and expensive. In printing technology, offset printing is generally used, but a curved surface printing machine must be used for curved surface printing. However, when a long discharge tube is used, the workability is very poor, the cost becomes high, and the accuracy of the electrode is remarkably lowered. Furthermore, depending on the type of ink, a microcrack is generated due to a difference in expansion coefficient, and the electrode is peeled off while the lamp is lit to shorten the lamp life.

  In addition, the conductive ink using a composite material in which a conductive substance and glass (silicon dioxide) are mixed has a vitreous nature, so it is extremely bonded and bite into the dielectric used in the discharge tube, Adhesion can be improved. Due to this extreme encroachment, the conductive material having a different expansion coefficient from that of the dielectric material may also encroach on the discharge tube, thereby causing micro cracks and the like to promote breakage, thereby reducing the lamp life. Moreover, in the composite in which the vitreous is mixed, the vitreous remains in the opening of the electrode when the printed electrode is sintered, and the illuminance of the lamp is lowered.

  The present invention has been conceived in order to solve the above-described problems of the prior art, and provides an electrode manufacturing method for an excimer lamp that is excellent in workability and can prevent a decrease in lamp life and luminous efficiency. The purpose is to do.

  An electrode manufacturing method for an excimer lamp according to the present invention includes a discharge tube including an inner tube and an outer tube formed in a coaxial cylindrical shape, and is disposed on an outer surface of the outer tube and an inner electrode disposed on the inner tube. An excimer lamp electrode manufacturing method in which a high voltage is applied between the outer electrode and the gas enclosed in the space between the inner tube and the outer tube to discharge light. A first step of forming an electrode pattern on a transfer paper coated with a conductive material, a second step of forming a cover coat covering the starch and the electrode pattern, and a transfer paper obtained in the second step A fourth step of moistening and adhering to the surface of the outer tube, a fourth step of peeling the transfer paper and leaving the electrode pattern together with the cover coat on the surface of the outer tube, and the fourth step Firing the electrode pattern left in the process It is a method to go through the fifth step that.

  The electrode pattern in the electrode manufacturing method of the present invention is formed of a metal of gold, silver, platinum, nickel, chromium or an alloy of these two or more metals.

  According to the excimer lamp electrode manufacturing method of the present invention, the outer electrode transfers the electrode pattern printed on the transfer paper onto the outer surface of the discharge tube and burns it, so that the manufacturing process is very simple. Further, by changing the width and length of the transfer sheet, it is possible to easily cope with a discharge tube having an arbitrary length and diameter. Furthermore, since the outer electrode can be formed in close contact with the outer surface of the discharge tube, a remarkable practical effect that good light emission characteristics can be obtained can be achieved.

  Embodiments of an excimer lamp electrode manufacturing method according to the present invention will be described below with reference to the accompanying drawings.

  FIG. 1 is a longitudinal sectional view of an excimer lamp to which an electrode manufacturing method of the present invention is applied, and FIG. 2 is an enlarged view of a part of an outer electrode of the excimer lamp. As shown in FIG. 1, this excimer lamp is composed of an inner tube 11 and an outer tube 12 arranged coaxially, and both ends of the discharge tube 10 and the inner tube 11 are joined by joining portions 16 to form closed ends. The inner electrode 13 is provided on the inner surface and the outer electrode 14 is provided on the outer surface of the outer tube 12.

  By applying a high voltage from the high voltage AC power source 9 between the inner electrode 13 and the outer electrode 14, a discharge gas (rare gas such as argon, krypton, xenon, etc.) sealed in the inner space 15 of the discharge tube 10 is obtained. ) Is excimer discharged to emit ultraviolet light.

  As shown in FIG. 2, the outer electrode 14 is a network electrode having a honeycomb structure having a large number of openings 14 a formed by, for example, hexagonal thin wires 14 b. The outer electrode 14 is preferably formed of a metal such as gold, silver, platinum, nickel or chromium or an alloy of two or more kinds of these metals. The aperture ratio of the outer electrode 14 is selected to be 70% or more.

  In the example of the excimer lamp shown in FIG. 1, the discharge tube 10 is made of transparent quartz and has an overall length of about 380 mm. The outer diameter of the inner tube 11 is about 20 mm and the outer diameter of the outer tube 12 is about 30 mm. It is. The light emission length of the excimer lamp is about 300 mm.

  Next, a manufacturing process of the outer electrode 14 of the excimer lamp shown in FIG. 2 will be described based on FIGS.

  As shown in FIG. 3 (a), a transfer paper 3 having a surface coated with starch 31 is prepared. As shown in FIG. 3 (b), an electrode pattern 14c is formed on the surface of starch 31 with a conductive substance. Print by galleries or silk printing.

  As shown in FIG. 3C, a cover coat 17 is formed on the surface on which the electrode pattern 14c is printed to cover the starch 31.

  As shown in FIG. 3D, the transfer paper 3 covered with the cover coat 17 is moistened and wound around the outer tube 12 and attached.

  When immersed in water, the starch 31 is dissolved and the transfer paper 3 can be peeled off. When the transfer paper 3 is peeled off, the electrode pattern 14c remains on the surface of the outer tube 12 together with the cover coat 17, as shown in FIG.

  When the discharge tube 10 to which the electrode pattern 14c has been transferred is baked (baked) in a high-temperature furnace at 600 ° C. to 700 ° C., the cover coat 17 burns and disappears, and as shown in FIG. Electrode 14 can be formed.

  The thickness of the mesh electrode 14 of the excimer lamp formed through the above steps is about 2.0 to 2.5 μm, and the line width is about 400 μm. Therefore, the aperture ratio of the mesh electrode 14 is about 77%.

  Next, an excimer lamp having an electrode formed by braiding the conventional metal wire shown in FIG. 4 (A) and an excimer lamp having a mesh electrode formed by the electrode manufacturing method of the present invention shown in FIG. 4 (B). Compare behavior.

In the conventional mesh electrode shown in FIG. 4A, a metal wire 40 is disposed on the outer surface of the outer tube 12 of the discharge tube 10. Further, at the intersecting portion, the intersecting metal lines 41 are superimposed on the metal lines 40 as indicated by broken lines. At places other than the intersection, the radiation beam with the angle indicated by the angle θ ₁ can be emitted to the outside, but at the intersection portion, only the radiation beam of θ ₂ narrower than θ ₁ is emitted to the outside, and light emission The amount is limited and the luminous efficiency is reduced.

On the other hand, in the mesh electrode 14 of the present invention shown in FIG. 4B, since the thickness of the mesh electrode 14 is suppressed to about 0.1 mm or less with respect to the outer diameter of the discharge tube 10, a wide radiation angle as shown in the figure. Light up to θ ₃ can be emitted to the outside, and the luminous efficiency is greatly improved.

The longitudinal cross-sectional view which shows the structure of an example of the excimer lamp which applies the electrode manufacturing method of this invention, The enlarged view of the outer electrode applied to the excimer lamp shown in FIG. Sectional drawing which shows the electrode manufacturing process of the excimer lamp by this invention, It is a characteristic comparison figure of the outer electrode (A) using the braided electrode of the conventional metal wire, and the outer electrode (B) of the excimer lamp manufactured by this invention.

Explanation of symbols

10 discharge tube
11 Inner pipe
12 outer pipe
13 Inner electrode
14 Outer electrode (mesh electrode)
14a opening
14b fine wire
14c Electrode pattern
17 Cover coat 3 Transfer paper

Claims (2)

A discharge tube including an inner tube and an outer tube formed in a coaxial cylindrical shape, and a high voltage is applied between an inner electrode disposed inside the inner tube and an outer electrode disposed on the outer surface of the outer tube. An excimer lamp electrode manufacturing method for applying and discharging a gas enclosed in a space between the inner tube and the outer tube,
A first step of forming an electrode pattern with a conductive material on a transfer paper having a starch applied beforehand on the surface;
A second step of forming a cover coat covering the starch and the electrode pattern;
A third step of moistening the transfer paper obtained in the second step and attaching it to the surface of the outer tube;
A fourth step of peeling the transfer paper and leaving the electrode pattern together with the cover coat on the surface of the outer tube;
An excimer lamp electrode manufacturing method comprising a fifth step of firing the electrode pattern left in the fourth step. 2. The method of manufacturing an electrode of an excimer lamp according to claim 1, wherein the electrode pattern is made of a metal of gold, silver, platinum, nickel, chromium or an alloy of two or more metals.

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