JP2006063173A - Method for producing fiber-reinforced composite material and apparatus for producing fiber-reinforced composite material - Google Patents

Method for producing fiber-reinforced composite material and apparatus for producing fiber-reinforced composite material Download PDF

Info

Publication number
JP2006063173A
JP2006063173A JP2004246476A JP2004246476A JP2006063173A JP 2006063173 A JP2006063173 A JP 2006063173A JP 2004246476 A JP2004246476 A JP 2004246476A JP 2004246476 A JP2004246476 A JP 2004246476A JP 2006063173 A JP2006063173 A JP 2006063173A
Authority
JP
Japan
Prior art keywords
resin
tow
winding
speed
supply
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2004246476A
Other languages
Japanese (ja)
Other versions
JP4511286B2 (en
Inventor
Takayuki Matsumoto
隆之 松本
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eneos Corp
Original Assignee
Nippon Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Oil Corp filed Critical Nippon Oil Corp
Priority to JP2004246476A priority Critical patent/JP4511286B2/en
Publication of JP2006063173A publication Critical patent/JP2006063173A/en
Application granted granted Critical
Publication of JP4511286B2 publication Critical patent/JP4511286B2/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Abstract

<P>PROBLEM TO BE SOLVED: To provide a method for producing a fiber-reinforced composite material according to an FW (filament winding) method by which the resin content in a tow can uniformly be controlled and high-speed operation can be performed even when efficiency in carrying out FW molding continuous to the production of tow prepreg is improved. <P>SOLUTION: An apparatus for production is equipped with a tow delivering means, a resin feeding means to the tow, a resin impregnating means, a winding means for winding the resultant tow prepreg and a signal transmitting means for transmitting a feedback signal of the tow advancing speed to the resin feeding means. The apparatus is characterized as follows. Furthermore, the resin feeding means is provided with resin feeding pumps equipped with a resin feed rate controlling part for receiving the signal from the signal transmitting means and controlling the resin feed rate to the tow, a resin discharging nozzle and resin transfer pipes for transferring the resin from the resin feeding pumps to the nozzle. The resin transfer pipes are pipes without deforming by a change in the resin transfer rate in the pipe in order to feed the resin to the resin feeding means so as to make the resin content of the tow constant according to the advancing speed. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本発明は、特にFW(フィラメントワインディング)成形を利用した繊維強化プラスチック等のトウプリプレグが巻回された繊維強化複合材料の製造法及び該製造法等に用いることができる製造装置に関する。   The present invention relates to a manufacturing method of a fiber reinforced composite material in which a tow prepreg such as a fiber reinforced plastic using FW (filament winding) molding is wound, and a manufacturing apparatus that can be used for the manufacturing method.

炭素繊維、ガラス繊維、芳香族ポリアミド繊維等の強化繊維とエポキシ樹脂からなる複合材料は、比強度、比弾性率に優れているため、スポーツ用途、航空機等の構造材料、土木材料、ロール等の分野に広く使用されている。
これらの複合材料を製造するため、強化繊維をそのまま加工用材料として用いる場合もあるが、多くの場合は樹脂を含浸して織物プリプレグ、チョップドファイバープリミックス、シートプリプレグ、トウプリプレグ等の中間加工材料として使用される場合が多い。
いずれの場合においても最終製品である複合材料成形物の製造コストを低減し、一方では品質を高くすることが望まれている。特に複合材料の繊維とマトリックス樹脂との割合をコントロールすることは、複合材料成形物の強度、弾性率、熱膨張率等の物性を高くし、品質の安定した製品を得る上で極めて重要である。
このような複合材料成形物の製造法としてはFW成形法が知られており、該方法は、産業用ロールやゴルフシャフト等、筒状の成型物を量産するのに適した成型法であるため、幅広く用いられている。
Composite materials consisting of carbon fiber, glass fiber, aromatic polyamide fiber and other reinforcing fibers and epoxy resin are excellent in specific strength and specific elastic modulus, so it can be used for sports applications, structural materials for aircraft, civil engineering materials, rolls, etc. Widely used in the field.
In order to produce these composite materials, reinforcing fibers may be used as processing materials as they are, but in many cases, they are impregnated with resin and used as intermediate processing materials such as woven prepregs, chopped fiber prepregs, sheet prepregs, and tow prepregs. Often used as.
In any case, it is desired to reduce the manufacturing cost of the composite material molded product that is the final product, while increasing the quality. In particular, controlling the ratio of the fiber and matrix resin of the composite material is extremely important for improving the physical properties such as strength, elastic modulus, and thermal expansion coefficient of the composite material molding, and obtaining a product with stable quality. .
As a method for producing such a composite material molded product, the FW molding method is known, and this method is a molding method suitable for mass-producing cylindrical molded products such as industrial rolls and golf shafts. Widely used.

FW成形における現在の主流は、液状の樹脂を用いる、レジンバス法、回転ロール法等のいわゆるウェット法である。
レジンバス法は、トウをレジンバス内に通過させて樹脂含浸させた後、オリフィス、ロール等によって余剰の樹脂を搾り取り樹脂含有量を調整する方法である。しかし、この方法はオリフィス、ロール等で余剰の樹脂を搾り取る際にトウとの摩擦が生じ、糸切れ、毛羽立ち等を伴うトウの損傷が生じる。また樹脂を搾り取ることによって樹脂含有量を調整するため、樹脂含有量を1%の精度で調整することが難しく、さらに樹脂含有量が40質量%以下のものを製造することは困難である。また、レジンバス内に直接トウを通過させるので、レジンバス内が毛羽等で汚損してしまう問題が生じる。
回転ロール法は、回転ロール上に樹脂層を形成しトウに転写するような転写ロール式の含浸法、例えばドクターブレードを持つ回転ドラムによる含浸法である。しかし、この方法においてもドクターブレードと回転ロール間のギャップの微調整が難しく、またトウの糸幅の不均一性による転写率のばらつきにより、樹脂含有量の均一性を保つことは難しい。また回転ロールとトウとの摩擦により、上記方法と同様に糸切れ、毛羽立ち等によるトウの損傷及びレジンバス内の汚損が生じる。
前記レジンバス法及び回転ロール法のいずれも、反応性の高い樹脂を用いることが多く、このため室温で徐々に硬化反応が進行し、ワインディング中に樹脂粘度が増加する傾向がある。このような粘度変化は樹脂のピックアップ量に影響するため、結果として樹脂含量の均一性が損なわれることになる。
これらの方法により製造された成型品は、繊維と樹脂との重量比を精度良く一定にすることが困難であることによる品質安定性の低さ、またトウの摩擦による損傷を防ぐために生産速度が低いことによる製造コストの高さ等の問題がある。
The current mainstream in FW molding is a so-called wet method such as a resin bath method or a rotating roll method using a liquid resin.
The resin bath method is a method in which after the tow is passed through a resin bath and impregnated with a resin, excess resin is squeezed out by an orifice, a roll or the like to adjust the resin content. However, in this method, friction with the tow occurs when excess resin is squeezed out with an orifice, a roll, etc., and damage of the tow accompanied by yarn breakage, fluffing, etc. occurs. In addition, since the resin content is adjusted by squeezing out the resin, it is difficult to adjust the resin content with an accuracy of 1%, and it is difficult to manufacture a resin content of 40% by mass or less. In addition, since the tow is directly passed through the resin bath, there is a problem that the inside of the resin bath is fouled by fuzz or the like.
The rotary roll method is a transfer roll type impregnation method in which a resin layer is formed on a rotary roll and transferred to a tow, for example, an impregnation method using a rotary drum having a doctor blade. However, even in this method, it is difficult to finely adjust the gap between the doctor blade and the rotating roll, and it is difficult to maintain the uniformity of the resin content due to the variation in the transfer rate due to the nonuniformity of the tow thread width. Further, due to the friction between the rotating roll and the tow, the tow is damaged due to yarn breakage, fluffing, and the like in the resin bath as in the above method.
In both the resin bath method and the rotating roll method, a highly reactive resin is often used. Therefore, the curing reaction gradually proceeds at room temperature, and the resin viscosity tends to increase during winding. Such a change in viscosity affects the amount of resin pick-up, and as a result, the uniformity of the resin content is impaired.
Molded products manufactured by these methods have low quality stability due to the difficulty of maintaining a constant weight ratio between fiber and resin, and the production rate is low to prevent damage due to tow friction. There is a problem such as high manufacturing cost due to being low.

そこで、予め樹脂が含浸されたトウプリプレグを用いてFWを行う、いわゆるドライ法が用いられることがある。しかし、この方法は、トウプリプレグを製造する工程とFWを行う工程の2工程を別に行うので、必然的にトータルコストが高くなる。また、単純にFW工程の前に、トウプリプレグ製造ラインを設置して連続運転することによるトータルコストの低減も考えられる。
ところで、トウプリプレグの製造法としては、例えば、特許文献1において、ノズルを介してマトリックス樹脂を一定の供給量でトウに供給し、かつ該ノズルを通過するトウを一定速度に制御することにより、トウへの樹脂含浸量の均一性を実現しうる製造法が提案されている。
一方、FWでは、トウプリプレグの折り返しやヘリカル巻き、或いは異形形状のマンドレルにワインディングを行う等の動作を伴う。このため、上記のようなトウプリプレグの製造法に連続してFWを行う場合、トウの速度が大きく変化し、トウ速度を一定に制御することが極めて困難である。従って、特許文献1に記載されるようなトウプリプレグの製造装置をそのままFW装置の前段に設置しても所望の効果、即ち、トウへの樹脂含有量を一定に制御できるという効果を達成することができない。
特開平9−17634号公報
Therefore, a so-called dry method in which FW is performed using a tow prepreg impregnated with a resin in advance may be used. However, this method inevitably increases the total cost because the two steps of manufacturing the tow prepreg and the step of performing FW are performed separately. It is also possible to reduce the total cost by simply installing the tow prepreg production line and continuously operating it before the FW process.
By the way, as a method for producing a tow prepreg, for example, in Patent Document 1, a matrix resin is supplied to a tow at a constant supply amount via a nozzle, and the tow passing through the nozzle is controlled at a constant speed. There has been proposed a production method capable of realizing the uniformity of the resin impregnation amount in tow.
On the other hand, FW involves operations such as folding a tow prepreg, helical winding, or winding a deformed mandrel. For this reason, when performing FW continuously to the above tow prepreg manufacturing method, the tow speed changes greatly, and it is extremely difficult to control the tow speed at a constant level. Therefore, even if a tow prepreg manufacturing apparatus as described in Patent Document 1 is installed in the front stage of the FW apparatus as it is, a desired effect, that is, an effect that the resin content in the tow can be controlled to be constant is achieved. I can't.
Japanese Patent Laid-Open No. 9-17634

本発明の目的は、トウプリプレグの製造に連続してFW(フィラメントワインディング)成形を行う効率性を向上させた場合にも、トウの糸方向に対する樹脂含有量を均一に制御でき、しかも高速運転が可能なFW法によるトウプリプレグが巻回された繊維強化複合材料の製造法及び該方法等に使用できる製造装置を提供することにある。   The object of the present invention is to uniformly control the resin content in the tow yarn direction even when the efficiency of performing FW (filament winding) molding is continuously performed in the manufacture of tow prepregs, and at high speed operation. An object of the present invention is to provide a method for producing a fiber-reinforced composite material in which a tow prepreg is wound by a possible FW method, and a production apparatus that can be used in the method.

本発明者らは、上記課題を解決するために鋭意検討した、まず、トウプリプレグの製造に連続してFW成形を行う効率性の向上を達成するに際して、トウの進行速度を一定に制御することはFW時におけるトウプリプレグの動作を鑑みた場合、上述のとおり現実的には不可能に近いことを認識した。そこで、トウの進行速度変化を前提にトウへの樹脂供給量を変化させるために、トウの進行速度を感知し、該速度のフィードバック信号を樹脂供給手段に送り、トウへの樹脂供給量をトウの進行速度に合わせて変化させる手段に着目した。
しかし、現実には、トウへの樹脂含有量を常に一定範囲に保持することができず、その原因を鋭意探求した。ところで、通常のトウプリプレグの製造に採用される樹脂供給手段において、樹脂供給ポンプと樹脂排出ノズルとを接続する樹脂移送管には、取り回しがし易いポリウレタン等の柔軟なプラスチック管が採用されている。このようなプラスチック管の採用は、トウ進行速度の変化が少ないトウプリプレグの製造においては何ら問題がないものである。しかし、前記原因の探求をしていく過程で、本発明のようにトウの進行速度が変化することを前提とした場合には、この樹脂移送管の材質が問題であることをが判ってきた。そこで、この樹脂移送管の材質を金属等の管内における樹脂移送量の変化により変形しないものを採用したところ上記課題が解決でき、本発明を完成するに至った。
The present inventors diligently studied to solve the above problems. First, when achieving the improvement in efficiency of performing FW molding continuously to the production of the tow prepreg, the tow traveling speed is controlled to be constant. Realized that it was practically impossible as described above when considering the operation of tow prepreg during FW. Therefore, in order to change the amount of resin supplied to the tow on the assumption that the tow traveling speed changes, the tow traveling speed is sensed, a feedback signal of the speed is sent to the resin supplying means, and the amount of resin supplied to the tow is reduced. We paid attention to the means to change it according to the speed of progress.
However, in reality, the resin content in the tow could not always be kept within a certain range, and the cause was eagerly investigated. By the way, in a resin supply means adopted for manufacturing a normal tow prepreg, a flexible plastic pipe such as polyurethane that is easy to handle is adopted as a resin transfer pipe connecting a resin supply pump and a resin discharge nozzle. . The use of such a plastic tube has no problem in the production of a tow prepreg with little change in tow travel speed. However, in the process of searching for the cause, it has been found that the material of the resin transfer pipe is a problem when it is assumed that the progress speed of the tow changes as in the present invention. . Therefore, when the material of the resin transfer pipe that is not deformed by the change of the resin transfer amount in the pipe of metal or the like is adopted, the above problems can be solved and the present invention has been completed.

すなわち本発明によれば、トウ繰出し手段と、該トウに樹脂を供給する樹脂供給手段と、供給された該樹脂をトウに含浸させる樹脂含浸手段と、樹脂含浸されたトウプリプレグを巻取り部に巻つける巻回手段と、トウの進行速度を感知し、該速度のフィードバック信号を前記樹脂供給手段に送る信号送信手段とを備え、且つ前記樹脂供給手段が、前記信号送信手段からのフィードバック信号を受理し、樹脂のトウへの供給量を制御する樹脂供給量制御部を具備する樹脂供給ポンプと、樹脂をトウに供給するノズルと、樹脂供給ポンプから樹脂を該ノズルに移送する樹脂移送管とを有する装置を用いてフィラメントワインディングによりトウプリプレグを巻回させた繊維強化複合材料を製造する方法であって、前記トウ繰出し手段によりトウを繰出し、前記樹脂供給手段によりトウに樹脂を供給し、前記樹脂含浸手段により樹脂をトウに含浸させ、樹脂含浸されたトウプリプレグを前記巻回手段により巻取り部に巻つけるにあたり、前記樹脂供給手段において、前記信号送信手段からのフィードバック信号を受理し、トウの進行速度に合わせてトウの樹脂含有量が一定になるように、前記樹脂移送管を、該管内の樹脂移送量の変化により変形しない管としてトウに樹脂供給することを特徴とするトウプリプレグが巻回された繊維強化複合材料の製造法が提供される。
また本発明によれば、トウ繰出し手段と、該トウに樹脂を供給する樹脂供給手段と、供給された該樹脂をトウに含浸させる樹脂含浸手段と、樹脂含浸されたトウプリプレグを巻取り部に巻つける巻回手段と、トウの進行速度を感知し、該速度のフィードバック信号を前記樹脂供給手段に送る信号送信手段とを備え、前記樹脂供給手段が、前記信号送信手段からのフィードバック信号を受理し、樹脂のトウへの供給量を制御する樹脂供給量制御部を具備する樹脂供給ポンプと、樹脂をトウに供給するノズルと、樹脂供給ポンプから樹脂を該ノズルに移送する樹脂移送管とを有し、前記信号送信手段からのフィードバック信号を受理し、トウの進行速度に合わせてトウの樹脂含有量が一定になるように前記樹脂供給手段により樹脂を供給するために、前記樹脂移送管を、該管内の樹脂移送量の変化により変形しない管としたことを特徴とするトウプリプレグが巻回された繊維強化複合材料の製造装置が提供される。
That is, according to the present invention, the tow feeding means, the resin supply means for supplying the resin to the tow, the resin impregnation means for impregnating the supplied resin with the tow, and the resin-impregnated tow prepreg in the winding part A winding means for winding, and a signal transmission means for sensing a traveling speed of the tow and sending a feedback signal of the speed to the resin supply means, and the resin supply means receives a feedback signal from the signal transmission means. A resin supply pump having a resin supply amount control unit that receives and controls the supply amount of the resin to the tow, a nozzle that supplies the resin to the tow, and a resin transfer pipe that transfers the resin from the resin supply pump to the nozzle; A fiber reinforced composite material in which a tow prepreg is wound by filament winding using a device having a tow is provided. The resin supply means supplies the resin to the tow by the resin supply means, impregnates the tow with the resin impregnation means, and winds the resin-impregnated tow prepreg around the winding portion by the winding means. The resin transfer pipe is not deformed by a change in the resin transfer amount in the pipe so that the feedback signal from the signal transmission means is received and the resin content of the tow becomes constant in accordance with the progressing speed of the tow. A method for producing a fiber-reinforced composite material in which a tow prepreg is wound is provided, wherein a resin is supplied to the tow as a tube.
According to the present invention, the tow feeding means, the resin supply means for supplying the resin to the tow, the resin impregnation means for impregnating the supplied resin with the tow, and the resin-impregnated tow prepreg in the winding part A winding means for winding, and a signal transmission means for sensing a speed of the tow and sending a feedback signal of the speed to the resin supply means, and the resin supply means accepts a feedback signal from the signal transmission means And a resin supply pump having a resin supply amount control unit for controlling the supply amount of the resin to the tow, a nozzle for supplying the resin to the tow, and a resin transfer pipe for transferring the resin from the resin supply pump to the nozzle. And receiving the feedback signal from the signal transmission means, and supplying the resin by the resin supply means so that the resin content of the tow becomes constant in accordance with the progressing speed of the tow The resin transfer pipe manufacturing apparatus of fiber reinforced composite material tow prepreg is wound, characterized in that the tube is not deformed by a change in the resin transfer amount in the tube is provided.

本発明のトウプリプレグが巻回された繊維強化複合材料の製造法及び製造装置は、上記構成、特に、トウの進行速度を感知し、該速度のフィードバック信号を樹脂供給手段に送り、トウへの樹脂供給量をトウの進行速度に合わせて変化させる手段と、樹脂供給手段において、樹脂供給ポンプと樹脂排出ノズルとを接続する樹脂移送管として、該管内の樹脂移送量の変化により変形しない管とを採用するので、トウプリプレグの製造に連続してFW成形を行う効率性を向上させた場合にも、トウの糸方向に対する樹脂含有量を均一に制御でき、しかも高速運転をも可能にしてトウプリプレグが巻回された繊維強化複合材料が効率良く製造できる。   The manufacturing method and the manufacturing apparatus of the fiber reinforced composite material wound with the tow prepreg of the present invention is configured to detect the above-described configuration, in particular, the progress speed of the tow, and send a feedback signal of the speed to the resin supply means. A means for changing the resin supply amount in accordance with the progressing speed of the tow, and a resin transfer pipe for connecting the resin supply pump and the resin discharge nozzle in the resin supply means; a pipe that is not deformed by a change in the resin transfer quantity in the pipe; Therefore, even if the efficiency of performing FW molding continuously in the production of tow prepregs is improved, the resin content in the tow yarn direction can be controlled uniformly, and high-speed operation is also possible. A fiber-reinforced composite material wound with a prepreg can be efficiently manufactured.

以下、図面を参照して本発明を更に詳細に説明するが、本発明はこれに限定されない。
図1は、本発明の製造法を実施しうる繊維強化複合材料の製造装置における一実施形態の例を説明するための概略図であって、10は、トウプリプレグの製造からFW成形を連続して実施しうる繊維強化複合材料の製造装置である。装置10は、トウを繰出すクリール11を備えるトウ繰出し手段と、樹脂タンク(12a,12b)、樹脂供給ポンプ(13a,13b)、樹脂混合用スタティツクミキサー14、扁平ノズル15及び樹脂移送管(16a,16b,16c)を備える樹脂供給手段と、樹脂含浸熱プーリー17及び加熱可能なニップロール18を備える樹脂含浸手段と、トウの進行速度を感知する速度センサープーリー19と、該速度のフィードバック信号を前記樹脂供給手段に送る信号送信器20と、トウプリプレグをFWでマンドレル21aに巻きつける、デリバリーアイ21bを有する巻回部21とを備える。
前記繰出し手段と樹脂供給手段との間には、図示するようにガイドプーリー(22a,22b)及び予熱プーリー(23a,23b)が設けられている。
Hereinafter, the present invention will be described in more detail with reference to the drawings, but the present invention is not limited thereto.
FIG. 1 is a schematic diagram for explaining an example of an embodiment in a fiber-reinforced composite material manufacturing apparatus that can carry out the manufacturing method of the present invention, wherein 10 is a series of FW molding from the manufacture of tow prepregs. It is the manufacturing apparatus of the fiber reinforced composite material which can be implemented. The apparatus 10 includes a tow feeding means including a creel 11 for feeding tows, a resin tank (12a, 12b), a resin supply pump (13a, 13b), a resin mixing static mixer 14, a flat nozzle 15, and a resin transfer pipe. Resin supply means comprising (16a, 16b, 16c), resin impregnation means comprising a resin impregnated heat pulley 17 and a heatable nip roll 18, a speed sensor pulley 19 for sensing the tow travel speed, and a feedback signal of the speed Is sent to the resin supply means, and a winding part 21 having a delivery eye 21b for winding the tow prepreg around the mandrel 21a by FW.
As shown in the figure, guide pulleys (22a, 22b) and preheating pulleys (23a, 23b) are provided between the feeding means and the resin supply means.

次に、図1に示される装置を用いて本発明の製造法を実施する例を説明する。まず、クリール11から繰り出されたトウは、ガイドプーリー(22a,22b)を通過して予熱プーリー23aに通されて、所定温度まで加熱され同時にトウの断面は扁平な形状となる。予熱プーリー23aを通過したトウは次の予熱プーリー23bに通される。
一方、樹脂タンク(12a,12b)には2液型のマトリックス樹脂と硬化剤とが別個に保存されており、FW運転時にそれぞれ樹脂供給ポンプ(13a,13b)に送られる。樹脂タンク(12a,12b)は、マトリックス樹脂の可使時間を長くできるように密閉型のものが好ましく用いられる。マトリックス樹脂の加熱は、樹脂タンク(12a,12b)、樹脂移送管(16a,16b,16c)又はノズル15等に適当な加熱手段を付与することにより行うことができる。ポンプ(13a,13b)による樹脂及び硬化剤の供給量制御は、センサープーリー19で測定されたトウの速度のフィードバック信号を信号送信器20から受理し、トウの樹脂含有量が常に一定量となるようポンプの回転速度を制御する樹脂供給量制御部(図示せず)により調整される。
Next, an example in which the manufacturing method of the present invention is carried out using the apparatus shown in FIG. 1 will be described. First, the tow fed out from the creel 11 passes through the guide pulleys (22a, 22b), passes through the preheating pulley 23a, is heated to a predetermined temperature, and at the same time, the toe has a flat cross section. The tow that has passed through the preheating pulley 23a is passed through the next preheating pulley 23b.
On the other hand, the two-component matrix resin and the curing agent are stored separately in the resin tanks (12a, 12b), and are sent to the resin supply pumps (13a, 13b) during the FW operation, respectively. As the resin tanks (12a, 12b), a sealed tank is preferably used so that the pot life of the matrix resin can be increased. The matrix resin can be heated by applying appropriate heating means to the resin tanks (12a, 12b), the resin transfer pipes (16a, 16b, 16c), the nozzle 15, or the like. The supply amount control of the resin and the curing agent by the pumps (13a, 13b) receives the feedback signal of the tow speed measured by the sensor pulley 19 from the signal transmitter 20, and the resin content of the tow is always a constant amount. It is adjusted by a resin supply amount control unit (not shown) that controls the rotational speed of the pump.

ポンプ(13a,13b)からの樹脂及び硬化剤は、樹脂移送管(16a,16b)を介してスタティックミキサー14に送られて混合され、樹脂移送管16cを介して扁平ノズル15を通して、熱プーリー17を通過するトウの表面に供給される。この際、樹脂が一液型の場合には、一方の樹脂タンク12b、ポンプ13b及びスタティックミキサー14を省くことができる。またノズルとして扁平ノズル15を用いることにより、樹脂は広がったトウの幅全面に引き伸ばされた形で供給される。
前記樹脂移送管(16a,16b,16c)は、トウの速度に同期した樹脂供給を実現するために、管内の樹脂移送量の変化により変形しない管、例えば、銅管等の金属製管とする必要がある。ここで、通常トウプリプレグの製造に使用されているポリウレタン等の柔軟なプラスチック管を用いると、トウの速度が変動することにより、ポンプの回転数が変化した際に、プラスチック管自体が変形、例えば膨れやしぼみが生じ、樹脂供給量の変動に追随できずに遅れが生じ、結果としてトウの樹脂含有量を一定に保持することができなくなる。
The resin and the curing agent from the pumps (13a, 13b) are sent to the static mixer 14 via the resin transfer pipes (16a, 16b) and mixed, and then passed through the flat nozzle 15 via the resin transfer pipe 16c, and the heat pulley 17 Supplied to the surface of the tow that passes through. At this time, when the resin is a one-pack type, the one resin tank 12b, the pump 13b, and the static mixer 14 can be omitted. Further, by using the flat nozzle 15 as the nozzle, the resin is supplied in a form stretched over the entire width of the expanded tow.
The resin transfer pipes (16a, 16b, 16c) are pipes that are not deformed by a change in the resin transfer amount in the pipe, for example, metal pipes such as copper pipes, in order to realize resin supply synchronized with the tow speed. There is a need. Here, if a flexible plastic tube such as polyurethane, which is usually used for manufacturing tow prepregs, is used, the plastic tube itself deforms when the number of rotations of the pump changes due to fluctuations in the tow speed, for example, Swelling or squeezing occurs, and a delay occurs without being able to follow the fluctuation of the resin supply amount. As a result, the resin content of tow cannot be kept constant.

前記樹脂供給されたトウは、ニップロール18を通過することにより、樹脂がトウ内部に含浸され、樹脂含有量がトウの長手方向に均一で、かつ糸束内での樹脂の分布が均一なトウプリプレグが製造される。
続いて、トウプリプレグは速度センサープーリー19を通過後、巻取り部21のデリバリアイ21bを通って、マンドレル21aに巻き取られる。
トウプリプレグの線速度は、センサープーリー19により常時測定され、リアルタイムで信号送信器20から樹脂供給量を制御するポンプ(13a,13b)にフィードバックされるため、例えば、デリバリアイ21bの折り返し時に速度が低下した際も、あるいは、巻き始めから巻き終わりまでにおけるワインディング成形体の径が変化した場合でも、樹脂供給量が制御され、トウに対する樹脂含浸量は終始一定に制御されてFW成形が実施される。
The tow supplied with the resin passes through the nip roll 18 so that the resin is impregnated inside the tow, the resin content is uniform in the longitudinal direction of the tow, and the resin distribution in the yarn bundle is uniform. Is manufactured.
Subsequently, after passing through the speed sensor pulley 19, the tow prepreg passes through the delivery 21 b of the winding unit 21 and is wound around the mandrel 21 a.
The linear speed of the tow prepreg is constantly measured by the sensor pulley 19 and is fed back in real time from the signal transmitter 20 to the pumps (13a, 13b) that control the resin supply amount. Even when it decreases or when the diameter of the winding molded body changes from the beginning of winding to the end of winding, the resin supply amount is controlled, and the amount of resin impregnation to the tow is controlled to be constant throughout the FW molding. .

図1においては、クリール、ガイドプーリー、予熱プーリー、ノズル、熱プーリー等はそれぞれ1個又は2個であるが、それ以上を並列に設置して複数のトウを同時にワインディングすることもできる。   In FIG. 1, there are one or two creels, guide pulleys, preheat pulleys, nozzles, heat pulleys, etc., but it is also possible to wind more than one tow simultaneously by installing more than one.

本発明の製造法において、トウへの樹脂含有量の設定値に対する精度は±2%以下、好ましくは±1%以下にすることができる。また、樹脂含有量の設定範囲は特に限定されないが通常10〜50質量%、好ましくは20〜40質量%にすることができる。樹脂含有量が50質量%を超える場合は液だれがあって樹脂含有量を精度よく制御することが困難であり、また10質量%未満ではトウ内部に樹脂を均一に含浸させることが困難になる恐れがある。
トウへの樹脂含有量の制御は、前述のとおり、糸速あたりのポンプの回転数を制御することで任意の樹脂供給量でのFW成形を実施することができる。
In the production method of the present invention, the accuracy with respect to the set value of the resin content in the tow can be ± 2% or less, preferably ± 1% or less. Moreover, although the setting range of resin content is not specifically limited, Usually, 10-50 mass%, Preferably it can be 20-40 mass%. When the resin content exceeds 50% by mass, it is difficult to control the resin content with high accuracy, and when it is less than 10% by mass, it is difficult to uniformly impregnate the resin inside the tow. There is a fear.
As described above, the resin content in the tow can be controlled by controlling the number of revolutions of the pump per yarn speed, so that FW molding can be performed with an arbitrary resin supply amount.

前記糸速は、強化繊維の種類により好ましい範囲を適宜決定することができる。例えば、炭素繊維の場合は、通常5〜200m/分、好ましくは10〜150m/分の糸速とすることができる。炭素繊維の糸速が5m/分未満では生産性が低下する恐れがあり、また200m/分を超えると糸切れや毛羽が発生し易くなる。また糸速は樹脂の粘度、特に樹脂供給時あるいは含浸時の粘度により好ましい範囲を適宜決定することができる。
前記樹脂の粘度が0.01〜10ポイズの場合には、通常5〜200m/分、好ましくは10〜150m/分の糸速とすることが好ましい。樹脂の粘度が10ポイズを超え、100ポイズ以下の場合には、通常5〜150m/分、好ましくは10〜120m/分の糸速とすることができる。樹脂の粘度が100ポイズを超え、300ポイズ以下の場合には、通常5〜120m/分、好ましくは10〜100m/分の糸速とすることができる。樹脂の粘度が300ポイズより大きい場合には、糸速は低速化し、粘度が0.01ポイズより小さい場合は高速化することが可能であるが、液だれが発生し易くなる。
A preferable range of the yarn speed can be appropriately determined depending on the type of the reinforcing fiber. For example, in the case of carbon fiber, the yarn speed can be usually 5 to 200 m / min, preferably 10 to 150 m / min. If the yarn speed of the carbon fiber is less than 5 m / min, the productivity may decrease, and if it exceeds 200 m / min, yarn breakage and fluff are likely to occur. The yarn speed can be appropriately determined in a preferable range depending on the viscosity of the resin, particularly the viscosity at the time of supplying or impregnating the resin.
When the viscosity of the resin is 0.01 to 10 poise, the yarn speed is usually 5 to 200 m / min, preferably 10 to 150 m / min. When the viscosity of the resin exceeds 10 poise and is 100 poise or less, the yarn speed is usually 5 to 150 m / min, preferably 10 to 120 m / min. When the viscosity of the resin exceeds 100 poise and is 300 poise or less, the yarn speed is usually 5 to 120 m / min, preferably 10 to 100 m / min. If the viscosity of the resin is greater than 300 poise, the yarn speed can be reduced. If the viscosity is less than 0.01 poise, the speed can be increased, but dripping tends to occur.

前記樹脂を供給する方法は、定量性に優れた樹脂供給ポンプを用いることが好ましい。定量供給性に優れるポンプの種類は特に限定されず、例えば、ロータリーポンプ、プランジャーポンプ、ギアポンプ、モーノポンプ、渦巻ポンプ、カスケードポンプ、ミッドランドポンプ、ダイヤフラムポンプ等が挙げられる。   The method for supplying the resin preferably uses a resin supply pump having excellent quantitative properties. The kind of pump excellent in fixed_quantity | feed_rate supply property is not specifically limited, For example, a rotary pump, a plunger pump, a gear pump, a Mono pump, a spiral pump, a cascade pump, a midland pump, a diaphragm pump etc. are mentioned.

トウへの樹脂供給量は、糸速に応じて樹脂の供給量を調整することにより容易に制御することができる。樹脂の供給量は、[(糸速)×(単位長さあたりのトウの重さ)×(樹脂含有量(質量%)の設定値)]/[100−(樹脂含有量(質量%)の設定値)]で決まるが、通常0.1〜240g/分、好ましくは1〜100g/分の範囲で設定することができる。   The amount of resin supplied to the tow can be easily controlled by adjusting the amount of resin supplied according to the yarn speed. The amount of resin supplied is [(yarn speed) × (weight of tow per unit length) × (setting value of resin content (mass%))] / [100− (resin content (mass%)) Set value)], but is usually 0.1 to 240 g / min, preferably 1 to 100 g / min.

トウに適用される強化繊維は特に限定されず、例えば、炭素繊維、ガラス繊維、アルミナ繊維、炭化珪素繊維、ボロン繊維、アラミド繊維等が具体的に挙げられ、特に炭素繊維が好ましく用いられる。更に好ましくは、樹脂が含浸し難い、繊維径が6μm以下でかつ繊度が800g/km以上の炭素繊維が挙げられる。   The reinforcing fiber applied to the tow is not particularly limited, and specific examples include carbon fiber, glass fiber, alumina fiber, silicon carbide fiber, boron fiber, and aramid fiber, and carbon fiber is particularly preferably used. More preferably, carbon fibers that are difficult to be impregnated with resin, have a fiber diameter of 6 μm or less, and a fineness of 800 g / km or more can be used.

前記樹脂は特に限定されず、例えば、熱硬化性の樹脂、特にエポキシ樹脂が取り扱い易いので好ましく挙げられる。エポキシ樹脂としては、潜在型硬化剤を用いた一液型のエポキシ樹脂でもよいが、より低粘度の2液型エポキシ樹脂をスタティックミキサーにより混合しながら用いることが好ましい。スタティックミキサーの使用により、従来のウェット法FWにおける問題点の1つであった、ワインディング中に樹脂が徐々に反応して粘度が上昇し、従って樹脂含浸量が増加してしまうという問題が解決できる。
本発明の製造法においては、樹脂供給時、供給前あるいは供給後に、樹脂及び/又はトウを、それぞれ樹脂の硬化温度より30℃以下の温度を上限として加熱することで、トウ内部へ樹脂を含浸し易くすることができる。該加熱は、通常15〜1500℃で行い、好ましくは15〜900℃の範囲で行うことで樹脂の粘度を容易に安定させることができる。
The resin is not particularly limited, and for example, a thermosetting resin, particularly an epoxy resin is preferable because it is easy to handle. The epoxy resin may be a one-component epoxy resin using a latent curing agent, but it is preferable to use a two-component epoxy resin having a lower viscosity while mixing with a static mixer. By using a static mixer, one of the problems in the conventional wet method FW can be solved that the resin gradually reacts during winding to increase the viscosity and therefore the amount of resin impregnation increases. .
In the production method of the present invention, the resin and / or the tow are heated up to a temperature of 30 ° C. or less from the curing temperature of the resin, respectively, at the time of supplying the resin, before or after the supply, thereby impregnating the resin inside the tow. Can be made easier. The heating is usually performed at 15 to 1500 ° C., preferably 15 to 900 ° C., whereby the viscosity of the resin can be easily stabilized.

前記樹脂の加熱は、樹脂槽中のみならず、ノズルに至るまでの樹脂移送管においても行うことが好ましい。樹脂移送管中において樹脂温度が低下すると、樹脂粘度が上昇し、最悪の場合樹脂により管が閉塞する恐れがある。樹脂移送管の加熱は、例えば、管にリボンヒーターを巻回して加熱する方法が簡便で有効である。この際、リボンヒーターからの熱を素早く、かつ均一に管内の樹脂に伝達するため、樹脂移送管自体の熱伝導率は高いことが必要である。このような観点から樹脂移送管は、銅等の金属製であることが好ましい。   The heating of the resin is preferably performed not only in the resin tank but also in the resin transfer pipe leading to the nozzle. When the resin temperature decreases in the resin transfer pipe, the resin viscosity increases, and in the worst case, the pipe may be blocked by the resin. For heating the resin transfer tube, for example, a method of winding a ribbon heater around the tube and heating it is simple and effective. At this time, in order to transfer heat from the ribbon heater quickly and uniformly to the resin in the tube, the resin transfer tube itself needs to have a high thermal conductivity. From such a viewpoint, the resin transfer tube is preferably made of a metal such as copper.

粘度の高い樹脂を用いる場合は、加熱又は溶剤希釈等の処理によって樹脂の粘度を、通常0.01〜300ポイズ、好ましくは0.1〜100ポイズ、最も好ましくは0.1〜10ポイズの範囲に低粘度化して使用することが望ましい。特に樹脂の温度が15〜30℃で粘度が上記範囲内にあれば取り扱いが容易で好ましい。樹脂の粘度が300ポイズを超える場合はトウヘの含浸が不十分となる恐れがあり、かつトウの毛羽が発生し易くなる。また粘度が0.01ポイズに満たない場合は液だれし易くなる恐れがある。
トウヘの樹脂の含浸し易さは、樹脂の粘度だけでなく、トウのフィラメント径や使用されるサイジング剤でも異なる。フィラメント径が小さいトウや硬めのサイジング剤を使用したトウは樹脂が含浸し難い。
When using a resin having a high viscosity, the viscosity of the resin is usually 0.01 to 300 poise, preferably 0.1 to 100 poise, and most preferably 0.1 to 10 poise by heating or solvent dilution. It is desirable to lower the viscosity. In particular, if the temperature of the resin is 15 to 30 ° C. and the viscosity is within the above range, the handling is easy and preferable. When the viscosity of the resin exceeds 300 poise, impregnation of the tow may be insufficient and toe fluff is likely to occur. Further, when the viscosity is less than 0.01 poise, there is a possibility that the liquid may easily drip.
The ease of impregnation of the resin with the tow differs not only with the viscosity of the resin but also with the filament diameter of the tow and the sizing agent used. Tow with a small filament diameter or a hard sizing agent is difficult to impregnate with resin.

トウの加熱は、樹脂供給前、供給時あるいは供給後いずれでも行うことができるが、前述のような含浸し難いトウを用いる場合は、樹脂供給前にトウを予熱プーリーにより通常15〜150℃、好ましくは15〜90℃に加熱することが好ましい。
トウの加熱方法は特に限定されないが、トウの加熱、トウの扁平化及び樹脂の含浸を同時に行うことができる予熱プーリー及び熱プーリーを使用して行うことが好ましい。該プーリーの使用によって樹脂の含浸を効果的に促進することができる。また並列に熱プーリーを2個以上並べて、複数本のトウを同時に運転することも容易であり、場所をとらずに、しかも大量生産がし易い。
Heating of the tow can be performed either before, during or after the resin supply, but when using a tow that is difficult to impregnate as described above, the tow is usually 15 to 150 ° C. by a preheating pulley before supplying the resin, It is preferable to heat to 15 to 90 ° C.
The tow heating method is not particularly limited, but it is preferable to use a preheat pulley and a heat pulley that can simultaneously perform tow heating, toe flattening, and resin impregnation. The use of the pulley can effectively promote the impregnation of the resin. Moreover, it is easy to operate two or more tows simultaneously by arranging two or more heat pulleys in parallel, and it is easy to mass-produce without taking up space.

トウの樹脂含有量は、プーリーの溝の断面形状によっても影響を受ける。予熱プーリー及び熱プーリーの溝の断面形状は、U字型、V字型、逆U字型、底が平らなU字型等いずれの形状でも使用できるが、底が平らなU字型のものが、均一な厚みにトウを扁平化でき、かつ樹脂をより均一にトウに含浸させることができるので好ましい。
扁平なトウの幅と厚みの比は、通常10〜1000:1、好ましくは30〜100:1である。また、本発明では前述のような同様な効果が得られるならばプーリーの替わりにドラムやロール等を使用することができる。
The resin content of tow is also affected by the cross-sectional shape of the pulley groove. The preheat pulley and the groove of the heat pulley groove can be any shape such as U-shape, V-shape, inverted U-shape, U-shape with flat bottom, but U-shape with flat bottom However, it is preferable because the tow can be flattened to a uniform thickness and the resin can be more uniformly impregnated with the tow.
The ratio of the width and thickness of the flat tow is usually 10 to 1000: 1, preferably 30 to 100: 1. In the present invention, a drum, a roll or the like can be used instead of the pulley if the same effect as described above can be obtained.

以下、実施例及び比較例により本発明を更に詳細に説明するが本発明はこれにより限定されない。
実施例1
トウとして三菱レイヨン(株)製の炭素繊維TRH50−12K(商品名、フィラメント数12000本、トウの単位長さ当たりの重量0.81g/m)を用い、25℃における粘度が50ポイズのエポキシ樹脂主剤からなるマトリックス樹脂と、同粘度が0.4ポイズの硬化剤とからなる、硬化温度130℃の2液型熱硬化性エポキシ樹脂を用い、図1に示す装置を用いて上述の方法に従ってFWを実施した。
樹脂を供給するノズル15を通過するトウの最高線速度は20m/分から開始し、製造上問題が発生する(毛羽の発生、樹脂含浸不良等)まで10m/分単位で速度を上げていくことにより、最高運転速度を求めた。いずれの速度でも樹脂含有量の目標値は30質量%として運転を行った。
また、ワインディングされた成形体の10カ所の部位から2cm角のサンプルを切り出し、実際の樹脂含有量を測定した。結果を表1に示す。
EXAMPLES Hereinafter, although an Example and a comparative example demonstrate this invention further in detail, this invention is not limited by this.
Example 1
Carbon fiber TRH50-12K manufactured by Mitsubishi Rayon Co., Ltd. (trade name, number of filaments 12,000, weight per unit length of tow 0.81 g / m) as tow, epoxy resin having a viscosity of 50 poise at 25 ° C. Using a two-component thermosetting epoxy resin having a curing temperature of 130 ° C. composed of a matrix resin composed of a base material and a curing agent having the same viscosity of 0.4 poise, using the apparatus shown in FIG. Carried out.
The maximum linear velocity of the tow that passes through the nozzle 15 that supplies the resin starts from 20 m / min, and is increased in increments of 10 m / min until production problems occur (generation of fuzz, poor resin impregnation, etc.). Sought the maximum driving speed. The operation was carried out with the target value of the resin content at 30% by mass at any speed.
Further, 2 cm square samples were cut out from 10 portions of the wound molded body, and the actual resin content was measured. The results are shown in Table 1.

比較例1
図1の製造装置において、樹脂移送管(16a,16b,16c)をポリウレタン製の管に変更した以外は実施例1と同様に運転し、最高運転速度及び10カ所の樹脂含有量を測定した。結果を表1に示す。
Comparative Example 1
In the production apparatus of FIG. 1, the operation was performed in the same manner as in Example 1 except that the resin transfer pipes (16a, 16b, 16c) were changed to polyurethane pipes, and the maximum operation speed and the resin content at 10 locations were measured. The results are shown in Table 1.

比較例2
実施例1と同様のトウに、実施例1と同様の2液型熱硬化性エポキシ樹脂を予備混合した上で、ドクターブレードを持つ回転ドラムを使用して含浸させ、30質量%の目標樹脂含有量となるようにFWを行い、実施例1と同様に最高運転速度及び10カ所の樹脂含有量を測定した。結果を表1に示す。
Comparative Example 2
The same two-component thermosetting epoxy resin as in Example 1 is premixed in the same tow as in Example 1, and then impregnated using a rotating drum having a doctor blade, and contains 30% by weight of the target resin. FW was performed so that the amount was equal, and the maximum operation speed and the resin content at 10 locations were measured in the same manner as in Example 1. The results are shown in Table 1.

比較例3
実施例1と同様のトウに、予めエポキシ樹脂を30質量%含浸されたトウプリプレグ(新日本石油(株)製、商品名TRH50−12−RC30−25SY2)を用いて、FWを行い、実施例1と同様に最高運転速度及び10カ所の樹脂含有量を測定した。結果を表1に示す。
Comparative Example 3
FW was performed using a tow prepreg (trade name TRH50-12-RC30-25SY2 manufactured by Nippon Oil Corporation) impregnated with 30% by mass of an epoxy resin in advance in the same tow as in Example 1. Similarly to 1, the maximum operating speed and the resin content at 10 locations were measured. The results are shown in Table 1.

Figure 2006063173
表1から明らかなように、本発明の製造法により、従来のウェット法によるFWに対し、2倍以上の運転速度が可能となり、しかも製品の樹脂含有量の均一性も極めて高いことが判る。また、本発明の製造法により、高コストのトウプリプレグを使用しなくても、トウプリプレグ使用時と同レベルの生産性、樹脂含有量の均一性等の物性が得られることが判る。
Figure 2006063173
As is clear from Table 1, it can be seen that the production method of the present invention enables an operation speed that is at least twice that of the conventional wet method FW, and that the uniformity of the resin content of the product is extremely high. Further, it can be seen that the production method of the present invention can provide physical properties such as productivity and uniformity of resin content at the same level as when using a tow prepreg without using a high-cost tow prepreg.

本発明の製造法を実施しうる繊維強化複合材料の製造装置における一実施形態の例を説明するための概略図である。It is the schematic for demonstrating the example of one Embodiment in the manufacturing apparatus of the fiber reinforced composite material which can implement the manufacturing method of this invention.

符号の説明Explanation of symbols

10:繊維強化複合材料の製造装置
11:クリール
12a,12b:樹脂タンク
13a,13b:樹脂供給ポンプ
14:スタティツクミキサー
15:扁平ノズル
16a,16b,16c:樹脂移送管
17:樹脂含浸熱プーリー
18:ニップロール
19:速度センサープーリー
20:信号送信器
21a:マンドレル
21b:デリバリーアイ
21:巻回部
10: Fiber reinforced composite material manufacturing apparatus 11: Creel 12a, 12b: Resin tank 13a, 13b: Resin supply pump 14: Static mixer 15: Flat nozzles 16a, 16b, 16c: Resin transfer pipe 17: Resin impregnated heat pulley 18: Nip roll 19: Speed sensor pulley 20: Signal transmitter 21a: Mandrel 21b: Delivery eye 21: Winding part

Claims (4)

トウ繰出し手段と、該トウに樹脂を供給する樹脂供給手段と、供給された該樹脂をトウに含浸させる樹脂含浸手段と、樹脂含浸されたトウプリプレグを巻取り部に巻つける巻回手段と、トウの進行速度を感知し、該速度のフィードバック信号を前記樹脂供給手段に送る信号送信手段とを備え、且つ前記樹脂供給手段が、前記信号送信手段からのフィードバック信号を受理し、樹脂のトウへの供給量を制御する樹脂供給量制御部を具備する樹脂供給ポンプと、樹脂をトウに供給するノズルと、樹脂供給ポンプから樹脂を該ノズルに移送する樹脂移送管とを有する装置を用いてフィラメントワインディングによりトウプリプレグを巻回させた繊維強化複合材料を製造する方法であって、
前記トウ繰出し手段によりトウを繰出し、前記樹脂供給手段によりトウに樹脂を供給し、前記樹脂含浸手段により樹脂をトウに含浸させ、樹脂含浸されたトウプリプレグを前記巻回手段により巻取り部に巻つけるにあたり、
前記樹脂供給手段において、前記信号送信手段からのフィードバック信号を受理し、トウの進行速度に合わせてトウの樹脂含有量が一定になるように、前記樹脂移送管を、該管内の樹脂移送量の変化により変形しない管としてトウに樹脂供給することを特徴とするトウプリプレグが巻回された繊維強化複合材料の製造法。
A tow feeding means, a resin supply means for supplying a resin to the tow, a resin impregnation means for impregnating the supplied resin with the tow, a winding means for winding the resin-impregnated tow prepreg around the winding portion, And a signal transmission means for sensing a tow traveling speed and sending a feedback signal of the speed to the resin supply means, and the resin supply means accepts a feedback signal from the signal transmission means to the resin tow. Filament using a device having a resin supply pump having a resin supply amount control unit for controlling the supply amount of the resin, a nozzle for supplying resin to the tow, and a resin transfer pipe for transferring resin from the resin supply pump to the nozzle A method for producing a fiber-reinforced composite material in which a tow prepreg is wound by winding,
The tow is fed by the tow feeding means, the resin is supplied to the tow by the resin supply means, the tow is impregnated with the resin by the resin impregnation means, and the resin-impregnated tow prepreg is wound around the winding portion by the winding means. In putting on
In the resin supply means, the feedback signal from the signal transmission means is received, and the resin transfer pipe is set to a resin transfer amount in the pipe so that the resin content of the tow becomes constant in accordance with the progressing speed of the tow. A method for producing a fiber-reinforced composite material in which a tow prepreg is wound, wherein a resin is supplied to the tow as a tube that does not deform due to change.
樹脂として2液型樹脂を用いるために、前記樹脂供給ポンプを2個備え、これら樹脂供給ポンプと前記ノズルとの間にスタティックミキサーを前記樹脂移送管に連結して設けた装置を用い、2個の樹脂供給ポンプから排出される2液型樹脂のそれぞれを、前記スタティックミキサーにより混合し、前記樹脂移送管を介して前記ノズルに移送することを特徴とする請求項1記載の製造法。   In order to use a two-component resin as a resin, two resin supply pumps are provided, and a device in which a static mixer is connected to the resin transfer pipe between the resin supply pump and the nozzle is used. 2. The production method according to claim 1, wherein each of the two-component resins discharged from the resin supply pump is mixed by the static mixer and transferred to the nozzle through the resin transfer pipe. 前記樹脂移送量の変化により変形しない樹脂移送管が、金属製の管であることを特徴とする請求項1又は2記載の製造法。   The method according to claim 1 or 2, wherein the resin transfer pipe that is not deformed by a change in the resin transfer amount is a metal pipe. トウ繰出し手段と、該トウに樹脂を供給する樹脂供給手段と、供給された該樹脂をトウに含浸させる樹脂含浸手段と、樹脂含浸されたトウプリプレグを巻取り部に巻つける巻回手段と、トウの進行速度を感知し、該速度のフィードバック信号を前記樹脂供給手段に送る信号送信手段とを備え、
前記樹脂供給手段が、前記信号送信手段からのフィードバック信号を受理し、樹脂のトウへの供給量を制御する樹脂供給量制御部を具備する樹脂供給ポンプと、樹脂をトウに供給するノズルと、樹脂供給ポンプから樹脂を該ノズルに移送する樹脂移送管とを有し、
前記信号送信手段からのフィードバック信号を受理し、樹脂をトウの進行速度に合わせてトウの樹脂含有量が一定になるように前記樹脂供給手段により樹脂を供給するために、前記樹脂移送管を、該管内の樹脂移送量の変化により変形しない管としたことを特徴とするトウプリプレグが巻回された繊維強化複合材料の製造装置。
A tow feeding means, a resin supply means for supplying a resin to the tow, a resin impregnation means for impregnating the supplied resin with the tow, a winding means for winding the resin-impregnated tow prepreg around the winding portion, A signal transmission means for sensing the progress speed of the tow and sending a feedback signal of the speed to the resin supply means;
The resin supply means receives a feedback signal from the signal transmission means, and includes a resin supply pump including a resin supply amount control unit that controls the supply amount of resin to the tow, a nozzle that supplies resin to the tow, A resin transfer pipe for transferring the resin from the resin supply pump to the nozzle,
In order to receive the feedback signal from the signal transmitting means and supply the resin by the resin supplying means so that the resin content of the tow becomes constant according to the progressing speed of the tow, the resin transfer pipe, An apparatus for producing a fiber-reinforced composite material wound with a tow prepreg, wherein the pipe is not deformed by a change in the amount of resin transferred in the pipe.
JP2004246476A 2004-08-26 2004-08-26 Manufacturing method of fiber reinforced composite material and manufacturing apparatus of fiber reinforced composite material Active JP4511286B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2004246476A JP4511286B2 (en) 2004-08-26 2004-08-26 Manufacturing method of fiber reinforced composite material and manufacturing apparatus of fiber reinforced composite material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2004246476A JP4511286B2 (en) 2004-08-26 2004-08-26 Manufacturing method of fiber reinforced composite material and manufacturing apparatus of fiber reinforced composite material

Publications (2)

Publication Number Publication Date
JP2006063173A true JP2006063173A (en) 2006-03-09
JP4511286B2 JP4511286B2 (en) 2010-07-28

Family

ID=36109936

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2004246476A Active JP4511286B2 (en) 2004-08-26 2004-08-26 Manufacturing method of fiber reinforced composite material and manufacturing apparatus of fiber reinforced composite material

Country Status (1)

Country Link
JP (1) JP4511286B2 (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009107202A (en) * 2007-10-30 2009-05-21 Murata Mach Ltd Resin deposit method and resin deposit device in filament winding molding
JP2009126055A (en) * 2007-11-22 2009-06-11 Murata Mach Ltd Resin adhesion apparatus
CN102022589A (en) * 2010-12-22 2011-04-20 南京诺尔泰复合材料设备制造有限公司 Method and device for preparing composite tube having axial fibers
WO2013183667A1 (en) 2012-06-05 2013-12-12 三菱レイヨン株式会社 Epoxy resin composition
WO2017099060A1 (en) 2015-12-10 2017-06-15 三菱レイヨン株式会社 Tow prepreg, composite material-reinforced pressure vessel, and method for producing composite material-reinforced pressure vessel
WO2017104823A1 (en) 2015-12-16 2017-06-22 三菱ケミカル株式会社 Prepreg tape and use thereof
WO2018181983A1 (en) 2017-03-31 2018-10-04 三菱ケミカル株式会社 Prepreg sheet, method for manufacturing same, skin material-provided unitary layer, method for manufacturing article molded from fiber-reinforced composite material, and article molded from fiber-reinforced composite material
WO2019244994A1 (en) 2018-06-20 2019-12-26 三菱ケミカル株式会社 Prepreg sheet and manufacturing method therefor, fiber-reinforced composite material molded article and manufacturing method therefor, and method for manufacturing preform
WO2020218610A1 (en) 2019-04-26 2020-10-29 三菱ケミカル株式会社 Method for manufacturing molded article of fiber-reinforced composite material, reinforcing fiber substrate and molded article of fiber-reinforced composite material
JP7421944B2 (en) 2020-02-17 2024-01-25 本田技研工業株式会社 Tow prepreg manufacturing equipment and manufacturing method

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102032819B1 (en) * 2018-03-30 2019-10-17 주식회사 이지컴퍼지트 Apparatus for manufacturing tow prepreg and method for the same

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08142208A (en) * 1994-11-24 1996-06-04 Mitsubishi Rayon Co Ltd Production of filament winding molded product
JPH09176346A (en) * 1995-12-27 1997-07-08 Nippon Oil Co Ltd Production of tow prepreg
JP2000191807A (en) * 1998-12-24 2000-07-11 Mitsubishi Rayon Co Ltd Tow prepreg and preparation thereof
JP2005305927A (en) * 2004-04-23 2005-11-04 Toyota Motor Corp Filament winding device and processing device

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08142208A (en) * 1994-11-24 1996-06-04 Mitsubishi Rayon Co Ltd Production of filament winding molded product
JPH09176346A (en) * 1995-12-27 1997-07-08 Nippon Oil Co Ltd Production of tow prepreg
JP2000191807A (en) * 1998-12-24 2000-07-11 Mitsubishi Rayon Co Ltd Tow prepreg and preparation thereof
JP2005305927A (en) * 2004-04-23 2005-11-04 Toyota Motor Corp Filament winding device and processing device

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009107202A (en) * 2007-10-30 2009-05-21 Murata Mach Ltd Resin deposit method and resin deposit device in filament winding molding
JP2009126055A (en) * 2007-11-22 2009-06-11 Murata Mach Ltd Resin adhesion apparatus
CN102022589A (en) * 2010-12-22 2011-04-20 南京诺尔泰复合材料设备制造有限公司 Method and device for preparing composite tube having axial fibers
WO2013183667A1 (en) 2012-06-05 2013-12-12 三菱レイヨン株式会社 Epoxy resin composition
US10233324B2 (en) 2012-06-05 2019-03-19 Mitsubishi Chemical Corporation Epoxy resin composition
WO2017099060A1 (en) 2015-12-10 2017-06-15 三菱レイヨン株式会社 Tow prepreg, composite material-reinforced pressure vessel, and method for producing composite material-reinforced pressure vessel
WO2017104823A1 (en) 2015-12-16 2017-06-22 三菱ケミカル株式会社 Prepreg tape and use thereof
WO2018181983A1 (en) 2017-03-31 2018-10-04 三菱ケミカル株式会社 Prepreg sheet, method for manufacturing same, skin material-provided unitary layer, method for manufacturing article molded from fiber-reinforced composite material, and article molded from fiber-reinforced composite material
WO2019244994A1 (en) 2018-06-20 2019-12-26 三菱ケミカル株式会社 Prepreg sheet and manufacturing method therefor, fiber-reinforced composite material molded article and manufacturing method therefor, and method for manufacturing preform
WO2020218610A1 (en) 2019-04-26 2020-10-29 三菱ケミカル株式会社 Method for manufacturing molded article of fiber-reinforced composite material, reinforcing fiber substrate and molded article of fiber-reinforced composite material
JP7421944B2 (en) 2020-02-17 2024-01-25 本田技研工業株式会社 Tow prepreg manufacturing equipment and manufacturing method

Also Published As

Publication number Publication date
JP4511286B2 (en) 2010-07-28

Similar Documents

Publication Publication Date Title
CN108368281B (en) Tow prepreg, composite material-reinforced pressure vessel, and method for producing composite material-reinforced pressure vessel
JP4511286B2 (en) Manufacturing method of fiber reinforced composite material and manufacturing apparatus of fiber reinforced composite material
JP5726292B2 (en) Apparatus and method for widening fiber bundles for continuous production of prepregs
US20120251823A1 (en) Tow prepreg and system and method for forming the same
KR101731686B1 (en) Solidified fibre bundles
JP3575718B2 (en) Manufacturing method of tow prepreg
KR102300301B1 (en) Coating solution-impregnated reinforced fiber fabric, sheet-like integral body, prepreg, prepreg tape, and manufacturing method of fiber-reinforced composite material
WO2022057298A1 (en) Long basalt fiber thermoplastic consumable for 3d printing, preparation method therefor and preparation device therefor
JP2005335296A (en) Manufacturing method of tow prepreg
JP6619789B2 (en) Tow prepreg manufacturing apparatus and manufacturing method thereof
JP5540722B2 (en) Prepreg manufacturing apparatus and manufacturing method
WO2010107119A1 (en) Process and device for producing composite container
JPWO2020040153A1 (en) Prepreg manufacturing method and manufacturing equipment
JPS61229535A (en) Method and device for manufacturing fiber reinforced resin sheet
JP3635773B2 (en) Yarn prepreg manufacturing method and apparatus
KR102032819B1 (en) Apparatus for manufacturing tow prepreg and method for the same
JP2014148573A (en) Method for manufacturing tow prepreg
JPH11130882A (en) Yarn prepreg and its preparation
TWI541397B (en) Equipment and method for treating a continuous filament tow
JPS646012B2 (en)
KR20180066396A (en) Manufacturing apparatus for tow prepreg and method thereof
JP2019107772A (en) Filament winding apparatus
JP2010221401A (en) Method and apparatus for manufacturing composite container
JP4187279B2 (en) Manufacturing method of filament winding molded product
JPS61229536A (en) Method and apparatus for producing fiber-reinforced resin sheet

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20061208

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20090423

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20090512

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20090629

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20091020

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20100413

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20100506

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130514

Year of fee payment: 3

R150 Certificate of patent or registration of utility model

Ref document number: 4511286

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

Free format text: JAPANESE INTERMEDIATE CODE: R150

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130514

Year of fee payment: 3

S531 Written request for registration of change of domicile

Free format text: JAPANESE INTERMEDIATE CODE: R313531

S533 Written request for registration of change of name

Free format text: JAPANESE INTERMEDIATE CODE: R313533

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20140514

Year of fee payment: 4

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

S531 Written request for registration of change of domicile

Free format text: JAPANESE INTERMEDIATE CODE: R313531

S533 Written request for registration of change of name

Free format text: JAPANESE INTERMEDIATE CODE: R313533

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

S533 Written request for registration of change of name

Free format text: JAPANESE INTERMEDIATE CODE: R313533

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

S533 Written request for registration of change of name

Free format text: JAPANESE INTERMEDIATE CODE: R313533

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250