JP2006016402A - Cosmetic for cleaning body - Google Patents
Cosmetic for cleaning body Download PDFInfo
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- JP2006016402A JP2006016402A JP2005226297A JP2005226297A JP2006016402A JP 2006016402 A JP2006016402 A JP 2006016402A JP 2005226297 A JP2005226297 A JP 2005226297A JP 2005226297 A JP2005226297 A JP 2005226297A JP 2006016402 A JP2006016402 A JP 2006016402A
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- 229920000728 polyester Polymers 0.000 description 1
- 239000004633 polyglycolic acid Substances 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- PYJBVGYZXWPIKK-UHFFFAOYSA-M potassium;tetradecanoate Chemical compound [K+].CCCCCCCCCCCCCC([O-])=O PYJBVGYZXWPIKK-UHFFFAOYSA-M 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 235000010409 propane-1,2-diol alginate Nutrition 0.000 description 1
- 239000000770 propane-1,2-diol alginate Substances 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- RADKZDMFGJYCBB-UHFFFAOYSA-N pyridoxal hydrochloride Natural products CC1=NC=C(CO)C(C=O)=C1O RADKZDMFGJYCBB-UHFFFAOYSA-N 0.000 description 1
- 229940079889 pyrrolidonecarboxylic acid Drugs 0.000 description 1
- MUPFEKGTMRGPLJ-ZQSKZDJDSA-N raffinose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO[C@@H]2[C@@H]([C@@H](O)[C@@H](O)[C@@H](CO)O2)O)O1 MUPFEKGTMRGPLJ-ZQSKZDJDSA-N 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 1
- 229960001755 resorcinol Drugs 0.000 description 1
- 229960002477 riboflavin Drugs 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000008165 rice bran oil Substances 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 235000002020 sage Nutrition 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 229940058287 salicylic acid derivative anticestodals Drugs 0.000 description 1
- 150000003872 salicylic acid derivatives Chemical class 0.000 description 1
- 229930182490 saponin Natural products 0.000 description 1
- 150000007949 saponins Chemical class 0.000 description 1
- 235000017709 saponins Nutrition 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 235000020637 scallop Nutrition 0.000 description 1
- 230000021148 sequestering of metal ion Effects 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 229940057910 shea butter Drugs 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 235000011083 sodium citrates Nutrition 0.000 description 1
- 239000001540 sodium lactate Substances 0.000 description 1
- 235000011088 sodium lactate Nutrition 0.000 description 1
- 229940005581 sodium lactate Drugs 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- YWIVKILSMZOHHF-QJZPQSOGSA-N sodium;(2s,3s,4s,5r,6r)-6-[(2s,3r,4r,5s,6r)-3-acetamido-2-[(2s,3s,4r,5r,6r)-6-[(2r,3r,4r,5s,6r)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2- Chemical class [Na+].CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 YWIVKILSMZOHHF-QJZPQSOGSA-N 0.000 description 1
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 229960002920 sorbitol Drugs 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000000021 stimulant Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- LRBQNJMCXXYXIU-NRMVVENXSA-N tannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-NRMVVENXSA-N 0.000 description 1
- 235000015523 tannic acid Nutrition 0.000 description 1
- 229920002258 tannic acid Polymers 0.000 description 1
- 229940033123 tannic acid Drugs 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000013616 tea Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
- 229960002447 thiram Drugs 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- 239000001585 thymus vulgaris Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 229960000984 tocofersolan Drugs 0.000 description 1
- 229940042585 tocopherol acetate Drugs 0.000 description 1
- 235000019149 tocopherols Nutrition 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- PMBRBOODEWULOI-UHFFFAOYSA-N trichloromethanide Chemical compound Cl[C-](Cl)Cl PMBRBOODEWULOI-UHFFFAOYSA-N 0.000 description 1
- QPQANCNBWQXGTQ-UHFFFAOYSA-N trihydroxy(trimethylsilylperoxy)silane Chemical compound C[Si](C)(C)OO[Si](O)(O)O QPQANCNBWQXGTQ-UHFFFAOYSA-N 0.000 description 1
- OUYCCCASQSFEME-UHFFFAOYSA-N tyrosine Natural products OC(=O)C(N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-UHFFFAOYSA-N 0.000 description 1
- 210000003954 umbilical cord Anatomy 0.000 description 1
- 229960002703 undecylenic acid Drugs 0.000 description 1
- 229940045136 urea Drugs 0.000 description 1
- 229940116269 uric acid Drugs 0.000 description 1
- 239000004474 valine Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 235000019155 vitamin A Nutrition 0.000 description 1
- 239000011719 vitamin A Substances 0.000 description 1
- 235000019156 vitamin B Nutrition 0.000 description 1
- 239000011720 vitamin B Substances 0.000 description 1
- 235000019164 vitamin B2 Nutrition 0.000 description 1
- 239000011716 vitamin B2 Substances 0.000 description 1
- 235000019158 vitamin B6 Nutrition 0.000 description 1
- 239000011726 vitamin B6 Substances 0.000 description 1
- 235000011912 vitamin B7 Nutrition 0.000 description 1
- 239000011735 vitamin B7 Substances 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
- 235000019166 vitamin D Nutrition 0.000 description 1
- 239000011710 vitamin D Substances 0.000 description 1
- 150000003710 vitamin D derivatives Chemical class 0.000 description 1
- 229940045997 vitamin a Drugs 0.000 description 1
- 229940011671 vitamin b6 Drugs 0.000 description 1
- 229940046008 vitamin d Drugs 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 229940075420 xanthine Drugs 0.000 description 1
- 229920001221 xylan Polymers 0.000 description 1
- 150000004823 xylans Chemical class 0.000 description 1
- 239000012138 yeast extract Substances 0.000 description 1
- 239000009538 yokuinin Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229960001296 zinc oxide Drugs 0.000 description 1
- 229940043810 zinc pyrithione Drugs 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
- PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 description 1
- 239000002076 α-tocopherol Substances 0.000 description 1
- 235000004835 α-tocopherol Nutrition 0.000 description 1
- 235000007680 β-tocopherol Nutrition 0.000 description 1
- 239000011590 β-tocopherol Substances 0.000 description 1
- 239000002478 γ-tocopherol Substances 0.000 description 1
- QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 description 1
- QUEDXNHFTDJVIY-DQCZWYHMSA-N γ-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-DQCZWYHMSA-N 0.000 description 1
Abstract
Description
本発明は使用感の改善された身体清浄用化粧料に関する。 The present invention relates to a body-cleaning cosmetic material with improved usability.
身体清浄用化粧料として界面活性剤を用いることは従来行われてきたことであり、殊に、産業用分野では切削油やグリースのような強固な汚れを取り除き、しかも皮膚のあれを最小限にとどめるために非イオン性界面活性剤とスクラブ粒子を含有する皮膚清浄用化粧料が用いられてきており、特許文献1〜7に等開示されている。
しかしながら従来用いられてきた配合においては使用後にベタツキ感が残り、使用者の満足を得られないという問題点があった。
The use of surfactants as body cleansing cosmetics has been practiced in the past, especially in the industrial field to remove strong dirt such as cutting oils and greases while minimizing skin roughness. In order to keep it, skin cleansing cosmetics containing nonionic surfactants and scrub particles have been used, and are disclosed in Patent Documents 1 to 7 and the like.
However, the conventionally used formulations have a problem that a sticky feeling remains after use and the user's satisfaction cannot be obtained.
本発明の目的は、使用後にベタツキ感が残らない身体清浄用化粧料を提供することである。 An object of the present invention is to provide a cosmetic for body cleaning that does not leave a sticky feeling after use.
本発明者はかかる問題を解決するために鋭意検討を行った結果、使用後のベタツキ感の原因が、用いられる界面活性剤にあることを見出し、特定の高使用感界面活性剤を用いることによって解決することを見出して本発明を完成するに至った。
すなわち本発明は、下記に記載する通りの特定の高使用感界面活性剤を配合してなる身体清浄用化粧料である。
(1)ポリオキシエチレン残基およびオキシプロピレン残基からなる親水基を有する非イオン性界面活性剤とスクラブ粒子を含有することを特徴とする身体洗浄用化粧料。
(2)ポリオキシエチレンオキシプロピレンラウリルエーテルを界面活性剤として配合し、スクラブ粒子を含有することを特徴とする身体清浄用化粧料。
(3)スクラブ粒子として有機質粒子を3〜20質量%を含有する事を特徴とする(1)または(2)に記載の身体清浄用化粧料。
(4)増粘剤を含有する事を特徴とする(1)〜(3)のいずれかに記載の身体清浄用化粧料。
(5)増粘剤が合成高分子であることを特徴とする(1)〜(4)のいずれかに記載の身体清浄用化粧料。
(6)スクラブ粒子が生分解性有機質粒子であることを特徴とする(1)〜(5)のいずれかに記載の身体清浄用化粧料。
(7)手指の清浄に用いられる事を特徴とする(1)〜(6)のいずれかに記載の身体清浄用化粧料。
As a result of diligent studies to solve such problems, the present inventors have found that the surfactant used is the cause of stickiness after use, and by using a specific high-use surfactant. The present invention has been completed by finding a solution.
That is, the present invention is a body cleansing cosmetic comprising a specific high-use surfactant as described below.
(1) A body washing cosmetic comprising a nonionic surfactant having a hydrophilic group comprising a polyoxyethylene residue and an oxypropylene residue and scrub particles.
(2) A body cleaning cosmetic comprising polyoxyethyleneoxypropylene lauryl ether as a surfactant and scrubbing particles.
(3) The body cleaning cosmetic according to (1) or (2), wherein the organic particles are contained as scrub particles in an amount of 3 to 20% by mass.
(4) The body cleaning cosmetic according to any one of (1) to (3), which further comprises a thickener.
(5) The body cleaning cosmetic according to any one of (1) to (4), wherein the thickener is a synthetic polymer.
(6) The body-cleaning cosmetic according to any one of (1) to ( 5 ) , wherein the scrub particles are biodegradable organic particles.
(7) The body cleaning cosmetic according to any one of (1) to (6), which is used for cleaning fingers.
本発明により、使用後のべたつき感を低減し、著しく使用感が改善された身体清浄用化粧料が得られる。 According to the present invention, it is possible to obtain a body-cleaning cosmetic material that has reduced stickiness after use and is remarkably improved in use feeling.
以下、本発明を詳しく説明する。
本発明は、必須成分として特定の高使用感界面活性剤を含有する。更に、本発明は手指、足、胴体、顔、頭部を洗浄する用途に用いることが可能であるが、手指に付着した油、錆、カーボン等の強固な汚れを除去するのに最適である。
また、本発明に用いられる特定の高使用感界面活性剤は、高使用感界面活性剤であり具体的には、
陽イオン性界面活性剤としては:
アンモニウム系では;
塩化アルキルトリメチルアンモニウム、塩化アルキルジメチルベンジルアンモニウム、塩化ジアルキルジメチルアンモニウム、臭化アルキルトリメチルアンモニウム、塩化アルキルペンタエトキシアンモニウム、エチル硫酸ラノリン脂肪酸アミノプロピルエチルジメチルアンモニウム、カチオン化セルロース、
アミド系では;
アシルジエチルアミノエチルアミド、アシルジメチルアミノプロピルアミド、ポリオキシエチレン脂肪酸アミド、
その他では;
ミリスチルジメチルアミンオキシド、
The present invention will be described in detail below.
The present invention contains a specific high-use surfactant as an essential component. Furthermore, the present invention can be used for washing fingers, feet, torso, face and head, but is most suitable for removing strong dirt such as oil, rust and carbon adhering to fingers. .
In addition, the specific high-use surfactant used in the present invention is a high-use surfactant, specifically,
Cationic surfactants include:
For ammonium systems;
Alkyltrimethylammonium chloride, alkyldimethylbenzylammonium chloride, dialkyldimethylammonium chloride, alkyltrimethylammonium bromide, alkylpentaethoxyammonium chloride, ethyl lanolin sulfate fatty acid aminopropylethyldimethylammonium, cationized cellulose,
In the amide system;
Acyl diethylaminoethylamide, acyldimethylaminopropylamide, polyoxyethylene fatty acid amide,
In other cases;
Myristyldimethylamine oxide,
両イオン性界面活性剤としては:
ベタイン系では;
脂肪酸残基の炭素数が13以上のアルキルジメチルアミノ酢酸ベタイン、アシルアミドプロピルジメチルアミノ酢酸ベタイン、
イミダゾリニウム系では;
N−アルキル−N−カルボキシメチル−N−ヒドロキシエチルイミダゾリニウムベタイン、N−アルキル−N―カルボキシメチル−N−ヒドロキシエチルエチレンジアミン・ラウリル硫酸およびその塩、
グリシン型では;
ポリオクチルポリアミノエチルグリシン、
アミノプロピオン酸型では;
アルキルアミノプロピオン酸、アルキルアミノジプロピオン酸、
Amphoteric surfactants include:
For betaine;
Alkyldimethylaminoacetic acid betaine having a fatty acid residue of 13 or more carbon atoms, acylamidopropyldimethylaminoacetic acid betaine,
For imidazolinium series:
N-alkyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, N-alkyl-N-carboxymethyl-N-hydroxyethylethylenediamine lauryl sulfate and salts thereof,
For glycine type;
Polyoctyl polyaminoethylglycine,
For aminopropionic acid type;
Alkylaminopropionic acid, alkylaminodipropionic acid,
陰イオン性界面活性剤としては:
石鹸では;
炭素数が17以下のナトリウム石鹸、
アミノ酸系では;
脂肪酸残基の炭素数が17以下のアシルサルコシンおよびその塩、アシルアミノ酸およびその塩(ただし、アシルグルタミン酸トリエタノールアミン塩は洗い落とし時にヌルツキがあるので本願発明の目的には適さない)、
アシル化ペプチドおよびその塩(ただし、アシル化ペプチドナトリウム塩はベタツキがあるので本願発明の目的には適さない)
ポリオキシアルキレン付加物では;
ポリオキシエチレンアルキルエーテルカルボン酸及びその塩、ポリオキシエチレンアルキルエーテル硫酸及びその塩、ポリオキシエチレンアルキルエーテルスルホン酸およびその塩、
リン酸系では;
アルキルリン酸およびそのカリウム塩またはアルカノールアミン塩、ポリオキシエチレンアルキルエーテルリン酸およびその塩、
スルホコハク酸系では;
スルホコハク酸ジアルキルおよびその塩、ポリオキシエチレンスルホコハク酸アルキルエーテルおよびその塩、
アルキルフェノール系では;
アルキルフェノールエーテルリン酸エステルおよびその塩、
Anionic surfactants include:
With soap;
Sodium soap with 17 or less carbon atoms,
In amino acid systems;
Acyl sarcosine having a carbon number of 17 or less in fatty acid residues and salts thereof, acyl amino acids and salts thereof (however, acyl glutamic acid triethanolamine salt is not suitable for the purpose of the present invention because it has a nullness when washed off),
Acylated peptides and salts thereof (however, acylated peptide sodium salt is not suitable for the purposes of the present invention because of its stickiness)
For polyoxyalkylene adducts;
Polyoxyethylene alkyl ether carboxylic acid and its salt, polyoxyethylene alkyl ether sulfuric acid and its salt, polyoxyethylene alkyl ether sulfonic acid and its salt,
In phosphate system;
Alkyl phosphoric acid and its potassium salt or alkanolamine salt, polyoxyethylene alkyl ether phosphoric acid and its salt,
For sulfosuccinic acid systems;
Dialkyl sulfosuccinate and salts thereof, polyoxyethylene sulfosuccinic acid alkyl ether and salts thereof,
For alkylphenols:
Alkylphenol ether phosphates and salts thereof,
非イオン性界面活性剤としては:
ポリオキシアルキレンエーテル系では;
ポリオキシエチレンポリオキシプロピレンアルキルエーテル、ポリオキシエチレンソルビットミツロウ、ポリオキシエチレンヒマシ油、ポリオキシエチレンステロール、ポリオキシエチレン水素添加ステロール、ポリオキシエチレンラノリン、ポリオキシエチレンラノリンアルコール、ポリオキシエチレンアルキルフェニルホルムアルデヒド縮合物
リン脂質としては;
レシチン、
エステル系では;
プロピレングリコール脂肪酸エステル、グリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ポリオキシエチレングリセリン脂肪酸エステル、ソルビタン脂肪酸エステル、脂肪酸残基の炭素数が17以下のポリオキシエチレンソルビタン脂肪酸エステル、脂肪酸残基が飽和炭素鎖であるポリオキシエチレンソルビット脂肪酸エステル、ポリエチレングリコール脂肪酸エステル、
から選ぶことが出来、さらに、この中でも非イオン性界面活性剤は刺激性が特に低い点が優れており、次いで両イオン性界面活性剤、陽イオン生界面活性剤、陰イオン性界面活性剤の順に優れる。一方、洗浄力の高さから清潔になったと感じる爽快感を与える効果は陰イオン性界面活性剤が最も優れ、陽イオン性界面活性剤、両イオン性界面活性剤、非イオン性界面活性剤の順である。
Nonionic surfactants include:
For polyoxyalkylene ethers;
Polyoxyethylene polyoxypropylene alkyl ether, polyoxyethylene sorbit beeswax, polyoxyethylene castor oil, polyoxyethylene sterol, polyoxyethylene hydrogenated sterol, polyoxyethylene lanolin, polyoxyethylene lanolin alcohol, polyoxyethylene alkylphenyl formaldehyde Condensates As phospholipids:
lecithin,
For ester systems:
Propylene glycol fatty acid ester, glycerin fatty acid ester, polyglycerin fatty acid ester, polyoxyethylene glycerin fatty acid ester, sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester having a fatty acid residue of 17 or less, fatty acid residue is saturated carbon chain Some polyoxyethylene sorbit fatty acid esters, polyethylene glycol fatty acid esters,
Furthermore, among these, nonionic surfactants are excellent in that they are particularly low in irritation, followed by amphoteric surfactants, cationic biosurfactants, and anionic surfactants. Excellent in order. On the other hand, anionic surfactants are the most effective in giving a refreshing feeling that they have been cleaned due to their high detergency, and they are the most effective of cationic surfactants, amphoteric surfactants, and nonionic surfactants. In order.
とりわけ、非イオン性界面活性剤の中でもポリオキシアルキレンエーテル系の方がエステル系やリン脂質よりも製剤の安定性で勝っており、環境中での分解性の高さではエステル系、リン脂質系がポリオキシアルキレン付加物よりも優れている。
また、ポリオキシエチレンポリオキシプロピレンアルキルエーテルは最も使用感が好適で、これに次いでポリグリセリン脂肪酸エステル、ポリエチレングリコール脂肪酸エステル、ポリオキシエチレングリセリン脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、ソルビタン脂肪酸エステルの順で優れている。
In particular, among nonionic surfactants, the polyoxyalkylene ether type is superior to the ester type and phospholipid in terms of the stability of the preparation, and the high degradability in the environment is ester type and phospholipid type. Is superior to the polyoxyalkylene adduct.
Polyoxyethylene polyoxypropylene alkyl ethers are most suitable for use, followed by polyglycerin fatty acid ester, polyethylene glycol fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyoxyethylene sorbitan fatty acid ester, and sorbitan fatty acid ester in this order. Is excellent.
また、陰イオン性界面活性剤は泡立ちが良く、洗浄力に優れ、使用感がさっぱりとしているので使用者に爽快感を与える効果に優れている。ポリオキシアルキレン付加物の中ではポリオキシエチレンアルキルエーテルスルホン酸、ポリオキシエチレンアルキルエーテルリン酸、ポリオキシエチレンアルキルエーテルカルボン酸、ポリオキシエチレンアルキルエーテル硫酸の順に使用感がよい。
また、陰イオン性界面活性剤の中では、アミノ酸系、ポリオキシアルキレン付加物、スルホコハク酸系、石鹸、リン酸系、アルキルフェノール系の順に刺激性が少なく、アルキルフェノール系、リン酸系、石鹸、スルホコハク酸系、ポリオキシアルキレン付加物、アミノ酸系、の順に洗浄力が高い点で好適である。
In addition, anionic surfactants are excellent in foaming, excellent in detergency, and refreshing to the user, so that they are excellent in the effect of giving the user a refreshing feeling. Among the polyoxyalkylene adducts, polyoxyethylene alkyl ether sulfonic acid, polyoxyethylene alkyl ether phosphoric acid, polyoxyethylene alkyl ether carboxylic acid, and polyoxyethylene alkyl ether sulfuric acid are preferable in this order.
Among anionic surfactants, amino acids, polyoxyalkylene adducts, sulfosuccinic acids, soaps, phosphoric acids, and alkylphenols are less irritating in this order, and alkylphenols, phosphoric acids, soaps, sulfosuccinics. The acid-based, polyoxyalkylene adduct, and amino acid-based materials are preferred in that they have high detergency.
より更に好ましくは、直鎖脂肪族の疎水基を有する非イオン性界面活性剤であることが望ましく、更に好ましくは非イオン性界面活性剤がポリオキシプロピレンを親水基として有するものまたは炭素数16以上の飽和または不飽和炭素鎖を疎水基として有するものであることがのぞましい。 More preferably, it is desirable that it is a nonionic surfactant having a linear aliphatic hydrophobic group, and even more preferable that the nonionic surfactant has polyoxypropylene as a hydrophilic group or a carbon number of 16 or more. And having a saturated or unsaturated carbon chain as a hydrophobic group.
また、本発明の身体清浄用化粧料は、スクラブ粒子を含有させることによって洗浄力を増強し、界面活性剤の含有量を必要最小限とすることが望ましく、スクラブ粒子として有機質粒子3〜20質量%を含むものが最適である。すなわち、スクラブ粒子として含有する粒子としては皮膚を傷つけない適当な硬度を持つものとして有機質粒子であることが好ましく、中でも粒子径分布、粒子形状が揃っているという点では合成高分子が好ましく、とりわけ高密度および低密度のポリエチレン粒子が最適である。一方、環境中での分解性の良さでは動植物由来の物であることが好ましい。
更に、本発明の身体清浄用化粧料は増粘剤を含有することによりスクラブ粒子の均一な分散状態を維持することが望ましく、更に好ましくは増粘剤として合成高分子を用いることによりベタツキの少ない良好な使用感を得ることが出来る。
In addition, it is desirable that the cosmetic for body cleaning of the present invention enhances detergency by containing scrub particles and minimizes the content of surfactant, and 3 to 20 mass of organic particles as scrub particles. The one containing% is optimal. That is, the particles contained as scrub particles are preferably organic particles having an appropriate hardness that does not damage the skin, and among them, a synthetic polymer is preferable in that the particle size distribution and the particle shape are uniform. High density and low density polyethylene particles are optimal. On the other hand, it is preferable to be derived from animals and plants in terms of good degradability in the environment.
Furthermore, it is desirable that the body cleansing cosmetic of the present invention contains a thickener to maintain a uniform dispersion state of the scrub particles, and more preferably, it is less sticky by using a synthetic polymer as the thickener. Good usability can be obtained.
また、本発明の身体清浄用化粧料は生分解性有機質粒子をスクラブ粒子として含有することにより、より環境に適合したものとすることが出来る。
生分解性有機質粒子としてはキトサン/セルロース/でん粉混合物粒子、でん粉/ポリビニルアルコール混合物粒子、ポリエステルカーボネート粒子、ポリエチレンサクシネート粒子、ポリカプロラクトン系樹脂粒子、ポリグリコール酸粒子、ポリテトラメチレンアジペート・コ・テレフタレート粒子、ポリブチレンアジペートテレフタレート粒子、ポリブチレンサクシネート・コ・アジペート・コ・テレフタレート粒子、ポリブチレンサクシネートアジペート粒子、ポリブチレンサクシネートカーボネート粒子、ポリブチレンサクシネートテレフタレート粒子、ポリブチレンサクシネート粒子およびポリ乳酸粒子を用いることが適当であり、好ましくはポリブチレンサクシネート、ポリブチレンサクシネートアジペートまたはポリ乳酸の粒子から選ばれる一種または二種以上であり、更に好ましくはポリブチレンサクシネートアジペートまたはポリ乳酸であり、より更に好ましくはポリブチレンサクシネートアジペートを含有する。
Further, the body cleaning cosmetic of the present invention can be made more suitable for the environment by containing biodegradable organic particles as scrubbing particles.
Biodegradable organic particles include chitosan / cellulose / starch mixture particles, starch / polyvinyl alcohol mixture particles, polyester carbonate particles, polyethylene succinate particles, polycaprolactone resin particles, polyglycolic acid particles, polytetramethylene adipate co-terephthalate Particles, polybutylene adipate terephthalate particles, polybutylene succinate co-adipate co-terephthalate particles, polybutylene succinate adipate particles, polybutylene succinate carbonate particles, polybutylene succinate terephthalate particles, polybutylene succinate particles and poly It is appropriate to use lactic acid particles, preferably polybutylene succinate, polybutylene succinate adipate or polylactic acid granules And the chosen one or more kinds from, more preferably a polybutylene succinate adipate or polylactic acid, more preferably contains polybutylene succinate adipate more.
一方、本発明の身体清浄用化粧料は、発明の効果を阻害しない範囲において通常化粧料等に用いられる他の成分と適宜、併用しうる。例えば、炭酸カルシウム、タルク、マイカ、カオリン、ラウロイルリジン、二酸化チタン、二酸化亜鉛等の粉末成分;ホホバ油、マカデミアナッツ油、アボガド油、月見草油、ミンク油、ナタネ油、ヒマシ油、ヒマワリ油、トーモロコシ油、カカオ油、ヤシ油、コメヌカ油、オリーブ油、アーモンド油、ごま油、サフラワー油、大豆油、椿油、パーシック油、ヒマシ油、ミンク油、綿実油、モクロウ、パーム油、パーム核油、卵黄油、ラノリン、スクワレン等の天然動植物油脂類、合成トリグリセライド;スクワラン、流動パラフィン、ワセリン、セレシン、マイクロクリスタリンワックス、イソパラフィン等の炭化水素類;カルナバウロウ、パラフィンワックス、鯨ロウ、ミツロウ、キヤンデリラワックス、ラノリン等のワックス類;セタノール、ステアリルアルコール、ラウリルアルコール、セトステアリルアルコール、オレイルアルコール、ベヘニルアルコール、ラノリンアルコール、水添ラノリンアルコール、ヘキシルデカノール、オクチルドデカノール等の高級アルコール類; On the other hand, the body cleaning cosmetic of the present invention can be appropriately used in combination with other components usually used in cosmetics and the like as long as the effects of the invention are not impaired. For example, powder components such as calcium carbonate, talc, mica, kaolin, lauroyl lysine, titanium dioxide, zinc dioxide; jojoba oil, macadamia nut oil, avocado oil, evening primrose oil, mink oil, rapeseed oil, castor oil, sunflower oil, corn oil , Cocoa oil, coconut oil, rice bran oil, olive oil, almond oil, sesame oil, safflower oil, soybean oil, coconut oil, persic oil, castor oil, mink oil, cottonseed oil, owl, palm oil, palm kernel oil, egg yolk oil, lanolin , Squalene and other natural animal and vegetable oils, synthetic triglycerides; hydrocarbons such as squalane, liquid paraffin, petrolatum, ceresin, microcrystalline wax, isoparaffin; carnauba wax, paraffin wax, whale wax, beeswax, candelilla wax, lanolin, etc. Class; Seta Lumpur, stearyl alcohol, higher alcohols lauryl alcohol, cetostearyl alcohol, oleyl alcohol, behenyl alcohol, lanolin alcohol, hydrogenated lanolin alcohol, hexyl decanol, octyl dodecanol;
ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘニン酸、イソステアリン酸、オレイン酸、リノレン酸、リノール酸、オキシステアリン酸、ウンデシレン酸、ラノリン脂肪酸、硬質ラノリン脂肪酸、軟質ラノリン脂肪酸等の高級脂肪酸類;コレステリル−オクチルドデシル−ベヘニル等のコレステロールおよびその誘導体;イソプロピルミリスチン酸、イソプロピルパルミチン酸、イソプロピルステアリン酸、2エチルヘキサン酸グリセロール、ブチルステアリン酸、リノール酸エチル等のエステル類;ジエチレングリコールモノプロピルエーテル、ポリオキシエチレンポリオキシプロピレンペンタエリトリトールエーテル、ポリオキシプロピレンブチルエーテル等の極性オイル; Higher fatty acids such as lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, isostearic acid, oleic acid, linolenic acid, linoleic acid, oxystearic acid, undecylenic acid, lanolin fatty acid, hard lanolin fatty acid, soft lanolin fatty acid; Cholesterol such as cholesteryl-octyldodecyl-behenyl and derivatives thereof; esters such as isopropyl myristic acid, isopropyl palmitic acid, isopropyl stearic acid, glycerol 2-ethylhexanoate, butyl stearic acid, ethyl linoleate; diethylene glycol monopropyl ether, polyoxy Polar oils such as ethylene polyoxypropylene pentaerythritol ether, polyoxypropylene butyl ether;
その他、メチルフェニルポリシロキサン、メチルポリシロキサン、オクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサン、ドデカメチルシクロヘキサシロキサン、メチルシクロポリシロキサン、オクタメチルトリシロキサン、デカメチルテトラシロキサン、ポリオキシエチレン・メチルポリシロキサン共重合体、ポリオキシプロピレン・メチルポリシロキサン共重合体、ポリ(オキシエチレン・オキシプロピレン)メチルポリシロキサン共重合体、メチルハイドロジェンポリシロキサン、テトラヒドロテトラメチルシクロテトラシロキサン、ステアロキシメチルポリシロキサン、セトキシメチルポリシロキサン、メチルポリシロキサンエマルション、高重合メチルポリシロキサン(1)および(2)、トリメチルシロキシケイ酸、架橋型メチルポリシロキサン、架橋型メチルフェニルポリシロキサン、架橋型メチルフェニルポリシロキサン、架橋型メチルフェニルポリシロキサン(2)等、更にはアミノ変性シリコーン、エポキシ変性シリコーン、カルボキシル変性シリコーン、カルビノール変性シリコーン、メタクリル変性シリコーン、メルカプト変性シリコーン、フェノール変性シリコーン、片末端反応性シリコーン、異種官能基変性シリコーン、ポリエーテル変性シリコーン、メチルスチリル変性シリコーン、アルキル変性シリコーン、高級脂肪酸エステル変性シリコーン、親水性特殊変性シリコーン、高級アルコキシ変性シリコーン、高級脂肪酸含有シリコーン、フッ素変性シリコーン等の各種誘導体を含むシリコーン類; Others: methylphenylpolysiloxane, methylpolysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, methylcyclopolysiloxane, octamethyltrisiloxane, decamethyltetrasiloxane, polyoxyethylene / methylpoly Siloxane copolymer, polyoxypropylene / methylpolysiloxane copolymer, poly (oxyethylene / oxypropylene) methylpolysiloxane copolymer, methylhydrogenpolysiloxane, tetrahydrotetramethylcyclotetrasiloxane, stearoxymethylpolysiloxane, Cetoxymethylpolysiloxane, methylpolysiloxane emulsion, highly polymerized methylpolysiloxane (1) and (2), trimethylsiloxy Silicic acid, cross-linked methylpolysiloxane, cross-linked methylphenyl polysiloxane, cross-linked methylphenyl polysiloxane, cross-linked methylphenyl polysiloxane (2), etc., amino-modified silicone, epoxy-modified silicone, carboxyl-modified silicone, carbinol Modified silicone, methacryl-modified silicone, mercapto-modified silicone, phenol-modified silicone, one-end reactive silicone, different functional group-modified silicone, polyether-modified silicone, methylstyryl-modified silicone, alkyl-modified silicone, higher fatty acid ester-modified silicone, hydrophilic special Silicones containing various derivatives such as modified silicones, higher alkoxy-modified silicones, higher fatty acid-containing silicones, fluorine-modified silicones;
パラアミノ安息香酸およびその誘導体、ホモメチル−7N−アセチルアラントイラニレート、ブチルメトキシベンゾイルメタン、ジ−パラメトキシケイ皮酸ーモノー2ーエチルヘキサン酸グリセリル、オクチルシンナメート等のパラメトキシケイ皮酸誘導体、アミルサリシレート等のサリチル酸誘導体、2,4−ジヒドロキシベンゾフェノン等のベンゾフェノン誘導体、ジメトキシベンジリデンジオキソイミダゾリンプロピオン酸エチルヘキシル、酢酸液状ラノリン、コガネバナ根抽出エキス、トリアニリノ−p−カルボエチルヘキシルオキシ−トリアジン等の紫外線吸収剤;アルブチン、コウジ酸、リン酸アスコルビン酸マグネシウムなどのアスコルビン酸およびその誘導体、グルタチオン、甘草エキス、チョウジエキス、茶抽出物、アスタキサンチン、牛胎盤エキス、トコフェロールおよびその誘導体、トラネキサム酸およびその塩、アズレン、γ−ヒドロキシ酪酸等の美白成分; Paraaminobenzoic acid and its derivatives, homomethyl-7N-acetylaranthranilate, butylmethoxybenzoylmethane, di-paramethoxycinnamic acid-mono-2-ethylhexanoic acid glyceryl, octylcinnamate and other paramethoxycinnamic acid derivatives, amyl salicylate, etc. UV-absorbers such as arbutin, salicylic acid derivatives, benzophenone derivatives such as 2,4-dihydroxybenzophenone, ethyl hexyl dimethoxybenzylidenedioxoimidazoline propionate, liquid lanolin acetate, coganebana root extract, trianilino-p-carboethylhexyloxy-triazine; Ascorbic acid and its derivatives such as kojic acid, magnesium phosphate ascorbate, glutathione, licorice extract, clove extract, tea extract, ascorbic acid Xanthine, bovine placenta extract, tocopherol and derivatives thereof, tranexamic acid and its salts, azulene, whitening components such as γ- hydroxybutyrate;
マルチトール、ソルビトール、グリセリン、プロピレングリコール、1,3−ブチレングリコール、ポリエチレングリコール、グリコール等の多価アルコール、ピロリドンカルボン酸ソーダ、乳酸ソーダ、クエン酸ソーダなど有機酸およびその塩、ヒアルロン酸ソーダなどヒアルロン酸およびその塩、酵母および酵母抽出液の加水分解物、酵母培養液、乳酸菌培養液など醗酵代謝産物、コラーゲン、エラスチン、ケラチン、セリシン等の水溶性蛋白、コラーゲン加水分解物、カゼイン加水分解物、シルク加水分解物、ポリアスパラギン酸ナトリウム等のぺプチド類およびその塩、トレハロース、キシロビオース、マルトース、ラフィノース、メリビオース、蔗糖、ブドウ糖、植物性粘質多糖等の糖類、結晶性セルロース、非結晶性セルロース、キシラン、マンナン、ガラクタン、アラビナン、アラビノキシラン等の多糖類およびその誘導体、水溶性キチン、キトサン、ペクチン、コンドロイチン硫酸およびその塩等のグリコサミノグリカンおよびその塩、グリシン、セリン、スレオニン、アラニン、アスパラギン酸、チロシン、バリン、ロイシン、アルギニン、グルタミン、プロリン酸等のアミノ酸、アミノカルボニル反応物等の糖アミノ酸化合物、アロエ、マロニエ等の植物抽出液、トリメチルグリシン、尿素、尿酸、アンモニア、レシチン、ラノリン、スクワラン、スクワレン、グルコサミン、クレアチニン、DNA、RNA等の核酸関連物質等の保湿剤;カルボキシメチルセルロース、ヒドロキシエチルセルロースヒドロキシプロピルトリメチルアンモニウムクロリドエーテル、エチルセルロース、ヒドロキシプロピルセルロース、メチルヒドロキシプロピルセルロース、デンプン、可溶性デンプン、カルボキシメチルデンプン、メチルデンプン、アルギン酸プロピレングリコールエステル、メチルセルロース、アラビアガム、キサンタンガム、グアーガム、ローカストビンガム、クインスシード、カラギーナン、ガラクタン、ペクチン、マンナン、デキストラン、サクシノグルカン、カードラン、ゼラチン、カゼイン、アルブミン、コラーゲン、メトキシエチレン無水マレイン酸共重合体、両性メタクリル酸エステル共重合体、ポリ塩化ジメチルメチレンピペリジニウム、ポリアクリル酸エステル共重合体、ポリ酢酸ビニル、ポリビニルアルコール、ポリビニルピロリドン、ポリビニルメチルエーテル、カルボキシビニルポリマー、ポリアクリル酸、ニトロセルロース、ポリエチレングリコール脂肪酸エステル、ジステアリン酸ポリエチレングリコール等のポリオキシエチレン脂肪酸エステル、ポリオキシエチレンジオレイン酸メチルグルコシド等のポリオキシエチレン脂肪酸エステルメチルグリコシド等の増粘剤; Maltitol, sorbitol, glycerin, propylene glycol, 1,3-butylene glycol, polyhydric alcohols such as polyethylene glycol, glycol, organic acids such as pyrrolidone carboxylic acid soda, sodium lactate and sodium citrate, and salts thereof, hyaluronic acid such as sodium hyaluronate Acids and salts thereof, yeast and yeast extract hydrolysates, yeast culture fluid, fermentation metabolites such as lactic acid bacteria culture fluid, collagen, elastin, keratin, sericin and other water soluble proteins, collagen hydrolysates, casein hydrolysates, Silk hydrolyzate, peptides such as sodium polyaspartate and salts thereof, trehalose, xylobiose, maltose, raffinose, melibiose, sucrose, glucose, saccharides such as vegetable viscous polysaccharides, crystalline cellulose, amorphous cellulose Polysaccharides such as xylan, mannan, galactan, arabinan, arabinoxylan and their derivatives, glycosaminoglycans and their salts such as water-soluble chitin, chitosan, pectin, chondroitin sulfate and their salts, glycine, serine, threonine, alanine, aspartic acid , Tyrosine, valine, leucine, arginine, glutamine, amino acids such as prophosphoric acid, sugar amino acid compounds such as aminocarbonyl reactants, plant extracts such as aloe, maronier, trimethylglycine, urea, uric acid, ammonia, lecithin, lanolin, squalane , Squalene, glucosamine, creatinine, humectants such as nucleic acid-related substances such as DNA, RNA; carboxymethylcellulose, hydroxyethylcellulose hydroxypropyltrimethylammonium chloride , Ethyl cellulose, hydroxypropyl cellulose, methyl hydroxypropyl cellulose, starch, soluble starch, carboxymethyl starch, methyl starch, propylene glycol alginate, methyl cellulose, gum arabic, xanthan gum, guar gum, locust bin gum, quince seed, carrageenan, galactan, pectin, Mannan, dextran, succinoglucan, curdlan, gelatin, casein, albumin, collagen, methoxyethylene maleic anhydride copolymer, amphoteric methacrylate copolymer, polydimethylmethylenepiperidinium chloride, polyacrylate copolymer Coalescence, polyvinyl acetate, polyvinyl alcohol, polyvinyl pyrrolidone, polyvinyl methyl ether, carboxy Thickeners such as vinyl polymer, polyacrylic acid, nitrocellulose, polyethylene glycol fatty acid ester, polyoxyethylene fatty acid ester such as polyethylene glycol distearate, polyoxyethylene fatty acid ester methyl glycoside such as polyoxyethylene dioleic acid methyl glucoside;
エチレンジアミン四酢酸およびその塩類、ヒドロキシエチレンジアミン3酢酸およびその塩類、リン酸、アスコルビン酸、コハク酸、グルコン酸、ポリリン酸塩類、メタリン酸塩類などの金属イオン封鎖剤;エタノール、プロピレングリコール、1,3ーブチレグリコール等の有機溶剤、ブチルヒドロキシトルエン、トコフェロール、フィチン酸等の酸化防止剤;安息香酸およびその塩、サリチル酸およびその塩、ソルビン酸およびその塩、パラオキシ安息香酸アルキルエステル(エチルパラベン、ブチルパラベン等)およびその塩、デヒドロ酢酸およびその塩類、パラクロルメタクレゾール、ヘキサクロロフェン、ホウ酸、レゾルシン、トリブロムサラン、オルトフェニルフェノール、グルコン酸クロルヘキシジン、チラム、感光素201号、フェノキシエタノール、塩化ベンゼトニウム、ハロカルバン、塩化クロルヘキシジン、トリクロロカルバニド、酢酸トコフェロール、ジンクピリチオン、ヒノキチオール、フェノール、イソプロピルメチルフェノール、2,4,4−トリクロロ−2−ヒドロキシフェノール、ヘキサクロロフェン等の抗菌・防腐剤; Metal ion sequestering agents such as ethylenediaminetetraacetic acid and its salts, hydroxyethylenediaminetriacetic acid and its salts, phosphoric acid, ascorbic acid, succinic acid, gluconic acid, polyphosphates, metaphosphates; ethanol, propylene glycol, 1,3- Organic solvents such as butylene glycol, antioxidants such as butylhydroxytoluene, tocopherol and phytic acid; benzoic acid and salts thereof, salicylic acid and salts thereof, sorbic acid and salts thereof, paraoxybenzoic acid alkyl esters (ethylparaben, butylparaben) Etc.) and salts thereof, dehydroacetic acid and salts thereof, parachlormetacresol, hexachlorophene, boric acid, resorcin, tribromosaran, orthophenylphenol, chlorhexidine gluconate, thiram, photosensitizer 201 , Phenoxyethanol, benzethonium chloride, halocarban, chlorhexidine chloride, trichlorocarbanide, tocopherol acetate, zinc pyrithione, hinokitiol, phenol, isopropylmethylphenol, 2,4,4-trichloro-2-hydroxyphenol, hexachlorophene, etc. ;
クエン酸、リンゴ酸、酒石酸、乳酸、アジピン酸、グルタミン酸、アスパラギン酸、マレイン酸等の有機酸;ビタミンA及びその誘導体;ビタミンB6塩酸塩、ビタミンB6トリパルミテート、ビタミンB6ジオクタノエート、ビタミンB2及びその誘導体等のビタミンB類;アスコルビン酸、アスコルビン酸硫酸エステル、アスコルビン酸リン酸エステル等のビタミンC類、αトコフェロール、βトコフェロール、γトコフェロール等のビタミンE類、ビタミンD類、ビタミンH、パントテン酸等のビタミン類; Organic acids such as citric acid, malic acid, tartaric acid, lactic acid, adipic acid, glutamic acid, aspartic acid, maleic acid; vitamin A and its derivatives; vitamin B6 hydrochloride, vitamin B6 tripalmitate, vitamin B6 dioctanoate, vitamin B2 and the like Vitamin B such as derivatives; vitamin C such as ascorbic acid, ascorbic acid sulfate, ascorbic acid phosphate, vitamin E such as α-tocopherol, β-tocopherol, γ-tocopherol, vitamin D, vitamin H, pantothenic acid, etc. Vitamins;
ニコチン酸アミド、ニコチン酸ベンジル、γ−オリザノール、アラントイン、グリチルリチン酸(塩)グリチルレチン酸およびその誘導体、ヒノキチオール、ムシジン、ビサボロール、ユーカリプトール、チモールイノシトール、サポニン類(キラヤサポニン、アズキサポニン、ヘチマサポニン等)トラネキサム酸、パントテルエチルエーテル、エチニルエストラジオール、セファランジン、プラセンタエキス、センブリエキス、セファランチン、ビタミンEおよびその誘導体、ガンマーオリザノールなどの血行促進剤;トウガラシチンキ、ショオウキョウチンキ、カンタリスチンキ、ニコチン酸ベンジルエステルなどの局所刺激剤、各種ビタミンやアミノ酸などの栄養剤、グリチルレチン酸、グリチルリチン酸誘導体、アラントイン、アズレン、アミノカプロン酸、ヒドロコルチゾンなどの抗炎症剤;酸化亜鉛、硫酸亜鉛、アラントインヒドロキシアルミニウム、塩化アルミニウム、スルホ石炭酸亜鉛、タンニン酸などの収斂剤;メントール、カンフルなどの清涼剤;抗ヒスタミン剤;トコフェロール類、BHA、BHT、没食子酸、NDGAなどの酸化防止剤等の各種薬剤; Nicotinamide, benzyl nicotinate, γ-oryzanol, allantoin, glycyrrhizic acid (salt) glycyrrhetinic acid and its derivatives, hinokitiol, mucidin, bisabolol, eucalyptol, thymolinositol, saponins (Quillajasaponin, azoxaponin, hetimasaponin ) Blood circulation promoters such as tranexamic acid, pantothel ethyl ether, ethinyl estradiol, cephalandin, placenta extract, assembly extract, cephalanthin, vitamin E and its derivatives, gamma oryzanol; red pepper tincture, red ginger tincture, cantharis tincture, benzyl nicotinate Local stimulants such as esters, nutrients such as various vitamins and amino acids, glycyrrhetinic acid, glycyrrhizic acid derivatives, allantoin, as Anti-inflammatory agents such as zinc, aminocaproic acid and hydrocortisone; astringents such as zinc oxide, zinc sulfate, allantoin hydroxyaluminum, aluminum chloride, zinc sulfococolate and tannic acid; refreshing agents such as menthol and camphor; antihistamines; tocopherols and BHA , Various agents such as antioxidants such as BHT, gallic acid and NDGA;
サッカロマイセスなどの酵母、糸状菌、バクテリア、牛胎盤、人胎盤、人臍帯、酵母、牛コラーゲン、牛乳由来蛋白、小麦、大豆、牛血液、ブタ血液、鶏冠、カミツレ、キュウリ、コメ、シアバター、シラカバ、茶、トマト、ニンニク、ハマメリス、バラ、ヘチマ、ホップ、モモ、アンズ、レモン、キウイ、ドクダミ、トウガラシ、クララ、ギシギシ、コウホネ、セージ、ノコギリ草、ゼニアオイ、センキュウ、センブリ、タイム、トウキ、トウヒ、バーチ、スギナ、ヘチマ、マロニエ、ユキノシタ、アルニカ、ユリ、ヨモギ、シャクヤク、アロエ、アロエベラ、オウゴン、オウバク、コウカ、ベニバナ、サンシン、シコン、タイソウ、チンピ、ニンジン、ヨクイニン、ハトムギ、クチナシ、サワラ等の動植物・微生物およびその一部から有機溶媒、アルコール、多価アルコール、水、水性アルコール等で抽出または加水分解して得た天然エキス;色素;香料;精製水等を配合することができる。 Saccharomyces yeasts, filamentous fungi, bacteria, bovine placenta, human placenta, human umbilical cord, yeast, bovine collagen, milk-derived protein, wheat, soybean, cow blood, pig blood, chicken crown, chamomile, cucumber, rice, shea butter, birch , Tea, tomato, garlic, hamamelis, rose, loofah, hop, peach, apricot, lemon, kiwi, dokudami, capsicum, clara, scallop, kohone, sage, sawtooth grass, mallow, senkyu, assembly, thyme, spruce, spruce, Birch, Horsetail, Loofah, Maronie, Yukinosita, Arnica, Lily, Mugwort, Peonies, Aloe, Aloe Vera, Ogon, Owaku, Mukai, Safflower, Sanshin, Shikon, Tycho, Chimpi, Carrot, Yokuinin, Barley, Gardenia, Sawara, etc.・ Present from microorganisms and parts thereof It can be blended purified water and the like; solvent, alcohols, polyhydric alcohols, water, natural extracts obtained by extraction or hydrolysis in aqueous alcohol; dyes; perfume.
この内粉末成分との併用は、物理的な摩擦効果によって洗浄力を高めると共に、粒子表面に汚れを吸着することで有効である。
また、油性成分との併用は油性成分の溶剤効果により油性の汚れを可溶化する効果があるために洗浄力の向上に適している。油性成分の中でも、シリコーン類との併用は使用後にさっぱりした感触を与える為に特に有効である。
さらに、保湿剤を併用することは過剰な脱脂による皮膚の荒れを防止することが出来、使用感の向上に寄与する。
The combined use with the inner powder component is effective by increasing the cleaning power by the physical friction effect and adsorbing dirt on the particle surface.
Further, the combined use with the oil component is suitable for improving the detergency because it has the effect of solubilizing the oily dirt due to the solvent effect of the oil component. Among oil components, the combined use with silicones is particularly effective for giving a refreshing feel after use.
Furthermore, using a moisturizing agent together can prevent rough skin due to excessive degreasing, and contributes to an improved feeling of use.
金属イオン封鎖剤、酸化防止剤、防腐剤との併用は長期間または過酷な使用条件下における製品の変化を防止し、良好な使用感を提供しつづける上で有効である。 The combined use with a sequestering agent, an antioxidant and a preservative is effective in preventing a change in the product under a long-term or severe use condition and providing a good feeling of use.
次に、本発明を実施例により更に詳細に説明するが、本発明はこれによって何ら限定されるものではない。
[実施例1]
下記組成により手指清浄用化粧料を得た。
ポリオキシエチレン(5)ポリオキシプロピレン(5)ラウリルエーテル 15質量部
ミリスチルジメチルアミンオキシド 3質量部
プロピレングリコール 5質量部
ラノリン 0.5質量部
香料 0.2質量部
カルボキシビニルポリマー 0.2質量部
トリエタノールアミン 0.1質量部
水 66質量部
を混合し、攪拌溶解した物に
ポリエチレン粉末 10質量部
を混合し、攪拌分散して洗浄剤組成物を得た。
EXAMPLES Next, although an Example demonstrates this invention still in detail, this invention is not limited at all by this.
[Example 1]
A hand cleaning cosmetic was obtained with the following composition.
Polyoxyethylene (5) Polyoxypropylene (5) Lauryl ether 15 parts by weight Myristyldimethylamine oxide 3 parts by weight Propylene glycol 5 parts by weight Lanolin 0.5 parts by weight Fragrance 0.2 parts by weight Carboxyvinyl polymer 0.2 parts by weight Tri Ethanolamine 0.1 parts by weight Water 66 parts by weight were mixed and dissolved by stirring. Then, 10 parts by weight of polyethylene powder was mixed and stirred and dispersed to obtain a cleaning composition.
[実施例2]
下記組成により手指清浄用化粧料を得た。
プロピレングリコールオレイン酸エステル 15質量部
ポリオキシエチレン(40)ソルビタンヤシ油脂肪酸エステル 3質量部
プロピレングリコール 5質量部
ラノリン 0.5質量部
香料 0.2質量部
カルボキシビニルポリマー 0.2質量部
トリエタノールアミン 0.1質量部
水 66質量部
を混合し、攪拌溶解した物に
ポリエチレン粉末 10質量部
を混合し、攪拌分散して洗浄剤組成物を得た。
[Example 2]
A hand cleaning cosmetic was obtained with the following composition.
Propylene glycol oleate 15 parts by weight Polyoxyethylene (40) sorbitan coconut fatty acid ester 3 parts by weight Propylene glycol 5 parts by weight Lanolin 0.5 parts by weight Fragrance 0.2 parts by weight Carboxyvinyl polymer 0.2 parts by weight Triethanolamine 0.1 parts by mass of water 66 parts by mass was mixed, and 10 parts by mass of polyethylene powder was mixed into the product obtained by stirring and dissolving, followed by stirring and dispersing to obtain a cleaning composition.
[実施例3]
下記組成により手指清浄用化粧料を得た。
デカグリセリンジステアリン酸エステル 15質量部
ポリエチレングリコール(10)ラウリン酸エステル 3質量部
プロピレングリコール 5質量部
ラノリン 0.5質量部
香料 0.2質量部
カルボキシビニルポリマー 0.2質量部
トリエタノールアミン 0.1質量部
水 66質量部
を混合し、攪拌溶解した物に
ポリエチレン粉末 10質量部
を混合し、攪拌分散して洗浄剤組成物を得た。
[Example 3]
A hand cleaning cosmetic was obtained with the following composition.
Decaglycerin distearate 15 parts by weight Polyethylene glycol (10) Laurate 3 parts by weight Propylene glycol 5 parts by weight Lanolin 0.5 parts by weight Fragrance 0.2 parts by weight Carboxyvinyl polymer 0.2 parts by weight Triethanolamine 0.1 Mixing part by weight 66 parts by weight of water, 10 parts by weight of polyethylene powder was mixed with the product dissolved by stirring, and dispersed by stirring to obtain a cleaning composition.
[実施例4]
下記組成により手指清浄用化粧料を得た。
ポリオキシエチレン(6)ソルビットラウリン油脂肪酸エステル 15質量部
ポリオキシエチレン(10)ラノリン 3質量部
プロピレングリコール 5質量部
ラノリン 0.5質量部
香料 0.2質量部
カルボキシビニルポリマー 0.2質量部
トリエタノールアミン 0.1質量部
水 66質量部
を混合し、攪拌溶解した物に
ポリエチレン粉末 10質量部
を混合し、攪拌分散して洗浄剤組成物を得た。
[Example 4]
A hand cleaning cosmetic was obtained with the following composition.
Polyoxyethylene (6) Sorbit Laurin oil fatty acid ester 15 parts by mass Polyoxyethylene (10) Lanolin 3 parts by mass Propylene glycol 5 parts by mass Lanolin 0.5 parts by mass Fragrance 0.2 parts by mass Carboxyvinyl polymer 0.2 parts by mass Tri Ethanolamine 0.1 parts by weight Water 66 parts by weight were mixed and dissolved by stirring. Then, 10 parts by weight of polyethylene powder was mixed and stirred and dispersed to obtain a cleaning composition.
[実施例5]
下記組成により手指清浄用化粧料を得た。
ポリオキシエチレン(60)ヒマシ油 15質量部
グリセリンモノステアリン酸エステル 3質量部
プロピレングリコール 5質量部
ラノリン 0.5質量部
香料 0.2質量部
カルボキシビニルポリマー 0.2質量部
トリエタノールアミン 0.1質量部
水 66質量部
を混合し、攪拌溶解した物に
ポリエチレン粉末 10質量部
を混合し、攪拌分散して洗浄剤組成物を得た。
[Example 5]
A hand cleaning cosmetic was obtained with the following composition.
Polyoxyethylene (60) castor oil 15 parts by weight Glycerin monostearate 3 parts by weight Propylene glycol 5 parts by weight Lanolin 0.5 parts by weight Fragrance 0.2 parts by weight Carboxyvinyl polymer 0.2 parts by weight Triethanolamine 0.1 Part by mass 66 parts by mass of water was mixed, and 10 parts by mass of polyethylene powder was mixed with the product dissolved by stirring, and dispersed by stirring to obtain a cleaning composition.
[実施例6]
下記組成により手指清浄用化粧料を得た。
ポリオキシエチレン(15)グリセリンステアリン酸エステル 15質量部
ソルビタンヤシ油脂肪酸エステル 3質量部
プロピレングリコール 5質量部
ラノリン 0.5質量部
香料 0.2質量部
カルボキシビニルポリマー 0.2質量部
トリエタノールアミン 0.1質量部
水 66質量部
を混合し、攪拌溶解した物に
ポリエチレン粉末 10質量部
を混合し、攪拌分散して洗浄剤組成物を得た。
[Example 6]
A hand cleaning cosmetic was obtained with the following composition.
Polyoxyethylene (15) glycerin stearate 15 parts by weight Sorbitan coconut oil fatty acid ester 3 parts by weight Propylene glycol 5 parts by weight Lanolin 0.5 parts by weight Fragrance 0.2 parts by weight Carboxyvinyl polymer 0.2 parts by weight Triethanolamine 0 0.1 parts by weight of water and 66 parts by weight of water were mixed, and 10 parts by weight of polyethylene powder was mixed into the product obtained by stirring and dissolving, followed by stirring and dispersing to obtain a cleaning composition.
[実施例7]
下記組成により手指清浄用化粧料を得た。
N−ヤシ油脂肪酸アシルグルタミン酸ナトリウム液 50質量部
ポリオキシエチレン(1)ラウリルエーテルリン酸エステルナトリウム液 25質量部
香料 0.1質量部
ポリビニルアルコール 1質量部
水 9.4質量部
を混合、攪拌溶解し、さらに
ナイロンパウダー 14.5質量部
を混合、攪拌分散して洗浄剤組成物を得た。
[Example 7]
A hand cleaning cosmetic was obtained with the following composition.
N-coconut oil fatty acid sodium acyl glutamate solution 50 parts by weight Polyoxyethylene (1) sodium lauryl ether phosphate solution 25 parts by weight Fragrance 0.1 part by weight Polyvinyl alcohol 1 part by weight Water 9.4 parts by weight are mixed and dissolved. Further, 14.5 parts by mass of nylon powder was mixed, stirred and dispersed to obtain a detergent composition.
[実施例8]
下記組成により手指清浄用化粧料を得た。
ポリオキシエチレン(10)ラウリルエーテルカルボン酸ナトリウム液 50質量部
ポリオキシエチレン(10)ラウリルエーテル硫酸エステルナトリウム液 25質量部
香料 0.1質量部
ポリビニルアルコール 1質量部
水 9.4質量部
を混合、攪拌溶解し、さらに
ナイロンパウダー 14.5質量部
を混合、攪拌分散して洗浄剤組成物を得た。
[Example 8]
A hand cleaning cosmetic was obtained with the following composition.
Polyoxyethylene (10) sodium lauryl ether carboxylate solution 50 parts by weight Polyoxyethylene (10) sodium lauryl ether sulfate ester liquid 25 parts by weight Fragrance 0.1 part by weight Polyvinyl alcohol 1 part by weight Water 9.4 parts by weight, The mixture was stirred and dissolved, and further 14.5 parts by mass of nylon powder was mixed, stirred and dispersed to obtain a detergent composition.
[実施例9]
下記組成により手指清浄用化粧料を得た。
ポリオキシエチレン(10)ラウリルエーテルスルホン酸カリウム液 50質量部
ポリオキシエチレンスルホコハク酸ラウリルエーテルカリウム液 25質量部
香料 0.1質量部
ポリビニルアルコール 1質量部
水 9.4質量部
を混合、攪拌溶解し、さらに
ナイロンパウダー 14.5質量部
を混合、攪拌分散して洗浄剤組成物を得た。
[Example 9]
A hand cleaning cosmetic was obtained with the following composition.
Polyoxyethylene (10) potassium lauryl ether sulfonate solution 50 parts by mass Polyoxyethylene sulfosuccinate lauryl ether potassium solution 25 parts by mass Fragrance 0.1 parts by mass Polyvinyl alcohol 1 part by mass Water 9.4 parts by mass Further, 14.5 parts by mass of nylon powder was mixed and dispersed by stirring to obtain a cleaning composition.
[実施例10]
下記組成により手指清浄用化粧料を得た。
ポリオキシエチレンラウリルエーテル硫酸トリエタノールアミン液 50質量部ラウリルフェノールエーテルリン酸エステルトリエタノールアミン液 25質量部
香料 0.1質量部
ポリビニルアルコール 1質量部
水 9.4質量部
を混合、攪拌溶解し、さらに
ナイロンパウダー 14.5質量部
を混合、攪拌分散して洗浄剤組成物を得た。
[Example 10]
A hand cleaning cosmetic was obtained with the following composition.
Polyoxyethylene lauryl ether sulfate triethanolamine solution 50 parts by mass Laurylphenol ether phosphate triethanolamine solution 25 parts by mass Perfume 0.1 parts by mass Polyvinyl alcohol 1 part by mass Water 9.4 parts by mass Further, 14.5 parts by mass of nylon powder was mixed, stirred and dispersed to obtain a detergent composition.
[実施例11]
下記組成により手指清浄用化粧料を得た。
ポリオキシエチレンポリオキシプロピレンラウリルエーテル(HLB15) 5.0質量部
ポリオキシエチレンポリオキシプロピレンラウリルエーテル(HLB11) 7.0質量部
ヤシ油脂肪酸ジエタノールアミド(1:2) 2.0質量部
ポリオキシエチレンラノリン 0.5質量部
高融点ポリエチレン末(懸濁重合) 8.0質量部
カルボキシビニルポリマー 0.3質量部
プロピレングリコール 2.0質量部
グリセリン 1.0質量部
塩化ベンザルコニウム 0.1質量部
パラオキシ安息香酸メチル 0.01質量部
エデト酸2ナトリウム 0.05質量部
香料 0.05質量部
水道水 73.99質量部
を混合し、攪拌分散して使用感の優れた洗浄剤組成物を得た
[Example 11]
A hand cleaning cosmetic was obtained with the following composition.
Polyoxyethylene polyoxypropylene lauryl ether (HLB15) 5.0 parts by mass Polyoxyethylene polyoxypropylene lauryl ether (HLB11) 7.0 parts by mass Palm oil fatty acid diethanolamide (1: 2) 2.0 parts by mass Polyoxyethylene Lanolin 0.5 parts by mass High-melting polyethylene powder (suspension polymerization) 8.0 parts by mass Carboxyvinyl polymer 0.3 parts by mass Propylene glycol 2.0 parts by mass Glycerin 1.0 parts by mass Benzalkonium chloride 0.1 parts by mass Methyl paraoxybenzoate 0.01 parts by weight Disodium edetate 0.05 parts by weight Fragrance 0.05 parts by weight Tap water 73.99 parts by weight is mixed and stirred to obtain a detergent composition with excellent usability. The
[実施例12]
下記組成により手指清浄用化粧料を得た。
ポリオキシエチレンポリオキシプロピレンラウリルエーテル(HLB15) 4.0質量部
ポリオキシエチレンポリオキシプロピレンラウリルエーテル(HLB11) 6.0質量部
ヤシ油脂肪酸ジエタノールアミド(1:2) 2.0質量部
低融点ポリエチレン末(粉砕) 8.0質量部
カルボキシビニルポリマー 0.4質量部
ポリオキシエチレンラノリン 0.5質量部
グリセリン 1.0質量部
プロピレングリコール 2.0質量部
塩化ベンザルコニウム 0.1質量部
パラオキシ安息香酸メチル 0.01質量部
植物エキス 0.05質量部
エデト酸2ナトリウム 0.05質量部
色素 0.002質量部
香料 0.05質量部
水 75.838質量部
を混合し、攪拌分散して使用感の優れた洗浄剤組成物を得た
[Example 12]
A hand cleaning cosmetic was obtained with the following composition.
Polyoxyethylene polyoxypropylene lauryl ether (HLB15) 4.0 parts by mass Polyoxyethylene polyoxypropylene lauryl ether (HLB11) 6.0 parts by mass Palm oil fatty acid diethanolamide (1: 2) 2.0 parts by mass Low melting point polyethylene Powder (ground) 8.0 parts by weight Carboxyvinyl polymer 0.4 parts by weight Polyoxyethylene lanolin 0.5 parts by weight Glycerin 1.0 parts by weight Propylene glycol 2.0 parts by weight Benzalkonium chloride 0.1 parts by weight Paraoxybenzoic acid Methyl acid 0.01 parts by weight Plant extract 0.05 parts by weight Disodium edetate 0.05 parts by weight Dye 0.002 parts by weight Fragrance 0.05 parts by weight Water 75.838 parts by weight, mixed and stirred for use A detergent composition with an excellent feel was obtained.
[実施例13]
下記組成により手指清浄用化粧料を得た。
ポリオキシエチレンポリオキシプロピレンラウリルエーテル(HLB15) 4.0質量部
ポリオキシエチレンポリオキシプロピレンラウリルエーテル(HLB11) 6.0質量部
ヤシ油脂肪酸ジエタノールアミド(1:2) 2.0質量部
ポリブチレンサクシネートアジペート(粉砕) 5.0質量部
カルボキシビニルポリマー 0.4質量部
ポリオキシエチレンラノリン 0.5質量部
グリセリン 1.0質量部
プロピレングリコール 2.0質量部
塩化ベンザルコニウム 0.1質量部
パラオキシ安息香酸メチル 0.01質量部
植物エキス 0.05質量部
エデト酸2ナトリウム 0.05質量部
色素 0.002質量部
香料 0.05質量部
水 75.838質量部
を混合し、攪拌分散して使用感の優れた洗浄剤組成物を得た
[Example 13]
A hand cleaning cosmetic was obtained with the following composition.
Polyoxyethylene polyoxypropylene lauryl ether (HLB15) 4.0 parts by mass Polyoxyethylene polyoxypropylene lauryl ether (HLB11) 6.0 parts by mass Coconut oil fatty acid diethanolamide (1: 2) 2.0 parts by mass Polybutylene sushi Nate adipate (ground) 5.0 parts by weight Carboxyvinyl polymer 0.4 parts by weight Polyoxyethylene lanolin 0.5 parts by weight Glycerin 1.0 parts by weight Propylene glycol 2.0 parts by weight Benzalkonium chloride 0.1 parts by weight Paraoxy Methyl benzoate 0.01 parts by weight Plant extract 0.05 parts by weight Disodium edetate 0.05 parts by weight Dye 0.002 parts by weight Fragrance 0.05 parts by weight Water 75.838 parts by weight A detergent composition with excellent usability was obtained.
[比較例1]
下記組成により手指清浄用化粧料を得た。
ポリオキシエチレン(9)ラウリルエーテル 15質量部
ヤシ油脂肪酸ジエタノールアミド 3質量部
プロピレングリコール 5質量部
ラノリン 0.5質量部
香料 0.2質量部
カルボキシビニルポリマー 0.2質量部
水 66.1質量部
を混合し、攪拌溶解した物に
ポリエチレン粉末 10質量部
を混合し、攪拌分散して洗浄剤組成物を得た。
[Comparative Example 1]
A hand cleaning cosmetic was obtained with the following composition.
Polyoxyethylene (9) lauryl ether 15 parts by weight Palm oil fatty acid diethanolamide 3 parts by weight Propylene glycol 5 parts by weight Lanolin 0.5 parts by weight Fragrance 0.2 parts by weight Carboxyvinyl polymer 0.2 parts by weight Water 66.1 parts by weight Were mixed with stirring and dissolved, and 10 parts by weight of polyethylene powder was mixed and stirred and dispersed to obtain a cleaning composition.
[比較例2]
下記組成により手指清浄用化粧料を得た。
ポリオキシエチレン(20)硬化ヒマシ油 15質量部
ラウリルジメチルアミンオキシド 3質量部
プロピレングリコール 5質量部
ラノリン 0.5質量部
香料 0.2質量部
カルボキシビニルポリマー 0.2質量部
トリエタノールアミン 0.1質量部
水 66質量部
を混合し、攪拌溶解した物に
ポリエチレン粉末 10質量部
を混合し、攪拌分散して洗浄剤組成物を得た。
[Comparative Example 2]
A hand cleaning cosmetic was obtained with the following composition.
Polyoxyethylene (20) hydrogenated castor oil 15 parts by weight Lauryldimethylamine oxide 3 parts by weight Propylene glycol 5 parts by weight Lanolin 0.5 parts by weight Fragrance 0.2 parts by weight Carboxyvinyl polymer 0.2 parts by weight Triethanolamine 0.1 Part by mass 66 parts by mass of water was mixed, and 10 parts by mass of polyethylene powder was mixed with the product dissolved by stirring, and dispersed by stirring to obtain a cleaning composition.
[比較例3]
下記組成により手指清浄用化粧料を得た。
ポリオキシエチレン(7.5)ノニルフェニルエーテル 15質量部
ポリオキシエチレン(6)ソルビタンモノステアレート 3質量部
プロピレングリコール 5質量部
ラノリン 0.5質量部
香料 0.2質量部
カルボキシビニルポリマー 0.2質量部
トリエタノールアミン 0.1質量部
水 66質量部
を混合し、攪拌溶解した物に
ポリエチレン粉末 10質量部
を混合し、攪拌分散して洗浄剤組成物を得た。
[Comparative Example 3]
A hand cleaning cosmetic was obtained with the following composition.
Polyoxyethylene (7.5) nonylphenyl ether 15 parts by mass Polyoxyethylene (6) sorbitan monostearate 3 parts by mass Propylene glycol 5 parts by mass Lanolin 0.5 parts by mass Fragrance 0.2 parts by mass Carboxyvinyl polymer 0.2 Part by weight Triethanolamine 0.1 part by weight Water 66 parts by weight was mixed and dissolved by stirring. Then, 10 parts by weight of polyethylene powder was mixed and dispersed by stirring to obtain a detergent composition.
[比較例4]
下記組成により手指清浄用化粧料を得た。
ポリオキシエチレン(6)ソルビトールテトラオレエート 15質量部
ラウリルジメチルアミノ酢酸ベタイン 3質量部
プロピレングリコール 5質量部
ラノリン 0.5質量部
香料 0.2質量部
カルボキシビニルポリマー 0.2質量部
トリエタノールアミン 0.1質量部
水 66質量部
を混合し、攪拌溶解した物に
ポリエチレン粉末 10質量部
を混合し、攪拌分散して洗浄剤組成物を得た。
[Comparative Example 4]
A hand cleaning cosmetic was obtained with the following composition.
Polyoxyethylene (6) sorbitol tetraoleate 15 parts by weight Lauryldimethylaminoacetic acid betaine 3 parts by weight Propylene glycol 5 parts by weight Lanolin 0.5 parts by weight Fragrance 0.2 parts by weight Carboxyvinyl polymer 0.2 parts by weight Triethanolamine 0 .1 part by mass of water 66 parts by mass of water, and 10 parts by mass of polyethylene powder were mixed into the product obtained by stirring and dissolving, followed by stirring and dispersing to obtain a cleaning composition.
[比較例5]
下記組成により手指清浄用化粧料を得た。
ポリオキシエチレン(7)ラウリルエーテル 15質量部
ミリスチン酸モノエタノールアミド 3質量部
プロピレングリコール 5質量部
ラノリン 0.5質量部
香料 0.2質量部
カルボキシビニルポリマー 0.2質量部
トリエタノールアミン 0.1質量部
水 66質量部
を混合し、攪拌溶解した物に
ポリエチレン粉末 10質量部
を混合し、攪拌分散して洗浄剤組成物を得た。
[Comparative Example 5]
A hand cleaning cosmetic was obtained with the following composition.
Polyoxyethylene (7) lauryl ether 15 parts by weight Myristic acid monoethanolamide 3 parts by weight Propylene glycol 5 parts by weight Lanolin 0.5 parts by weight Fragrance 0.2 parts by weight Carboxyvinyl polymer 0.2 parts by weight Triethanolamine 0.1 Part by mass 66 parts by mass of water was mixed, and 10 parts by mass of polyethylene powder was mixed with the product dissolved by stirring, and dispersed by stirring to obtain a cleaning composition.
[比較例6]
下記組成により手指清浄用化粧料を得た。
ポリオキシエチレン(4.2)ラウリルエーテル 15質量部
塩化ベンザルコニウム液 3質量部
プロピレングリコール 5質量部
ラノリン 0.5質量部
香料 0.2質量部
カルボキシビニルポリマー 0.2質量部
トリエタノールアミン 0.1質量部
水 66質量部
を混合し、攪拌溶解した物に
ポリエチレン粉末 10質量部
を混合し、攪拌分散して洗浄剤組成物を得た。
[Comparative Example 6]
A hand cleaning cosmetic was obtained with the following composition.
Polyoxyethylene (4.2) lauryl ether 15 parts by mass Benzalkonium chloride solution 3 parts by mass Propylene glycol 5 parts by mass Lanolin 0.5 parts by mass Fragrance 0.2 parts by mass Carboxyvinyl polymer 0.2 parts by mass Triethanolamine 0 .1 part by mass of water 66 parts by mass of water, and 10 parts by mass of polyethylene powder were mixed into the product obtained by stirring and dissolving, followed by stirring and dispersing to obtain a cleaning composition.
[比較例7]
下記組成により手指清浄用化粧料を得た。
ポリオキシエチレン(5)ラウリルフェニルスルホン酸ナトリウム液 50質量部
ミリスチン酸カリウム液 25質量部
香料 0.1質量部
ポリビニルアルコール 1質量部
水 9.4質量部
を混合、攪拌溶解し、さらに
ナイロンパウダー 14.5質量部
を混合、攪拌分散して洗浄剤組成物を得た。
[Comparative Example 7]
A hand cleaning cosmetic was obtained with the following composition.
Polyoxyethylene (5) sodium lauryl phenyl sulfonate solution 50 parts by weight Potassium myristate solution 25 parts by weight Fragrance 0.1 part by weight Polyvinyl alcohol 1 part by weight Water 9.4 parts by weight are mixed, stirred and dissolved, and further nylon powder 14 .5 parts by mass was mixed, stirred and dispersed to obtain a detergent composition.
[比較例8]
下記組成により手指清浄用化粧料を得た。
ラウリルスルホン酸ナトリウム液 50質量部
ラウリル硫酸ナトリウム液 25質量部
香料 0.1質量部
ポリビニルアルコール 1質量部
水 9.4質量部
を混合、攪拌溶解し、さらに
ナイロンパウダー 14.5質量部
を混合、攪拌分散して洗浄剤組成物を得た。
[Comparative Example 8]
A hand cleaning cosmetic was obtained with the following composition.
Sodium lauryl sulfonate solution 50 parts by weight Sodium lauryl sulfate solution 25 parts by weight Fragrance 0.1 part by weight Polyvinyl alcohol 1 part by weight Water 9.4 parts by weight are mixed, stirred and dissolved, and further 14.5 parts by weight of nylon powder are mixed. A detergent composition was obtained by stirring and dispersing.
[比較例9]
下記組成により手指清浄用化粧料を得た。
N−ヤシ油脂肪酸アシルグルタミン酸トリエタノールアミン液 50質量部
ポリオキシエチレンヤシ油脂肪酸アミド液 25質量部
香料 0.1重量部
ポリビニルアルコール 1質量部
水 9.4質量部
を混合、攪拌溶解し、さらに
ナイロンパウダー 14.5質量部
を混合、攪拌分散して洗浄剤組成物を得た
[Comparative Example 9]
A hand cleaning cosmetic was obtained with the following composition.
N-coconut oil fatty acid acyl glutamic acid triethanolamine solution 50 parts by weight Polyoxyethylene coconut oil fatty acid amide solution 25 parts by weight Fragrance 0.1 part by weight Polyvinyl alcohol 1 part by weight Water 9.4 parts by weight are mixed, stirred and dissolved. 14.5 parts by mass of nylon powder was mixed and dispersed by stirring to obtain a detergent composition.
[比較例10]
下記組成により手指清浄用化粧料を得た。
N−ヤシ油脂肪酸アシル加水分解タンパクナトリウム液 50質量部
N−ヤシ油脂肪酸アシルサルコシンナトリウム液 25質量部
香料 0.1質量部
ポリビニルアルコール 1質量部
水 9.4質量部
を混合、攪拌溶解し、さらに
ナイロンパウダー 14.5質量部
を混合、攪拌分散して洗浄剤組成物を得た。
<評価>
実施例1乃至12および比較例1乃至10について20名の男女のパネラーにより官能評価を行い、「使用後にべたつきを感じる」と評価した人数を数えた。
その結果を表1に示す。
[Comparative Example 10]
A hand cleaning cosmetic was obtained with the following composition.
N-coconut oil fatty acid acyl hydrolyzed protein sodium solution 50 parts by weight N-coconut oil fatty acid acyl sarcosine sodium solution 25 parts by weight Fragrance 0.1 part by weight Polyvinyl alcohol 1 part by weight Water 9.4 parts by weight are mixed, stirred and dissolved, Further, 14.5 parts by mass of nylon powder was mixed, stirred and dispersed to obtain a detergent composition.
<Evaluation>
For Examples 1 to 12 and Comparative Examples 1 to 10, sensory evaluation was performed by 20 male and female panelists, and the number of people who evaluated that they felt sticky after use was counted.
The results are shown in Table 1.
実施例1乃至12および比較例1乃至10について20名の男女のパネラーにより官能評価を行い、「使用後に爽快感が不足する」と評価した人数を数えた。その結果を表2に示す。 For Examples 1 to 12 and Comparative Examples 1 to 10, a sensory evaluation was performed by 20 male and female panelists, and the number of people who evaluated that “the refreshing feeling was insufficient after use” was counted. The results are shown in Table 2.
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JP2012233128A (en) * | 2011-05-09 | 2012-11-29 | Asahi Kasei Chemicals Corp | Cosmetic for body washing |
EP2575771A1 (en) | 2010-05-24 | 2013-04-10 | Micro Powders Inc. | Composition comprising biodegradable polymers for use in a cosmetic composition |
JP2013136732A (en) * | 2011-11-28 | 2013-07-11 | Asahi Kasei Chemicals Corp | Detergent and method of producing the same |
JP2014520198A (en) * | 2011-06-20 | 2014-08-21 | ザ プロクター アンド ギャンブル カンパニー | Liquid cleaning and / or cleansing composition |
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JP5793276B2 (en) * | 2011-09-08 | 2015-10-14 | 株式会社 エヌテクス | Decontamination soap for hand washing |
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EP2575771A1 (en) | 2010-05-24 | 2013-04-10 | Micro Powders Inc. | Composition comprising biodegradable polymers for use in a cosmetic composition |
JP2012233128A (en) * | 2011-05-09 | 2012-11-29 | Asahi Kasei Chemicals Corp | Cosmetic for body washing |
JP2014520198A (en) * | 2011-06-20 | 2014-08-21 | ザ プロクター アンド ギャンブル カンパニー | Liquid cleaning and / or cleansing composition |
JP2013136732A (en) * | 2011-11-28 | 2013-07-11 | Asahi Kasei Chemicals Corp | Detergent and method of producing the same |
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