JP2006001126A - Scribble preventing plate - Google Patents

Scribble preventing plate Download PDF

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JP2006001126A
JP2006001126A JP2004179644A JP2004179644A JP2006001126A JP 2006001126 A JP2006001126 A JP 2006001126A JP 2004179644 A JP2004179644 A JP 2004179644A JP 2004179644 A JP2004179644 A JP 2004179644A JP 2006001126 A JP2006001126 A JP 2006001126A
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graffiti
scribbles
paint
scribble
layer
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Hirotsugu Kamashika
博次 鎌鹿
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Kurimoto Kasei Kogyo KK
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Kurimoto Kasei Kogyo KK
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a scribble preventing plate which is difficult to scribble and can easily erase the scribbles. <P>SOLUTION: In the scribble preventing plate P, a primer is applied on the surface of an FRP plate substrate 1 to smooth the surface, a pattern 4 matching a peripheral scene is UV output-printed on the surface, and a ceramic coating 3 is applied to make the thickness of the coating film 5-10 μm. In the case of scribbles by lacquer spraying, they are left to stand for about 2 h for drying, and an adhesive tape is stuck on its coating film surface and peeled off. Alternatively, the scribbles are eliminated with a lacquer thinner. In the case of scribbles by an oily ink, they are wiped off with tissues if they are fresh. When the scribbles are dried, they are rubbed off with a dry waste cloth. In this way, the scribbles are completely eliminated from the surface 3 of the plate P. Pollutants including car exhaust gas and dust can be eliminated similarly. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

この発明は、落書きがし難く、仮に落書きをしても容易にその落書きを除去できる落書き防止板に関するものである。   The present invention relates to a graffiti prevention plate that is difficult to graffiti and can easily remove the graffiti even if it is graffiti.

橋脚面、駅構内の壁面、公衆トイレ内壁面などには、心ない者が落書きを行い、その落書きは、街の景観を損なうだけでなく、治安の悪化を招く社会問題となっている。   A heartless person performs graffiti on bridge piers, station walls, public toilet walls, etc., and the graffiti is not only detracting from the cityscape but also a social problem that leads to worsening security.

このため、従来から、その落書きを防止したり、その落書きを容易に除去して落書き意欲を喪失させるための手段が考えられ、その一つとして、壁面などに落書き防止用塗料を塗布する手段がある(特許文献1、2参照)。
また、その落書き防止用塗料を表面に塗布した落書き防止板(パネル)も提案されており(特許文献3、4参照)、そのパネルを壁面に設ける手段がある。
For this reason, conventionally, there has been considered a means for preventing the graffiti or removing the graffiti easily by removing the graffiti, and as one of them, there is a means for applying graffiti prevention paint on the wall surface. Yes (see Patent Documents 1 and 2).
In addition, a graffiti prevention plate (panel) in which the graffiti prevention paint is applied to the surface has been proposed (see Patent Documents 3 and 4), and there is means for providing the panel on the wall surface.

特開2003−321545号公報JP 2003-321545 A 特開2004−67783号公報Japanese Patent Application Laid-Open No. 2004-67783 特開平8−197678号公報JP-A-8-197678 特開2001−315253号公報JP 2001-315253 A

通常、落書きは、その落書き用インクが、水性、油性のどちらにしろ、壁面の微細な穴(凹凸)にそのインクが染み込む(入り込む)ことにより、その除去が困難となる。その凹凸は、塗布層が固ければ固いほどなくなるため、従来の落書き防止用には、セラミック塗料などの常温硬化型無機質塗料を採用している。
このとき、常温硬化型無機質塗料、特にセラミック塗料は、その塗膜を薄くすることが困難であり、現場作業では、50μm厚が限界である。また、落書き防止板にあっても、その塗膜厚は、50μm以上である(特許文献3 段落0016第14〜16行参照)。
しかし、落書き防止用塗膜は、その膜厚は薄い方が好ましく、特に、セラミック塗料は、50μm厚程度では、クラックが生じ、そのクラックに落書きインクが染みて、その落書きを確実に消せない(除去できない)。
このように、従来の塗膜面及び落書き防止板では十分な効果を得ていないのが実情である。また、落書き防止板は高価なものであった。
Usually, the graffiti ink becomes difficult to remove because the ink permeates into the fine holes (unevenness) on the wall surface, regardless of whether the ink for graffiti is aqueous or oily. Since the unevenness becomes harder as the coating layer becomes harder, a conventional room temperature curable inorganic paint such as a ceramic paint is used for preventing graffiti.
At this time, it is difficult to thin the coating film of a room temperature curable inorganic paint, particularly a ceramic paint, and the thickness of 50 μm is the limit in field work. Moreover, even if it exists in a graffiti prevention board, the coating-film thickness is 50 micrometers or more (refer patent document 3 Paragraph 0016 14th-16th lines).
However, the graffiti-preventing coating film preferably has a smaller film thickness. In particular, the ceramic paint has a crack of about 50 μm thickness, and cracks are generated. Cannot be removed).
Thus, the actual situation is that the conventional coating surface and the graffiti prevention plate have not obtained sufficient effects. Moreover, the graffiti prevention board was expensive.

この発明は、安価にして落書きを確実に除去し得るようにすることを課題とする。   This invention makes it a subject to make it cheap and to be able to remove a graffiti reliably.

上記課題を達成するために、この発明は、FRP板基材の表面にその表面を平滑化するプライマー層を形成し、そのプライマー層の表面に、工場で塗膜厚12μm以下の常温硬化型無機質塗料層を形成することとしたのである。   In order to achieve the above object, the present invention forms a primer layer for smoothing the surface of the FRP plate base material, and a room temperature curable inorganic material having a coating thickness of 12 μm or less at the factory on the surface of the primer layer. The paint layer was formed.

FRP板は、繊維強化プラスチックから成る板(ボード)であって、樹脂塗料との親和性が高いとともに、高強度及び高靭性を有する。このため、塗布層のプライマーとして使用される樹脂製のものと親和性があって、そのプライマーにより、表面の凹凸が円滑になって、平滑なプライマー塗布面を形成する。   The FRP board is a board (board) made of fiber reinforced plastic, has high affinity with resin paint, and has high strength and high toughness. For this reason, it has affinity with the resin-made thing used as a primer of an application layer, and the unevenness | corrugation of a surface becomes smooth with the primer, and a smooth primer application surface is formed.

この平滑なプライマー面に落書き防止に優れた常温硬化型無機質塗料層を形成することとなるため、その常温硬化型無機質塗料層は、薄くすることができる。その塗膜の層が薄ければ、クラックが生じにくく、凹凸や穴は極小となり、かつ極めて少なくなり、落書きされてもそのインクがその穴等内に入り込むことが殆どない。このため、落書きは、塗料層表面から、容易に剥がす(除去する)ことができる。   Since the room temperature curable inorganic coating layer excellent in graffiti prevention is formed on the smooth primer surface, the room temperature curable inorganic coating layer can be made thin. If the coating layer is thin, cracks are unlikely to occur, the unevenness and the holes are minimized, and the number of holes is extremely small. For this reason, graffiti can be easily peeled off (removed) from the surface of the paint layer.

さらに、従来では、手塗りが主流であり、その塗膜厚は、上述のように、50μm以上であり、その膜厚では、落書きを円滑に除去できなかった。すなわち、発明者は、その落書き防止用塗料層(塗膜)厚が12μm以下になると、落書き除去効果が増すことを発見した。   Furthermore, conventionally, hand-painting has been the mainstream, and the coating film thickness is 50 μm or more as described above, and graffiti could not be removed smoothly with that film thickness. That is, the inventor has found that the graffiti removal effect increases when the graffiti prevention paint layer (coating film) thickness is 12 μm or less.

落書き防止用塗料としては、セラミック塗料が優れており、そのセラミック塗料の場合、プライマー層は、そのセラミック塗料と親和性のあるアクリルシリコーン系塗料で形成するとよい。このとき、そのセラミック塗料の塗膜厚は5μm以上として、十分な落書き剥離性を発揮するようにすることが好ましい。   A ceramic paint is excellent as a graffiti-preventing paint. In the case of the ceramic paint, the primer layer may be formed of an acrylic silicone paint having an affinity for the ceramic paint. At this time, it is preferable that the coating thickness of the ceramic coating is 5 μm or more so as to exhibit sufficient graffiti peelability.

因みに、従来、落書き防止用塗料層厚が50μm以上であったのは、熟練の者でもその程度の膜厚で塗布するのが限度であるからと考える。
この発明においては、工場における厳しい管理下で、その落書き防止用塗料の塗布を行うことにより、その薄い膜厚が可能になった。工場生産であれば、常温硬化型無機質塗料の塗膜厚の管理を正確に行うことができ、高品質の製品を提供することができる。
Incidentally, the reason why the graffiti prevention paint layer thickness has been 50 μm or more in the past is that even a skilled person is limited to coating with such a film thickness.
In the present invention, the thin film thickness can be achieved by applying the graffiti-preventing paint under strict management in a factory. If it is factory production, it is possible to accurately manage the coating thickness of the room temperature curable inorganic paint, and to provide a high quality product.

この発明は、以上のように、FRP板基材表面をプライマーにより平滑化し、その上に塗膜厚12μm以下の常温硬化型無機質塗料層を工場で形成した構成としたので、水性インク、油性インクの別なく、そのインクによる落書きを容易に除去することができる。
落書きが容易に除去されれば、落書きする心ない者も落書きする意欲がなくなって、落書きが抑制される。すなわち、落書き防止が図られる。
In the present invention, as described above, the surface of the FRP plate base material is smoothed with a primer, and a room temperature curable inorganic coating layer having a coating thickness of 12 μm or less is formed thereon at the factory. Regardless of, the graffiti by the ink can be easily removed.
If graffiti is easily removed, even those who don't have graffiti will not be willing to graffiti and graffiti will be suppressed. That is, graffiti prevention is achieved.

図1に一実施形態を示し、この実施形態は、工場において、FRP板基材1の表面を、No.1000のサンドペーパーを用いて目荒らしを行った後、アルコールにて脱脂して下地処理を行った。この下地処理後のFRP板基材1の表面にプライマー塗料2としてアクリルシリコーン系2液硬化塗料(例えば、「大橋化学工業株式会社製 商品名:エバハートNo800(S)(アクリル樹脂を主剤、シリコーン樹脂を硬化剤とし、その重量比が主剤:硬化剤=10:1))を層厚:15〜20μmで塗布して、その表面を平滑化してプライマー塗布面とした(下塗り)。   One embodiment is shown in FIG. 1, which is the same as that of the FRP plate substrate 1 in a factory. After performing roughening using 1000 sandpaper, the base was treated by degreasing with alcohol. An acrylic silicone-based two-component curable paint (for example, “Ohashi Chemical Industry Co., Ltd., trade name: Evahart No800 (S) (primary acrylic resin, silicone resin) And a weight ratio of main agent: curing agent = 10: 1) was applied at a layer thickness of 15-20 μm, and the surface was smoothed to obtain a primer-coated surface (undercoat).

そのプライマー塗布面2に、さらに、常温硬化型無機質塗料である無機系セラミック塗料(例えば、大橋化学工業株式会社製 商品名:エバハートNo100(S)(塗料分類としてはセラミック塗料であり、樹脂骨格は無機質のシリコーンであって、主剤と硬化剤の重量比が主剤:硬化剤=10:1))3を層厚:5〜10μmで塗布した(上塗り)。
ここで、上記エバハートNo100(S)は、層厚:5μm以上では、後述の落書きなどの剥離性がほぼ一定となり、一方、クラックの発生危険度は、層厚:7μmまでは殆どなく、それ以後、徐々に上昇し、層厚:10μm付近において10%程度となり、以後も上昇を続け、層厚:20μmで危険度:20%を超える。このため、許容範囲として、層厚:5〜10μmが好ましい。
Further, an inorganic ceramic paint which is a room temperature curable inorganic paint (for example, manufactured by Ohashi Chemical Industry Co., Ltd., trade name: EVAHART No100 (S) (the paint classification is ceramic paint, and the resin skeleton is Inorganic silicone, the weight ratio of the main agent to the curing agent was main agent: curing agent = 10: 1)) 3 was applied at a layer thickness of 5 to 10 μm (top coating).
Here, in the above Evahart No100 (S), when the layer thickness is 5 μm or more, the peeling property such as graffiti described later becomes almost constant, while the risk of cracking hardly reaches the layer thickness: 7 μm, and thereafter It gradually increases, and the layer thickness is about 10% in the vicinity of 10 μm, and continues to increase after that, and the layer thickness is 20 μm and the degree of risk exceeds 20%. For this reason, as a tolerance, layer thickness: 5-10 micrometers is preferable.

その層2、3の塗布手段は、ローラ塗布、エアーガン塗布などの周知のものを採用し、そのエアーガン塗布の際には、適宜にシンナーを混ぜて噴霧性を高める。このシンナーの混合は、下塗り剤と上塗り剤の界面を形成して両者が直接に接しない(付着しない)効果を発揮し、また、平滑化も高める。特に、トルエン系のシンナーを使用するとよい。
また、プライマー塗料や常温硬化型無機質塗料のその主剤と硬化剤との混合比は、上記に限らず、FRP板との付着性、落書き防止性を考慮に入れて、適宜に設定する。
As the means for applying the layers 2 and 3, well-known means such as roller application and air gun application are adopted, and when applying the air gun, a thinner is appropriately mixed to improve sprayability. The mixing of the thinner forms an interface between the undercoat and the top coat, exhibits an effect that the two do not directly contact (does not adhere), and improves smoothness. In particular, toluene-based thinner may be used.
Further, the mixing ratio of the main agent and the curing agent of the primer coating or the room temperature curable inorganic coating is not limited to the above, and is appropriately set in consideration of the adhesion to the FRP plate and the anti-graffiti properties.

この実施例において、図2に示すように、下塗り層2の表面に、種々の模様(例えば、木目、石面模様、花、絵画、全面着色など)を印刷し、その模様4の上に、透明の上塗り層3を形成した板Pとすることができる。
このようにすれば、装飾性の高い落書き防止板Pとすることができ、例えば、周辺の景観に合った壁面とすることができる。このとき、その模様4はUV出力プリントとすることが好ましい。因みに、UV出力プリントとは、紫外線を強制的にあてて硬化させるもので、紫外線による劣化が無い利点を有する。
In this embodiment, as shown in FIG. 2, various patterns (for example, wood grain, stone surface pattern, flowers, painting, full-color coloring, etc.) are printed on the surface of the undercoat layer 2. It can be set as the board P in which the transparent overcoat layer 3 is formed.
If it does in this way, it can be set as the graffiti prevention board P with high decorating property, for example, can be set as the wall surface suitable for the surrounding scenery. At this time, the pattern 4 is preferably a UV output print. Incidentally, the UV output print is forcibly applied with ultraviolet rays to be cured, and has an advantage that there is no deterioration due to the ultraviolet rays.

これらの落書き防止板Pに、ラッカースプレーで落書きし、その落書きを2時間ほど放置してその落書き塗膜が乾燥した後、粘着テープをその塗膜面に貼着後、剥がすことにより、その落書きは容易に除去できた。また、ラッカーシンナーによっても容易に除去できた。前者は、塗膜が厚い場合に有利であり、粘着テープで除去できない場合には、クリアーラッカーをその落書き塗膜に重ね塗りしてその厚みを厚くしたのち剥がすようにする。
この落書きが剥がれた(除去した)面3は、耐薬品性に優れ、全くその痕跡がないものとなった。
Graffiti on these graffiti prevention plates P with lacquer spray, leave the graffiti for about 2 hours, dry the graffiti paint film, stick the adhesive tape on the paint film surface, peel off the graffiti Could easily be removed. It could also be easily removed with lacquer thinner. The former is advantageous when the coating film is thick, and if it cannot be removed with an adhesive tape, a clear lacquer is applied over the graffiti coating film to increase the thickness and then peeled off.
The surface 3 from which the graffiti was peeled off (removed) was excellent in chemical resistance and had no trace at all.

この落書き防止板Pに、油性インクで落書し、その直後においては、ティッシュペーパーで簡単に拭き取ることができた。乾燥後においては、乾燥したウェスで擦り取ることができ、また、上記の粘着テープ、ラッカーシンナーによる方法で容易に除去することができた。
この落書きが剥がれた(除去した)面3は、同様に、全くその痕跡がないものとなった。
The graffiti prevention plate P was written with oil-based ink, and immediately after that, it could be easily wiped off with tissue paper. After drying, it could be scraped off with a dry waste, and could be easily removed by the method using the above-mentioned adhesive tape and lacquer thinner.
The surface 3 from which this graffiti was peeled (removed) was similarly free of any traces.

車の排気ガス、塵などの汚染物質をこの落書き防止板Pに付着させた場合には、ラッカーシンナーによって容易に除去することができ、その汚染物質が剥離除去された面(上塗り層)3は、同様に、全くその痕跡がないものとなった。
これらのことから、この板Pは、落書きの除去のみならず、貼り紙やシールを貼着されても、それを容易に剥がすことができる。
When pollutants such as car exhaust gas and dust adhere to this graffiti prevention plate P, the surface (topcoat layer) 3 from which the pollutants have been removed can be easily removed by lacquer thinner. Similarly, there was no trace at all.
From these things, this board P can peel off easily not only the removal of graffiti but also a sticker or a sticker.

この実施例の落書き防止板Pは、直接に下地に取付けることができるため、その取付け面の態様を選ばない。このため、下地処理も不要となり、工期の短縮が可能で、落書き防止面(壁面)の構築のコストダウンを図ることができる。   Since the graffiti prevention plate P of this embodiment can be directly attached to the ground, the form of the attachment surface is not selected. For this reason, the ground treatment is not required, the construction period can be shortened, and the cost for constructing the graffiti prevention surface (wall surface) can be reduced.

その取付け態様としては、橋脚、構造物などの定期的に母材の打音試験を行う場所等の取り外しを必要とする場所では、図3に示すように、その周りに当て板11を当て、その当て板11をビス12で母材Aに止めることにより、取付けるようにすると良い。
一方、建物の外壁、門塀、定期的に母材Aの打音試験を行なわない場所等の取り外しを必要としない場所では、図4に示すように、この落書き防止板Pを母材Aにビス12により直接に取付けることができる。
As a mounting mode, in a place where removal such as a place where a hammering test of a base material is periodically performed such as a bridge pier and a structure is necessary, as shown in FIG. It is preferable that the backing plate 11 is attached to the base material A by screws 12.
On the other hand, in a place where it is not necessary to remove the outer wall of the building, the gate, or the place where the base material A is not subjected to a hammering test regularly, the graffiti prevention plate P is used as the base material A as shown in FIG. It can be attached directly with screws 12.

このような落書き防止板Pであると、現場では、その取付け作業しか発生しない(取付け作業のみでその取り付けが完了する)。このため、天候に影響を受けずに作業を進めることができて作業性がよい。この作業性が良いことは、施工日数、作業時間に制約がある場所でも、計画的に作業を遂行できるため、塗布が現場施工の現状に比べれば、工期の短縮、コスト削減が可能である。また、塗布作業がなく、取付け作業だけでよいことは、塗布という特殊な技能を要求されず、熟練を要しないため、この落書き防止板Pは取り扱いが容易といえる。   With such a graffiti prevention plate P, only the installation work occurs at the site (the installation is completed only by the installation work). For this reason, work can be performed without being affected by the weather, and workability is good. The good workability means that work can be carried out systematically even in places where there are restrictions on the number of work days and work time, so that the work period can be shortened and costs can be reduced compared to the current situation of on-site construction. Moreover, since there is no application | coating operation | work and only installation work is required, since the special skill of application | coating is not requested | required and skill is not required, it can be said that this graffiti prevention board P is easy to handle.

この落書き防止板Pの使用個所としては、種々の落書きされる壁面に採用できるが、例えば、鉄道分野においては、線路側部の法面、民家との境界のブロック壁面、高架下通路部の側壁面、駅構内側壁面などが考えられる。
道路、河川分野においては、橋の橋脚面、道路脇の法面などが考えられる。公園分野においては、公園内の案内看板、公衆便所の側壁面などが考えられる。また、建築分野においては、門塀面、外壁面などが考えられる。
This graffiti prevention plate P can be used on various graffitied wall surfaces. For example, in the railway field, the slope of the railroad side, the block wall surface of the border with private houses, the side of the underpass passage The wall surface, the inner wall surface of the station, etc. can be considered.
In the road and river fields, bridge pier surfaces and roadside slopes can be considered. In the park field, information signs in the park, side walls of public toilets, etc. are conceivable. In the field of architecture, gate walls, outer wall surfaces, etc. can be considered.

さらに、この実施例の落書き防止板Pは、塗膜3表面の水接触角が約118°と大きいため、着雪し難く、着雪防止材としても使用できる。また、この落書き防止板Pは部分補修、交換が可能のため、維持管理費を安価とすることもできる。   Furthermore, since the graffiti prevention plate P of this example has a large water contact angle of about 118 ° on the surface of the coating film 3, it is difficult to snow and can also be used as a snow accretion prevention material. Further, since the graffiti prevention plate P can be partially repaired and replaced, the maintenance cost can be reduced.

FRP板1に代えてポリカボネート板、アルミニウム板などの金属板等を採用することもできる。   Instead of the FRP plate 1, a metal plate such as a polycarbonate plate or an aluminum plate may be employed.

一実施例の断面図Cross section of one embodiment 他の実施例の断面図Cross-sectional view of another embodiment 実施例の取付け説明図Installation illustration of the embodiment 同他の取付け説明図Other installation instructions

符号の説明Explanation of symbols

1 FRP板
2 プライマー層
3 常温硬化型無機質塗料(塗膜)層
4 模様
P 落書き防止板
DESCRIPTION OF SYMBOLS 1 FRP board 2 Primer layer 3 Room temperature curing type inorganic paint (coating film) layer 4 Pattern P Graffiti prevention board

Claims (4)

FRP板基材1の表面にその表面を平滑化するプライマー層2が形成され、そのプライマー層2の表面に、工場にて塗膜厚12μm以下の常温硬化型無機質塗料層3が形成された落書き防止板。   Graffiti on which a primer layer 2 for smoothing the surface is formed on the surface of the FRP plate substrate 1, and a room temperature curable inorganic coating layer 3 having a coating thickness of 12 μm or less is formed on the surface of the primer layer 2 at the factory. Prevention plate. 上記プライマー層2がアクリルシリコーン系塗料、上記常温硬化型無機質塗料層3がセラミック塗料からなることを特徴とする請求項1に記載の落書き防止板。   2. The graffiti prevention plate according to claim 1, wherein the primer layer 2 comprises an acrylic silicone paint, and the room temperature curable inorganic paint layer 3 comprises a ceramic paint. 上記セラミック塗料の塗膜厚を5μm以上としたことを特徴とする請求項2に記載の落書き防止板。   The graffiti prevention plate according to claim 2, wherein the coating thickness of the ceramic paint is 5 μm or more. 上記プライマー層2の表面に模様4を印刷し、上記常温硬化型無機質塗料層3を透明としたことを特徴とする請求項1乃至3の何れかに記載の落書き防止板。   The graffiti prevention board according to any one of claims 1 to 3, wherein a pattern 4 is printed on the surface of the primer layer 2 to make the room temperature curable inorganic coating layer 3 transparent.
JP2004179644A 2004-06-17 2004-06-17 Scribble preventing plate Pending JP2006001126A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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Application Number Title Priority Date Filing Date
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Country Link
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008136969A (en) * 2006-12-04 2008-06-19 East Japan Railway Co Surface treatment method of concrete building frame

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08197678A (en) * 1995-01-23 1996-08-06 Teruo Iwasaki Antistaining panel material
JPH09141193A (en) * 1995-11-24 1997-06-03 Matsushita Electric Works Ltd Coated plate with high resistance to pollution
JP2004075970A (en) * 2002-06-18 2004-03-11 Shin Etsu Chem Co Ltd Hard-coating agent and article formed with the hard coat

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08197678A (en) * 1995-01-23 1996-08-06 Teruo Iwasaki Antistaining panel material
JPH09141193A (en) * 1995-11-24 1997-06-03 Matsushita Electric Works Ltd Coated plate with high resistance to pollution
JP2004075970A (en) * 2002-06-18 2004-03-11 Shin Etsu Chem Co Ltd Hard-coating agent and article formed with the hard coat

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008136969A (en) * 2006-12-04 2008-06-19 East Japan Railway Co Surface treatment method of concrete building frame

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