JP2005514531A5 - - Google Patents
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- JP2005514531A5 JP2005514531A5 JP2003558117A JP2003558117A JP2005514531A5 JP 2005514531 A5 JP2005514531 A5 JP 2005514531A5 JP 2003558117 A JP2003558117 A JP 2003558117A JP 2003558117 A JP2003558117 A JP 2003558117A JP 2005514531 A5 JP2005514531 A5 JP 2005514531A5
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- 239000000203 mixture Substances 0.000 claims description 37
- 239000011230 binding agent Substances 0.000 claims description 21
- 239000000969 carrier Substances 0.000 claims description 19
- 239000003795 chemical substances by application Substances 0.000 claims description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 239000008187 granular material Substances 0.000 claims description 13
- 239000000654 additive Substances 0.000 claims description 10
- 239000007787 solid Substances 0.000 claims description 10
- 239000003599 detergent Substances 0.000 claims description 7
- 239000004753 textile Substances 0.000 claims description 7
- 238000009472 formulation Methods 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 239000002657 fibrous material Substances 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- 239000011780 sodium chloride Substances 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 claims description 2
- 239000000155 melt Substances 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- 239000007921 spray Substances 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 claims description 2
- -1 amino, hydroxy Chemical group 0.000 claims 15
- 239000000975 dye Substances 0.000 claims 13
- 125000000217 alkyl group Chemical group 0.000 claims 12
- 238000006068 polycondensation reaction Methods 0.000 claims 11
- 239000000047 product Substances 0.000 claims 11
- PZZYQPZGQPZBDN-UHFFFAOYSA-N Aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 claims 8
- 125000002947 alkylene group Chemical group 0.000 claims 8
- XZMCDFZZKTWFGF-UHFFFAOYSA-N carbodiimide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 claims 7
- 150000007522 mineralic acids Chemical class 0.000 claims 7
- 150000007524 organic acids Chemical class 0.000 claims 7
- 125000003545 alkoxy group Chemical group 0.000 claims 6
- 150000001412 amines Chemical class 0.000 claims 6
- 239000001913 cellulose Substances 0.000 claims 6
- 125000004093 cyano group Chemical group *C#N 0.000 claims 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims 6
- 125000005842 heteroatoms Chemical group 0.000 claims 6
- 229910052739 hydrogen Inorganic materials 0.000 claims 6
- 239000001257 hydrogen Substances 0.000 claims 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims 6
- 239000005995 Aluminium silicate Substances 0.000 claims 5
- 230000000996 additive Effects 0.000 claims 5
- 235000012211 aluminium silicate Nutrition 0.000 claims 5
- 125000004432 carbon atoms Chemical group C* 0.000 claims 5
- 229920002678 cellulose Polymers 0.000 claims 5
- 235000010980 cellulose Nutrition 0.000 claims 5
- 239000000454 talc Substances 0.000 claims 5
- 229910052623 talc Inorganic materials 0.000 claims 5
- 239000002253 acid Substances 0.000 claims 4
- 239000007859 condensation product Substances 0.000 claims 4
- 150000002431 hydrogen Chemical class 0.000 claims 4
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims 3
- 229920001353 Dextrin Polymers 0.000 claims 3
- 239000004375 Dextrin Substances 0.000 claims 3
- 108010010803 Gelatin Proteins 0.000 claims 3
- 229940031574 HYDROXYMETHYL CELLULOSE Drugs 0.000 claims 3
- 239000005909 Kieselgur Substances 0.000 claims 3
- 239000002202 Polyethylene glycol Substances 0.000 claims 3
- 239000004372 Polyvinyl alcohol Substances 0.000 claims 3
- 229920002472 Starch Polymers 0.000 claims 3
- HWKQNAWCHQMZHK-UHFFFAOYSA-N Trolnitrate Chemical compound [O-][N+](=O)OCCN(CCO[N+]([O-])=O)CCO[N+]([O-])=O HWKQNAWCHQMZHK-UHFFFAOYSA-N 0.000 claims 3
- 239000000440 bentonite Substances 0.000 claims 3
- 229910000278 bentonite Inorganic materials 0.000 claims 3
- 239000004202 carbamide Substances 0.000 claims 3
- 239000001768 carboxy methyl cellulose Substances 0.000 claims 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims 3
- 150000001875 compounds Chemical class 0.000 claims 3
- 229920001577 copolymer Polymers 0.000 claims 3
- 235000019425 dextrin Nutrition 0.000 claims 3
- 238000004090 dissolution Methods 0.000 claims 3
- 239000010433 feldspar Substances 0.000 claims 3
- 239000000945 filler Substances 0.000 claims 3
- 239000010419 fine particle Substances 0.000 claims 3
- 229920000159 gelatin Polymers 0.000 claims 3
- 239000008273 gelatin Substances 0.000 claims 3
- 235000019322 gelatine Nutrition 0.000 claims 3
- 235000011852 gelatine desserts Nutrition 0.000 claims 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N glycol Chemical group OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 3
- 229920003063 hydroxymethyl cellulose Polymers 0.000 claims 3
- 239000010445 mica Substances 0.000 claims 3
- 229910052618 mica group Inorganic materials 0.000 claims 3
- 239000000049 pigment Substances 0.000 claims 3
- 229920001223 polyethylene glycol Polymers 0.000 claims 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 3
- 239000008107 starch Substances 0.000 claims 3
- 235000019698 starch Nutrition 0.000 claims 3
- 239000000126 substance Substances 0.000 claims 3
- 239000002562 thickening agent Substances 0.000 claims 3
- 239000000080 wetting agent Substances 0.000 claims 3
- 239000010457 zeolite Substances 0.000 claims 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims 2
- 229920000168 Microcrystalline cellulose Polymers 0.000 claims 2
- 229910004298 SiO 2 Inorganic materials 0.000 claims 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 2
- FKHIFSZMMVMEQY-UHFFFAOYSA-N Talc Chemical compound [Mg+2].[O-][Si]([O-])=O FKHIFSZMMVMEQY-UHFFFAOYSA-N 0.000 claims 2
- 229910010413 TiO 2 Inorganic materials 0.000 claims 2
- 239000012190 activator Substances 0.000 claims 2
- 125000003342 alkenyl group Chemical group 0.000 claims 2
- 125000005466 alkylenyl group Chemical group 0.000 claims 2
- 239000003945 anionic surfactant Substances 0.000 claims 2
- 239000007844 bleaching agent Substances 0.000 claims 2
- 239000007884 disintegrant Substances 0.000 claims 2
- 239000002270 dispersing agent Substances 0.000 claims 2
- 239000004744 fabric Substances 0.000 claims 2
- 238000005562 fading Methods 0.000 claims 2
- 239000006081 fluorescent whitening agent Substances 0.000 claims 2
- 239000006260 foam Substances 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 2
- 125000002632 imidazolidinyl group Chemical group 0.000 claims 2
- 239000000391 magnesium silicate Substances 0.000 claims 2
- 229940099273 magnesium trisilicate Drugs 0.000 claims 2
- 229910000386 magnesium trisilicate Inorganic materials 0.000 claims 2
- 235000019793 magnesium trisilicate Nutrition 0.000 claims 2
- 235000019813 microcrystalline cellulose Nutrition 0.000 claims 2
- 239000008108 microcrystalline cellulose Substances 0.000 claims 2
- 229940016286 microcrystalline cellulose Drugs 0.000 claims 2
- 239000002736 nonionic surfactant Substances 0.000 claims 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N oxane Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims 2
- 150000002978 peroxides Chemical class 0.000 claims 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims 2
- 229920000642 polymer Polymers 0.000 claims 2
- 238000005406 washing Methods 0.000 claims 2
- 229920003169 water-soluble polymer Polymers 0.000 claims 2
- GHNRTXCRBJQVGN-UHFFFAOYSA-N 4-dodecan-6-ylbenzenesulfonic acid Chemical compound CCCCCCC(CCCCC)C1=CC=C(S(O)(=O)=O)C=C1 GHNRTXCRBJQVGN-UHFFFAOYSA-N 0.000 claims 1
- AIXZBGVLNVRQSS-UHFFFAOYSA-N 5-tert-butyl-2-[5-(5-tert-butyl-1,3-benzoxazol-2-yl)thiophen-2-yl]-1,3-benzoxazole Chemical compound CC(C)(C)C1=CC=C2OC(C3=CC=C(S3)C=3OC4=CC=C(C=C4N=3)C(C)(C)C)=NC2=C1 AIXZBGVLNVRQSS-UHFFFAOYSA-N 0.000 claims 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-L CHEBI:8154 Chemical class [O-]P([O-])=O ABLZXFCXXLZCGV-UHFFFAOYSA-L 0.000 claims 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N DETA Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims 1
- 102000004190 Enzymes Human genes 0.000 claims 1
- 108090000790 Enzymes Proteins 0.000 claims 1
- JRKICGRDRMAZLK-UHFFFAOYSA-N Peroxydisulfuric acid Chemical compound OS(=O)(=O)OOS(O)(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-N 0.000 claims 1
- 239000004698 Polyethylene (PE) Substances 0.000 claims 1
- 229940043230 Sarcosine Drugs 0.000 claims 1
- 108010077895 Sarcosine Proteins 0.000 claims 1
- 239000006096 absorbing agent Substances 0.000 claims 1
- 150000007513 acids Chemical class 0.000 claims 1
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 229910000318 alkali metal phosphate Inorganic materials 0.000 claims 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims 1
- 230000003078 antioxidant Effects 0.000 claims 1
- 239000003963 antioxidant agent Substances 0.000 claims 1
- 239000002216 antistatic agent Substances 0.000 claims 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims 1
- 239000003086 colorant Substances 0.000 claims 1
- 239000008139 complexing agent Substances 0.000 claims 1
- QGBSISYHAICWAH-UHFFFAOYSA-N cyanoguanidine Chemical group NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 claims 1
- 230000000249 desinfective Effects 0.000 claims 1
- 238000002845 discoloration Methods 0.000 claims 1
- 239000000428 dust Substances 0.000 claims 1
- 238000004043 dyeing Methods 0.000 claims 1
- 239000003205 fragrance Substances 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 230000003287 optical Effects 0.000 claims 1
- 150000004967 organic peroxy acids Chemical class 0.000 claims 1
- 239000003002 pH adjusting agent Substances 0.000 claims 1
- PNIJRIIGBGFYHF-UHFFFAOYSA-P perboric acid Chemical compound [H+].[H+].O[B-]1(O)OO[B-](O)(O)OO1 PNIJRIIGBGFYHF-UHFFFAOYSA-P 0.000 claims 1
- 239000002304 perfume Substances 0.000 claims 1
- 229920000768 polyamine Polymers 0.000 claims 1
- 229920005646 polycarboxylate Polymers 0.000 claims 1
- 229920000573 polyethylene Polymers 0.000 claims 1
- 229920003124 powdered cellulose Polymers 0.000 claims 1
- 235000019814 powdered cellulose Nutrition 0.000 claims 1
- 150000003138 primary alcohols Chemical class 0.000 claims 1
- 150000004760 silicates Chemical class 0.000 claims 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 claims 1
- 239000002689 soil Substances 0.000 claims 1
- 238000001694 spray drying Methods 0.000 claims 1
- 239000000375 suspending agent Substances 0.000 claims 1
- 239000000243 solution Substances 0.000 description 10
- 238000005469 granulation Methods 0.000 description 4
- 230000003179 granulation Effects 0.000 description 4
- 238000010923 batch production Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 239000011859 microparticle Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
Description
本発明の方法のさらなる好ましい変種において、織物繊維材料は、以下の成分を少なくとも１種類含んでいる担体を含む微粒子組成物を用いて処理される：
１）水溶性の無機塩および／または有機塩で、特に通例の織物洗剤組成物の構成成分であってよいが、好ましくは界面活性剤成分ではないもの、
２）微粉化された有機固体で、水中で膨潤可能および／または部分的に水溶性であるもの、ならびに
３）高度に微分散された水不溶性の無機担体。
In a further preferred variant of the process according to the invention, the textile fiber material is treated with a particulate composition comprising a carrier comprising at least one of the following components:
1) Water-soluble inorganic and / or organic salts, which may be components of conventional textile detergent compositions, but preferably not surfactant components,
2) A finely divided organic solid that is swellable and / or partially water soluble in water, and
3) A highly finely dispersed water-insoluble inorganic carrier.
本発明の微粒子組成物、特に顆粒物は、液体または固体の染料固着剤から出発して、種々の方法、すなわち：
ｉ）染料固着剤、または染料固着剤およびバインダーを溶解し、そして
その後、固体担体をその溶液と接触させて、好ましくは溶液中に分散体を形成させるか、あるいは
ii）染料固着剤、または染料固着剤およびバインダーを溶解し、そして
その後、この溶液を固体担体に塗布し、またはその溶液で固体担体を顆粒化するか、あるいは
iii）染料固着剤、担体およびバインダーを含むペーストを押出成形するか、あるいは
iv）染料固着剤、担体および、可能であればさらにバインダーからなる混合物を、さらなるバインダーが溶解していてよい溶媒または溶融物をスプレー塗布することによって、顆粒化させ、
そして、方法ｉ）、ii）、iii）もしくはiv）によって得られた組成物を乾燥するか、または冷却により固化させる方法で製造される。得られた顆粒物のコーティングは、たとえば、その後の工程で、顆粒物にコーティング材料溶液をスプレー塗布して乾燥するか、または溶融物でコーティングすることによって実施することも可能である。
The microparticle compositions of the invention, in particular granules, start from liquid or solid dye fixing agents in various ways, namely:
i) dissolving the dye fixing agent, or dye fixing agent and binder, and then contacting the solid support with the solution, preferably to form a dispersion in the solution, or
ii) dissolving the dye fixing agent, or dye fixing agent and binder, and then applying this solution to a solid carrier, or granulating the solid carrier with that solution, or
iii) extruding a paste containing a dye fixing agent, a carrier and a binder, or
iv) granulating the mixture of dye fixing agent, carrier and possibly further binder by spraying a solvent or melt in which further binder can be dissolved,
The composition obtained by the method i) , ii) , iii) or iv) is produced by drying or solidifying by cooling. Coating of the resulting granules can be carried out, for example, by spraying the granules with a coating material solution in the subsequent step and drying or coating with a melt.
方法ｉ）について：
まず、有効成分、バインダーおよび場合によりさらなる添加剤を水に溶解し、そしてその混合物を、場合により加熱しながら、均一な溶液が得られるまで撹拌する。ついで、担体材料をこの水溶液中に懸濁させる。この混合物を、均一な懸濁物が得られるまで撹拌する。この懸濁物の固形分は、好ましくは、溶液の全重量を基準にして少なくとも３０重量％、特に４０〜５０重量％であるべきである。溶液の粘度は、好ましくは１，５００mPa・s未満である。
For method i) :
First, the active ingredient, binder and optionally further additives are dissolved in water and the mixture is stirred, optionally with heating, until a homogeneous solution is obtained. The carrier material is then suspended in this aqueous solution. The mixture is stirred until a uniform suspension is obtained. The solids content of this suspension should preferably be at least 30% by weight, in particular 40-50% by weight, based on the total weight of the solution. The viscosity of the solution is preferably less than 1,500 mPa · s.
方法ii）について：
まず、溶解された染料固着剤、ならびに場合によりさらなるバインダーおよび添加剤からなる溶液を調製する。ついでこの溶液を、スプレー装置により造粒装置中の担体に吹きかけ、凝集によって顆粒を形成させる。顆粒化は、バッチ法または連続手順のいずれかで達成させる。適した造粒装置は、流動床造粒装置、または水平型もしくは縦型の回転式混合機である。顆粒化操作が完了したら、所望の残留量以外の水を顆粒物から除去する。この脱水操作は、同一の装置または別個の後乾燥器のいずれかにおいて実施する。
About method ii) :
First, a solution is prepared consisting of the dissolved dye fixing agent and optionally further binders and additives. The solution is then sprayed onto the carrier in the granulator with a spray device to form granules by agglomeration. Granulation is accomplished in either a batch process or a continuous procedure. Suitable granulators are fluid bed granulators or horizontal or vertical rotary mixers. When the granulation operation is complete, water other than the desired residual amount is removed from the granulate. This dehydration operation is carried out either in the same apparatus or in a separate post-dryer.
方法iii）について：
染料固着剤、担体および場合によりバインダーからなるペーストを、混練装置中で調製する。これらの成分は、適量の水を添加するか、または配合物成分の１種類以上を溶融することによってペースト化する。ついでこのペーストを押出機に供給し、円柱形粒子（直径０．５〜２mm、長さ１〜３mm；直径／長さ比１：１〜１：４）に成形する。押し出した材料を、さらなる工程で乾燥／固化させる。希望するならば、押し出した材料を別工程で球状に丸めてもよい。生成した微細物は、すべて工程中に再循環される。
For method iii) :
A paste consisting of a dye fixing agent, a carrier and optionally a binder is prepared in a kneader. These components are pasted by adding an appropriate amount of water or melting one or more of the formulation components. The paste is then fed into an extruder and formed into cylindrical particles (diameter 0.5-2 mm, length 1-3 mm; diameter / length ratio 1: 1-1: 4). The extruded material is dried / solidified in a further step. If desired, the extruded material may be rounded into a sphere in a separate step. All produced fines are recycled in the process.
方法iv）について：
染料固着剤、担体およびバインダーからなる均一な乾燥混合物を混合機中で調製する。ついでこの混合物に、溶融したバインダー、バインダー水溶液または、適切なら水単独を、造粒装置中においてスプレーで吹きかけて、その混合物を顆粒化する。この顆粒化は、バッチ法または連続手順のいずれかで達成させる。適した造粒装置は、流動床造粒装置、および水平型または縦型の回転式混合機の両方である。顆粒化操作が完了したら、所望の残留量以外の水を顆粒物から除去するか、または溶融したバインダーの場合には顆粒物を固化させる。
About method iv) :
A uniform dry mixture consisting of dye fixing agent, carrier and binder is prepared in a mixer. The mixture is then sprayed with molten binder, aqueous binder solution or water alone, if appropriate, in a granulator to granulate the mixture. This granulation is accomplished either by a batch process or a continuous procedure. Suitable granulators are both fluid bed granulators and horizontal or vertical rotary mixers. When the granulation operation is complete, water other than the desired residual amount is removed from the granule or, in the case of a molten binder, the granule is solidified.
Claims (18)
ａ）１〜９０重量％の、式：
（式中、
Ｒ 1 、Ｒ 2 、Ｒ 3 およびＲ 4 それぞれは、互いに独立して、水素、または非置換の、もしくはアミノ、ヒドロキシ、シアノにより、もしくはＣ 1 〜Ｃ 4 アルコキシにより置換されたアルキルであり、そして
Ａは、非置換の、もしくは置換された、または非中断の、もしくはヘテロ原子の１個以上により中断されたアルキレンである）
のアミンとシアナミドとの塩基性重縮合生成物（該重縮合生成物は、非中和か、または無機酸もしくは有機酸で全体的もしくは部分的に中和されている）水溶性染料固着剤、
ｂ）２〜８０重量％の担体、
ｃ）０〜６０重量％の水溶性／水分散性バインダー、
ｄ）０〜２０重量％のさらなる添加剤、および
ｅ）０〜１５重量％の水、
（ここで、それぞれの場合のパーセント値は、組成物の全重量を基準とする重量パーセントを意味する）。 A method of reducing dye fading and color transfer from a textile fiber material, comprising treating the textile fiber material with a particulate composition comprising:
a) 1 to 90% by weight of the formula:
(Where
Each of R 1 , R 2 , R 3 and R 4 is, independently of one another, hydrogen, or alkyl, unsubstituted or substituted by amino, hydroxy, cyano or by C 1 -C 4 alkoxy;
A is unsubstituted, substituted, or uninterrupted, or alkylene interrupted by one or more of the heteroatoms)
A basic polycondensation product of an amine with cyanamide, the polycondensation product being non-neutralized or wholly or partially neutralized with an inorganic or organic acid ,
b) 2-80% by weight of support,
c) 0-60% by weight of a water-soluble / water-dispersible binder,
d) 0-20% by weight of further additives, and e) 0-15% by weight of water,
(Where the percentage values in each case mean weight percentages based on the total weight of the composition).
１）水溶性の無機塩および／または有機塩であって、このものは特に通常の織物用洗剤組成物の成分であってよいが、好ましくは界面活性剤の成分ではないもの、
２）微粉化有機固体であって、水中で膨潤可能および／または水溶性であるもの、ならびに
３）水不溶性の無機担体であって、超微分散されているもの。 The process according to any one of claims 1 to 6 , wherein the treatment is carried out using a particulate composition comprising a carrier comprising at least one of the following components:
1) Water-soluble inorganic and / or organic salts, which may in particular be components of ordinary textile detergent compositions, but preferably not surfactant components,
2) Finely divided organic solids that are swellable and / or water soluble in water, and
3) A water-insoluble inorganic carrier that is ultrafinely dispersed.
ａ）１〜９０重量％の、式：
（式中、
Ｒ 1 、Ｒ 2 、Ｒ 3 およびＲ 4 それぞれは、互いに独立して、水素、または非置換の、もしくはアミノ、ヒドロキシ、シアノにより、もしくはＣ 1 〜Ｃ 4 アルコキシにより置換されたアルキルであり、そして
Ａは、非置換の、もしくは置換された、または非中断の、もしくはヘテロ原子の１個以上により中断されたアルキレンである）
のアミンとシアナミドとの塩基性重縮合生成物（該重縮合生成物は、非中和か、または無機酸もしくは有機酸で全体的もしくは部分的に中和されている）水溶性染料固着剤、
ｂ）２〜８０重量％の担体、
ｃ）０〜６０重量％の水溶性／水分散性バインダー、
ｄ）０〜２０重量％のさらなる添加剤、および
ｅ）０〜１５重量％の水、
（ここで、それぞれの場合のパーセント値は、組成物の全重量を基準とする重量％を意味し、そして成分ａ）、ｂ）、ｃ）、ｄ）およびｅ）の定義は、請求項１〜１２による）。 A particulate composition comprising:
a) 1 to 90% by weight of the formula:
(Where
Each of R 1 , R 2 , R 3 and R 4 , independently of one another, is hydrogen or alkyl, unsubstituted or substituted by amino, hydroxy, cyano, or C 1 -C 4 alkoxy;
A is unsubstituted, substituted, or uninterrupted, or alkylene interrupted by one or more of the heteroatoms)
A basic polycondensation product of an amine with cyanamide, which is non-neutralized or wholly or partially neutralized with an inorganic or organic acid ;
b) 2-80% by weight of support,
c) 0-60% by weight of a water-soluble / water-dispersible binder,
d) 0-20% by weight of further additives, and e) 0-15% by weight of water,
(Where the percentage values in each case mean weight percent based on the total weight of the composition, and the definitions of components a), b), c), d) and e) are defined in claim 1 To 12 ).
ｉ）染料固着剤、または染料固着剤とバインダー、ここで水溶性染料固着剤は、式：
（式中、
Ｒ 1 、Ｒ 2 、Ｒ 3 およびＲ 4 それぞれは、互いに独立して、水素、または非置換の、もしくはアミノ、ヒドロキシ、シアノにより、もしくはＣ 1 〜Ｃ 4 アルコキシにより置換されたアルキルであり、そして
Ａは、非置換の、もしくは置換された、または非中断の、もしくはヘテロ原子の１個以上により中断されたアルキレンである）
のアミンとシアナミドとの塩基性重縮合生成物（該重縮合生成物は、非中和か、または無機酸もしくは有機酸で全体的もしくは部分的に中和されている）を溶解し、そして
その後、固体担体をその溶液と接触させて、好ましくは溶液中に分散体を形成させるか、あるいは
ii）方法ｉ）で定義された染料固着剤、または染料固着剤とバインダーを溶解し、そして
その後、この溶液を固体担体に塗布し、またはその溶液で固体担体を顆粒化するか、あるいは
iii）方法ｉ）で定義された染料固着剤、担体およびバインダーを含むペーストを押出成形するか、あるいは
iv）方法ｉ）で定義された染料固着剤、担体および、可能であればさらにバインダーからなる混合物を、さらなるバインダーが溶解していてよい溶媒または溶融物のスプレー塗布によって顆粒化させ、
そして、方法ｉ）、ii）、iii）もしくはiv）によって得られた組成物を乾燥するか、または冷却により固化させることを含む方法。 A method for producing a fine particle composition comprising:
i) A dye fixing agent, or a dye fixing agent and a binder , wherein the water-soluble dye fixing agent has the formula:
(Where
Each of R 1 , R 2 , R 3 and R 4 , independently of one another, is hydrogen or alkyl, unsubstituted or substituted by amino, hydroxy, cyano, or C 1 -C 4 alkoxy;
A is unsubstituted, substituted, or uninterrupted, or alkylene interrupted by one or more of the heteroatoms)
A basic polycondensation product of an amine with cyanamide, which is non-neutralized or wholly or partially neutralized with an inorganic or organic acid , and then Contacting the solid support with the solution, preferably to form a dispersion in the solution, or
ii) dissolving the dye fixing agent or dye fixing agent and binder as defined in method i) and then applying this solution to a solid carrier or granulating the solid carrier with that solution, or
iii) extruding a paste comprising a dye fixing agent, carrier and binder as defined in method i) , or
iv) granulating the mixture of dye-fixing agent, carrier as defined in method i) and possibly further binder by spray application of a solvent or melt in which further binder can be dissolved,
And a method comprising drying or solidifying by cooling the composition obtained by method i) , ii) , iii) or iv) .
Ｉ）５〜９０％（洗剤配合物の全重量を基準にして）の、
Ａ）アニオン性界面活性剤の少なくとも１種類、および／または
Ｂ）非イオン性界面活性剤の少なくとも１種類、
II）５〜７０％（洗剤配合物の全重量を基準にして）の、
Ｃ）ビルダー物質の少なくとも１種類、
III）０〜３０％（洗剤配合物の全重量を基準にして）の、
Ｄ）過酸化物の少なくとも１種類、および場合により活性化剤の少なくとも１種類、
IV）０．１〜７０％の、
Ｅ）以下を含む微粒子組成物の少なくとも１種類：
ａ）１〜９０重量％の、式：
（式中、
Ｒ 1 、Ｒ 2 、Ｒ 3 およびＲ 4 それぞれは、互いに独立して、水素、または非置換の、もしくはアミノ、ヒドロキシ、シアノにより、もしくはＣ 1 〜Ｃ 4 アルコキシにより置換されたアルキルであり、そして
Ａは、非置換の、もしくは置換された、または非中断の、もしくはヘテロ原子の１個以上により中断されたアルキレンである）
のアミンとシアナミドとの塩基性重縮合生成物（該重縮合生成物は、非中和か、または無機酸もしくは有機酸で全体的もしくは部分的に中和されている）水溶性染料固着剤の少なくとも１種類、
ｂ）２〜８０重量％の、担体の少なくとも１種類、
ｃ）０〜６０重量％の、水溶性／水分散性バインダーの少なくとも１種類、
ｄ）０〜２０重量％の、さらなる添加剤の少なくとも１種類、および
ｅ）０〜１５重量％の水、
Ｖ）０〜６０％の、
Ｆ）さらなる添加剤の少なくとも１種類、ならびに
VI）０〜１２％の、
Ｇ）水。 Detergent formulations comprising the following for reducing dye fading or color transfer from textile fiber materials:
I) 5-90% (based on the total weight of the detergent formulation)
A) at least one anionic surfactant, and / or B) at least one nonionic surfactant,
II) 5-70% (based on the total weight of the detergent formulation)
C) at least one builder substance,
III) 0-30% (based on the total weight of the detergent formulation),
D) at least one peroxide and optionally at least one activator;
IV) 0.1-70%
E) At least one particulate composition comprising:
a) 1 to 90% by weight of the formula:
(Where
Each of R 1 , R 2 , R 3 and R 4 is, independently of one another, hydrogen, or alkyl, unsubstituted or substituted by amino, hydroxy, cyano or by C 1 -C 4 alkoxy;
A is unsubstituted, substituted, or uninterrupted, or alkylene interrupted by one or more of the heteroatoms)
A basic polycondensation product of an amine with cyanamide, which is non-neutralized or wholly or partially neutralized with an inorganic or organic acid ; At least one,
b) 2 to 80% by weight of at least one carrier,
c) 0-60% by weight of at least one water-soluble / water-dispersible binder,
d) 0-20% by weight of at least one further additive, and e) 0-15% by weight of water,
V) 0-60%
F) at least one further additive, and
VI) 0-12%,
G) Water.
Ｉ）５〜９０％の、
Ａ）Ｃ12〜Ｃ22アルキルポリオキシエチレン硫酸塩（アルキル部分が炭素原子１０〜２０個を有し、その頭頂基がエチレンオキシド単位を平均２〜３個有する）；アルキルベンゼンスルホン酸塩（アルキル部分に炭素原子９〜１５個を有する）；アルキルナフタレンスルホン酸塩（それぞれのアルキル部分に炭素原子６〜１６個を有する）；または式：Ｒ11−ＣＯ−Ｎ（Ｒ12）−ＣＨ2ＣＯＯＭ1（式中、Ｒ11は、アルキルまたはアルケニルであって、そのアルキルまたはアルケニル部分に炭素原子８〜１８個を有するものであり、Ｒ12は、Ｃ1〜Ｃ4アルキルであり、そしてＭ1は、アルカリ金属である）のサルコシン酸アルカリ金属塩よりなる群からの、アニオン界面活性剤の少なくとも１種類、および／または
Ｂ）エチレンオキシド３〜８molと、炭素原子９〜１５個を有する第一級アルコール１molとの縮合生成物よりなる群からの、非イオン性界面活性剤の少なくとも１種類、
II）５〜７０％の、
Ｃ）アルカリ金属の、リン酸塩；炭酸塩；重炭酸塩；ケイ酸塩；アルミニウムケイ酸塩；ポリカルボン酸塩；ポリカルボン酸；有機ホスホン酸塩またはアミノアルキレンポリ（アルキレンホスホン酸塩）よりなる群からの、ビルダー物質、
III）０〜３０％の、
Ｄ）有機モノ−またはポリ過酸化物；有機過酸またはそれの塩；過硫酸；過ホウ酸；過炭酸；過ケイ酸よりなる群からの、過酸化物、
IV）０．１〜７０％の、
Ｅ）以下を含む顆粒物：
ａ）１〜９０重量％、好ましくは５〜８８重量％、特に１０〜７８重量％の、式：
（式中、
Ｒ 1 、Ｒ 2 、Ｒ 3 およびＲ 4 それぞれは、互いに独立して、水素、または非置換の、もしくはアミノ、ヒドロキシ、シアノにより、もしくはＣ 1 〜Ｃ 4 アルコキシにより置換されたアルキルであり、そして
Ａは、非置換の、もしくは置換された、または非中断の、もしくはヘテロ原子の１個以上により中断されたアルキレンである）
のアミンとシアナミドとの塩基性重縮合生成物（該重縮合生成物は、非中和か、または無機酸もしくは有機酸で全体的もしくは部分的に中和されている）、該塩基性重縮合生成物は、好ましくはイミダゾリジン単位を含有するものである、
ｂ）２〜８０重量％の、ゼオライト、ベントナイト、けいそう土、タルク、カオリン、雲母、フラー土、セルロース、長石、および尿素とホルムアルデヒドの縮合生成物よりなる群からの、担体の少なくとも１種類、
ｃ）０〜６０重量％の、デンプン、麦芽デキストリン、カルボキシメチルセルロース、ヒドロキシメチルセルロース、ポリエチレングリコール、エチレンオキシド／プロピレンオキシドコポリマー、ポリビニルアルコールおよびゼラチンよりなる群からの、非イオン性分散剤および／または水溶性ポリマーの少なくとも１種類、
ｄ）０〜２０重量％の、湿潤剤；崩壊剤；充填剤、水不溶性もしくは水溶性の染料または顔料；溶解促進剤；蛍光増白剤；アルミニウムケイ酸塩；粉末化セルロース；繊維状セルロース；微結晶セルロース；タルク；カオリン；ＴｉＯ2；ＳｉＯ2；およびマグネシウム三ケイ酸塩よりなる群からの、さらなる添加剤の少なくとも１種類、ならびに
ｅ）０〜１５重量％の水、
（それぞれの場合、顆粒物の全重量を基準）、
Ｖ）０〜６０％の、
Ｆ）蛍光増白剤；汚れ懸濁剤；ｐＨ調節剤；泡制御剤；スプレー乾燥性および顆粒化性調節のための塩類；香料；帯電防止剤；柔軟剤；酵素；漂白剤；顔料；調色剤；織物の洗濯中に、洗濯条件下で織物から溶出してきて洗濯液中に存在する染料によって染まるのを防ぐ、さらなるポリマー類；および漂白剤活性化剤よりなる群からの、さらなる添加剤、ならびに
VI）０〜１２％の、
Ｇ）水。 The detergent formulation of claim 16 , comprising:
I) 5-90%
The alkylbenzene sulfonate (alkyl moiety; where A) C 12 -C 22 alkyl polyoxyethylene sulfates (alkyl moiety has 10 to 20 carbon atoms, the top group is the average two or three chromatic ethylene oxide units) Alkyl naphthalene sulfonate (having 6 to 16 carbon atoms in each alkyl moiety); or the formula: R 11 —CO—N (R 12 ) —CH 2 COOM 1 (having 9 to 15 carbon atoms); In which R 11 is alkyl or alkenyl having 8 to 18 carbon atoms in the alkyl or alkenyl moiety, R 12 is C 1 -C 4 alkyl, and M 1 is At least one anionic surfactant from the group consisting of alkali metal sarcosine acids) and / or B) ethylene oxide ~8mol and, from the group consisting of condensation products of primary alcohols 1mol having 9-15 carbon atoms, at least one non-ionic surfactant,
II) 5-70%
C) From alkali metal phosphates; carbonates; bicarbonates; silicates; aluminum silicates; polycarboxylates; polycarboxylic acids; organic phosphonates or aminoalkylene poly (alkylene phosphonates) Builder substances from the group consisting of
III) 0-30%
D) organic mono- or polyperoxides; organic peracids or salts thereof; persulfuric acid; perboric acid; percarbonate; peroxides from the group consisting of persilicic acid,
IV) 0.1-70%
E) Granules containing:
a) 1 to 90% by weight, preferably 5 to 88% by weight, in particular 10 to 78% by weight of the formula:
(Where
Each of R 1 , R 2 , R 3 and R 4 is, independently of one another, hydrogen, or alkyl, unsubstituted or substituted by amino, hydroxy, cyano or by C 1 -C 4 alkoxy;
A is unsubstituted, substituted, or uninterrupted, or alkylene interrupted by one or more of the heteroatoms)
A basic polycondensation product of an amine with cyanamide (the polycondensation product is non-neutralized or wholly or partially neutralized with an inorganic or organic acid), the basic polycondensation products, preferably those containing imidazolidine units,
b) at least one carrier from the group consisting of 2 to 80% by weight of zeolite, bentonite, diatomaceous earth, talc, kaolin, mica, fuller's earth, cellulose, feldspar, and condensation products of urea and formaldehyde,
c) 0 to 60% by weight of nonionic dispersant and / or water-soluble polymer from the group consisting of starch, malt dextrin, carboxymethylcellulose, hydroxymethylcellulose, polyethylene glycol, ethylene oxide / propylene oxide copolymer, polyvinyl alcohol and gelatin At least one of
d) 0-20% by weight of wetting agent; disintegrant; filler, water-insoluble or water-soluble dye or pigment; dissolution promoter; fluorescent brightener; aluminum silicate; powdered cellulose; microcrystalline cellulose; talc; kaolin; TiO 2; SiO 2; from the group consisting of magnesium trisilicate, at least one further additive, and e) 0 to 15 wt% of water,
(In each case based on the total weight of the granule),
V) 0-60%
F) Fluorescent whitening agent; soil suspending agent; pH adjusting agent; foam control agent; salt for adjusting spray drying and granulating property; fragrance; antistatic agent; softener; enzyme; bleaching agent; Additional additives from the group consisting of: colorants; during the washing of the fabric, further polymers that elute from the fabric under washing conditions and prevent dyeing by the dyes present in the wash liquor; and a bleach activator And
VI) 0-12%,
G) Water.
Ａ）０．５〜５０重量％（組成物の全重量を基準にして）の、柔軟剤成分の少なくとも１種類；
Ｂ）０．００５〜１５重量％（組成物の全重量を基準にして）の、増粘剤、特にポリマー増粘剤の少なくとも１種類；
Ｃ）０．１〜７０重量％（組成物の全重量を基準にして）の、以下を含む顆粒物：
ａ）１〜９０重量％、好ましくは５〜８８重量％、より好ましくは１０〜７８重量％の、式：
（式中、
Ｒ 1 、Ｒ 2 、Ｒ 3 およびＲ 4 それぞれは、互いに独立して、水素、または非置換の、もしくはアミノ、ヒドロキシ、シアノにより、もしくはＣ 1 〜Ｃ 4 アルコキシにより置換されたアルキルであり、そして
Ａは、非置換の、もしくは置換された、または非中断の、もしくはヘテロ原子の１個以上により中断されたアルキレンである）
のアミンとシアナミドとの塩基性重縮合生成物（該重縮合生成物は、非中和か、または無機酸もしくは有機酸で全体的もしくは部分的に中和されている）、該塩基性重縮合生成物は、好ましくはイミダゾリジン単位を含有するものである、
ｂ）２〜８０重量％の、ゼオライト、ベントナイト、けいそう土、タルク、カオリン、雲母、フラー土、セルロース、長石、および尿素とホルムアルデヒドの縮合生成物よりなる群からの、担体の少なくとも１種類、
ｃ）０〜６０重量％の、デンプン、麦芽デキストリン、カルボキシメチルセルロース、ヒドロキシメチルセルロース、ポリエチレングリコール、エチレンオキシド／プロピレンオキシドコポリマー、ポリビニルアルコールおよびゼラチンよりなる群からの、非イオン性分散剤および／または水溶性ポリマーの少なくとも１種類、ならびに
ｄ）０〜２０重量％の、湿潤剤；崩壊剤；充填剤、水不溶性もしくは水溶性の染料または顔料；溶解促進剤；蛍光増白剤；アルミニウムケイ酸塩；粉末化セルロース；繊維状セルロース；微結晶セルロース；タルク；カオリン；ＴｉＯ2；ＳｉＯ2；およびマグネシウム三ケイ酸塩よりなる群からの、さらなる添加剤の少なくとも１種類、ならびに
ｅ）０〜１５重量％の水、
（それぞれの場合、顆粒物の全重量を基準）、
Ｄ）０〜２０重量％（組成物の全重量を基準にして）の、さらなる通常の補助物質の少なくとも１種類、ならびに
Ｅ）水で全体を１００重量％になる量。 A softener formulation for reducing dye discoloration or color transfer from textile fiber materials comprising:
A) 0.5-50% by weight (based on the total weight of the composition) of at least one softener component;
B) 0.005 to 15% by weight (based on the total weight of the composition) of at least one thickener, in particular a polymer thickener;
C) Granules comprising 0.1 to 70% by weight (based on the total weight of the composition) comprising:
a) 1 to 90% by weight, preferably 5 to 88% by weight, more preferably 10 to 78% by weight of the formula:
(Where
Each of R 1 , R 2 , R 3 and R 4 is, independently of one another, hydrogen, or alkyl, unsubstituted or substituted by amino, hydroxy, cyano or by C 1 -C 4 alkoxy;
A is unsubstituted, substituted, or uninterrupted, or alkylene interrupted by one or more heteroatoms)
A basic polycondensation product of an amine with cyanamide (the polycondensation product is non-neutralized or wholly or partially neutralized with an inorganic or organic acid), the basic polycondensation products, preferably those containing imidazolidine units,
b) at least one carrier from the group consisting of 2 to 80% by weight of zeolite, bentonite, diatomaceous earth, talc, kaolin, mica, fuller's earth, cellulose, feldspar, and condensation products of urea and formaldehyde,
c) 0 to 60% by weight nonionic dispersant and / or water-soluble polymer from the group consisting of starch, malt dextrin, carboxymethylcellulose, hydroxymethylcellulose, polyethylene glycol, ethylene oxide / propylene oxide copolymer, polyvinyl alcohol and gelatin D) 0-20% by weight of a wetting agent; a disintegrant; a filler, a water-insoluble or water-soluble dye or pigment; a dissolution accelerator; an optical brightener; an aluminum silicate; At least one additional additive from the group consisting of cellulose; fibrous cellulose; microcrystalline cellulose; talc; kaolin; TiO 2 ; SiO 2 ; and magnesium trisilicate; and e) 0-15 wt% water. ,
(In each case based on the total weight of the granule),
D) 0-20% by weight (based on the total weight of the composition) of at least one further conventional auxiliary substance, and E) an amount of 100% by weight overall with water.
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|---|---|---|---|
| EP02405002 | 2002-01-07 | ||
| PCT/EP2002/014785 WO2003057815A1 (en) | 2002-01-07 | 2002-12-27 | Particulate composition comprising dye fixatives |
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| US (1) | US20050039266A1 (en) |
| EP (1) | EP1472333A1 (en) |
| JP (1) | JP4443929B2 (en) |
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| EP2248884A1 (en) * | 2004-07-22 | 2010-11-10 | The Procter & Gamble Company | Detergent Compositions Comprising Coloured Particles |
| JP5043293B2 (en) * | 2004-09-16 | 2012-10-10 | スリーエム イノベイティブ プロパティズ カンパニー | Female materials for mechanical fasteners and disposable diapers |
| DE102004048752A1 (en) | 2004-10-05 | 2006-04-06 | Cognis Ip Management Gmbh | Liquid surfactant mixtures |
| GB0422533D0 (en) * | 2004-10-11 | 2004-11-10 | Univ Leeds | Non-aqueous treatment method |
| DE102005039168A1 (en) * | 2005-08-17 | 2007-02-22 | Cognis Ip Management Gmbh | Solid agents containing cationic polymers |
| GB0607047D0 (en) * | 2006-04-07 | 2006-05-17 | Univ Leeds | Novel cleaning method |
| JP5245148B2 (en) * | 2007-08-07 | 2013-07-24 | ライオン株式会社 | Liquid softener composition |
| FR2928377A1 (en) * | 2008-03-06 | 2009-09-11 | Rhodia Operations Sas | Composition, useful to treat and/or modify surface e.g. textile, comprises copolymer comprising cationic units and other units, where the cationic unit comprises quaternary ammonium/inium group and other unit comprises vinyl-lactam |
| EP2212409B1 (en) * | 2007-11-06 | 2017-08-16 | Rhodia Opérations | Copolymer for treatment of laundry or hard surface |
| IT1402263B1 (en) * | 2010-09-14 | 2013-08-28 | Lamberti Spa | FABRIC CATCH-COLORS |
| US20120085250A1 (en) * | 2010-10-12 | 2012-04-12 | Ecolab Usa Inc. | Novel method of treating textiles with starch to eliminate sticking |
| WO2012117024A1 (en) * | 2011-03-01 | 2012-09-07 | Basf Se | Polymers inhibiting dye transfer and having improved storage stability and processability for detergents and cleaning agents |
| BR112014026300A2 (en) * | 2012-04-23 | 2017-06-27 | Unilever Nv | liquid, isotropic, aqueous, externally structured laundry detergent composition |
| CN103242982A (en) * | 2013-05-21 | 2013-08-14 | 海安县联发张氏色织有限公司 | Fabric washing agent |
| US10435831B1 (en) * | 2014-07-15 | 2019-10-08 | Rita Harry-Ogiste | Fabric treating accessories and associated use thereof |
| CN105820893B (en) * | 2015-01-07 | 2020-08-14 | 杭州绿泽宇和生物科技有限公司 | Disposable household washing article |
| PE20181462A1 (en) | 2015-11-06 | 2018-09-13 | Ecolab Usa Inc | METHODS AND SYSTEMS FOR DUST CONTROL |
| WO2018028928A1 (en) | 2016-08-10 | 2018-02-15 | Unilever Plc | Laundry composition |
| CN106917233A (en) * | 2017-03-09 | 2017-07-04 | 无锡小天鹅股份有限公司 | For the color protection device and washing machine of washing machine |
| EP3736320A1 (en) * | 2019-05-08 | 2020-11-11 | The Procter & Gamble Company | Particles for through the wash laundry softening |
| CN112442771B (en) * | 2020-11-13 | 2022-03-08 | 浙江羊绒世家服饰股份有限公司 | Water-soluble fiber and high count cashmere yarn spinning process |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4728337A (en) * | 1985-11-08 | 1988-03-01 | Ciba-Geigy Corporation | Assistant combination and use thereof as wool textile finishing agent |
| US4961755A (en) * | 1987-12-29 | 1990-10-09 | Ciba-Geigy Corporation | Coated active substances: dye coated with polyethylene oxide-propylene oxide or with ethoxylated stearyldi phenyloxyethyl diethylenetriamine |
| US5030242A (en) * | 1989-07-21 | 1991-07-09 | Bellaire David L | Method of imparting random coloration patterns in fabric |
| TW307804B (en) * | 1994-07-12 | 1997-06-11 | Ciba Sc Holding Ag | |
| DE69710749T2 (en) * | 1996-10-18 | 2002-11-14 | Procter & Gamble | DETERGENT COMPOSITIONS |
| DE19643281A1 (en) * | 1996-10-21 | 1998-04-23 | Basf Ag | Use of polycationic condensation products as a color-fixing additive for detergents and laundry aftertreatment agents |
| DE19646437A1 (en) * | 1996-11-11 | 1998-05-14 | Basf Ag | Use of quaternized vinylimidazole units containing polymers as a color-fixing and dye transfer-inhibiting additive to laundry after-treatment agents and to detergents |
| CN1170916C (en) * | 1996-12-31 | 2004-10-13 | 普罗格特-甘布尔公司 | Laundry detergent compositions comprising dye fixatives |
| CA2283876C (en) * | 1997-03-15 | 2004-04-13 | The Procter & Gamble Company | Delivery systems |
| US6187740B1 (en) * | 1997-07-11 | 2001-02-13 | The Procter & Gamble Company | Alkaline detergent compositions comprising a specific cellulase |
| EP0918089A1 (en) * | 1997-11-24 | 1999-05-26 | The Procter & Gamble Company | Fabric care compositions |
| US6008316A (en) * | 1998-09-03 | 1999-12-28 | National Starch And Chemical Investment Holding Corporation | Functionalized polyamines |
| GB9821217D0 (en) * | 1998-09-30 | 1998-11-25 | Unilever Plc | Treatment for substrates |
| CZ20021828A3 (en) * | 1999-12-03 | 2002-10-16 | The Procter & Gamble Company | Additive delivery particles and laundry or cleaning agent containing thereof |
| US6627591B2 (en) * | 1999-12-17 | 2003-09-30 | Unilever Home & Personal Care Usa Division Of Conopco, Inc. | Dye fixing composition |
| DE10015991A1 (en) * | 2000-03-31 | 2001-10-11 | Henkel Kgaa | Textile care products |
| DE10019405A1 (en) * | 2000-04-19 | 2001-10-25 | Cognis Deutschland Gmbh | Dry detergent granulate production comprises reducing fatty alcohol content in technical mixture of alkyl and/or alkenyl-oligoglycosides and mixing resultant melt with detergent additives in mixer or extruder |
-
2002
- 2002-12-27 AU AU2002367419A patent/AU2002367419B2/en not_active Ceased
- 2002-12-27 KR KR10-2004-7010627A patent/KR20040073553A/en active IP Right Grant
- 2002-12-27 BR BR0215478-1A patent/BR0215478A/en not_active IP Right Cessation
- 2002-12-27 EP EP02806027A patent/EP1472333A1/en not_active Withdrawn
- 2002-12-27 WO PCT/EP2002/014785 patent/WO2003057815A1/en active Application Filing
- 2002-12-27 JP JP2003558117A patent/JP4443929B2/en not_active Expired - Fee Related
- 2002-12-27 US US10/500,778 patent/US20050039266A1/en not_active Abandoned
- 2002-12-27 CN CNB028268237A patent/CN100335605C/en not_active Expired - Fee Related
- 2002-12-27 MX MXPA04006559A patent/MXPA04006559A/en active IP Right Grant
-
2004
- 2004-06-10 ZA ZA200404615A patent/ZA200404615B/en unknown
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