JP2005343175A - Reversible thermal sensitive recording medium and reversible thermal sensitive recorder - Google Patents

Reversible thermal sensitive recording medium and reversible thermal sensitive recorder Download PDF

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JP2005343175A
JP2005343175A JP2005175758A JP2005175758A JP2005343175A JP 2005343175 A JP2005343175 A JP 2005343175A JP 2005175758 A JP2005175758 A JP 2005175758A JP 2005175758 A JP2005175758 A JP 2005175758A JP 2005343175 A JP2005343175 A JP 2005343175A
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reversible thermosensitive
thermosensitive recording
erasing
recording
area
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JP2005343175A5 (en
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Atsushi Kutami
篤 久田見
Tetsuya Amano
哲也 天野
Kazumi Suzuki
一己 鈴木
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Ricoh Co Ltd
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Ricoh Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a reversible thermal sensitive recording medium difficult to generate heat deformation (curling) by heating for recording/erasing. <P>SOLUTION: A recording area is formed by a width of ≤50% of total width in a cross direction or a longitudinal direction in a central part, or the recording area is formed by an area of ≤60% of total area in the central part, and the remainder is made non recording area to obtain the reversible thermal sensitive recording medium. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本発明は、熱エネルギーの制御により可逆的に発色状態・消色状態を安定して形成できる記録領域を有し、繰り返し印字・消去が可能な可逆性感熱記録媒体、及びそれの印字・消去に用いる可逆性感熱記録装置に関する。   The present invention provides a reversible thermosensitive recording medium having a recording area that can be stably formed in a colored state and a decolored state reversibly by controlling thermal energy, and for printing and erasing the same. The present invention relates to a reversible thermosensitive recording apparatus to be used.

従来のハードコピーは、一般に紙などの記録媒体に外部からインクあるいはトナーなどの着色剤を付着固定して画像形成を行うか、あるいは感熱記録紙のように、紙などの基材上に感熱記録層を設け、これにエネルギーを加えて可視画像を形成するなど、永久画像を形成するものであった。   Conventional hard copy generally forms images by attaching and fixing a colorant such as ink or toner to a recording medium such as paper from the outside, or heat-sensitive recording on a substrate such as paper, like heat-sensitive recording paper. A permanent image was formed by providing a layer and applying energy to the layer to form a visible image.

しかし、最近複写機やファクシミリの普及、コンピューターからの情報出力によって記録媒体の消費量が急激に増大し、紙などの原料である木材の需要にともなう樹木の伐採からくる自然破壊や、廃棄物処理など社会問題を引き起こしている。この問題を解決するため、記録した可視画像を消去でき、繰り返し使用可能な記録媒体が注目されている。   However, due to the recent spread of copiers and facsimiles and the output of information from computers, the consumption of recording media has increased dramatically. Natural destruction resulting from the felling of trees due to the demand for wood as a raw material for paper and waste disposal Causing social problems. In order to solve this problem, a recording medium that can erase a recorded visible image and can be used repeatedly has attracted attention.

この繰り返し使用な記録媒体には例えば、有機低分子結晶粒子を分散した高分子膜の光散乱性変化を利用し、透明と白濁の二状態を可逆的に形成できる記録媒体がある(特開昭55−154198号など)。そして、この記録媒体は、すでに磁気カードの内容表示部として実用化されている。しかし、表示される画像は、黒や青の着色地肌またはアルミ蒸着膜などの光反射性の地肌に白色の印字となるので、通常のハードコピーとしては違和感が大きく適していない。   Examples of such a repetitive recording medium include a recording medium capable of reversibly forming two states of transparency and cloudiness by utilizing the light scattering property of a polymer film in which organic low-molecular crystal particles are dispersed (Japanese Patent Laid-Open No. Sho). 55-154198 etc.). This recording medium has already been put into practical use as a content display section of a magnetic card. However, since the displayed image is printed in white on a black or blue colored background or a light-reflective background such as an aluminum vapor deposition film, an uncomfortable feeling is not suitable as a normal hard copy.

この課題に対して、可逆的に発色と消色の二安定状態を取り得るロイコ染料を顕色剤とともに用い、白色地肌に可逆的に発色印字画像を形成できる可逆性感熱記録媒体が提供されている(特開平5−124360号、特開平10−119440号など)。   In response to this problem, there is provided a reversible thermosensitive recording medium using a leuco dye capable of reversibly developing and decoloring, together with a developer, and capable of reversibly forming a color printed image on a white background. (JP-A-5-124360, JP-A-10-119440, etc.).

だが、このロイコ染料タイプは印字エネルギー、消去エネルギーがともに高いため、この可逆性感熱記録媒体は記録・消去によって、特に消去によって熱変形(カール)が生じる。可逆性感熱記録媒体にカールが生じると、以降の記録・消去がスムーズに行なわれず、良質の画像が得られなかったり、画像の消去が完全に行なわれなかったりする。通常、消去は記録装置の所定位置に可逆性感熱記録媒体を搬送し加熱して行なわれるが、前記のカールの程度はこの搬送方向に対して垂直方向(巾方向)に顕著である。その理由は可逆性感熱記録媒体の搬送方向は加熱状態が均一(一様)であること、また多くの場合、可逆性感熱記録媒体の搬送方向に支持体の縦目が形成されていることから、伸縮が生じやすいためと思われる。   However, since this leuco dye type has high printing energy and erasing energy, this reversible thermosensitive recording medium undergoes thermal deformation (curl) by recording and erasing, especially by erasing. When curling occurs in the reversible thermosensitive recording medium, subsequent recording / erasing is not performed smoothly, and a high-quality image cannot be obtained, or the image is not completely erased. Usually, erasing is performed by transporting and heating a reversible thermosensitive recording medium to a predetermined position of the recording apparatus. The degree of curling is remarkable in the direction perpendicular to the transport direction (width direction). This is because the heating state is uniform (uniform) in the transport direction of the reversible thermosensitive recording medium, and in many cases, vertical lines of the support are formed in the transport direction of the reversible thermosensitive recording medium. It seems that expansion and contraction is likely to occur.

本発明の目的は、記録及び消去によっても熱変形(カール)の生じにくい可逆性感熱記録媒体及びこれの記録・消去に用いられる可逆性感熱記録装置を提供することである。   An object of the present invention is to provide a reversible thermosensitive recording medium that hardly undergoes thermal deformation (curl) even by recording and erasing, and a reversible thermosensitive recording apparatus used for recording / erasing the same.

本発明によれば、第一に、支持体の表面に、中央部に横方向又は縦方向の全巾の50%以下の巾で記録領域が形成され、その記録領域を挟むようにそれぞれが該全巾の25%以上の巾で二つの非記録領域が形成され、全体として正方形又は短形を呈してなり、かつ、該記録領域が電子供与性呈色性化合物と電子受容性化合物を主成分とし、加熱温度および/または加熱後の冷却速度の違いにより相対的に発色した状態と消色した状態を形成しうる可逆性熱発色組成物を含有する可逆性感熱記録層であることを特徴とする可逆性感熱記録媒体が提供される。   According to the present invention, first, on the surface of the support, a recording area having a width of 50% or less of the total width in the horizontal direction or the vertical direction is formed at the center, and each of the recording areas is sandwiched between the recording areas. Two non-recording areas are formed with a width of 25% or more of the entire width, and the whole area is square or short, and the recording area is mainly composed of an electron-donating color-forming compound and an electron-accepting compound. And a reversible thermosensitive recording layer containing a reversible thermochromic composition capable of forming a relatively colored state and a decolored state due to a difference in heating temperature and / or cooling rate after heating. A reversible thermosensitive recording medium is provided.

第二に、支持体の表面に、中心部に全面積の60%以下の面積で記録領域が形成され、その記録領域を囲むように非記録領域が形成され、全体として正方形又は短形を呈してなり、かつ、該記録領域が電子供与性呈色性化合物と電子受容性化合物を主成分とし、加熱温度および/または加熱後の冷却速度の違いにより相対的に発色した状態と消色した状態を形成しうる可逆性熱発色組成物を含有する可逆性感熱記録層であることを特徴とする可逆性感熱記録媒体が提供される。   Second, on the surface of the support, a recording area is formed in the central portion with an area of 60% or less of the total area, and a non-recording area is formed so as to surround the recording area, and it has a square or short shape as a whole. And the recording area is mainly composed of an electron-donating color-forming compound and an electron-accepting compound, and is relatively colored and decolored depending on the heating temperature and / or the cooling rate after heating. There is provided a reversible thermosensitive recording medium, which is a reversible thermosensitive recording layer containing a reversible thermochromic composition capable of forming a color.

第三に、支持体の裏面に粘着層が設けられることを特徴とする上記第一又は第二の可逆性感熱記録媒体が提供される。   Third, the first or second reversible thermosensitive recording medium is provided, wherein an adhesive layer is provided on the back surface of the support.

第四に、全体の形態がカード状であることを特徴とする上記第一〜三のいずれかに記載の可逆性感熱記録媒体が提供される。   Fourthly, the reversible thermosensitive recording medium described in any one of the first to third is characterized in that the whole form is a card shape.

第五に、上記第一〜四の可逆性感熱記録媒体の記録領域に画像形成を行うための記録手段、および該記録領域に形成された画像を消去するための消去手段を備えたことを特徴とする可逆性感熱記録装置が提供される。   Fifth, the recording apparatus for forming an image in the recording area of the first to fourth reversible thermosensitive recording media, and an erasing means for erasing the image formed in the recording area are provided. A reversible thermosensitive recording apparatus is provided.

第六に、記録手段及び消去手段は、記録・消去時以外は可逆性感熱記録媒体と非接触又は非加圧接触状態にあり、記録・消去時に該可逆性感熱記録媒体の記録領域だけに加圧接触状態となることを特徴とする上記第五の可逆性感熱記録装置が提供される。   Sixth, the recording means and the erasing means are in a non-contact or non-pressurized contact state with the reversible thermosensitive recording medium except during recording / erasing, and are added only to the recording area of the reversible thermosensitive recording medium during recording / erasing. The fifth reversible thermosensitive recording device is provided, which is in a pressure contact state.

第七に、画像の消去時、消去後又は消去と同時に可逆性感熱記録媒体の裏面を加熱するための裏面加熱手段を備えたことを特徴とする上記第五又は第六の可逆性感熱記録装置が提供される。   Seventh, the fifth or sixth reversible thermosensitive recording apparatus comprising a back surface heating means for heating the back surface of the reversible thermosensitive recording medium at the time of erasing an image, after erasing or simultaneously with erasing. Is provided.

第八に、記録又は消去により昇温された可逆性感熱記録媒体を冷却するための冷却手段を備えたことを特徴とする上記第五〜七のいずれかに記載の可逆性感熱記録装置が提供される。   Eighth, the reversible thermosensitive recording apparatus according to any one of the fifth to seventh aspects, further comprising a cooling means for cooling the reversible thermosensitive recording medium heated by recording or erasing. Is done.

本発明の可逆性感熱記録媒体並びに可逆性感熱記録装置の使用によれば、加熱による変形が少なくて済む。   According to the use of the reversible thermosensitive recording medium and the reversible thermosensitive recording apparatus of the present invention, deformation due to heating can be reduced.

以下、本発明をさらに詳細に説明する。図1(a)に示すように、本発明の可逆性感熱記録媒体11の層構成は、プラスチック、紙、合成紙などからなる厚み1mm以下好ましくは50〜500μmの支持体12上に成膜された記録領域を形成する可逆性感熱記録層13、その記録層上に該記録層の劣化を防ぐための透明保護層14が積層されている。ただし、前述及び後述から明らかなように、可逆性感熱記録層13は支持体12の表面の全体に形成されてはいない。この他に必要に応じ、支持体と可逆性感熱記録層の間に下引き層、可逆性感熱記録層と保護層の間に中間層、保護層上の一部又は全面に着色印刷インキ層、さらにインキ層部分又は非インキ付着を含めた表面に透明保護層を設ける場合もある。   Hereinafter, the present invention will be described in more detail. As shown in FIG. 1A, the layer structure of the reversible thermosensitive recording medium 11 of the present invention is formed on a support 12 made of plastic, paper, synthetic paper or the like and having a thickness of 1 mm or less, preferably 50 to 500 μm. A reversible thermosensitive recording layer 13 forming a recording area, and a transparent protective layer 14 for preventing the recording layer from being deteriorated are laminated on the recording layer. However, as is clear from the above and below, the reversible thermosensitive recording layer 13 is not formed on the entire surface of the support 12. In addition to this, an undercoat layer between the support and the reversible thermosensitive recording layer, an intermediate layer between the reversible thermosensitive recording layer and the protective layer, a colored printing ink layer on a part or the entire surface of the protective layer, Further, a transparent protective layer may be provided on the surface including the ink layer portion or non-ink adhesion.

可逆性感熱記録層13の厚さは1〜30μmが好ましく、2〜20μmがさらに好ましい。この可逆性感熱記録層は結着樹脂中にロイコ染料および顕色剤を分散させることによって形成されている。   The thickness of the reversible thermosensitive recording layer 13 is preferably 1 to 30 μm, and more preferably 2 to 20 μm. This reversible thermosensitive recording layer is formed by dispersing a leuco dye and a developer in a binder resin.

可逆性感熱記録層に用いられる結着樹脂としては、ガラス転移温度が50℃以上が好ましく、60℃以上が更に好ましく、また100℃以下が好ましく、80℃以下が更に好ましい。具体的には、ポリ塩化ビニル、塩化ビニル−酢酸ビニル共重合体、塩化ビニル−酢酸ビニル−ビニルアルコール共重合体、塩化ビニル−酢酸ビニル−マレイン酸共重合体、塩化ビニル−アクリレート共重合体等の塩化ビニル系共重合体;ポリ塩化ビニリデン、塩化ビニリデン−塩化ビニル共重合体、塩化ビニリデン−アクリロニトリル共重合体等の塩化ビニリデン系共重合体;ポリエステル;ポリアミド;ポリアタリレート又はポリメタクリレート或いはアクリレート、メタクリレート共重合体;シリコーン樹脂、ポリエチレン、ポリプロピレン、ポリスチレン、ポリアクリルアミド、ポリビニルピロリドン、天然ゴム、ポリビニルアルコール、ポリアクロレイン、ポリカーボネート等が挙げられる。これらの樹脂は少なくとも一種で或いは二種以上混合して用いてもよい。   The binder resin used for the reversible thermosensitive recording layer preferably has a glass transition temperature of 50 ° C. or higher, more preferably 60 ° C. or higher, preferably 100 ° C. or lower, and more preferably 80 ° C. or lower. Specifically, polyvinyl chloride, vinyl chloride-vinyl acetate copolymer, vinyl chloride-vinyl acetate-vinyl alcohol copolymer, vinyl chloride-vinyl acetate-maleic acid copolymer, vinyl chloride-acrylate copolymer, etc. A vinyl chloride copolymer of polyvinylidene chloride such as polyvinylidene chloride, vinylidene chloride-vinyl chloride copolymer, vinylidene chloride-acrylonitrile copolymer; polyester; polyamide; polyacrylate or polymethacrylate or acrylate; Methacrylate copolymer; silicone resin, polyethylene, polypropylene, polystyrene, polyacrylamide, polyvinyl pyrrolidone, natural rubber, polyvinyl alcohol, polyacrolein, polycarbonate and the like. These resins may be used alone or in combination of two or more.

可逆性感熱記録層に用いられるロイコ染料は、たとえばフタリド系化合物、アザフタリド系化合物、フルオラン系化合物、フェノチアジン系化合物、ロイコオーラミン系化合物など公知の染料前駆体である。   The leuco dye used for the reversible thermosensitive recording layer is a known dye precursor such as a phthalide compound, an azaphthalide compound, a fluoran compound, a phenothiazine compound, or a leucooramine compound.

可逆性感熱記録層に用いられる顕色剤は、分子内にロイコ染料を発色させる顕色能をもつ構造、たとえばフェノール性水酸基、カルボン酸基、リン酸基などと、分子間の凝集力を制御する構造、たとえば長鎖炭化水素基が連結した構造をもつ化合物である。連結部分にはヘテロ原子を含む2価の基を介していてもよく、また長鎖炭化水素基中にもヘテロ原子を含む2価の基または芳香族基が含まれていてもよい。具体的には、特開平5−124360号公報などに記載されている公知の顕色剤が使用できる。この顕色剤の融点は120℃以上が好ましく、140℃がさらに好ましい。   The developer used in the reversible thermosensitive recording layer controls the cohesive force between molecules, such as phenolic hydroxyl groups, carboxylic acid groups, and phosphate groups, which have the ability to develop leuco dyes in the molecule. For example, a compound having a structure in which long-chain hydrocarbon groups are linked. The connecting part may be through a divalent group containing a hetero atom, and the long chain hydrocarbon group may contain a divalent group or an aromatic group containing a hetero atom. Specifically, a known developer described in JP-A-5-124360 can be used. The melting point of the developer is preferably 120 ° C. or higher, and more preferably 140 ° C.

この顕色剤の融点は120℃以上が好ましく、140℃がさらに好ましい。可逆性感熱記録層を保護するために設けられる透明保護層(厚さ0.1〜5μm)の材料としては、シリコーン系ゴム、シリコーン樹脂(特開昭63−221087号公報に記載)、ポリシロキサングラフトポリマー(特開昭63−317385号公報に記載)や紫外線硬化樹脂又は電子線硬化樹脂(特開平02−566号公報に記載)等が挙げられる。これらの中には、有機若しくは無機のフィラーを含有することができる。   The melting point of the developer is preferably 120 ° C. or higher, and more preferably 140 ° C. Examples of the material for the transparent protective layer (thickness 0.1 to 5 μm) provided to protect the reversible thermosensitive recording layer include silicone rubber, silicone resin (described in JP-A-63-221087), polysiloxane. Examples thereof include a graft polymer (described in JP-A No. 63-317385), an ultraviolet curable resin, an electron beam curable resin (described in JP-A No. 02-566), and the like. In these, an organic or inorganic filler can be contained.

透明保護層形成液の溶剤やモノマー成分等から可逆性感熱記録層を保護するために設けられる中間層(厚さ0.2〜2μm)の材料としては、可逆性感熱記録層に用いられる樹脂として挙げたものの他に下記のような熱硬化性樹脂、熱可塑性樹脂、UV硬化樹脂、EB硬化樹脂が使用可能である。即ち、ポリエチレン、ポリプロピレン、ポリスチレン、ポリビニルアルコール、ポリビニルブチラール、ポリウレタン、飽和ポリエステル、不飽和ポリエステル、エポキシ樹脂、フェノール樹脂、ポリカーボネート、ポリアミド等が挙げられる。   As a material for the intermediate layer (thickness 0.2 to 2 μm) provided to protect the reversible thermosensitive recording layer from the solvent, monomer component, etc. of the transparent protective layer forming liquid, as a resin used for the reversible thermosensitive recording layer In addition to those listed above, the following thermosetting resins, thermoplastic resins, UV curable resins, and EB curable resins can be used. That is, polyethylene, polypropylene, polystyrene, polyvinyl alcohol, polyvinyl butyral, polyurethane, saturated polyester, unsaturated polyester, epoxy resin, phenol resin, polycarbonate, polyamide and the like can be mentioned.

支持体と可逆性感熱記録層との接着を良好にするために設けられる下引き層(厚さ0.1〜2μm)の材料としては、従来公知の水溶性高分子及び/又は水性高分子エマルジョンから適宜選択されるのが好ましい。その具体例としては、水溶性高分子として、例えばポリビニルアルコール、澱粉及びその誘導体、メトキシセルロース、ヒドロキシエチルセルロース、カルボキシメチルセルロース、メチルセルロース、エチルセルロース等のセルロース誘導体、ポリアクリル酸ソーダ、ポリビニルピロリドン、アクリルアミド−アクリル酸エステル共重合体、アクリルアミド−アクリル酸エステル−メタクリル酸三元共重合体、スチレン−無水マレイン酸共重合体アルカリ塩、ポリアクリルアミド、アルギン酸ソーダ、ゼラチン、カゼイン等が挙げられる。また、水性高分子エマルジョンとしては、スチレン−ブタジエン共重合体、スチレン−ブタジエン−アクリル系共重合体等のラテックスや、酢酸ビニル樹脂、酢酸ビニル−アクリル酸共重合体、スチレン−アクリル酸エステル共重合体、アクリル酸エステル樹脂、ポリウレタン樹脂等のエマルジョン等が挙げられる。   Examples of the material for the undercoat layer (thickness of 0.1 to 2 μm) provided to improve the adhesion between the support and the reversible thermosensitive recording layer include conventionally known water-soluble polymers and / or aqueous polymer emulsions. Is preferably selected from the following. Specific examples thereof include water-soluble polymers such as polyvinyl alcohol, starch and derivatives thereof, cellulose derivatives such as methoxycellulose, hydroxyethylcellulose, carboxymethylcellulose, methylcellulose, and ethylcellulose, sodium polyacrylate, polyvinylpyrrolidone, and acrylamide-acrylic acid. Examples include ester copolymers, acrylamide-acrylic acid ester-methacrylic acid terpolymers, styrene-maleic anhydride copolymer alkali salts, polyacrylamide, sodium alginate, gelatin, and casein. Examples of the aqueous polymer emulsion include latex such as styrene-butadiene copolymer and styrene-butadiene-acrylic copolymer, vinyl acetate resin, vinyl acetate-acrylic acid copolymer, styrene-acrylic acid ester copolymer. Examples thereof include emulsions such as coalescence, acrylic ester resin, and polyurethane resin.

また、本発明の可逆性感熱記録媒体は図1(b)に示すように、支持体12の裏面には、可逆性感熱記録層13とは別のタイプの記録・記憶材料を含んだ層(例えば、磁気層15など)を設けても良い。磁気層15は厚さ5〜15μmくらいで、通常用いられている酸化鉄、バリウムフェライト等と塩ビ系やウレタン系或いはナイロン系樹脂を用い、支持体裏面に塗工形成されるが、または蒸着、スパッタリング等の方法により樹脂を用いずに形成される。   Further, as shown in FIG. 1B, the reversible thermosensitive recording medium of the present invention is a layer containing a recording / memory material of a type different from the reversible thermosensitive recording layer 13 on the back surface of the support 12 ( For example, a magnetic layer 15 or the like may be provided. The magnetic layer 15 has a thickness of about 5 to 15 μm, and is formed on the back surface of the support by using a commonly used iron oxide, barium ferrite or the like and a vinyl resin, a urethane resin, or a nylon resin, or vapor deposition, It is formed without using a resin by a method such as sputtering.

更に、本発明の可逆性感熱記録媒体は図1(c)に示すように、支持体12の可逆性感熱記録層13と反対側に粘着層16を設け、別の支持体12’に貼着できるようにしてもよく、可逆性感熱記録ラベルとすることもできる。粘着層(厚さ10〜30μm)の材料は一般的に粘着剤として使われているものが使用可能である。具体例としては、ユリア樹脂、メラミン樹脂、フェノール樹脂、エポキシ樹脂、酢酸ビニル系樹脂、酢酸ビニル−アクリル系共重合体、エチレン−酢酸ビニル共重合体、アクリル系樹脂、ポリビニルエーテル系樹脂、塩化ビニル−酢酸ビニル系共重合体、ポリスチレン系樹脂、ポリエステル系樹脂、ポリウレタン系樹脂、ポリアミド系樹脂、塩素化ポリオレフイン系樹脂、ポリビニルブチラール系樹脂、アクリル酸エステル系共重合体、メタクリル酸エステル系共重合体、天然ゴム、シアノアクリレート系樹脂、シリコン系樹脂などが挙げられるが、これらに限定されるものではない。粘着層の材料はホットメルトタイプでも良い。また剥離紙を用いても良いし、無剥離紙タイプでも良い。   Furthermore, as shown in FIG. 1 (c), the reversible thermosensitive recording medium of the present invention is provided with an adhesive layer 16 on the opposite side of the support 12 from the reversible thermosensitive recording layer 13, and affixed to another support 12 ′. It may be possible to use a reversible thermosensitive recording label. As the material for the adhesive layer (thickness: 10 to 30 μm), those generally used as an adhesive can be used. Specific examples include urea resin, melamine resin, phenol resin, epoxy resin, vinyl acetate resin, vinyl acetate-acrylic copolymer, ethylene-vinyl acetate copolymer, acrylic resin, polyvinyl ether resin, vinyl chloride. -Vinyl acetate copolymer, polystyrene resin, polyester resin, polyurethane resin, polyamide resin, chlorinated polyolefin resin, polyvinyl butyral resin, acrylate copolymer, methacrylate ester copolymer , Natural rubber, cyanoacrylate resin, silicon resin, and the like, but are not limited thereto. The material of the adhesive layer may be a hot melt type. Further, release paper may be used or non-release paper type may be used.

これらのロイコ染料および顕色剤を用いた可逆性感熱記録媒体は、図2に示すプロセスで発色・消色する。すなわち、初期の消色状態(A)を加熱すると温度T1以上でロイコ染料と顕色剤が熔融混合して発色し(B)、この状態を急冷すると発色状態のまま固定される(C)。発色状態(C)を加熱していくと、発色温度T1より低い温度T2で消色し(D)、冷却すれば初期と同様の消色状態となる。ここで熔融発色状態(B)からの冷却を徐冷とすると、降温の過程で濃度が低下し、極端な場合にはほとんど消色した状態となる。 A reversible thermosensitive recording medium using these leuco dyes and developer develops and decolors by the process shown in FIG. That is, when the initial decolored state (A) is heated, the leuco dye and the developer are melted and mixed at a temperature T 1 or higher (B), and when this state is rapidly cooled, the colored state is fixed (C). . When the color development state (C) is heated, the color is erased at a temperature T 2 lower than the color development temperature T 1 (D). Here, when cooling from the melt coloring state (B) is gradually cooled, the concentration is lowered in the process of lowering the temperature, and in an extreme case, the state is almost decolored.

可逆性感熱記録媒体は、すでに印字してある発色画像を消去して、新たに別の印字を行い書き換えるのが通常の使用方法であり、一般には消去工程と印字工程は連続的に行われる。消去工程では可逆性感熱記録媒体は消去温度(通常100〜180℃)に加熱される。上記の可逆性感熱記録媒体の印字された発色部を完全に消去するには0.1〜2秒程度の加熱時間が必要である。   In a reversible thermosensitive recording medium, it is a normal usage method to erase a color image that has already been printed, and perform another printing to rewrite it. In general, the erasing process and the printing process are performed continuously. In the erasing process, the reversible thermosensitive recording medium is heated to an erasing temperature (usually 100 to 180 ° C.). A heating time of about 0.1 to 2 seconds is required to completely erase the printed color portion of the reversible thermosensitive recording medium.

ところで、このような加熱を行うために、従来においては、たとえば図3に示すようないわゆるスタンパと呼ばれる印刻型の消去手段51がとられてきた。これは、発熱抵抗体によって消去温度に制御された加熱部材54、たとえば金属板や金属ブロックを可逆性感熱記録媒体11の消去する部分(記録領域)全体に、弾性部材53を有する押圧部材52により押し当てる方法(ホットスタンプ方式)である。しかし、このホットスタンプ方式は、図4(a)(b)に示すような可逆性感熱記録部分即ち記録領域(ここでは消去域100に相当する)の大きい記録媒体では消去域100のみしか加圧加熱しないため、部分的な媒体の熱変形(カール)が生じる。図4(a)(b)において、101及び102は非消去域(非記録領域)である。   Incidentally, in order to perform such heating, conventionally, for example, a so-called stamper erasing means 51 called a stamper as shown in FIG. 3 has been taken. This is because a pressing member 52 having an elastic member 53 is provided on the entire portion (recording area) where the reversible thermosensitive recording medium 11 is erased by a heating member 54 controlled to an erasing temperature by a heating resistor, for example, a metal plate or a metal block. This is a pressing method (hot stamp method). However, this hot stamping method applies pressure only to the erasing area 100 in a reversible thermosensitive recording portion, that is, a recording medium having a large recording area (corresponding to the erasing area 100 here) as shown in FIGS. Since it is not heated, partial thermal deformation (curl) of the medium occurs. 4A and 4B, reference numerals 101 and 102 denote non-erased areas (non-recording areas).

しかしながら、このような部分的な媒体の熱変形(カール)は図5(a)(b)及び図6のように、可逆性感熱記録媒体の中央部又は中心部の狭い部分に可逆性感熱記録部分(消去域100)がある場合、熱変形(カール)は起こるがその部分に留まり、変形度(カールの程度)は格段に少なくなることを見出し本発明に至った。   However, such partial thermal deformation (curl) of the medium is reversible thermosensitive recording in the central part of the reversible thermosensitive recording medium or in a narrow part of the central part as shown in FIGS. When there is a portion (erasing area 100), thermal deformation (curl) occurs but remains in that portion, and the degree of deformation (degree of curl) has been found to be significantly reduced, leading to the present invention.

図5(a)は本発明の可逆性感熱記録媒体全体における記録領域(消去域100)の位置関係を示す例であり、消去域100が上下に設けられた非消去域101、102で挟まれた形態のものである。ここで図面上、縦方向の全巾をL1とした場合、中央部の消去域100の巾m1はL1の50%以下であり、非消去域101、102の巾n1、n2はそれぞれL1の25%以上である。なお、ここではn1=n2であるのが好ましい。図5R>5(b)は上記図5(a)の可逆性感熱記録媒体を90°回転した状態のもの、又は図面上、横方向の全巾をL2とした場合、中央部の消去域100の巾m2はL2の50%以下であり、非消去域101、102の巾n3、n4はそれぞれL2の25%以上としたものである。なお、ここではn3=n4であるのが好ましい。 FIG. 5A is an example showing the positional relationship of the recording area (erasing area 100) in the entire reversible thermosensitive recording medium of the present invention, and the erasing area 100 is sandwiched between non-erasing areas 101 and 102 provided above and below. It is of the form. Here, when the total width in the vertical direction is L 1 in the drawing, the width m 1 of the erase region 100 in the center is 50% or less of L 1 , and the widths n 1 and n 2 of the non-erasable regions 101 and 102 Is 25% or more of L 1 . Here, n 1 = n 2 is preferable. FIG. 5R> 5 (b) shows a state in which the reversible thermosensitive recording medium of FIG. 5 (a) is rotated by 90 °, or when the total width in the lateral direction is L 2 in the drawing, the erased area at the center. The width m 2 of 100 is 50% or less of L 2 , and the widths n 3 and n 4 of the non-erasable areas 101 and 102 are 25% or more of L 2 , respectively. Here, it is preferable that n 3 = n 4 .

これら図5(a)(b)の可逆性感熱記録媒体は、記録・消去に際してそれぞれ矢印方向に移動させることによって熱変形(カール)を著しく減少させることができる。   These reversible thermosensitive recording media shown in FIGS. 5A and 5B can remarkably reduce thermal deformation (curl) by moving in the direction of the arrow during recording and erasing.

図6は本発明の可逆性感熱記録媒体全体における消去域100の位置関係を示す他の例であり、消去域100が中心部に設けられ、これが非消去域103で囲まれた状態のものである。ここで図面上、消去域100は媒体全体の60%以下の面積を占める。また、非消去域103の巾n5、n6、n7、n8において、n5=n6、n7=n8であるのが好ましい。この図6に示す可逆性感熱記録媒体は、図5(a)(b)に示すものと相違して、記録・消去に際して図面上縦方向、横方向いずれに移動させても熱変形(カール)を著しく減少させることができる。 FIG. 6 is another example showing the positional relationship of the erasure area 100 in the entire reversible thermosensitive recording medium of the present invention. The erasure area 100 is provided at the center and is surrounded by the non-erasure area 103. is there. Here, in the drawing, the erase area 100 occupies an area of 60% or less of the entire medium. Further, in the widths n 5 , n 6 , n 7 , and n 8 of the non-erasable region 103, it is preferable that n 5 = n 6 and n 7 = n 8 . The reversible thermosensitive recording medium shown in FIG. 6 differs from that shown in FIGS. 5 (a) and 5 (b) in that it is thermally deformed (curl) when it is moved in the vertical direction or the horizontal direction in the drawing during recording / erasing. Can be significantly reduced.

当然のことながら、記録領域の面積が小さい程加熱によるカールは少なくなる。従って、図5及び図6に示した可逆性感熱記録媒体を裏面から図7(a)(b)又は(c)のように同じ加熱処理を行うと変形がより改善される。媒体裏面にも熱が加わり、表面に縮みと同じくらい裏面が縮むためである。図7で(a)は両面加熱(非同時)、(b)は両面加熱(同時)、(c)は反転させての両面加熱(非同時)を表している。なお、ホットスタンプ方式は、熱が媒体にこもるため、冷却装置が場合によっては必要であり、消去直後冷却するとカールは少なくなる。また、カールの特性として、低温で長時間接触するより、高温で短時間接触する方がカールが少なくなる特性がある。   Naturally, the smaller the area of the recording area, the less curling due to heating. Therefore, when the reversible thermosensitive recording medium shown in FIGS. 5 and 6 is subjected to the same heat treatment from the back as shown in FIGS. 7A, 7B, or 7C, the deformation is further improved. This is because heat is also applied to the back surface of the medium, and the back surface shrinks as much as shrinkage. 7A shows double-sided heating (non-simultaneous), FIG. 7B shows double-sided heating (simultaneous), and FIG. 7C shows reverse-sided heating (non-simultaneous). In the hot stamp method, heat is trapped in the medium, so that a cooling device is necessary depending on the case, and curling is reduced when cooling is performed immediately after erasing. Further, as a characteristic of curling, there is a characteristic that curling is less when a contact is made for a short time at a high temperature than for a long time contact at a low temperature.

この点から、可逆性感熱記録装置における消去手段は表面温度を高くして消去手段の巾を短くし、短時間の接触で同じ媒体温度を実現した方が好ましい。実験の結果、表面温度にも依るが、消去手段の接触巾は1.2〜5.0mmの範囲が良好である。1.2mm以下では熱供給が十分とれなくなり、また5.0mm以上ではカールを少なく抑えられない。   From this point, it is preferable that the erasing unit in the reversible thermosensitive recording apparatus realizes the same medium temperature with a short contact time by increasing the surface temperature to shorten the width of the erasing unit. As a result of the experiment, although depending on the surface temperature, the contact width of the erasing means is preferably in the range of 1.2 to 5.0 mm. If the thickness is 1.2 mm or less, sufficient heat supply cannot be obtained, and if it is 5.0 mm or more, curling cannot be reduced.

図8は本発明の好適な可逆性感熱記録装置の主要部を表わしたものである。消去手段6はセラミック基板61に発熱体62が設けられ上部が保護層63で覆われている。対向は回転ローラー(自動又は従動)から成るプラテンローラー71である。このプラテンローラーは加熱されていてもよい。   FIG. 8 shows a main part of a preferred reversible thermosensitive recording apparatus of the present invention. In the erasing means 6, a heating element 62 is provided on a ceramic substrate 61 and the upper part is covered with a protective layer 63. Opposing is a platen roller 71 composed of a rotating roller (automatic or driven). This platen roller may be heated.

次に、実施例をあげて本発明を具体的に説明する。ここでの“カール度”は、可逆性感熱記録媒体に画像を形成し、さらにこの画像を消去する操作を10回繰り返した後、20℃50%RHの雰囲気に1時間そのままの状態で放置し、最大のうき(x)を可逆性感熱記録媒体の進行方向と垂直になる側面の位置から観察し定規で測定した値をいう。   Next, the present invention will be specifically described with reference to examples. The “curl degree” here refers to forming an image on a reversible thermosensitive recording medium, and further erasing the image 10 times, and then leaving it in an atmosphere of 20 ° C. and 50% RH for 1 hour. The maximum swell (x) is a value measured with a ruler from the position of the side surface perpendicular to the traveling direction of the reversible thermosensitive recording medium.

実施例1
図6型の可逆性感熱記録媒体の磁気記録層付JISサイズのカード(8.6cm×5.4cm、厚み0.3mm)の記録領域(27.9cm2でカード全体の60%を占める)を、金属ブロックのホットスタンプで温度130〜140℃、1sec、荷重1200g〜1500gの条件で画像消去処理を行ったところ、図9(イ)のような変形になり、カール度(x)は3.5mmであった。
Example 1
A recording area (27.9 cm 2 occupies 60% of the entire card) of a JIS size card (8.6 cm × 5.4 cm, thickness 0.3 mm) with a magnetic recording layer of the reversible thermosensitive recording medium of FIG. When the image erasing process was performed under the conditions of a metal block hot stamping at a temperature of 130 to 140 ° C. for 1 sec and a load of 1200 g to 1500 g, the deformation was as shown in FIG. It was 5 mm.

実施例2
図5(a)型可逆性感熱記録カード(8.6cm×5.4cm、厚さ0.3mm)で記録領域の面積を23.2cm2(50%)にした以外は実施例1と同様にしたところ、図9(ロ)のような変形になり、カール度(x)は3.0mmであった。なお、ここでの画像消去は図5(a)の矢印方向にカードを移動させている。
Example 2
The same as in Example 1 except that the area of the recording area was changed to 23.2 cm 2 (50%) with the FIG. 5 (a) type reversible thermosensitive recording card (8.6 cm × 5.4 cm, thickness 0.3 mm). As a result, the deformation was as shown in FIG. 9B, and the curl degree (x) was 3.0 mm. In this case, the image is erased by moving the card in the direction of the arrow in FIG.

実施例3
図5(b)型可逆性感熱記録カード(8.6cm×5.4cm、厚さ0.3mm)で、記録領域の面積を23.2cm2(50%)にした以外は実施例1と同様にしたところ、図9(ハ)のような変形になり、カール度(x)は3.0mmであった。ここでの画像消去は図5(b)の矢印方向にカードを移動させている。
Example 3
Example 5 (b) type reversible thermosensitive recording card (8.6 cm × 5.4 cm, thickness 0.3 mm), except that the area of the recording area was set to 23.2 cm 2 (50%). As a result, the deformation was as shown in FIG. 9C, and the curl degree (x) was 3.0 mm. In this image erasing, the card is moved in the direction of the arrow in FIG.

実施例4
図6型可逆性感熱記録カード(8.6cm×5.4cm、厚さ0.3mm)で記録領域の面積27.9cm2(60%)にして実施例1と同様に画像消去した後、直ぐに金属プレートに接触させ冷却したところ、図9(ニ)のような変形になり、カール度(x)は3.0mmであった。
Example 4
Immediately after erasing the image in the same manner as in Example 1 with a recording area of 27.9 cm 2 (60%) using a 6-type reversible thermosensitive recording card (8.6 cm × 5.4 cm, thickness 0.3 mm), immediately When contacted with the metal plate and cooled, the deformation was as shown in FIG. 9 (d), and the curl degree (x) was 3.0 mm.

実施例5
実施例4と同じ可逆性感熱記録媒体をその消去範囲で図7R>7(b)に示したような、消去(加熱)バーと、受けとして加熱された裏面加熱バーとを併用した装置で画像消去したところ、図9(ホ)のような変形になり、カール度(x)は3mmであった。なお、消去バーの長さはカード巾の70%で、図示しない装置により、消去バーを加圧/解除の制御し、長手の70%あまりを消去した。
Example 5
An image of the same reversible thermosensitive recording medium as in Example 4 in an erasing range using an apparatus that uses an erasing (heating) bar and a backside heating bar heated as a receiver as shown in FIG. 7R> 7 (b). When deleted, the deformation was as shown in FIG. 9E, and the curl degree (x) was 3 mm. The length of the erasure bar was 70% of the card width, and the erasure bar was controlled to be pressed / released by a device (not shown) to erase about 70% of the length.

実施例6
図5(a)型可逆性感熱記録媒体(8.6cm×5.4cm、厚さ0.3mm)で、記録領域の面積が23.2cm2(50%)のもの、消去手段を図9の媒体進行方向接触巾2mmのセラミックヒーターを用い、荷重200g、長手方向で25%解除、50%消去、25%(長さ)と消去バーを制御し、記録画像を消去したところ、図9(ヘ)のような変形となり、カール度(x)は2.5mmであった。なお、消去はスピード30mm/sec、温度150〜160℃、処理長さ4.3cm(50%)である。
Example 6
FIG. 5A shows a reversible thermosensitive recording medium (8.6 cm × 5.4 cm, thickness 0.3 mm) having a recording area of 23.2 cm 2 (50%). When a ceramic heater having a contact width of 2 mm in the medium traveling direction was used to control the erase bar with a load of 200 g, 25% release in the longitudinal direction, 50% erase, and 25% (length), the recorded image was erased. ) And the degree of curl (x) was 2.5 mm. The erasing is performed at a speed of 30 mm / sec, a temperature of 150 to 160 ° C., and a processing length of 4.3 cm (50%).

実施例7
大日本インキ化学工業社製、DS−1731の磁気カードの反対面に、支持体を紙とし裏面に粘着層を有する図6R>6型の可逆性感熱記録媒体(8.6cm×5.4cm、厚さ0.3mm)をはりつけたもの(厚み500μm)を実施例6と同じように消去したところ、図9(ト)のような変形になり、カール度(x)は1.5mmであった。
Example 7
6R> 6 type reversible thermosensitive recording medium (8.6 cm × 5.4 cm, having a support on paper and an adhesive layer on the back side on the opposite side of a DS-1731 magnetic card manufactured by Dainippon Ink & Chemicals, Inc. When the material with a thickness of 0.3 mm was affixed (thickness: 500 μm) in the same manner as in Example 6, the deformation was as shown in FIG. 9 (G), and the curl degree (x) was 1.5 mm. .

比較例1
図4(b)型の可逆性感熱記録媒体(8.6cm×5.4cm、厚さ0.3mm)で、上部50%の記録領域と下部50%の非記録領域のものを実施例1の消去方式で記録領域の片面消去処理すると、図9(チ)のような変形になり、カール度(x)は5mmであった。
Comparative Example 1
The reversible thermosensitive recording medium of FIG. 4B type (8.6 cm × 5.4 cm, thickness 0.3 mm) having the upper 50% recording area and the lower 50% non-recording area as in Example 1. When the single-sided erasure processing of the recording area was performed by the erasing method, the deformation was as shown in FIG. 9 (h), and the curl degree (x) was 5 mm.

比較例2
全面が可逆性感熱記録層の記録媒体(8.6cm×5.4cm、厚さ0.3mm)に対し全面消去した後、実施例4と同様金属プレートで消去したところ、図9(リ)のような変形になり、カール度(x)は5.0mmであった。
Comparative Example 2
When the entire surface was erased from a recording medium having a reversible thermosensitive recording layer (8.6 cm × 5.4 cm, thickness 0.3 mm) and then erased with a metal plate in the same manner as in Example 4, the result shown in FIG. The curl degree (x) was 5.0 mm.

(a)(b)(c)は本発明の可逆性感熱記録媒体の三例の層構成を示した図である。(A) (b) (c) is a figure which showed the layer structure of three examples of the reversible thermosensitive recording medium of this invention. 記録層の発色・消色が行なわれることの説明図である。It is explanatory drawing that color development and erasing of a recording layer are performed. 消色手段が従来のポットスチンプを用いることの説明図である。It is explanatory drawing that a decoloring means uses the conventional pot stick. (a)(b)は従来の可逆性感熱記録媒体の二例の消色域、非消去域の位置関係を表わした図である。(A) and (b) are diagrams showing the positional relationship between the decoloring area and the non-erasing area of two examples of a conventional reversible thermosensitive recording medium. (a)(b)は本発明の可逆性感熱記録媒体の二例の消去域、非消去域の位置関係を表わした図である。(A) and (b) are diagrams showing the positional relationship between the erased area and the non-erased area of two examples of the reversible thermosensitive recording medium of the present invention. 本発明の他の可逆性感熱記録媒体の消去域、非消去域の位置関係を表わした図である。It is a figure showing the positional relationship of the erasure | elimination area | region of the other reversible thermosensitive recording medium of this invention, and a non-erasable area | region. (a)(b)(c)は画像消去する際、消去域を加熱するとともに媒体裏面も加熱することを表わした三例の図である。(A), (b), and (c) are three examples showing that when erasing an image, the erase area is heated and the back surface of the medium is also heated. 本発明の好ましい可逆性感熱記録装置の消去部の概略を示した図である。It is the figure which showed the outline of the erasing part of the preferable reversible thermosensitive recording apparatus of this invention. (イ)(ロ)(ハ)(ニ)(ホ)(ヘ)(ト)は実施例1〜7の可逆性感熱記録媒体のカールの様子を模式的に表わした図、(チ)(リ)は比較例1、2の可逆性感熱記録媒体のカールの様子を表わした図である。(A), (b), (c), (d), (e), (f), and (g) are diagrams schematically showing the curling state of the reversible thermosensitive recording media of Examples 1 to 7. ) Is a diagram showing the curl of the reversible thermosensitive recording media of Comparative Examples 1 and 2. FIG.

符号の説明Explanation of symbols

6 消去手段
11 可逆性感熱記録媒体(発色消色型記録媒体)
12 支持体
12’ 他の支持体
13 可逆性感熱記録層
14 透明保護層
15 磁気層
16 粘着層
51 消去手段(消去バー)
51’ 裏面加熱バー
52 押圧部材
53 弾性部材
54 加熱部材
61 セラミック基板
62 発熱体
63 保護層
71 プラテンローラー
100 消去域
101、102、103 非消去域
6 Erasing means 11 Reversible thermosensitive recording medium (color erasable recording medium)
DESCRIPTION OF SYMBOLS 12 Support body 12 'Other support bodies 13 Reversible thermosensitive recording layer 14 Transparent protective layer 15 Magnetic layer 16 Adhesive layer 51 Erasing means (erasing bar)
51 'Back surface heating bar 52 Pressing member 53 Elastic member 54 Heating member 61 Ceramic substrate 62 Heating element 63 Protective layer 71 Platen roller 100 Erase area 101, 102, 103 Non-erase area

Claims (8)

支持体の表面に、中央部に横方向又は縦方向の全巾の50%以下の巾で記録領域が形成され、その記録領域を挟むようにそれぞれが該全巾の25%以上の巾で二つの非記録領域が形成され、全体として正方形又は短形を呈してなり、かつ、該記録領域が電子供与性呈色性化合物と電子受容性化合物を主成分とし、加熱温度および/または加熱後の冷却速度の違いにより相対的に発色した状態と消色した状態を形成しうる可逆性熱発色組成物を含有する可逆性感熱記録層であることを特徴とする可逆性感熱記録媒体。   On the surface of the support, a recording area is formed in the central portion with a width of 50% or less of the total width in the horizontal direction or the vertical direction, and each has a width of 25% or more of the total width so as to sandwich the recording area. One non-recording area is formed, and the recording area has a square or short shape as a whole, and the recording area is mainly composed of an electron-donating color-forming compound and an electron-accepting compound, and is heated and / or after heating. A reversible thermosensitive recording layer comprising a reversible thermochromic composition capable of forming a relatively colored state and a decolored state due to a difference in cooling rate. 支持体の表面に、中心部に全面積の60%以下の面積で記録領域が形成され、その記録領域を囲むように非記録領域が形成され、全体として正方形又は短形を呈してなり、かつ、該記録領域が電子供与性呈色性化合物と電子受容性化合物を主成分とし、加熱温度および/または加熱後の冷却速度の違いにより相対的に発色した状態と消色した状態を形成しうる可逆性熱発色組成物を含有する可逆性感熱記録層であることを特徴とする可逆性感熱記録媒体。   On the surface of the support, a recording area is formed in the central portion with an area of 60% or less of the total area, a non-recording area is formed so as to surround the recording area, and the whole has a square or short shape, and The recording region is mainly composed of an electron-donating color-forming compound and an electron-accepting compound, and can form a relatively colored state and a decolored state depending on the heating temperature and / or the cooling rate after heating. A reversible thermosensitive recording medium comprising a reversible thermosensitive recording layer containing a reversible thermochromic composition. 支持体の裏面に粘着層が設けられることを特徴とする請求項1又は2記載の可逆性感熱記録媒体。   The reversible thermosensitive recording medium according to claim 1, wherein an adhesive layer is provided on the back surface of the support. 全体の形態がカード状であることを特徴とする請求項1〜3のいずれかに記載の可逆性感熱記録媒体。   The reversible thermosensitive recording medium according to any one of claims 1 to 3, wherein the entire form is card-like. 請求項1〜4のいずれかに記載の可逆性感熱記録媒体の記録領域に画像形成を行うための記録手段、および該記録領域に形成された画像を消去するための消去手段を備えたことを特徴とする可逆性感熱記録装置。   A recording means for forming an image on a recording area of the reversible thermosensitive recording medium according to any one of claims 1 to 4, and an erasing means for erasing an image formed in the recording area. A reversible thermosensitive recording device. 記録手段及び消去手段は、記録・消去時以外は可逆性感熱記録媒体と非接触又は非加圧接触状態にあり、記録・消去時に該可逆性感熱記録媒体の記録領域だけに加圧接触状態となることを特徴とする請求項5記載の可逆性感熱記録装置。   The recording means and the erasing means are in a non-contact or non-pressing contact state with the reversible thermosensitive recording medium except during recording / erasing, and only in a recording contact area of the reversible thermosensitive recording medium during recording / erasing. The reversible thermosensitive recording apparatus according to claim 5, wherein 画像の消去時、消去後又は消去と同時に可逆性感熱記録媒体の支持体裏面を加熱するための裏面加熱手段を備えたことを特徴とする請求項5又は6記載の可逆性感熱記録装置。   7. The reversible thermosensitive recording apparatus according to claim 5, further comprising a back surface heating means for heating the back surface of the support of the reversible thermosensitive recording medium at the time of erasing the image, after erasing or simultaneously with erasing. 記録又は消去により昇温された可逆性感熱記録媒体を冷却するための冷却手段を備えたことを特徴とする請求項5〜7のいずれかに記載の可逆性感熱記録装置。
The reversible thermosensitive recording apparatus according to any one of claims 5 to 7, further comprising a cooling means for cooling the reversible thermosensitive recording medium heated by recording or erasing.
JP2005175758A 2005-06-15 2005-06-15 Reversible thermal sensitive recording medium and reversible thermal sensitive recorder Pending JP2005343175A (en)

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