JP2005325309A - Conductive grease composition and rolling device - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a conductive grease composition which shows excellent conductivity and oil separation resistance even at high temperatures and scarcely leaks when used in a rolling device and to provide a rolling device which shows excellent conductivity even at high temperatures and scarcely undergoes leak of a grease composition. <P>SOLUTION: The conductive grease composition comprising a perfluoropolyether oil and two types of carbon blacks is packed into the cavity of a deep groove ball bearing. One type of the carbon blacks has a mean primary particle diameter of 30 nm, a specific surface area of 800 m<SP>2</SP>/g, and a DBP absorption of 360 ml/100 g, and the other type of the carbon blacks has a mean primary particle diameter of 66 nm, a specific surface area of 27 m<SP>2</SP>/g, and a DBP absorption of 68 ml/100 g. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

  The present invention relates to a grease composition and a rolling device excellent in conductivity.

  In general office equipment and information equipment such as a copying machine, a large number of rolling bearings are used for the movable parts. An oil film is formed between the raceway surfaces of the inner and outer rings of the rolling bearing and the rolling elements during rotation, and the raceway surfaces and the rolling elements are not in contact with each other. In such a rolling bearing, static electricity is generated along with the rotation, so that there are cases where the radiation noise has an adverse effect such as distortion on a copy image of the copying machine.

  In order to prevent such inconvenience, the inner and outer races and rolling elements are made conductive by encapsulating conductive grease inside the rolling bearing, and one of the inner and outer races is grounded. Therefore, a countermeasure is taken to remove static electricity from the rolling bearing. And as conductive grease, what added carbon black as a thickener and an electroconductivity imparting additive was the mainstream (for example, the thing of patent document 1).

  However, rolling bearings filled with such conductive grease initially show excellent conductivity (the inner and outer races and rolling elements are in a conductive state), but the conductivity decreases with time. As a result, there is a problem that the electrical resistance value between the inner and outer rings of the rolling bearing (hereinafter referred to as the bearing resistance value) may increase. And, as the cause of such a phenomenon, the following was considered.

  That is, the conductive grease is initially sufficiently present on the contact surface between the raceway surface of the bearing ring and the rolling element of the rolling bearing, and the carbon black in the conductive grease causes a gap between the raceway ring and the rolling element. Conductivity is ensured, but due to the relative movement between the race and rolling elements, the conductive grease is removed from the contact surface over time, and the chain structure of carbon black particles is destroyed. A phenomenon occurs in which the conductivity decreases and the bearing resistance value increases with time.

  Further, as described in Patent Document 2, when the rolling bearing is rotated for a long time, it is said that an oxide film generated on the raceway surface of the rolling bearing increases the electric resistance value between the inner and outer rings. ing. As a countermeasure, a method using an extreme pressure additive or an anti-wear agent to protect the rolling contact surface of a rolling bearing (see Patent Document 2), a method of blending inorganic compound fine particles (see Patent Document 3). There is. However, extreme pressure additives generally have little effect at high temperatures. Further, when inorganic compound fine particles are simply added, the grease often hardens or softens with time, and the oil separation degree is not stable over time.

Furthermore, the heat roller support part and the fixing part of office equipment such as a copying machine and a laser beam printer may have a high temperature of about 200 ° C. Therefore, the conductive grease used for the rolling bearing used in this part is not sufficient in heat resistance when a normal lubricating oil is used as a base oil, so it is difficult to ensure sufficient conductivity over a long period of time. there were.
Usually, examples of the lubricating oil used as the base oil of the conductive grease include mineral oil, poly α-olefin, ether oil, ester oil, etc., but the use limit temperature of these base oils is 160 ° C. at most. is there. Therefore, the conventional method of removing static electricity using a conductive brush is still used in the rolling bearings used in the high temperature part as described above.

  Further, Patent Document 4 discloses a conductive grease that has a relatively large amount of carbon black having a small amount of dibutyl phthalate absorption (hereinafter referred to as DBP absorption amount) to stabilize the conductivity over a long period of time. Has been described. In office equipment and information equipment, resin parts that are easily deteriorated by grease and oil are frequently used. Therefore, it is preferable that grease leakage and oil separation from the rolling bearing be as small as possible. Since conductive grease has a small DBP absorption amount of carbon black, which is also a thickener, there is a risk that the degree of oil separation will be high, particularly at high temperatures.

In addition, Patent Documents 5 and 6 describe conductive grease containing fluorine oil and carbon black as basic components in consideration of high-temperature durability, but when used in an oil separation degree or in a rolling bearing. There is room for improvement in the problem of grease leakage.
Japanese Patent Publication No. 63-24038 JP 2002-80879 A JP 2003-42166 A JP 2002-53890 A JP 2001-304276 A JP 2002-250353 A

  Therefore, the present invention solves the problems of the prior art as described above, exhibits excellent conductivity even at high temperatures, is difficult to oil-release, and leaks when used in rolling devices such as rolling bearings. It is an object of the present invention to provide a conductive grease composition that is difficult to resist. Another object of the present invention is to provide a rolling device and a deep groove ball bearing that exhibit excellent conductivity even at high temperatures and are less likely to cause leakage of the grease composition.

In order to solve the above problems, the present invention has the following configuration. That is, the conductive grease composition according to claim 1 of the present invention is a conductive grease composition containing a base oil and carbon black, wherein the base oil contains at least one of mineral oil and synthetic oil, Carbon black has an average primary particle size of 10 nm to 200 nm and a specific surface area of 20 m ² / g to 80 m ² / g, an average primary particle size of 10 nm to 200 nm and a specific surface area of 200 m. ² / g or more and 1500 m < ² > / g or less of second carbon black.

  With such a configuration, excellent conductivity is exhibited even at a high temperature, and oil separation is difficult even at a high temperature. Further, even when used in a rolling device such as a rolling bearing, it is difficult to leak from the rolling device to the outside. That is, excellent conductivity is imparted by the first carbon black, and oil separation is suppressed by the second carbon black. And by containing both carbon black, aggregation of carbon black is suppressed and moderate fluidity | liquidity is provided to a grease composition.

If the specific surface areas of both carbon blacks are within the above range, the above-described excellent effects can be obtained, but the specific surface area of the first carbon black is more preferably 23 m ² / g to 80 m ² / g. 23 m ² / g or more and 60 m ² / g or less is more preferable, and 27 m ² / g or more and 42 m ² / g or less is most preferable. Further, more preferably a specific surface area of the second carbon black is less than 250 meters ² / g or more 1000 m ² / g, more preferably at most 320 m ² / g or more ^{1000m 2 / g, 370m 2 /} g or more 800m Most preferably, it is ² / g or less. In addition, the numerical value of the specific surface area in this invention is a value measured by the nitrogen adsorption method.

  Further, when the average primary particle size is less than 10 nm, there is a high possibility that the carbon blacks aggregate, and when it exceeds 200 nm, the fluidity of the conductive grease composition may be hindered. In order to make such a problem less likely to occur, the average primary particle size of both carbon blacks is more preferably 10 nm or more and 100 nm or less, further preferably 10 nm or more and 80 nm or less, and 13 nm or more and 70 nm or less. Most preferably it is.

The conductive grease composition of claim 2 according to the present invention is the conductive grease composition of claim 1, wherein the DBP absorption amount of the first carbon black is 30 ml / 100 g or more and 160 ml / 100 g or less. The DBP absorption amount of the second carbon black is 80 ml / 100 g or more and 500 ml / 100 g or less.
When the DBP absorption amount of the first carbon black is less than 30 ml / 100 g, the dispersibility of the first carbon black in the conductive grease composition tends to be insufficient, and when it exceeds 160 ml / 100 g, the carbon blacks aggregate together. The effect of preventing is reduced. In order to make such a problem less likely to occur, the DBP absorption amount of the first carbon black is more preferably 50 ml / 100 g or more and 160 ml / 100 g or less, and preferably 60 ml / 100 g or more and 150 ml / 100 g or less. More preferably, it is 67 ml / 100 g or more and 140 ml / 100 g or less.

  Further, when the DBP absorption amount of the second carbon black is less than 80 ml / 100 g, leakage of the base oil or the like is likely to occur, and when it exceeds 500 ml / 100 g, the tendency of the carbon blacks to aggregate increases. In order to make such a problem less likely to occur, the DBP absorption amount of the second carbon black is more preferably 90 ml / 100 g or more and 450 ml / 100 g or less, and preferably 100 ml / 100 g or more and 400 ml / 100 g or less. More preferably, it is 140 ml / 100 g or more and 360 ml / 100 g or less.

Furthermore, the conductive grease composition according to claim 3 of the present invention is the conductive grease composition according to claim 1 or 2, wherein the synthetic oil has a kinematic viscosity at 40 ° C. of 10 mm ² / s or more. It is a fluorine oil of 500 mm ² / s or less.
Since fluorine oil is excellent in heat resistance, a conductive grease composition containing fluorine oil as a base oil exhibits better conductivity at high temperatures. Also, since fluorine oil has a small chemical attack on the resin, even if the conductive grease composition or base oil leaks from a rolling device such as a rolling bearing and comes into contact with surrounding resin parts, the resin parts deteriorate. Is unlikely to occur.

If the kinematic viscosity at 40 ° C. of the fluorine oil is less than 10 mm ² / s, the heat resistance may be insufficient, and if it exceeds 500 mm ² / s, the torque when used in a rolling device is excessive. There is a risk. When encapsulated in a rolling device used at a high temperature of about 200 ° C., the kinematic viscosity at 40 ° C. of fluorine oil is 200 mm ² / s or more and 450 mm ² / s due to the balance between torque performance and heat resistance. Or less, more preferably 250 mm ² / s or more and 400 mm ² / s or less, and most preferably 300 mm ² / s or more and 400 mm ² / s or less.

Furthermore, the conductive grease composition of Claim 4 which concerns on this invention is a conductive grease composition as described in any one of Claims 1-3, WHEREIN: Said 1st carbon black and said 2nd carbon black The mass ratio is 25:75 or more and 95: 5 or less, and the total content of the first carbon black and the second carbon black is 1.5 mass% or more and 20 mass% or less of the entire composition. It is characterized by that.
With such a configuration, the characteristics of both carbon blacks are balanced, and the conductivity and fluidity of the conductive grease composition are improved. Further, leakage from the rolling device and base oil separation are less likely to occur.

  When the proportion of the first carbon black in the total amount of the first carbon black and the second carbon black is less than 25% by mass (that is, the proportion of the second carbon black exceeds 75% by mass), the thickening effect by the carbon black is Since it increases, the total carbon black content can be reduced, but oil separation at high temperatures may increase. On the other hand, if the proportion of the second carbon black is less than 5% by mass (that is, the proportion of the first carbon black exceeds 95% by mass), the retention of the base oil becomes insufficient. There is a need to do more. Further, although the initial conductivity is good, there is a possibility that good conductivity cannot be maintained over a long period of time.

In order to make such a problem less likely to occur, the mass ratio of the first carbon black to the second carbon black is more preferably 50:50 or more and 95: 5 or less, and 75:25 or more and 90:10. More preferably, it is 75:25 or more and 88:12 or less.
Further, if the total content of the first carbon black and the second carbon black is less than 1.5% by mass of the entire conductive grease composition, the conductivity may be insufficient, and the base oil There is a possibility that the oil release of the oil cannot be sufficiently suppressed. On the other hand, if it exceeds 20% by mass, the fluidity of the conductive grease composition may be reduced.
In order to make such a problem less likely to occur, the total content of the first carbon black and the second carbon black is more preferably 3% by mass or more and 17% by mass or less of the entire conductive grease composition. Preferably, it is 5 mass% or more and 15 mass% or less, More preferably, it is 7 mass% or more and 13 mass% or less.

  Furthermore, the conductive grease composition of claim 5 according to the present invention is the conductive grease composition according to any one of claims 1 to 4, wherein the metal oxide has an average primary particle size of 5 nm to 10 μm. It is characterized by containing 0.05% by mass or more and 5% by mass or less of one or more powders among a material, metal nitride, metal carbide, clay mineral, cluster diamond, and fullerene.

  If it is such a structure, it can suppress that an oxide film produces | generates on the track surface and rolling element surface of a rolling device. If the average primary particle size of each powder is less than 5 nm, the effect of preventing the formation of an oxide film is insufficient, and if it exceeds 10 μm, it acts as a foreign substance when used in a rolling device such as a rolling bearing. There is a risk. In order to make such a problem less likely to occur, the average primary particle size is more preferably 5 nm or more and 2 μm or less, further preferably 10 nm or more and 500 nm or less, and most preferably 10 nm or more and 200 nm or less. .

  Further, if the content of the powder is less than 0.05% by mass of the entire conductive grease composition, the effect of preventing the formation of an oxide film is poor, and if it exceeds 5% by mass, the flow of the conductive grease composition There is a risk that the performance will deteriorate, or the raceway surface and the rolling element surface will be excessively scraped off. In order to make such a problem less likely to occur, the content of the powder is more preferably 0.05% by mass or more and 2% by mass or less of the entire conductive grease composition, and 0.1% by mass or more and 1% or less. The content is more preferably no greater than mass%, and most preferably no less than 0.1 mass% and no greater than 0.5 mass%.

  Furthermore, the conductive grease composition of Claim 6 which concerns on this invention is a conductive grease composition as described in any one of Claims 1-5, A fiber length is 5 nm or more and 10 micrometers or less, and an aspect-ratio is. One or more carbon nanotubes, carbon nanofibers, carbon nanohorns, carbon fibers, and metal oxide whiskers that are 5 or more and 1000 or less are contained in an amount of 0.05% by mass or more and 5% by mass or less of the entire composition. To do.

  The conductive grease composition containing such a fibrous material is more excellent in conductivity. If the fiber length of each of the above-mentioned fibrous materials is less than 5 nm, the effect of improving the conductivity is poor, and if it is more than 10 μm, it may act as a foreign substance when used in a rolling device such as a rolling bearing. is there. Further, if the content of the fibrous material is less than 0.05% by mass of the entire conductive grease composition, the effect of improving the conductivity is poor, and if it is more than 5% by mass, the flow of the conductive grease composition May decrease.

Furthermore, the conductive grease composition of Claim 7 which concerns on this invention is a conductive grease composition as described in any one of Claims 1-6, The miscibility is 200-300, It is characterized by the above-mentioned. And
If the penetration is less than 200, the conductive grease composition is hard and the fluidity is insufficient. If it exceeds 300, the conductive grease composition is soft and may leak from the rolling device. There is.

  A thickener may be added to adjust the blending degree. The type of thickener is not particularly limited, but a polytetrafluoroethylene resin (hereinafter referred to as PTFE resin) having an average primary particle size of 5 nm to 10 μm is preferable. When the average primary particle size is less than 5 nm, the effect of increasing is poor, and when it exceeds 10 μm, it may act as a foreign substance when used in a rolling device such as a rolling bearing.

The content of the PTFE resin is not particularly limited as long as the penetration degree of the conductive grease composition is 200 or more and 300 or less, but is preferably 1.5% by mass or more and 20% by mass or less. If it is less than 1.5% by mass, the thickening effect is poor, and if it exceeds 20% by mass, the fluidity of the conductive grease composition may be insufficient.
Furthermore, the conductive grease composition according to claim 8 of the present invention is the conductive grease composition according to any one of claims 1 to 7, wherein the conductive grease composition is for a rolling bearing.

  Furthermore, the rolling device according to claim 9 according to the present invention has an inner member having a raceway surface on the outer surface, and a raceway surface facing the raceway surface of the inner member, and is disposed outside the inner member. A gap formed between the inner member and the outer member, in a rolling device comprising: an outer member formed and a plurality of rolling elements arranged to roll between the raceway surfaces. The conductive grease composition according to any one of claims 1 to 7 is filled in the part.

  Furthermore, the deep groove ball bearing according to claim 10 according to the present invention is attached to any one of the inner ring, the outer ring, a plurality of balls rotatably arranged between the two wheels, and the both wheels. In a deep groove ball bearing comprising a seal or a shield interposed between the conductive grease composition according to any one of claims 1 to 8, in a gap formed between the wheels. It is characterized by filling 15% by volume or more and 35% by volume or less of the volume of the gap.

  The conductive grease composition as described above is suitable for a rolling device such as a rolling bearing, and particularly suitable for a deep groove ball bearing having a seal or a shield. The rolling device of the present invention is excellent in electrical conductivity, heat resistance, and durability, and is difficult to cause leakage of the grease composition. In the case of a deep groove ball bearing, the filling amount of the conductive grease composition is preferably 15% by volume or more and 35% by volume or less of the volume of the gap. If the amount is less than 15% by volume, the amount of the conductive grease composition may be too small to cause poor lubrication at an early stage. If the amount is more than 35% by volume, the conductive grease composition tends to leak.

  The present invention can be applied to various rolling devices. For example, a rolling bearing, a ball screw, a linear guide device, a linear motion bearing, and the like. Here, the inner member in the present invention refers to an inner ring when the rolling device is a rolling bearing, a screw shaft when the ball screw is also used, a guide rail when the linear guide device is used, and a linear bearing. In the case, each means an axis. The outer member is the outer ring when the rolling device is a rolling bearing, the nut when it is a ball screw, the slider when it is a linear guide device, and the outer cylinder when it is also a linear bearing. Each means.

  The conductive grease composition of the present invention exhibits excellent electrical conductivity even at high temperatures, is difficult to oil-release, and is difficult to leak when used in a rolling device such as a rolling bearing. In addition, the rolling device and the deep groove ball bearing of the present invention exhibit excellent conductivity even at high temperatures, and the grease composition is less likely to leak.

Embodiments of the present invention will be described in detail with reference to the drawings.
The deep groove ball bearing shown in FIG. 1 includes an inner ring 1, an outer ring 2, a plurality of balls 3 that are rotatably arranged between the inner ring 1 and the outer ring 2, and a plurality of balls 3 between the inner ring 1 and the outer ring 2. A retainer 4 to be retained, and shields 5 and 5 attached to inner peripheral surfaces of both end portions of the outer ring 2 are provided. The shield 5 is interposed between the inner ring 1 and the outer ring 2 and substantially covers the opening between the outer peripheral surface of the inner ring 1 and the inner peripheral surface of the outer ring 2. In addition, a gap formed between the inner ring 1 and the outer ring 2 is filled with a conductive grease composition 6 and sealed inside the deep groove ball bearing by a shield 5. The amount of the conductive grease composition 6 filled is 15 volume% or more and 35 volume% or less of the volume of the gap.

This conductive grease composition 6 comprises a base oil and two types of carbon black, and has a blending degree of 200 or more and 300 or less. If desired, various additives such as an oxide film formation inhibitor and a conductivity improver. May be contained.
Of the two types of carbon black, the first carbon black has an average primary particle size of 10 nm to 200 nm, a specific surface area of 20 m ² / g to 80 m ² / g, and a DBP absorption of 30 ml / 100 g to 160 ml / 100 g. The second carbon black has an average primary particle size of 10 nm to 200 nm, a specific surface area of 200 m ² / g to 1500 m ² / g, and a DBP absorption of 80 ml / 100 g to 500 ml / 100 g.

The mass ratio of the first carbon black and the second carbon black contained in the conductive grease composition 6 is 25:75 or more and 95: 5 or less, and the total of the first carbon black and the second carbon black is Content is 1.5 to 20 mass% of the whole conductive grease composition 6.
Such carbon black may be selected from various commercially available products based on the average primary particle size, specific surface area, and DBP absorption. For example, “Toka Black” series and “Seast” series manufactured by Tokai Carbon Co., Ltd., “Mitsubishi Carbon Black” series manufactured by Mitsubishi Chemical Corporation, “Denka Black” series manufactured by Denki Kagaku Kogyo Co., Ltd., Lion Akzo Corporation "Ketjen Black" series can be used. Also, so-called acetylene black, fly ash and the like can be used as long as properties such as average primary particle size and specific surface area are within the scope of the present invention.

  Specifically, as the first carbon black, Talker Black series # 7360SB, # 7350 / F, # 7270SB, # 7100F, # 7050, # 4500, # 4400, # 4300, # 3845, # 3800 or "Seast" series of seast 3, NH, N, 116HM, 116, FM, SO, V, SVH, FY, S, SP can be used. In addition, “Mitsubishi Carbon Black” series MA220, MA230, # 25, # 20, # 10, # 5, # 95, # 260, # 3030, # 3050, CF9 and “Denka Black” series Denka Black granular products , Powdery products, HS-100, etc. can be used.

Among these, Talker Black # 7050 (average primary particle size 66 nm, specific surface area 28 m ² / g, DBP absorption 66 ml / 100 g), Seast V (average primary particle size 62 nm, specific surface area 27 m ² / g, DBP absorption) 87 ml / 100 g), Siesto SVH (average primary particle size 62 nm, specific surface area 32 m ² / g, DBP absorption 140 ml / 100 g), Siesto S (average primary particle size 66 nm, specific surface area 27 m ² / g, DBP absorption 68 ml / 100 g), Denka Black HS-100 (average primary particle size 48 nm, specific surface area 39 m ² / g, DBP absorption 140 ml / 100 g) can be preferably used.

  Further, as the second carbon black, Talker Black # 8500 / F, # 8300 / F, # 5500, Mitsubishi Carbon Black # 2700, # 2650, # 2600, # 2400, # 2350, # 2300, # 2200, # 990, # 980, # 970, # 960, # 950, # 900, # 850, # 3230, Ketjen Black EC, etc. can be used.

Among these, Talker Black # 5500 (average primary particle size 25 nm, specific surface area 225 m ² / g, DBP absorption 155 ml / 100 g), Mitsubishi Carbon Black # 3230 (average primary particle size 23 nm, specific surface area 220 m ² / g, DBP absorption 140 ml / 100 g), Ketjen black EC (average primary particle size 30 nm, specific surface area 800 m ² / g, DBP absorption 360 ml / 100 g) can be preferably used.

  Moreover, as base oil, mineral oil and synthetic oil are suitable. Examples of the mineral oil include paraffinic mineral oil and naphthenic mineral oil, and examples of the synthetic oil include ester oil, ether oil, polyglycol oil, silicone oil, synthetic hydrocarbon oil, fluorosilicone oil, and fluorine oil. Among these, in view of high heat resistance and small chemical attack on the resin, fluorine oil and synthetic hydrocarbon oil are preferable, and in particular, perfluoropolyether oil, poly α-olefin oil (hereinafter referred to as PAO oil). ) Is preferred. In consideration of use at 200 ° C. or higher, perfluoropolyether oil is optimal.

Further, the oxide film formation inhibitor added to the conductive grease composition 6 as desired includes metal oxides, metal nitrides, metal carbides, clay minerals, cluster diamonds, having an average primary particle size of 5 nm to 10 μm. And one or more powders of fullerene are preferred. Specific examples include silica (silicon oxide), alumina (aluminum oxide), titanium oxide, zinc oxide, zirconium oxide, barium titanate, zirconium titanate, silicon nitride, zirconium nitride, chromium nitride, silicon carbide, titanium carbide, carbonized. tungsten, smectite, bentonite, boron nitride, carbon nitride, C ₆₀ fullerene, C ₇₂ fullerene, C ₈₄ fullerene, and the like. Among these, metal oxides such as magnesium oxide, zinc oxide and zirconium oxide are particularly suitable, and magnesium oxide is most suitable.

The addition amount of the oxide film formation inhibitor is preferably 0.05% by mass or more and 5% by mass or less of the entire conductive grease composition 6.
Furthermore, the conductivity improver optionally added to the conductive grease composition 6 includes carbon nanotubes, carbon nanofibers, carbon nanohorns having a fiber length of 5 nm to 10 μm and an aspect ratio of 5 to 1000, One or more of carbon fibers and metal oxide whiskers are preferred. Among these, carbon nanotubes are particularly suitable.

The addition amount of the conductivity improver is preferably 0.05% by mass or more and 5% by mass or less of the entire conductive grease composition 6.
In addition, this embodiment shows an example of this invention and this invention is not limited to this embodiment.
For example, a thickener may be added to the conductive grease composition 6 in order to adjust the blending degree. The type of thickener is not particularly limited, but the aforementioned PTFE resin is preferable.

Further, in the present embodiment, the deep groove ball bearing has been described as an example of the rolling device, but the type of the rolling bearing is not limited to the deep groove ball bearing, and the present invention is applicable to various types of rolling bearings. It can be applied to. For example, radial type rolling bearings such as angular contact ball bearings, self-aligning ball bearings, cylindrical roller bearings, tapered roller bearings, needle roller bearings, and self-aligning roller bearings, and thrust types such as thrust ball bearings and thrust roller bearings This is a rolling bearing.
Furthermore, the present invention can be applied not only to rolling bearings but also to various other types of rolling devices. For example, a ball screw, a linear guide device, a linear motion bearing, or the like.

A rolling test was performed on the rolling bearing encapsulating the conductive grease composition, and the bearing resistance value during rotation and the leakage amount of the conductive grease composition after 200 hours of rotation were measured. The test method will be described below.
A deep groove ball bearing was mounted on the apparatus as shown in FIG. 2 and the electrical resistance value (maximum value) between the rotating inner and outer rings was measured. In FIG. 2, reference numeral 11 denotes a deep groove ball bearing to be measured. The shaft member 12 attached to the inner ring 11 a is rotationally driven by a motor 13 to rotate the bearing 11. A predetermined constant voltage is applied by the constant voltage power supply 14 between the shaft member 12 and the outer ring 11b integrated with the inner ring 11a.

  The resistance measuring device 15 connected in parallel with the constant voltage power supply 14 outputs the measured voltage value (analog value) to the A / D conversion circuit 16. The A / D conversion circuit 16 converts it into a digital value at a preset sampling cycle, and outputs the converted digital signal to the arithmetic processing unit 17. In this embodiment, the sampling period is set to 50 kHz (sampling time interval = 0.02 ms).

  The arithmetic processing unit 17 includes a maximum resistance value calculating unit 17A, a threshold processing unit 17B, and a wave number counting unit 17C. The maximum resistance value calculation unit 17A calculates the maximum resistance value based on the input digital signal. The threshold processing unit 17B performs threshold processing on the input digital signal with a predetermined threshold to remove noise. The wave number counting unit 17C counts the number of fluctuations per predetermined time unit, that is, the wave number of the wave mountain, by the increase / decrease change of the pulse value over time, and the average value of the wave number per unit time. Ask for. Further, the arithmetic processing unit 17 outputs the obtained maximum resistance value and the average value of the wave number per unit time to the display unit 18. In this embodiment, the unit time for counting the wave number is set to 0.328 seconds. The display device 18 is composed of a display or the like, and displays the maximum resistance value obtained by the arithmetic processing device 17 and the average value of the wave number per unit time.

Next, a method for evaluating the bearing resistance value of the deep groove ball bearing 11 using the apparatus having the above configuration will be described.
A predetermined constant voltage is applied between the inner and outer rings 11 a and 11 b of the deep groove ball bearing 11 from the constant voltage power source 14 while the motor 13 is driven and the shaft member 12, that is, the inner ring 11 a is rotated at a predetermined rotational speed. At this time, a current flows between the inner and outer rings 11a and 11b, but the voltage fluctuates due to a spark or the like. The voltage is measured by the resistance measuring device 15, and then converted into a digital value by the A / D conversion circuit 16. Based on the digital signal, the arithmetic processing device 17 determines the maximum resistance value and the wave number per predetermined unit time. The obtained value is displayed on the display device 18.
The measurement conditions are shown below.
Rotational speed of the shaft member 12: 120 min ⁻¹
Radial load (Fr) applied to the bearing 11: 98 N
Applied voltage: 30V
Resistance: 300kΩ
Maximum current: 100 μA
Atmosphere temperature: 230 ° C

Several types of bearings with different types of the conductive grease composition to be sealed were prepared, and the bearing resistance value (maximum value) during rotation was measured for each bearing using the apparatus configured as described above. The bearing resistance value was measured after 200 hours and 400 hours after rotation. At the same time, the leakage amount of the conductive grease composition after 200 hours of rotation was measured by a mass method.
The used rolling bearing is a deep groove ball bearing (inner diameter: 30 mm, outer diameter: 42 mm, width: 7 mm) manufactured by Nippon Seiko Co., Ltd., having a nominal number of 6806ZZ. The conductive grease composition having the composition shown in FIG. The amount of the conductive grease composition filled is 25% by volume of the void volume.

Further, another type of bearing filled with a conductive grease composition having the composition shown in Tables 1 and 2 was prepared, a rotation test was performed, and the torque at that time was measured.
The used rolling bearing is a deep groove ball bearing manufactured by NSK Ltd. (inner diameter 8 mm, outer diameter 22 mm, width 7 mm), and a conductive grease composition is filled in a gap formed between the inner ring and the outer ring. It is. The amount of the conductive grease composition filled is 25% by volume of the void volume. Two such bearings were installed in a housing and rotated under the following conditions, and the torque of the housing at that time was measured with a tension gauge. The torque was measured at the time of start-up and at the time of rotation (when the torque became stable after 3 minutes from the start-up).
Rotational speed: 150 min ^-1
Axial load (Fa): 27.4N
Atmospheric temperature: Room temperature

  In Tables 1 and 2, the numerical value described in the column of each component such as carbon black is the mass ratio of each component when the entire conductive grease composition is 100. Moreover, although content of base oil is not described in Table 1, 2, it is the remainder which deducted content of each above-mentioned component from the whole conductive grease composition.

The base oil used in the conductive grease compositions of Examples 1 to 6 and Comparative Examples 1 to 4 is a perfluoropolyether oil having a kinematic viscosity at 40 ° C. of 390 mm ² / s. Carbon black A in Tables 1 and 2 is Ketjen Black EC (average primary particle size 30 nm, specific surface area 800 m ² / g, DBP absorption 360 ml / 100 g) manufactured by Lion Akzo. B is Denka Black HS-100 (average primary particle size 48 nm, specific surface area 39 m ² / g, DBP absorption 140 ml / 100 g) manufactured by Denki Kagaku Kogyo Co., Ltd., and carbon black C is Seest S manufactured by Tokai Carbon Co., Ltd. (Average primary particle size 66 nm, specific surface area 27 m ² / g, DBP absorption 68 ml / 100 g).

Furthermore, metal oxide (magnesium oxide fine particles having an average primary particle size of 50 nm) and synthetic mica were used as an oxide film formation inhibitor.
Tables 1 and 2 collectively show the measurement results of the bearing resistance value, the bearing torque, and the leakage amount of the conductive grease composition. In Tables 1 and 2, when the bearing resistance value is less than 10 kΩ, ◎, when it is 10 kΩ or more and less than 20 kΩ, ○, when it is 20 kΩ or more and less than 40 kΩ, Δ, or 40 kΩ or more. If there is, it is indicated by a cross. Further, when the leakage amount of the grease composition is less than 12% by mass of the filling amount, it is marked with ◯. It is indicated by a mark. Furthermore, the torque of the bearing is shown as a relative value when the torque during rotation of Comparative Example 1 is 1.

  As can be seen from Tables 1 and 2, the bearings of Examples 1 to 6 had lower torque than the bearings of Comparative Examples 2 to 4. It can be seen that when the total amount of the solid components (carbon black, oxide film formation inhibitor, and thickener) is large, the torque becomes high, and particularly when it exceeds 20% by mass, the torque becomes high (see the graph of FIG. 3). . Further, even at high temperatures, the bearing resistance value was small (excellent conductivity) and the amount of leakage of the conductive grease composition was small. Further, from the comparison between the bearing of Example 5 and the bearing of Comparative Example 2, even when the total content of carbon black is the same, the use of a combination of a plurality of types of carbon black as described above is more conductive. It can be seen that the amount of leakage of the conductive grease composition is small and the torque is low.

  Such a rolling bearing is suitable for supporting rotating parts such as an optical part, a paper feeding part, a developing part, a fixing part, and a paper discharging part in office equipment such as a copying machine and a printer. If the grease composition leaks from the rolling bearing for such an application, the leaked grease composition may contaminate the paper. However, as described above, the bearing of each example has a leakage amount of the conductive grease composition. Since there are few, it is hard to produce the above inconveniences.

  In addition, if the leaked grease adheres to the resin member used around the bearing in the office equipment, the resin member may be adversely affected. As described above, the bearing of each example has a conductive grease composition. Since the amount of leakage is small, the above-mentioned adverse effects are unlikely to occur. Even if the leaked conductive grease composition adheres to the resin member, the base oil of the conductive grease composition is a fluorine oil that does not adversely affect the resin (has a low chemical attack property). Since the degree of oil separation at a high temperature of the functional grease composition is low, the resin member is unlikely to be adversely affected.

  Among the rolling bearings for the above-mentioned applications, especially the rolling bearings used for the heat roller support part of the office equipment may have a high temperature of 200 ° C. or higher, so there is a large temperature difference between the operating time and the stopping time. For this reason, the change in viscosity of the base oil blended in the grease increases, and the oil may be released. However, the bearings of the respective examples have a small oil separation degree even at high temperatures, so that the above disadvantages are not likely to occur.

  Moreover, although it is requested | required that electroconductivity is maintained over a long period of time also under high temperature, since the electroconductivity under high temperature is excellent, it is suitable for a heat roller support part. Furthermore, in order to realize a smooth start of the heat roller, the rolling bearing used for the heat roller support portion needs to have a low torque. However, since the bearings of the respective embodiments have a low torque as described above, Suitable for roller support.

  In addition, as for oil separation degree, it is preferable that the measured value by the method (measurement conditions are 200 degreeC and 24 hours) prescribed | regulated to JISK22005.7 is 9 mass% or less. A plurality of types of carbon black are used, but it is preferable to select the type and blending ratio of the carbon black so that the DBP absorption amount as a whole of the carbon black is 10 ml / 100 g or more and 35 ml / 100 g or less.

  Next, the graph of FIG. 4 shows the relationship between the bearing resistance value and the leakage amount of the conductive grease composition and the amount of the conductive grease composition filled in the bearing (ratio to the volume of the gap). Show. The conductive grease composition used was that of Example 1 described above. In addition, the bearing resistance value and the leakage amount of the conductive grease composition in this graph are defined as 1 when the bearing resistance value and the leakage amount of the conductive grease composition are 25% by volume of the conductive grease composition. The relative values are shown respectively. From this graph, it can be seen that when the filling amount of the conductive grease composition is 15 volume% or more and 35 volume% or less, the conductivity of the bearing is excellent and the leakage amount of the conductive grease composition is small.

Next, another type of bearing filled with a conductive grease composition having the composition shown in Tables 1 and 2 was prepared, and a rotation test was performed to evaluate its seizure durability.
The used rolling bearing is a deep groove ball bearing having a nominal number of 6305 manufactured by NSK Ltd., and a conductive grease composition is filled in a gap formed between the inner ring and the outer ring. The amount of the conductive grease composition filled is 15% by volume of the void volume. Such a bearing was rotated under the following conditions, and the time until seizure occurred (seizure life) was measured. It was assumed that seizure occurred when the temperature of the bearing increased and the torque of the motor that rotationally drives the bearing (measured by the current value) occurred.
Rotational speed: 3000 min ^-1
Axial load (Fa): 1470N
Radial load (Fr): 98N
Atmospheric temperature: 150 ° C

  The results are shown in the graph of FIG. The seizure life in this graph is shown as a relative value when the seizure life of the bearing of Example 1 is 1. From this graph, it can be seen that when the total amount of solid components (carbon black, oxide film formation inhibitor, and thickener) is less than 3% by mass, the seizure life becomes insufficient. This is because the conductive grease composition leaks from the bearing because the amount of the solid component is small and the hardness of the conductive grease composition is insufficient. Moreover, also when the total amount of a solid component exceeds 25 mass%, the seizure life becomes insufficient. This is because the conductive grease composition becomes too hard.

  The present invention is applicable to, for example, high temperature portions (photosensitive drum (fixing portion), heat roller support portion, etc.) in office equipment and information equipment such as copying machines and laser beam printers.

It is a fragmentary longitudinal cross-section explaining the structure of the deep groove ball bearing which is one Embodiment of this invention. It is a schematic block diagram of the apparatus which measures the resistance value of a bearing. It is a graph which shows the relationship between the total amount of a solid component, and a bearing torque. It is a graph which shows the relationship between the filling amount of a conductive grease composition, a bearing resistance value, and the leakage amount of a conductive grease composition. It is a graph which shows the relationship between the total amount of a solid component, and a seizure lifetime.

Explanation of symbols

1 Inner ring 2 Outer ring 3 Ball 5 Shield 6 Conductive grease composition

Claims (10)

In the conductive grease composition containing the base oil and carbon black,
The base oil contains at least one of mineral oil and synthetic oil,
The carbon black has a primary carbon black having an average primary particle size of 10 nm to 200 nm and a specific surface area of 20 m ² / g to 80 m ² / g, an average primary particle size of 10 nm to 200 nm, and a specific surface area. 200 meters ² / g or more 1500 m ² / g and less second carbon black, the conductive grease composition characterized by containing a.   The DBP absorption amount of the first carbon black is 30 ml / 100 g or more and 160 ml / 100 g or less, and the DBP absorption amount of the second carbon black is 80 ml / 100 g or more and 500 ml / 100 g or less. The conductive grease composition as described. 3. The conductive grease composition according to claim 1, wherein the synthetic oil is a fluorine oil having a kinematic viscosity at 40 ° C. of 10 mm ² / s to 500 mm ² / s.   The mass ratio of the first carbon black and the second carbon black is 25:75 or more and 95: 5 or less, and the total content of the first carbon black and the second carbon black is the whole composition The conductive grease composition according to claim 1, wherein the conductive grease composition is 1.5% by mass or more and 20% by mass or less.   One or more powders of metal oxides, metal nitrides, metal carbides, clay minerals, cluster diamonds, and fullerenes having an average primary particle size of 5 nm or more and 10 μm or less are 0.05% by mass or more and 5% by mass of the entire composition. The conductive grease composition according to any one of claims 1 to 4, which is contained in an amount of not more than%.   One or more carbon nanotubes, carbon nanofibers, carbon nanohorns, carbon fibers, and metal oxide whiskers having a fiber length of 5 nm to 10 μm and an aspect ratio of 5 to 1000 are added to 0.05% of the total composition. The conductive grease composition according to claim 1, wherein the conductive grease composition is contained in an amount of 5% by mass or more and 5% by mass or less.   The conductive grease composition according to any one of claims 1 to 6, wherein the blending penetration is 200 or more and 300 or less.   It is an object for rolling bearings, The electrically conductive grease composition as described in any one of Claims 1-7 characterized by the above-mentioned.   An inner member having a raceway surface on the outer surface, an outer member having a raceway surface opposite to the raceway surface of the inner member and disposed outside the inner member, and rolling between the raceway surfaces In a rolling device provided with a plurality of rolling elements arranged freely, in a crevice formed between the inner member and the outer member, The rolling device according to any one of claims 1 to 7 A rolling device filled with the conductive grease composition. A deep groove ball comprising an inner ring, an outer ring, a plurality of balls arranged so as to be able to roll between the two wheels, and a seal or shield attached to one of the two wheels and interposed between the two wheels. In the bearing
Filling the gap formed between the two wheels with the conductive grease composition according to any one of claims 1 to 8 in an amount of 15% by volume to 35% by volume of the volume of the gap. A featured deep groove ball bearing.

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