JP2005307582A - Decorative sheet, method of producing the same, and floor material - Google Patents

Decorative sheet, method of producing the same, and floor material Download PDF

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JP2005307582A
JP2005307582A JP2004126500A JP2004126500A JP2005307582A JP 2005307582 A JP2005307582 A JP 2005307582A JP 2004126500 A JP2004126500 A JP 2004126500A JP 2004126500 A JP2004126500 A JP 2004126500A JP 2005307582 A JP2005307582 A JP 2005307582A
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pattern
groove
joint
grooves
decorative sheet
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JP4259388B2 (en
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Hiroshi Shibata
洋 柴田
Hajime Harima
一 播摩
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Toppan Inc
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Toppan Printing Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C5/00Processes for producing special ornamental bodies
    • B44C5/04Ornamental plaques, e.g. decorative panels, decorative veneers

Abstract

<P>PROBLEM TO BE SOLVED: To provide a decorative sheet which ensures sufficient decorative appearance of joint-like grooves, that is comparable to the decorative appearance of a conventional wooden flooring material, and is stably produceable, and to provide a method of producing the dressing sheet, and a floor material using the dressing sheet. <P>SOLUTION: The dressing sheet 1 is produced by forming patterned grooves inclusive of at least the joint-like grooves 126 in a longitudinal direction and a direction B orthogonal to the same, in a surface of a long sheet substrate 11, and filling a coloring agent 13 in the patterned grooves. Herein a depth of the joint-like grooves 12b in the longitudinal direction and the direction B orthogonal to the same is set to 50 to 80 μm, and an opening width of the same is set to 0.7 to 1.2 mm. Thus when the coloring agent 13 is filled in the patterned grooves in the longitudinal direction A according to a wiping method, the coloring agent 13 can be also sufficiently filled in the joint-like grooves 12b in the direction B orthogonal to the longitudinal direction. Further the joint-like grooves in the direction B have sufficient width, and therefore the entire patterned grooves stably exhibit sufficient decorative appearance as the joint-like grooves. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本発明は、住宅等の建築物における内装床材の表面化粧用として好適な化粧シートとその製造方法並びに当該化粧シートを用いた床材に関する。   The present invention relates to a decorative sheet suitable for surface decoration of interior flooring in a building such as a house, a manufacturing method thereof, and a flooring using the decorative sheet.

従来、住宅等の建築物における内装用の床材としては、合板等の下地基材の表面に突板を貼着し、その表面に木工機械により縦横に目地状の溝加工を施して、溝部を着色塗料により着色した後、全面に紫外線硬化型塗料等による表面保護層を形成してなる、いわゆる木質系フローリング材が最も一般的である。しかし、この床材は、突板が天然素材である為、1枚1枚の色のばらつきが大きく、壁や天井、家具等との色調の調和も困難であることなどの問題があった。   Conventionally, as a flooring material for interiors in a building such as a house, a veneer is pasted on the surface of a base material such as a plywood, and a groove is formed on the surface by jointing grooves vertically and horizontally by a woodworking machine. A so-called woody flooring material in which a surface protective layer is formed on the entire surface with an ultraviolet curable paint after coloring with a colored paint is most common. However, since this veneer is made of a natural material, there is a problem that the color variation of each sheet is large and it is difficult to harmonize the color with walls, ceilings, furniture, and the like.

所望の色調の床材を安定した品質で大量生産可能な方法として、予め合成樹脂フィルムに印刷等による絵柄を施してなる化粧シートを用意しておき、これを合板等の下地基材の表面に貼着する方法も提案されている(特許文献1)。化粧シートの貼着後、前記木質系フローリング材の目地を模した溝加工を施し、その溝に着色塗料による着色を施せば、木質系フローリング材に近似した意匠感を有する床材が得られる。但し、この方法では製造工程が煩雑で生産性も低い上、溝加工により形成した目地部に合板等の下地基材が露出するため、目地部の耐水性が劣る欠点がある。そこで、予め表面にエンボス加工やワイピング処理を施した化粧シート(特許文献2)を用意しておく方法も考えられ、この方法によれば、該化粧シートを下地基材の表面に貼着するだけで、木質系フローリング材に匹敵する優れた意匠を有し、目地部の耐水性にも優れた床材が、簡便に得られる利点がある。   As a method that enables mass production of floor materials of the desired color with stable quality, prepare a decorative sheet that has been printed in advance on a synthetic resin film, and place this on the surface of a base material such as plywood. A method of sticking has also been proposed (Patent Document 1). After sticking the decorative sheet, a groove material simulating the joint of the wooden flooring material is applied, and the groove is colored with a colored paint to obtain a flooring material having a design feeling similar to that of the wooden flooring material. However, this method has a drawback that the manufacturing process is complicated and productivity is low, and the base material such as plywood is exposed at the joint formed by grooving, so that the water resistance of the joint is inferior. Therefore, a method of preparing a decorative sheet (Patent Document 2) whose surface has been previously embossed or wiped is also conceivable. According to this method, the decorative sheet is simply adhered to the surface of the base substrate. Thus, there is an advantage that a flooring material having an excellent design comparable to a wooden flooring material and excellent in water resistance of joints can be easily obtained.

しかし、木質系フローリング材の目地は、長方形の床材の長手方向のみならず、長手方向と直交方向にも形成されるのが一般的であるが、これを模したエンボス・ワイピング化粧シートを作製しようとすると、ワイピング処理工程において、ワイピング処理方向(化粧シートの長手方向)と直交方向の目地状溝には、着色剤を良好な状態で充填することが難しく、目地部の意匠感が不十分となり易いという問題点があった。   However, joints of wooden flooring materials are generally formed not only in the longitudinal direction of the rectangular flooring but also in the direction orthogonal to the longitudinal direction, but embossed and wiping decorative sheets that mimic this are produced. In this case, in the wiping treatment step, it is difficult to fill the joint grooves in the direction perpendicular to the wiping treatment direction (longitudinal direction of the decorative sheet) in a good state, and the design feeling of the joints is insufficient. There was a problem that it was easy to become.

本発明者らはこの問題点を解決するために、先に特願2003−401183号にて従来の木質系フローリング材に匹敵する十分な目地状溝の意匠感を確保しつつ安定的に製造可能な化粧シートとその製造方法並びに該化粧シートを用いた床材として、長尺シート状基材の表面に、長手方向と直交方向の目地状溝を少なくとも含むパターン状溝が形成されており、該パターン状溝には着色剤が充填されてなる化粧シートであって、前記長手方向と直交方向の目地状溝は、深さが50〜80μm、開口幅が0.7〜1.2mmとした特許を出願した。   In order to solve this problem, the inventors of the present invention previously described in Japanese Patent Application No. 2003-401183 can be stably manufactured while ensuring a sufficient design feeling of jointed grooves comparable to conventional woody flooring materials. As a flooring material using the decorative sheet and its manufacturing method and the decorative sheet, a pattern-shaped groove including at least joint grooves in the direction perpendicular to the longitudinal direction is formed on the surface of the long sheet-like base material, Patent application title: Patterned groove is a decorative sheet filled with a colorant, and the joint groove in the direction perpendicular to the longitudinal direction has a depth of 50 to 80 μm and an opening width of 0.7 to 1.2 mm Filed.

しかしながら、この発明においては目地状溝の開口部の大きさに制約があり、ワイピングによりインキが掻き取られやすいので、開口部の大きさを小さくする必要があった。開口部を小さくすることでワイピングで掻き取られても残るようにはなるが、開口部を大きく(1.2mm以上)とするとインキが残らず、またインキが残ったとしても均一ではなかった。
実用新案登録第3051531号公報 特開平8−230113号公報
However, in the present invention, the size of the opening of the joint groove is limited, and the ink is easily scraped off by wiping. Therefore, it is necessary to reduce the size of the opening. By making the opening portion small, it remains even if it is scraped off by wiping. However, if the opening portion is made large (1.2 mm or more), ink does not remain, and even if ink remains, it is not uniform.
Utility Model Registration No. 3051531 JP-A-8-230113

本発明は、前記問題点を解決するためになされたものでありその課題とするところは、開口部が大きな場合でも安定してインキ残りがきれいな化粧シートを提供することにある。   The present invention has been made in order to solve the above-mentioned problems, and the object of the present invention is to provide a decorative sheet having a stable and clean ink residue even when the opening is large.

本発明はこの課題を解決するため、すなわち請求項1記載の発明は、長尺シート状基材の表面に、長手方向と直交方向の目地状溝を少なくとも含むパターン状溝が形成されており、該パターン状溝には着色剤が充填されてなる化粧シートであって、前記目地状溝の底部に5〜25μmの深さで微細な凹凸パターンが施され、パターン凹部の面積がパターン凸部の面積より広いことを特徴とする化粧シートである。   The present invention solves this problem, that is, the invention according to claim 1 is characterized in that a patterned groove including at least joint grooves in the direction perpendicular to the longitudinal direction is formed on the surface of the long sheet-like substrate, The pattern-like groove is a decorative sheet filled with a colorant, and a fine concavo-convex pattern is applied to the bottom of the joint-like groove at a depth of 5 to 25 μm, and the area of the pattern concave portion is the pattern convex portion. It is a decorative sheet characterized by being wider than the area.

また、請求項2記載の発明は、前記長手方向と直交方向の目地状溝は、深さが40〜80μm、開口幅が0.5〜3.0mmであることを特徴とする請求項1記載の化粧シートである。   The invention according to claim 2 is characterized in that the joint grooves in the direction perpendicular to the longitudinal direction have a depth of 40 to 80 μm and an opening width of 0.5 to 3.0 mm. This is a decorative sheet.

また、請求項3記載の発明は、長尺シート状基材の表面に、長手方向と直交方向に深さ40〜80μm、開口幅が0.5〜3.0mmの目地状溝を少なくとも含むパターン状溝を形成し、前記目地状溝の底部に5〜25μmの深さで微細な凹凸パターンを形成し、前記パターン状溝にワイピング法により着色剤を充填してなることを特徴とする化粧シートの製造方法である。   The invention according to claim 3 is a pattern including at least a joint groove having a depth of 40 to 80 μm and an opening width of 0.5 to 3.0 mm in the direction perpendicular to the longitudinal direction on the surface of the long sheet-like substrate. A decorative sheet comprising: a groove-like groove, a fine uneven pattern formed at a depth of 5 to 25 μm at the bottom of the joint-like groove, and the pattern-like groove filled with a colorant by a wiping method. It is a manufacturing method.

また、請求項4記載の発明は、前記長尺シート状基材は、少なくとも表面部に前記パターン状深さよりも厚い熱可塑性樹脂層を備えてなり、前記パターン状溝は、該熱可塑性樹脂層の溶融押出成形時に、溶融状態の熱可塑性樹脂層の片面に冷却エンボスロールを押し当てることにより形成することを特徴とする請求項3記載の化粧シートの製造方法である。   According to a fourth aspect of the present invention, the long sheet-like base material includes a thermoplastic resin layer that is thicker than the pattern-like depth on at least a surface portion, and the pattern-like groove includes the thermoplastic resin layer. 4. The decorative sheet manufacturing method according to claim 3, wherein a cooling embossing roll is pressed against one surface of the molten thermoplastic resin layer during the melt extrusion molding.

また、請求項5記載の発明は、請求項1〜4記載の前記化粧シートを下地基材に貼り合わせてなることを特徴とする床材である。   The invention according to claim 5 is a flooring material, wherein the decorative sheet according to claims 1 to 4 is bonded to a base substrate.

本発明の請求項1記載の発明によれば、目地状溝底部に微細な凹凸パターンを設けることにより、ワイピング法による着色剤充填後のブレードの侵入による着色剤の掻き出し量を抑え、十分な濃度の着色を確保して、長手方向と直交方向Bの目地状溝にも目地としての十分な意匠感を備えた化粧シートの提供が可能となる。   According to the invention of claim 1 of the present invention, by providing a fine uneven pattern at the bottom of the joint groove, the amount of colorant scraped by the penetration of the blade after filling with the colorant by the wiping method is suppressed, and a sufficient concentration It is possible to provide a decorative sheet having sufficient design feeling as a joint in the joint groove in the direction B perpendicular to the longitudinal direction.

本発明の請求項2記載の発明によれば、長手方向と直交方向Bの目地状溝12aの深さを50〜80μmとし、且つ開口幅を0.7〜1.2mmとすることによって、目地として認識されるに十分な幅を確保することが可能となる。   According to the invention described in claim 2 of the present invention, the joint groove 12a in the direction B perpendicular to the longitudinal direction has a depth of 50 to 80 μm and an opening width of 0.7 to 1.2 mm. It is possible to ensure a sufficient width to be recognized as.

本発明の請求項3記載の発明によれば、ワイピング法により着色剤を充填してなることにより、着色剤が満遍なく必要な箇所に侵入し、不要な箇所は掻き出されるため、目地としての意匠をはっきり表現することが可能となる。   According to the invention described in claim 3 of the present invention, the colorant is filled by the wiping method, so that the colorant uniformly intrudes into necessary portions and unnecessary portions are scraped out. Can be expressed clearly.

本発明の請求項4記載の発明によれば、少なくとも表面部に前記パターン状深さよりも厚い熱可塑性樹脂層を備えることにより、パターン溝の加工による凹凸が裏抜けすることがなく、長尺シートの裏面への凹凸発生が抑えられ、ワイピング加工時の掻き取りムラや掻き残し等の問題を回避することが可能となる。   According to the invention of claim 4 of the present invention, at least the surface portion is provided with the thermoplastic resin layer thicker than the pattern-like depth, so that the unevenness due to the processing of the pattern groove does not pass through, and the long sheet Occurrence of unevenness on the back surface of the sheet can be suppressed, and problems such as scraping unevenness and unremaining scraping during wiping can be avoided.

本発明の請求項5記載の発明によれば、目地状溝内を十分に着色可能であり、しかも目地状溝として認識されるに十分な開口幅を有しているので、従来の木質系フローリング材に匹敵する目地状溝の意匠感を有する床材を容易にかつ安価で得ることが可能となる。   According to the invention described in claim 5 of the present invention, the interior of the joint groove can be sufficiently colored, and has a sufficient opening width to be recognized as the joint groove, so that the conventional woody flooring It becomes possible to easily and inexpensively obtain a flooring material having a design feeling of joint grooves that is comparable to the material.

図1に本発明の化粧シートの一実施例の外観の構造を示す。図2に本発明の床材の一実施例の断面の構造を示す。化粧シート1の長手方向をA、長手方向と直交方向をB
とする。パターン状溝12は少なくともBの方向の目地状溝12bを有するものであり、この底部に微細なパターン4が設けられてなり、着色剤13が充填されてなる。
FIG. 1 shows an external structure of an embodiment of the decorative sheet of the present invention. FIG. 2 shows a cross-sectional structure of one embodiment of the flooring of the present invention. The longitudinal direction of the decorative sheet 1 is A, and the longitudinal direction and the orthogonal direction are B
And The pattern-like groove 12 has at least joint-like grooves 12b in the direction B, and a fine pattern 4 is provided at the bottom of the pattern-like groove 12 and is filled with a colorant 13.

本発明の化粧シート1における長尺シート状基材11は、表面にパターン状溝12の形成が可能な長尺シート体であれば、任意の素材からなるものが使用可能である。例えば、紙、合成樹脂フィルム、金属箔等、或いはそれらの積層体等である。パターン状溝12の形成は、通例、エンボス加工法によって行われるので、長尺シート状基材11の少なくとも表面部は、エンボス加工適性に優れた熱可塑性樹脂層からなっていることが好ましい。   The long sheet-like base material 11 in the decorative sheet 1 of the present invention can be made of any material as long as it is a long sheet body capable of forming the patterned groove 12 on the surface. For example, it is paper, a synthetic resin film, a metal foil, or a laminate thereof. Since the formation of the pattern-like grooves 12 is usually performed by an embossing method, it is preferable that at least the surface portion of the long sheet-like base material 11 is made of a thermoplastic resin layer excellent in embossing suitability.

長尺シート状基材11の表面には、長手方向と直交方向Bの目地状溝12bを少なくとも含むパターン状溝12が形成される。但し、ここで言う長手方向と直交方向Bとは、長尺シート状基材11の長手方向Aに対して正確に90度の方向である必要は必ずしもなく、見た目が大体直交方向と感じられる角度であれば意匠上は許容され、数度程度の誤差があっても良い。また、長手方向と直交方向Bの目地状溝12bは、長尺シート状基材11の全幅に及ぶ長さのものであっても良いが、図1に示す様に、全幅の一部分に相当する長さのものであっても良く、両者が混在していても良い。   On the surface of the long sheet-like base material 11, pattern-like grooves 12 including at least joint-like grooves 12 b in the direction B perpendicular to the longitudinal direction are formed. However, the longitudinal direction and the orthogonal direction B referred to here do not necessarily need to be exactly 90 degrees with respect to the longitudinal direction A of the long sheet-like base material 11, and the angle at which the appearance is generally perceived as the orthogonal direction. If so, the design is allowed and there may be an error of about several degrees. Further, the joint grooves 12b in the direction B perpendicular to the longitudinal direction may have a length extending over the entire width of the long sheet-like substrate 11, but correspond to a part of the entire width as shown in FIG. The thing of length may be sufficient and both may be mixed.

パターン状溝12としては、長手方向と直交方向Bの目地状溝12bのほか、長手方向Aの目地状溝12aを設けることもできる。一般的には、従来の木質系フローリング材の意匠を模して、図1に示す様に、長手方向Aに連続した目地状溝12aが所定幅で複数条設けられ、その相互間に、隣接する長手方向Aの目地状溝12aを結ぶ長手方向と直交方向Bの目地状溝12bが、互い違いの位置関係で多数設けられる場合が多い。これらの目地状溝12a、12bの断面形状は、例えばV字状、U字状、R面状等任意である。   As the pattern-like grooves 12, joint grooves 12a in the longitudinal direction A can be provided in addition to joint grooves 12b in the direction B perpendicular to the longitudinal direction. In general, imitating the design of a conventional woody flooring material, as shown in FIG. 1, a plurality of joint-like grooves 12a continuous in the longitudinal direction A are provided with a predetermined width and adjacent to each other. In many cases, a large number of joint grooves 12b in the direction B perpendicular to the longitudinal direction connecting the joint grooves 12a in the longitudinal direction A are provided in an alternating positional relationship. The cross-sectional shape of these joint grooves 12a and 12b is arbitrary, for example, V-shaped, U-shaped, R-shaped.

本発明においては、長手方向と直交方向Bの目地状溝12bの底面に、目地状溝12a、12bよりも微細な凹凸パターン15を形成してなる。これは図3に示すような格子状でも万線状でもよく、凹部の面積が凸部の面積より大きければよい。   In the present invention, an uneven pattern 15 finer than the joint grooves 12a and 12b is formed on the bottom surface of the joint grooves 12b in the direction B perpendicular to the longitudinal direction. This may be in the form of a grid or a line as shown in FIG.

この凹凸パターン15の凹部の内部には、着色剤13が充填されて着色される。この着色剤13の充填方法としては、凸条ロールを用いたロール塗装法やインクジェット法なども考えられるが、任意のパターン状溝12に対応可能で作業も簡便な方法として、長尺シート状基材の表面全面に着色剤13を塗布した後、パターン状溝12以外の凸部表面上の着色剤13をブレードで掻き取って除去する、いわゆるワイピング法によることが好ましい。   The concave portion of the concave / convex pattern 15 is filled with a colorant 13 and colored. As a filling method of the colorant 13, a roll coating method using a ridge roll, an ink jet method, or the like is conceivable. It is preferable to use a so-called wiping method in which after the colorant 13 is applied to the entire surface of the material, the colorant 13 on the surface of the convex portion other than the pattern-like grooves 12 is removed by scraping with a blade.

このワイピング法において問題となるのが、長尺シート状基材11の長手方向と直交方向Bの目地状溝12bである。すなわち、ワイピング法における過剰な着色剤13の除去のためのブレードは、長尺シート状基材11に対して相対的にその長手方向Aに走行するので、長手方向と直交方向Bの目地状溝12bがあると、ブレードがこの目地状溝12bの内部に侵入し、そこに塗布された着色剤13を掻き出してしまうため、目地状溝12bの内部に十分に着色剤13を充填することができない場合がある。目地状溝12bの幅を極く狭くすれば、ブレードの侵入は防止できるが、目地としての意匠感が出なくなってしまう。   A problem in this wiping method is the joint groove 12b in the direction B perpendicular to the longitudinal direction of the long sheet-like substrate 11. That is, since the blade for removing the excessive colorant 13 in the wiping method runs in the longitudinal direction A relative to the long sheet-like base material 11, the joint grooves in the direction B perpendicular to the longitudinal direction. If there is 12b, the blade enters the joint groove 12b and scrapes the colorant 13 applied thereto, so that the joint 13 cannot be sufficiently filled with the colorant 13. There is a case. If the width of the joint groove 12b is extremely narrow, the blade can be prevented from entering, but the design feeling as a joint cannot be obtained.

そこで、本発明者らが鋭意検討した結果、前記目地状溝底部に微細な凹凸パターンを設けることにより、ワイピング法による着色剤充填後のブレードの侵入による着色剤の掻き出し量を抑え、十分な濃度の着色を確保して、長手方向と直交方向Bの目地状溝にも目地としての十分な意匠感を備えた化粧シートの提供が可能となる。   Therefore, as a result of intensive studies by the present inventors, by providing a fine uneven pattern at the bottom of the joint groove, the amount of colorant scraped by the penetration of the blade after filling the colorant by the wiping method is suppressed, and a sufficient concentration It is possible to provide a decorative sheet having sufficient design feeling as a joint in the joint groove in the direction B perpendicular to the longitudinal direction.

長尺シート状基材11の表面部を構成する熱可塑性樹脂層は、少なくとも上記パターン状溝12の深さ(最大深さ)よりも厚く設けることが好ましい。そうでないと、パターン状溝12のエンボス加工による凹凸が裏抜けして、長尺シート状基材11の裏面に凹凸が発生する結果、ワイピング加工時の掻き取りムラや掻き残し等の原因となる場合があるからである。   The thermoplastic resin layer constituting the surface portion of the long sheet-like substrate 11 is preferably provided at least thicker than the depth (maximum depth) of the patterned groove 12. Otherwise, the unevenness due to the embossing of the pattern-like groove 12 is exposed, and the unevenness is generated on the back surface of the long sheet-like base material 11, resulting in scraping unevenness or unscratch left during the wiping process. Because there are cases.

上記熱可塑性樹脂層にパターン状溝12を形成する方法としては、既にフィルムないしシート状に成形され冷却固化された熱可塑性樹脂層に対して熱圧エンボス加工を施す方法もある。しかし、この方法によると、エンボス版の凸部が樹脂層中に押し込まれた際に、該凸部の両側に樹脂が押しやられることにより、パターン状溝12の輪郭部に盛り上がり部が発生し易く、この盛り上がり部が後述するワイピング加工の際に着色剤13の掻き残しの原因となり易い。   As a method of forming the pattern-like grooves 12 in the thermoplastic resin layer, there is a method in which hot-press embossing is performed on the thermoplastic resin layer that has already been formed into a film or a sheet and cooled and solidified. However, according to this method, when the convex portion of the embossed plate is pushed into the resin layer, the resin is pushed on both sides of the convex portion, so that a raised portion is likely to occur in the contour portion of the pattern-like groove 12. The raised portion is liable to cause scraping of the colorant 13 during the wiping process described later.

特に、パターン状溝12が長尺シート状基材11の長手方向と直交方向Bの目地状溝12bを含む場合には、目地状溝12bの下流側輪郭部の盛り上がり部によってブレードが跳ね上がり、該盛り上がり部の下流側にパターン状溝12と平行な線状に掻き残しが発生する場合が多い。この掻き残しを解消するために、ブレードの押圧力を増すと、目地状溝12bの内部へのブレードの侵入量が増して、着色剤13の充填不足を招く結果となり易い。   In particular, when the pattern-like groove 12 includes the joint groove 12b in the direction B orthogonal to the longitudinal direction of the long sheet-like base material 11, the blade jumps up by the raised portion of the downstream contour portion of the joint groove 12b, In many cases, scrapes are left in a line parallel to the pattern-like groove 12 on the downstream side of the raised portion. When the pressing force of the blade is increased in order to eliminate this scraping, the amount of the blade entering the joint groove 12b is increased, which tends to result in insufficient filling of the colorant 13.

この問題を解決するためには、既にフィルムないしシート状に成形された熱可塑性樹脂層を使用する代わりに、該熱可塑性樹脂層の溶融押出成形時に、溶融状態の熱可塑性樹脂層の片面に冷却エンボスロールを押し当てることによりエンボス加工を行う、溶融押出同時エンボス加工法によることが最も好ましい。この方法によれば、いわば樹脂を溶融状態で型に流し込むのと同様の成形方法であるから、その表面形状はエンボス版の表面形状が忠実に再現されたものとなり、パターン状溝12の輪郭部に盛り上がり部が形成されることがないので、上記した様な掻き残し問題を発生することがない。   In order to solve this problem, instead of using a thermoplastic resin layer already formed into a film or sheet, at the time of melt extrusion molding of the thermoplastic resin layer, cooling is performed on one side of the molten thermoplastic resin layer. It is most preferable to use a melt extrusion simultaneous embossing method in which embossing is performed by pressing an embossing roll. According to this method, since it is a molding method similar to pouring the resin into the mold in a molten state, the surface shape is a faithful reproduction of the surface shape of the embossed plate, and the contour portion of the pattern-like groove 12 As a result, no swelled portion is formed, so that the above-mentioned problem of unscratching remains.

また、上記溶融押出同時エンボス加工法によれば、エンボス加工による凹凸形状が熱可塑性樹脂層の裏面に現れる裏抜け現象も殆ど発生せず、裏面の平滑な長尺シート状基材11が得られるので、長尺シート状基材11の裏面の凹凸に起因するワイピング加工時の掻き取りムラや掻き残し等の防止にも有効である。   In addition, according to the melt extrusion simultaneous embossing method, the back and forth phenomenon in which the uneven shape by the embossing appears on the back surface of the thermoplastic resin layer hardly occurs, and the long sheet-like substrate 11 having a smooth back surface is obtained. Therefore, it is also effective for preventing unevenness of scraping or unscratch remaining during wiping processing due to the unevenness of the back surface of the long sheet-like base material 11.

図2に示した例では、長尺シート状基材11は、表面側から順に、透明熱可塑性樹脂層11a、接着性樹脂層12b、アンカー剤層11c、絵柄層11d、着色熱可塑性樹脂層11e、易接着層11fから構成されている。この長尺シート状基材11は、着色熱可塑性樹脂層11eの表面に絵柄層11dを印刷し、さらにアンカー剤層11cを塗布し、該アンカー剤層11c面に、接着性樹脂層12b及び透明熱可塑性樹脂層11aを溶融押出積層し、該透明熱可塑性樹脂層11aの表面にパターン状溝12のエンボス加工を施して得ることができる。このパターン状溝12に着色剤13が充填され、さらに全面に表面保護層14が形成されて、化粧シート1が構成されている。   In the example shown in FIG. 2, the long sheet-like base material 11 includes, in order from the surface side, a transparent thermoplastic resin layer 11a, an adhesive resin layer 12b, an anchor agent layer 11c, a picture layer 11d, and a colored thermoplastic resin layer 11e. It is composed of an easily adhesive layer 11f. This long sheet-like base material 11 has a pattern layer 11d printed on the surface of the colored thermoplastic resin layer 11e, and further applied with an anchor agent layer 11c. On the surface of the anchor agent layer 11c, an adhesive resin layer 12b and a transparent It can be obtained by melt extrusion laminating the thermoplastic resin layer 11a and embossing the patterned grooves 12 on the surface of the transparent thermoplastic resin layer 11a. The decorative groove 1 is configured by filling the pattern-like grooves 12 with a colorant 13 and further forming a surface protective layer 14 on the entire surface.

透明熱可塑性樹脂層11a及び着色熱可塑性樹脂層11eに使用する熱可塑性樹脂としては、ポリオレフィン系樹脂、ポリエステル系樹脂、アクリル系樹脂、スチレン系樹脂、ビニル系樹脂、ポリアミド系樹脂等や、これらの混合物、共重合体、積層体等を任意に使用することができる。さらに必要に応じて、着色剤、充填剤、紫外線吸収剤、光安定剤、熱安定剤等の各種の添加剤が添加されていてもよい。着色熱可塑性樹脂層11eの厚みは50〜150μm程度、透明熱可塑性樹脂層11aの厚み(但し、接着性樹脂層12bを共押出する場合はその厚みとの合計厚みとして)は80〜120μm程度とすることが好ましい。   Examples of the thermoplastic resin used in the transparent thermoplastic resin layer 11a and the colored thermoplastic resin layer 11e include polyolefin resins, polyester resins, acrylic resins, styrene resins, vinyl resins, polyamide resins, and the like. Mixtures, copolymers, laminates and the like can be arbitrarily used. Furthermore, various additives such as a colorant, a filler, an ultraviolet absorber, a light stabilizer, and a heat stabilizer may be added as necessary. The thickness of the colored thermoplastic resin layer 11e is about 50 to 150 μm, and the thickness of the transparent thermoplastic resin layer 11a (however, when the adhesive resin layer 12b is coextruded is about 80 to 120 μm). It is preferable to do.

絵柄層11dは、有機又は無機の着色顔料を樹脂バインダー中に分散してなる公知の印刷インキを使用して、例えばグラビア印刷法、オフセット印刷法、スクリーン印刷法等の公知の印刷方法で形成すればよい。絵柄の種類にも制限はなく、例えば木目柄、石目柄、抽象柄等、所望により任意である。   The pattern layer 11d is formed by a known printing method such as a gravure printing method, an offset printing method, or a screen printing method using a known printing ink in which an organic or inorganic coloring pigment is dispersed in a resin binder. That's fine. There is no limitation on the type of the picture pattern, and for example, a wood grain pattern, a stone pattern, an abstract pattern, and the like can be arbitrarily selected.

アンカー剤層11cは、ポリエステルポリオール、ポリエーテルポリオール、アクリルポリオール等のポリオール系樹脂と、イソシアネート系硬化剤とからなる2液硬化型ウレタン系樹脂等を主成分とするアンカー剤を、乾燥後の厚み1〜5μm程度に塗布して形成することができる。   The anchor agent layer 11c has a thickness after drying an anchor agent mainly composed of a two-component curable urethane resin composed of a polyol resin such as polyester polyol, polyether polyol, and acrylic polyol and an isocyanate curing agent. It can be formed by coating to about 1 to 5 μm.

接着性樹脂層11bは、透明熱可塑性樹脂層11aを溶融押出積層法により着色熱可塑性樹脂層11e上に積層する際に、層間密着強度を向上させるために、透明熱可塑性樹脂層11aとの共押出により積層を行うものであり、マレイン酸等の不飽和カルボン酸をグラフト共重合したポリエチレン又はポリプロピレン等の酸変性ポリオレフィン系樹脂等を好ましく使用することができる。厚みは通例、10〜50μm程度である。   The adhesive resin layer 11b is used together with the transparent thermoplastic resin layer 11a in order to improve the interlayer adhesion strength when the transparent thermoplastic resin layer 11a is laminated on the colored thermoplastic resin layer 11e by the melt extrusion lamination method. Lamination is performed by extrusion, and an acid-modified polyolefin resin such as polyethylene or polypropylene obtained by graft copolymerization with an unsaturated carboxylic acid such as maleic acid can be preferably used. The thickness is usually about 10 to 50 μm.

易接着層11fは、後述する下地基材2との貼り合わせの際に、貼り合わせ用の汎用接着剤3との接着性を向上させるためのもので、例えばウレタン系樹脂、エチレン−酢酸ビニル共重合体系樹脂、塩素化ポリオレフィン系樹脂、アクリル系樹脂等を主成分とし、必要に応じてブロッキング防止のためのシリカ粉末等の添加剤が添加されたプライマー剤を使用することができる。厚みは通例、0.5〜5μm程度である。   The easy-adhesion layer 11f is for improving adhesiveness with the general-purpose adhesive 3 for bonding at the time of bonding to the base material 2 to be described later. For example, the urethane-based resin and the ethylene-vinyl acetate copolymer are used. It is possible to use a primer agent mainly composed of a polymer resin, a chlorinated polyolefin resin, an acrylic resin, etc., and an additive such as silica powder for preventing blocking as required. The thickness is usually about 0.5 to 5 μm.

パターン状溝12に充填する着色剤13は、絵柄層11dに使用する印刷インキと同様、有機又は無機の着色顔料を樹脂バインダー中に分散してなる塗料を使用することができるが、耐久性の面からは硬化型樹脂系のものを使用することが好ましく、例えば1液硬化型又は2液硬化型のウレタン系樹脂をバインダーとする塗料等を使用することが好ましい。   As the colorant 13 to be filled in the pattern-like groove 12, a paint obtained by dispersing an organic or inorganic color pigment in a resin binder can be used as in the printing ink used for the picture layer 11d. From the surface, it is preferable to use a curable resin-based material, for example, it is preferable to use a paint or the like having a one-component or two-component curable urethane resin as a binder.

表面保護層14は、化粧シート1の表面に耐摩耗性、耐傷性、耐溶剤性、耐候性等の表面物性を付与するためのものであるから、硬化型樹脂を使用することが好ましく、例えば2液硬化型ウレタン系樹脂や、自己架橋型アクリル系樹脂、メラミン系樹脂、エポキシ系樹脂、アミノアルキド系樹脂等の熱硬化型樹脂や、(メタ)アクリレート系、エポキシ系、ポリエステル系等の紫外線又は電子線の照射により硬化する電離放射線硬化型樹脂等を使用することが好ましい。   Since the surface protective layer 14 is for imparting surface properties such as abrasion resistance, scratch resistance, solvent resistance, and weather resistance to the surface of the decorative sheet 1, it is preferable to use a curable resin. Thermosetting resins such as two-component curable urethane resins, self-crosslinking acrylic resins, melamine resins, epoxy resins, and amino alkyd resins, and ultraviolet rays such as (meth) acrylate, epoxy, and polyester resins Alternatively, it is preferable to use an ionizing radiation curable resin that is cured by irradiation with an electron beam.

表面保護層14には、例えば着色剤、充填剤、紫外線吸収剤、光安定剤、熱安定剤、減摩剤、滑剤、抗菌剤、帯電防止剤、防滑用骨材等の添加剤を任意に添加してもよい。表面保護層14の厚みは、通例、1〜50μm程度であり、特に、床材の表面材としての耐傷性及び下地基材2へのラミネート等の後加工性を考慮すれば、6〜15μm程度とすることが最も好ましい。   For the surface protective layer 14, for example, additives such as a colorant, a filler, an ultraviolet absorber, a light stabilizer, a heat stabilizer, a lubricant, a lubricant, an antibacterial agent, an antistatic agent, and an anti-slip aggregate are optionally added. It may be added. The thickness of the surface protective layer 14 is usually about 1 to 50 μm, and in particular, considering the scratch resistance as the surface material of the flooring and the post-processability such as lamination to the base substrate 2, about 6 to 15 μm. Is most preferable.

以上に説明した本発明の化粧シートを、適宜の下地基材2の表面に貼り合わせることにより、本発明の床材4が得られる。下地基材2は、従来の床材におけるそれと同様のものを使用することができ、例えば日本農林規格に規定される普通合板や、木質繊維板、木質合成樹脂板(木粉等の木質系充填剤を合成樹脂に配合して板状に成形したもの)等を使用することができる。厚みは通例、3〜30mm程度である。   The flooring 4 of the present invention is obtained by bonding the decorative sheet of the present invention described above to the surface of an appropriate base material 2. The base material 2 can be the same as that of the conventional flooring material. For example, ordinary plywood, wood fiber board, wood synthetic resin board (wooden filling such as wood flour) prescribed in the Japanese Agricultural Standards A compound obtained by blending an agent with a synthetic resin and formed into a plate shape) can be used. The thickness is usually about 3 to 30 mm.

下地基材2と化粧シート1の貼り合わせに使用する接着剤3は汎用のもので良く、例えば1液酢酸ビニル樹脂エマルジョン系接着剤や、2液ウレタン変性ビニル樹脂水性接着剤等を使用することができる。このほか、2液ウレタン系溶剤型接着剤や、湿気硬化型ウレタン系ホットメルト接着剤等の使用も可能である。塗布量は通例、30〜100g/m(wet)程度である。 The adhesive 3 used for bonding the base substrate 2 and the decorative sheet 1 may be a general-purpose one, for example, using a one-pack vinyl acetate resin emulsion-based adhesive or a two-pack urethane-modified vinyl resin aqueous adhesive. Can do. In addition, it is also possible to use a two-component urethane-based solvent-type adhesive, a moisture-curable urethane-based hot melt adhesive, or the like. The application amount is usually about 30 to 100 g / m 2 (wet).

紫外線吸収剤、光安定剤、熱安定剤、無機顔料及び有機顔料からなる不透明顔料を添加した厚み70μmのホモポリプロピレン樹脂フィルムの表面に、公知の不透明な無機顔料及び有機顔料を含む2液ウレタン樹脂系グラビアインキで木目柄を印刷し、2液ウレタン系樹脂を乾燥後の厚み1μmに塗工してアンカー剤層を形成し、該アンカー剤層面に、マレイン酸変性ポリプロピレン系接着性樹脂と、紫外線吸収剤、光安定剤及び熱安定剤を添加した透明なホモポリプロピレン−ランダムポリプロピレン混合樹脂とを、厚みがそれぞれ15μm及び85μmとなる様に溶融押出し、その接着性樹脂面にオゾンガスを吹き付けながらラミネートすると同時に、冷却エンボスロールを使用してパターン状溝のエンボスを施した。なお、このパターン状溝は、長手方向及びそれと直交方向の目地状溝と、溝の底部の微細な凹凸パターンから構成されており、目地状溝の深さは60μm、開口幅は1.5mm、溝底部に格子状(格子内の凹部の四角の一辺が159μm、格子部の凸部の幅が10μm、凹部の面積は凸部の面積より広い)のパターンを凹凸差25μmで施した。   Two-component urethane resin containing a known opaque inorganic pigment and organic pigment on the surface of a 70 μm thick homopolypropylene resin film to which an opaque pigment composed of an ultraviolet absorber, a light stabilizer, a heat stabilizer, an inorganic pigment and an organic pigment is added A wood grain pattern is printed with a system gravure ink, and a two-component urethane resin is applied to a thickness of 1 μm after drying to form an anchor agent layer. On the anchor agent layer surface, a maleic acid-modified polypropylene adhesive resin and an ultraviolet ray When a transparent homopolypropylene-random polypropylene mixed resin added with an absorbent, a light stabilizer and a heat stabilizer is melt-extruded so as to have thicknesses of 15 μm and 85 μm, respectively, and laminated while spraying ozone gas on the adhesive resin surface. At the same time, the embossed pattern grooves were embossed using a cooled embossing roll. In addition, this pattern-like groove is composed of a joint groove in the longitudinal direction and a direction orthogonal thereto, and a fine uneven pattern at the bottom of the groove. The joint groove has a depth of 60 μm, an opening width of 1.5 mm, A lattice-like pattern (with one side of the square of the concave portion in the lattice being 159 μm, the width of the convex portion of the lattice portion being 10 μm, and the area of the concave portion being wider than the area of the convex portion) was applied to the bottom of the groove with an unevenness difference of 25 μm.

続いて、不透明な無機顔料及び有機顔料を含む2液ウレタン系着色塗料を全面に塗布し、合成樹脂製ブレードを使用して常法にてワイピング処理を施して、パターン状溝に着色塗料を充填した。しかる後、紫外線吸収剤、光安定剤、滑り止めのためのガラスビーズ等が添加された2液ウレタン系樹脂を、乾燥後の塗布量10g/mに塗布して表面保護層を形成し、裏面にはシリカ粉末を添加した2液ウレタン系樹脂を乾燥後の塗布量約1.5g/mに塗布して易接着層を形成して、本発明の化粧シートを作製した。 Subsequently, a two-component urethane-based colored paint containing an opaque inorganic pigment and organic pigment is applied to the entire surface, and a wiping treatment is applied in a conventional manner using a synthetic resin blade to fill the patterned groove with the colored paint. did. Thereafter, a two-component urethane resin to which an ultraviolet absorber, a light stabilizer, a glass bead for preventing slip, and the like are added is applied to a coating amount after drying of 10 g / m 2 to form a surface protective layer. On the back surface, a two-component urethane resin to which silica powder was added was applied at a coating amount of about 1.5 g / m 2 after drying to form an easy-adhesion layer, thereby producing a decorative sheet of the present invention.

また、上記化粧シートを、厚さ15mmのラワン系積層合板の表面に、ウレタン変性ビニル樹脂水性接着剤(コニシ株式会社製、CVC555:架橋剤v=100:5、塗布量60g/m(wet))にて貼り合わせて、本発明の床材を作製した。 In addition, the decorative sheet is coated on a surface of a 15 mm thick lauan laminated plywood with a urethane-modified vinyl resin aqueous adhesive (CVC555: cross-linking agent v = 100: 5, coating amount 60 g / m 2 (wet by Konishi Co., Ltd.). )) To produce a flooring of the present invention.

目地状溝の深さを60μm、開口幅を2.5mm、溝底部に格子状(格子内の凹部の四角の一辺が95μm、格子部の凸部の幅が74μm、凹部の面積は凸部の面積より広い)のパターンを凹凸差18μmで施した以外は実施例1と同様にして化粧シート、床材を作成した。   The depth of the joint grooves is 60 μm, the opening width is 2.5 mm, and the bottom of the groove is a lattice (the square side of the concave portion in the lattice is 95 μm, the width of the convex portion of the lattice portion is 74 μm, the area of the concave portion is A decorative sheet and a flooring were prepared in the same manner as in Example 1 except that a pattern of wider than the area was applied with an unevenness difference of 18 μm.

目地状溝の深さを60μm、開口幅を1.5mm、溝底部に万線状(凹部幅234μm、凸部幅20μm、凹部の面積は凸部の面積より広い)のパターンを凹凸差25μmで施した以外は実施例1と同様にして化粧シート、床材を作成した。   The depth of the joint groove is 60 μm, the opening width is 1.5 mm, and the groove bottom has a line-like pattern (recess width 234 μm, protrusion width 20 μm, the area of the recess is wider than the area of the protrusion) with an unevenness difference of 25 μm. A decorative sheet and a flooring were prepared in the same manner as in Example 1 except that it was applied.

目地状溝の深さを60μm、開口幅を2.5μm、溝底部に万線状(凹部幅140μm、凸部幅114μm、凹部の面積は凸部の面積より広い)のパターンを凹凸差18μmで施した以外は実施例1と同様にして化粧シート、床材を作成した。
<比較例1>
溝底部にパターンを付与しなかった以外は実施例1と同様にして化粧シート、床材を作成した。
<比較例2>
溝底部の万線状パターンを凹部幅114μm、凸部幅140μmとした以外は実施例3と同様にして、化粧シート、床材を作成した。
<評価>
上記実施例1、3は目地溝にも十分に着色剤が充填され、意匠性も良好であった。実施例2,4は凸部が広めのものであったが、十分に着色剤が充填された。比較例1は着色剤の充填が一部掃き取られまだら模様となり、比較例2では溝部に微細な凹凸パターンが浮き出てしまい、意匠性も悪いものとなった。
The depth of the joint groove is 60 μm, the opening width is 2.5 μm, and a line-like pattern (recess width 140 μm, protrusion width 114 μm, the area of the recess is wider than the area of the protrusion) is 18 μm. A decorative sheet and a flooring were prepared in the same manner as in Example 1 except that it was applied.
<Comparative Example 1>
A decorative sheet and a flooring were prepared in the same manner as in Example 1 except that no pattern was applied to the groove bottom.
<Comparative example 2>
A decorative sheet and a flooring were prepared in the same manner as in Example 3 except that the line-like pattern at the bottom of the groove was changed to a concave portion width of 114 μm and a convex portion width of 140 μm.
<Evaluation>
In Examples 1 and 3, the joint groove was sufficiently filled with the colorant, and the design was good. In Examples 2 and 4, the convex portion was wide, but the colorant was sufficiently filled. In Comparative Example 1, the filling of the colorant was partially swept away to form a mottled pattern, and in Comparative Example 2, a fine concavo-convex pattern emerged in the groove, resulting in poor design.

本発明の化粧シートの実施の形態を示す斜視図。The perspective view which shows embodiment of the decorative sheet of this invention. 本発明の化粧シート及び床材の実施の形態を示す側断面図。The sectional side view which shows embodiment of the decorative sheet and flooring of this invention. 本発明の溝底部の微細凹凸パターンの例を示す概略図。Schematic which shows the example of the fine uneven | corrugated pattern of the groove bottom part of this invention.

符号の説明Explanation of symbols

1……化粧シート
11……長尺シート状基材
11a…透明熱可塑性樹脂層
11b…接着性樹脂層
11c…アンカー剤層
11d…絵柄層
11e…着色熱可塑性樹脂層
11f…易接着層
12……パターン状溝
12a…長手方向の目地状溝
12b…長手方向と直交方向の目地状溝
13……着色剤
14……表面保護層
15……溝底部の微細凹凸パターン
2……下地基材
3……接着剤層
4……床材
A……長手方向
B……長手方向と直交方向
DESCRIPTION OF SYMBOLS 1 ... Cosmetic sheet 11 ... Long sheet-like base material 11a ... Transparent thermoplastic resin layer 11b ... Adhesive resin layer 11c ... Anchor agent layer 11d ... Pattern layer 11e ... Colored thermoplastic resin layer 11f ... Easy adhesion layer 12 ... ... Pattern-like groove 12a ... Longitudinal joint groove 12b ... Joint groove 13 in the direction orthogonal to the longitudinal direction ... Colorant 14 ... Surface protective layer 15 ... Fine uneven pattern 2 at the bottom of groove 2 ... Base substrate 3 …… Adhesive layer 4 …… Floor material A …… Longitudinal direction B …… Perpendicular to longitudinal direction

Claims (5)

長尺シート状基材の表面に、長手方向と直交方向の目地状溝を少なくとも含むパターン状溝が形成されており、該パターン状溝には着色剤が充填されてなる化粧シートであって、前記目地状溝の底部に5〜25μmの深さで微細な凹凸パターンが施され、パターン凹部の面積がパターン凸部の面積より広いことを特徴とする化粧シート。   On the surface of the long sheet-like base material, a pattern-like groove including at least joint grooves in the direction perpendicular to the longitudinal direction is formed, and the pattern-like groove is a decorative sheet that is filled with a colorant, A decorative sheet in which a fine concavo-convex pattern is applied to the bottom of the joint-like groove at a depth of 5 to 25 μm, and the area of the pattern concave portion is larger than the area of the pattern convex portion. 前記長手方向と直交方向の目地状溝は、深さが40〜80μm、開口幅が0.5〜3.0mmであることを特徴とする請求項1記載の化粧シート。   The decorative sheet according to claim 1, wherein the joint grooves in the direction perpendicular to the longitudinal direction have a depth of 40 to 80 µm and an opening width of 0.5 to 3.0 mm. 長尺シート状基材の表面に、長手方向と直交方向の目地状溝を少なくとも含むパターン状溝を形成し、前記目地状溝の底部に5〜25μmの深さで凹部面積が凸部面積より広い微細な凹凸パターンを形成し、前記パターン状溝にワイピング法により着色剤を充填してなることを特徴とする化粧シートの製造方法。   On the surface of the long sheet-like base material, a pattern-shaped groove including at least joint grooves in the direction perpendicular to the longitudinal direction is formed, and the recess area is smaller than the protrusion area at a depth of 5 to 25 μm at the bottom of the joint groove. A method for producing a decorative sheet, wherein a wide fine uneven pattern is formed, and the pattern-like groove is filled with a colorant by a wiping method. 前記長尺シート状基材は、少なくとも表面部に前記パターン状溝の深さよりも厚い熱可塑性樹脂層を備えてなり、前記パターン状溝は、前記熱可塑性樹脂層の溶融押出成形時に、溶融状態の熱可塑性樹脂層の片面に冷却エンボスロールを押し当てることにより形成することを特徴とする請求項3記載の化粧シートの製造方法。   The long sheet-like base material is provided with a thermoplastic resin layer thicker than the depth of the pattern-like groove on at least the surface portion, and the pattern-like groove is in a molten state at the time of melt extrusion molding of the thermoplastic resin layer. The method for producing a decorative sheet according to claim 3, wherein the sheet is formed by pressing a cooling embossing roll on one side of the thermoplastic resin layer. 請求項1〜4記載の前記化粧シートを下地基材に貼り合わせてなることを特徴とする床材。   A flooring material comprising the decorative sheet according to claim 1 bonded to a base substrate.
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