JP2005283082A - Combustion gas drying system - Google Patents

Combustion gas drying system Download PDF

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JP2005283082A
JP2005283082A JP2004127330A JP2004127330A JP2005283082A JP 2005283082 A JP2005283082 A JP 2005283082A JP 2004127330 A JP2004127330 A JP 2004127330A JP 2004127330 A JP2004127330 A JP 2004127330A JP 2005283082 A JP2005283082 A JP 2005283082A
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combustion gas
combustion
drying
kiln
processing
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Shigeyuki Nakamura
重行 中村
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ART KAIHATSU CENTER KK
ART KAIHATSU CT KK
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ART KAIHATSU CENTER KK
ART KAIHATSU CT KK
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a drying system capable of differentiating a drying product and capable of modifying it into a high grade product. <P>SOLUTION: This combustion gas drying system is constituted of a combustion furnace having fire resistance, and using a destruction rubbish (mainly sawing lumber) as fuel, and a sealed drying place (treatment oven hereafter) having heat resistance or fire resistance connected by a wall having an opening for passing direct firing heat energy (combustion gas hereafter) such as the combustion gas, smoking heat and the like, and uses direct introduction of the combustion gas into a top part of a treated object or an upper part thereof in the treatment oven, as the first means for uniform drying. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本発明は各種の木材乾燥方式の中の燃焼ガス乾燥処理に関するものである。  The present invention relates to a combustion gas drying process in various wood drying systems.

木材を中心とする乾燥技術は古米から様々な方法が開発され利用されている。電気熱や蒸気熱を利用して乾燥窯内の循環空気の温度や湿度を調節する熱気乾燥方式を始め、熱板乾燥、真空乾燥、除湿乾燥、高周波乾燥等が代表的な乾燥方式である。これらの乾燥方式の殆どは土台、柱、梁材や板材等の半製材品に木取りされた木材の乾燥に利用される。純粋の原木(丸太状態)を直接乾燥する方式には製材廃材を直焚き熱源とする燃焼ガス乾燥処理方式がある。  Various methods for drying technology centered on wood have been developed and used from old rice. Typical drying methods are hot plate drying, vacuum drying, dehumidification drying, high frequency drying, etc., including a hot air drying method in which the temperature and humidity of the circulating air in the drying kiln are adjusted using electric heat or steam heat. Most of these drying methods are used for drying wood that has been cut into semi-finished products such as foundations, pillars, beams and plates. A method for directly drying pure log (log state) includes a combustion gas drying method in which the sawmill waste is directly fired as a heat source.

燃焼ガス乾燥処理方式は別名で燻煙熱処理方式とも称される場合もある。方式の生まれた所以は製材の歩留り向上を目指して開発された乾燥方式である。開発手法の目標として、原木の中の成長残留応力の低減、含水率の低下と分布の均一化等がある。
客観的に見ても丸太処理と言う独走性と燻煙処理材としての差別、独占的な大きな市場性を有している。更には製材廃材を燃料とする社会資源から見ても優れた処理方式である。
The combustion gas drying treatment method is sometimes referred to as a soot heat treatment method. The reason why the method was born is a drying method that was developed with the aim of improving the yield of lumber. The goal of the development method is to reduce the residual residual stress in the raw wood, to reduce the moisture content and to make the distribution uniform.
From an objective point of view, it has a self-propelled nature called log processing, discrimination as a soot processing material, and a large marketability. Furthermore, it is an excellent treatment method even from the viewpoint of social resources that use lumber waste as fuel.

然し今日現在の乾燥処理木材製品市場にあって、燃焼ガス乾燥処理製材は他の乾燥処理方式製材に比べると遥かに小さな地位でしか与えられていない。この結果の原因の最大は乾燥処理製品精度の低さと中でもその不均一性に他ならない。これは目標とする含水率の低下と、分布の均一化が期待される程達成され得ない事を意味する。これには処理技術の未熟、非効率、非生産性と言った問題が同時に絡み合い、生産処理技術の発展を疎外してきた結果である。背景の状況分析をすると意外にも疎外の大もとは本処理方式即ち、燃焼ガス乾燥処理方式の誕生理由(目標)そのものの中にある。ここを方向的に意識改革し、技術的には略完全自動化まで解決することが全て問題の解決へと進む。  However, in today's dry wood products market, combustion gas dry lumber is given a much smaller position than other dry lumber. The largest cause of this result is none other than the low accuracy of the dried product and, among other things, its non-uniformity. This means that it cannot be achieved to the extent that a reduction in the target moisture content and a uniform distribution are expected. This is the result of entanglement of problems such as immaturity, inefficiency, and non-productivity of processing technology, and alienating the development of production processing technology. Surprisingly, when the background situation is analyzed, the main reason for the alienation is in the reason (target) itself of the present processing method, that is, the combustion gas drying method. Changing the consciousness in this direction and technically resolving to almost complete automation will all lead to the solution of the problem.

先ず、疎外の大もとは技術論的には燃料にあり、意識的には燃料としての製材廃材利用が製材の歩留り向上の一つへと直結している。突き詰めれば鶏と卵の論争になるが、ここは意識改革を先にすることが燃料の技術改革をすることの意義に繋がる。更には関連問題、課題解決の大きな意義が生まれる。
即ち、燃焼ガス乾燥処理の方式理由、目標を前記
First of all, the main reason for the alienation is fuel in terms of technology, and consciously, the use of sawmill waste as fuel is directly linked to one of the improvements in sawmill yield. At the end of the day, the controversy between chickens and eggs will be controversial, but this is where the change in awareness leads to the significance of fuel technology reform. In addition, related problems and the great significance of problem solving are born.
That is, the reason and target of the combustion gas drying process

で述べるように処理材木の独走性、処理製品材の差別独占的な市場性に大きく方向転換することが解決の全てである。As described in, all of the solutions are to make a major shift to the sole propriety of the treated timber and the distinctive marketability of the treated product.

乾燥処理で製材廃材を燃料とする燃焼炉の燃焼方式は極自然に自然通風式が採用されている。これは燃焼炉の焚き口である竈が下部で、処理窯の煙の出口が上部であるとする最も原理的且つ自然な燃焼形態をとっている事に他ならない。この事で燃料の調節、即ち処理窯の温度調節は当然の如く人為的に製材廃材の投入量で調節される。一部に燃焼ガス量を処理窯に導入する開口の開閉度をダンパー等で人為的に調節する方式を併用している場合もあるが、基本的に人為的な燃料管理、温度管理で且つ昼夜を問わず24時間体制の人為的な管理に変わりはない。温度計、温度センサー類も装備されている場合もあるが何れも視覚で捉える為の設備であり、制御処理又は計算処理等の自動管理には一切連動していない。敢えて記すなら連動若くは制御すべき機器類が一切無い事である。  Naturally ventilating is adopted as the combustion method of the combustion furnace that uses the sawn timber as fuel in the drying process. This is the most basic and natural combustion mode in which the soot that is the burning outlet of the combustion furnace is the lower part and the smoke outlet of the treatment kiln is the upper part. As a matter of course, the adjustment of the fuel, that is, the temperature adjustment of the processing kiln is artificially adjusted by the input amount of the sawdust. In some cases, a method of artificially adjusting the opening and closing degree of the opening that introduces the amount of combustion gas into the treatment kiln with a damper etc. is used together, but basically it is artificial fuel management, temperature management and day and night Regardless of whether or not the 24-hour artificial management. Although thermometers and temperature sensors may be equipped, both are facilities for visual recognition and are not linked to automatic management such as control processing or calculation processing. If you dare to write, there is no equipment to be linked or controlled.

燃焼ガス乾燥処理方式に依る処理製品の不均一製品を生む原因には大きく分けて三つの要因が重なる。その一つは前記  There are three main reasons for the generation of non-uniform processed products by the combustion gas drying method. One of them

で述べた人為的な燃料、温度管理から引き起こされる不均一である。今一つは乾燥処理窯の中の燃焼ガスの導入方法にある。一般的に熱を伴う木材等の乾燥の場合は熱ガスを処理窯の下部に導入する。これは導入された熱エネルギーの浮力を利用して熱ガスを移動させる最も原始的且つ自然の利に叶った方式である。処で、圧力を伴わない容器の中でこの自然の利を応用すればどうなるか。熱ガスは浮力のみに作用されてひたすら上を目指すのみである。今正に殆どの燃焼ガス乾燥処理窯の中ではこの現象が起きている。燃焼ガスはガス温度が高い程に窯の上部にある煙突を目がけて上昇する。途中燃焼ガスに否応なく触れる原木だけ、そして触れた部分だけ作用しながら上昇する。不均一の一つはこうして日々刻々と誕生させられる。The non-uniformity caused by the artificial fuel and temperature management mentioned in. The other is the method of introducing combustion gas in the drying furnace. In general, when drying wood with heat, a hot gas is introduced into the lower part of the processing kiln. This is the most primitive and natural method of moving the hot gas using the buoyancy of the introduced thermal energy. By the way, what happens if this natural advantage is applied in a container without pressure? The hot gas is only acted on by buoyancy and aims only upwards. This phenomenon has occurred in almost all combustion gas drying furnaces. The higher the gas temperature, the higher the combustion gas is aimed at the chimney at the top of the kiln. The log rises while acting only on the wood that touches the combustion gas on the way, and only the touched part. One of the inhomogeneities is thus born every day.

今一つの要因はこれ又極々自然の所作である処理窯内での原木の水平(以降横置きと言う)置き乾燥である。これは単純に原木の運搬集積上の便利さから横置きされたと推測される。又在来の乾燥処理窯の構造が安易に使用可能な倉庫、工場等を改造して使用することもあり、新たに処理窯を築造する場合も横置きの場合が天井高さを低く出来ることで構造的に横置きが慣習化したものと思われる。然しこの原木の横置き式乾燥処理は不均一要因の中でも最大要因である。
今、乾燥処理窯の中の横置きされた原木1本を仮定推理する。燃焼ガスで元口から末口まで仮に均一に熱せられたとする。原木の中の細胞壁にあった水分ガスは熱膨張の後凝縮させられて水滴となる。水滴となった水分は重力の作用で横置きされた原木の下部に集合させられる。原木が樹皮付の場合は1週間ほど連続乾燥しても集合した水分の10〜20%が蒸発するのみである。原木の樹皮無しでも完全丸太の場合で同じ乾燥処理でやっと50%前後の水分蒸発である。ここに横置き原木の内部上下に大きな温度差の不均一を生じる。更には上下の温度差と垂直応力の働きで上部には圧縮応力が、下部には引張り応力が生じ、原木内部で応力の差による不均一が生じる。
これらは原木を蒸し焼きで炭化即ち炭焼き窯での事象と同じである。原木を横置きにして炭を焼くと横置き原木の上部は炭化して炭になっているが、下部は煤にまみれて焼けただれの状態である。即ち生焼けである。炭焼きの達人たる先人立ちが炭を焼くとき窯の中で原木を縦置きする理由の一つがここにある。
Another factor is the natural (horizontal) standing drying of the raw wood in the processing kiln. This is presumed to have been placed sideways simply due to the convenience of transporting and collecting raw wood. In addition, warehouses and factories where the structure of conventional drying furnaces can be used easily can be remodeled and used, and the ceiling height can be lowered when a new furnace is installed or when it is placed horizontally. It seems that the horizontal placement has become customary. However, the horizontal drying process of this raw wood is the biggest factor among the non-uniform factors.
Now, a hypothetical reasoning is made on one horizontally placed log in the drying kiln. Suppose that the combustion gas is heated uniformly from the front to the end. Moisture gas in the cell walls in the raw wood is condensed after thermal expansion to form water droplets. Moisture in the form of water droplets is gathered at the bottom of the raw wood that was placed horizontally by the action of gravity. When the raw wood has a bark, only 10 to 20% of the collected water evaporates even after continuous drying for about one week. Even without the bark of the raw wood, it is only about 50% water evaporation with the same drying process in the case of a complete log. Here, a large non-uniformity in temperature difference occurs inside and below the horizontally placed log. Further, the upper and lower temperature difference and the vertical stress cause a compressive stress in the upper part and a tensile stress in the lower part, resulting in non-uniformity due to the difference in stress inside the log.
These are the same as the events in steaming the charcoal or charcoal. When charcoal is burnt with the raw wood placed horizontally, the upper part of the horizontal wood is charred and charcoal, but the lower part is covered with firewood and burned. That is, it is burnt. This is one of the reasons why a pioneer who is a master of charcoal grills places logs vertically in a kiln.

発明が解決しようとする課題Problems to be solved by the invention

従来の原木の燃焼ガス乾燥処理は前記  Conventional raw wood combustion gas drying process

~

説明内容が確実且つ必ず同時に重なる事である。然るに問題の解決には最小限にも前記三つの問題(要因)を同時に解決することに他ならない。It is sure that the explanation contents overlap at the same time. However, solving the problem is nothing but solving the above three problems (factors) at the same time.

今一つの解決の手助けとして燃焼ガス乾燥処理方式の論理の確立がある。今にあっても木材の乾燥は温度で乾かすと言う固定観念で行われていることにある。木材特有の吸湿と放湿の調湿作用で乾燥処理が行われ、この調湿作用を促す為に相対湿度の調節が必要であり、この相対湿度の調節の為に温度の調節が必要であることが余りにも認識されていない。その為に無やみに高温度が採用されこの高温度が更なる不均一を生み出すことに注意が払われていない。この論理の確立を問題解決の手段の中で展開する。  Another helping solution is to establish the logic of the combustion gas drying process. Even now, the drying of wood is carried out with the fixed idea of drying with temperature. Drying is performed by the moisture absorption and dehumidification characteristic of wood, and the relative humidity must be adjusted to promote this humidity adjustment, and the temperature must be adjusted to adjust this relative humidity. It is not recognized too much. For this reason, no attention has been paid to the fact that a high temperature is adopted without any consideration and this high temperature creates further non-uniformity. The establishment of this logic is developed as a means for solving problems.

課題を解決するための手段Means for solving the problem

本発明の燃焼ガス乾燥処理方式では、処理窯の上部に燃焼ガスを導入する。導入された窯の上部には煙突なるものが存在しない。このため燃焼ガスは窯の上部で均一な広がり現象をみせる。この広がりの燃焼ガスが燃焼ガス導入部の開口と同じ高さで満杯状態になると、その部分の空気の比容積が大きくなり、これに依って生じる水蒸気分圧の変化(上昇)圧力分だけ圧力が上昇する。この結果、燃焼ガスの浮力エネルギーに打ち勝つ圧力エネルギーが生じると、燃焼ガスは圧力の低い処を目指して圧力が均衡する処まで下降する。この燃焼ガスの下降の状態が窯全体に作用する圧力のため平面的に均一な下降圧力となる。この平面的な均一作用が原木の乾燥処理に対して完全無垢な均一性をもたらす絶対的な第1条件である。  In the combustion gas drying method of the present invention, the combustion gas is introduced into the upper part of the treatment kiln. There is no chimney at the top of the introduced kiln. For this reason, the combustion gas shows a uniform spreading phenomenon in the upper part of the kiln. When this widened combustion gas becomes full at the same height as the opening of the combustion gas inlet, the specific volume of air in that portion increases, and the pressure corresponding to the change (rise) pressure of the water vapor partial pressure caused by this increases. Rises. As a result, when pressure energy that overcomes the buoyancy energy of the combustion gas is generated, the combustion gas descends to a place where the pressure is balanced aiming at a place where the pressure is low. Due to the pressure acting on the entire kiln, the state of the combustion gas descending is a uniform planar descending pressure. This planar uniform action is an absolute first condition that provides innocent uniformity for the raw wood drying process.

燃焼ガスが処理窯の中で上部から下部へと平面的に均一下降を続ける為には常に燃焼ガスに一定以上の圧力エネルギーが増加する必要がある。処理窯の上部に導入された燃焼ガスの熱エネルギーは、原木上部の水分に一部の熱を与える。熱を受けた水分の約半分は凝縮して水滴となり下部に落下するが、残りの水分は蒸発潜熱即ち蒸気ガスとなり燃焼ガスと混合される。このため燃焼ガスは比重量が大きくなり、浮力に打ち勝って下部へ下降する。このように燃焼ガスは熱エネルギーを奪われる変わりに圧力エネルギーに相当する重力エネルギーを受け取るサイクルをゆっくりと繰り返しながら下降し下部床面に到達する。このエネルギーサイクルは一般的な燃焼計算上の通風力計算、その他の温度を伴う排気ガス計算等の中では完全に抵抗損であり、その中の圧力損失に相当する。その圧力損失を論理的に逆利用するところが完全な均一を保証する論理の成立であり、本発明の最大の手段でもある。故に本発明では床面若くは限りなく床面に近い下部の壁面に煙(燃焼ガス)の出口即ち煙道の入口を設ける訳である。  In order for the combustion gas to continue to descend uniformly from the upper part to the lower part in the treatment kiln, it is necessary to always increase the pressure energy above a certain level to the combustion gas. The thermal energy of the combustion gas introduced into the upper part of the treatment kiln gives a part of heat to the moisture in the upper part of the log. About half of the heat-treated moisture is condensed to form water droplets and falls to the lower part, while the remaining water becomes latent heat of vaporization, that is, vapor gas, and is mixed with the combustion gas. For this reason, the combustion gas has a higher specific weight, overcomes the buoyancy, and descends downward. In this way, the combustion gas descends while slowly repeating the cycle of receiving gravitational energy corresponding to pressure energy instead of being deprived of thermal energy, and reaches the lower floor surface. This energy cycle is completely resistance loss in general wind calculation for combustion calculation, exhaust gas calculation with other temperatures, and the like, and corresponds to pressure loss therein. The logical use of the pressure loss is the establishment of the logic that guarantees complete uniformity, and is the greatest means of the present invention. Therefore, in the present invention, an outlet for smoke (combustion gas), that is, an inlet for a flue is provided on the floor surface or a lower wall surface that is almost as close to the floor surface.

本発明は原木の横置き乾燥処理で生じる不均一性を完璧なまでに解消する手段として原木を縦置きで乾燥処理する。
処理窯上部に
In the present invention, as a means for completely eliminating the non-uniformity caused by the horizontal drying process of the raw wood, the raw wood is vertically dried.
At the top of the processing kiln

で説明した燃焼ガスの導入で生じる圧力エネルギーは処理窯上部の空間のみならず、縦置きされた原木の末口である頂部の内部細胞壁まで均一に作用する。この瞬間、縦置き原木の頂部では原木の内外の相対湿度の差による調湿作用即ち放湿作用が始まる。細胞壁の中にあった水分は放湿作用で仮道管に移動する。水分が移動するのと同時に細胞壁には高温の燃焼ガスが流入する。流入した高温ガスは細胞壁即ち原木の心材を温める。この心材が温まることで調湿作用が完了せず細胞壁に留まっていた僅かな水分も完全に仮道管に移動させられる。
縦置きされた原木の仮道管の繊維方向は重力作用を受ける縦方向となり、この仮道管に移動した水分は集合することで凝縮水滴となり、これに重力作用と重力加速作用を受けて落下するように仮道管を下部へと移動し、最後には原木の下部である元口から原木の外部へと放出される。この現象は長い木材等でたき火をする時に燃えている木材の反対側から盛んに沸騰状の水滴が流れ出る現象と全く同じ物理現象である。
原木を縦置きにして、原木の頂部を燃焼ガスで均一に刺激する程度のエネルギーで大きな水分の移動即ち確実な乾燥処理効果が得られる。これが原木縦置きの最大の理由であり、原木の横置き処理では絶対に起こりえない現象である。この現象は
The pressure energy generated by the introduction of the combustion gas described in the section acts not only on the space above the processing furnace but also on the inner cell wall at the top, which is the end of the vertically placed raw wood. At this moment, at the top of the vertically placed raw wood, a humidity control action, that is, a moisture releasing action due to a difference in relative humidity inside and outside the raw wood begins. Moisture in the cell wall moves to the temporary canal by a dehumidifying action. Simultaneously with the movement of water, hot combustion gases flow into the cell walls. The flowing hot gas warms the cell walls, ie the heartwood of the raw wood. When the heartwood is warmed, the humidity control action is not completed, and a slight amount of water remaining on the cell wall is completely moved to the temporary canal.
The fiber direction of the vertical path of the log of the raw wood is the vertical direction that receives the gravitational action, and the water that has moved to the temporary path becomes a condensed water droplet that collects and drops due to gravity and acceleration of gravity. Then, the temporary path pipe is moved downward, and finally, it is discharged from the original mouth, which is the lower part of the raw wood, to the outside of the raw wood. This phenomenon is the same physical phenomenon as a phenomenon in which boiling water droplets flow out from the opposite side of the burning wood when a bonfire is made with a long wood.
A large moisture movement, that is, a reliable drying effect can be obtained with such energy that the log is placed vertically and the top of the log is uniformly stimulated with combustion gas. This is the biggest reason for the vertical placement of logs, a phenomenon that can never occur in the horizontal processing of logs. This phenomenon

説明の論理で原木の頂部である末口から下部である元口まで完全な均一性をもって完璧に乾燥処理が進行させられることである。更にはこの均一完璧性が驚異的な処理時間の短縮と大きな省エネ化を計ることができることが本発明の燃焼ガス乾燥処理の大きな特徴である。The logic of the explanation is that the drying process is made to proceed perfectly with complete uniformity from the end of the raw wood to the bottom of the original wood. Furthermore, this uniform perfection is a major feature of the combustion gas drying process of the present invention that it can achieve tremendous reduction in processing time and great energy saving.

本発明の燃焼ガス乾燥処理方式の燃焼炉の燃焼方式は原則として押込通風式を選択する。処理施設の立地場所、気候条件、処理原木の長さから決定される処理窯の高さの条件、省エネその他の条件で自然通風式を選択または押込通風式と併用選択する場合もある。自然通風式を選択した場合若くは押込通風式と併用選択で処理工程上自然通風式運転中の場合、外気の気象条件特に急激な気圧の変化で風圧、風向が変わり処理窯内の通風力バランスが崩れ、煙道や煙突内の排気ガス速度が急減することで、煙道や煙突等が急激に冷却されることがある。又外気温度の急激な低下で冷却され、煙道や煙突内の排気燃焼ガスの浮力が小さくなり、結果として理論通風力の低下を招く場合もある。このような不測の事故を防止する為に、煙道や煙突の一部を燃焼炉の中を通過させることで冷却を防止するすることができ、最小限度の安定した理論通風力を維持することができる。この手段は押込通風力の計算過程にあっても不要の安全係数を抑制できる効果がある。今一つ燃焼ガス乾燥処理方式では乾燥開始初期と乾燥終了後期では処理窯内の温度や燃焼ガス比重が大きく変化する。この為に処理窯内の動圧は大きく変化する。この変化分を燃焼炉内で生まれる煙道や煙突の理論通風力に比例的に負担させる事が可能となる。これを実行することで、所要通風動力で不要な動力を装備する必要性が無く、合わせて不要な燃焼ガスの排気を防止することができる。  The combustion method of the combustion furnace of the combustion gas drying method of the present invention is basically selected from the forced draft method. Depending on the location of the treatment facility, the climatic conditions, the height of the treatment kiln determined from the length of the treated raw wood, energy saving and other conditions, the natural ventilation type may be selected or used in combination with the forced ventilation type. When natural ventilation type is selected or when combined with indentation ventilation type and natural ventilation type operation is used in the processing process, the wind pressure and wind direction change due to weather conditions of the outside air, especially sudden changes in atmospheric pressure, and the balance of ventilation in the treatment furnace The flue collapses and the exhaust gas velocity in the chimney and chimney rapidly decreases, so that the flue and chimney may be rapidly cooled. In addition, it is cooled by a sudden drop in the outside air temperature, and the buoyancy of the exhaust combustion gas in the flue or chimney is reduced, resulting in a decrease in theoretical wind power. In order to prevent such unexpected accidents, it is possible to prevent cooling by passing a part of the flue and chimney through the combustion furnace, and to maintain the minimum stable theoretical wind power. Can do. This means has an effect of suppressing unnecessary safety factors even in the calculation process of intrusion wind power. In the combustion gas drying treatment method, the temperature in the treatment furnace and the specific gravity of the combustion gas vary greatly between the beginning of drying and the end of drying. For this reason, the dynamic pressure in the treatment kiln changes greatly. This change can be proportionally borne by the theoretical wind power of the flues and chimneys created in the combustion furnace. By executing this, there is no need to provide unnecessary power with the required ventilation power, and unnecessary exhaust of combustion gas can be prevented.

本発明では燃料としての貴重な製材廃材を変更することなく、処理施設に運転管理の泊り込みをすることのなし自動運転制御体制を下記を手段として取り込む。
燃料としての製材廃材は燃焼炉に従事者が朝出社時と退社時の1日都合2回投入する。処理窯の温度調節は燃焼炉の燃焼空気の量を処理窯の温度センサー信号でCPU処理して連続的に調節する。燃焼空気量の調節手段は燃焼方式の運転手段が自然通風式の場合は電動ダンパーを開閉して、押込通風式の場合は給気ファンをON、OFFして調節する。処理装置の運転中、温度調節を必要としない場合にあっては給気ファンを停止する。然しこの状態に於いても処理窯の中の熱気が滞留することなく均一な燻煙処理を継続させることを目的として処理窯と燃焼炉の間の燻煙循環ファンを運転する。尚、この時の燃焼炉の燃焼方式は自然通風式となる。
In the present invention, the automatic operation control system without taking in operation management in the processing facility without changing valuable lumber waste as fuel is incorporated as the following means.
Sawdust as fuel is thrown into the combustion furnace twice a day when the worker leaves the company and leaves the company. The temperature of the processing furnace is continuously adjusted by processing the amount of combustion air in the combustion furnace with the CPU using the temperature sensor signal of the processing furnace. The combustion air amount adjusting means is adjusted by opening and closing the electric damper when the combustion type operating means is a natural ventilation type, and by turning the supply air fan on and off when the driving type is a forced draft type. If the temperature adjustment is not required during operation of the processing apparatus, the air supply fan is stopped. However, even in this state, the smoke circulation fan between the treatment kiln and the combustion furnace is operated for the purpose of continuing the uniform soot treatment without the hot air in the treatment kiln remaining. The combustion method of the combustion furnace at this time is a natural ventilation type.

発明の効果The invention's effect

従来の燃焼ガス乾燥処理方式は原木丸太の直接乾燥及び、製材廃材の燃料と言う客観的に見ても極めて広がりの多い産業方式と思えるが、殆ど発展して来なかった。その最大の要因の一つに処理方式の論理が確立されていないことに尽きる。
本発明は先ず具体的且つ確実な手段と論理を持って課題の解決を提示することから、木材加工産業のみならず、瀕死の状態にある国内林野産業に大きな活路の為の一石になると信じる。
Although the conventional combustion gas drying method seems to be an industrial method that is extremely widespread even when viewed objectively as direct drying of log logs and fuel for sawmill waste, it has hardly developed. One of the biggest factors is that the logic of the processing method has not been established.
Since the present invention presents a solution to the problem with specific and reliable means and logic first, we believe that it will be a stone for a great path not only in the wood processing industry but also in the dying domestic forest industry.

本発明の燃焼ガス乾燥処理方式は請求項1から請求項6を不変性を持って確実且つ同時に実践することで絶対的な結果を現わす。ここでの結果は関連社会及び産業市場に於ける信用と地位の確立にあてられる。  The combustion gas drying method of the present invention achieves an absolute result by reliably and simultaneously practicing claims 1 to 6 with invariance. The results here are devoted to establishing trust and status in relevant social and industrial markets.

燃焼ガス乾燥処理方式の信用と地位の確立ができたら、次は絶対的な製品の差別化である。差別化の一つは燻煙を全面に押し出した乾燥処理製品の処理精度の高級化である。特に歴史的な古材木に匹敵する強度と風味が出されるようになると新たな需要の開発に繋がる。この差別的高級化を目指す手段として、乾燥処理工程に於ける調湿作用の回数を増やすことで処理可能となる。特に基本乾燥処理工程が終わった後の燻煙処理の為の調湿作用工程処理は僅か1〜2日の時間で相当な差別的効果を現わす。  Once the confidence and status of the combustion gas drying treatment system has been established, the next step is absolute product differentiation. One of the differentiators is to upgrade the processing accuracy of dry processed products that extrude smoke. In particular, when the strength and flavor comparable to historical old timber are produced, it will lead to the development of new demand. As a means for aiming at this distinctive upgrading, processing can be performed by increasing the number of humidity control operations in the drying process. In particular, the humidity control process for the soot treatment after the basic drying process has been completed exhibits a significant discriminating effect in a time of only 1 to 2 days.

本発明の燃焼ガス乾燥処理方式の請求項6に基ずく無人化自動制御の度合を長時間無人化から完全無人化にすることは現在に於いても意図も簡単に移行できる。これは燃料である製材廃材をチップ材にすることと、燃焼炉に石炭時代に良く用いられた移動式のストーカーや自動投入機を用いる事で完全自動化を計れる。この事は原木等の巨大集積基地や、材木生産基地等に大型乾燥処理施設を建設することを可能とする。国内産原木の消費不況にある林野関連産業を大きく活性化させ、合わせて大きな雇用を創出すことに確実に貢献する。  Based on claim 6 of the combustion gas drying processing system of the present invention, the degree of unmanned automatic control can be easily shifted from the unmanned for a long time to completely unmanned. This can be fully automated by using scrap wood as a chip material and using a mobile stalker and automatic charging machine often used in the coal era for the combustion furnace. This makes it possible to construct a large drying treatment facility at a huge accumulation base such as raw wood or a timber production base. We will revitalize the forest-related industries in the recession of domestically produced timber and contribute to the creation of large jobs.

発明の実施の形態を実施例にもとづく図面を参照して説明する。
図1は燃焼ガス乾燥処理方式の燃焼炉と処理窯の一体型築造方式の平面図であり図2はその断面図を現わす。炉及び窯の構造体は鉄筋コンクリート製であるが、築造工法方式は現場打ちラーメン構造、PC組立工法、PCボックスカルバート工法その他と状況に合わせて選択築造する。
Embodiments of the present invention will be described with reference to the drawings based on the embodiments.
FIG. 1 is a plan view of an integrated construction method of a combustion furnace and a processing kiln of a combustion gas drying processing method, and FIG. 2 shows a sectional view thereof. The structure of the furnace and kiln is made of reinforced concrete, but the construction method is selectively built according to the situation, such as on-site ramen structure, PC assembly method, PC box culvert method and others.

処理窯1には搬出入路7から原木11が搬入され縦置き状態で集積される。燃焼炉2の中には燃料である製材廃材12の必要量(約日燃焼消費量×1/2相当)が投入口8から投入蓄積される。  The raw wood 11 is carried into the processing kiln 1 from the carry-in / out path 7 and accumulated in a vertically placed state. In the combustion furnace 2, a necessary amount of sawmill waste 12 as fuel (approximately equivalent to daily combustion consumption × ½) is charged and accumulated from the charging port 8.

燃焼炉の燃料12に着火し確実に燃焼を続ける状況を確認した後、燃焼炉2の開閉口である燃料の投入扉8と、灰溜管理扉9を確実に閉じる。自動制御盤20の運転スイッチをONにして燃焼用新鮮空気取入の為の給気ファン13の運転開始を確認する。処理窯1の搬出入路7から燃焼ガス(煙)15を確認した後搬出入路のシャッター7を完全に閉める。この後約20分〜30分後ぐらいに煙突10cから湯気状の淡白いガス(自動運転中は蒸気を多量に含む濃白色)を確認することで一部燃料の補給を除いて、温度センサー19や自動制御盤20に依る完全な自動運転体制に入る。  After confirming the state in which the fuel 12 of the combustion furnace is ignited and reliably continues combustion, the fuel input door 8 and the ash reservoir management door 9 which are the opening and closing ports of the combustion furnace 2 are securely closed. The operation switch of the automatic control panel 20 is turned ON to confirm the start of operation of the air supply fan 13 for taking in fresh air for combustion. After confirming the combustion gas (smoke) 15 from the loading / unloading path 7 of the processing furnace 1, the shutter 7 of the loading / unloading path is completely closed. After about 20 to 30 minutes thereafter, the temperature sensor 19 except for a part of fuel replenishment by checking steamy pale white gas (a dark white containing a large amount of steam during automatic operation) from the chimney 10c. And a fully automatic operation system that depends on the automatic control panel 20 is entered.

燃焼ガス15の経路の説明を図2の断面図でする。
新鮮な燃焼用空気17は給気ファン13に依って燃焼炉2の下部にある灰溜ピット6に送られる。この後炉床2bを通過して燃焼炉2に入る。燃焼炉2で燃料12を燃焼させて高温度の燃焼ガス15が生成される。燃焼ガス15は給気ファン13の動圧と高温度で作られる浮力に依って燃焼炉2の天井まで押し上げられる。この後燃焼ガス15は動圧と浮力の混合した圧力に依って隔壁4aの開口4bから処理窯1に向かって送り出される。
The route of the combustion gas 15 will be described with reference to the sectional view of FIG.
Fresh combustion air 17 is sent to the ash reservoir pit 6 at the lower part of the combustion furnace 2 by the air supply fan 13. Thereafter, it passes through the hearth 2b and enters the combustion furnace 2. The combustion gas 2 is burned in the combustion furnace 2 to generate high-temperature combustion gas 15. The combustion gas 15 is pushed up to the ceiling of the combustion furnace 2 by the dynamic pressure of the air supply fan 13 and the buoyancy created at a high temperature. Thereafter, the combustion gas 15 is sent out from the opening 4b of the partition wall 4a toward the processing kiln 1 according to the mixed pressure of dynamic pressure and buoyancy.

処理窯1にあって、燃焼炉2から導入された燃焼ガス15は開口4bとほぼ同じ高さの処理窯上部空間を満杯にする。この後燃焼ガス15は  In the treatment furnace 1, the combustion gas 15 introduced from the combustion furnace 2 fills up the treatment furnace upper space almost the same height as the opening 4b. After this, the combustion gas 15 is

で説明するように原木11に熱エネルギーを与え、代わりに圧力エネルギーに相当する重力エネルギーを受け取る形で、ゆっくりと窯全体を平面的に均一にしながら処理窯床1aまで下降する。窯床1aに達した燃焼ガスは床面を這うようにして排水舛兼用の集煙ピット10aに集められる。As described above, the thermal energy is given to the log 11 and instead the gravitational energy corresponding to the pressure energy is received, and the entire kiln is slowly lowered to the treatment kiln floor 1a while being uniformly planarized. The combustion gas that has reached the kiln floor 1a is collected in a smoke collecting pit 10a that also serves as a drainage so as to crawl the floor surface.

集煙ピット10aに集められた燃焼ガス15は、全エネルギーの約60%以上を原木11の乾燥処理に消費された状態である。排気燃焼ガス15となって残されたエネルギーの約70%以上は今だ凝縮して水滴になれない水蒸気ガスの重力エネルギーであるが、ここから煙突の理論通風力圏内に入り無理なく煙道10bを進む。煙道10bが燃焼炉2に入ると排気燃焼ガス15は、燃焼炉熱に依る浮力が加算され勢いよく煙突10cに突入した後外気に放出される。  The combustion gas 15 collected in the smoke collection pit 10a is in a state where about 60% or more of the total energy is consumed in the drying process of the raw wood 11. About 70% or more of the energy remaining as the exhaust combustion gas 15 is the gravity energy of the water vapor gas that is not yet condensed and formed into water droplets. Continue on. When the flue 10b enters the combustion furnace 2, the exhaust combustion gas 15 is added to the buoyancy due to the heat of the combustion furnace and vigorously enters the chimney 10c and is then released to the outside air.

燃焼炉2に着火されてから均一且つ完全に乾燥処理が完了するのに平均4日ほどの乾燥処理時間が必要である。この平均乾燥処理時間は夏場の原木11の含水率が冬場の原木11の1.5倍以上と高率に変化するため、夏場には処理時間が1日から2日ほど延びる。  It takes an average of four days for the drying process to be completed uniformly and completely after the combustion furnace 2 is ignited. In this average drying process time, the water content of the log 11 in the summer changes to a high rate of 1.5 times or more that of the log 11 in the winter, so that the process time extends from one day to two days in the summer.

実施例1は原木11の完全均一な乾燥を主眼とする基本乾燥処理方式の実施説明である。ここまでの基本乾燥処理の中で原木11の大きな調湿作用は乾燥初期の放湿作用と、乾燥終了期の吸湿作用と合わせて僅か2回である。  The first embodiment is an explanation of a basic drying processing method that focuses on completely uniform drying of the log 11. In the basic drying process so far, the large moisture conditioning action of the log 11 is only twice, including the moisture releasing action at the initial stage of drying and the moisture absorbing action at the end stage of drying.

で説明する乾燥処理製材品の差別的高級化を目指す初期の手段として、基本乾燥処理の僅か2回の調湿作用の中の乾燥終了期の吸湿作用に合わせて、高温熱を伴わない燻煙ガス18を燃焼炉2で多量に発生させこの燻煙ガスを処理窯1に送る。処理窯1に導入された燻煙ガス18を集煙ピット10aにある燻煙循環ファン21に接続された燻煙循環ダクト22で吸引して、再び灰溜ピット6を経由して燃焼炉2に送り燻煙ガス18の循環処理をする。燻煙ガス18の発生燃料には事前に燃焼炉2に導入して、便宜的に燻し乾燥させたおが屑等を使用する。この場合の燃焼炉2の燃焼方式は自然通風式として給気電動ダンパー14を開とし、給気ファン13は停止する。As an initial means of differentiating the quality of dry-processed lumber products explained in, soot that does not involve high-temperature heat in accordance with the hygroscopic effect at the end of drying in only two humidity control operations of the basic drying process A large amount of gas 18 is generated in the combustion furnace 2 and this soot gas is sent to the processing furnace 1. The smoke gas 18 introduced into the treatment kiln 1 is sucked by the smoke circulation duct 22 connected to the smoke circulation fan 21 in the smoke collection pit 10a, and is again returned to the combustion furnace 2 via the ashes pit 6. The feed smoke gas 18 is circulated. As the generated fuel of the soot gas 18, sawdust or the like introduced into the combustion furnace 2 in advance and dried for convenience is used. In this case, the combustion method of the combustion furnace 2 is a natural ventilation type, the air supply electric damper 14 is opened, and the air supply fan 13 is stopped.

発明の乾燥処理窯方式は木材等の薫蒸処理、防腐剤の含浸処理、防炎防火剤の含浸処理等の用途にも適用できる。  The drying furnace system of the invention can be applied to uses such as fumigation treatment of wood, impregnation treatment with preservatives, impregnation treatment with flameproofing and fireproofing agents.

本発明の実施例1及び実施例2にかかる燃焼ガス乾燥処理方式の基本的な形態の平面を示す図である。  It is a figure which shows the plane of the basic form of the combustion gas drying processing system concerning Example 1 and Example 2 of this invention. 本発明の実施例1及び実施例2にかかる燃焼ガス乾燥処理方式の基本的な形態の断面を示す図である。  It is a figure which shows the cross section of the basic form of the combustion gas drying processing system concerning Example 1 and Example 2 of this invention.

符号の説明Explanation of symbols

1 処理窯(コンクリート製)
1a 処理窯床(コンクリート製)
1b 床グレーチング
2 燃焼炉(耐火仕様仕上)
2a 燃焼炉床(耐火仕様仕上)
2b 炉床(鋳グレーチング)
3a 外壁(コンクリート製)
3b 外壁(内面耐火仕様仕上)
4a 隔壁(=内壁、燃焼炉側耐火仕様仕上)
4b 開口(燃焼ガス通路)
5a 屋根(コンクリート製)
5b 屋根(内面耐火仕様仕上)
6 灰溜ピット
7 原木搬出入路防火シャッター
8 燃料(製材廃材)投入防火扉
9 灰溜ピット管理防火扉
10a 集煙ピット(排水舛兼用)
10b 煙道
10c 煙突
10d 煙道保護コンクリート
11 原木(縦置き)
12 燃料(製材廃材)
13 給気ファン
14 給気電動ダンパー
15 燃焼ガス
16 燃焼排気ガス
17 新鮮空気
18 循環燻煙ガス
19 温度センサー
20 自動制御盤
21 燻煙循環ファン
22 燻煙循環ダクト
1 Processing kiln (made of concrete)
1a Treatment kiln floor (concrete)
1b Floor grating 2 Combustion furnace (Finish with fire resistance)
2a Combustion hearth (fireproof finish)
2b hearth (casting grating)
3a outer wall (made of concrete)
3b Outer wall (internal fireproof finish)
4a Bulkhead (= inner wall, combustion furnace side fireproof finish)
4b Opening (combustion gas passage)
5a Roof (concrete)
5b Roof (internal fireproof finish)
6 Ash storage pit 7 Firewood entry / exit fire prevention shutter 8 Fuel (sawmill sawn) fire door 9 Ash storage pit management fire door 10a Smoke collection pit (also used as drainage pit)
10b Chimney 10c Chimney 10d Flue protection concrete 11 Log (vertical)
12 Fuel (sawmill waste)
DESCRIPTION OF SYMBOLS 13 Supply air fan 14 Supply electric damper 15 Combustion gas 16 Combustion exhaust gas 17 Fresh air 18 Circulating smoke gas 19 Temperature sensor 20 Automatic control panel 21 Smoke circulation fan 22 Smoke circulation duct

Claims (6)

耐火性を有し、廃材(主には製材廃材)を燃料とする燃焼炉と、燃焼ガス、燻煙熱等の直焚きの熱エネルギー(以降燃焼ガスと言う)を通過させる為の開口(ダクト等を含む以降開口と言う)を有する壁(以降隔壁と言う)で接続され、耐熱又は耐火性を有する密閉乾燥処理場所(以降処理窯と言う)とで構成され、処理窯内部の被処理物体(原木や半製材品の木材等で、以降便宜上代表して原木と言う)の頂部又はその上部に燃焼ガスを直接導入することを均一乾燥の第1手段とすることを特徴とする燃焼ガス乾燥処理方式  Combustion furnace that has fire resistance and uses waste materials (mainly sawmill waste) as fuel, and an opening (duct) for passing direct heat energy (hereinafter referred to as combustion gas) such as combustion gas and smoke heat Are connected to a wall (hereinafter referred to as a partition wall) having a heat-resistant or fire-resistant sealed drying processing place (hereinafter referred to as a processing kiln), and an object to be processed inside the processing kiln. Combustion gas drying characterized in that the first means of uniform drying is to directly introduce the combustion gas to the top of or the top of (a raw wood or a semi-timber lumber, etc., hereinafter referred to as a raw wood for convenience) Processing method 請求項1の処理窯の上部に導入された燃焼ガスが窯上部に満たされることで窯の圧力が僅かに上がり、このこと自体で窯内部全体の圧力が窯内部の上下の温度差に関わらず均一化され、燃焼ガスを原木に均一に作用させることの第2手段として、処理窯からの排気ガス等(主に製材廃材を燃料とする燃焼ガスや燻煙熱処理に伴う原木含有水分等の蒸発ガス等で以降便宜上煙と言う)の出口(煙道または煙突の入口に相当する場所)を処理窯の下部である床面または床面に近い壁面等に設けることを特徴とする燃焼ガス乾燥処理方式  The combustion gas introduced into the upper part of the treatment kiln according to claim 1 is filled in the upper part of the kiln, so that the pressure of the kiln rises slightly. As a second means of making the combustion gas uniformly act on the raw wood, the exhaust gas from the processing kiln (evaporation of the raw wood-containing moisture accompanying the heat treatment mainly from the sawdust waste and the smoke heat treatment) Combustion gas drying process characterized by providing an outlet (a place corresponding to the entrance of a flue or chimney) for gas or the like on the floor surface near the floor or the bottom of the processing kiln. method 請求項1及び請求項2の処理窯の乾燥処理にあって、乾燥処理期間を極端に短縮させるばかりではなく、乾燥の均一性を原理的且つ、飛躍的に向上させる手段として原木を処理窯の中で垂直(以降縦置きと言う)に置き処理することを特徴とする燃焼ガス乾燥処理方式  In the drying treatment of the treatment kilns according to claim 1 and claim 2, not only drastically shortening the drying treatment period, but also using raw wood as a means for drastically improving drying uniformity in principle. Combustion gas drying process characterized by vertical processing (hereinafter referred to as vertical installation) 請求項1の燃焼炉の燃焼方式を自然通風式で運転する場合、請求項2の煙道または煙突手段にあって煙道、煙突が外気の気候条件に依り冷却等で理論通風力の低下を招く場合がある。この理論通風力の低下分を補足することを目的として、処理窯の煙の出口に接続された煙道や煙突を燃焼炉の中を通過させて外気に排気させることを手段及び特徴とする燃焼ガス乾燥処理方式  When the combustion method of the combustion furnace of claim 1 is operated by natural ventilation, the theoretical wind power is reduced by cooling or the like in the flue or chimney means of claim 2 depending on the climatic conditions of the outside air. May invite. Combustion characterized by means and characteristics of exhausting the flue and chimney connected to the smoke outlet of the processing kiln through the combustion furnace to the outside air for the purpose of supplementing this theoretical decrease in wind power Gas drying treatment method 請求項1から請求項4等で構成される本発明の燃焼ガス乾燥処理方式の処理運転中で温度調節を必要としない場合にあっても、高温度を伴わない燻煙ガスを安定して処理窯に送る事を目的とし、処理窯と燃焼炉の間に燻煙循環ダクト及び燻煙循環ファンを設けることを手段とする燃焼ガス乾燥処理方式  Even if the temperature adjustment is not required during the treatment operation of the combustion gas drying treatment method of the present invention constituted by claim 1 to claim 4, etc., the smoke gas without high temperature is stably treated. Combustion gas drying treatment system with the purpose of providing a smoke circulation duct and a smoke circulation fan between the treatment furnace and the combustion furnace for the purpose of sending to the kiln 請求項1の処理窯の内部温度を設定温度又は適正温度に長時間に亘り無人化自動運転調節する目的として温度センサー、調節器(コンピューターを含む以降CPUと言う)等により、給気ファン、電動ダンパー等で燃焼炉の燃焼空気量を調節することを手段とする燃焼ガス乾燥処理方式  A temperature sensor, a regulator (including a computer, hereinafter referred to as a CPU), etc. for the purpose of adjusting the internal temperature of the processing furnace of claim 1 to a set temperature or an appropriate temperature for an unmanned automatic operation over a long period of time. Combustion gas drying method using a damper to adjust the amount of combustion air in the combustion furnace
JP2004127330A 2004-03-29 2004-03-29 Combustion gas drying system Pending JP2005283082A (en)

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JP2005238533A (en) * 2004-02-25 2005-09-08 Makita Corp Reciprocating saw
US8034508B2 (en) 2005-09-03 2011-10-11 Samsung Sdi Co., Ltd. Polybenzoxazine-based compound, electrolyte membrane including the same, and fuel cell employing the electrolyte membrane
US8148028B2 (en) 2006-05-29 2012-04-03 Samsung Sdi Co., Ltd. Polybenzoxazines, electrolyte membrane comprising the same, and fuel cell employing the electrolyte membrane
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JP2005238533A (en) * 2004-02-25 2005-09-08 Makita Corp Reciprocating saw
US8349515B2 (en) 2005-09-03 2013-01-08 Samsung Sdi Co., Ltd. Polybenzoxazine-based compound, electrolyte membrane including the same, and fuel cell employing the electrolyte membrane
US8034508B2 (en) 2005-09-03 2011-10-11 Samsung Sdi Co., Ltd. Polybenzoxazine-based compound, electrolyte membrane including the same, and fuel cell employing the electrolyte membrane
US8426081B2 (en) 2005-09-03 2013-04-23 Samsung Sdi Co., Ltd. Polybenzoxazine-based compound, electrolyte membrane including the same, and fuel cell employing the electrolyte membrane
US8580455B2 (en) 2006-05-29 2013-11-12 Samsung Sdi Co., Ltd. Crosslinked polybenzoxazines, electrolyte membrane including the same, and fuel cell employing the electrolyte membrane
US8148028B2 (en) 2006-05-29 2012-04-03 Samsung Sdi Co., Ltd. Polybenzoxazines, electrolyte membrane comprising the same, and fuel cell employing the electrolyte membrane
US8679699B2 (en) 2006-08-22 2014-03-25 Samsung Sdi Co., Ltd Membrane electrode assembly for fuel cell and fuel cell employing the same
US9243012B2 (en) 2007-09-11 2016-01-26 Samsung Electronics Co., Ltd. Phosphorous containing benzoxazine-based monomer, or polymer thereof
US8252890B2 (en) 2007-09-11 2012-08-28 Samsung Electronics Co., Ltd. Benzoxazine-based monomer, polymer thereof, electrode for fuel cell including the same, electrolyte membrane for fuel cell including the same, and fuel cell using the same
US8192892B2 (en) 2007-09-11 2012-06-05 Samsung Electronics Co., Ltd. Phosphorous containing benzoxazine-based monomer, polymer thereof, electrode for fuel cell including the same, electrolyte membrane for fuel cell including the same, and fuel cell employing the same
US8715881B2 (en) 2007-09-11 2014-05-06 Samsung Electronics Co., Ltd. Benzoxazine-based monomer, polymer thereof, electrode for fuel cell including the same, electrolyte membrane for fuel cell including the same, and fuel cell using the same
US8298450B2 (en) 2007-10-11 2012-10-30 Samsung Electronics Co., Ltd. Polybenzimidazole-base complex, crosslinked material of polybenzoxazines formed thereof, and fuel cell using the same
US8323849B2 (en) 2007-11-02 2012-12-04 Samsung Electronics Co., Ltd. Electrolyte membrane containing a crosslinked polybenzoxazine-based compound for fuel cell and fuel cell using the same
US8512914B2 (en) 2007-11-02 2013-08-20 Samsung Electronics Co., Ltd. Phosphorus containing benzoxazine-based monomer, polymer thereof, electrode for fuel cell including the polymer, electrolyte membrane for fuel cell including the polymer, and fuel cell using the electrode
US8551669B2 (en) 2007-11-02 2013-10-08 Samsung Electronics Co., Ltd. Naphthoxazine benzoxazine-based monomer, polymer thereof, electrode for fuel cell including the polymer, electrolyte membrane for fuel cell including the polymer, and fuel cell using the electrode
US8188210B2 (en) 2007-11-02 2012-05-29 Samsung Electronics Co., Ltd. Naphthoxazine benzoxazine-based monomer, polymer thereof, electrode for fuel cell including the polymer, electrolyte membrane for fuel cell including the polymer, and fuel cell using the electrode
US8808941B2 (en) 2007-11-02 2014-08-19 Samsung Electronics Co., Ltd. Naphthoxazine benzoxazine-based monomer, polymer thereof, electrode for fuel cell including the polymer, electrolyte membrane for fuel cell including the polymer, and fuel cell using the electrode
US8227138B2 (en) 2007-11-02 2012-07-24 Samsung Electronics Co., Ltd. Phosphorus containing benzoxazine-based monomer, polymer thereof, electrode for fuel cell including the polymer, electrolyte membrane for fuel cell including the polymer, and fuel cell using the electrode
US8507148B2 (en) 2007-11-06 2013-08-13 Samsung Electronics Co., Ltd. Benzoxazine-based monomer, polymer thereof, electrode for fuel cell including the polymer, electrolyte membrane for fuel cell including the polymer, and fuel cell using the electrode
US8187766B2 (en) 2007-11-06 2012-05-29 Samsung Electronics Co., Ltd. Benzoxazine-based monomer, polymer thereof, electrode for fuel cell including the polymer, electrolyte membrane for fuel cell including the polymer, and fuel cell using the electrode
US8628895B2 (en) 2008-12-16 2014-01-14 Samsung Electronics Co., Ltd. Hyper-branched polymer, electrode including the polymer, electrolyte membrane including the polymer, and fuel cell including the electrode and/or the electrolyte membrane
JP2017080994A (en) * 2015-10-28 2017-05-18 有限会社宮内工務店 Smoking apparatus of lumber
CN106855347A (en) * 2015-12-08 2017-06-16 安徽友力节能设备有限公司 A kind of tea drier

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