JP2005254159A - Waste water treatment system and waste gas treatment system using the same - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a waste water treatment system by which the amount of the sludge to be generated can be reduced drastically and waste water can be treated efficiently and to provide a waste gas treatment system. <P>SOLUTION: This waste water treatment system is provided with: a fluorine treatment apparatus for removing fluorine in waste water; a heavy metal treatment apparatus for removing alkali metals and heavy metals in waste water; and a COD treatment apparatus for removing a COD component in waste water. The fluorine treatment apparatus is provided with: a reaction tank in which the pH of waste water is adjusted and the pH-adjusted fluorine-containing waste water is mixed with a calcium preparation, calcium fluoride and a macromolecular flocculant; a flocculation tank for flocculating calcium fluoride in the liquid mixture obtained in the reaction tank; and a precipitation tank for precipitating/separating the liquid mixture sent from the flocculation tank. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

  The present invention relates to a wastewater treatment system and an exhaust gas treatment system using the same.

Wastewater discharged from electronic industries such as semiconductor-related industries, power plants, and aluminum industries contains environmental pollutants such as fluorine, alkali metals, heavy metals, and COD components. A system that can be efficiently removed from the environment has been developed (for example, see Patent Document 1).
Thermal nuclear power generation, “Reduction of sludge generated in coal-fired flue gas desulfurization effluent treatment (Part 2)” Shigeo Shirakura, Yoshihiro Eto, Tadashi Takadoi, Ikuo Miura, Vol.33, No.12, pp.1319-1324 (1982)

  However, if the system is used to efficiently remove environmental pollutants from wastewater, a large amount of chemicals is required, and a large amount of sludge is generated by treating the wastewater.

  In recent years, sludge needs to be treated as industrial waste, and is in a situation where a large amount of cost is required. On the other hand, it is difficult to secure a landfill site for industrial waste disposal, and landfill disposal costs tend to increase.

  Therefore, an object of the present invention is to provide a wastewater treatment system capable of significantly reducing the amount of sludge generated and capable of efficiently treating wastewater, and an exhaust gas treatment system using the wastewater treatment system.

  In order to solve the above problems, a wastewater treatment system according to the present invention includes a fluorine treatment device that removes fluorine in wastewater, a heavy metal treatment device that removes alkali metals and heavy metals in the wastewater, and COD in the wastewater. In the wastewater treatment system comprising a COD treatment device for removing components, the fluorine treatment device comprises a coagulation tank for coagulating calcium fluoride in a mixed solution in which wastewater, calcium agent, seed crystal, and polymer flocculant are mixed. I will prepare. The fluorine treatment apparatus further includes separation means for separating and collecting the seed crystals collected together when the aggregated calcium fluoride is collected by centrifugal force, and regenerating the seed crystals collected by the separation means. A separation means for separating and recovering seed crystals having a particle diameter of only 5 to 100 μm among the seed crystals recovered together when recovering the aggregated calcium fluoride. Means and means for reusing the seed crystals recovered by the separation means.

  Moreover, the waste water treatment system according to the present invention includes a fluorine treatment device that removes fluorine in waste water, a heavy metal treatment device that removes alkali metals and heavy metals in the waste water, and a COD treatment that removes COD components in the waste water. In the wastewater treatment system comprising an apparatus, the fluorine treatment apparatus comprises: a reaction tank for mixing drainage, calcium agent, seed crystal, and polymer flocculant to prepare a mixed liquid; and a mixed liquid sent from the reaction tank A coagulation tank for coagulating calcium fluoride therein and a precipitation tank for precipitating and separating the mixed solution sent from the coagulation tank are provided. The fluorine treatment apparatus further includes a separating means for separating and recovering seed crystals from the precipitate separated by the precipitation tank by centrifugal force, and a means for adding the seed crystals recovered by the separating means to the reaction tank; The separation means for separating and recovering seed crystals having a particle size of 5 to 100 μm from the precipitate separated by the precipitation tank, and the reaction of the seed crystals recovered by the separation means. It is good also as providing the means to add to a tank.

  Examples of the separation means include a centrifugal separator such as a hydrocyclone (including a hydrocyclone and a high performance hydrocyclone), a centrifugal sedimentation separator, a centrifugal filtration separator, a centrifugal dehydrator, a filter, a pressure dehydration separator, and the like. Can be used. In addition, when separating and recovering seed crystals having a particle size in the range of 5 to 100 μm from the precipitate, for example, a centrifugal separator such as a liquid cyclone or a centrifugal sedimentation separator can be used. In addition, the heavy metal treatment apparatus includes a reaction tank that mixes the waste water and the polymer flocculant to prepare a mixed liquid, and a precipitation tank that precipitates and separates the mixed liquid sent from the reaction tank, It is good also as a means to add the deposit isolate | separated by the settling tank to a fluorine treatment apparatus as a pH adjuster of waste_water | drain.

  The exhaust gas treatment system according to the present invention recovers the dust removing agent containing the solid component after contacting the solid component in the exhaust gas with the dust removing agent, and uses the dust removing agent containing the solid component as waste water. A dust removing device that removes solid components in the exhaust gas by discharging to the waste gas, a fluorine treatment device that removes fluorine in the waste water discharged from the dust removing device, and an alkali metal and heavy metal in the waste water are removed. In an exhaust gas treatment system comprising a heavy metal treatment device and a COD treatment device that removes a COD component in the wastewater, the fluorine treatment device is in a mixed liquid in which wastewater, calcium agent, seed crystal, and polymer flocculant are mixed. And a coagulation tank for coagulating calcium fluoride.

  Further, the exhaust gas treatment system according to the present invention collects the dust removing agent containing the solid component after contacting the solid component in the exhaust gas with the dust removing agent, and uses the dust removing agent containing the solid component as waste water. A dust removing device that removes solid components in exhaust gas by discharging out of the system, a fluorine treatment device that removes fluorine in the waste water discharged from the dust removing device, and alkali metals and heavy metals in the waste water. In an exhaust gas treatment system comprising a heavy metal treatment device to be removed and a COD treatment device to remove a COD component in the waste water, the fluorine treatment device mixes waste water, calcium agent, calcium fluoride, and a polymer flocculant. A reaction tank for preparing a liquid mixture, a coagulation tank for aggregating calcium fluoride in the liquid mixture sent from the reaction tank, and a settling tank for precipitating and separating the liquid mixture sent from the coagulation tank. And further comprising a vessel, a.

  In addition, after making the exhaust gas treatment system which concerns on this invention contact the sulfur oxide contained in the exhaust gas from which the said solid component was removed, and the desulfurization agent, the desulfurization agent containing the said sulfur compound is collect | recovered, and the said sulfur oxide An absorption tower that removes sulfur oxides in the exhaust gas by discharging a desulfurization agent that contains sulfur to the outside of the system, and a desulfurization agent that contains the sulfur oxide discharged from the absorption tower into a solid component and a liquid component It is good also as providing further the solid-liquid separation means which isolate | separates and discharges a liquid component out of the system as waste water.

  The seed crystal is, for example, calcium fluoride. As the calcium agent, any calcium or a compound thereof may be used, but calcium carbonate (limestone, marble, etc.), gypsum, apatite, hydroxyapatite is capable of preventing scaling due to excessive injection of calcium. It is preferable to use a poorly soluble calcium agent such as (bone powder) or calcium phosphate. The polymer flocculant may be anionic, nonionic or cationic as long as it can agglomerate calcium fluoride, but it can agglomerate calcium fluoride efficiently. It is preferable to use an anionic flocculant having a weak anion to a medium anion. The anionic flocculant used as the polymer flocculant preferably has a colloid equivalent value in the range of -0.7 to -7.0 meq / g, and the colloid equivalent value is -0.7 to --2. Those within the range of .8 meq / g are particularly preferred.

  ADVANTAGE OF THE INVENTION According to this invention, the generation amount of sludge can be reduced significantly and the waste water treatment system and waste gas treatment system which can process waste_water | drain efficiently can be provided.

  Hereinafter, preferred embodiments will be described in detail with reference to the accompanying drawings.

=== Configuration diagram of wastewater treatment system ===
FIG. 1 shows a configuration diagram of an exhaust gas treatment system provided with a wastewater treatment system described as an embodiment of the present invention.

  As shown in FIG. 1, the exhaust gas treatment system includes a desulfurization apparatus 100, a waste water treatment system, and the like. The wastewater treatment system includes a fluorine treatment device 200, a heavy metal treatment device 500, a filtration device 600, a COD treatment device 700, a COD adsorption tower regeneration waste liquid treatment device 800, a discharge tank 900, and the like.

  The desulfurization apparatus 100 includes a dedusting tower (dedusting apparatus) 110, an absorption tower 120, a sedimentation concentration tank 130, and the like, and the dedusting tower 110 and the absorption tower 120 are connected by a pipe 2. The dust removal tower 110 removes a solid component (SS component) contained in the exhaust gas with a dust removal agent (for example, water such as clean water, seawater, wastewater treatment water, industrial water, and river water). The dedusting tower 110 has a pipe 1 for supplying exhaust gas and a pipe 2 for discharging exhaust gas from which SS components such as dust (alumina, silica, etc.), soot, sulfur compounds, nitrogen compounds, and fluorine compounds are removed. A pipe 3 for discharging the dust removing agent (slurry) containing the SS component, a pipe 6 for introducing the dust removing agent into the tower, and a dust removing agent containing the SS component discharged by the pipe 3 A pipe 4 for introducing a part into the tower is connected. The pipe 5 connected to the pipe 3 is for discharging a part of the dust removing agent including the SS component discharged from the dust removing tower 110 to the cooling bath 140.

  The absorption tower 120 is for removing sulfur oxide (SOx) contained in the exhaust gas. The absorption tower 120 includes a pipe 7 for discharging the desulfurized exhaust gas, and a pipe 8 for introducing a desulfurization agent (for example, a slurry solution containing limestone) from the exhaust gas into the tower. A pipe 9 for discharging the slurry containing the product obtained by the reaction between the sulfur oxide and the desulfurizing agent, and a pipe 10 for returning a part of the slurry discharged through the pipe 9 into the tower. ing.

  A sedimentation and concentration tank 130 such as a thickener is installed downstream of the absorption tower 120. A pipe 10 for returning the desulfurization agent separated in the tank to the absorption tower 120 is connected to the sedimentation concentration tank 130.

  The fluorine treatment apparatus 200 is for removing fluorine contained in the cooling system desulfurization drainage discharged from the cooling bath 140. The fluorine treatment apparatus 200 includes a neutralization tank (reaction tank) 210, an ultrafast coagulation sedimentation tank 220, and the like. The neutralization tank 210 adjusts the pH of the cooling system desulfurization drainage, or mixes the calcium agent, calcium fluoride, and the polymer flocculant (organic coagulant) with the pH adjustment of the cooling system desulfurization drainage. Is to do. The ultrahigh-speed coagulation sedimentation tank 220 is for coagulating and precipitating calcium fluoride produced by reacting fluorine in the waste water with the calcium agent and separating it into a supernatant and ash. The ultra-high-speed coagulation sedimentation tank 220 includes, for example, a coagulation tank that coagulates calcium fluoride generated by reacting fluorine in a waste water with a calcium agent, and sludge that concentrates ash containing the aggregated calcium fluoride to a high concentration. And a concentrating tank.

  The heavy metal processing apparatus 500 is for removing alkali metals and heavy metals in waste water. The heavy metal processing apparatus 500 includes a reaction tank (heavy metal processing tank) 520, a precipitation tank 530, and the like. The reaction tank 520 is for mixing waste water and a polymer flocculant using, for example, a stirrer. The sedimentation tank 530 is used for solid-liquid separation of alkali metals and heavy metals aggregated by the polymer flocculant.

  The filtration device 600 is for removing the SS component in the waste water, and includes a pH adjustment tank 610, a filter 620, and the like. The pH adjustment tank 610 is for adjusting the pH of the waste water to 4 to 5 in order to maintain the COD adsorption performance of the COD adsorption tower 710 described later. The filter 620 is for removing the SS component in the waste water to such an extent that the COD adsorption tower 710 does not cause any harmful effects.

  The COD processing apparatus 700 is for removing COD components in the waste water, and includes a COD adsorption tower 710, a neutralization processing tank 720, and the like. The COD adsorption tower 710 is for adsorbing and removing COD components contained in the wastewater, and the neutralization tank 720 is for adjusting the pH to 7 to 8.3 in order to discharge the wastewater from which COD has been removed. is there. The COD adsorption tower regeneration waste liquid treatment apparatus 800 is for treating the COD component removed by the COD adsorption tower 710. The discharge tank 900 is for temporarily storing the wastewater in order to measure the pH and turbidity of the wastewater from which the SS component, alkali metal, heavy metal, COD component and the like have been removed to confirm that there is no abnormality.

  Next, an example of the processing procedure of the exhaust gas processing system in the present embodiment will be described.

  Exhaust gas generated when fuel such as coal is burned is supplied to the dust removing tower 110 through the pipe 1. In the dedusting tower 110, a dust removing agent replenished from the pipe 6 is sprayed to remove SS components such as dust (alumina, silica, etc.), soot dust, sulfur compounds, nitrogen compounds, and fluorine compounds contained in the exhaust gas. . The exhaust gas from which the SS component has been removed is discharged from the pipe 2. The dust removing agent that has absorbed the SS component in the dust removing tower 110 is discharged to the cooling tank 140 through the pipes 3 and 5. A part of the dust removing agent that has absorbed the SS component is returned to the dust removing tower 110 through the pipes 3 and 4.

  The cooling system desulfurization waste water cooled in the cooling tank 140 is transferred to the neutralization tank 210 and adjusted to pH 7-9. Then, a calcium agent is added to the cooling system desulfurization drainage adjusted to pH 7.0 to generate calcium fluoride, and then calcium fluoride as a seed crystal and a polymer flocculant are added to use the seed crystal as a nucleus. A floc is formed and coagulated and precipitated in the ultrahigh-speed coagulating sedimentation tank 220. The precipitate that has been coagulated and precipitated in the ultrafast coagulating sedimentation tank 220 is discharged as ash, and the supernatant is transferred to the storage tank 310. If necessary, an inorganic flocculant (such as a sulfuric acid band) may be added to the wastewater in the neutralization tank 210.

  On the other hand, the exhaust gas dedusted by the dedusting tower 110 is sent to the absorption tower 120 through the pipe 2. In the absorption tower 120, the desulfurization agent supplied from the pipes 8, 10 is sprayed to absorb the sulfur oxide contained in the exhaust gas, and the desulfurization agent (slurry) that has absorbed the sulfur oxide is discharged to the sedimentation concentration tank 130. To do. A part of the slurry is circulated to the absorption tower 120 through the pipes 9 and 10 as a desulfurization agent. The exhaust gas desulfurized in the absorption tower 120 is discharged through the pipe 7.

  In the sedimentation concentration tank 130, the slurry is concentrated and settled, and gypsum is taken out therefrom. The extracted gypsum is dehydrated by a dehydrator or the like and effectively used as a raw material for cement or gypsum board. Absorption desulfurization waste water from which gypsum is removed in the sedimentation concentration tank 130 is discharged to the storage tank 310. A part of the absorption desulfurization waste water in the sedimentation tank 130 is circulated to the absorption tower 120 through the pipe 10. As described above, the desulfurization apparatus 100 including the dedusting tower 110 and the absorption tower 120 can remove SS components and sulfur oxides that cause environmental pollution from the exhaust gas. It becomes possible to prevent.

  Waste water collected in the storage tank 310 is transferred to the reaction tank 520 via the relay tank 510. In the reaction tank 520, after adding a polymer flocculant to the waste water adjusted to pH 10-11 by injecting an alkaline agent (for example, caustic soda) while stirring with a stirrer, the alkali metal in the waste water in the precipitation tank 530 Heavy metals are agglomerated and precipitated as hydroxides. The supernatant water settled and separated by the coagulation sedimentation is transferred to the pH adjusting tank 610. At this stage, the fluorine concentration is such that it can be discharged (concentration lower than 10 mg / l). On the other hand, flocs (sludge; mainly containing magnesium hydroxide, aluminum hydroxide, etc.) separated by coagulation sedimentation are used for neutralization of desulfurization effluent and removal of fluorine from desulfurization effluent. It is recycled to 210 and reused. Thus, by reusing flocs, the amount of alkali chemicals used can be reduced, and the amount of flocs can be reduced.

  In the pH adjusting tank 610, in order to prevent the adsorbent SS contamination of the COD adsorbing apparatus, an acidic chemical (for example, sulfuric acid) is injected into the supernatant water to adjust the pH to 3 to 4, and this is passed through the filter 620 and SS. Remove. Wastewater from which SS has been removed by the filter 620 is carried to the COD adsorption tower 710.

  In the COD adsorption tower 710, water is passed through a resin plate or activated carbon made of a synthetic adsorbent (for example, dithionate ion exchange resin, activated carbon, etc.) installed in the tower to adsorb and remove COD components from the waste water. The concentration of the COD component is set to 10 ppm or less. Wastewater having a COD component concentration of 10 ppm or less is transferred to a neutralization tank 720, adjusted to pH 7 with an alkaline agent (for example, caustic soda), and transferred to a discharge tank 900. And after measuring pH and turbidity and confirming that there is no abnormality, it discharges. On the other hand, the COD component removed by adsorption is processed by an acid thermal decomposition method using an acid-base catalytic reaction in the COD adsorption tower regeneration waste liquid treatment apparatus 800. The treated waste liquid is transferred to the storage tank 310.

  As described above, the exhaust gas treatment system 1000 according to the present invention requires a large amount of money to treat as industrial waste, and greatly reduces the amount of sludge generated in a difficult situation of securing a landfill. Can do. In addition, since the amount of chemicals used for the fluorine treatment can be significantly reduced, the total operating cost can be reduced.

  In the present embodiment, only the fluorine treatment apparatus 200 for treating high concentration fluorine is provided, but a fluorine treatment apparatus 300 for treating low concentration fluorine may be further provided. As shown in FIG. 1, the fluorine treatment apparatus 300 includes a reaction tank 320 for treating fluorine using a sulfuric acid band, a polymer flocculant, an alkaline agent, etc., and a precipitate for aluminum hydroxide and fluorine. A sedimentation tank 330, a concentration tank 340 for concentrating the sludge precipitated in the sedimentation tank 330, a sludge dewatering machine 350 for dewatering the sludge, and the like are provided.

  Moreover, it is good also as providing the nitrogen treatment apparatus 400 in the exhaust gas treatment system 1000 of this invention. Thereby, nitrogen contained in the waste water can be removed, and the concentration of nitrogen can be reduced to a predetermined value (70 ppm) or less. As shown in FIG. 1, the nitrogen treatment apparatus 400 includes a relay tank 410, a reaction tank (nitrogen treatment tank) 420 for treating nitrogen, a precipitation tank 430, and the like.

  In the above description, the fluorine treatment apparatus 200 of the exhaust gas treatment system 1000 includes the neutralization tank (reaction tank) 210, the ultrafast coagulation sedimentation tank 220, and the like, but the pH adjustment tank 1110, the reaction tank 1120, A coagulation tank 1130, a precipitation tank 1140, a pump 1150, a hydrocyclone 1170, and the like may be provided. Hereinafter, a fluorine treatment apparatus 1100 including a pH adjustment tank 1110, a reaction tank 1120, a coagulation tank 1130, a precipitation tank 1140, a pump 1150, a hydrocyclone 1170, and the like will be described.

  FIG. 2 is a block diagram of a fluorine processing apparatus 1100 described as an embodiment of the present invention. In the present embodiment, the case where the separation means is the hydrocyclone 70 will be described, but the present invention is not limited to this.

  As shown in FIG. 2, the fluorine treatment apparatus 1100 includes a pH adjustment tank 1110, a reaction tank 1120, a coagulation tank 1130, a precipitation tank 1140, a pump 1150, a hydrocyclone 1170, and the like.

  The pH adjustment tank 1110 is for adjusting the pH of the waste water. The reaction tank 1120 is for mixing a calcium agent, calcium fluoride as a seed crystal, and a polymer flocculant with wastewater whose pH is adjusted while stirring with a stirrer 1121. In the reaction tank 1120, the chemical reaction is promoted by stirring the mixed solution at a high speed.

  The aggregating tank 1130 is for aggregating the fluorine compound in the solution in the tank while stirring with the stirrer 1131. In the coagulation tank 1130, the coagulation rate of calcium fluoride (sludge floc) is promoted. Therefore, in order not to break the aggregated calcium fluoride, it is preferable to control the stirrer 31 to stir at a low speed. The sedimentation tank 1140 is for precipitating and separating the fluorinated compound aggregated from the mixed solution sent from the aggregation tank 1130.

  The hydrocyclone 1170 is for separating the sediment supplied from the sedimentation tank 1140 by the pump 1150 into sludge and chemicals for removing fluorine (for example, calcium agent and seed crystal). The size of the particle size of the chemical for removing fluorine is determined by the separation performance of the hydrocyclone 1170. Usually, a chemical having a particle size of 5 μm to 100 μm can be used, and the fluorine removal efficiency is high. It is preferable to use a chemical having a particle diameter of 5 to 30 μm at a high point, and it is particularly preferable to use a chemical having a particle diameter of 10 to 30 μm because the chemical can be reliably separated by the hydrocyclone 1170. As described above, by using the hydrocyclone 1170, the precipitate can be separated at high speed. In this embodiment, the hydrocyclone 1170 is used, but other centrifugal separators, centrifugal sedimentation separators, centrifugal filter separators, centrifugal dehydrators, filters, press dewatering separators, and the like are used. It is good.

  In the present embodiment, the deposit is supplied to the hydrocyclone 1170 through the pipe 1160. The seed crystal and calcium agent separated and recovered by the hydrocyclone 1170 are configured to be supplied to the reaction tank 1120.

  Further, in the present embodiment, pH adjustment treatment, pH-adjusted waste water, calcium agent, seed crystal, polymer flocculant, and the like, treatment for aggregating a fluorine compound from the mixed solution, and a coagulation tank The process of precipitating and separating the liquid mixture sent from 1130 is performed in separate tanks, but these processes may be performed in one tank, or these processes may be performed in two or three tanks. You may be able to perform.

Next, the processing procedure of the fluorine processing apparatus 1100 according to the present invention will be described.
The wastewater transferred from the cooling tank 140 is adjusted in the pH adjustment tank 1110 within the pH 7 to pH 10 range where the solubility of calcium fluoride is low by an alkaline agent (such as caustic soda), but is neutral pH (pH 7-8). It is preferable to adjust to. Thereby, it becomes possible to efficiently remove fluorine without dissolving calcium fluoride. In addition, in the range from neutral to weakly alkaline, sparingly soluble calcium agents dissolve in the wastewater only with low solubility, so the wastewater contains only a low concentration of calcium ions. Can be prevented. Accordingly, it is possible to prevent scaling in the piping caused by a large amount of calcium eluting, and an operation for removing calcium by the softening treatment becomes unnecessary. If necessary, an inorganic flocculant such as a sulfuric acid band may be used. By using this sulfuric acid band, the amount of sludge generated can be reduced. The inorganic flocculant is preferably added before adjusting the pH.

  Next, the pH adjusted waste water is transferred to the reaction tank 1120. And the added calcium agent and the fluorine in waste water are made to react, and the calcium fluoride (floc) which is a reaction material is formed.

  Further, in the reaction tank 1120, calcium fluoride as a seed crystal and a polymer flocculant are added, and the floc is formed with a stirrer 1131 in the aggregation tank 1130, thereby forming a heavy floc having the seed crystal as a nucleus. Thereby, the sedimentation speed of the floc can be increased, and the heavy floc can be quickly separated in the sedimentation tank 1140. It should be noted that the precipitate that is coagulated and precipitated in the precipitation tank 1140 contains seed crystals and unreacted calcium agent in addition to the floc. In this embodiment, in order to reuse the seed crystals and unreacted calcium agent contained in the precipitate, the hydrocyclone 1170 separates the seed crystal having a large particle diameter and the unreacted calcium agent from the precipitate. We are going to collect it. In addition, flocs having a small particle size are separated by a hydrocyclone 1170 and discharged as sludge. As described above, the seed crystal and the unreacted calcium agent are separated using the hydrocyclone 1170 and recycled, so that the seed crystal can be used semipermanently or the unreacted calcium agent can be effectively used. It becomes like this. Therefore, the amount of chemicals such as seed crystals and calcium agents and the amount of sludge generated can be reduced, and the total operating cost can be reduced.

  In addition, the fluorine treatment apparatuses 200 and 1100 in the wastewater treatment system and the exhaust gas treatment system 1000 according to the present embodiment include tanks (reaction tanks (neutralization tanks) 210 and 1120, agglomeration tank 1130, a precipitation tank 1140, ultrahigh-speed agglomeration However, each process may be performed in one tank, or these processes may be performed in two or more tanks. In this case, the seed crystals recovered together when recovering the calcium fluoride aggregated in the aggregation tanks 220 and 1130 are further separated and recovered by the separation means, and a predetermined tank (for example, the aggregation tank is used by the reuse means. 220, 1130, etc.). The means for reusing is, for example, a pipe connecting the hydrocyclone 1170 and a predetermined tank.

  As described above, by using the fluorine treatment apparatus 1100 according to the present invention, scaling due to calcium can be prevented and fluorine in waste water can be efficiently removed. Further, the amount of sulfuric acid band used in the conventional fluorination treatment can be minimized, and the fluorination treatment with less waste can be performed.

It is a figure which shows the structure of the waste gas treatment system provided with the waste water treatment system demonstrated as one Example of this invention. It is a figure which shows the structure of the fluorine processing apparatus demonstrated as one Example of this invention.

Explanation of symbols

DESCRIPTION OF SYMBOLS 100 Desulfurization apparatus 110 Dedusting tower 120 Absorption tower 200 Fluorine processing apparatus 310 Storage tank 500 Heavy metal processing apparatus 600 Filtration apparatus 700 COD processing apparatus 800 COD adsorption tower reproduction | regeneration waste liquid processing apparatus 900 Drain tank 1000 Exhaust gas treatment system 1100 Fluorine removal apparatus in waste water

Claims (11)

In a wastewater treatment system comprising a fluorine treatment device for removing fluorine in wastewater, a heavy metal treatment device for removing alkali metals and heavy metals in the wastewater, and a COD treatment device for removing COD components in the wastewater,
The said fluorine treatment apparatus is provided with the coagulation tank which aggregates calcium fluoride in the liquid mixture which mixed the waste_water | drain, the calcium agent, the seed crystal, and the polymer flocculent. The wastewater treatment system according to claim 1,
The fluorine treatment apparatus further recycles the seed crystals collected by the separation means, a separation means for separating and collecting the seed crystals collected together when the aggregated calcium fluoride is collected, by centrifugal force. And a wastewater treatment system comprising: means. The wastewater treatment system according to claim 1,
The fluorine treatment apparatus further includes a separation unit that separates and collects seed crystals having a particle diameter in the range of 5 to 100 μm among the seed crystals collected together when the aggregated calcium fluoride is collected, and the separation And a means for reusing the seed crystals recovered by the means. In a wastewater treatment system comprising a fluorine treatment device for removing fluorine in wastewater, a heavy metal treatment device for removing alkali metals and heavy metals in the wastewater, and a COD treatment device for removing COD components in the wastewater,
The fluorine treatment device comprises a reaction tank in which waste water, calcium agent, seed crystal, and polymer flocculant are mixed to prepare a mixed solution, and agglomeration for aggregating calcium fluoride in the mixed solution sent from the reaction vessel. A wastewater treatment system comprising: a tank; and a precipitation tank that precipitates and separates the liquid mixture sent from the aggregation tank. The waste water treatment system according to claim 4,
The fluorine treatment apparatus further includes a separating unit that separates and collects seed crystals from the precipitate separated by the settling tank by centrifugal force, and a unit that adds the seed crystals collected by the separating unit to the reaction tank. A wastewater treatment system characterized by comprising. The waste water treatment system according to claim 4,
The fluorine treatment apparatus further includes a separation unit that separates and collects seed crystals having a particle diameter of 5 to 100 μm from the precipitate separated by the precipitation tank, and a reaction tank that contains the seed crystals collected by the separation unit. And a means for adding to the wastewater treatment system. In the waste water treatment system according to any one of claims 2, 3, 5 or 6,
The waste water treatment system, wherein the separating means is a hydrocyclone. In the waste water treatment system according to any one of claims 1 to 7,
The heavy metal treatment device includes a reaction tank that mixes the waste water and the polymer flocculant to prepare a mixed liquid, and a precipitation tank that precipitates and separates the mixed liquid sent from the reaction tank,
A wastewater treatment system comprising means for adding the precipitate separated by the settling tank to a fluorine treatment apparatus as a pH adjuster for wastewater. After contacting the solid component in the exhaust gas with the dedusting agent, the dedusting agent containing the solid component is recovered, and the dedusting agent containing the solid component is discharged out of the system as waste water. A dedusting device for removing components, a fluorine treatment device for removing fluorine in the wastewater discharged from the dust removal device, a heavy metal treatment device for removing alkali metals and heavy metals in the wastewater, and in the wastewater In an exhaust gas treatment system comprising a COD treatment device for removing COD components,
The said fluorine treatment apparatus is equipped with the coagulation tank which aggregates calcium fluoride in the liquid mixture which mixed the waste_water | drain, the calcium agent, the seed crystal, and the polymer flocculent, The exhaust gas treatment system characterized by the above-mentioned. After contacting the solid component in the exhaust gas with the dedusting agent, the dedusting agent containing the solid component is recovered, and the dedusting agent containing the solid component is discharged out of the system as waste water. A dedusting device for removing components, a fluorine treatment device for removing fluorine in the wastewater discharged from the dust removal device, a heavy metal treatment device for removing alkali metals and heavy metals in the wastewater, and in the wastewater In an exhaust gas treatment system comprising a COD treatment device for removing COD components,
The fluorine treatment device mixes waste water, calcium agent, calcium fluoride, and polymer flocculant to prepare a mixed solution, and aggregates calcium fluoride in the mixed solution sent from the reaction vessel. An exhaust gas treatment system comprising: a coagulation tank; and a precipitation tank that precipitates and separates the mixed solution sent from the coagulation tank. The exhaust gas treatment system according to claim 9 or 10,
After contacting the sulfur oxide contained in the exhaust gas from which the solid component has been removed with a desulfurizing agent, the desulfurizing agent containing the sulfur compound is recovered, and the desulfurizing agent containing the sulfur oxide is discharged out of the system. An absorption tower for removing sulfur oxides in the exhaust gas, and a desulfurization agent containing the sulfur oxides discharged from the absorption tower is separated into a solid component and a liquid component, and the liquid component is discharged out of the system as waste water. An exhaust gas treatment system comprising: a solid-liquid separation means for discharging.

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