JP2005254036A - Combined contaminated soil cleaning apparatus - Google Patents

Combined contaminated soil cleaning apparatus Download PDF

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JP2005254036A
JP2005254036A JP2004065092A JP2004065092A JP2005254036A JP 2005254036 A JP2005254036 A JP 2005254036A JP 2004065092 A JP2004065092 A JP 2004065092A JP 2004065092 A JP2004065092 A JP 2004065092A JP 2005254036 A JP2005254036 A JP 2005254036A
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contaminated soil
soil
dust
classification
stirring
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JP4338029B2 (en
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Shigeru Suzuki
木 茂 鈴
Shintaro Hattori
部 新太郎 服
Tomohiro Teranishi
西 智 博 寺
Seiji Otsuka
塚 誠 治 大
Yoshikatsu Amakawa
川 義 勝 天
Yoichi Kinoshita
下 洋 一 木
Makoto Kondo
藤 眞 近
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Kajima Corp
Kajima Road Co Ltd
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Kajima Corp
Kajima Road Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a combined contaminated soil cleaning apparatus performing cleaning of the soil combined-contaminated by heavy metal, a volatile organic compound (VOC) such as a light oil having a low vaporization temperature, trichloroethylene and benzene, dioxin or the like. <P>SOLUTION: The combined contaminated soil cleaning apparatus is constituted by a rotatable cylindrical heating stirring crushing part 7 for heating, stirring and crushing the combined contaminated soil (SAo); a classification part 10 for classifying the crushed soil by a particle diameter; a drying/sorting device 3 in which a heating device 5 for feeding hot air to the heating stirring crushing part and a fixing casing 12 covering the heating stirring crushing part and the classification part are integrally constituted; an air discharge device 42 for sucking dust in the fixing casing; a dust collection duct for discharging the dust in the fixing casing to the outside; a bag filter 40 communicating with the dust collection duct; and a washing device 25 for washing the soil, of the combined contaminate soil classified by the classification part, having a remaining contamination exceeding a reference value with water. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

本発明は、重金属やガソリン、灯油、軽油等の油やトリクロロエチレン、ベンゼン等の揮発性有機化合物(VOC)、ダイオキシン(DXN)等で複合汚染された土壌を浄化処理する複合汚染土壌浄化処理装置に関する。   The present invention relates to a composite contaminated soil purification apparatus for purifying soil contaminated with heavy metals, gasoline, kerosene, light oil and other volatile organic compounds (VOC) such as trichlorethylene and benzene, dioxin (DXN) and the like. .

従来、重金属などは土壌の微細な部分に多く付着する傾向があり、そのような汚染土壌を浄化するには、たとえば処理対象土壌のすべてを水に投入して洗浄する水洗浄化が知られている(例えば、特許文献1、2、3参照)。
しかしながら、対象土壌すべてを水に投入することは大量の汚泥を作ることになり、脱水工程と大量の水処理が必須となる欠点がある。
Conventionally, heavy metals and the like tend to adhere to fine parts of the soil, and in order to purify such contaminated soil, for example, water washing is known in which all of the soil to be treated is poured into water and washed. (For example, see Patent Documents 1, 2, and 3).
However, when all the target soil is put into water, a large amount of sludge is produced, and there is a disadvantage that a dehydration step and a large amount of water treatment are essential.

また、例えばガソリン(沸点50℃〜)、灯油(沸点170℃〜)、軽油(沸点200℃〜)等の軽質油や70〜150℃で蒸発するトリクロロエチレン、ベンゼン等の揮発性有機化合物(VOC)で汚染された土壌の浄化を行うには、当該汚染土壌を加熱し、汚染物質を揮発分離したのち回収し吸着または分解することにより浄化している(例えば、特許文献4、5参照)。   Also, for example, light oils such as gasoline (boiling point 50 ° C. or higher), kerosene (boiling point 170 ° C. or higher), light oil (boiling point 200 ° C. or higher), volatile organic compounds (VOC) such as trichloroethylene and benzene that evaporate at 70 to 150 ° C. In order to purify contaminated soil, the contaminated soil is heated, volatilized and separated, and then collected and adsorbed or decomposed (see, for example, Patent Documents 4 and 5).

また、汚染土壌に適合する処理剤を混合して処理土をロータリーキルンで形成し、そこから排出された処理土から大粒径の処理土と小粒径の処理土をトロンメルで分別し大粒径の処理土を解砕機で解砕する土処理車の例もある(例えば、特許文献6参照)。   In addition, a treatment agent suitable for contaminated soil is mixed to form a treated soil with a rotary kiln, and the treated soil discharged from the treated soil is separated from the treated soil with a large particle size and the treated soil with a small particle size with a trommel. There is also an example of a soil treatment vehicle in which the treated soil is crushed by a pulverizer (see, for example, Patent Document 6).

上記のように通常は、汚染物質の性状によって各種方法別に処理していたが、今後も増加する汚染物資別の装置を使用するのではなく、1つの装置で各種汚染物質に適合する装置が必要であった。
特開平7−185513号公報(図1及びその説明参照) 特開2000−197878号公報(図1及びその説明参照) 特開2000−197879号公報(図1及びその説明参照) 特開2002−079234号公報(図1及びその説明参照) 特開2002−205049号公報(図1及びその説明参照) 特開平9−29223号公報(図1及びその説明参照)
As described above, it was usually treated for each method depending on the nature of the pollutant, but instead of using a device for each pollutant that will continue to increase in the future, it is necessary to use a single device that is compatible with each type of pollutant. Met.
JP-A-7-185513 (see FIG. 1 and its description) Japanese Unexamined Patent Publication No. 2000-197878 (see FIG. 1 and its description) Japanese Unexamined Patent Publication No. 2000-197879 (see FIG. 1 and its description) Japanese Patent Laid-Open No. 2002-079234 (see FIG. 1 and its description) JP 2002-205049 A (refer to FIG. 1 and the description thereof) Japanese Patent Laid-Open No. 9-29223 (see FIG. 1 and its description)

本発明は上述したような従来技術の様々な問題点に鑑みて提案されたものであり、重金属やガソリン、灯油、軽油等の油やトリクロロエチレン、ベンゼン等の揮発性有機化合物(VOC)、ダイオキシン(DXN)等で複合汚染された土壌を省水で浄化処理する複合汚染土壌浄化処理装置の提供を目的としている。   The present invention has been proposed in view of the various problems of the prior art as described above. Oils such as heavy metals, gasoline, kerosene and light oil, volatile organic compounds (VOC) such as trichloroethylene and benzene, dioxins ( The purpose of the present invention is to provide a complex contaminated soil purification treatment device for purifying soil contaminated with DXN) etc. with water saving.

本発明者は種々研究の結果、汚染土壌は粒度が細かい方が汚染物質の付着が多く、粒度が大きいほど汚染物質の付着が比較的に少ないことが解かった。そして粒度が大きい汚染土壌は汚染の程度が少ないので、加熱処理が比較的に容易であるから、粒度の細かい汚染土壌と共に全量を水洗浄化をする必要がないことがわかった。本発明による汚染土壌浄化処理装置では、上記に基づいて水洗浄化処理の負荷を軽減させるようにしている。   As a result of various studies, the present inventor has found that the contaminated soil has a smaller particle size, and the larger the particle size, the smaller the particle size. And since contaminated soil with a large particle size has a low degree of contamination, it was found that heat treatment is relatively easy, so that it is not necessary to wash the whole amount with contaminated soil with a fine particle size. In the contaminated soil purification treatment apparatus according to the present invention, the load of the water washing treatment is reduced based on the above.

本発明の複合汚染土壌浄化処理装置によれば、複合汚染土壌(SAo)を加熱して攪拌し粉砕する回転自在な円筒状の加熱攪拌粉砕部(7)と、加熱攪拌粉砕部(7)で粉砕された複合汚染土壌(SAo)を粒径によって分級する回転自在な円筒状の分級部(10)と、前記加熱攪拌粉砕部(7)に熱気を供給する加熱装置(5)と、加熱攪拌粉砕部(7)と分級部(10)とを被覆する固定ケーシング(12)とが一体に構成される乾燥選別装置(3)と、固定ケーシング(12)内のダストを吸引する排風装置(42)と、固定ケーシング(12)に設けられて固定ケーシング内のダストを外部に排出するライン(L12)と、そのライン(L12)に連通された集塵装置(40)と、前記分級部(7)で分級された小径の複合汚染土壌(SAo)のうちの残留汚染が基準値をこえるものを水洗する洗浄処理装置(25)とで構成されている(請求項1)。   According to the composite contaminated soil purification treatment apparatus of the present invention, a rotatable cylindrical heated stirring and pulverizing unit (7) for heating, stirring and pulverizing the composite contaminated soil (SAo), and a heated and stirred pulverizing unit (7). A rotatable cylindrical classification unit (10) for classifying the pulverized composite contaminated soil (SAo) according to particle size, a heating device (5) for supplying hot air to the heating and agitation crushing unit (7), and heating and agitation A dry sorting device (3) in which a fixed casing (12) that covers the pulverization unit (7) and the classification unit (10) is integrally formed, and an air exhaust device that sucks dust in the fixed casing (12) ( 42), a line (L12) provided in the fixed casing (12) for discharging the dust in the fixed casing to the outside, a dust collector (40) communicated with the line (L12), and the classification unit ( Small-diameter complex contaminated soil classified in 7) Residual contamination of SAo) is constituted out with cleaning apparatus for washing those exceeding the reference value (25) (claim 1).

本発明の具体的な実施にあたっては、加熱攪拌粉砕部と分級部とはシリーズに連通した一体に構成し、その軸心を加熱攪拌粉砕部が分級部より高くするように水平に対して傾斜させて、回転する汚染土壌が分級部方向に移動するように構成し、加熱攪拌粉砕部および分級部で発生した汚染物質を含むダストを集塵ダストから集塵装置に供給させる。集塵装置は、湿式の微粉水洗装置でも乾式の集塵バッグ、のいずれでもよい。
また、分級部で粒径に応じて分級された土壌は、汚染物資が除去されたか否かを公定分析して、無害であれば再生土として埋め戻しをし、汚染物資の除去が未了であれば従来の公知の洗浄処理装置によって洗浄処理を行う。これによって、従来のように汚染土壌のすべてを洗浄処理装置で処理することなく、洗浄処理を行う必要のある土壌のみを洗浄処理装置に供給するので洗浄処理装置の負荷が軽減して、汚染土壌の浄化処理量が増加する。
In a specific implementation of the present invention, the heating and stirring pulverizing unit and the classifying unit are integrally formed in communication with the series, and the axis is inclined with respect to the horizontal so that the heating and stirring and pulverizing unit is higher than the classifying unit. Thus, the rotating contaminated soil moves in the direction of the classifying unit, and the dust containing the pollutants generated in the heating and stirring pulverizing unit and the classifying unit is supplied from the dust collecting dust to the dust collecting device. The dust collector may be either a wet fine powder washing device or a dry dust bag.
In addition, the soil classified according to the particle size in the classification section is officially analyzed to determine whether or not the pollutant has been removed.If it is harmless, it is backfilled as reclaimed soil, and the removal of the pollutant has not been completed. If there is, a cleaning process is performed by a conventional known cleaning apparatus. As a result, only the soil that needs to be cleaned is supplied to the cleaning apparatus without processing all of the contaminated soil with the cleaning apparatus as in the past, so the load on the cleaning apparatus is reduced and the contaminated soil is reduced. The amount of purification treatment increases.

前記加熱攪拌粉砕部(7)は、攪拌羽根(7a)が装着されて塊状の複合汚染土壌(SAo)をほぐす加熱攪拌部分(7A)と、加熱されほぐされた複合汚染土壌(SAo)を粉砕する多数の粉砕鋼球(8)が移動自在に収容されているボールミル部分(7B)とで構成されていることが好ましい(請求項2)。   The heated stirring and pulverizing unit (7) is equipped with a stirring blade (7a) and pulverizes the heated and stirred portion (7A) for loosening the massive composite contaminated soil (SAo) and the heated and loosened composite contaminated soil (SAo). The ball mill portion (7B) in which a large number of pulverized steel balls (8) are movably accommodated is preferable (claim 2).

実施にあたっては、加熱攪拌粉砕部の加熱攪拌部分がシリーズに複数個あってもよく、ボールミル部分に収容される粉砕鋼球が分級部に移動しないよう構成することが必要である。   In implementation, there may be a plurality of heating and stirring portions of the heating and stirring pulverization unit in the series, and it is necessary to configure so that the pulverized steel balls accommodated in the ball mill portion do not move to the classification unit.

前記分級部(10)は網目の異なる複数の分級装置(10A、10B)で構成されていることが好ましい(請求項3)。   It is preferable that the classification unit (10) includes a plurality of classification devices (10A, 10B) having different meshes (Claim 3).

実施にあたっては、網目の細かいものから、粗いものまで分級装置が多いほうが、汚染物資が除去されたか否かの検査精度が向上して分級の効果が発揮される。   In the implementation, the more the classification device is from fine mesh to coarse one, the accuracy of the inspection of whether or not contaminants have been removed is improved and the effect of classification is exhibited.

前記分級部(10)に分級された土壌を攪拌する攪拌用圧縮空気を吹き付けるエアレーションノズル(15)が取付けられ、分級された土壌に冷却用水を吹き付ける散水ノズル(16)が取付けられていることが好ましい(請求項4)。   An aeration nozzle (15) for blowing compressed air for stirring that stirs the classified soil is attached to the classification unit (10), and a water spray nozzle (16) for blowing cooling water to the classified soil is attached. Preferred (claim 4).

散水ノズルは土壌に付着している汚染物資を気化させて除去する作用と、排出する土壌を危険のない温度にする作用を行はせる。エアレーションノズルは土壌を浮遊させ汚染物質をダストとして集塵装置に供給する作用を行はせる。   The watering nozzle can perform the action of vaporizing and removing the contaminants adhering to the soil and the action of bringing the discharged soil to a non-hazardous temperature. The aeration nozzle floats the soil and allows the contaminants to be supplied as dust to the dust collector.

本発明の作用効果を以下に列挙する。
(a) 本発明によれば、加熱攪拌粉砕部で油分、揮発性有機成分(VOC)等が揮発されてサイクロン、集塵装置でダストが分離されて無害処理をされた後に大気に開放される。また、粉砕された土壌の粒径を分級部で分級して重金属の付着しにくい大粒径土壌は基準値以下であれば、従来方式の洗浄処理装置で処理させるので、従来のような全汚染土壌を洗浄処理装置に投入せず、水洗量が少なく洗浄処理装置の負荷を軽減できる。
(b) 複合汚染土壌を加熱、粉砕水洗浄化するので、油分、揮発性有機物化合物、重金属、DXN等による複合汚染土壌全般の処理が可能である。
(c) 従来と異なり、溶液を用いて湿式分級することなく乾式で土壌粒子を分級できる。
(d) 洗浄分級に適している粒子の土壌のみを洗浄処理装置で汚染物質を分離できる。
The effects of the present invention are listed below.
(A) According to the present invention, oil, volatile organic components (VOC), and the like are volatilized in the heated stirring and pulverizing unit, and dust is separated in the cyclone and dust collector, and then released to the atmosphere. . In addition, if the particle size of the pulverized soil is classified by the classification part and the large particle size soil that is difficult for heavy metals to adhere to is less than the standard value, it is treated with a conventional cleaning treatment device, so conventional total contamination The soil is not thrown into the cleaning processing apparatus, and the amount of water washing is small, and the load of the cleaning processing apparatus can be reduced.
(B) Since the complex-contaminated soil is heated and washed with pulverized water, the entire complex-contaminated soil can be treated with oil, volatile organic compounds, heavy metals, DXN, and the like.
(C) Unlike conventional methods, soil particles can be classified by a dry method without using a solution to perform wet classification.
(D) Only the soil of particles suitable for cleaning classification can be separated with a cleaning treatment device.

以下、添付図面を参照して、本発明の実施形態について説明する。
図1は、本発明の複合汚染土壌浄化処理装置の実施形態を示している。
浄化処理すべき汚染土壌SAoを貯蔵するフィルタ2f付きの複数のストックビン2が汚染土壌SAoの集積所近傍に配設され、複数のストックビン2のそれぞれに設けられたコンベア2a、2aの下方に通常トロンメルと称される乾燥選別装置3の方向に延びるコンベア2bが配置されている。このコンベア2bは後述のように投入口12aに汚染土壌SAoを供給するようになっている。
Embodiments of the present invention will be described below with reference to the accompanying drawings.
FIG. 1 shows an embodiment of the composite contaminated soil purification apparatus of the present invention.
A plurality of stock bins 2 with a filter 2f for storing the contaminated soil SAo to be purified are disposed in the vicinity of the collection site of the contaminated soil SAo, and below conveyors 2a and 2a provided in each of the plurality of stock bins 2. A conveyor 2b extending in the direction of the drying and sorting apparatus 3, which is usually called a trommel, is arranged. As will be described later, the conveyor 2b supplies the contaminated soil SAo to the inlet 12a.

乾燥選別装置3の詳細を示す図2〜図7も参照して、乾燥選別装置3は、全体的に筒状の固定ケーシング12を備え、その固定ケーシング12の内部に円筒状の加熱攪拌粉砕部7と円筒状の分級部10とがシリーズに連通されて一体に構成され、ローラ18(図6)によって回転自在に装着されている。
乾燥選別装置3の軸心は、加熱攪拌粉砕部7側が水平に対して上方に傾斜して配設されていて、乾燥選別装置3内の汚染土壌が回転しながら分級部10方向に移動するよう構成されている。
2 to 7 showing the details of the dry sorting apparatus 3, the dry sorting apparatus 3 includes a cylindrical fixed casing 12 as a whole, and a cylindrical heated stirring and pulverizing section inside the fixed casing 12. 7 and the cylindrical classification part 10 are communicated with the series and configured integrally, and are rotatably mounted by a roller 18 (FIG. 6).
The axis of the dry sorting device 3 is arranged such that the heated stirring and grinding unit 7 side is inclined upward with respect to the horizontal so that the contaminated soil in the dry sorting device 3 moves toward the classifying unit 10 while rotating. It is configured.

加熱攪拌粉砕部7は、図示の例では加熱攪拌部分7Aとボールミル部分7Bとで構成されている。加熱攪拌部分7Aは、図においては固定ケーシング12の左方上部に設けられた汚染土壌の投入口12aに通気されていると共に、固定ケーシング12の外部に配置された加熱装置5の熱気ダクト5bに通気されている。加熱攪拌部分7Aの内部にシロッコファン状の複数の攪拌羽根7a(図5参照)が角度的に離隔して軸心に平行に取付けられている。攪拌羽根7aの先端部は汚染土壌SAoを上部まで掻き揚げるように折り曲げフランジ7bが形成されている。加熱攪拌部分7Aは図1のように複数個がシリーズに連通されていることが好ましい。   In the illustrated example, the heating and stirring pulverization unit 7 includes a heating and stirring portion 7A and a ball mill portion 7B. The heating and stirring portion 7A is vented to the contaminated soil inlet 12a provided in the upper left part of the fixed casing 12 in the drawing, and is connected to the hot air duct 5b of the heating device 5 disposed outside the fixed casing 12. Ventilated. A plurality of sirocco fan-like stirring blades 7a (see FIG. 5) are attached to the inside of the heating stirring portion 7A in parallel with the shaft center at an angular distance. A bending flange 7b is formed at the tip of the stirring blade 7a so that the contaminated soil SAo can be lifted up to the top. A plurality of heating and stirring portions 7A are preferably connected in series as shown in FIG.

ボールミル部分7Bは、多数の粉砕用の鋼球8を移動自由に収容していて、加熱攪拌部分7Aでほぐされた複合汚染土壌SAoを鋼球8の落下により粉砕するように構成され、また、鋼球8が分級部10に飛び出さないように構成されている。   The ball mill portion 7B accommodates a large number of pulverizing steel balls 8 so as to move freely, and is configured to pulverize the composite contaminated soil SAo loosened by the heating and stirring portion 7A when the steel balls 8 are dropped. The steel ball 8 is configured not to jump out to the classification unit 10.

加熱装置5は、バーナ5aによって外部の大気を500〜1100℃に加熱して回転する加熱攪拌部分7Aに熱気を送るように構成されている。特に重金属類を処理する場合は高温が好ましい。   The heating device 5 is configured to send hot air to the heating and stirring portion 7A that rotates by heating the external atmosphere to 500 to 1100 ° C. by the burner 5a. Particularly when treating heavy metals, a high temperature is preferred.

分級部10は、図示の例では第1及び第2分級装置10A、10Bで構成され、第1分級装置10Aは比較的細かい円筒状の網目で構成され、第2分級装置10Bは第1分級装置10Aより粗い網目で構成されていて、それぞれに網目を通過した土壌を受留するサージビン13a、13bが取付けられている。サージビン13aの下部にスクリュフィーダ14aが、サージビン13bの下部にベルトフィーダ14bが取付けられている。
第2分級装置10Bの後部に、第2分級装置10Bを通過しない大径の土壌が排出されるオーバサイズ排土樋12cが設けられている。
上記分級部10の構成によって、分級部10に入った土壌は3級に分級されて、以後の処理が決定されるようになっている。分級部10の分級装置の個所は任意に選択できる。
In the illustrated example, the classifying unit 10 includes first and second classifying devices 10A and 10B. The first classifying device 10A includes a relatively fine cylindrical mesh, and the second classifying device 10B is a first classifying device. Surge bins 13a and 13b, each of which is composed of a mesh coarser than 10A and receives the soil that has passed through the mesh, are attached. A screw feeder 14a is attached to the lower portion of the surge bin 13a, and a belt feeder 14b is attached to the lower portion of the surge bin 13b.
An oversized earth slag 12c through which large-diameter soil that does not pass through the second classifying device 10B is discharged is provided at the rear of the second classifying device 10B.
According to the configuration of the classification unit 10, the soil that has entered the classification unit 10 is classified into the third grade, and subsequent processing is determined. The location of the classification device of the classification unit 10 can be arbitrarily selected.

サージビン13a、13bの上部に散水ノズル16とエアレーションノズル15とが適度の角度で水分を散水し、圧縮空気によって土壌を吹き上げるように取付けられている。
これらのノズル15、16は本発明の実施に際して必ずしも設けなくてもよいが、エアレーションノズル15を設けることで、微細粒子を後述の集塵装置に移送しやすくでき、また散水ノズル16により分級した土壌の温度を下げてその後の取り扱いをしやすくすると共に、土壌の表面に付着した汚染物質を蒸発により分離しやすくできる。
A watering nozzle 16 and an aeration nozzle 15 are attached to the upper portions of the surge bins 13a and 13b so as to sprinkle water at an appropriate angle and blow up the soil with compressed air.
These nozzles 15 and 16 are not necessarily provided in the practice of the present invention, but by providing the aeration nozzle 15, fine particles can be easily transferred to a dust collector described later, and the soil classified by the watering nozzle 16 is used. It is possible to reduce the temperature of the soil to facilitate subsequent handling, and to easily separate contaminants attached to the soil surface by evaporation.

サージビン13a、13b内の分級した汚染土壌は、別途に公定分析計により汚染物質の残存有無を分析して、汚染物質が許容基準値以下の無害の処理土壌は埋め戻し域Edに埋め戻されるよう、また汚染物質が許容基準値以上残存しているサージビンの有害な処理土壌は従来仕様の洗浄処理装置25に送られ加水、混合洗浄、固形物の篩い分け、再度の洗浄等の処理によって浄化処理されるよう構成されている。   The classified contaminated soil in the surge bins 13a, 13b is separately analyzed for the presence or absence of contaminants using an official analyzer, and the harmless treated soil whose contaminants are below the permissible reference value is backfilled in the backfill area Ed. In addition, the surgebin's harmful treated soil in which contaminants remain above the permissible reference value is sent to a conventional washing device 25 for purification by hydration, mixed washing, sieving of solids, washing again, etc. It is configured to be.

固定ケーシング12の端部上部に、加熱攪拌粉砕部7および分級部10で発生した重金属などの有害物質が付着したダスト微粉と、ダスト微粉が回収された後の軽質油、揮発性有機化合物などの汚染物質を含む排気ガスを排出する集塵ダクト12bが設けられている。   Dust fine powder, to which harmful substances such as heavy metals generated in the heating and stirring pulverization section 7 and classification section 10 are attached to the upper end of the fixed casing 12, light oil after the dust fine powder is collected, volatile organic compounds, etc. A dust collection duct 12b that exhausts exhaust gas containing pollutants is provided.

集塵ダクト12bからの排ガスは、配管ラインL12によって乾式サイクロン30に連通され、乾式サイクロン30は配管ラインL30によって集塵装置40であるバッグフィルタに連通されている。乾式サイクロン30では粗粒ダストを分離し、バッグフィルタ40では微粒ダストを分離するよう構成されている。   The exhaust gas from the dust collection duct 12b is communicated with the dry cyclone 30 through the piping line L12, and the dry cyclone 30 is communicated with the bag filter which is the dust collector 40 through the piping line L30. The dry cyclone 30 is configured to separate coarse dust, and the bag filter 40 is configured to separate fine dust.

バッグフィルタ40からの排ガスは、排風装置42、脱臭装置44、中和装置46および煙突48を介して大気に放出されるよう構成されている。   The exhaust gas from the bag filter 40 is configured to be released to the atmosphere through the air exhaust device 42, the deodorizing device 44, the neutralizing device 46, and the chimney 48.

上記構成の複合汚染土壌浄化処理装置による汚染土壌処理の態様について、図1及び図2を参照して説明する。
山積みされた複合汚染土壌SAoはバックホーなどの建設機械によってほぐされ、ゴミ・異物などが除去される前処理をされてフィルタ2fを介して複数のストックビン2に投入される。
The aspect of the contaminated soil processing by the composite contaminated soil purification processing apparatus having the above configuration will be described with reference to FIGS. 1 and 2.
The piled composite contaminated soil SAo is loosened by a construction machine such as a backhoe, pretreated to remove dust, foreign matters, etc., and put into a plurality of stock bins 2 through filters 2f.

ストックビン2内の複合汚染土壌SAoは、コンベア2a、コンベア2bによって適宜の量が連続して乾燥選別装置3の投入口12aを介して加熱攪拌粉砕部7の加熱攪拌部分7Aに投入される。   An appropriate amount of the composite contaminated soil SAo in the stock bin 2 is continuously fed into the heating and stirring portion 7A of the heating and stirring and pulverizing unit 7 through the charging port 12a of the drying and sorting device 3 by the conveyor 2a and the conveyor 2b.

加熱攪拌部分7Aに投入された複合汚染土壌SAoは、攪拌羽根7aによって回転されると共に攪拌され、加熱装置5からの500〜900℃の熱気によって150〜300℃に乾燥される。ここで、複合汚染土壌SAoから熱によって水分、軽質油や揮発性有機化合物(VOC)などが排気ガス、ダスト微粉として分離される。   The composite contaminated soil SAo put into the heating and stirring portion 7A is rotated and stirred by the stirring blade 7a, and dried to 150 to 300 ° C. by hot air of 500 to 900 ° C. from the heating device 5. Here, moisture, light oil, volatile organic compounds (VOC) and the like are separated from the complex contaminated soil SAo as exhaust gas and dust fine powder by heat.

加熱攪拌部分7Aで乾燥され、ほぐしやすくなった複合汚染土壌SAoは、ボールミル部分7Bで粉砕鋼球8によって細かく粉砕される。この粉砕作業により前述の通り、複合汚染土壌SAoから重金属などの汚染濃度が高いダスト微細部分と、比較的汚染濃度の低い粒径部分とに分離される。   The composite contaminated soil SAo that has been dried in the heating and stirring portion 7A and easily loosened is finely pulverized by the pulverized steel balls 8 in the ball mill portion 7B. As described above, this pulverization operation separates the composite contaminated soil SAo into a fine dust portion having a high contamination concentration such as heavy metals and a particle size portion having a relatively low contamination concentration.

粉砕された複合汚染土壌SAoは、分級部10の第1分級装置10Aで細粒が篩い分け分級され、第2分級装置10Bで粗粒が篩い分け分級されると共に、大径粒が分級される。そして、細粒はサージビン13aに、粗粒はサージビン13bに落下して貯えられ、大径粒はオーバサイズ排土樋12cに送られる。   In the pulverized composite contaminated soil SAo, fine particles are sieved and classified by the first classification device 10A of the classification unit 10, coarse particles are sieved and classified by the second classification device 10B, and large-diameter particles are classified. . The fine particles are stored in the surge bin 13a and the coarse particles are stored in the surge bin 13b, and the large-diameter particles are sent to the oversized earthen basin 12c.

この分級落下時に、エアレーションノズル15からの圧縮空気と散水ノズル16からの水分供給により発生する水蒸気および分離粉塵は、複合汚染物質を含む前記ダスト微粉、排気ガスと共に排風装置42、バッグフィルタ40などにより回収され、乾式サイクロン30では粗粒ダストを分離され、集塵装置40では微粒ダストを分離され、さらに脱臭、中和処理されて無害化され大気に放散される。   At the time of the classification fall, the compressed air from the aeration nozzle 15 and the water vapor and separated dust generated by supplying water from the watering nozzle 16 are discharged together with the dust fine powder containing complex contaminants and the exhaust gas, the exhaust device 42, the bag filter 40, etc. In the dry cyclone 30, coarse dust is separated, and in the dust collector 40, fine dust is separated, further deodorized and neutralized, rendered harmless and released to the atmosphere.

上記のようにして粒径別に分級された複合汚染土壌SAoは、それぞれ公定分析により残留汚染濃度が分析され、許容基準値以上であれば従来公知の洗浄処理装置25に送られて水洗浄化され、許容基準値以内であれば、再生土として所定の埋め戻し域Edに埋め戻される。   The composite contaminated soil SAo classified according to particle size as described above is analyzed by official analysis for residual contamination concentration, and if it exceeds the allowable standard value, it is sent to a conventionally known cleaning treatment device 25 to be washed with water, If it is within the allowable reference value, it is backfilled in a predetermined backfill area Ed as reclaimed soil.

図8は、本発明の複合汚染土壌浄化処理装置の別の実施形態を示している。この実施例は土壌加熱装置5Aに汚染土壌SAoを投入する点および集塵装置40Aとして水洗装置を用いた点が、主として前記実施形態と異なっている。
図8において浄化処理すべき汚染土壌SAoを貯蔵するフィルタ2f付きの複数のストックビン2が汚染土壌SAoの集積所近傍に配設され、複数のストックビン2のそれぞれに設けられたコンベア2a、2aの下方に複合汚染土壌SAoを加熱する土壌加熱装置5Aに延びるコンベア2bが配置されている。
FIG. 8 shows another embodiment of the composite contaminated soil purification apparatus of the present invention. This example is mainly different from the above embodiment in that the contaminated soil SAo is put into the soil heating device 5A and a water washing device is used as the dust collecting device 40A.
In FIG. 8, a plurality of stock bins 2 with filters 2f for storing contaminated soil SAo to be purified are disposed in the vicinity of the collection site of contaminated soil SAo, and conveyors 2a and 2a provided in each of the plurality of stock bins 2. A conveyor 2b extending to the soil heating device 5A that heats the composite contaminated soil SAo is disposed below.

土壌加熱装置5Aは、コンベア2bからの適宜の量の複合汚染土壌SAoをバーナ5aによって加熱するよう構成されていて、加熱された複合汚染土壌SAoはコンベア5Bを介して乾燥選別装置3Aに供給されるよう構成されている。また、土壌加熱装置5Aの端部上部に集塵口5Abが設けられ配管ラインL5Aによって乾式サイクロン30に連通されている。   The soil heating device 5A is configured to heat an appropriate amount of the composite contaminated soil SAo from the conveyor 2b by the burner 5a, and the heated composite contaminated soil SAo is supplied to the dry sorting device 3A via the conveyor 5B. It is comprised so that. Further, a dust collection port 5Ab is provided at the upper end of the soil heating device 5A, and is communicated with the dry cyclone 30 by a piping line L5A.

乾燥選別装置3Aは、かまぼこ筒状の固定ケーシング12Aの内部に円筒状の攪拌粉砕部A7と円筒状の分級部10とがシリーズに連通されて一体に構成され、回転自在に装着されている。
乾燥選別装置3Aの軸心は、攪拌粉砕部A7側が水平に対して上方に傾斜して配設されていて、乾燥選別装置3A内の複合汚染土壌SAoが回転しながら分級部10方向に移動するよう構成されている。
In the dry sorting apparatus 3A, a cylindrical stirring and pulverizing section A7 and a cylindrical classification section 10 are communicated in series with each other in a kamaboko cylindrical fixed casing 12A, and are integrally mounted and rotatably mounted.
The axis of the dry sorting device 3A is disposed with the stirring and grinding unit A7 side inclined upward with respect to the horizontal, and the composite contaminated soil SAo in the dry sorting device 3A moves toward the classifying unit 10 while rotating. It is configured as follows.

攪拌粉砕部A7は、図示の例では1つの攪拌部分7Aとボールミル部分7Bとで構成されている。攪拌部分7Aは、図においては固定ケーシング12の左方上部に設けられた集塵口12Abに通気されていて、集塵口12Abは乾式サイクロン30に配管ラインL7によって連通されている。
攪拌部分7Aの内部にシロッコファン状の複数の羽根7aが軸心に平行に取付けられている。攪拌羽根7aの先端部は複合汚染土壌SAoを上部まで掻き揚げるように折り曲げフランジ7bが形成されている。攪拌部分7Aは複数個がシリーズに連通されていてもよい。
In the example shown in the figure, the stirring and grinding part A7 is composed of one stirring part 7A and a ball mill part 7B. The stirring portion 7A is ventilated through a dust collecting port 12Ab provided in the upper left part of the fixed casing 12 in the drawing, and the dust collecting port 12Ab is communicated with the dry cyclone 30 by a piping line L7.
A plurality of sirocco fan-like blades 7a are attached in parallel to the shaft center inside the stirring portion 7A. A bending flange 7b is formed at the tip of the stirring blade 7a so that the composite contaminated soil SAo is lifted up to the upper part. A plurality of stirring portions 7A may be communicated in series.

ボールミル部分7Bは、多数の粉砕鋼球8を移動自由に収容していて、攪拌部分7Aでほぐされた複合汚染土壌SAoを移動落下により粉砕するように構成され、また粉砕鋼球8が分級部10に飛び出さないように構成されている。   The ball mill portion 7B accommodates a large number of pulverized steel balls 8 so as to move freely, and is configured to pulverize the composite contaminated soil SAo loosened by the stirring portion 7A by moving and dropping, and the pulverized steel balls 8 are classified. 10 so as not to jump out.

分級部10は、第1及び第2分級装置10A、10Bで構成され、第1分級装置10Aは比較的細かい円筒状の網目で構成され、第2分級装置10Bは第1分級装置10Aより粗い網目で構成されていて、それぞれに網目を通過した土壌を受留するサージビン13a、13bが取付けられている。サージビン13aの下部にベルトフィーダ14cが、サージビン13bの下部にベルトフィーダ14bが取付けられている。   The classifying unit 10 includes first and second classifying devices 10A and 10B. The first classifying device 10A includes a relatively fine cylindrical mesh, and the second classifying device 10B has a coarser mesh than the first classifying device 10A. Surge bins 13a and 13b for receiving the soil that has passed through the mesh are attached to each. A belt feeder 14c is attached to the lower part of the surge bin 13a, and a belt feeder 14b is attached to the lower part of the surge bin 13b.

固定ケーシング12の第2分級装置10Bの後部に、第2分級装置10Bを通過しない大径の土壌が排出されるオーバサイズ排土樋12cが設けられている。
分級部10の構成によって、分級部10に入った土壌は3級に分級されて、たとえば第2分級装置10Bで分級された土壌が基準値以上の残存汚染を有する場合はラインL10によって洗浄処理装置25Aに搬送されるように構成されている。
At the rear of the second classifying device 10B of the fixed casing 12, an oversized earth slag 12c from which large-diameter soil that does not pass through the second classifying device 10B is discharged is provided.
By the configuration of the classification unit 10, the soil that has entered the classification unit 10 is classified into the third grade. For example, when the soil classified by the second classification device 10B has residual contamination that exceeds the reference value, the washing treatment apparatus is performed by the line L10. It is configured to be conveyed to 25A.

サージビン13a、13b内の分級した汚染土壌は別途に公定分析計により汚染物質の残存有無を分析して汚染物質が許容基準値以下の無害の処理土壌は埋め戻し域に埋め戻されるよう、また汚染物質が許容基準値以上残存しているサージビンの有害な処理土壌は前記のように、従来仕様の洗浄処理装置25Aに送られ加水、混合洗浄、固形物の篩い分け、再度の洗浄等の処理によって浄化処理されるよう構成されている。   The contaminated soil classified in the surge bins 13a and 13b is separately analyzed for the presence or absence of contaminants using an official analyzer, and the harmless treated soil whose contaminants are below the permissible standard value is backfilled in the backfill area. As described above, the harmful treatment soil of surge bins whose substances remain above the permissible reference value is sent to the conventional washing treatment apparatus 25A and subjected to treatment such as hydration, mixed washing, sieving of solids, and washing again. It is configured to be purified.

第1及び第2分級装置10A、10Bbの上部にエアレーションノズル15と散水ノズル16が適度の角度で圧縮空気によって土壌を吹き上げるよう取付けられている。   An aeration nozzle 15 and a water spray nozzle 16 are attached to the top of the first and second classifiers 10A and 10Bb so as to blow up the soil with compressed air at an appropriate angle.

固定ケーシング12Aの攪拌部分7A側の端部上部に攪拌粉砕部7および分級部10で発生した重金属などの有害物質が付着したダスト微粉と、ダスト微粉が回収された後の軽質油、揮発性有機化合物などの汚染物質を含む排気ガスを排出する集塵ダクト12Abが設けられている。   Dust fine powder in which harmful substances such as heavy metals generated in the stirring and pulverizing section 7 and the classification section 10 adhere to the upper end of the fixed casing 12A on the stirring section 7A side, light oil and volatile organic after the dust fine powder has been collected A dust collection duct 12Ab for exhausting exhaust gas containing contaminants such as compounds is provided.

集塵ダクト12Abは配管ラインL7によって乾式サイクロン30に連通され、乾式サイクロン30は配管ラインL30によって排風装置42を介して水洗式集塵装置40Aに連通されている。乾式サイクロン30では粗粒ダストを分離し、集塵装置40Aでは微粒スラリーを分離するよう構成されている。
分離された粗粒ダストと微粒スラリーは洗浄処理装置25に回収されるよう構成されている
集塵装置40Aは図示の例では水洗集塵装置である。
集塵装置40Aは、煙突48を介して大気に連通されるよう構成されている。
上記以外の構成機能は、第1実施形態と同様である。
The dust collection duct 12Ab communicates with the dry cyclone 30 through a piping line L7, and the dry cyclone 30 communicates with the flushing dust collection device 40A through the exhaust line 42 through the piping line L30. The dry cyclone 30 is configured to separate coarse dust, and the dust collector 40A is configured to separate fine slurry.
The separated coarse dust and fine slurry are configured to be collected by the cleaning treatment device 25. The dust collection device 40A is a water washing dust collection device in the illustrated example.
The dust collector 40A is configured to communicate with the atmosphere via the chimney 48.
Other constituent functions are the same as those of the first embodiment.

上記構成の複合汚染土壌浄化処理装置による汚染土壌処理方法について、図8を参照して説明する。
異物等を除去された複合汚染土壌SAoはフィルタ2fを介してストックビン2内に貯留され、コンベア2a、コンベア2bによって適宜の量が連続して土壌加熱装置5Aに投入される。
A contaminated soil treatment method using the composite contaminated soil purification apparatus having the above-described configuration will be described with reference to FIG.
The composite contaminated soil SAo from which foreign matters and the like have been removed is stored in the stock bin 2 via the filter 2f, and appropriate amounts are continuously fed into the soil heating device 5A by the conveyors 2a and 2b.

土壌加熱装置5Aに投入された複合汚染土壌SAoは、加熱されて水分、軽質油分、揮発性有機成分等が揮発除去される。これらの揮発成分は集塵口5Abから配管ラインL5Aを介して乾式サイクロン30に供給される。   The combined contaminated soil SAo put into the soil heating device 5A is heated to volatilize and remove moisture, light oil, volatile organic components, and the like. These volatile components are supplied to the dry cyclone 30 from the dust collection port 5Ab via the piping line L5A.

揮発成分を除去された複合汚染土壌SAoは乾燥選別装置3Aに送られ、攪拌部分7Aで攪拌羽根7aによって回転されると共に攪拌され、ほぐされる。   The composite contaminated soil SAo from which the volatile components have been removed is sent to the dry sorting device 3A, and is rotated and stirred by the stirring blade 7a in the stirring portion 7A.

攪拌部分7Aでほぐされた複合汚染土壌SAoは、ボールミル部分7Bで粉砕鋼球8によって細かく粉砕される。ここで複合汚染土壌SAoから重金属などの汚染濃度が高いダスト微細部分と、比較的汚染濃度の低い粒径物とに分離される。   The composite contaminated soil SAo loosened in the stirring portion 7A is finely pulverized by the pulverized steel balls 8 in the ball mill portion 7B. Here, the composite contaminated soil SAo is separated into fine dust portions having a high contamination concentration such as heavy metals and particle sizes having a relatively low contamination concentration.

粉砕された複合汚染土壌SAoは、分級部10の第1分級装置10Aで細粒が篩い分け分級され、第2分級装置10Bで粗粒が篩い分け分級されると共に、大径粒が分級される。そして、細粒はサージビン13aに、粗粒はサージビン13bに落下して貯えられ、大径粒はオーバサイズ排土樋12cに送られる。   In the pulverized composite contaminated soil SAo, fine particles are sieved and classified by the first classification device 10A of the classification unit 10, coarse particles are sieved and classified by the second classification device 10B, and large-diameter particles are classified. . The fine particles are stored in the surge bin 13a and the coarse particles are stored in the surge bin 13b, and the large-diameter particles are sent to the oversized earthen basin 12c.

この分級落下時に、エアレーションノズル15からの圧縮空気と安全のための土壌温度の低下用散水ノズル16からの水分供給により発生する水蒸気および分離粉塵は、複合汚染物質を含むダスト微粉、排気ガスと共に集塵ダクト12Abから排風装置42、集塵装置40などにより回収され、乾式サイクロン30では粗粒ダストを分離され、集塵装置40では微粒ダストを分離されて無害化され煙突48から大気に放散される。   At the time of this classification fall, the compressed air from the aeration nozzle 15 and the water vapor and separated dust generated by the water supply from the water spray nozzle 16 for lowering the soil temperature for safety are collected together with dust fine powder and exhaust gas containing complex pollutants. The dust is collected from the dust duct 12Ab by the air exhaust device 42, the dust collector 40, etc., the coarse dust is separated by the dry cyclone 30, the fine dust is separated by the dust collector 40, detoxified, and diffused from the chimney 48 to the atmosphere. The

上記のようにして粒径別に分級された複合汚染土壌SAoは、それぞれ公定分析により残留汚染濃度が分析され、許容基準値以上であれば従来公知の洗浄処理装置25Aに送られて水洗浄化され、許容基準値以内であれば、再生土として所定の埋め戻し域Edに埋め戻される。   The composite contaminated soil SAo classified according to particle size as described above is analyzed for the residual contamination concentration by official analysis, and if it exceeds the allowable reference value, it is sent to a conventionally known cleaning treatment device 25A to be washed with water, If it is within the allowable reference value, it is backfilled in a predetermined backfill area Ed as reclaimed soil.

本発明は土壌のみならずその他の複合汚染の浄化処理にも実施できる。   The present invention can be applied not only to soil but also to purification treatment of other complex pollution.

本発明の複合汚染土壌浄化処理装置の第1実施形態のブロック構成図。The block block diagram of 1st Embodiment of the composite-contaminated soil purification processing apparatus of this invention. 図1に使用される乾燥選別装置の側面図。FIG. 2 is a side view of the dry sorting apparatus used in FIG. 1. 図2のX1矢視図。FIG. 3 is an X1 arrow view of FIG. 2. 図2のX2矢視図。X2 arrow line view of FIG. 図2のA−A断面図。AA sectional drawing of FIG. 図2のB−B断面図。BB sectional drawing of FIG. 図2のC−C断面図。CC sectional drawing of FIG. 第2実施形態のブロック構成図。The block block diagram of 2nd Embodiment.

符号の説明Explanation of symbols

SAo・・複合汚染土壌
Ed・・・埋戻し域
2・・・・ストックビン
2a、2b・・・コンベア
3・・・・乾燥選別装置
5・・・・加熱装置
5a・・・バーナ
5b・・・熱気ダクト
6・・・・コンベア
7・・・・加熱攪拌粉砕部
7a・・・攪拌羽根
7A・・・加熱攪拌部分
7B・・・ボールミル部分
8・・・・粉砕鋼球
10・・・分級部
10A・・第1分級装置
10B・・第2分級装置
12・・・固定ケーシング
12a・・投入口
12b・・集塵ダクト
12c・・オーバサイズ排土樋
13・・・サージビン
13a・・第1サージビン
13b・・第2サージビン
15・・・エアレーションノズル
16・・・散水ノズル
30・・・サイクロン
40、40A・・・集塵装置
42・・・排風装置
44・・・脱臭装置
46・・・中和装置
48・・・煙突
SAo ··· Complex contaminated soil Ed · Backfill area 2 · · · Stock bins 2a and 2b · · · Conveyor 3 · · · Drying and sorting device 5 · · · Heating device 5a · · · Burner 5b ··· · Hot air duct 6 ··· Conveyor 7 ··· Heated and agitated and pulverized portion 7a · · · Agitation blade 7A · · · Heated and agitated portion 7B · · · Ball mill portion 8 ··· Crushed steel ball 10 ··· Classification Part 10A ··· First classification device 10B · · · Second classification device 12 ··· Fixed casing 12a ·············· Inlet 12b ··· Dust collection duct 12c · · 13b..Second surge bin 15 ... Aeration nozzle 16 ... Water spray nozzle 30 ... Cyclone 40, 40A ... Dust collector 42 ... Air exhaust device 44 ... Deodorizer 46 ... Medium Japanese equipment 48 ... chimney

Claims (4)

複合汚染土壌を加熱して攪拌し粉砕する回転自在な円筒状の加熱攪拌粉砕部と、その加熱攪拌粉砕部で粉砕された複合汚染土壌を粒径によって分級する回転自在な円筒状の分級部と、前記加熱攪拌粉砕部に熱気を供給する加熱装置と、加熱攪拌粉砕部と分級部とを被覆する固定ケーシングとが一体に構成される乾燥選別装置と、固定ケーシング内のダストを外部に吸引する排風装置と、固定ケーシングに設けられて固定ケーシング内のダストを排出するラインと、そのラインに連通された集塵装置と、前記分級部で分級された複合汚染土壌のうちの残留汚染が基準値をこえるものを水洗する洗浄処理装置とで構成されることを特徴とする複合汚染土壌浄化処理装置。   A rotatable cylindrical heated stirring and grinding unit that heats, stirs and pulverizes the composite contaminated soil, and a rotatable cylindrical classification unit that classifies the composite contaminated soil crushed by the heated stirred and pulverized unit according to particle size , A drying / separating apparatus in which a heating device for supplying hot air to the heated stirring / pulverizing unit, a fixed casing covering the heated stirring / pulverizing unit and the classification unit, and dust in the fixed casing are sucked to the outside. Residual contamination of the mixed-contaminated soil classified by the classification unit is classified as a ventilator, a line provided in the fixed casing for discharging dust in the fixed casing, a dust collector connected to the line, and the classification unit A combined contaminated soil remediation treatment apparatus characterized by comprising a washing treatment apparatus for washing a substance exceeding a value. 前記加熱攪拌粉砕部は、攪拌羽根が装着されて塊状の複合汚染土壌をほぐす加熱攪拌部分と、加熱されほぐされた複合汚染土壌を粉砕する多数の粉砕鋼球が移動自在に収容されているボールミル部分とで構成されている請求項1記載の複合汚染土壌浄化処理装置。   The heating and agitation pulverization unit is a ball mill in which agitation blades are attached to loosen a lump of complex contaminated soil, and a large number of pulverized steel balls for crushing the heated and loosened complex contaminated soil are movably accommodated. The composite contaminated soil purification processing apparatus of Claim 1 comprised by the part. 前記分級部は網目の異なる複数の分級装置で構成されている請求項1または請求項2の複合汚染土壌浄化処理装置。   The composite contaminated soil purification apparatus according to claim 1 or 2, wherein the classification unit includes a plurality of classification apparatuses having different meshes. 前記分級部に分級された土壌を攪拌する攪拌用圧縮空気を吹き付けるエアレーションノズルが取付けられ、分級された土壌に冷却用水を吹き付ける散水ノズルが取付けられている請求項1〜請求項3の何れか1項の複合汚染土壌浄化処理装置。   The aeration nozzle which blows the compressed air for stirring which stirs the classified soil to the said classification | category part is attached, The watering nozzle which blows the water for cooling to the classified soil is attached. Item Contaminated soil purification treatment equipment.
JP2004065092A 2004-03-09 2004-03-09 Combined contaminated soil purification equipment Expired - Fee Related JP4338029B2 (en)

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JP2013208592A (en) * 2012-03-30 2013-10-10 Ube Machinery Corporation Ltd Method for treating contaminated soil and treatment system for contaminated soil
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