JP2005234047A - Method for repairing halftone defect in binary mask - Google Patents

Method for repairing halftone defect in binary mask Download PDF

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JP2005234047A
JP2005234047A JP2004040346A JP2004040346A JP2005234047A JP 2005234047 A JP2005234047 A JP 2005234047A JP 2004040346 A JP2004040346 A JP 2004040346A JP 2004040346 A JP2004040346 A JP 2004040346A JP 2005234047 A JP2005234047 A JP 2005234047A
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defect
halftone
fib
light shielding
shielding film
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JP4313694B2 (en
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Tomokazu Kosakai
智一 小堺
Osamu Takaoka
修 高岡
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Hitachi High Tech Science Corp
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SII NanoTechnology Inc
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Abstract

<P>PROBLEM TO BE SOLVED: To repair a halftone defect causing imperfect light shielding in a binary mask with high accuracy and excellent transfer properties. <P>SOLUTION: The following phenomenon is utilized; an FIB-CVD light shielding film 8 with little halo does not grow on a gallium implanted chromium film but can grow on a glass part 6 exposed by etching. Part of the halftone defect 2 in the binary mask to which the FIB-CVD light shielding film 8 is made less attachable by implantation of gallium of focused ion beams 1 is shaved up to a glass substrate by gas assisted etching. The FIB-CVD light shielding film 8 is then grown from the exposed glass part 6 to repair the halftone defect. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

本発明はウェーハへのパターン転写に使用されるフォトマスクの欠陥修正方法に関するものである。   The present invention relates to a defect correction method for a photomask used for pattern transfer onto a wafer.

半導体集積回路の微細化の進展に伴い、パターン転写の原版であるフォトマスク上のパターンも微細化が進んでいる。フォトマスクは原版であるため、欠陥があると転写されるもの全てに欠陥が作り込まれてしまうことになるため、無欠陥であることが求められている。マスク加工プロセス上どうしても欠陥が発生してしまうため、レーザーを用いて欠陥の修正がおこなわれてきた。しかしパターンが微細化されると修正しなければならない欠陥も小さくなり、レーザーではこのような微細欠陥に対応できないため、最近では集束イオンビーム(FIB)を用いた修正が使用されるようになってきている。   With the progress of miniaturization of semiconductor integrated circuits, the pattern on a photomask which is an original pattern transfer is also miniaturized. Since the photomask is an original plate, if there is a defect, a defect is created in all the transferred objects, and therefore it is required to be defect-free. Since defects are inevitably generated in the mask processing process, defects have been corrected using a laser. However, when the pattern is miniaturized, the number of defects that must be corrected becomes smaller, and the laser cannot handle such fine defects. Therefore, correction using a focused ion beam (FIB) has recently been used. ing.

マスクの欠陥には正常パターンと比べてパターン余剰である黒欠陥や正常パターンと比べてパターン不足である白欠陥に加えて遮光膜パターンが部分的に薄くて光が透過してしまうハーフトーン欠陥がある。黒欠陥や白欠陥はFIBのガス支援エッチングやFIB-CVD遮光膜で修正されている(例えば非特許文献1)。ハーフトーン欠陥もFIBで修正可能であるが、バイナリパターンにFIB-CVD遮光膜をつけて修正しなければならない、遮光が完全でないハーフトーン欠陥を修正する場合にFIBのプライマリビームであるガリウムがある程度以上遮光膜パターンのクロムに注入されると遮光膜として特性の優れたFIB-CVD膜がクロム膜上に成長できないという問題があった。   Mask defects include black defects, which are surplus patterns compared to normal patterns, white defects, which are insufficient patterns compared to normal patterns, and halftone defects where the light shielding film pattern is partially thin and allows light to pass through. is there. Black defects and white defects are corrected by FIB gas-assisted etching or FIB-CVD light shielding film (for example, Non-Patent Document 1). Halftone defects can also be corrected by FIB, but FIB-CVD light shielding film must be attached to the binary pattern. When correcting halftone defects that are not completely shielded, some of the FIB primary beam gallium is used. As described above, when the light-shielding film pattern is injected into chromium, there is a problem that an FIB-CVD film having excellent characteristics as a light-shielding film cannot be grown on the chromium film.

上記問題に対してハーフトーン部分をFIBのガス支援エッチングで全部削ってFIB-CVD遮光膜をつけることでも修正可能であるが、加工時間がかかる上にハーフトーン部分を全部削るときに加工部や加工部周辺にオーバーエッチが生じて欠陥修正個所の転写特性を低下させてしまうことがあった。   The above problem can be corrected by cutting the entire halftone part with FIB gas-assisted etching and applying a FIB-CVD light shielding film. In some cases, overetching occurs in the periphery of the processed portion, thereby deteriorating the transfer characteristics of the defect correction portion.

またガリウムの注入されたクロム膜でも付着する他のFIB-CVD遮光膜原料ガスを使ってFIB-CVD膜を堆積することでもハーフトーン欠陥を修正することができるが、付着しやすい原料ガスの堆積膜周辺に望ましくない薄膜(ハロー成分)が大きく、欠陥修正個所の転写特性を低下させてしまうという問題があった。   Halftone defects can also be corrected by depositing a FIB-CVD film using another FIB-CVD light shielding film source gas that adheres even to a gallium-implanted chromium film. There is a problem that an undesired thin film (halo component) is large in the periphery of the film, thereby deteriorating the transfer characteristics of the defect correction portion.

集束イオンビームのガリウムが注入された、遮光が完全でないクロムマスクのハーフトーン欠陥に対して上記のようなオーバーエッチやハローのない高精度かつ転写特性の優れた欠陥修正方法が求められている。
R. Hagiwara, A. Yasaka, K. Aita, O. Takaoka, Y. Koyama, T. Kozakai, T. Doi, M. Muramatsu, K. Suzuki, Y. Sugiyama, O. Matsuda, M. Okabe, M. Hasuda, T. Adachi, Y. Morikawa, M. Nishiguchi, Y. Sato, N. Hayashi, T. Ozawa, Y. Tanaka, and N. Yoshioka, Proc. of SPIE 5130 510-519(2003)
There is a need for a defect correction method with high accuracy and excellent transfer characteristics, without over-etching or halo, as described above, for half-tone defects in a chromium mask in which gallium of a focused ion beam is implanted and light shielding is not complete.
R. Hagiwara, A. Yasaka, K. Aita, O. Takaoka, Y. Koyama, T. Kozakai, T. Doi, M. Muramatsu, K. Suzuki, Y. Sugiyama, O. Matsuda, M. Okabe, M. Hasuda, T. Adachi, Y. Morikawa, M. Nishiguchi, Y. Sato, N. Hayashi, T. Ozawa, Y. Tanaka, and N. Yoshioka, Proc. Of SPIE 5130 510-519 (2003)

本発明はバイナリマスクの遮光が完全でないハーフトーン欠陥の修正を可能にしようとするものである。   The present invention seeks to enable correction of halftone defects where the light shielding of the binary mask is not perfect.

ガリウムが注入されたクロム膜にはハローの少ないFIB-CVD遮光膜は成長しないが、エッチングして露出したガラス部には成長できることを利用する。まず集束イオンビームのガリウムの注入によってFIB-CVD遮光膜がつきにくくなったバイナリマスクのハーフトーン欠陥の一部分を遮光膜の横方向の成長で覆うことができる間隔をとってガス支援エッチングでガラス基板まで削り込む。次に暴露したガラス部分からFIB-CVD遮光膜を成長させてハーフトーン欠陥を修正する。   Although the FIB-CVD light-shielding film with few halos does not grow on the chromium film implanted with gallium, it can be used to grow on the glass part exposed by etching. First, a glass substrate is formed by gas-assisted etching with a gap that can cover a part of the halftone defect of the binary mask, which has become difficult to attach to the FIB-CVD light shielding film by focused ion beam gallium implantation. Grind up to. Next, a FIB-CVD light shielding film is grown from the exposed glass portion to correct the halftone defect.

エッチングで露出させたガラス部からハローの少ないFIB-CVD遮光膜を成長できるので、修正部周辺にハローが発生して修正部の転写特性を低下することはない。ガラス部から成長したFIB-CVD遮光膜は横方向にも成長するので残ったハーフトーン欠陥上もカバーすることができる。   Since the FIB-CVD light-shielding film with less halo can be grown from the glass portion exposed by etching, halo does not occur around the correction portion and the transfer characteristics of the correction portion are not deteriorated. The FIB-CVD light-shielding film grown from the glass part also grows in the horizontal direction, so it can cover the remaining halftone defects.

ハーフトーン欠陥の一部分だけをエッチングするため、転写特性を低下するような大きなオーバーエッチ部は生じない。ハーフトーン欠陥を全部削って十分に遮光できる厚いFIB-CVD遮光膜を成長させるのに比べて短い時間で修正することもできる。   Since only a part of the halftone defect is etched, a large over-etched portion that deteriorates transfer characteristics does not occur. It can also be corrected in a shorter time than growing a thick FIB-CVD light shielding film that can cut off all the halftone defects and sufficiently shield the light.

遮光の不完全なハーフトーン欠陥を持つバイナリマスクを集束イオンビーム装置に導入し、欠陥検査装置で欠陥が見つかった座標に移動する。数kVから数10kVに加速され、イオン光学系により数nm〜数100nmに集束されたイオンビーム1をハーフトーン欠陥を含む領域を走査し、集束イオンビームの走査に同期して二次電子信号もしくは二次イオン信号を取りこんでハーフトーン欠陥を含む領域の二次電子像もしくは二次イオン像を取得し、修正すべき欠陥領域2を認識する。集束したイオンビームを走査するときには、バイナリマスクは絶縁体であるガラスまたは石英基板上にクロム膜のパターンをつけたものなので、イオンビームだけだとチャージアップしてイメージが歪んだり見えなくなってしまうため、数100pAから数nAの電子ビームを同じ位置に広域に照射して過剰な電荷を中和しながら行う。図1(a)に示すように認識したハーフトーン欠陥2の一部分6をエッチング支援ガス供給系5から供給しながら集束イオンビーム1を選択照射しエッチング機能でガラス基板3まで削り込む。ハーフトーン欠陥の一部分の削り込みを行う間隔dは遮光膜の横方向の成長で残したハーフトーン欠陥を覆うことができる間隔をとっておく。図1(b)に示すように、上記削りこんだ部分を含めて再度欠陥領域を認識し、遮光膜原料供給系7から遮光膜原料ガスを供給しながらもともとハーフトーン欠陥であった領域のみ集束イオンビームを選択照射すればエッチングで露出させたガラス部6からFIB-CVD遮光膜8が成長し、このFIB-CVD膜は横方向にも成長するので残ったハーフトーン欠陥上もカバーすることができ、バイナリマスクの遮光の不完全なハーフトーン欠陥を修正することができる。   A binary mask having a halftone defect with incomplete light shielding is introduced into the focused ion beam apparatus and moved to the coordinates where the defect is found by the defect inspection apparatus. The ion beam 1 accelerated from several kV to several tens of kV and focused by ion optics to a few nm to several hundred nm is scanned in a region including a halftone defect, and a secondary electron signal or The secondary ion signal is taken in to acquire a secondary electron image or secondary ion image of the region including the halftone defect, and the defect region 2 to be corrected is recognized. When scanning a focused ion beam, the binary mask is a glass or quartz substrate, which is an insulator, with a chrome film pattern. If only the ion beam is charged, the image will be distorted or invisible. The irradiation is performed while irradiating an electron beam of several hundred pA to several nA over a wide area at the same position to neutralize excessive charges. As shown in FIG. 1 (a), while the portion 6 of the recognized halftone defect 2 is supplied from the etching assisting gas supply system 5, the focused ion beam 1 is selectively irradiated and etched to the glass substrate 3 by the etching function. The interval d at which a part of the halftone defect is etched away is an interval that can cover the halftone defect left by the lateral growth of the light shielding film. As shown in FIG. 1 (b), the defect area including the shaved portion is recognized again, and only the area that was originally a halftone defect is focused while supplying the light shielding film raw material gas from the light shielding film raw material supply system 7. If the ion beam is selectively irradiated, the FIB-CVD light shielding film 8 grows from the glass portion 6 exposed by etching, and this FIB-CVD film also grows in the lateral direction, so that it can also cover the remaining halftone defects. Incomplete halftone defects in the light shielding of the binary mask can be corrected.

最初の工程のハーフトーン欠陥2の一部分をエッチングで削り込んでガラス部を露出させる方法として、図2のようなストライプ状以外にも図3に示すような格子状や図4に示すようなスパイラル状でも遮光膜の横方向の成長で残したハーフトーン欠陥2を覆うことができる間隔をとっておけば、FIB-CVD遮光膜8を成長させることができ、バイナリマスクの遮光の不完全なハーフトーン欠陥を修正することができる。   In addition to the stripe shape as shown in FIG. 2, a lattice shape as shown in FIG. 3 or a spiral as shown in FIG. 4 is used as a method of exposing part of the halftone defect 2 in the first process by etching. If the spacing is sufficient to cover the halftone defect 2 left by the lateral growth of the light-shielding film, the FIB-CVD light-shielding film 8 can be grown. Tone defects can be corrected.

また最初の工程のハーフトーン欠陥2の一部分のエッチングを図1に示すような垂直断面ではなく、図5( a)に示すようなテーパ状の断面にすれば、次工程のFIB-CVD遮光膜8の横方向の成長が助長されるので、図5(b)に示すように垂直な断面の場合よりも広い間隔でエッチングしてもバイナリマスクの遮光の不完全なハーフトーン欠陥を修正することができる。   If the etching of a part of the halftone defect 2 in the first step is not a vertical cross section as shown in FIG. 1, but a tapered cross section as shown in FIG. Since the lateral growth of 8 is promoted, even if etching at a wider interval than in the case of a vertical cross section as shown in FIG. Can do.

本発明の特徴を最も良く表す概略断面図である。It is a schematic sectional drawing which best expresses the feature of the present invention. 本発明でハーフトーン欠陥の一部分のエッチングを行う方法の一実施例を示す平面図である。It is a top view which shows one Example of the method of etching a part of halftone defect by this invention. 本発明でハーフトーン欠陥の一部分のエッチングを行う方法の一実施例を示す平面図である。It is a top view which shows one Example of the method of etching a part of halftone defect by this invention. 本発明でハーフトーン欠陥の一部分のエッチングを行う方法の一実施例を示す平面図である。It is a top view which shows one Example of the method of etching a part of halftone defect by this invention. 本発明でハーフトーン欠陥の一部分のエッチングを行う方法の一実施例を示す概略断面図である。It is a schematic sectional drawing which shows one Example of the method of etching a part of halftone defect by this invention.

符号の説明Explanation of symbols

1 集束イオンビーム
2 遮光の不完全なハーフトーン欠陥
3 ガラス基板
4 クロム膜
5 エッチング支援ガス供給系
6 エッチング部
7 遮光膜原料ガス供給系
8 FIB-CVD遮光膜
1 Focused ion beam
2 Incomplete shading halftone defect
3 Glass substrate
4 Chromium film
5 Etching support gas supply system
6 Etching part
7 Shading film source gas supply system
8 FIB-CVD light shielding film

Claims (5)

バイナリマスクの遮光の不完全なハーフトーン欠陥の一部分を集束イオンビームのエッチング機能でガラス基板まで削り込んで、該削り込んだ部分から集束イオンビームCVD遮光膜を成長させてハーフトーン欠陥を修正することを特徴とするフォトマスクのハーフトーン欠陥修正方法。   A part of the half-tone defect with incomplete light shielding of the binary mask is cut into the glass substrate by the etching function of the focused ion beam, and a focused ion beam CVD light-shielding film is grown from the etched part to correct the half-tone defect. A method for correcting a halftone defect in a photomask, which is characterized in that: 前記ハーフトーン欠陥の一部分の削り込みがストライプ状であることを特徴とする請求項1記載のフォトマスクのハーフトーン欠陥修正方法。   2. The method for correcting a halftone defect in a photomask according to claim 1, wherein a part of the halftone defect is etched in a stripe shape. 前記ハーフトーン欠陥の一部分の削り込みが格子状であることを特徴とする請求項1記載のフォトマスクのハーフトーン欠陥修正方法。   2. The method of correcting a halftone defect in a photomask according to claim 1, wherein a part of the halftone defect is etched in a lattice shape. 前記ハーフトーン欠陥の一部分の削り込みがスパイラル状であることを特徴とする請求項1記載のフォトマスクのハーフトーン欠陥修正方法。   2. The method for correcting a halftone defect in a photomask according to claim 1, wherein a part of the halftone defect is cut in a spiral shape. 前記ハーフトーン欠陥の一部分の削り込みの断面形状がテーパ状であることを特徴とする請求項1記載のフォトマスクのハーフトーン欠陥修正方法。   2. The method for correcting a halftone defect of a photomask according to claim 1, wherein a cross-sectional shape of a part of the halftone defect is tapered.
JP2004040346A 2004-02-17 2004-02-17 Binary mask halftone defect correction method Expired - Fee Related JP4313694B2 (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100936716B1 (en) 2005-09-23 2010-01-13 엘지이노텍 주식회사 Method for repairing defect of half tone mask and repaired half tone mask
JP2013238775A (en) * 2012-05-16 2013-11-28 Shin Etsu Chem Co Ltd Method for manufacturing photomask blank, photomask blank, photomask and method for transferring pattern

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100936716B1 (en) 2005-09-23 2010-01-13 엘지이노텍 주식회사 Method for repairing defect of half tone mask and repaired half tone mask
JP2013238775A (en) * 2012-05-16 2013-11-28 Shin Etsu Chem Co Ltd Method for manufacturing photomask blank, photomask blank, photomask and method for transferring pattern
TWI564651B (en) * 2012-05-16 2017-01-01 信越化學工業股份有限公司 Photomask blank manufacturing method
US9689066B2 (en) 2012-05-16 2017-06-27 Shin-Etsu Chemical Co., Ltd. Photomask blank manufacturing method, photomask blank, photomask, and pattern transfer method

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