JP2005215457A - Method for manufacturing electrophotographic photoreceptor, process cartridge, and electrophotographic apparatus - Google Patents

Method for manufacturing electrophotographic photoreceptor, process cartridge, and electrophotographic apparatus Download PDF

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JP2005215457A
JP2005215457A JP2004023587A JP2004023587A JP2005215457A JP 2005215457 A JP2005215457 A JP 2005215457A JP 2004023587 A JP2004023587 A JP 2004023587A JP 2004023587 A JP2004023587 A JP 2004023587A JP 2005215457 A JP2005215457 A JP 2005215457A
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pushing
insert
peripheral surface
surface side
cylindrical support
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Hidenori Ogawa
英紀 小川
Yoshihisa Saito
善久 斉藤
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Canon Inc
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a method for manufacturing an electrophotographic photoreceptor employing an insert pushing method which flexibly pushes inserts of various shapes and is excellent in terms of mass production and cost. <P>SOLUTION: The method for manufacturing the electrophotographic photoreceptor having: a photosensitive layer on an outer peripheral surface side of a cylindrical support; and an insert on an inner peripheral surface side of the cylindrical support, includes a photosensitive layer forming process of forming the photosensitive layer on the outer peripheral surface side of the cylindrical support and an insert pushing process of pushing the insert by a pushing member to the inner peripheral surface side of the cylindrical support. The pushing member has a plurality of freely expandable and contractible projections in the pushing direction and has a projection fixing means for fixing the projections in the prescribed positions. The insert pushing process pushes the inserts to the inner peripheral surface side of the cylindrical support by exerting the pushing force in the pushing direction of the inserts from the projections fixed in the prescribed position by the projection fixing means. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

本発明は、円筒状支持体の外周面側に感光層を有し、該円筒状支持体の内周面側に挿入体を有する電子写真感光体の製造方法に関し、また、該電子写真感光体を有するプロセスカートリッジおよび電子写真装置に関する。   The present invention relates to a method for producing an electrophotographic photosensitive member having a photosensitive layer on the outer peripheral surface side of a cylindrical support and an insert on the inner peripheral surface side of the cylindrical support, and the electrophotographic photosensitive member. The present invention relates to a process cartridge and an electrophotographic apparatus.

電子写真方式は、円筒状支持体の外周面側に感光層を有する電子写真感光体の表面に、帯電および露光(画像露光)によって静電潜像を形成し、この静電潜像をトナーによって現像してトナー像を形成し、このトナー像を紙などの転写材に転写することによって画像形成物(コピー、プリント)を得るというプロセスを採用した方式が一般的である。また、トナー像を転写した後の電子写真感光体の表面は、必要に応じてクリーニングされる。   In the electrophotographic system, an electrostatic latent image is formed by charging and exposure (image exposure) on the surface of an electrophotographic photosensitive member having a photosensitive layer on the outer peripheral surface side of a cylindrical support, and the electrostatic latent image is formed with toner. A system that employs a process in which a toner image is formed by development and an image formed product (copy, print) is obtained by transferring the toner image onto a transfer material such as paper is generally used. Further, the surface of the electrophotographic photosensitive member after the toner image is transferred is cleaned as necessary.

このプロセスを採用した電子写真装置においては、様々な原因から騒音が発生することがある。   In an electrophotographic apparatus employing this process, noise may be generated due to various causes.

騒音発生の1つの原因として、電子写真感光体の表面の帯電が挙げられる。   One cause of noise generation is charging of the surface of the electrophotographic photosensitive member.

帯電装置としては、従来、非接触帯電装置であるコロナ帯電装置が汎用されていたが、近年、電子写真感光体に接触配置された接触帯電部材に外部電源から電圧を印加して電子写真感光体の表面の帯電を行う接触帯電装置が実用化されている。   Conventionally, a corona charging device, which is a non-contact charging device, has been widely used as a charging device. However, in recent years, a voltage is applied from an external power source to a contact charging member placed in contact with the electrophotographic photosensitive member. A contact charging device for charging the surface of the substrate has been put into practical use.

接触帯電装置としては、帯電均一性の観点から、接触帯電部材に外部電源から1〜2kV程度の直流電圧と2kVP−Pの交流電圧とを重畳した振動電圧を印加して電子写真感光体の表面の帯電を行う装置が一般的である。 Contact as the charging device, from the viewpoint of charging uniformity, the contact charging member from an external power source applies a vibration voltage obtained by superimposing the alternating voltage of the DC voltage and 2 kV P-P of about 1~2kV the electrophotographic photosensitive member A device that charges the surface is common.

しかしながら、振動電圧が印加された接触帯電部材は、電子写真感光体との間で接触−離間を繰り返すため、電子写真感光体が振動し、帯電音と呼ばれる騒音が発生することがある。   However, since the contact charging member to which the oscillating voltage is applied repeats contact and separation with the electrophotographic photosensitive member, the electrophotographic photosensitive member may vibrate and noise called charging noise may be generated.

また、騒音発生の別の原因として、電子写真感光体の表面のクリーニングが挙げられる。   Another cause of noise generation is cleaning of the surface of the electrophotographic photosensitive member.

近年の電子写真感光体の高耐久化に伴い、電子写真感光体とクリーニング部材との摩擦力が大きくなり、その結果、電子写真感光体とクリーニング部材との間で振動音(騒音)が発生することがある。これは、回転する電子写真感光体とクリーニング部材との摩擦力によって、特に電子写真感光体の回転開始時や回転停止時といった低速回転時にスティックスリップ振動が増大し、電子写真感光体が過度に振動することによって発生する振動音である。   As the electrophotographic photosensitive member becomes more durable in recent years, the frictional force between the electrophotographic photosensitive member and the cleaning member increases, and as a result, vibration noise (noise) occurs between the electrophotographic photosensitive member and the cleaning member. Sometimes. This is because the stick-slip vibration increases due to the frictional force between the rotating electrophotographic photosensitive member and the cleaning member, particularly when the electrophotographic photosensitive member starts rotating or when the rotation stops, and the electrophotographic photosensitive member vibrates excessively. It is a vibration sound generated by doing.

これらの騒音を防止する方法の1つとして、電子写真感光体の円筒状支持体の内周面側に、弾性体や樹脂や金属などの挿入体を押し込むことが知られている(特開平05−035048号公報(特許文献1)など)。また、挿入体の形状や固定方法についても、様々な方法が知られている(特開平06−019377号公報(特許文献2)など)。   As one of the methods for preventing these noises, it is known to push an insertion body such as an elastic body, resin, metal or the like into the inner peripheral surface side of the cylindrical support of the electrophotographic photosensitive member (Japanese Patent Laid-Open No. 05/1995). No. 035048 (Patent Document 1) and the like. Various methods are known for the shape and fixing method of the insert (Japanese Patent Laid-Open No. 06-019377 (Patent Document 2), etc.).

しかしながら、これら従来の技術では、挿入体の端面形状が限定されたり、また、挿入体の端面の精度が低いと自動押し込み装置などにおいて挿入中の詰まりなどが発生したりしていた。また、異なる端面形状の挿入体を連続して押し込めない(量産性が低い)ことや、特殊な形状の挿入体に対する自動化ができない(生産コストが高い)ことなども問題となっていた。
特開平05−035048号公報 特開平06−019377号公報
However, in these conventional techniques, the shape of the end face of the insert is limited, and if the accuracy of the end face of the insert is low, the automatic push-in device or the like may be clogged during insertion. In addition, the inserts having different end face shapes cannot be pushed in continuously (low mass productivity), and the inserts having special shapes cannot be automated (the production cost is high).
JP 05-035048 A JP 06-019377 A

本発明の目的は、従来の問題点を解決し、様々な形状の挿入体をフレキシブルに押し込むことができる、量産性、コスト面に優れた挿入体押し込み方法を採用した、電子写真感光体の製造方法を提供することにある。   An object of the present invention is to manufacture an electrophotographic photoreceptor using an insert push-in method that solves the conventional problems and can insert various shapes of inserts flexibly and is excellent in mass productivity and cost. It is to provide a method.

また、本発明の目的は、上記製造方法により製造された電子写真感光体を有するプロセスカートリッジおよび電子写真装置を提供することにある。   Another object of the present invention is to provide a process cartridge and an electrophotographic apparatus having an electrophotographic photosensitive member manufactured by the above manufacturing method.

本発明は、円筒状支持体の外周面側に感光層を有し、該円筒状支持体の内周面側に挿入体を有する電子写真感光体の製造方法であって、
該円筒状支持体の外周面側に該感光層を形成する感光層形成工程と、
該円筒状支持体の内周面側に押し込み部材によって該挿入体を押し込む挿入体押し込み工程と
を有する電子写真感光体の製造方法において、
該押し込み部材は、押し込み方向に伸縮自在な突起を複数有し、かつ、該突起を所定位置で固定する突起固定手段を有し、
該挿入体押し込み工程は、該突起固定手段により所定位置に固定された該突起から該挿入体に押し込み方向の押圧力を加えることによって、該円筒状支持体の内周面側に該挿入体を押し込む工程である
ことを特徴とする電子写真感光体の製造方法である。
The present invention is a method for producing an electrophotographic photosensitive member having a photosensitive layer on the outer peripheral surface side of a cylindrical support, and having an insert on the inner peripheral surface side of the cylindrical support,
A photosensitive layer forming step of forming the photosensitive layer on the outer peripheral surface side of the cylindrical support;
In the method of manufacturing an electrophotographic photosensitive member, comprising: an insertion body pushing step of pushing the insertion body into the inner peripheral surface side of the cylindrical support by a pushing member;
The push-in member has a plurality of protrusions that can expand and contract in the push-in direction, and has a protrusion fixing means that fixes the protrusions at a predetermined position.
In the inserting body pushing step, the inserting body is applied to the inner peripheral surface side of the cylindrical support body by applying a pushing force in the pushing direction to the inserting body from the protrusion fixed at a predetermined position by the protrusion fixing means. An electrophotographic photosensitive member production method characterized by being a pressing step.

本発明によれば、様々な形状の挿入体をフレキシブルに押し込むことができる、量産性、コスト面に優れた挿入体押し込み方法を採用した、電子写真感光体の製造方法を提供することができる。   According to the present invention, it is possible to provide a method for producing an electrophotographic photosensitive member that employs an insert push-in method that can flexibly push inserts of various shapes and is excellent in mass productivity and cost.

また、本発明によれば、上記製造方法により製造された電子写真感光体を有するプロセスカートリッジおよび電子写真装置を提供することができる。   In addition, according to the present invention, it is possible to provide a process cartridge and an electrophotographic apparatus having the electrophotographic photosensitive member manufactured by the above manufacturing method.

以下、本発明を詳細に説明する。   Hereinafter, the present invention will be described in detail.

図1は、挿入体押し込み装置の概略構成の例を示す図である。   FIG. 1 is a diagram illustrating an example of a schematic configuration of an insertion body pushing device.

図1において、101は円筒状支持体、104は感光層、106は挿入体、107は突起、108は突起固定手段、109は押し込み部材、110は支持部、111は挿入体ガイドレールである。   In FIG. 1, 101 is a cylindrical support, 104 is a photosensitive layer, 106 is an insert, 107 is a protrusion, 108 is a protrusion fixing means, 109 is a pushing member, 110 is a support portion, and 111 is an insert guide rail.

円筒状支持体101の外周面側に感光層104を設けたものを支持部110にセットし、挿入体106を挿入体ガイドレール111にセットする(図1(a))。次に、突起107および突起固定手段108を有する押し込み部材109を移動させて、挿入体106の端部形状に沿うように突起107を伸縮させ、突起固定手段108により突起107を所定の位置で固定する。この状態で、突起107から挿入体106に押し込み方向の押圧力を加えて、円筒状支持体101の内周面側に挿入体106を押し込む(図1(b))。挿入後は、固定を解除して各突起を原点に復帰させることができる。   A cylindrical support 101 provided with a photosensitive layer 104 on the outer peripheral surface side is set on a support 110, and an insert 106 is set on an insert guide rail 111 (FIG. 1A). Next, the pushing member 109 having the protrusion 107 and the protrusion fixing means 108 is moved to expand and contract the protrusion 107 so as to follow the shape of the end portion of the insert 106, and the protrusion 107 is fixed at a predetermined position by the protrusion fixing means 108. To do. In this state, a pressing force in the pressing direction is applied from the protrusion 107 to the insertion body 106 to push the insertion body 106 into the inner peripheral surface side of the cylindrical support 101 (FIG. 1B). After insertion, the fixing can be released and each projection can be returned to the origin.

この構成により、挿入体106の端部形状がどのような形状でも円筒状支持体101の内周面側に押し込むことができる。   With this configuration, any shape of the end of the insert 106 can be pushed into the inner peripheral surface of the cylindrical support 101.

次に、電子写真感光体の層構成について説明する。   Next, the layer structure of the electrophotographic photoreceptor will be described.

上述のとおり、本発明の製造方法により製造される電子写真感光体は、円筒状支持体(以下、単に支持体ともいう)の外周面に感光層を有する電子写真感光体である。   As described above, the electrophotographic photoreceptor produced by the production method of the present invention is an electrophotographic photoreceptor having a photosensitive layer on the outer peripheral surface of a cylindrical support (hereinafter also simply referred to as a support).

感光層は、電荷輸送物質と電荷発生物質を同一の層に含有する単層型感光層であっても、電荷発生物質を含有する電荷発生層と電荷輸送物質を含有する電荷輸送層とに分離した積層型(機能分離型)感光層であってもよいが、電子写真特性の観点からは積層型感光層が好ましい。また、積層型感光層には、支持体側から電荷発生層、電荷輸送層の順に積層した順層型感光層と、支持体側から電荷輸送層、電荷発生層の順に積層した逆層型感光層があるが、電子写真特性の観点からは順層型感光層が好ましい。   The photosensitive layer is separated into a charge generating layer containing a charge generating material and a charge transporting layer containing a charge transporting material even if it is a single layer type photosensitive layer containing the charge transporting material and the charge generating material in the same layer. A laminated type (functional separation type) photosensitive layer may be used, but a laminated type photosensitive layer is preferred from the viewpoint of electrophotographic characteristics. The laminated photosensitive layer has a normal layer type photosensitive layer laminated in the order of the charge generation layer and the charge transport layer from the support side, and a reverse layer type photosensitive layer laminated in the order of the charge transport layer and the charge generation layer from the support side. However, a normal photosensitive layer is preferred from the viewpoint of electrophotographic characteristics.

支持体としては、導電性を有していればよく(導電性支持体)、例えば、アルミニウム、アルミニウム合金、ステンレスなどの金属製の支持体を用いることができる。また、アルミニウム、アルミニウム合金、酸化インジウム−酸化スズ合金などを真空蒸着によって被膜形成された層を有する上記金属製支持体やプラスチック製支持体を用いることもできる。また、カーボンブラック、酸化スズ粒子、酸化チタン粒子、銀粒子などの導電性粒子を適当な結着樹脂と共にプラスチックや紙に含浸した支持体や、導電性結着樹脂を有するプラスチック製の支持体などを用いることもできる。   As a support body, what is necessary is just to have electroconductivity (conductive support body), for example, metal supports, such as aluminum, an aluminum alloy, and stainless steel, can be used. Moreover, the said metal support body and plastic support body which have the layer in which aluminum, aluminum alloy, the indium oxide tin oxide alloy etc. were formed into a film by vacuum deposition can also be used. In addition, a support in which conductive particles such as carbon black, tin oxide particles, titanium oxide particles, and silver particles are impregnated into plastic or paper together with an appropriate binder resin, or a plastic support having a conductive binder resin, etc. Can also be used.

支持体と感光層(電荷発生層、電荷輸送層)または後述の中間層との間には、レーザー光などの散乱による干渉縞の防止や、支持体の傷の被覆を目的とした導電層を設けてもよい。導電層は、カーボンブラック、金属粒子などの導電性粒子を結着樹脂に分散させて形成することができる。導電層の膜厚は、0.1〜30μmであることが好ましく、特には0.5〜20μmであることがより好ましい。   Between the support and the photosensitive layer (charge generation layer, charge transport layer) or an intermediate layer described later, there is a conductive layer for the purpose of preventing interference fringes due to scattering of laser light or the like and covering the scratches on the support. It may be provided. The conductive layer can be formed by dispersing conductive particles such as carbon black and metal particles in a binder resin. The thickness of the conductive layer is preferably 0.1 to 30 μm, and more preferably 0.5 to 20 μm.

また、支持体または導電層と感光層(電荷発生層、電荷輸送層)との間には、バリア機能や接着機能を有する中間層を設けてもよい。中間層は、感光層の接着性改良、塗工性改良、支持体からの電荷注入性改良、感光層の電気的破壊に対する保護などのために形成される。中間層は、カゼイン樹脂、ポリビニルアルコール樹脂、エチルセルロース樹脂、エチレン−アクリル酸コポリマー、ポリアミド樹脂、変性ポリアミド樹脂、ポリウレタン樹脂、ゼラチン樹脂、酸化アルミニウムなどの材料を用いて形成することができる。中間層の膜厚は0.05〜5μmであることが好ましく、特には0.3〜1.5μmであることがより好ましい。   Further, an intermediate layer having a barrier function or an adhesive function may be provided between the support or the conductive layer and the photosensitive layer (charge generation layer, charge transport layer). The intermediate layer is formed for the purpose of improving the adhesion of the photosensitive layer, improving the coating property, improving the charge injection property from the support, and protecting the photosensitive layer from electrical breakdown. The intermediate layer can be formed using materials such as casein resin, polyvinyl alcohol resin, ethyl cellulose resin, ethylene-acrylic acid copolymer, polyamide resin, modified polyamide resin, polyurethane resin, gelatin resin, and aluminum oxide. The thickness of the intermediate layer is preferably 0.05 to 5 μm, and more preferably 0.3 to 1.5 μm.

本発明の電子写真感光体に用いられる電荷発生物質としては、例えば、モノアゾ、ジスアゾ、トリスアゾなどのアゾ顔料や、金属フタロシアニン、非金属フタロシアニンなどのフタロシアニン顔料や、インジゴ、チオインジゴなどのインジゴ顔料や、ペリレン酸無水物、ペリレン酸イミドなどのペリレン顔料や、アンスラキノン、ピレンキノンなどの多環キノン顔料や、スクワリリウム色素や、ピリリウム塩およびチアピリリウム塩や、トリフェニルメタン色素や、セレン、セレン−テルル、アモルファスシリコンなどの無機物質や、キナクリドン顔料や、アズレニウム塩顔料や、シアニン染料や、キサンテン色素や、キノンイミン色素や、スチリル色素や、硫化カドミウムや、酸化亜鉛などが挙げられる。これら電荷発生物質は1種のみ用いてもよく、2種以上用いてもよい。   Examples of the charge generating material used in the electrophotographic photoreceptor of the present invention include azo pigments such as monoazo, disazo, and trisazo, phthalocyanine pigments such as metal phthalocyanine and nonmetal phthalocyanine, indigo pigments such as indigo and thioindigo, Perylene pigments such as perylene acid anhydride and perylene imide, polycyclic quinone pigments such as anthraquinone and pyrenequinone, squarylium dyes, pyrylium salts and thiapyrylium salts, triphenylmethane dyes, selenium, selenium-tellurium, amorphous Examples thereof include inorganic substances such as silicon, quinacridone pigments, azulenium salt pigments, cyanine dyes, xanthene dyes, quinoneimine dyes, styryl dyes, cadmium sulfide, and zinc oxide. These charge generation materials may be used alone or in combination of two or more.

感光層が積層型感光層である場合、電荷発生層に用いる結着樹脂としては、例えば、ポリカーボネート樹脂、ポリエステル樹脂、ポリアリレート樹脂、ブチラール樹脂、ポリスチレン樹脂、ポリビニルアセタール樹脂、ジアリルフタレート樹脂、アクリル樹脂、メタクリル樹脂、酢酸ビニル樹脂、フェノール樹脂、シリコーン樹脂、ポリスルホン樹脂、スチレン−ブタジエン共重合体樹脂、アルキッド樹脂、エポキシ樹脂、尿素樹脂、塩化ビニル−酢酸ビニル共重合体樹脂などが挙げられる。特には、ブチラール樹脂などが好ましい。これらは単独、混合または共重合体として1種または2種以上用いることができる。   When the photosensitive layer is a laminated photosensitive layer, examples of the binder resin used for the charge generation layer include polycarbonate resin, polyester resin, polyarylate resin, butyral resin, polystyrene resin, polyvinyl acetal resin, diallyl phthalate resin, and acrylic resin. Methacrylic resin, vinyl acetate resin, phenol resin, silicone resin, polysulfone resin, styrene-butadiene copolymer resin, alkyd resin, epoxy resin, urea resin, vinyl chloride-vinyl acetate copolymer resin, and the like. In particular, a butyral resin is preferable. These can be used singly or in combination of two or more as a mixture or copolymer.

電荷発生層は、電荷発生物質を結着樹脂および溶剤と共に分散して得られる電荷発生層用塗布液を塗布し、乾燥することによって形成することができる。分散方法としては、ホモジナイザー、超音波、ボールミル、サンドミル、ロールミル、振動ミル、アトライター、液衝突型高速分散機などを用いた方法が挙げられる。電荷発生物質と結着樹脂との割合は、1:0.3〜1:4(質量比)の範囲が好ましい。   The charge generation layer can be formed by applying and drying a charge generation layer coating solution obtained by dispersing a charge generation material together with a binder resin and a solvent. Examples of the dispersion method include a method using a homogenizer, an ultrasonic wave, a ball mill, a sand mill, a roll mill, a vibration mill, an attritor, a liquid collision type high-speed disperser, and the like. The ratio between the charge generating material and the binder resin is preferably in the range of 1: 0.3 to 1: 4 (mass ratio).

電荷発生層用塗布液に用いる溶剤は、使用する結着樹脂や電荷発生物質の溶解性や分散安定性から選択されるが、有機溶剤としてはアルコール、スルホキシド、ケトン、エーテル、エステル、脂肪族ハロゲン化炭化水素、芳香族化合物などが挙げられる。   The solvent used in the coating solution for the charge generation layer is selected from the solubility and dispersion stability of the binder resin and charge generation material used, and the organic solvents include alcohols, sulfoxides, ketones, ethers, esters, aliphatic halogens. Hydrocarbons and aromatic compounds.

電荷発生層の膜厚は5μm以下であることが好ましく、特には0.1〜2μmであることがより好ましい。   The thickness of the charge generation layer is preferably 5 μm or less, and more preferably 0.1 to 2 μm.

また、電荷発生層には、種々の増感剤、酸化防止剤、紫外線吸収剤、可塑剤などを必要に応じて添加することもできる。   In addition, various sensitizers, antioxidants, ultraviolet absorbers, plasticizers, and the like can be added to the charge generation layer as necessary.

本発明の電子写真感光体に用いられる電荷輸送物質としては、例えば、トリアリールアミン化合物、ヒドラゾン化合物、スチリル化合物、スチルベン化合物、ピラゾリン化合物、オキサゾール化合物、チアゾール化合物、トリアリールメタン化合物などが挙げられる。これら電荷輸送物質は1種のみ用いてもよく、2種以上用いてもよい。   Examples of the charge transport material used in the electrophotographic photoreceptor of the present invention include triarylamine compounds, hydrazone compounds, styryl compounds, stilbene compounds, pyrazoline compounds, oxazole compounds, thiazole compounds, and triarylmethane compounds. These charge transport materials may be used alone or in combination of two or more.

感光層が積層型感光層である場合、電荷輸送層に用いる結着樹脂としては、例えば、アクリル樹脂、メタクリル樹脂、ポリアクリルアミド樹脂、アクリロニトリル樹脂、ポリアミド樹脂、ポリビニルブチラール樹脂、塩化ビニル樹脂、酢酸ビニル樹脂、フェノキシ樹脂、フェノール樹脂、ポリスチレン樹脂、ポリエステル樹脂、ポリカーボネート樹脂、ポリアリレート樹脂、ポリスルホン樹脂、ポリフェニレンオキシド樹脂、エポキシ樹脂、ポリウレタン樹脂、アルキド樹脂、不飽和樹脂などが挙げられる。特には、ポリカーボネート樹脂、ポリアリレート樹脂などが好ましい。これらは単独、混合または共重合体として1種または2種以上用いることができる。   When the photosensitive layer is a laminated photosensitive layer, examples of the binder resin used for the charge transport layer include acrylic resin, methacrylic resin, polyacrylamide resin, acrylonitrile resin, polyamide resin, polyvinyl butyral resin, vinyl chloride resin, vinyl acetate. Examples include resins, phenoxy resins, phenol resins, polystyrene resins, polyester resins, polycarbonate resins, polyarylate resins, polysulfone resins, polyphenylene oxide resins, epoxy resins, polyurethane resins, alkyd resins, and unsaturated resins. In particular, polycarbonate resin, polyarylate resin and the like are preferable. These can be used singly or in combination of two or more as a mixture or copolymer.

電荷輸送層は、電荷輸送物質と結着樹脂を溶剤に溶解して得られる電荷輸送層用塗布液を塗布し、乾燥することによって形成することができる。電荷輸送物質と結着樹脂との割合は、5:1〜1:5(質量比)の範囲が好ましく、特には3:1〜1:3(質量比)の範囲がより好ましい。   The charge transport layer can be formed by applying and drying a charge transport layer coating solution obtained by dissolving a charge transport material and a binder resin in a solvent. The ratio between the charge transport material and the binder resin is preferably in the range of 5: 1 to 1: 5 (mass ratio), and more preferably in the range of 3: 1 to 1: 3 (mass ratio).

電荷輸送層用塗布液に用いる溶剤としては、アセトン、メチルエチルケトンなどのケトン、酢酸メチル、酢酸エチルなどのエステル、トルエン、キシレンなどの芳香族炭化水素、1,4−ジオキサン、テトラヒドロフランなどのエーテル、クロロベンゼン、クロロホルム、四塩化炭素などのハロゲン原子で置換された炭化水素などが用いられる。   Solvents used in the charge transport layer coating solution include ketones such as acetone and methyl ethyl ketone, esters such as methyl acetate and ethyl acetate, aromatic hydrocarbons such as toluene and xylene, ethers such as 1,4-dioxane and tetrahydrofuran, and chlorobenzene. , Hydrocarbons substituted with halogen atoms such as chloroform and carbon tetrachloride are used.

電荷輸送層の膜厚は5〜50μmであることが好ましく、特には10〜35μmであることがより好ましい。   The thickness of the charge transport layer is preferably 5 to 50 μm, and more preferably 10 to 35 μm.

また、電荷輸送層には、酸化防止剤、紫外線吸収剤、可塑剤などを必要に応じて添加することもできる。   In addition, an antioxidant, an ultraviolet absorber, a plasticizer, and the like can be added to the charge transport layer as necessary.

感光層が単層型感光層である場合、該単層型感光層は、上記電荷発生物質および上記電荷輸送物質を上記結着樹脂および上記溶剤と共に分散して得られる単層型感光層用塗布液を塗布し、乾燥することによって形成することができる。   When the photosensitive layer is a single-layer type photosensitive layer, the single-layer type photosensitive layer is a coating for a single-layer type photosensitive layer obtained by dispersing the charge generation material and the charge transport material together with the binder resin and the solvent. It can be formed by applying a liquid and drying.

また、感光層上には、該感光層を保護することを目的とした保護層を設けてもよい。保護層は、上述した各種結着樹脂を溶剤に溶解して得られる保護層用塗布液を塗布し、乾燥することによって形成することができる。   Further, a protective layer may be provided on the photosensitive layer for the purpose of protecting the photosensitive layer. The protective layer can be formed by applying and drying a protective layer coating solution obtained by dissolving the various binder resins described above in a solvent.

保護層の膜厚は0.5〜10μmであることが好ましく、特には1〜5μmであることが好ましい。   The thickness of the protective layer is preferably 0.5 to 10 μm, and particularly preferably 1 to 5 μm.

上記各層の塗布液を塗布する際には、例えば、浸漬コーティング法(浸漬塗布法)、スプレーコーティング法、スピンナーコーティング法、ローラーコーティング法、マイヤーバーコーティング法、ブレードコーティング法などの塗布方法を用いることができる。   When applying the coating liquid for each of the above layers, for example, a coating method such as a dip coating method (a dip coating method), a spray coating method, a spinner coating method, a roller coating method, a Meyer bar coating method, a blade coating method, or the like is used. Can do.

図2に、電子写真感光体を有するプロセスカートリッジを備えた電子写真装置の概略構成の一例を示す。   FIG. 2 shows an example of a schematic configuration of an electrophotographic apparatus provided with a process cartridge having an electrophotographic photosensitive member.

図2において、1は円筒状の電子写真感光体であり、軸2を中心に矢印方向に所定の周速度で回転駆動される。   In FIG. 2, reference numeral 1 denotes a cylindrical electrophotographic photosensitive member, which is driven to rotate at a predetermined peripheral speed in the direction of an arrow about an axis 2.

回転駆動される電子写真感光体1の表面は、帯電手段(一次帯電手段:帯電ローラーなど)3により、正または負の所定電位に均一に帯電され、次いで、スリット露光やレーザービーム走査露光などの露光手段(不図示)から出力される露光光(画像露光光)4を受ける。こうして電子写真感光体1の表面に、目的の画像に対応した静電潜像が順次形成されていく。   The surface of the electrophotographic photosensitive member 1 that is rotationally driven is uniformly charged to a predetermined positive or negative potential by a charging unit (primary charging unit: charging roller or the like) 3, and then subjected to slit exposure, laser beam scanning exposure, or the like. Exposure light (image exposure light) 4 output from exposure means (not shown) is received. In this way, electrostatic latent images corresponding to the target image are sequentially formed on the surface of the electrophotographic photosensitive member 1.

電子写真感光体1の表面に形成された静電潜像は、現像手段5の現像剤に含まれるトナーにより現像されてトナー像となる。次いで、電子写真感光体1の表面に形成担持されているトナー像が、転写手段(転写ローラーなど)6からの転写バイアスによって、転写材供給手段(不図示)から電子写真感光体1と転写手段6との間(当接部)に電子写真感光体1の回転と同期して取り出されて給送された転写材(紙など)Pに順次転写されていく。   The electrostatic latent image formed on the surface of the electrophotographic photoreceptor 1 is developed with toner contained in the developer of the developing means 5 to become a toner image. Next, the toner image formed and supported on the surface of the electrophotographic photoreceptor 1 is transferred from a transfer material supply means (not shown) to the electrophotographic photoreceptor 1 and the transfer means by a transfer bias from a transfer means (transfer roller or the like) 6. 6 (contact portion) is sequentially transferred onto a transfer material (paper or the like) P taken out and fed in synchronization with the rotation of the electrophotographic photosensitive member 1.

トナー像の転写を受けた転写材Pは、電子写真感光体1の表面から分離されて定着手段8へ導入されて像定着を受けることにより画像形成物(プリント、コピー)として装置外へプリントアウトされる。   The transfer material P that has received the transfer of the toner image is separated from the surface of the electrophotographic photosensitive member 1 and introduced into the fixing means 8 to receive the image fixing, and is printed out as an image formed product (print, copy). Is done.

トナー像転写後の電子写真感光体1の表面は、クリーニング手段(クリーニングブレードなど)7によって転写残りの現像剤(トナー)の除去を受けて清浄面化され、さらに前露光手段(不図示)からの前露光光(不図示)により除電処理された後、繰り返し画像形成に使用される。なお、図2に示すように、帯電手段3が帯電ローラーなどを用いた接触帯電手段である場合は、前露光は必ずしも必要ではない。   The surface of the electrophotographic photosensitive member 1 after the transfer of the toner image is cleaned by a cleaning means (cleaning blade or the like) 7 to remove the developer (toner) remaining after transfer, and further from a pre-exposure means (not shown). After being subjected to charge removal processing by pre-exposure light (not shown), it is repeatedly used for image formation. As shown in FIG. 2, when the charging unit 3 is a contact charging unit using a charging roller or the like, pre-exposure is not necessarily required.

上述の電子写真感光体1、帯電手段3、現像手段5、転写手段6およびクリーニング手段7などの構成要素のうち、複数のものを容器に納めてプロセスカートリッジとして一体に結合して構成し、このプロセスカートリッジを複写機やレーザービームプリンターなどの電子写真装置本体に対して着脱自在に構成してもよい。図2では、電子写真感光体1と、帯電手段3、現像手段5およびクリーニング手段7とを一体に支持してカートリッジ化して、電子写真装置本体のレールなどの案内手段10を用いて電子写真装置本体に着脱自在なプロセスカートリッジ9としている。   Among the above-described components such as the electrophotographic photosensitive member 1, the charging unit 3, the developing unit 5, the transfer unit 6 and the cleaning unit 7, a plurality of components are housed in a container and integrally combined as a process cartridge. The process cartridge may be configured to be detachable from an electrophotographic apparatus main body such as a copying machine or a laser beam printer. In FIG. 2, the electrophotographic photosensitive member 1, the charging unit 3, the developing unit 5 and the cleaning unit 7 are integrally supported to form a cartridge, and the electrophotographic apparatus is used by using a guide unit 10 such as a rail of the electrophotographic apparatus main body. The process cartridge 9 is detachable from the main body.

以下に、具体的な実施例を挙げて本発明をさらに詳細に説明する。ただし、本発明はこれらに限定されるものではない。なお、実施例中の「部」は「質量部」を意味する。   Hereinafter, the present invention will be described in more detail with reference to specific examples. However, the present invention is not limited to these. In the examples, “part” means “part by mass”.

(実施例1)
直径30mm、肉厚0.75mm、長さ260mmのアルミニウムシリンダーを支持体(円筒状支持体)とした。
(Example 1)
An aluminum cylinder having a diameter of 30 mm, a thickness of 0.75 mm, and a length of 260 mm was used as a support (cylindrical support).

次に、SnOコート処理硫酸バリウム(導電性粒子)10部、酸化チタン(抵抗調整用)2部、フェノール樹脂(商品名:プライオーフェンJ−325、大日本インキ化学工業(株)製)6部、シリコーンオイル(レベリング剤)0.001部、および、メタノール4部/メトキシプロパノール16部の混合溶媒を、直径1mmのガラスビーズを用いたサンドミル装置で2時間分散して、導電層用塗布液を調製した。 Next, 10 parts of SnO 2 coated barium sulfate (conductive particles), 2 parts of titanium oxide (for resistance adjustment), phenol resin (trade name: Priorofen J-325, manufactured by Dainippon Ink & Chemicals, Inc.) 6 Particulates, 0.001 part of silicone oil (leveling agent), and a mixed solvent of 4 parts of methanol / 16 parts of methoxypropanol were dispersed for 2 hours in a sand mill using glass beads having a diameter of 1 mm to obtain a coating solution for a conductive layer. Was prepared.

この導電層用塗布液を、支持体上に浸漬塗布し、140℃で30分間熱硬化して、膜厚が15μmの導電層を形成した。   This conductive layer coating solution was applied by dip coating on a support and thermally cured at 140 ° C. for 30 minutes to form a conductive layer having a thickness of 15 μm.

次に、N−メトキシメチル化ナイロン3部、および、共重合ナイロン3部を、メタノール65部/n−ブタノール30部の混合溶媒に溶解して、中間層用塗布液を調製した。   Next, 3 parts of N-methoxymethylated nylon and 3 parts of copolymer nylon were dissolved in a mixed solvent of 65 parts of methanol / 30 parts of n-butanol to prepare an intermediate layer coating solution.

この中間層用塗布液を、導電層上に浸漬塗布し、80℃で10分間乾燥して、膜厚が0.5μmの中間層を形成した。   This intermediate layer coating solution was dip coated on the conductive layer and dried at 80 ° C. for 10 minutes to form an intermediate layer having a thickness of 0.5 μm.

次に、下記式で示される構造を有するアゾ顔料(電荷発生物質)4部、   Next, 4 parts of an azo pigment (charge generation material) having a structure represented by the following formula:

Figure 2005215457
Figure 2005215457

ポリビニルブチラール樹脂(商品名:エスレックBLS、積水化学(株)製)2部およびシクロヘキサノン35部を、直径1mmのガラスビーズを用いたサンドミル装置で12時間分散し、次に、メチルエチルケトン60部を加えて電荷発生層用塗布液を調製した。 Disperse 2 parts of polyvinyl butyral resin (trade name: ESREC BLS, manufactured by Sekisui Chemical Co., Ltd.) and 35 parts of cyclohexanone for 12 hours in a sand mill using glass beads having a diameter of 1 mm, and then add 60 parts of methyl ethyl ketone. A coating solution for charge generation layer was prepared.

この電荷発生層用塗布液を、中間層上に浸漬塗布し、80℃で10分間乾燥して、膜厚が0.3μmの電荷発生層を形成した。   This charge generation layer coating solution was dip coated on the intermediate layer and dried at 80 ° C. for 10 minutes to form a charge generation layer having a thickness of 0.3 μm.

次に、下記式で示される構造を有するアミン化合物(電荷輸送物質)7部、   Next, 7 parts of an amine compound (charge transport material) having a structure represented by the following formula:

Figure 2005215457
Figure 2005215457

下記式で示される構造を有するアミン化合物(電荷輸送物質)1部、 1 part of an amine compound (charge transport material) having a structure represented by the following formula:

Figure 2005215457
Figure 2005215457

および、ポリカーボネート樹脂(商品名:ユーピロンZ200、三菱ガス化学(株)製)10部を、クロロベンゼン80部に溶解して電荷輸送層用塗布液を調製した。 And 10 parts of polycarbonate resin (trade name: Iupilon Z200, manufactured by Mitsubishi Gas Chemical Co., Ltd.) was dissolved in 80 parts of chlorobenzene to prepare a coating solution for charge transport layer.

この電荷輸送層用塗布液を、電荷発生層上に浸漬塗布し、120℃で1時間乾燥して、膜厚が30μmの電荷輸送層を形成した。   This charge transport layer coating solution was dip coated on the charge generation layer and dried at 120 ° C. for 1 hour to form a charge transport layer having a thickness of 30 μm.

次に、円筒状支持体の内周面側に、シアノアクリレート系瞬間接着剤0.1gを塗布した後、アルミニウム製の円柱状挿入体(外径28.48mm、長さ65mm、図4参照)を、図3に示す直径2mmの突起が5つある押し込み部材を用い、図1に示す構成の挿入体押し込み装置を用いて、支持体の中央部まで押し込んだ。   Next, 0.1 g of cyanoacrylate instantaneous adhesive was applied to the inner peripheral surface side of the cylindrical support, and then a columnar insert made of aluminum (outer diameter 28.48 mm, length 65 mm, see FIG. 4). 3 was pushed to the center of the support using the push-in member having five protrusions with a diameter of 2 mm shown in FIG. 3 and the insert push-in device having the configuration shown in FIG.

このようにして、円筒状支持体の外周面側に感光層を有し、円筒状支持体の内周面側に挿入体を有する電子写真感光体を作製した。   Thus, an electrophotographic photosensitive member having a photosensitive layer on the outer peripheral surface side of the cylindrical support and an insert on the inner peripheral surface side of the cylindrical support was produced.

この作業を100回行い、合計100個の電子写真感光体を作製したところ、挿入体押し込み時に、挿入体の詰まりは発生しなかった。   This operation was performed 100 times to produce a total of 100 electrophotographic photoreceptors. As a result, the insert was not clogged when the insert was pushed.

(実施例2)
実施例1において、挿入体をアルミニウム製の円筒状挿入体(外径28.48mm、内径15mm、長さ65mm、図5参照)に変更した以外は、実施例1と同様にして電子写真感光体を作製した。
(Example 2)
An electrophotographic photoreceptor in the same manner as in Example 1 except that the insert in Example 1 was changed to an aluminum cylindrical insert (outer diameter 28.48 mm, inner diameter 15 mm, length 65 mm, see FIG. 5). Was made.

実施例1と同様、合計100個の電子写真感光体を作製したところ、挿入体押し込み時に、挿入体の詰まりは発生しなかった。   As in Example 1, when a total of 100 electrophotographic photosensitive members were produced, the insert was not clogged when the insert was pushed.

(実施例3)
実施例1において、挿入体をABS樹脂製のスリットを有する円筒状挿入体(外径28.8mm、内径15mm、長さ100mm、図6参照)に変更した以外は、実施例1と同様にして電子写真感光体を作製した。
(Example 3)
Example 1 was the same as Example 1 except that the insert was changed to a cylindrical insert having an ABS resin slit (outer diameter 28.8 mm, inner diameter 15 mm, length 100 mm, see FIG. 6). An electrophotographic photosensitive member was produced.

実施例1と同様、合計100個の電子写真感光体を作製したところ、挿入体押し込み時に、挿入体の詰まりは発生しなかった。   As in Example 1, when a total of 100 electrophotographic photosensitive members were produced, the insert was not clogged when the insert was pushed.

(実施例4)
実施例1において、挿入体を鉄製芯(外径10mm、長さ100mm)にウレタンゴムをチューブ状に被覆してなる挿入体(外径28.6mm、図7参照)に変更した以外は、実施例1と同様にして電子写真感光体を作製した。
Example 4
In Example 1, except that the insert was changed to an insert (outer diameter 28.6 mm, see FIG. 7) formed by coating an iron core (outer diameter 10 mm, length 100 mm) with urethane rubber in a tube shape. An electrophotographic photosensitive member was produced in the same manner as in Example 1.

実施例1と同様、合計100個の電子写真感光体を作製したところ、挿入体押し込み時に、挿入体の詰まりは発生しなかった。   As in Example 1, when a total of 100 electrophotographic photosensitive members were produced, the insert was not clogged when the insert was pushed.

(実施例5)
実施例1において、押し込み部材を図8に示す直径2mmの突起が2つある押し込み部材に変更した以外は、実施例1と同様にして電子写真感光体を作製した。
(Example 5)
An electrophotographic photosensitive member was produced in the same manner as in Example 1 except that the pushing member was changed to a pushing member having two protrusions having a diameter of 2 mm shown in FIG.

実施例1と同様、合計100個の電子写真感光体を作製したところ、挿入体押し込み時に、挿入体の詰まりは発生しなかった。   As in Example 1, when a total of 100 electrophotographic photosensitive members were produced, the insert was not clogged when the insert was pushed.

(比較例1)
実施例1において、押し込み部材を図9に示す直径15mmの突き当て部が1つある押し込み部材(突起および突起固定手段を有さず)に変更した以外は、実施例1と同様にして電子写真感光体を作製した。
(Comparative Example 1)
In Example 1, the electrophotographic process was carried out in the same manner as in Example 1 except that the pushing member was changed to a pushing member having one abutting portion having a diameter of 15 mm shown in FIG. 9 (no protrusions and no protrusion fixing means). A photoconductor was prepared.

実施例1と同様、合計100個の電子写真感光体を作製したところ、100個中5個について、挿入体押し込み時に挿入体の詰まりが発生した。   As in Example 1, when a total of 100 electrophotographic photosensitive members were produced, clogging of the insert occurred when the insert was pushed in 5 out of 100.

(比較例2)
実施例2において、押し込み部材を図10に示す直径20mmの突き当て部が1つある押し込み部材(突起および突起固定手段を有さず)に変更した以外は、実施例2と同様にして電子写真感光体を作製した。
(Comparative Example 2)
In Example 2, the electrophotography was performed in the same manner as in Example 2 except that the pushing member was changed to a pushing member having one abutting portion having a diameter of 20 mm shown in FIG. 10 (no protrusion and no protrusion fixing means). A photoconductor was prepared.

実施例2と同様、合計100個の電子写真感光体を作製したところ、100個中4個について、挿入体押し込み時に挿入体の詰まりが発生した。   As in Example 2, a total of 100 electrophotographic photoconductors were produced. As a result, for 4 out of 100 electrophotographic photoreceptors, the insert was clogged when the insert was pushed.

(比較例3)
実施例4において、押し込み部材を図11に示す直径10mmの突き当て部が1つある押し込み部材(突起および突起固定手段を有さず)に変更した以外は、実施例4と同様にして電子写真感光体を作製した。
(Comparative Example 3)
In Example 4, the electrophotographic process was performed in the same manner as in Example 4 except that the pushing member was changed to a pushing member having one abutting portion having a diameter of 10 mm as shown in FIG. 11 (no protrusions and no protrusion fixing means). A photoconductor was prepared.

実施例2と同様、合計100個の電子写真感光体を作製したところ、100個中8個について、挿入体押し込み時に挿入体の詰まりが発生した。   As in Example 2, when a total of 100 electrophotographic photoreceptors were produced, about 8 out of 100 electrophotographic photoreceptors were clogged with the insert when the insert was pushed.

挿入体押し込み装置の概略構成。Schematic configuration of an insert pushing device. 電子写真感光体を有するプロセスカートリッジを備えた電子写真装置の概略構成。1 is a schematic configuration of an electrophotographic apparatus including a process cartridge having an electrophotographic photosensitive member. 直径2mmの突起が5つある押し込み部材。Pushing member with 5 protrusions with a diameter of 2 mm. アルミニウム製の円柱状挿入体。A cylindrical insert made of aluminum. アルミニウム製の円筒状挿入体。A cylindrical insert made of aluminum. ABS樹脂製のスリットを有する円筒状挿入体。A cylindrical insert having a slit made of ABS resin. 鉄製芯にウレタンゴムをチューブ状に被覆してなる挿入体。An insert formed by coating an iron core with urethane rubber in a tube shape. 直径2mmの突起が2つある押し込み部材。Pushing member with two 2 mm diameter protrusions. 直径15mmの突き当て部が1つある押し込み部材。A pushing member having one abutting portion having a diameter of 15 mm. 直径20mmの突き当て部が1つある押し込み部材。A pushing member having one abutting portion having a diameter of 20 mm. 直径10mmの突き当て部が1つある押し込み部材。A pushing member having one abutting portion having a diameter of 10 mm.

符号の説明Explanation of symbols

101 円筒状支持体
104 感光層
106 挿入体
107 突起
108 突起固定手段
109 押し込み部材
110 支持部
111 挿入体ガイドレール
1 電子写真感光体
2 軸
3 帯電手段
4 露光光
5 現像手段
6 転写手段
7 クリーニング手段
8 定着手段
9 プロセスカートリッジ
10 案内手段
DESCRIPTION OF SYMBOLS 101 Cylindrical support body 104 Photosensitive layer 106 Insertion body 107 Protrusion 108 Protrusion fixing means 109 Pushing member 110 Support part 111 Insertion body guide rail 1 Electrophotographic photoreceptor 2 Axis 3 Charging means 4 Exposure light 5 Developing means 6 Transfer means 7 Cleaning means 8 Fixing means 9 Process cartridge 10 Guide means

Claims (3)

円筒状支持体の外周面側に感光層を有し、該円筒状支持体の内周面側に挿入体を有する電子写真感光体の製造方法であって、
該円筒状支持体の外周面側に該感光層を形成する感光層形成工程と、
該円筒状支持体の内周面側に押し込み部材によって該挿入体を押し込む挿入体押し込み工程と
を有する電子写真感光体の製造方法において、
該押し込み部材は、押し込み方向に伸縮自在な突起を複数有し、かつ、該突起を所定位置で固定する突起固定手段を有し、
該挿入体押し込み工程は、該突起固定手段により所定位置に固定された該突起から該挿入体に押し込み方向の押圧力を加えることによって、該円筒状支持体の内周面側に該挿入体を押し込む工程である
ことを特徴とする電子写真感光体の製造方法。
A method for producing an electrophotographic photosensitive member having a photosensitive layer on the outer peripheral surface side of a cylindrical support, and having an insert on the inner peripheral surface side of the cylindrical support,
A photosensitive layer forming step of forming the photosensitive layer on the outer peripheral surface side of the cylindrical support;
In the method of manufacturing an electrophotographic photosensitive member, comprising: an insertion body pushing step of pushing the insertion body into the inner peripheral surface side of the cylindrical support by a pushing member;
The push-in member has a plurality of protrusions that can expand and contract in the push-in direction, and has a protrusion fixing means that fixes the protrusions at a predetermined position.
In the inserting body pushing step, the inserting body is applied to the inner peripheral surface side of the cylindrical support body by applying a pushing force in the pushing direction to the inserting body from the protrusion fixed at a predetermined position by the protrusion fixing means. A process for producing an electrophotographic photosensitive member, which is a pressing process.
請求項1に記載の製造方法により製造された電子写真感光体と、帯電手段、現像手段、転写手段およびクリーニング手段からなる群より選択される少なくとも1つの手段とを一体に支持し、電子写真装置本体に着脱自在であることを特徴とするプロセスカートリッジ。   An electrophotographic apparatus which integrally supports an electrophotographic photosensitive member produced by the production method according to claim 1 and at least one means selected from the group consisting of a charging means, a developing means, a transfer means and a cleaning means. A process cartridge which is detachable from the main body. 請求項1に記載の電子写真感光体、帯電手段、露光手段、現像手段および転写手段を有することを特徴とする電子写真装置。
An electrophotographic apparatus comprising the electrophotographic photosensitive member according to claim 1, a charging unit, an exposure unit, a developing unit, and a transfer unit.
JP2004023587A 2004-01-30 2004-01-30 Method for manufacturing electrophotographic photoreceptor, process cartridge, and electrophotographic apparatus Withdrawn JP2005215457A (en)

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