JP2005206532A - Hair-treating agent - Google Patents
Hair-treating agent Download PDFInfo
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- JP2005206532A JP2005206532A JP2004015381A JP2004015381A JP2005206532A JP 2005206532 A JP2005206532 A JP 2005206532A JP 2004015381 A JP2004015381 A JP 2004015381A JP 2004015381 A JP2004015381 A JP 2004015381A JP 2005206532 A JP2005206532 A JP 2005206532A
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- oil
- treatment agent
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Abstract
Description
本発明は、毛髪処理剤に関し、さらに詳しくは、毛髪に優れた指通り性と充分な柔軟性を付与することができる毛髪処理剤に関する。 The present invention relates to a hair treatment agent, and more particularly, to a hair treatment agent capable of imparting excellent fingering property and sufficient flexibility to hair.
毛髪に染毛のためのブリーチ処理やパーマネントウエーブ処理などの化学的処理を行うと、キューティクルの損傷や毛髪内部構造の変化により毛髪の指通り性や柔軟性が悪化する。そのため、そのような損傷を受けた毛髪にスタイリング剤によってヘアスタイルを整えようとすると、スタイリング剤の作用が充分に発揮できず、所望のヘアスタイルが得られなかったり、同一のスタイリングを用い、同一の手法でヘアスタイルを整えようとしているにもかかわらず、毛髪の損傷の程度によって、ヘアスタイルが変わってくるという問題があった。 When chemical treatment such as bleaching treatment or permanent wave treatment for hair dyeing is performed on the hair, the finger fingering and flexibility of the hair deteriorate due to cuticle damage and changes in the internal structure of the hair. Therefore, when trying to arrange a hairstyle with a styling agent on such damaged hair, the effect of the styling agent cannot be fully exerted, the desired hairstyle cannot be obtained, or the same styling is used and the same In spite of trying to arrange the hairstyle by this method, there is a problem that the hairstyle changes depending on the degree of hair damage.
そのため、スタイリング剤の使用に先立ち、スタイリング剤の作用を充分に発揮させて、所望のヘアスタイルを得たり、ヘアスタイルのバラツキ発生を防止することができるようにするため、あらかじめ毛髪に指通り性や柔軟性を付与して、毛髪を均一な状態にしておくための毛髪処理剤が必要になる。 For this reason, prior to using the styling agent, the styling agent is fully exerted to obtain the desired hair style and prevent hair style variation. And a hair treatment agent for imparting flexibility and keeping the hair uniform.
そのような目的で使用する毛髪処理剤として、従来は、カチオン性界面活性剤やカチオン性ポリマー、カチオン性シリコーンなどを含有させたヘアーリンスやヘアトリートメントなどが用いられていたが、これらのヘアーリンスやヘアトリートメントでは毛髪に優れた指通り性や充分な柔軟性を付与することが難しかった。また、同様の目的で使用する毛髪処理剤として、メチルハイドロジェンポリシロキサンを用いて毛髪表面に皮膜を形成させる方式の２剤式毛髪処理剤も提案されている。
しかしながら、上記特許文献１に記載の２剤式毛髪処理剤は、施術方法が煩雑である上に、染毛のためのブリーチ処理やパーマネントウエーブ処理によって損傷した毛髪に対しては、優れた指通り性と充分な柔軟性を付与することができなかった。 However, the two-component hair treatment agent described in the above-mentioned Patent Document 1 has a complicated treatment method, and is excellent in handling for hair damaged by bleaching treatment or permanent wave treatment for hair dyeing. And sufficient flexibility cannot be imparted.
本発明は、上記のような従来の毛髪処理剤の問題点を解決し、毛髪に優れた指通り性と充分な柔軟性を付与することができる毛髪処理剤を提供することを目的とする。 An object of this invention is to provide the hair treatment agent which solves the problem of the above conventional hair treatment agents, and can provide the excellent fingering property and sufficient softness | flexibility to hair.
本発明者らは、上記課題を解決するため鋭意検討を重ねた結果、難揮発性ジメチルシリコーン、２５℃で液状のエステルおよび揮発性シリコーンを含有させて毛髪処理剤を構成するときは、毛髪に優れた指通り性と充分な柔軟性を付与することができ、それによって、上記課題を解決できることを見出し、本発明を完成するに至った。 As a result of intensive studies to solve the above problems, the present inventors have found that when a hair treatment agent is constituted by containing a hardly volatile dimethyl silicone, a liquid ester at 25 ° C. and a volatile silicone, It has been found that excellent fingering and sufficient flexibility can be imparted, thereby solving the above problems, and the present invention has been completed.
本発明の毛髪処理剤は、毛髪に優れた指通り性と充分な柔軟性を付与することができる。 The hair treatment agent of the present invention can impart excellent fingering property and sufficient flexibility to the hair.
すなわち、本発明の毛髪処理剤では、難揮発性ジメチルシリコーンによって毛髪に指通り性と柔軟性を付与し、２５℃で液状のエステルによって毛髪に柔軟性を付与し、揮発性シリコーンによって配合成分を均一に溶解または分散させているので、それらの相剰性作用によって、毛髪に優れた指通り性と柔軟性を付与することができる。従って、本発明の毛髪処理剤によれば、毛髪のパサつきも抑えることができる。 That is, in the hair treatment agent of the present invention, finger-hardness and flexibility are imparted to the hair by the hardly volatile dimethyl silicone, flexibility is imparted to the hair by the liquid ester at 25 ° C., and the compounding ingredients are added by the volatile silicone. Since they are uniformly dissolved or dispersed, their fingering properties and flexibility can be imparted to the hair by their coherent action. Therefore, according to the hair treatment agent of the present invention, it is also possible to suppress hair loss.
本発明の毛髪処理剤は、スタイリング剤の使用に先立って使用する前処理剤的な毛髪処理剤として開発したものであるが、それのみにとどまらず、それ自身で毛髪に優れた指通り性と充分な柔軟性を付与することができるので、上記のようなスタイリング剤の前処理剤的な用途だけでなく、それ単独でスタイリング剤、リーブオンタイプ（洗い流さない）のトリートメント剤などとして使用したり、応用することができる。 The hair treatment agent of the present invention was developed as a pretreatment agent-like hair treatment agent to be used prior to the use of the styling agent, but it is not limited to that. Sufficient flexibility can be given, so it can be used not only as a pretreatment agent for the styling agent as described above, but also as a styling agent or leave-on type treatment agent. Can be applied.
本発明の毛髪処理剤を構成するにあたって用いる難揮発性ジメチルシリコーンとは、２５℃で液状のジメチルシリコーンであって揮発性シリコーンに比べて揮発性の低いものをいい、そのような難揮発性シリコーンとしては、例えば、メチルポリシロキサン、高重合メチルポリシロキサン、アミノエチルアミノプロピルメチルシロキサン・ジメチルシロキサン共重合体、高重合ジメチルシロキサン・メチル（アミノプロピル）シロキサン共重合体などから選ばれる少なくとも一つを含むことが好ましく、特に高重合メチルポリシロキサン・高重合ジメチルシロキサン・メチル（アミノプロピル）シロキサン共重合体が好ましい。そして、この難揮発性ジメチルシリコーンの毛髪処理剤中の含有量としては、０．０１〜２０質量％が好ましく、特に０．１〜１０質量％が好ましい。この難揮発性ジメチルシリコーンの毛髪処理剤中の含有量が上記範囲よりも少ない場合は、毛髪に優れた指通り性と充分な柔軟性を付与することができず、難揮発性ジメチルシリコーンの毛髪処理剤中の含有量が上記範囲より多い場合は、毛髪にベタつきを生じさせ、さらには毛髪をゴワつかせることになる。 The hardly volatile dimethyl silicone used in constituting the hair treatment agent of the present invention is a dimethyl silicone which is liquid at 25 ° C. and has a lower volatility than volatile silicone, and such a hardly volatile silicone. As, for example, at least one selected from methylpolysiloxane, highly polymerized methylpolysiloxane, aminoethylaminopropylmethylsiloxane / dimethylsiloxane copolymer, highly polymerized dimethylsiloxane / methyl (aminopropyl) siloxane copolymer, etc. In particular, a highly polymerized methylpolysiloxane, a highly polymerized dimethylsiloxane, and a methyl (aminopropyl) siloxane copolymer are preferable. And as content in the hair treatment agent of this hardly volatile dimethyl silicone, 0.01-20 mass% is preferable, and 0.1-10 mass% is especially preferable. If the content of the hardly volatile dimethyl silicone in the hair treatment agent is less than the above range, the hair cannot be imparted with excellent fingering property and sufficient flexibility, and the hardly volatile dimethyl silicone hair. When the content in the treatment agent is larger than the above range, the hair is made sticky and the hair is made stiff.
２５℃で液状のエステルとしては、例えば、安息香酸アルキル（Ｃ12〜15）、リンゴ酸ジイソステアリル、コハク酸ジ２−エチルヘキシル、コハク酸ジエトキシエチル、エイコセン酸カプリリルなどが好ましい。そして、この２５℃で液状のエステルの毛髪処理剤中の含有量としては、０．０１〜２０質量％が好ましく、特に０．１〜１０質量％が好ましい。この２５℃で液状のエステルの毛髪処理剤中の含有量が上記範囲より少ない場合は、毛髪に充分な柔軟性を付与することができず、そのため、毛髪のパサつきを抑えることができず、また、２５℃で液状のエステルの毛髪処理剤中の含有量が上記範囲より多い場合は、毛髪を濡れたような外観にするとともに、毛髪にべたつきを生じることになる。 The ester liquid at 25 ° C., for example, benzoic acid alkyl (C 12 ~ 15), diisostearyl malate, succinate di-2-ethylhexyl, diethoxyethyl succinate, etc. eicosenoic acid caprylyl are preferred. And as content in the hair treatment agent of this ester liquid at 25 degreeC, 0.01-20 mass% is preferable, and 0.1-10 mass% is especially preferable. When the content of the liquid ester in the hair treatment agent at 25 ° C. is less than the above range, it is not possible to impart sufficient flexibility to the hair, and therefore it is not possible to suppress the hairiness of the hair, Moreover, when there is more content in the hair treatment agent of liquid ester at 25 degreeC than the said range, while making hair look wet, stickiness will be produced.
揮発性シリコーンとしては、例えば、環状シリコーンや低粘度ジメチルシリコーンなどが好ましく、具体的には、特にオクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサン、ドデカメチルシクロヘキサシロキサンなどの環状シリコーンやオクタメチルトリシロキサン、デカメチルテトラシロキサン、メチルポリシロキサン（０．６５〜５ｃｓ）などの低粘度ジメチルシリコーンなどが好ましい。そして、この揮発性シリコーンの毛髪処理剤中における含有量としては、７０質量％以上が好ましく、特に８５質量％以上が好ましく、また、９９．９８質量％以下が好ましい。この揮発性シリコーンの毛髪処理剤中の含有量が７０質量％より少ない場合は、毛髪に均一に塗布することができず、また、揮発性シリコーンの毛髪処理剤中の含有量が９９．９８質量％より多い場合は、難揮発性ジメチルシリコーンや２５℃で液状のエステルを必要量含有させることができなくなる。 As the volatile silicone, for example, cyclic silicone and low-viscosity dimethyl silicone are preferable. Specifically, cyclic silicones such as octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, and octamethyltrimethyl are particularly preferable. Low viscosity dimethyl silicone such as siloxane, decamethyltetrasiloxane, methylpolysiloxane (0.65 to 5 cs) and the like are preferable. And as content in this hair treatment agent of this volatile silicone, 70 mass% or more is preferable, 85 mass% or more is especially preferable, and 99.98 mass% or less is preferable. When the content of the volatile silicone in the hair treatment agent is less than 70% by mass, it cannot be uniformly applied to the hair, and the content of the volatile silicone in the hair treatment agent is 99.98% by mass. When it is more than%, it becomes impossible to contain the required amount of the hardly volatile dimethyl silicone and the liquid ester at 25 ° C.
本発明の毛髪処理剤は、上記難揮発性ジメチルシリコーン、２５℃で液状のエステルおよび揮発性シリコーンを混合することによって調製されるが、調製時の作業性や使用時の取り扱いやすさを考慮すると、植物油を添加することが好ましい。 The hair treatment agent of the present invention is prepared by mixing the above-mentioned hardly volatile dimethyl silicone, liquid ester at 25 ° C. and volatile silicone, but considering the workability during preparation and the ease of handling during use. It is preferable to add vegetable oil.
上記植物油は、２５℃で液状であって前記揮発性シリコーンに比べて揮発性が低いものであるが、そのような植物油としては、例えば、シア脂、オリーブ油、メドウフォーム油、マカデミアナッツ油、ユチャ油、アボカド油、植物性スクワラン、サザンカ油、パーシック油、ククイナッツ油、ビャクダン抽出油、キハダ樹皮抽出油、オオムギ抽出油、ブドウ種子油、ゴマ油、サフラワー油、アルモンド油、大豆油、トウモロコシ油、ヒマシ油、ヒマワリ油、ヘーゼルナッツ油、ホホバ油、ラッカセイ油、ローズヒップ油などが好適に用いられる。 The vegetable oil is liquid at 25 ° C. and is less volatile than the volatile silicone. Examples of such vegetable oil include shea fat, olive oil, meadow foam oil, macadamia nut oil, and yucha oil. , Avocado oil, vegetable squalene, sasanqua oil, persic oil, cucumber nut oil, sandalwood extract oil, yellowfin bark extract oil, barley extract oil, grape seed oil, sesame oil, safflower oil, almond oil, soybean oil, corn oil, castor Oil, sunflower oil, hazelnut oil, jojoba oil, peanut oil, rosehip oil and the like are preferably used.
さらに、本発明の非水系毛髪処理剤の調製にあたっては、上記成分以外にも本発明の効果を損なわない範囲で他の成分を適宜添加することができる。そのような添加成分としては、例えば、炭化水素化合物、非イオン性界面活性剤、アニオン性界面活性剤、両性界面活性剤、油類、湿潤剤、防腐剤、キレート剤、香料、着色剤などが挙げられる。 Furthermore, in preparing the non-aqueous hair treatment agent of the present invention, other components can be appropriately added in addition to the above components as long as the effects of the present invention are not impaired. Examples of such additional components include hydrocarbon compounds, nonionic surfactants, anionic surfactants, amphoteric surfactants, oils, wetting agents, preservatives, chelating agents, fragrances, and coloring agents. Can be mentioned.
これらの任意成分に関しては特に限定されることはないが、上記炭化水素系化合物としては、例えば、流動パラフィン、スクワランなどが好適に用いられ、非イオン性界面活性剤としては、例えば、ポリオキシエチレンセチルエーテル、ポリオキシエチレンオレイルエーテル、ポリオキシエチレンヒマシ油などが好適に用いられ、アニオン性界面活性剤としては、例えば、ポリオキシエチレンラウリル硫酸ナトリウム、α−オレフィン酸ナトリウムなどが好適に用いられ、両性界面活性剤としては、例えば、ベタインなどが好適に用いられ、湿潤剤としては、例えば、グリセリン、ポリエチレングリコール、プロピレングリコール、ジプロピレングリコール、１，３−ブチレングリコール、ソルビトール、マルチトール、ピロリドンカルボン酸などが好適に用いられ、防腐剤としては、例えば、パラオキシ安息香酸メチル、パラオキシ安息香酸プロピル、安息香酸ナトリウム、フェノキシエタノールなどが好適に用いられ、キレート剤としては、例えば、エチレンジアミン四酢酸またはその塩、ジエチレントリアミン五酢酸またはその塩、ヒドロキシエチルエチレンジアミン三酢酸またはその塩、ヒドロキシエタンジホスホン酸またはその塩などが好適に用いられる。 Although these optional components are not particularly limited, for example, liquid paraffin, squalane and the like are preferably used as the hydrocarbon compound, and examples of the nonionic surfactant include polyoxyethylene. Cetyl ether, polyoxyethylene oleyl ether, polyoxyethylene castor oil and the like are preferably used, and as the anionic surfactant, for example, polyoxyethylene sodium lauryl sulfate, α-olefin acid sodium and the like are preferably used, As the amphoteric surfactant, for example, betaine is preferably used, and as the wetting agent, for example, glycerin, polyethylene glycol, propylene glycol, dipropylene glycol, 1,3-butylene glycol, sorbitol, maltitol, pyrrolidone carboxylic acid. As the preservative, for example, methyl paraoxybenzoate, propyl paraoxybenzoate, sodium benzoate, phenoxyethanol and the like are preferably used, and as the chelating agent, for example, ethylenediaminetetraacetic acid or a salt thereof, Diethylenetriaminepentaacetic acid or its salt, hydroxyethylethylenediaminetriacetic acid or its salt, hydroxyethanediphosphonic acid or its salt, etc. are preferably used.
本発明の毛髪処理剤は、その剤型に関して特に限定されることなく、例えば、ジェル状、液状など、種々の剤型を採用することができる。また、本発明の毛髪処理剤は、非水系で調製した方が、使用後の乾燥が早く、毛髪に使用した後、すぐにスタイリング剤を使用することができるので、通常、非水系に調製されるが、水が若干混入していてもよい。ただし、その水分量は０．５質量％以下であることが好ましく、特に０．１質量％以下であることが好ましい。 The hair treatment agent of the present invention is not particularly limited with respect to its dosage form, and various dosage forms such as gel and liquid can be adopted. In addition, the hair treatment agent of the present invention is usually prepared in a non-aqueous system because it is faster to dry after use and can be used immediately after being used on hair. However, water may be mixed slightly. However, the water content is preferably 0.5% by mass or less, and particularly preferably 0.1% by mass or less.
つぎに、実施例を挙げて本発明をより具体的に説明する。ただし、本発明はそれらの実施例のみに限定されるものではない。なお、以下の実施例などにおいては、毛髪処理剤全体で１００質量％になるように、各成分の配合量（含有量）を％で示すが、その％はいずれも質量％であり、また、表中ではその％の表示を省略し、配合量を示す数値のみで表示する。 Next, the present invention will be described more specifically with reference to examples. However, this invention is not limited only to those Examples. In the following examples and the like, the blending amount (content) of each component is shown in% so that the hair treatment agent as a whole is 100% by mass, all of which are% by mass, In the table, the display of% is omitted, and only the numerical value indicating the blending amount is displayed.
実施例１〜１０および比較例１〜３
表１〜表２に示す組成で実施例１〜１０の毛髪処理剤を調製し、表３に示す組成で比較例１〜３の毛髪処理剤を調製した。
Examples 1-10 and Comparative Examples 1-3
The hair treatment agents of Examples 1 to 10 were prepared with the compositions shown in Tables 1 and 2, and the hair treatment agents of Comparative Examples 1 to 3 were prepared with the compositions shown in Table 3.
実施例１〜１０の毛髪処理剤の調製にあたって、難揮発性ジメチルシリコーンとしては高重合メチルポリシロキサンを用い、２５℃で液状のエステルとしては安息香酸アルキル（Ｃ12〜15）〔この安息香酸アルキル（Ｃ12〜15）とは、炭素数１２〜１５のアルキル基が混在したアルキル基を安息香酸にエステル化させた安息香酸のアルキルエステルである〕を用い、揮発性シリコーンとしてはデカメチルシクロペンタシロキサンを用い、植物油としてはシア脂を用いた。そして、表１〜表３中のシア脂の１００という配合量は、表中の「シア脂にて」という記載からも明らかなように、シア脂を配合することによって毛髪処理剤全体を１００質量％にするという意味の配合量である。 In the preparation of the hair treatment agents of Examples 1 to 10, highly polymerized methylpolysiloxane was used as the hardly volatile dimethyl silicone, and alkyl benzoate (C 12 to 15 ) [this alkyl benzoate as the liquid ester at 25 ° C. (C 12-15) is an alkyl ester of benzoic acid obtained by esterifying an alkyl group in which an alkyl group having 12 to 15 carbon atoms is mixed with benzoic acid], and decamethylcyclopenta is used as the volatile silicone. Siloxane was used, and shea fat was used as vegetable oil. And the compounding quantity called 100 of the shea fat in Table 1-Table 3 is 100 mass of the whole hair treatment agent by mix | blending shea fat so that it may become clear also from the description of "with shea fat" in a table | surface. It is a blending amount meaning to be%.
得られた実施例１〜１０および比較例１〜３の毛髪処理剤について、毛髪への指通り性および柔軟性の付与作用の評価を行った。その結果を表４に示す。なお、それらの評価方法は、次の通りである。 The hair treatment agents of Examples 1 to 10 and Comparative Examples 1 to 3 thus obtained were evaluated for imparting fingering property and flexibility to the hair. The results are shown in Table 4. In addition, those evaluation methods are as follows.
まず、毛髪への指通り性および柔軟性の評価試験にあたって用いる毛髪としては、以下に示すようにブリーチ処理とパーマネントウエーブ処理を施すことによって損傷を受けさせた毛髪を用いた。 First, as the hair used in the evaluation test of the finger penetration and flexibility to the hair, hair damaged by performing bleaching treatment and permanent wave treatment as shown below was used.
毛髪へのブリーチ処理およびパーマネントウエーブ処理：
毛髪に損傷を受けさせるためのブリーチ処理とパーマネントウエーブ処理は、以下に示すブリーチ剤とパーマネントウエーブ剤を用いて行った。
Hair bleaching and permanent wave treatment:
The bleaching treatment and permanent wave treatment for damaging the hair were performed using the following bleaching agent and permanent wave treatment.
ブリーチ処理のためのブリーチ剤は、３５％過酸化水素水１７．１４％を含み精製水で全量を１００％にしたものと、２５％アンモニア水１．００％を含み精製水で全量を１００％にしたものとを等量混合して調製した。 The bleaching agent for bleaching treatment includes 35% hydrogen peroxide solution 17.14% and 100% with purified water, and 25% ammonia water 1.00% and 100% with purified water. It was prepared by mixing an equal amount of the above.
また、パーマネントウエーブ処理のための第１剤としては、ＤＬ−システイン塩酸塩５．５％とアセチルシステイン０．５％と５０％チオグリコール酸アンモニウム液１．８％と８０％モノエタノールアミン液４．７％を含み、２５％アンモニア水でｐＨ９．３に調整し、精製水で全量を１００％にしたものを用意し、第２剤としては、臭素酸ナトリウム６．５％とクエン酸０．１％とリン酸０．０５％とリン酸水素一水素ナトリウム０．５％を含み、精製水で全量を１００％にしたものを用意した。 As the first agent for permanent wave treatment, DL-cysteine hydrochloride 5.5%, acetylcysteine 0.5%, 50% ammonium thioglycolate solution 1.8%, and 80% monoethanolamine solution 4 , Containing 7%, adjusted to pH 9.3 with 25% aqueous ammonia and made up to 100% with purified water. The second agent is 6.5% sodium bromate and 0.5% citric acid. A solution containing 1%, 0.05% phosphoric acid and 0.5% sodium hydrogen hydrogenphosphate and having the total amount made up to 100% with purified water was prepared.
そして、ブリーチ処理は、上記ブリーチ処理液１００ｍｌ中に健康毛から採取した長さ２０ｃｍ、質量２ｇの毛束を浸漬し、３５℃の高温振とう器中にて３０分間振とうすることによって行い、ついで、精製水で水洗した後、上記毛束を直径１０ｍｍのロッドに巻き付け、それら全体を前記パーマネントウエーブ用第１剤１００ｍｌ中に浸漬し、３５℃の恒温振とう器中にて３０分間振とうし、精製水で水洗した後、それら全体を前記パーマネントウエーブ用第２剤１００ｍｌに浸漬し、３５℃で３０分間振とうし、精製水で水洗した後、自然乾燥して、パーマネントウエーブ処理を行い、このブリーチ処理とそれに続くパーマネントウエーブ処理をそれぞれ３回ずつ繰り返して毛髪に損傷を受けさせた。 And the bleaching treatment is performed by immersing a hair bundle of 20 cm in length and 2 g in mass collected from healthy hair in 100 ml of the bleaching treatment solution and shaking for 30 minutes in a high-temperature shaker at 35 ° C. Next, after rinsing with purified water, the hair bundle is wound around a rod having a diameter of 10 mm, the whole is immersed in 100 ml of the first permanent wave agent, and shaken in a constant temperature shaker at 35 ° C. for 30 minutes. Then, after rinsing with purified water, all of them are immersed in 100 ml of the second permanent wave agent, shaken at 35 ° C. for 30 minutes, rinsed with purified water, air dried, and subjected to permanent wave treatment. The bleaching treatment and the subsequent permanent wave treatment were repeated three times each to damage the hair.
指通り性および柔軟性の評価方法：
前記のように実施例１〜１０および比較例１〜３の毛髪処理剤を上記のブリーチ処理とそれに続くパーマネントウエーブ処理により損傷を受けさせた毛髪にそれぞれ０．５ｇずつ塗布し、２０名のパネラーに指通り性および柔軟性を手触りにより評価させ、その評価結果をそれぞれ次の評価基準により点数化し、２０名のパネラーの評価結果に基づく点数を合計し、下記の総合評価基準により表４に記号化して示す。
How to assess fingering and flexibility:
As described above, each of the hair treatment agents of Examples 1 to 10 and Comparative Examples 1 to 3 was applied to each of the hairs damaged by the bleaching treatment and the subsequent permanent wave treatment in an amount of 0.5 g. The evaluation results are scored according to the following evaluation criteria, and the scores based on the evaluation results of the 20 panelists are totaled. Shown in the form.
評価基準：
５点：非常に良い
４点：良い
３点：普通
２点：悪い
１点：非常に悪い
Evaluation criteria:
5 points: very good 4 points: good 3 points: normal 2 points: bad 1 point: very bad
総合評価：
◎：点数の合計が８０点以上
○：点数の合計が６０点以上８０点未満
△：点数の合計が４０点以上６０点未満
×：点数の合計が２０点以上４０点未満
Comprehensive evaluation:
◎: Total score is 80 or more ○: Total score is 60 or more and less than 80 △: Total score is 40 or more and less than 60 ×: Total score is 20 or more and less than 40
表４に示すように、実施例１〜１０の毛髪処理剤は、比較例１〜３の毛髪処理剤に比べて、指通り性および柔軟性のいずれに関しても、評価値が高く、毛髪に優れた指通り性と充分な柔軟性を付与することができ、毛髪のパサつきを抑えることができた。 As shown in Table 4, the hair treatment agents of Examples 1 to 10 have high evaluation values for both fingering property and flexibility as compared with the hair treatment agents of Comparative Examples 1 to 3, and are excellent in hair. It was possible to impart smoothness to fingers and sufficient flexibility, and to suppress hair pattering.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004015381A JP4333988B2 (en) | 2004-01-23 | 2004-01-23 | Hair treatment agent |
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| JP4333988B2 JP4333988B2 (en) | 2009-09-16 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2017109954A (en) * | 2015-12-17 | 2017-06-22 | 株式会社ミルボン | Nonaqueous hair cosmetic and hair treatment method |
| JP2017125071A (en) * | 2017-04-24 | 2017-07-20 | 株式会社ミルボン | Non-aqueous hair cosmetic and method for treating hair |
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2004
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2017109954A (en) * | 2015-12-17 | 2017-06-22 | 株式会社ミルボン | Nonaqueous hair cosmetic and hair treatment method |
| JP2017125071A (en) * | 2017-04-24 | 2017-07-20 | 株式会社ミルボン | Non-aqueous hair cosmetic and method for treating hair |
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| JP4333988B2 (en) | 2009-09-16 |
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