JP2005198531A - Tea beverage - Google Patents

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JP2005198531A
JP2005198531A JP2004006696A JP2004006696A JP2005198531A JP 2005198531 A JP2005198531 A JP 2005198531A JP 2004006696 A JP2004006696 A JP 2004006696A JP 2004006696 A JP2004006696 A JP 2004006696A JP 2005198531 A JP2005198531 A JP 2005198531A
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tea
tea extract
transparent container
extract
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JP4355222B2 (en
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Hitoshi Niino
仁 新納
Hitoshi Kinugasa
仁 衣笠
Kazunori Okanoya
和則 岡野谷
Shuhei Kuribayashi
修平 栗林
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Ito En Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a tea beverage causing no generation of precipitation and deterioration in color and flavor even after long preservation or long warming. <P>SOLUTION: The tea beverage charged in a transparent container comprises the following: (1) the transparent container; (2) tea extract liquid hermetically charged in the transparent container and adjusted pH to 3.0-5.0; and (3) a pH adjustment agent adjusting the tea extract liquid to pH 5.5-7.0 when dissolved. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

本発明は、透明容器詰茶飲料に関する。さらに詳しくは、長期保存または長期加温しても茶抽出液に特有のオリの発生が無く、また、茶抽出液の色劣化が少なく、飲用時において該茶抽出液のpHを調整することで、茶抽出液本来の味、香りを再現することのできる透明容器詰茶飲料に関する。   The present invention relates to a transparent containerized tea beverage. More specifically, there is no occurrence of oliage peculiar to the tea extract even after long-term storage or long-term heating, and there is little color deterioration of the tea extract, and by adjusting the pH of the tea extract at the time of drinking, The present invention relates to a transparent container-packed tea beverage capable of reproducing the original taste and aroma of tea extract.

最近、ビンやプラスチック等の透明容器に密封充填してなる茶飲料が次々に製品化されている。茶飲料、中でも緑茶飲料は保存中に浮遊物状、フロック状あるいは白濁状の懸濁・沈殿物であるオリを発生することがあり、室温での長期保存は約9ヶ月が目安となっていた。また、加温販売の際には、約2週間程度の長期加温により茶抽出液の色が赤く劣化し、香味の劣化も著しかった。このため、店頭での加温販売は、加温時間や加温温度の制限、例えば、一度加温した商品の再加温は避けるなどの制限や加温する温度の上限などが定められていた。このようなオリの発生や色の劣化は、特に透明容器詰茶飲料の場合には視覚的商品価値を失うことにもなっていた。   Recently, tea beverages that are sealed and filled in transparent containers such as bottles and plastics have been commercialized one after another. Tea drinks, especially green tea drinks, may generate a floating, flock-like, or cloudy suspension / precipitate during storage, and the long-term storage at room temperature is approximately 9 months. . In addition, at the time of warming sale, the color of the tea extract deteriorated red due to long-term heating for about 2 weeks, and the flavor deterioration was also remarkable. For this reason, in the warming sales at stores, there are restrictions on the heating time and temperature, for example, restrictions such as avoiding reheating of products that have been heated once, and upper limits on the temperature to be heated . Such occurrence of orientation and deterioration of color have also caused a loss of visual commercial value, particularly in the case of transparent container-packed tea beverages.

本発明の目的は、長期保存または長期加温しても茶抽出液に特有のオリの発生や色、香味の劣化が見られない茶飲料を提供することにある。   An object of the present invention is to provide a tea beverage in which the occurrence of oli, the color and flavor of the tea extract are not observed even after long-term storage or long-term heating.

本発明のさらに他の目的および利点は、以下の説明から明らかになろう。   Still other objects and advantages of the present invention will become apparent from the following description.

本発明によれば、本発明の上記目的および利点は、(1)透明容器、
(2)上記透明容器に密閉充填され且つpH3.0〜5.0の範囲に調整された茶抽出液 および
(3)上記茶抽出液に溶解するための、そして溶解したとき上記茶抽出液のpHを5.5〜7.0に調整するためのpH調整剤
からなることを特徴とする、透明容器充填の茶飲料によって達成される。
According to the present invention, the above objects and advantages of the present invention are: (1) a transparent container,
(2) a tea extract hermetically filled in the transparent container and adjusted to a pH of 3.0 to 5.0, and (3) for dissolving in the tea extract and when dissolved, the tea extract It is achieved by a transparent container-filled tea beverage characterized by comprising a pH adjusting agent for adjusting the pH to 5.5 to 7.0.

本発明によれば、長期保存あるいは長期加温しても茶抽出液に特有のオリの発生や色、香味の劣化のない商品価値の高い茶飲料を提供することができる。   ADVANTAGE OF THE INVENTION According to this invention, the tea drink with a high commercial value without generation | occurrence | production of an orientation peculiar to a tea extract, a color, and flavor deterioration even if it preserve | saves for a long term or it heats for a long term can be provided.

発明の実施するための最良の形態BEST MODE FOR CARRYING OUT THE INVENTION

茶抽出液をpH3.0〜5.0、好ましくはpH3.5〜4.5の酸性下に調整した後、透明容器に密封充填すると、長期保存または長期加温しても特有のオリの発生が無く、また、色劣化が少ない茶抽出液とすることができる。しかし、この茶抽出液をそのまま飲用すると、茶抽出液本来の味、香りが不足するため、飲用時において茶抽出液の本来のpH域である5.5〜7.0、好ましくはpH6.0〜6.5の弱酸性下に再調整して、味、香りを再現する。   After the tea extract is adjusted to an acidity of pH 3.0 to 5.0, preferably pH 3.5 to 4.5 and then sealed and filled in a transparent container, the occurrence of peculiar olices even after long-term storage or long-term heating And a tea extract with little color deterioration. However, when this tea extract is drunk as it is, the original taste and aroma of the tea extract are insufficient, so that the original pH range of the tea extract at the time of drinking is 5.5 to 7.0, preferably pH 6.0. Re-adjust under a weak acidity of ~ 6.5 to reproduce taste and aroma.

本発明の茶飲料は、pH3.0〜5.0の範囲に調整された茶抽出液を透明容器に密閉充填し、この茶飲料の飲用時において茶抽出液のpHを5.5〜7.0に調整するためのpH調整剤を組合せたものからなる。   In the tea beverage of the present invention, a tea extract adjusted to a pH of 3.0 to 5.0 is hermetically filled in a transparent container, and the pH of the tea extract is 5.5 to 7. It consists of a combination of pH adjusting agents for adjusting to zero.

透明容器としては、例えばポリエチレンテレフタレート製ボトル、ガラスビン等を挙げることができる。   Examples of the transparent container include polyethylene terephthalate bottles and glass bottles.

抽出に使用する原料茶葉は、茶樹(学名:Camellia sinensis)から摘採した葉や茎であればその産地、栽培方法、摘採時期などを限定せず、どのような茶種も対象とすることができる。そして、これらの茶葉等を蒸すか或いは炒るかなどの手段で酵素活性を停止させた不発酵茶であれば、煎茶、釜炒り茶、かぶせ茶、玉露、てん茶、抹茶、番茶、焙じ茶、蒸製玉緑茶、釜炒製玉緑茶などを使用することができる。また、半発酵茶である烏龍茶、発酵茶である紅茶や弱発酵茶であるジャスミン茶等のいずれの種類も用いることができる。なお、これらの二種類以上を組合わせてもよい。また、麦茶、そば茶など茶樹(学名:Camellia sinensis)から摘採した葉や茎以外でも弱酸性の茶飲料として飲用されるものも対象とすることができる。 The raw tea leaves used for extraction are not limited to their origin, cultivation method, harvesting time, etc. as long as they are leaves and stems plucked from tea trees (scientific name: Camellia sinensis ), and any tea type can be targeted. . And if it is a non-fermented tea whose enzyme activity has been stopped by means such as steaming or roasting these tea leaves, etc., sencha, kettle roasted tea, kabusecha, gyokuro, tencha, matcha, bancha, roasted tea, steamed Tama green tea, kettle roasted ball green tea, etc. can be used. Moreover, any kind, such as oolong tea which is semi-fermented tea, black tea which is fermented tea, and jasmine tea which is weakly fermented tea can be used. Two or more of these may be combined. Moreover, what is drunk as a weakly acidic tea drink other than the leaf or stem plucked from tea trees (scientific name: Camellia sinensis ), such as barley tea and buckwheat tea, can also be targeted.

これらの原料茶葉を抽出して茶抽出液を製造する方法は、それ自体公知の方法を採用することができる。   As a method for producing a tea extract by extracting these raw tea leaves, a method known per se can be adopted.

茶抽出液のpHを3.0〜5.0に調整するために、茶抽出液に酸性物質を添加する。酸性物質としては、食品添加物として認められている物質、例えばアスコルビン酸またはその塩が好ましい。   In order to adjust the pH of the tea extract to 3.0 to 5.0, an acidic substance is added to the tea extract. As the acidic substance, a substance recognized as a food additive, for example, ascorbic acid or a salt thereof is preferable.

また、飲用時には、上記茶抽出液に溶解して茶抽出液のpHを5.5〜7.0に調整するためにアルカリ性物質であるpH調整剤を添加する。その例としては、同様に食品添加物として認められている物質、例えば炭酸水素ナトリウム等が好ましい。かかるアルカリ性のpH調整剤は、透明容器のキャップ内に予め封入しておき、開封時に直接透明容器内の茶抽出液に添加できるようにしたり、あるいはチューブや袋に封入して付属品として添付し、開封後茶抽出液に添加できるようにすることができる。また、pH調整剤は、例えば粉状、粒子状、タブレット状、液状などどのような形態でもよい。pH調整剤の添加量は、適宜変更可能であるが、その例として、茶抽出液を酸性のpH3.0〜5.0に調整するためアスコルビン酸を使用した場合には、炭酸水素ナトリウムをアスコルビン酸添加量の70〜85%、好ましくは70〜80%添加することで茶抽出液のpHを弱酸性の5.5〜7.0に再調整することができる。   Moreover, at the time of drinking, in order to melt | dissolve in the said tea extract and adjust the pH of a tea extract to 5.5-7.0, the pH adjuster which is an alkaline substance is added. For example, a substance that is also recognized as a food additive, such as sodium bicarbonate, is preferable. Such an alkaline pH adjuster is enclosed in a cap of a transparent container in advance so that it can be added directly to the tea extract in the transparent container at the time of opening, or enclosed in a tube or bag and attached as an accessory. It can be added to the tea extract after opening. In addition, the pH adjuster may be in any form such as powder, particle, tablet, or liquid. The addition amount of the pH adjuster can be appropriately changed. For example, when ascorbic acid is used to adjust the tea extract to an acidic pH of 3.0 to 5.0, sodium bicarbonate is added to ascorbine. By adding 70 to 85%, preferably 70 to 80% of the amount of acid added, the pH of the tea extract can be readjusted to 5.5 to 7.0, which is weakly acidic.

また、本発明の茶飲料の他形態として、透明容器に炭酸水素ナトリウムなどのアルカリ剤を添加した水溶液に、酸性茶粉末を飲用時に添加したり、透明容器に充填した水に、酸性茶粉末とアルカリ剤を添加して飲用することも考えられる。なお、茶粉末を酸性にする方法としては、茶粉末に、酸性化剤を添加することで簡易に作成することができるが、その際にもpHは3.0〜5.0、好ましくはpH.3.5〜4.5の酸性下に調整することが必要である。また、酸性茶粉末は、粉状、粒子状、タブレット状などどのような形態でもよい。アルカリ剤を添加した水溶液であるアルカリ水は、酸性茶粉末を添加した際に、pHが5.5〜7.0に再調製できるようにすることが好ましい。なお、酸性茶粉末のアルカリ水への添加量はその際、適宜変更可能である。   As another form of the tea beverage of the present invention, an acidic tea powder is added to an aqueous solution in which an alkaline agent such as sodium hydrogen carbonate is added to a transparent container at the time of drinking, or an acidic tea powder is added to water filled in a transparent container. It is also conceivable to add an alkaline agent for drinking. In addition, as a method of acidifying the tea powder, it can be easily prepared by adding an acidifying agent to the tea powder, but in that case, the pH is 3.0 to 5.0, preferably pH. . It is necessary to adjust the acidity of 3.5 to 4.5. Further, the acidic tea powder may be in any form such as powder, particles, and tablets. It is preferable that the alkaline water, which is an aqueous solution to which an alkaline agent is added, can be re-adjusted to a pH of 5.5 to 7.0 when acidic tea powder is added. In addition, the addition amount to the alkaline water of acidic tea powder can be changed suitably in that case.

また、茶抽出液を酸性下に調整した後、チルド飲料として流通させ、飲用時においてアルカリ剤を各自添加することも、オリの発生や水色、香味の劣化をさらに改善する上で有効である。   In addition, it is also effective for further improving the occurrence of orientation, light blue, and flavor deterioration by adjusting the tea extract to acidity and then distributing it as a chilled beverage and adding an alkaline agent at the time of drinking.

以下、実施例により本発明を詳述する。   Hereinafter, the present invention will be described in detail by way of examples.

試験1
90℃、1,200mlのイオン交換水(pH5.9)に緑茶(荒茶)30gを添加して、1分毎に攪拌しながら5分間抽出した。その後、メッシュ(150メッシュ)にて粗濾過し、室温まで冷却してからネル布(50μm)により濾過した。得られた抽出液にアスコルビン酸0.72gを添加し、7,000rpmで10分間遠心分離後、その上清を微細濾過(アドバンテック社製1μmMF膜)し、さらにその濾液にアスコルビン酸1.08gを加え最終液量4,000mlの酸性下に調整した茶抽出液を得た。前記茶抽出液のうち2,000mlには、さらに炭酸水素ナトリウムを添加して、pHを6.0に再調整した抽出液を弱酸性緑茶とし、残りの前記茶抽出液は、そのままを酸性緑茶として、それぞれ97℃まで加熱して缶に充填した。その後、121℃、7分の条件でレトルト殺菌を行い、十分に冷却してからクリーンベンチ内で耐熱性ペットボトルに充填し直した。これらの弱酸性緑茶と酸性緑茶のそれぞれを、60℃で長期加温して茶抽出液の経時変化を、オリ生成、pH変化および官能試験により観察した。結果を下記表1(オリ生成)、表2(pH変化)および表3(官能評価)に示した。
Test 1
30 g of green tea (raw tea) was added to 1,200 ml of ion-exchanged water (pH 5.9) at 90 ° C. and extracted for 5 minutes while stirring every minute. Thereafter, the mixture was roughly filtered with a mesh (150 mesh), cooled to room temperature, and then filtered with a flannel cloth (50 μm). 0.72 g of ascorbic acid was added to the obtained extract, and after centrifugation at 7,000 rpm for 10 minutes, the supernatant was finely filtered (1 μm F membrane manufactured by Advantech), and 1.08 g of ascorbic acid was further added to the filtrate. In addition, a tea extract adjusted under acidic conditions with a final liquid volume of 4,000 ml was obtained. To 2,000 ml of the tea extract, sodium bicarbonate is further added to adjust the pH to 6.0 to make weakly acidic green tea, and the remaining tea extract is left as acidic green tea. Each was heated to 97 ° C. and filled into cans. Thereafter, retort sterilization was performed at 121 ° C. for 7 minutes, and after sufficiently cooling, the heat-resistant PET bottle was refilled in a clean bench. Each of these weakly acidic green tea and acidic green tea was warmed at 60 ° C. for a long period of time, and the change with time of the tea extract was observed by orientation generation, pH change and sensory test. The results are shown in Table 1 (origin formation), Table 2 (pH change) and Table 3 (sensory evaluation).

オリ生成は3段階評価を行った。−は生成せず、+は僅かに生成が認められ、++は生成がはっきり認められたことを示した。   Oli production was evaluated in three stages. -Was not formed, + was slightly observed, and ++ was clearly observed.

pH変化は表2中にpH値をそのまま示した。官能試験は5人のパネラーにより、各人5点評価を行い、その平均値で示した。少数点以下は切り捨てた。   The pH change is shown in Table 2 as it is. In the sensory test, each panel was evaluated by five panelists using five panelists, and the average value was shown. Rounded down to the nearest whole number.

Figure 2005198531
Figure 2005198531

Figure 2005198531
Figure 2005198531

Figure 2005198531
Figure 2005198531

また、茶抽出液の色の変化を図1(L値)、図2(a値)および図3(b値)に示した。さらに、茶抽出液中の(−)エピガロカテキン(EGC)、(−)ガロカテキンガレート(GCG)、(−)エピガロカテキンガレート(EGCG)、(−)ガロカテキン(GC)、(−)カテキン(C)、(−)エピカテキン(EC)、(−)エピカテキンガレート(ECG)、(−)カテキンガレート(CG)、EGCGメチル化体(EGCG3''Me)およびストリクチニン(strictinin)のそれぞれの含量変化を図4(EGC)、図5(GCG)、図6(EGCG)、図7(GC)、図8(C)、図9(EC)、図10(ECG)、図11(CG)、図12(EGCG3''Me)および図13(ストリクチニン)に示した。   The change in the color of the tea extract is shown in FIG. 1 (L value), FIG. 2 (a value), and FIG. 3 (b value). Further, (−) epigallocatechin (EGC), (−) gallocatechin gallate (GCG), (−) epigallocatechin gallate (EGCG), (−) gallocatechin (GC), (−) catechin in the tea extract (C), (−) epicatechin (EC), (−) epicatechin gallate (ECG), (−) catechin gallate (CG), EGCG methylated form (EGCG3 ″ Me), and strictinin 4 (EGC), FIG. 5 (GCG), FIG. 6 (EGCG), FIG. 7 (GC), FIG. 8 (C), FIG. 9 (EC), FIG. 10 (ECG), and FIG. 11 (CG). FIG. 12 (EGCG3 ″ Me) and FIG. 13 (strectinin).

試験2
試験1で製造した酸性緑茶を、飲用時において炭酸水素ナトリウムで弱酸性下(pH6.0)に再調整してから飲用し、味と香りを官能試験により評価した(評価基準は試験1に同じ)。結果を表4に示した。
Test 2
The acid green tea produced in Test 1 was readjusted with sodium hydrogen carbonate (pH 6.0) at the time of drinking before drinking, and taste and aroma were evaluated by a sensory test (the evaluation criteria are the same as in Test 1). ). The results are shown in Table 4.

Figure 2005198531
Figure 2005198531

実施例における茶抽出液のL値の経時変化Change with time of L value of tea extract in Examples 実施例における茶抽出液のa値の経時変化Change with time of a value of tea extract in Examples 実施例における茶抽出液のb値の経時変化Change with time of b value of tea extract in Examples 実施例における茶抽出液のEGC含量の経時変化Change with time of EGC content of tea extract in Examples 実施例における茶抽出液のGCG含量の経時変化Change with time of GCG content of tea extract in Examples 実施例における茶抽出液のEGCG含量の経時変化Change with time of EGCG content of tea extract in Examples 実施例における茶抽出液のGC含量の経時変化Time course of GC content of tea extract in Examples 実施例における茶抽出液のC含量の経時変化Changes in C content of tea extract in the examples 実施例における茶抽出液のEC含量の経時変化Changes in EC content of tea extract in the examples over time 実施例における茶抽出液のECG含量の経時変化Change with time of ECG content of tea extract in Examples 実施例における茶抽出液のCG含量の経時変化Change with time of CG content of tea extract in Examples 実施例における茶抽出液のEGCG3''Me含量の経時変化Change with time of EGCG3 ″ Me content of tea extract in Examples 実施例における茶抽出液のストリクチニン含量の経時変化Changes in strictinin content of tea extract in the examples

Claims (3)

(1)透明容器、
(2)上記透明容器に密閉充填され且つpH3.0〜5.0の範囲に調整された茶抽出液 および
(3)上記茶抽出液に溶解するための、そして溶解したとき上記茶抽出液のpHを5.5〜7.0に調整するためのpH調整剤
からなることを特徴とする、透明容器充填の茶飲料。
(1) Transparent container,
(2) a tea extract hermetically filled in the transparent container and adjusted to a pH of 3.0 to 5.0, and (3) for dissolving in the tea extract and when dissolved, the tea extract A tea beverage filled in a transparent container, comprising a pH adjuster for adjusting the pH to 5.5 to 7.0.
透明容器に密閉充填された茶抽出液(2)のpHが、アスコルビン酸またはその塩により調整されている請求項1に記載の茶飲料。 The tea beverage according to claim 1, wherein the pH of the tea extract (2) hermetically filled in the transparent container is adjusted with ascorbic acid or a salt thereof. pH調整剤(3)が炭酸水素ナトリウムである請求項1に記載の茶飲料。

The tea beverage according to claim 1, wherein the pH adjuster (3) is sodium hydrogen carbonate.

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009195168A (en) * 2008-02-21 2009-09-03 Yakult Honsha Co Ltd Buckwheat tea drink, method for producing the same, and method for preventing suspension/precipitation formation of tea drink
JP2018508217A (en) * 2015-03-03 2018-03-29 ウッドール,ガイ Beverage

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009195168A (en) * 2008-02-21 2009-09-03 Yakult Honsha Co Ltd Buckwheat tea drink, method for producing the same, and method for preventing suspension/precipitation formation of tea drink
JP2018508217A (en) * 2015-03-03 2018-03-29 ウッドール,ガイ Beverage

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