JP2005154918A - Nonwoven fabric and method for producing the same - Google Patents

Nonwoven fabric and method for producing the same Download PDF

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JP2005154918A
JP2005154918A JP2003392355A JP2003392355A JP2005154918A JP 2005154918 A JP2005154918 A JP 2005154918A JP 2003392355 A JP2003392355 A JP 2003392355A JP 2003392355 A JP2003392355 A JP 2003392355A JP 2005154918 A JP2005154918 A JP 2005154918A
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nonwoven fabric
needle
needle punching
deep
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JP2005154918A5 (en
JP4406723B2 (en
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Koichi Matsubara
弘一 松原
Toshiaki Harada
敏明 原田
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Gifu Prefecture
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a nonwoven fabric whose interfiber interlacements in a constant direction and in a direction different from the constant direction can be increased to exhibit a good strength and a good elongation and which is suitable for three-dimensional forming treatments, and to provide a method for producing a nonwoven fabric, by which such the nonwoven fabric can simply be obtained. <P>SOLUTION: The nonwoven fabric suitably used for three-dimensional forming treatments is obtained by applying a needle punching treatment to a nonwoven fabric material 16 with a needle punching treatment apparatus 11 in a constant direction and then applying a needle-punching treatment in a direction different from the constant direction. It is preferable on a point capable of improving the strength and the elongation all around that the different direction is a direction orthogonal to the constant direction. The nonwoven fabric is useful for a deep drawing treatment among the three-dimensional forming treatments. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

本発明は、ニードルパンチ加工を複数方向に施して得られ、深絞り成形加工等の立体成形加工に好適に用いられる不織布及びその製造方法に関するものである。更に詳しくは、長手方向にニードルパンチ加工を施した不織布素材を長手方向と直交する方向に切断し、切断された不織布素材を90°回転させ、前記長手方向と直交方向にニードルパンチ加工を施して得られる不織布及びその製造方法に関するものである。   The present invention relates to a nonwoven fabric obtained by performing needle punching in a plurality of directions, and preferably used for three-dimensional molding such as deep drawing, and a method for producing the same. More specifically, the nonwoven fabric material that has been subjected to needle punching in the longitudinal direction is cut in a direction perpendicular to the longitudinal direction, the cut nonwoven fabric material is rotated by 90 °, and needle punching is performed in the direction orthogonal to the longitudinal direction. The present invention relates to a nonwoven fabric obtained and a method for producing the same.

不織布の高付加価値品の一つとして、不織布素材を使った立体成形加工が盛んに行われている。通常、短繊維を用いニードルパンチを施した不織布は塑性加工が困難であるため、原材料、不織布の形成方法、立体成形加工法等に様々な工夫を施すことによって立体成形加工品の作製が行われている。   As one of high-value-added non-woven products, three-dimensional molding using non-woven materials is actively performed. Usually, non-woven fabrics made of staple fibers and needle punched are difficult to be plastically processed, and therefore, three-dimensional molded processed products are produced by applying various innovations to raw materials, nonwoven fabric forming methods, three-dimensional molding processing methods, etc. ing.

例えば、第1の従来技術では、二基のカード装置を用いて二層のマットを積層状態で供給した後ニードルパンチ加工部とニードルパンチ加工の省略部を作製し、立体成形加工を行ったとき、ニードルパンチ加工の省略部が伸び代の役目を果たして形状保持性を高めている(特許文献1を参照)。第2の従来技術では、熱可塑性樹脂からなる繊維より不織布を得、それを塑性変形させて、一定方向に多数の襞を有する伸縮性不織布を作製している(特許文献2を参照)。更に、第3の従来技術では、捲縮性繊維を用いたウェブにニードルパンチ加工を施し、加熱処理することによって伸縮性不織布を得ている(特許文献3を参照)。
特開2000−6705号公報(第2頁、第3頁及び図3) 特開平9−324352号公報(第2頁及び第3頁) 特開平3−69647号公報(第1頁及び第3頁)
For example, in the first prior art, when two layers of mats are supplied in a stacked state using two card devices, a needle punched portion and a needle punched portion are omitted, and three-dimensional forming is performed. In addition, the omission portion of the needle punching serves as a stretch allowance to enhance the shape retention (see Patent Document 1). In the second prior art, a non-woven fabric is obtained from fibers made of a thermoplastic resin, which is plastically deformed to produce a stretchable non-woven fabric having a number of wrinkles in a certain direction (see Patent Document 2). Furthermore, in the third prior art, a stretchable nonwoven fabric is obtained by subjecting a web using crimpable fibers to needle punching and heat treatment (see Patent Document 3).
Japanese Unexamined Patent Publication No. 2000-6705 (Page 2, Page 3, and FIG. 3) JP-A-9-324352 (Pages 2 and 3) Japanese Patent Laid-Open No. 3-69647 (first and third pages)

ところが、第1の従来技術におけるマットはニードルパンチ加工の方向性が一方向のみであるため、絞り成形加工等の立体成形を行う場合に伸縮性が偏り、均一な強度も得られず、特に深絞り成形には不適当である。係る不織布は、繊維の配向性、ニードルパンチの方向性が一方向であり、その方向に繊維が流れて方向性ができるため、その方向とは異なる方向の強度が弱くなる。そして、この不織布を用いて深絞り成形加工を行うと、不織布は縦横均一に引き伸ばされるため、拘束が弱い横方向で不織布が破断する現象が起きる場合がある。   However, since the mat in the first prior art has only one direction of needle punching, the stretchability is biased when three-dimensional forming such as drawing forming is performed, and uniform strength is not obtained. It is not suitable for drawing. In such a nonwoven fabric, the orientation of the fibers and the direction of the needle punch are in one direction, and the fibers flow in that direction, thereby forming the direction, so that the strength in a direction different from that direction becomes weak. When a deep drawing process is performed using this nonwoven fabric, the nonwoven fabric is stretched uniformly in the vertical and horizontal directions, and the nonwoven fabric may break in the lateral direction where the constraint is weak.

第2の従来技術によって得られる不織布を用いて立体成形品を得ることが考えられるが、襞加工の方向が一方向であるため、上記と同様に深絞り成形加工等の立体成形には不適当である。また、低目付の不織布には対応することができるが、特に目付量が100g/m2を超える場合には、襞をつけることが困難となり、伸縮性を得ることも難しくなって襞加工にも制限が加えられる。 Although it is conceivable to obtain a three-dimensional molded article using the nonwoven fabric obtained by the second prior art, it is unsuitable for three-dimensional molding such as deep drawing molding as described above because the direction of wrinkling is one direction. It is. It can also be applied to low-weight nonwoven fabrics, but it is difficult to get wrinkles, especially when the weight per unit area exceeds 100 g / m 2, and it is difficult to obtain stretchability, which makes it difficult for wrinkle processing. Restrictions are added.

第3の従来技術に開示されている伸縮性不織布に成形加工を行い、立体成形品を得るということも考えられる。しかし、捲縮性繊維を用いた不織布に立体成形加工を行うと、捲縮を発現させたときに繊維の伸縮むらが目立ちやすくなり、不織布の地合が悪くなるため、深絞り成形品等の立体成形品を得ることが困難であるという問題がある。   It is also conceivable that the stretchable nonwoven fabric disclosed in the third prior art is molded to obtain a three-dimensional molded product. However, when a three-dimensional molding process is performed on a nonwoven fabric using crimpable fibers, the stretch unevenness of the fibers becomes conspicuous when crimping is expressed, and the texture of the nonwoven fabric deteriorates. There is a problem that it is difficult to obtain a three-dimensional molded product.

本発明は、このような従来技術に存在する問題点に着目してなされたものである。その目的とするところは、一定方向とそれとは異なる方向における繊維間の交絡を増加させて良好な強度及び伸びを発揮することができ、立体成形加工に好適な不織布及びそのような不織布を簡単に得ることができる不織布の製造方法を提供することにある。   The present invention has been made paying attention to such problems existing in the prior art. The purpose is to increase the entanglement between the fibers in a certain direction and the direction different from it, and to exhibit good strength and elongation, and to easily create a nonwoven fabric suitable for three-dimensional molding and such a nonwoven fabric. It is providing the manufacturing method of the nonwoven fabric which can be obtained.

上記の目的を達成するために、請求項1に記載の発明の不織布は、不織布素材に対して一定方向に沿ってニードルパンチ加工を施した後、前記一定方向とは異なる方向に沿ってニードルパンチ加工を施して得られることを特徴とするものである。   In order to achieve the above object, the nonwoven fabric of the invention according to claim 1 is a needle punch along a direction different from the certain direction after needle punching is performed along a certain direction with respect to the nonwoven material. It is obtained by processing.

請求項2に記載の発明の不織布は、請求項1に係る発明において、前記異なる方向は一定方向に対して直交する方向であるものである。
請求項3に記載の発明の不織布は、請求項2に係る発明において、立体成形加工に用いられるものである。
In the nonwoven fabric of the invention according to claim 2, in the invention according to claim 1, the different direction is a direction orthogonal to a certain direction.
The non-woven fabric of the invention according to claim 3 is used for the three-dimensional molding in the invention according to claim 2.

請求項4に記載の発明の不織布は、請求項3に係る発明において、立体成形加工は深絞り成形加工である。
請求項5に記載の発明の不織布の製造方法は、不織布素材に対して一定方向に沿ってニードルパンチ加工を施した後、前記一定方向とは異なる方向に沿ってニードルパンチ加工を施すことを特徴とするものである。
The nonwoven fabric of the invention according to claim 4 is the invention according to claim 3, wherein the three-dimensional forming process is a deep drawing process.
The manufacturing method of the nonwoven fabric of the invention according to claim 5 is characterized in that after punching the nonwoven fabric material along a certain direction, needle punching is performed along a direction different from the certain direction. It is what.

本発明によれば、次のような効果を発揮することができる。
請求項1に記載の発明の不織布によれば、一定方向とそれとは異なる方向における繊維間の交絡を増加させて良好な強度及び伸びを発揮させることができ、立体成形加工に好適であるという効果を奏する。
According to the present invention, the following effects can be exhibited.
According to the nonwoven fabric of the invention described in claim 1, it is possible to increase the entanglement between fibers in a certain direction and a direction different from the constant direction, thereby exhibiting good strength and elongation, and an effect that it is suitable for three-dimensional molding processing. Play.

請求項2に記載の発明の不織布によれば、請求項1に係る発明の効果に加えて、一定方向とそれと直交する方向の強度を向上させることができる。
請求項3に記載の発明の不織布によれば、請求項2に係る発明の効果に加えて、不織布は立体成形加工に好適に用いることができる。
According to the nonwoven fabric of the invention described in claim 2, in addition to the effect of the invention according to claim 1, the strength in a certain direction and a direction orthogonal thereto can be improved.
According to the nonwoven fabric of the invention of claim 3, in addition to the effect of the invention of claim 2, the nonwoven fabric can be suitably used for three-dimensional molding.

請求項4に記載の発明の不織布によれば、請求項3に係る発明の効果に加えて、不織布は特に深絞り成形加工に好適に用いることができる。
請求項5に記載の発明の不織布の製造方法によれば、ニードルパンチ加工を一定方向に沿って施した後、それとは異なる方向に沿って施すという簡単な操作で、一定方向とそれとは異なる方向における強度を向上させ、立体成形加工に好適な不織布を得ることができる。
According to the non-woven fabric of the invention described in claim 4, in addition to the effect of the invention according to claim 3, the non-woven fabric can be suitably used particularly for deep drawing.
According to the method for manufacturing a nonwoven fabric of the invention according to claim 5, the needle punching process is performed along a certain direction, and then performed along a direction different from the needle punching process. The non-woven fabric suitable for three-dimensional forming can be obtained.

以下、本発明の実施形態につき、図面を用いて詳細に説明する。
本実施形態の不織布は、一定方向に沿ってニードルパンチ加工を施した不織布に、その方向とは異なる方向に沿ってニードルパンチ加工を施すことにより得られるものである。ここで、ニードルパンチ加工の方向性は、不織布の上若しくは下又は上下からニードルをパンチングして繊維を交絡させるものであるが、パンチングを行いながら、同時に不織布が一方向に移動するため、その方向に方向性ができることを意味する。一定方向とその方向とは異なる方向にニードルパンチ加工を施すことにより、不織布は一定方向に繊維が絡み合う(交絡する)と同時に、それとは異なる方向にも繊維が絡み合っている。従って、不織布は一定方向及びそれとは異なる方向に良好な強度を有すると共に、優れた伸びを発現することができる。
Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings.
The nonwoven fabric of this embodiment is obtained by subjecting a nonwoven fabric that has been subjected to needle punching along a certain direction to needle punching along a direction different from that direction. Here, the directionality of the needle punching process is to punch the needle from above, below or above and below the nonwoven fabric to entangle the fibers, but since the nonwoven fabric simultaneously moves in one direction while punching, that direction It means that there is a direction. By performing needle punching in a certain direction and a direction different from that direction, the nonwoven fabric is entangled (entangled) with fibers in a certain direction, and at the same time, the fibers are also entangled in a different direction. Therefore, the nonwoven fabric has a good strength in a certain direction and a different direction, and can exhibit excellent elongation.

異なる方向としては、一定方向に対して交差する方向であればよいが、直交していることが、不織布の強度と伸びを全周により均等になるように発揮することができる点で最も好ましい。この不織布を用いて立体成形加工を行うと、不織布は縦横により均一になるように引き伸ばされる。従って、不織布をこのように構成することにより、深絞り成形加工等の立体成形加工に適したものとすることができる。   The different direction may be any direction that intersects a certain direction, but it is most preferable that the direction is orthogonal because the strength and elongation of the nonwoven fabric can be evenly distributed over the entire circumference. When a three-dimensional molding process is performed using this nonwoven fabric, the nonwoven fabric is stretched so as to be more uniform in the vertical and horizontal directions. Therefore, by configuring the nonwoven fabric in this way, it can be made suitable for three-dimensional molding such as deep drawing.

次に、上記のような不織布を得るための好適な製造装置及び製造方法について説明する。まず、開繊機を用いて予め所定の重量になるように秤量したステープル(短繊維)を開繊した後、ローラーカードを用いて不織布素材(パラレルウェブ又はマット)とする。次いで、図1から図3に模式的に示すように、ニードルパンチ加工装置11を用いて、ニードルパンチ加工を行う。すなわち、装置本体12は四角盤状をなす上下一対の基盤13を備えている。各基盤13には縦、横に一定間隔をおいて上下対応する位置に貫通孔14が設けられている。両基盤13間に形成されている通路15にはニードルパンチ加工を施す前の不織布素材16が通過できるようになっている。   Next, the suitable manufacturing apparatus and manufacturing method for obtaining the above nonwoven fabric are demonstrated. First, staples (short fibers) weighed in advance to have a predetermined weight using a spreader are opened, and then a nonwoven fabric material (parallel web or mat) is formed using a roller card. Next, as schematically shown in FIGS. 1 to 3, needle punching is performed using a needle punch processing device 11. That is, the apparatus main body 12 includes a pair of upper and lower bases 13 that form a square disk shape. Each base 13 is provided with through-holes 14 at vertical and horizontal positions at regular intervals. A non-woven fabric material 16 before being subjected to needle punching can pass through a passage 15 formed between both bases 13.

基盤13の上方位置には多数のニードル17が下方へ突設されたニードル支持盤18が上下動可能に配置されている。ニードル17は前記一対の基盤13に設けられた貫通孔14に挿通されるように、同じ配列で設けられている。そして、ニードル支持盤18が下降し、ニードル17が基盤13の貫通孔14を貫通することにより、通路15を通過する不織布素材16に対してニードルパンチ加工を施すように構成されている。   A needle support plate 18 having a large number of needles 17 projecting downward is disposed above the base 13 so as to be movable up and down. The needles 17 are provided in the same arrangement so as to be inserted through the through holes 14 provided in the pair of bases 13. The needle support plate 18 is lowered and the needle 17 penetrates the through hole 14 of the base 13 so that the nonwoven fabric material 16 passing through the passage 15 is subjected to needle punching.

このようなニードルパンチ加工装置11を用いてニードルパンチ加工を行なう場合には、不織布素材16を一対の基盤13間の通路15を連続的に通過させる。一方、ニードル支持盤18を下降させ、各ニードル17を基盤13の貫通孔14に貫通させ、ニードル17の下死点から上昇させる。この動作を不織布素材16の移動速度に対応させて行なう。これにより、不織布素材16の一方向にニードルパンチ加工が施される。   When needle punching is performed using such a needle punching device 11, the nonwoven fabric material 16 is continuously passed through the passage 15 between the pair of bases 13. On the other hand, the needle support plate 18 is lowered, the needles 17 are passed through the through holes 14 of the base 13, and the needles 17 are raised from the bottom dead center. This operation is performed in accordance with the moving speed of the nonwoven fabric material 16. Thereby, needle punching is performed in one direction of the nonwoven fabric material 16.

図2の二点鎖線で示すように、装置本体12から出てきた不織布素材16を一定の長さ、例えばほぼ正方形となるように切断する。そして、図3に示すように、係る不織布素材16を90°回転させ、前後の不織布素材16と重なり部分16aを有するように配置し、上記と同様にして再度、ニードルパンチ加工を施す。このようにして、不織布素材16に縦方向と横方向の両方向にニードルパンチ加工による方向性を持たせた不織布19が得られるのである。   As shown by a two-dot chain line in FIG. 2, the non-woven fabric material 16 that has come out of the apparatus main body 12 is cut into a certain length, for example, a substantially square shape. Then, as shown in FIG. 3, the nonwoven fabric material 16 is rotated by 90 °, arranged so as to have an overlapping portion 16 a with the preceding and following nonwoven fabric materials 16, and subjected to needle punching again in the same manner as described above. In this way, a nonwoven fabric 19 is obtained in which the nonwoven fabric material 16 is given directionality by needle punching in both the longitudinal direction and the lateral direction.

次に、得られた不織布19を用い、立体成形加工としての深絞り成形加工を行う装置及び方法について説明する。図4に示すように、円筒状に形成されたダイス20の中心には円柱状の成形凹部21が貫設されている。ダイス20上には不織布19を押圧して皺の発生を止める皺押え22が配置されている。成形凹部21の上方位置にはプレス成形機のパンチ23が上下動可能に配置され、皺押え22で押圧された不織布19を成形凹部21内に押し込んで不織布19を引き伸ばし、深絞り成形品24を製造するように構成されている。   Next, an apparatus and a method for performing a deep drawing process as a three-dimensional molding process using the obtained nonwoven fabric 19 will be described. As shown in FIG. 4, a columnar molding recess 21 is provided through the center of the cylindrically formed die 20. On the die 20, a heel presser 22 is disposed that presses the nonwoven fabric 19 to stop wrinkles. A punch 23 of a press molding machine is disposed above the molding recess 21 so as to be movable up and down. The nonwoven fabric 19 pressed by the presser foot 22 is pushed into the molding recess 21 to stretch the nonwoven fabric 19, and a deep-drawn molded product 24 is formed. It is configured to manufacture.

さて、複数方向にニードルパンチ加工を施してなる不織布19を製造するには、まずポリ乳酸、ポリエステル等のステープルからカード装置により不織布素材16(ウェブ)を作製する。そして、図1に示すように、この不織布素材16をニードルパンチ加工装置11の通路15を通して一定方向に移動させると共に、ニードル17を上下動させることによりその一定方向に沿ってニードルパンチ加工を施して不織布素材16を得る。このとき、不織布素材16を構成する繊維は一定方向に流れて絡み合いが生じ、その方向に結合力の大きい方向性が発現される。続いて、図2に示すように、得られた不織布素材16を、前記一定方向と直交方向に切断し、図3に示すようにそれを並べて再度ニードルパンチ加工を施す。このとき、繊維には直交方向にもその方向に結合力の大きい方向性が発現される。このようにして、複数方向に強度が高く、伸びの大きい不織布19が得られる。   In order to manufacture the nonwoven fabric 19 formed by performing needle punching in a plurality of directions, first, a nonwoven fabric material 16 (web) is prepared from a staple such as polylactic acid or polyester by a card device. Then, as shown in FIG. 1, the nonwoven fabric material 16 is moved in a certain direction through the passage 15 of the needle punching device 11, and the needle 17 is moved up and down to perform needle punching along the certain direction. A non-woven fabric material 16 is obtained. At this time, the fibers constituting the nonwoven fabric material 16 flow in a certain direction and are entangled with each other, and a direction having a large binding force is expressed in that direction. Subsequently, as shown in FIG. 2, the obtained nonwoven fabric material 16 is cut in a direction orthogonal to the certain direction, arranged as shown in FIG. 3, and subjected to needle punching again. At this time, the fiber exhibits a directionality having a large binding force in the orthogonal direction. In this way, the nonwoven fabric 19 having high strength in a plurality of directions and large elongation can be obtained.

続いて、得られた不織布19に対して深絞り成形加工を施すには、図4に示すように、ダイス20上に不織布19を載せ、成形凹部21以外の部分を皺押え22で押圧する。その状態で図5に示すようにプレス成形機のパンチ23を下降させ、不織布19を成形凹部21内に押し込んで不織布19を引き伸ばし、絞り深さdの深絞り成形品24を得る。不織布19は、一定方向とその直交方向に強度と伸びが大きいことから、深絞り成形加工を施したときに追従性が良く、立体形状を良好に保持することができる。   Subsequently, in order to perform deep drawing processing on the obtained nonwoven fabric 19, the nonwoven fabric 19 is placed on the die 20 as shown in FIG. In this state, as shown in FIG. 5, the punch 23 of the press molding machine is lowered, and the nonwoven fabric 19 is pushed into the molding recess 21 to stretch the nonwoven fabric 19 to obtain a deep-drawn molded product 24 having a drawing depth d. Since the nonwoven fabric 19 has high strength and elongation in a certain direction and a direction perpendicular thereto, the nonwoven fabric 19 has good followability when a deep drawing process is performed, and can maintain a good three-dimensional shape.

以上の実施形態によって発揮される効果について説明する。
・ 本実施形態の不織布19は、ニードルパンチ加工を長手方向に沿って施した後に、長手方向とは異なる方向に沿って施して得られる。このため、長手方向とそれとは異なる方向の2方向における繊維間の交絡を増加させることができ、両方向における不織布19の強度及び伸びを向上させることができる。異なる方向が長手方向と直交方向であることにより、不織布19全体の強度及び伸びをより均等に向上させることができる。従って、そのような不織布19は立体成形加工、特に深絞り成形加工に好適に用いることができ、得られる成形品は形状保持性に優れている。その結果、深絞り成形加工による深絞り成形品24は、部品用パッケージ等の包装資材、美粧性パッケージ、生ゴミトレイ等の生活関連資材、育苗ポット、育林ポットなどの農林用・園芸資材、自動車用関連資材等として用いることができ、産業上大変有用である。
The effect exhibited by the above embodiment will be described.
-The nonwoven fabric 19 of this embodiment is obtained by giving along the direction different from a longitudinal direction, after giving a needle punch process along a longitudinal direction. For this reason, the entanglement between the fibers in the longitudinal direction and two different directions can be increased, and the strength and elongation of the nonwoven fabric 19 in both directions can be improved. When the different direction is the direction orthogonal to the longitudinal direction, the strength and elongation of the nonwoven fabric 19 as a whole can be improved more uniformly. Therefore, such a nonwoven fabric 19 can be suitably used for three-dimensional molding, particularly deep drawing, and the resulting molded product is excellent in shape retention. As a result, deep-drawn molded products 24 by deep-draw molding are used for packaging materials such as parts packages, cosmetic packages, life-related materials such as garbage trays, agricultural and horticultural materials such as nursery pots and planting pots, and automobiles. It can be used as related materials and is very useful in industry.

・ 本実施形態の不織布19は、ニードルパンチ加工を長手方向に沿って施した後、続いてそれとは異なる方向に沿って再度ニードルパンチ加工を施すという簡単な操作で、長手方向とそれとは異なる方向における強度を向上させた不織布を容易に得ることができる。つまり、特殊な原材料や特殊な機器を用いることなく、ニードルパンチ加工法の簡単な改良により、簡便でかつ容易に深絞り成形加工に適した不織布19を得ることができる。   The nonwoven fabric 19 of the present embodiment has a simple operation in which the needle punching process is performed along the longitudinal direction and then the needle punching process is performed again along the direction different from the needle punching process. A nonwoven fabric with improved strength can be easily obtained. That is, the nonwoven fabric 19 suitable for deep drawing can be obtained simply and easily by simple improvement of the needle punching method without using special raw materials or special equipment.

以下に、実施例及び比較例を挙げて前記実施形態を更に具体的に説明する。
(実施例1)
ポリ乳酸ステープル(繊度2.2dtex、繊維長51mm)を開繊機により2回開繊を行い、ローラーカードによりパラレルウェブを作製した。このパラレルウェブに対し、その長手方向に沿ってニードル密度50本/m2のニードルパンチ加工を行って不織布素材16とした。続いて、この不織布素材16を長手方向に直交する短手方向に等分して切断し、各不織布素材16を90°回転させ、不織布素材16の端部10cmずつが重なり部分16aとなるように積層して、再度ニードル密度50本/m2のニードルパンチ加工を施した。つまりは縦方向と横方向との2方向からニードルパンチ加工を施した不織布19が得られた。目付量90g/m2としたものをサンプル1とした。
Hereinafter, the embodiment will be described more specifically with reference to examples and comparative examples.
(Example 1)
Polylactic acid staples (fineness: 2.2 dtex, fiber length: 51 mm) were opened twice with a spreader, and a parallel web was produced with a roller card. The parallel web was subjected to needle punching with a needle density of 50 needles / m 2 along the longitudinal direction to obtain a nonwoven fabric material 16. Subsequently, the nonwoven fabric material 16 is equally cut in the short direction perpendicular to the longitudinal direction, and each nonwoven fabric material 16 is rotated by 90 ° so that the end portions 10 cm of the nonwoven fabric material 16 become overlapping portions 16a. After the lamination, needle punching with a needle density of 50 / m 2 was performed again. That is, the nonwoven fabric 19 which gave the needle punch process from two directions, the vertical direction and a horizontal direction, was obtained. Sample 1 having a basis weight of 90 g / m 2 was used.

同様に、1回目のニードルパンチ加工のニードル密度を75本/m2、2回目のニードルパンチ加工のニードル密度75本/m2で、目付量90g/m2の不織布をサンプル2とした。また、1回目のニードルパンチ加工のニードル密度を100本/m2、2回目のニードルパンチ加工のニードル密度を100本/m2で、目付量90g/m2の不織布19をサンプル3とした。これらの不織布19について、JIS L1913一般短繊維不織布試験方法により、引張強さ及び伸び率の測定を行った。また、このときの試料のつかみ間隔を100mmとした。 Similarly, sample 2 was a nonwoven fabric having a needle density of 75 needles / m 2 in the first needle punching process and a needle density of 75 needles / m 2 in the second needle punching process and a basis weight of 90 g / m 2 . Sample 3 was a nonwoven fabric 19 having a needle density of 100 needles / m 2 in the first needle punching process, a needle density of 100 needles / m 2 in the second needle punching process, and a basis weight of 90 g / m 2 . About these nonwoven fabrics 19, the tensile strength and elongation rate were measured by the JIS L1913 general short fiber nonwoven fabric test method. Further, the holding interval of the sample at this time was set to 100 mm.

ところで、深絞り成形加工における不織布19の特性として、その強度と伸び率の値が大きく、かつ伸び率の縦方向と横方向の比が1に近いものが要求される。上記不織布製造方法のニードル密度をさらに大きくした場合、不織布の縦方向、横方向共に引張強さが大きくなり、伸び率は縦方向が小さく、横方向が大きくなる傾向となる。1回目のニードルパンチ加工と2回目のニードルパンチ加工のニードル密度は同数である必要はなく、ニードル密度を可変調整すれば、縦方向と横方向の伸び率が同等で、縦横均等に伸びる不織布19を作製することが可能となる。また、この場合、不織布の伸び率は、用いるステープルの繊度や繊維長により変わるため、ニードル密度の調整が必要なことは当然である。   By the way, the properties of the nonwoven fabric 19 in the deep drawing process are required to have a large strength and elongation value and a ratio of the elongation rate in the vertical and horizontal directions close to 1. When the needle density of the nonwoven fabric production method is further increased, the tensile strength is increased in both the longitudinal direction and the transverse direction of the nonwoven fabric, and the elongation rate tends to be small in the longitudinal direction and large in the lateral direction. The needle density of the first needle punching process and the second needle punching process do not need to be the same number, and if the needle density is variably adjusted, the nonwoven fabric 19 that extends in the vertical and horizontal directions has the same elongation in the vertical and horizontal directions. Can be produced. In this case, since the elongation percentage of the nonwoven fabric varies depending on the fineness and fiber length of the staple used, it is naturally necessary to adjust the needle density.

次に、立体成形加工を行う。上記方法で作製した不織布19を図4に示す前述のダイス20、皺押え22、プレス成形機のパンチ23等で構成される円筒深絞り成形金型に装着し、プレス成形機のパンチ23を下降させることにより深絞り成形加工を行った。図5に示すように、パンチ23の絞り深さdはサンプル1と2では30mm、サンプル3は35mmとし、成形設定温度80℃、実際の金型温度73℃、成形時間5分とした。このときの結果を表1に示す。図6に得られた深絞り成形品24を示す。この結果、サンプル3では絞り高さ/絞り径の比が0.45で形状性に優れた不織布19の深絞り成形品24を得ることができた。また、表1に記述されている深絞り成形品24の形状性が良好とは、深絞り成形品24の割れ、破れ、す抜けムラが無く、地合が優れたもののことをいう。   Next, a three-dimensional molding process is performed. The non-woven fabric 19 produced by the above method is mounted on a cylindrical deep drawing mold composed of the above-described die 20 shown in FIG. 4, the punch 22, the punch 23 of the press molding machine, etc., and the punch 23 of the press molding machine is lowered. By doing so, deep drawing was performed. As shown in FIG. 5, the drawing depth d of the punch 23 was 30 mm for the samples 1 and 2, 35 mm for the sample 3, the molding set temperature 80 ° C., the actual mold temperature 73 ° C., and the molding time 5 minutes. The results are shown in Table 1. FIG. 6 shows the deep-drawn molded product 24 obtained. As a result, it was possible to obtain a deep-drawn molded article 24 of the nonwoven fabric 19 having excellent drawing properties with a drawing height / drawing diameter ratio of 0.45. Further, the good shape of the deep-drawn molded product 24 described in Table 1 means that the deep-drawn molded product 24 is free from cracks, breaks, and voids and has excellent texture.

また、1回目のニードルパンチ加工のニードル密度が100本/m2、2回目が100本/m2で目付量が100g/m2、150g/m2、200g/m2である不織布に、同様の深絞り成形加工を行った。パンチ絞り深さ35mmのとき、絞り高さ/絞り径:0.41〜0.45で形状性が優れた深絞り成形品24を得ることができた。 Also, the first non-woven needle density of the needle punching is 100 / m 2, 2 time is 100 / m 2 weight per unit area 100 g / m 2 in, 150 g / m 2, 200 g / m 2, similarly The deep drawing was processed. When the punch drawing depth was 35 mm, it was possible to obtain a deep drawing molded product 24 having excellent drawing characteristics with drawing height / drawing diameter: 0.41 to 0.45.

この製造方法であれば、不織布素材16としてのパラレルウェブに限らず、ランダムウェブ又はクロスウェブを用いても良く、さらに、一度ニードルパンチ加工を行った不織布素材16を別の不織布素材16に積層しても良い。この場合、1回目のニードルパンチ加工の方向性が2回目のニードルパンチ加工の方向性と直交するように配置すれば良い。つまりは、不織布素材16の長手方向のみならず、幅方向にもニードルパンチ加工を行うことができれば良いのである。更には、不織布素材16の長手方向とその長手方向より120°ずらした方向及び長手方向より240°ずらした方向からと3方向からニードルパンチ加工を施すことも可能である。   If it is this manufacturing method, you may use not only the parallel web as the nonwoven fabric material 16 but a random web or a cross web, Furthermore, the nonwoven fabric material 16 which once performed needle punching is laminated | stacked on another nonwoven fabric material 16. May be. In this case, the direction of the first needle punching may be arranged so as to be orthogonal to the direction of the second needle punching. That is, it is only necessary to perform needle punching not only in the longitudinal direction of the nonwoven fabric material 16 but also in the width direction. Furthermore, it is also possible to perform needle punching from three directions, that is, the longitudinal direction of the nonwoven fabric material 16, the direction shifted by 120 ° from the longitudinal direction, and the direction shifted by 240 ° from the longitudinal direction.

不織布素材16は冷間成形加工だけではひずみ回復が起こるため、熱成形加工が必要となる。そこで、熱可塑性繊維等を配合し、加熱による立体成形物の形状保持、つまりは熱接着を行う。加熱温度は、低すぎると熱接着による形状保持が困難となり、高すぎると形状がペーパーライクとなり、不織布素材16の風合いが失われるため、通常は材料のガラス転移温度以上かつ融点より30℃低い温度以下が適当である。また、形状保持を行うには、不織布素材16の組成の全てをポリエチレン、ポリプロピレン及びその共重合体や変性体を含むポリオレフィン系、ナイロン6、ナイロン66、ナイロン12等のポリアミド系、ポリエチレンテレフタレート、ポリブチレンテレフタレート、ポリ乳酸等のポリエステル系、ポリカーボネート、ポリエーテルイミド、ポリフェニレンサルファイド、ポリエーテルケトン等の熱可塑性繊維としても良いし、上記以外の熱可塑性繊維やその他に天然繊維、化学繊維等の熱可塑性繊維以外のものを配合しても良い。また、形状保持を行うためには、熱可塑性繊維に拘る必要はなく、熱可塑性粉末、樹脂、エマルジョン、熱硬化性繊維、粉末、樹脂、エマルジョン等で代替しても良い。   Since the nonwoven fabric material 16 recovers strain only by cold forming, thermoforming is required. Therefore, thermoplastic fibers and the like are blended, and the shape of the three-dimensional molded product is maintained by heating, that is, thermal bonding is performed. If the heating temperature is too low, it will be difficult to maintain the shape by thermal bonding, and if it is too high, the shape will become paper-like and the texture of the nonwoven fabric material 16 will be lost. The following are appropriate. In order to maintain the shape, all the composition of the nonwoven fabric material 16 is made of polyethylene, polypropylene, and polyolefins including copolymers and modified materials thereof, polyamides such as nylon 6, nylon 66, and nylon 12, polyethylene terephthalate, poly It may be a thermoplastic fiber such as butylene terephthalate, polyester such as polylactic acid, polycarbonate, polyetherimide, polyphenylene sulfide, polyether ketone, or other thermoplastic fibers other than those mentioned above, and other thermoplastic fibers such as natural fibers and chemical fibers. You may mix | blend things other than a fiber. In order to maintain the shape, it is not necessary to be concerned with the thermoplastic fiber, and it may be replaced with a thermoplastic powder, resin, emulsion, thermosetting fiber, powder, resin, emulsion or the like.

(実施例2)
ポリ乳酸ステープル(繊度1.7dtex、繊維長51mm)を用いて、ニードル密度100本/m2の目付量154g/m2の不織布素材16を作製した。この不織布素材16を長手方向と直交方向に切断し、90°回転させて目付量13g/m2の不織布素材16上に載せ、100本/m2のニードルパンチ加工を行い積層不織布とした。この積層不織布を用いて深絞り成形加工を行った。深絞り成形加工の絞り深さdは30mm、成形設定温度80℃、実際の金型温度は73℃、成形時間5分とし、サンプル4とした。このときの結果を表1に示す。この結果、絞り高さ/絞り径:0.49で形状性が優れた深絞り成形品24を得ることができた。
(Example 2)
Using a polylactic acid staple (fineness: 1.7 dtex, fiber length: 51 mm), a nonwoven fabric material 16 having a needle density of 100 / m 2 and a basis weight of 154 g / m 2 was produced. The nonwoven fabric material 16 was cut in a direction perpendicular to the longitudinal direction, rotated 90 ° and placed on the nonwoven fabric material 16 having a basis weight of 13 g / m 2 , and subjected to needle punching at 100 pieces / m 2 to obtain a laminated nonwoven fabric. Using this laminated nonwoven fabric, deep drawing was performed. The drawing depth d of the deep drawing process was 30 mm, the molding set temperature was 80 ° C., the actual mold temperature was 73 ° C., and the molding time was 5 minutes. The results are shown in Table 1. As a result, it was possible to obtain a deep-drawn molded article 24 having excellent drawing properties at drawing height / drawing diameter: 0.49.

(実施例3)
ポリエステルステープル(繊度2.2dtex、繊維長51mm)を用いたニードル密度200本/m2の不織布を長手方向に直交する短手方向に切断し、90°回転させて、不織布素材16の端部10cmずつが重なり部分16aとなるように積層して、再度ニードル密度50本/m2のニードルパンチ加工を行い不織布19を得た。このときの目付量は160g/m2とし、深絞り成形加工の絞り深さdは40mm、成形設定温度80℃、実際の金型温度73℃、成形時間5分として得られた不織布19をサンプル5とした。このときの結果を表1に示す。その結果、絞り高さ/絞り径が0.57で形状性に優れた深絞り成形品24を得ることができた。
(Example 3)
A non-woven fabric having a needle density of 200 / m 2 using polyester staples (fineness: 2.2 dtex, fiber length: 51 mm) is cut in the transverse direction perpendicular to the longitudinal direction, rotated 90 °, and 10 cm at the end portion of the nonwoven fabric material 16 Were laminated so as to be an overlapping portion 16a, and needle punching with a needle density of 50 / m 2 was performed again to obtain a nonwoven fabric 19. The basis weight at this time is 160 g / m 2 , the drawing depth d of the deep drawing process is 40 mm, the molding set temperature is 80 ° C., the actual mold temperature is 73 ° C., and the molding time is 5 minutes. It was set to 5. The results are shown in Table 1. As a result, it was possible to obtain a deep-drawn molded product 24 having a drawing height / drawing diameter of 0.57 and excellent shape.

Figure 2005154918
表1に示したように、実施例1ではニードル密度を変えても引張強さ及び伸び率を縦方向及び横方向に発揮することができ、深絞り成形品24の形状性を良好に維持することができた。また、実施例2及び実施例3においても深絞り成形品24の形状性を良好に維持することができた。
Figure 2005154918
As shown in Table 1, in Example 1, even if the needle density is changed, the tensile strength and the elongation can be exhibited in the vertical direction and the horizontal direction, and the shape of the deep-drawn molded product 24 is maintained well. I was able to. Moreover, also in Example 2 and Example 3, the shape of the deep-drawn molded product 24 could be maintained satisfactorily.

(比較例1)
実施例1と同様のポリ乳酸ステープルを用いて同様の不織布素材(パラレルウェブ)を作製した。得られた不織布素材にニードル密度50本/m2のニードルパンチ加工を行った。目付量90g/m2とし、サンプル6とした。同様にニードル密度100本/m2のニードルパンチ加工を行った不織布をサンプル7、ニードル密度200本/m2のニードルパンチ加工を行った不織布をサンプル8とした。作製された不織布を用いて深絞り成形加工を行った。このときの結果を表2に示す。ここで、表2で記述の測定困難の意味を説明する。この不織布の繊維配向性、ニードルパンチ方向性は縦方向のみである。横方向の強度物性は、交絡力が弱いため、強度が弱くなり、伸び率は大きな値を示すこととなるが、不織布が均等に伸びるのではなく、す抜けムラを発生しながら伸びていくため、測定困難とした。
(Comparative Example 1)
The same non-woven fabric material (parallel web) was produced using the same polylactic acid staple as in Example 1. The obtained nonwoven material was subjected to needle punching with a needle density of 50 / m 2 . The basis weight was 90 g / m 2 and Sample 6 was obtained. Similarly, sample 7 was a nonwoven fabric subjected to needle punching with a needle density of 100 / m 2 , and sample 8 was a nonwoven fabric subjected to needle punching with a needle density of 200 / m 2 . Using the produced non-woven fabric, deep drawing was performed. The results at this time are shown in Table 2. Here, the meaning of measurement difficulty described in Table 2 will be described. This nonwoven fabric has fiber orientation and needle punch direction only in the longitudinal direction. The strength properties in the transverse direction are weak because the entanglement force is weak, and the strength is weak, and the elongation rate shows a large value, but the nonwoven fabric does not stretch evenly, but stretches while generating unevenness in passing through. It was difficult to measure.

作製した深絞り成形品は、パンチ絞り深さ25mmのとき、絞り高さ/絞り径が0.30〜0.34となった。これは実施例1よりもパンチ絞り深さが浅いにも関わらず、ニードルパンチ加工を行った長手方向から破れ、形状性が優れた深絞り成形品を得ることができなかった。また、表2に記述している深絞り成形品の形状性が不良とは、深絞り成形品の割れ、破れ、又はす抜けムラが有り、地合が悪いもののことをいう。   The produced deep-drawn molded product had a drawing height / drawing diameter of 0.30 to 0.34 when the punch drawing depth was 25 mm. In spite of the fact that the punch drawing depth was shallower than in Example 1, it was broken from the longitudinal direction in which the needle punching was performed, and a deep drawing molded product having excellent shape could not be obtained. In addition, the poor shape of the deep-drawn molded product described in Table 2 means that the deep-drawn molded product has cracks, breaks, or unevenness in appearance, and the formation is poor.

(比較例2)
実施例1と同様のポリ乳酸ステープルから同様の不織布素材(パラレルウェブ)を作製した。この不織布素材を長手方向に直交する方向に切断し、90°回転させ、ウェブの端と端が重なるように並べて配置し、ニードル密度100本/m2のニードルパンチ加工を施した。目付量を90g/m2とし、サンプル9とした。作製した不織布素材を用いて深絞り成形加工を行った。このときの結果を表2に示す。作製した深絞り成形品は、絞り深さ25mmのとき、絞り高さ/絞り径が0.37となったが、比較例1と同様にニードルパンチ加工を行った長手方向から破れ、形状性が優れた深絞り成形品を得ることができなかった。
(Comparative Example 2)
A similar non-woven material (parallel web) was produced from the same polylactic acid staple as in Example 1. The nonwoven fabric material was cut in a direction perpendicular to the longitudinal direction, rotated 90 °, arranged side by side so that the ends of the web overlapped, and subjected to needle punching with a needle density of 100 / m 2 . The basis weight was 90 g / m 2 and Sample 9 was obtained. Using the produced nonwoven fabric material, deep drawing was performed. The results at this time are shown in Table 2. The produced deep-drawn molded product had a drawing height / drawing diameter of 0.37 when the drawing depth was 25 mm, but it was broken from the longitudinal direction in which needle punching was performed in the same manner as in Comparative Example 1, and the shape was low. An excellent deep drawing product could not be obtained.

(比較例3)
ポリエステルステープル(繊度3.3dtex、繊維長64mm)を用いてローラーカード及びクロスラッパーより不織布素材(クロスウェブ)を作製した。このクロスウェブにニードル密度200本/m2のニードルパンチ加工を施した目付量125g/m2の不織布をサンプル10とし、同様の深絞り成形加工を行った。このときの結果を表2に示す。作製した深絞り成形品は、絞り深さ35mmのとき、絞り高さ/絞り径が0.50となったが、深絞り成形金型のパンチの底面に当たる不織布部分が主に伸びるため、地合が悪くなり、形状性に優れた深絞り成形品を得ることができなかった。
(Comparative Example 3)
A nonwoven fabric material (cross web) was prepared from a roller card and a cross wrapper using polyester staples (fineness: 3.3 dtex, fiber length: 64 mm). The cross web needle density 200 yarns / m 2 of needle punching charity was basis weight 125 g / m 2 nonwoven fabric was used as the sample 10 was subjected to molding aperture similar depth. The results at this time are shown in Table 2. The drawn deep-drawn product has a drawing height / drawing diameter of 0.50 when the drawing depth is 35 mm. However, since the nonwoven fabric portion mainly hits the bottom of the punch of the deep drawing mold, As a result, it was not possible to obtain a deep-drawn molded product excellent in shape.

Figure 2005154918
表2に示したように、比較例1〜3ではニードルパンチ加工が一方向のみであることから、深絞り成形品24の形状性が不良であった。
Figure 2005154918
As shown in Table 2, in Comparative Examples 1 to 3, since the needle punching is only in one direction, the shape of the deep-drawn molded product 24 was poor.

尚、本実施形態は、次のように変更して具体化することも可能である。
・ ニードルパンチ加工を一定方向とは異なる方向に沿って施す場合、一定方向とは異なる複数方向すなわち3方向以上の方向にニードルパンチ加工を施すこともできる。この場合、一定方向と異なる複数方向とが全周に均等に位置するように、異なる複数方向を設定することが望ましい。このようにすれば、得られる不織布の強度と伸びを全周にわたって更に均一にすることができる。
In addition, this embodiment can also be changed and embodied as follows.
When needle punching is performed along a direction different from a certain direction, needle punching can be performed in a plurality of directions different from the certain direction, that is, in three or more directions. In this case, it is desirable to set different directions so that a certain direction and different directions are evenly positioned on the entire circumference. If it does in this way, the intensity | strength and elongation of the nonwoven fabric obtained can be made further uniform over a perimeter.

・ 立体成形加工として、プレス成形加工、真空成形加工等を採用することも可能である。
・ ニードルパンチ加工を一定方向とは異なる方向に沿って施す場合、不織布素材16を異なる方向に移動させたり、ニードルパンチ加工装置11を異なる方向に移動させることも可能である。
・ It is possible to adopt press forming, vacuum forming, etc. as the three-dimensional forming.
-When performing a needle punch process along the direction different from a fixed direction, it is also possible to move the nonwoven fabric raw material 16 to a different direction, and to move the needle punch processing apparatus 11 to a different direction.

更に、前記実施形態より把握できる技術的思想について以下に記載する。
(1) 前記異なる方向は一定方向に対して直交する方向である請求項5に記載の不織布の製造方法。この製造方法によれば、簡単な操作で、一定方向とそれと直交する方向における強度を向上させた不織布を得ることができる。
(2) 前記一定方向に沿ってニードルパンチ加工を施した後、不織布素材をその直交方向に切断し、90°向きを変えてニードルパンチ加工を施すように構成する上記技術的思想(1)に記載の不織布の製造方法。この製造方法によれば、ニードルパンチ加工装置の向きを変えたりすることなく、一定方向と直交する方向に容易にニードルパンチ加工を施すことができる。
Further, the technical idea that can be grasped from the embodiment will be described below.
(1) The method for producing a nonwoven fabric according to claim 5, wherein the different direction is a direction orthogonal to a certain direction. According to this manufacturing method, it is possible to obtain a non-woven fabric with improved strength in a certain direction and a direction perpendicular thereto by a simple operation.
(2) According to the above technical idea (1) configured to perform needle punching along the fixed direction, then cut the nonwoven fabric material in the orthogonal direction, and change the direction by 90 ° to perform needle punching. The manufacturing method of the nonwoven fabric as described. According to this manufacturing method, needle punching can be easily performed in a direction orthogonal to a certain direction without changing the direction of the needle punching device.

実施形態におけるニードルパンチ装置を示す概略説明図。BRIEF DESCRIPTION OF THE DRAWINGS Schematic explanatory drawing which shows the needle punch apparatus in embodiment. 図1の平面図。The top view of FIG. ニードルパンチ加工を縦方向の後、横方向に施す状態を示す平面図。The top view which shows the state which performs a needle punch process in a horizontal direction after a vertical direction. 深絞り加工装置を示す断面図。Sectional drawing which shows a deep drawing processing apparatus. 深絞り加工を行なった後の状態の深絞り加工装置を示す断面図。Sectional drawing which shows the deep drawing apparatus of the state after performing deep drawing. 深絞り成形品を示す断面図。Sectional drawing which shows a deep drawing molded article.

符号の説明Explanation of symbols

11…ニードルパンチ加工装置、16…不織布素材、19…不織布。   DESCRIPTION OF SYMBOLS 11 ... Needle punch processing apparatus, 16 ... Nonwoven fabric material, 19 ... Nonwoven fabric.

Claims (5)

不織布素材に対して一定方向に沿ってニードルパンチ加工を施した後、前記一定方向とは異なる方向に沿ってニードルパンチ加工を施して得られることを特徴とする不織布。 A nonwoven fabric obtained by subjecting a nonwoven fabric material to needle punching along a certain direction and then performing needle punching along a direction different from the certain direction. 前記異なる方向は一定方向に対して直交する方向である請求項1に記載の不織布。 The nonwoven fabric according to claim 1, wherein the different direction is a direction orthogonal to a certain direction. 立体成形加工に用いられる請求項2に記載の不織布。 The nonwoven fabric of Claim 2 used for a three-dimensional shaping | molding process. 立体成形加工は深絞り成形加工である請求項3に記載の不織布。 The nonwoven fabric according to claim 3, wherein the three-dimensional forming process is a deep drawing process. 不織布素材に対して一定方向に沿ってニードルパンチ加工を施した後、前記一定方向とは異なる方向に沿ってニードルパンチ加工を施すことを特徴とする不織布の製造方法。 A method for producing a nonwoven fabric, comprising performing needle punching along a certain direction on a nonwoven fabric material, and thereafter performing needle punching along a direction different from the certain direction.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014019992A (en) * 2012-07-23 2014-02-03 Nippon Ester Co Ltd Short fiber nonwoven fabric of high elongation

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014019992A (en) * 2012-07-23 2014-02-03 Nippon Ester Co Ltd Short fiber nonwoven fabric of high elongation

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