JP2005120466A - HIGH STRENGTH Cr-Mo ALLOY STEEL FOR SPEED CHANGE GEAR - Google Patents

HIGH STRENGTH Cr-Mo ALLOY STEEL FOR SPEED CHANGE GEAR Download PDF

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JP2005120466A
JP2005120466A JP2004254064A JP2004254064A JP2005120466A JP 2005120466 A JP2005120466 A JP 2005120466A JP 2004254064 A JP2004254064 A JP 2004254064A JP 2004254064 A JP2004254064 A JP 2004254064A JP 2005120466 A JP2005120466 A JP 2005120466A
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Bong Rae Cho
鳳 來 趙
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Hyundai Motor Co
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/22Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/26Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum

Abstract

<P>PROBLEM TO BE SOLVED: To provide high strength Cr-Mo alloy steel for a speed change gear which can solve the problem that nickel added when producing carburizing steel for a gear is expensive and reduces workability, and the the problem in the reduction of productivity, the reduction of the service life in a working tool or the like caused by the difficulty in the working of a gear using Ni-Cr-Mo alloy steel. <P>SOLUTION: The high strength Cr-Mo alloy steel for a speed change gear has a composition composed essentially of Fe and having alloy based components comprising, by weight, 0.17 to 0.21% C, ≤0.15% Si, 0.60 to 0.85% Mn, ≤0.02% P, ≤0.03% S, 1.25 to 1.45% Cr, 0.55 to 0.65% Mo and 0.015 to 0.035% Nb, and in which the content of dissolved oxygen is controlled to ≤15 ppm. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

本発明は、変速機歯車用高強度Cr−Mo合金鋼に関するものであって、優れた物性を有しながらもコストタウンが実現できて、また結晶粒微細化効果の極大化により高温浸炭が可能で熱処理サイクルの時間を減らすことができる変速機歯車用高強度Cr−Mo合金鋼に関するものである。   The present invention relates to a high-strength Cr-Mo alloy steel for transmission gears, which can realize a cost town while having excellent physical properties, and can perform high-temperature carburization by maximizing the effect of grain refinement. This relates to a high-strength Cr—Mo alloy steel for transmission gears that can reduce the heat treatment cycle time.

一般に、自動車変速機歯車の製造工程は、図1に示すように、素材→熱間または冷間鍛造→冷却(空冷または放冷)→加工前熱処理(ISO Annealing or Normalizing)→加工(Shaving & Hobbing)→浸炭熱処理→後加工(研磨、Honing)などの工程を経て製造されている。   In general, as shown in FIG. 1, the manufacturing process of an automobile transmission gear is as follows: material → hot or cold forging → cooling (air cooling or cooling) → pre-processing heat treatment (ISO annealing or normalizing) → processing (shaving & hobbing) ) → Carburizing heat treatment → Post-processing (polishing, Honing) and the like.

従来、自動車変速機歯車用合金鋼としてよく使用される素材には、Cr合金鋼、Cr−Mo合金鋼、Ni−Cr−Mo合金鋼などがあり、主に浸炭熱処理を行って使用するが、各々の工程に適合して、安価で、熱処理後の物性にも優れたものが最適の合金鋼素材であると言える。
即ち、鍛造性及び加工性に優れて、値段も安く、物性(例えば、疲労特性、衝撃特性など)にも優れているものが好ましい。
Conventionally, materials often used as alloy steel for automobile transmission gears include Cr alloy steel, Cr-Mo alloy steel, Ni-Cr-Mo alloy steel, etc., which are mainly used after carburizing heat treatment, It can be said that the most suitable alloy steel material is suitable for each process, inexpensive and excellent in physical properties after heat treatment.
That is, those excellent in forgeability and workability, cheap in price, and excellent in physical properties (for example, fatigue characteristics, impact characteristics, etc.) are preferable.

Cr合金鋼とCr−Mo合金鋼は、廉価であるが、疲労特性及び衝撃特性が優れておらず、主に大きい負荷を受けない歯車によく使われている(特開平9−201644号、特開平4−88148号)。
反面、Ni−Cr−Mo合金鋼は、Niを含有するため高価で、加工が難しいという大きい短所はあるが、疲労特性及び衝撃特性に優れているため主に大きい負荷を受ける歯車類に適用される(特開平9−296250号、特開昭63−235452号)。
北米やヨーロッパなどの自動車メーカーでは、Niの値段がアジア地域よりは安いため、自動車のギア及びシャフト用としてNi−Cr−Mo合金鋼をよく使用する。
Cr alloy steel and Cr—Mo alloy steel are inexpensive, but they are not excellent in fatigue characteristics and impact characteristics and are often used mainly for gears that do not receive a large load (Japanese Patent Laid-Open No. 9-201644, special characteristics). Kaihei 4-88148).
On the other hand, Ni-Cr-Mo alloy steel is expensive because it contains Ni and has a major disadvantage that it is difficult to process, but it has excellent fatigue characteristics and impact characteristics, so it is mainly applied to gears that receive large loads. (Japanese Patent Laid-Open Nos. 9-296250 and 63-235452).
In automobile manufacturers such as North America and Europe, Ni-Cr-Mo alloy steel is often used for automobile gears and shafts because Ni is cheaper than in Asia.

通常、歯車用の浸炭鋼の場合、焼入性を高めて、高強度、高靱性を得るために、合金元素のMoやNiを添加するが、Niは高価であるとともに鋼の靱性を過度に高めるため様々な問題を起こす。例えば、歯車に加工する際、切削性が悪く歯車の歯面粗度を悪化させ、加工具の寿命を短縮するため生産性低下につながると言う問題点がある。
従って、焼入性及び加工性の問題だけではなく、コストダウンの側面からも優れたNi−Cr−Mo合金鋼に代替可能なCr−Mo合金鋼の開発が望まれている。
特開平9−296250号公報 特開昭63−235452号公報 特開平9−201644号公報 特開平4−88148号公報
Usually, in the case of carburized steel for gears, in order to increase hardenability and obtain high strength and high toughness, alloy elements Mo and Ni are added, but Ni is expensive and excessively increases the toughness of the steel. Cause various problems to increase. For example, when processing into a gear, there is a problem that the cutting performance is poor, the tooth surface roughness of the gear is deteriorated, and the life of the processing tool is shortened, leading to a decrease in productivity.
Therefore, development of Cr—Mo alloy steel that can replace Ni—Cr—Mo alloy steel, which is excellent not only in terms of hardenability and workability but also in terms of cost reduction, is desired.
Japanese Patent Laid-Open No. 9-296250 Japanese Patent Laid-Open No. 63-235452 Japanese Patent Laid-Open No. 9-201644 JP-A-4-88148

本発明は、前記のような問題点を解決するためになされたもので、歯車用浸炭鋼の製造時に添加するニッケルが高価で加工性を低下させる問題点と、Ni−Cr−Mo合金鋼を適用する歯車の加工の難しさによる生産性の低下、加工具の寿命短縮などの問題点を解決することができる変速機歯車用高強度Cr−Mo合金鋼を提供することにその目的がある。   The present invention has been made to solve the above-described problems. Nickel added at the time of manufacture of carburized steel for gears is expensive and has a problem that workability is lowered. The object is to provide a high-strength Cr—Mo alloy steel for transmission gears that can solve problems such as a decrease in productivity due to difficulty in processing the gear to be applied and a reduction in the life of the processing tool.

また、従来のCr−Mo合金鋼及びNi−Cr−Mo合金鋼の短所は改善し、高強度、高耐久性、コンパクト設計への対応等の長所はそのまま保持でき、結晶粒微細化効果の大幅向上による高温浸炭によって熱処理サイクルの時間を短縮することでコストタウンが計れる変速機歯車用高強度Cr−Mo合金鋼を提供することにその目的がある。   In addition, the disadvantages of conventional Cr-Mo alloy steel and Ni-Cr-Mo alloy steel have been improved, and the advantages such as high strength, high durability, and compatibility with compact design can be maintained as they are, and the effect of grain refinement has been greatly improved. The object is to provide a high-strength Cr-Mo alloy steel for transmission gears that can reduce the cost town by shortening the heat treatment cycle time by high-temperature carburization due to the improvement.

以下、本発明をさらに詳細に説明する。
本発明は、変速機歯車用高強度Cr−Mo合金鋼において、Feを主成分とし、0.17〜0.21重量%のCと、0.15重量%以下のSiと、0.60〜0.85重量%のMnと、0.02重量%以下のPと、0.03重量%以下のSと、1.25〜1.45重量%のCrと、0.55〜0.65重量%のMoと、0.015〜0.035重量%のNbとを含有する合金系成分で、溶存酸素量を15ppm以下にすることを特徴とする。
Hereinafter, the present invention will be described in more detail.
The present invention relates to a high-strength Cr-Mo alloy steel for transmission gears, which contains Fe as a main component, 0.17 to 0.21 wt% C, 0.15 wt% or less Si, 0.85 wt% Mn, 0.02 wt% or less P, 0.03% wt or less S, 1.25 to 1.45 wt% Cr, 0.55 to 0.65 wt% %, And an alloy component containing 0.015 to 0.035% by weight of Nb, and the dissolved oxygen content is 15 ppm or less.

本発明による変速機歯車用高強度Cr−Mo合金鋼は、高価なNiを含有するNi−Cr−Mo合金鋼に比べ、低廉であるにも拘わらず同等以上の特性を有し、加工具の寿命を延長する効果が得られる。
特に、高負荷を受けるため従来のCr−Mo合金鋼は適用困難であった歯車類及びシャフト類(Output Final Gear, Differential Drive Gear, 高出力手動変速機のInput and Output Shaftなど)に広く適用可能な利点を有する。
The high-strength Cr-Mo alloy steel for transmission gears according to the present invention has the same or better characteristics in spite of being cheaper than Ni-Cr-Mo alloy steel containing expensive Ni. The effect of extending the life is obtained.
In particular, it is widely applicable to gears and shafts (such as Output Final Gear, Differential Drive Gear, and Input and Output Shaft of high-power manual transmission), which are difficult to apply to conventional Cr-Mo alloy steel due to high load. Have the advantages.

本発明による変速機歯車用高強度Cr−Mo合金鋼では、加工性を向上させるためにNiは添加せず、その代わりに、CrとMoの含有量を従来のCr−Mo合金鋼の含有量より増して特性を補完した。
また、Cr含有量増加による表面異常層増加の問題は、Si含有量を下げることで克服し、Mo含有量増加によるMo炭化物析出問題は、Moより炭化物形成親和度の高いNbの含有量を通常より多くして克服した。
また、CrとMo含有量増加の結果である強度向上による加工性低下は、Sの含有量を害のない範囲で増加させることにより改善した。
In the high-strength Cr-Mo alloy steel for transmission gears according to the present invention, Ni is not added in order to improve workability. Instead, the content of Cr and Mo is changed to the content of conventional Cr-Mo alloy steel. More characteristic complemented.
Moreover, the problem of the surface abnormal layer increase due to the Cr content increase is overcome by lowering the Si content, and the Mo carbide precipitation problem due to the Mo content increase is usually caused by the Nb content having a higher carbide forming affinity than Mo. Overcame with more.
Moreover, the workability fall by the strength improvement which is a result of the Cr and Mo content increase was improved by increasing S content in the harmless range.

以下、本発明の主要構成元素についてさらに詳細に説明する。
表1は、本発明によるCr−Mo合金鋼の成分と、従来のCr−Mo合金鋼及びNi−Cr−Mo合金鋼の成分とを比較して示したものである。
Hereinafter, the main constituent elements of the present invention will be described in more detail.
Table 1 shows a comparison of the components of the Cr-Mo alloy steel according to the present invention and the components of the conventional Cr-Mo alloy steel and Ni-Cr-Mo alloy steel.

Figure 2005120466
Figure 2005120466

本発明のCr−Mo合金鋼には、加工性向上及びコストダウンの点からNiを添加せず、Cは、物性と焼入性を考慮して0.17〜0.21重量%添加する。
Si含有量は、合金鋼100重量%に対し、0.15重量%以下として浸炭時発生する表面異常層を低減させた。
その理由は、本発明では、特性向上のために表面異常層を生じやすいCrの含有量を、従来のCr−Mo合金鋼に比べ増やしたため、Siが0.15重量%を超える場合は、表面異常層の過剰生成による悪影響が現れるためである。
Ni is not added to the Cr—Mo alloy steel of the present invention from the viewpoint of improving workability and reducing costs, and C is added in an amount of 0.17 to 0.21% by weight in consideration of physical properties and hardenability.
The Si content was set to 0.15% by weight or less with respect to 100% by weight of the alloy steel to reduce the surface abnormal layer generated during carburizing.
The reason for this is that, in the present invention, the content of Cr, which is likely to cause a surface abnormal layer to improve the characteristics, is increased as compared with the conventional Cr-Mo alloy steel. This is because an adverse effect due to excessive formation of the abnormal layer appears.

Cr含有量は、合金鋼100重量%に対し、1.25〜1.45重量%としたが、これはCr含有量が1.25重量%未満の場合、従来のCr−Mo合金鋼の特性と近いものとなり特性向上がみられないためである。
また、Cr含有量が1.45重量%を超える場合は、コストアップとなるほか、浸炭時、表面の浸炭層にCr炭化物(またはCr−Mo系炭化物)が析出し、脆性が強くなるとともに、Siの含有量を0.15重量%以下に制限したにもかかわらず、表面異常層の厚さが15μm以上になるためである。
The Cr content was set to 1.25 to 1.45% by weight with respect to 100% by weight of the alloy steel. When the Cr content is less than 1.25% by weight, the characteristics of the conventional Cr—Mo alloy steel are obtained. This is because the characteristics are not improved.
In addition, when the Cr content exceeds 1.45% by weight, the cost increases, and when carburizing, Cr carbide (or Cr-Mo carbide) is precipitated on the carburized layer on the surface, and the brittleness becomes strong. This is because the thickness of the surface abnormal layer becomes 15 μm or more despite the Si content being limited to 0.15 wt% or less.

Moは、合金鋼100重量%に対し、従来のCr−Mo合金鋼より多い0.55〜0.65重量%を含有する。その含有量が0.55重量%未満の場合はCrの場合と同様に、従来のCr−Mo合金鋼の特性と比べ、改善効果があまり大きくないため、Ni−Cr−Mo合金鋼を代替するほどの改善効果がない。
Mo含有量が0.65重量%を超える場合、Moより炭化物形成親和度の高いNbの含量を既存より多くしたにもかかわらず、浸炭層にCr−Mo系炭化物が粒界に析出するだけではなく、粒界の周りに微細なクラックが生じて、脆性が大きくなる問題が発生する。
Mo contains 0.55-0.65 weight% more than the conventional Cr-Mo alloy steel with respect to 100 weight% of alloy steel. When the content is less than 0.55% by weight, the improvement effect is not so large compared with the characteristics of the conventional Cr-Mo alloy steel, as in the case of Cr. Therefore, the Ni-Cr-Mo alloy steel is substituted. There is no improvement effect.
When the Mo content exceeds 0.65% by weight, the Cr-Mo based carbide is not precipitated at the grain boundaries in the carburized layer, although the content of Nb having a higher carbide forming affinity than Mo is increased compared to the existing content. However, there is a problem in that fine cracks are generated around the grain boundaries and brittleness is increased.

Sは、加工性の低下を改善するために、害のない範囲内で、従来のCr−Mo合金鋼に比べ、含有量の上限を0.03重量%に上げた。
また、高温浸炭時、結晶粒の粗大化を防止し、結晶粒の微細化効果を最大にするために、Nbを0.015〜0.035重量%添加した。
Nbは、合金鋼内で微細なNb窒化物及び炭化物を作って結晶粒の粗大化を抑える元素であって、その含有量が0.015重量%未満であると効果があまり大きくなく、0.035重量%を超えると、炭化物が結晶粒界に過剰析出して脆性が大きくなる問題がある。
本発明のCr−Mo合金鋼では、従来のCr−Mo合金鋼に比べNb含有量の上限値を上げたが、これは、MoやCrの含量増加によるMo炭化物やCr炭化物の形成を防ぐためである。
また、鋼の不純物の含量を減らし清浄度を向上させるために、溶存酸素量を15ppm以下に抑えた。
In order to improve the decrease in workability, S increases the upper limit of the content to 0.03% by weight within a harmless range as compared with the conventional Cr—Mo alloy steel.
In addition, Nb was added in an amount of 0.015 to 0.035% by weight in order to prevent coarsening of crystal grains and maximize the effect of crystal grain refinement during high temperature carburization.
Nb is an element that forms fine Nb nitrides and carbides in the alloy steel and suppresses the coarsening of crystal grains. If its content is less than 0.015% by weight, the effect is not so great. If it exceeds 035% by weight, there is a problem that carbides are excessively precipitated at the grain boundaries to increase brittleness.
In the Cr-Mo alloy steel of the present invention, the upper limit of the Nb content is increased compared to the conventional Cr-Mo alloy steel, but this is to prevent the formation of Mo carbides and Cr carbides due to an increase in the Mo and Cr contents. It is.
Further, in order to reduce the content of impurities in the steel and improve the cleanliness, the amount of dissolved oxygen was suppressed to 15 ppm or less.

以下、実施例を通じて本発明をさらに詳細に説明するが、本発明はこれに限定されるものではない。
本発明の実施例及び比較例の合金成分は、次の表2に示した通りであって、通常の方法により合金鋼を製造した。
表2において、実施例は本発明の合金鋼であり、比較例1〜4は合金含量による特性の影響を分析するために製造した合金鋼であって、比較例5〜7は、従来に量産及び適用中の合金鋼である。
Hereinafter, the present invention will be described in more detail through examples, but the present invention is not limited thereto.
The alloy components of Examples and Comparative Examples of the present invention are as shown in Table 2 below, and alloy steels were produced by ordinary methods.
In Table 2, Examples are alloy steels of the present invention, Comparative Examples 1 to 4 are alloy steels manufactured to analyze the influence of properties due to alloy content, and Comparative Examples 5 to 7 are mass produced in the past. And alloy steel in application.

Figure 2005120466
Figure 2005120466

試験例
表2の実施例及び比較例について変速機用歯車に必要な基本物性を実験し比較した。
表3及び表4、図2はその結果を示したものである。表3は、浸炭熱処理後の疲労特性及び衝撃特性の試験結果を示したものである。
表4は、歯車の製造時に重要な因子である加工性を比較した結果であって、手動変速機用特定歯車のシェービング(shaving)加工時の加工ツール(tool)1個当たりの歯車加工数量を示す。
加工性試験は、本発明の鋼の実施例及び従来の鋼の比較例5〜6に対して行った。
Test Example The basic physical properties necessary for a transmission gear were tested and compared for the examples and comparative examples in Table 2.
Tables 3 and 4 and FIG. 2 show the results. Table 3 shows the test results of fatigue characteristics and impact characteristics after carburizing heat treatment.
Table 4 shows the results of a comparison of processability, which is an important factor when manufacturing gears, and shows the number of gears processed per tool when a specific gear for a manual transmission is shaved. Show.
The workability test was performed on the steel examples of the present invention and the conventional steel comparative examples 5-6.

図2は、本発明の鋼の実施例と、現在ヨーロッパのメーカーで高強度用素材として適用されている従来鋼の比較例7について、歯車状態における疲労特性を試験して比較した結果である。   FIG. 2 is a result of comparing the fatigue characteristics in the gear state by comparing the steel example of the present invention and the comparative example 7 of the conventional steel currently used as a high-strength material by European manufacturers.

Figure 2005120466
Figure 2005120466

Figure 2005120466
Figure 2005120466

表3から分かるように、本発明実施例の鋼は、Niが添加されていないにもかかわらず、従来のCr−Mo系合金鋼である比較例5より著しく優れた特性を示し、また、従来のNi−Cr−Mo系合金鋼である比較例6、7との比較では同等以上の特性を示した。   As can be seen from Table 3, the steels of the examples of the present invention exhibited significantly superior characteristics compared to the comparative example 5 which is a conventional Cr-Mo alloy steel, even though Ni was not added. In comparison with Comparative Examples 6 and 7 which are Ni-Cr-Mo alloy steels, the same or better characteristics were shown.

CrとMoの含有量を調整して比較した結果を要約すると、両合金元素の含有量が本発明の含有量の範囲を超えた場合(比較例1と比較例3)、焼入性が高くなるだけではなく、浸炭された表面硬化層にCr−Mo系炭化物が粒界に多量析出して脆性が大きくなる短所があった(衝撃値低下)。
反面、本発明の含有量より少ない場合は、疲労関連特性が著しく劣ることが分かった。
Summarizing the results of adjusting and comparing the contents of Cr and Mo, when the contents of both alloy elements exceed the content range of the present invention (Comparative Example 1 and Comparative Example 3), the hardenability is high. In addition, the carburized hardened layer has a disadvantage that a large amount of Cr-Mo carbide precipitates at the grain boundaries and the brittleness increases (impact value reduction).
On the other hand, when the content is less than the content of the present invention, it has been found that the fatigue-related characteristics are remarkably inferior.

また、Nbを添加した場合の結晶粒の大きさは、Nb添加による微細化効果により、Nbを添加していない場合(比較例5)に比べ、全ての点で優れており、また、Nbの添加により高温浸炭が可能になって、熱処理サイクルタイムを短縮することもできると予想される。
加工性も、本発明の実施例が、従来のNi−Cr−Mo系合金鋼である比較例6に比べ著しく向上(約33%)したが、これは、Sの含有量を増加させることにより、強度向上による加工性の低下を改善したからである。
In addition, the size of the crystal grains when Nb is added is superior in all respects compared to the case where Nb is not added (Comparative Example 5) due to the refinement effect due to the addition of Nb. Addition makes it possible to perform high-temperature carburization and shorten the heat treatment cycle time.
The workability was also significantly improved (about 33%) in the example of the present invention as compared with Comparative Example 6 which is a conventional Ni—Cr—Mo alloy steel. This is because the S content is increased. This is because the deterioration of workability due to the strength improvement was improved.

自動車の変速機用歯車の製造工程を示す製造工程図である。It is a manufacturing process figure which shows the manufacturing process of the gearwheel for transmissions of a motor vehicle. 歯車の曲げ疲労試験の結果を示すグラフである。It is a graph which shows the result of the bending fatigue test of a gearwheel.

Claims (1)

Feを主成分として、0.17〜0.21重量%のCと、0.15重量%以下のSiと、0.60〜0.85重量%のMnと、0.02重量%以下のPと、0.03重量%以下のSと、1.25〜1.45重量%のCrと、0.55〜0.65重量%のMoと、0.015〜0.035重量%のNbとを含有する合金系成分で、溶存酸素量を15ppm以下にすることを特徴とする変速機歯車用高強度Cr−Mo合金鋼。   With Fe as the main component, 0.17 to 0.21 wt% C, 0.15 wt% or less Si, 0.60 to 0.85 wt% Mn, and 0.02 wt% or less P 0.03% by weight or less of S, 1.25 to 1.45% by weight of Cr, 0.55 to 0.65% by weight of Mo, 0.015 to 0.035% by weight of Nb, A high-strength Cr-Mo alloy steel for transmission gears, characterized in that the dissolved oxygen content is 15 ppm or less.
JP2004254064A 2003-09-30 2004-09-01 HIGH STRENGTH Cr-Mo ALLOY STEEL FOR SPEED CHANGE GEAR Pending JP2005120466A (en)

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CN100532615C (en) * 2007-12-18 2009-08-26 本钢板材股份有限公司 Vehicle wheel steel smelting method
US8696314B2 (en) * 2010-06-15 2014-04-15 General Electric Company Gear set, wind turbine incorporating such a gear set and method of servicing a wind turbine
EP2800642B1 (en) 2012-01-05 2020-07-01 Höganäs AB (publ) New metal powder and use thereof
KR101685486B1 (en) * 2015-04-14 2016-12-13 현대자동차주식회사 Carburizing alloy steel improved durability and the method of manufacturing the same
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