JP2005076007A - Method of thermally decomposing medical waste including chlorine-containing plastic and thermal decomposition apparatus - Google Patents
Method of thermally decomposing medical waste including chlorine-containing plastic and thermal decomposition apparatus Download PDFInfo
- Publication number
- JP2005076007A JP2005076007A JP2003311521A JP2003311521A JP2005076007A JP 2005076007 A JP2005076007 A JP 2005076007A JP 2003311521 A JP2003311521 A JP 2003311521A JP 2003311521 A JP2003311521 A JP 2003311521A JP 2005076007 A JP2005076007 A JP 2005076007A
- Authority
- JP
- Japan
- Prior art keywords
- thermal decomposition
- waste
- medical waste
- heating container
- gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000005979 thermal decomposition reaction Methods 0.000 title claims abstract description 45
- 229920003023 plastic Polymers 0.000 title claims abstract description 36
- 239000004033 plastic Substances 0.000 title claims abstract description 36
- 239000002906 medical waste Substances 0.000 title claims abstract description 31
- 238000000034 method Methods 0.000 title claims abstract description 31
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 title claims abstract description 28
- 239000000460 chlorine Substances 0.000 title claims abstract description 28
- 229910052801 chlorine Inorganic materials 0.000 title claims abstract description 28
- 239000007789 gas Substances 0.000 claims abstract description 108
- 238000010438 heat treatment Methods 0.000 claims abstract description 57
- 239000002699 waste material Substances 0.000 claims abstract description 50
- 238000006386 neutralization reaction Methods 0.000 claims abstract description 30
- 230000006835 compression Effects 0.000 claims abstract description 12
- 238000007906 compression Methods 0.000 claims abstract description 12
- 239000001301 oxygen Substances 0.000 claims abstract description 10
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 10
- 230000005484 gravity Effects 0.000 claims abstract description 8
- 238000000197 pyrolysis Methods 0.000 claims description 64
- 239000000126 substance Substances 0.000 claims description 19
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 16
- 230000002378 acidificating effect Effects 0.000 claims description 16
- 238000002485 combustion reaction Methods 0.000 claims description 16
- 238000000502 dialysis Methods 0.000 claims description 16
- 229910000041 hydrogen chloride Inorganic materials 0.000 claims description 16
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims description 16
- 238000004140 cleaning Methods 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 5
- 238000007790 scraping Methods 0.000 claims description 3
- 230000001954 sterilising effect Effects 0.000 abstract description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 38
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 27
- 239000003513 alkali Substances 0.000 description 19
- 239000011269 tar Substances 0.000 description 17
- 238000005406 washing Methods 0.000 description 15
- 230000001877 deodorizing effect Effects 0.000 description 10
- 239000004071 soot Substances 0.000 description 10
- 239000002253 acid Substances 0.000 description 9
- 238000009835 boiling Methods 0.000 description 9
- 239000003921 oil Substances 0.000 description 9
- 235000011121 sodium hydroxide Nutrition 0.000 description 9
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 8
- KVGZZAHHUNAVKZ-UHFFFAOYSA-N 1,4-Dioxin Chemical compound O1C=COC=C1 KVGZZAHHUNAVKZ-UHFFFAOYSA-N 0.000 description 7
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- 238000004332 deodorization Methods 0.000 description 6
- 239000010781 infectious medical waste Substances 0.000 description 5
- 210000003734 kidney Anatomy 0.000 description 5
- 230000003472 neutralizing effect Effects 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 239000008346 aqueous phase Substances 0.000 description 4
- 239000008280 blood Substances 0.000 description 4
- 210000004369 blood Anatomy 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- 239000001294 propane Substances 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 238000001784 detoxification Methods 0.000 description 3
- 150000002013 dioxins Chemical class 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000004659 sterilization and disinfection Methods 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 230000006837 decompression Effects 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 229910052602 gypsum Inorganic materials 0.000 description 2
- 239000010440 gypsum Substances 0.000 description 2
- 230000007257 malfunction Effects 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000010979 pH adjustment Methods 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 239000002918 waste heat Substances 0.000 description 2
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 210000001124 body fluid Anatomy 0.000 description 1
- 239000010839 body fluid Substances 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000009841 combustion method Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000011038 discontinuous diafiltration by volume reduction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 230000002458 infectious effect Effects 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 239000010808 liquid waste Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- -1 polyethylene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 230000008685 targeting Effects 0.000 description 1
- 239000010833 unregulated medical waste Substances 0.000 description 1
Images
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
Abstract
Description
本発明は、腎透析セットの廃棄物等の塩素含有プラスチックを含む比較的少量の医療廃棄物(感染性廃棄物も含む)の熱分解法およびそのための装置に関する。 The present invention relates to a method for thermally decomposing a relatively small amount of medical waste (including infectious waste) containing chlorine-containing plastic such as waste from a renal dialysis set and an apparatus therefor.
医療廃棄物のうちでも腎透析セットの廃棄物は、血液等の体液を含むために感染性である可能性が高いうえ、材質中に塩化ビニル樹脂を多く含むため、最も処理が困難な廃棄物の一つである。
しかし、従来から、腎透析セットの廃棄物は塩化水素ガスやダイオキシンの発生という問題がありながら焼却処分されてきたのが実情である。焼却処理の場合でも排ガス中の塩化水素ガスを中和し、燃焼温度を高くしてダイオキシンの量を減少させることは技術的には可能で、実際に大型の焼却炉では実施されるようになってきた。
ところが、特に感染性廃棄物を大型の焼却炉で処理する場合、該焼却炉まで搬送する時の危険性や該焼却炉が故障して大量の廃棄物が感染性廃棄物によって汚染された場合の危険性等を考えれば、感染性廃棄物が発生した場所で、小規模に処理することが望ましい。
Among the medical waste, the kidney dialysis set waste is most difficult to treat because it contains a lot of body fluid such as blood and is highly infectious and contains a lot of vinyl chloride resin in the material. one of.
However, it has been the case that the waste from the renal dialysis set has been disposed of by incineration, despite the problem of hydrogen chloride gas and dioxin generation. Even in the incineration process, it is technically possible to neutralize the hydrogen chloride gas in the exhaust gas and raise the combustion temperature to reduce the amount of dioxin, and in practice it is now practiced in large incinerators. I came.
However, especially when infectious waste is processed in a large incinerator, there are dangers when it is transported to the incinerator or when the incinerator fails and a large amount of waste is contaminated by infectious waste. Considering the dangers, it is desirable to process on a small scale where infectious waste is generated.
このような事情のため、排ガス中の塩化水素ガスを中和処理できる小型焼却炉の開発も試みられているが、大量の排ガスを処理する必要があるため、価格的に問題があり、市場に受け入れられるには至っていない。また、バッチ的に操業する焼却炉の場合、燃焼が安定している状態でのダイオキシン発生量はある程度抑制することは可能であるが、操業開始時と終了時に燃焼が不安定になると大量のダイオキシンを発生するという問題がある。 For these reasons, attempts have been made to develop a small incinerator that can neutralize hydrogen chloride gas in the exhaust gas. It has not been accepted. In addition, incinerators that operate in batches can reduce the amount of dioxin generated in a state where combustion is stable, but if the combustion becomes unstable at the start and end of operation, a large amount of dioxin is generated. There is a problem of generating.
これに反し熱分解法の場合は、バッチ的な操業であっても、熱分解排ガスの高沸点成分を除去し、酸性ガスを中和した後の排ガスを完全燃焼させれば、操業開始から終了までのどの時点でも完全燃焼後の排ガス中に含まれるダイオキシンの量は極めて少量で問題がないという利点がある。また、塩化ビニル樹脂を多く含む廃棄物を処理する場合、発生する熱分解排ガス中の塩化水素ガスを中和する際も、発生する排ガス量が少ないため装置が小さくて済むという利点もある。 On the other hand, in the case of the pyrolysis method, even if it is a batch operation, if the high boiling point component of the pyrolysis exhaust gas is removed and the exhaust gas after neutralizing the acid gas is completely burned, the operation ends from the start of operation. There is an advantage that the amount of dioxin contained in the exhaust gas after complete combustion is extremely small at any point in time, and there is no problem. In addition, when treating waste containing a large amount of vinyl chloride resin, there is an advantage that the apparatus can be made small because the amount of generated exhaust gas is small when neutralizing hydrogen chloride gas in the generated pyrolysis exhaust gas.
ただし熱分解法は、熱分解に要するエネルギーを外部から供給する必要があることと、熱分解の速度が燃焼に比べて遅いため、コストパフォーマンスにおいて燃焼法に劣るという欠点があり、そのために普及が遅れていた。
この欠点を解消するために廃棄物を圧縮した後に熱分解する方法は既に試みられている。しかし、これらの方法は連続押出装置による炭化方式あるいはトンネル炉加熱方式によるものであり、装置が大掛かりになる(特許文献1、2)。
また、感染性廃棄物には圧縮不能の金属製品や石膏製品を含むことがあるため、実際に適用するにはかなりの制約があると考えられる。
However, the thermal decomposition method has the disadvantages that it is necessary to supply the energy required for the thermal decomposition from the outside, and the thermal decomposition rate is slower than the combustion, so that it is inferior to the combustion method in terms of cost performance. It was late.
In order to solve this drawback, a method of thermally decomposing the waste after compressing the waste has already been tried. However, these methods are based on a carbonization system using a continuous extrusion apparatus or a tunnel furnace heating system, and the apparatus becomes large (Patent Documents 1 and 2).
Also, infectious waste may contain incompressible metal products and gypsum products, so there may be considerable limitations in practical application.
さらに、熱分解法では、熱分解炉から熱分解生成ガスを排出する配管(排ガス管)の閉塞という問題を生じることがある。これを防止するために排ガス管を加熱する方策が知られているが、塩化ビニル樹脂の可塑剤由来生成物である無水フタル酸の析出防止には効果が期待できるものの、タールや煤の固着に対しては十分な効果は期待できない。 Furthermore, in the pyrolysis method, there may be a problem that a pipe (exhaust gas pipe) for discharging the pyrolysis product gas from the pyrolysis furnace is blocked. In order to prevent this, a method of heating the exhaust gas pipe is known, but although it can be expected to prevent precipitation of phthalic anhydride, which is a plasticizer-derived product of vinyl chloride resin, it can prevent tar and soot from sticking. However, it cannot be expected to have a sufficient effect.
また、熱分解により発生する塩化水素等を含む酸性ガスを中和するには、炭酸カルシウム等の水不溶性アルカリを中和槽に過剰に投入して中和するか、苛性ソーダ等の水溶性アルカリを過剰に投入しておき、処理終了後に処理液のpHを改めて微調整する等、中和を確実なものとするためにアルカリを過剰に投入しがちであった。しかしながら、過剰になった不溶性アルカリ懸濁液は放置により沈降するので、これもまた配管の閉塞等の原因となり問題であった。苛性ソーダ水溶液を用いてのpH自動調整も考えられるが、中和時にはタール等の油分が混入していることからpHセンサーの故障や誤作動の恐れがあり、pH自動調整装置の維持管理が困難である。 In addition, in order to neutralize acidic gas containing hydrogen chloride generated by thermal decomposition, water-insoluble alkali such as calcium carbonate is excessively added to the neutralization tank for neutralization, or water-soluble alkali such as caustic soda is added. In order to ensure neutralization, such as adding excessively and finely adjusting the pH of the treatment liquid again after completion of the treatment, the alkali tends to be excessively added. However, since the excess insoluble alkali suspension settles upon standing, this also causes a blockage of the piping and the like, which is a problem. Although automatic pH adjustment using caustic soda aqueous solution is also possible, since oil such as tar is mixed during neutralization, there is a risk of malfunction of the pH sensor and malfunction, making it difficult to maintain and manage the automatic pH adjustment device. is there.
本発明は上記の問題点を解決するためになされたものであり、本発明の目的は、塩素含有プラスチックを含む比較的少量の医療廃棄物を連続的にではなく、バッチ毎に処理して、しかも環境を汚すことなく減容、減量、殺菌(無害化)するための効率的、かつ、操業性に優れた熱分解方法およびそのためのコンパクトな熱分解装置を提供することである。 The present invention has been made to solve the above problems, and the object of the present invention is to treat a relatively small amount of medical waste containing chlorine-containing plastics batch by batch rather than continuously, Moreover, it is an object of the present invention to provide an efficient and efficient thermal decomposition method for reducing the volume, reducing the weight, and sterilizing (detoxifying) without polluting the environment, and a compact thermal decomposition apparatus therefor.
本発明者らは、上記目的を達成すべく種々検討した結果、嵩高な塩素含有プラスチックを含む腎透析廃棄物(通常、廃棄物用袋に入れられた状態での嵩比重は0.09kg/リットル程度)を加熱容器に投入し、加熱容器内で簡易な圧縮装置によってある一定の割合まで常温で圧縮することで、操業者が危険な物質の飛散に曝される危険性を冒すことなく、バッチあたりの処理量を増大できると同時に、熱効率を向上させることができることを見いだした。なお、一般の医療廃棄物を加熱時に圧縮するのは、医療廃棄物中に混入している金属製品や石膏製品等のため装置の破損を招くことがあるため、実際上は難しい。
また、塩素含有プラスチックの含有量が予知できる医療用廃棄物を対象とすることにより、熱分解排ガス中の酸性ガスの中和に要するアルカリの量も予知できることから、熱分解装置の管理が容易になることも分かった。これらの知見に基づいて本発明を完成させるに至った。
As a result of various studies to achieve the above object, the present inventors have found that renal dialysis waste containing bulky chlorine-containing plastic (usually the bulk specific gravity in a waste bag is 0.09 kg / liter). Batch) without incurring the risk of operators being exposed to splashes of dangerous substances by putting them into a heating vessel and compressing them at room temperature to a certain percentage with a simple compression device in the heating vessel. It has been found that the heat treatment efficiency can be improved at the same time that the per-unit throughput can be increased. Note that it is actually difficult to compress general medical waste when heated, because the device may be damaged due to metal products, gypsum products, and the like mixed in the medical waste.
In addition, by targeting medical waste that can predict the content of chlorine-containing plastics, it is possible to predict the amount of alkali required to neutralize the acidic gas in the pyrolysis exhaust gas. I found out that The present invention has been completed based on these findings.
かかる本発明によれば、塩素含有プラスチックを含む医療用廃棄物を加熱容器中で無酸素あるいは低酸素状態でバッチ式に熱分解するに際し、加熱容器に投入された該廃棄物を、加熱容器内に設置した圧縮装置により、常温で、投入当初の嵩比重の1.5〜3.0倍に圧縮した後に熱分解させ、熱分解生成ガスを加熱容器外に吸引して中和および燃焼処理することを特徴とする塩素含有プラスチックを含む医療用廃棄物の熱分解方法が提供される。
また、本発明によれば、塩素含有プラスチックを含む医療用廃棄物を無酸素あるいは低酸素状態で熱分解する、外部加熱によって該廃棄物を熱分解させることが可能で、開閉可能な該廃棄物投入口と熱分解生成ガス排出口を有する加熱容器および該加熱容器の該排出口とガス排出管で連結された熱分解生成ガス処理装置とから構成される装置において、該加熱容器には該廃棄物を常温で圧縮することが可能な圧縮装置が設けられ、該熱分解生成ガス処理装置は該ガス洗浄装置および熱分解生成ガス燃焼装置からなることを特徴とする塩素含有プラスチックを含む医療用廃棄物の熱分解装置が提供される。
According to the present invention, when the medical waste containing chlorine-containing plastic is thermally decomposed batchwise in an oxygen-free or low-oxygen state in the heating container, the waste charged in the heating container is stored in the heating container. Compressed at 1.5 to 3.0 times the bulk specific gravity at the beginning of charging with a compression device installed in the chamber and then pyrolyzed, and the pyrolysis product gas is sucked out of the heating container to neutralize and burn it. A method for thermally decomposing medical waste containing a chlorine-containing plastic is provided.
In addition, according to the present invention, medical waste containing chlorine-containing plastic can be thermally decomposed in an oxygen-free or low-oxygen state, the waste can be thermally decomposed by external heating, and the waste that can be opened and closed An apparatus comprising: a heating container having a charging port and a pyrolysis product gas discharge port; and a pyrolysis product gas processing device connected by the discharge port of the heating container and a gas discharge pipe. A medical device including a chlorine-containing plastic, characterized in that a compression device capable of compressing an object at room temperature is provided, and the pyrolysis product gas treatment device comprises the gas cleaning device and the pyrolysis product gas combustion device An object pyrolysis apparatus is provided.
本発明によれば、環境を汚染する物質の発生が極めて少なく、減容、減量、殺菌(無害化)が可能で、効率的、かつ、操業性に優れた塩素含有プラスチックを含む医療用廃棄物の熱分解方法および熱分解装置が提供される。 According to the present invention, medical waste containing a chlorine-containing plastic that is extremely low in volume, volume, and sterilization (detoxification), is efficient, and has excellent operability. A thermal decomposition method and a thermal decomposition apparatus are provided.
腎透析廃棄物のように塩化ビニル樹脂等の塩素含有プラスチックを含む廃棄物をバッチ毎に少量処理して、ダイオキシンの発生量をできるだけ少なくするためには、焼却方式ではなく熱分解方式により熱分解後、発生する酸性排ガスを中和し、中和後の排ガスを完全燃焼させる方式が有効である。
このような熱分解方式は、例えば、特開平11−270822号公報等により既に知られている。既知の熱分解方式は、減圧熱分解方式をとっているものが多いが、これは発生した酸性排ガスを中和し、高沸点成分を凝縮除去するための排ガス処理装置に圧損が生じるため、ブロワーや真空ポンプ等で吸引しないと加熱容器(以下では熱分解炉ということがある。)が加圧状態になって未処理の熱分解排ガスが漏れ出す危険があり、これを回避するために減圧下で行なっている。例えば、小型装置であって、熱分解炉や中和装置の密封が容易であれば減圧は必須条件ではない。
In order to reduce the amount of dioxins generated as much as possible by processing a small amount of waste containing chlorine-containing plastics such as vinyl chloride resin, such as renal dialysis waste, thermal decomposition is not performed by incineration but by thermal decomposition. Thereafter, it is effective to neutralize the generated acidic exhaust gas and completely burn the exhaust gas after neutralization.
Such a thermal decomposition method is already known, for example, from JP-A-11-270822. Many of the known thermal decomposition methods employ a reduced pressure pyrolysis method, but this causes neutralization of the generated acidic exhaust gas and pressure loss occurs in the exhaust gas treatment device for condensing and removing the high boiling point components. If not sucked with a vacuum pump, etc., there is a risk that the heating vessel (hereinafter sometimes referred to as a pyrolysis furnace) will be pressurized and the untreated pyrolysis exhaust gas will leak out. It is done in. For example, if it is a small apparatus and a thermal decomposition furnace or a neutralization apparatus can be easily sealed, decompression is not an essential condition.
本発明の塩素含有プラスチックを含む医療廃棄物の加熱分解処理は、上記のような公知の熱分解方法を用いるが、該医療用廃棄物を、熱分解炉内で、その内に設置された圧縮装置で所定の割合まで圧縮した後に加熱分解することが特徴である。
該医療用廃棄物は、熱分解炉の処理能力および熱分解効率を高めるために、熱分解炉投入当初の嵩比重の1.5〜3.0倍、好ましくは1.5〜2.5倍、より好ましくは1.5〜2.0倍の嵩比重となるように、常温で圧縮することが好ましい。このように圧縮して、熱分解炉の容積のほぼ90%まで充填して熱分解を行なうことで処理能力を著しく向上させることができる。また、熱分解はバッチ式である。
The thermal decomposition treatment of the medical waste containing the chlorine-containing plastic according to the present invention uses the known thermal decomposition method as described above, and the medical waste is compressed in the thermal decomposition furnace. It is characterized in that it is thermally decomposed after being compressed to a predetermined ratio by an apparatus.
The medical waste is 1.5 to 3.0 times, preferably 1.5 to 2.5 times the bulk specific gravity at the beginning of the pyrolysis furnace, in order to increase the treatment capacity and pyrolysis efficiency of the pyrolysis furnace. It is preferable to compress at room temperature so that the bulk specific gravity is more preferably 1.5 to 2.0 times. By compressing in this way and filling up to approximately 90% of the volume of the pyrolysis furnace and carrying out pyrolysis, the processing capacity can be significantly improved. Thermal decomposition is a batch type.
熱分解は、無酸素状態または低酸素状態(塩素含有プラスチックが熱分解してダイオキシンを生成しない濃度)で、該医療用廃棄物を、例えば、250〜550℃に加熱して行う。熱分解生成ガスは熱分解炉から排出され、排ガス中の酸性ガス(塩化水素)は水洗、中和によって除去され、高沸点成分のタール分は凝縮除去される。これらの成分が除去された後の排ガスは燃焼処理される。
塩素含有プラスチックを含む医療廃棄物は、このような熱分解によって無害化(殺菌)と同時に減容されるが、その際問題となる量のダイオキシンは生成しない。
Thermal decomposition is performed by heating the medical waste to, for example, 250 to 550 ° C. in an oxygen-free state or a low-oxygen state (a concentration at which the chlorine-containing plastic is not thermally decomposed to produce dioxins). The pyrolysis product gas is discharged from the pyrolysis furnace, the acidic gas (hydrogen chloride) in the exhaust gas is removed by washing and neutralization, and the tar content of the high boiling point component is condensed and removed. The exhaust gas after these components are removed is subjected to combustion treatment.
Although medical waste containing chlorine-containing plastics is reduced in volume at the same time as detoxification (sterilization) by such thermal decomposition, a problematic amount of dioxin is not generated.
本発明においては、熱分解させる塩素含有プラスチックを含む医療廃棄物を、例えば、腎透析関連廃棄物等の特定な医療用廃棄物に限定することで、廃棄物中の塩素含有プラスチックの含有量が予知可能となり、その結果、該廃棄物の熱分解によって生成する酸性ガス量が予知できることから、中和槽で使用するアルカリの量も予知可能となる。従って、一定量の該医療廃棄物を熱分解する際に、バッチ毎に予知量の酸性がスを中和するのに必要な量のアルカリを予め中和槽に添加しておくだけで中和が行われ、過剰にアルカリを使用する必要もなく、中和層のpHを逐次測定し、アルカリでpHを調整する必要もなく、中和操作が極めて容易となる利点がある。 In the present invention, the medical waste containing chlorine-containing plastic to be thermally decomposed is limited to a specific medical waste such as renal dialysis-related waste, so that the content of chlorine-containing plastic in the waste is reduced. As a result, the amount of acid gas generated by thermal decomposition of the waste can be predicted, and therefore the amount of alkali used in the neutralization tank can also be predicted. Therefore, when thermally decomposing a certain amount of medical waste, the amount of alkali required for neutralizing the amount of acid required for each batch is neutralized by adding in advance to the neutralization tank. There is no need to use an alkali excessively, there is no need to sequentially measure the pH of the neutralization layer, and there is no need to adjust the pH with an alkali, and there is an advantage that the neutralization operation becomes extremely easy.
本発明の熱分解に使用する熱分解炉は、開・密閉可能な投入口と熱分解生成ガスの排出口を備えている必要がある。熱分解炉および配管(熱分解生成ガス(排ガス)排出管)等は、材質的には最大500℃前後の高温で酸性ガスと接触、排ガスを処理するため、ある程度以上の耐熱性と耐蝕性が必要である。例えば、材質としてはステンレス等が挙げられるが、上記の要件を満たす限りは材質は特に限定されない。 The pyrolysis furnace used for the pyrolysis of the present invention needs to be provided with an inlet that can be opened and sealed and an outlet for the pyrolysis product gas. Pyrolysis furnaces and pipes (pyrolysis product gas (exhaust gas) discharge pipes) are in contact with acid gas at high temperatures of up to around 500 ° C and treat exhaust gas, so they have a certain level of heat resistance and corrosion resistance. is necessary. For example, the material may be stainless steel or the like, but the material is not particularly limited as long as the above requirements are satisfied.
熱分解は、通常、排出口を除いて熱分解炉を密閉した状態で外部から加熱して行うが、加熱した窒素等の不活性ガスを炉内に吹き込んで加熱することも可能である。要はダイオキシンの発生を防止するため、加熱に際し熱分解炉内を低酸素または無酸素の状態に保つことである。 Pyrolysis is usually performed by heating from outside with the pyrolysis furnace sealed except for the discharge port, but it is also possible to heat by heating an inert gas such as heated nitrogen into the furnace. The point is to keep the inside of the pyrolysis furnace in a low oxygen or oxygen-free state during heating in order to prevent the generation of dioxins.
塩素化プラスチックを含む廃棄物の熱分解によって発生する排ガス中には、通常、水蒸気の他に塩化水素のような酸性物質や、タール等の油分をはじめとした有機化合物、煤等が含まれている。
排ガス中のタールや煤は、熱分解炉の排出管内に次第に蓄積して、熱分解炉の圧力上昇を招いたり、排出管内を閉塞するという重大なトラブルを招くことがある。本発明者らは、バッチ処理毎の熱分解炉の減圧度から排出管内の汚れを推定し、運転開始前に排出管を解体して清掃を実施していたが、排出管内に簡易な掻取り装置を設けることを鋭意工夫した結果、時間をかけることなく排出管内の汚れを除去でき、汚れの蓄積を防止できることを確認した。掻取り装置は、排出管内に付着、蓄積したタール分が容易に掻き出されるものであれば特に限定されず、例えば、排出管内を前後に動かすことができる棒状の柄の先端に排出管の内径よりは小さい径を有する帯状円環を取り付けた掻取り棒等が挙げられる。
Exhaust gas generated by thermal decomposition of waste containing chlorinated plastic usually contains acidic substances such as hydrogen chloride, organic compounds such as oil such as tar, soot, etc. in addition to water vapor. Yes.
Tar and soot in the exhaust gas may gradually accumulate in the exhaust pipe of the pyrolysis furnace, leading to a serious increase in the pressure of the pyrolysis furnace or clogging the exhaust pipe. The present inventors estimated the dirt in the discharge pipe from the degree of decompression of the pyrolysis furnace for each batch processing, and dismantled the discharge pipe and started cleaning before the start of operation. As a result of diligently providing the device, it was confirmed that dirt in the discharge pipe could be removed without taking time and accumulation of dirt could be prevented. The scraping device is not particularly limited as long as the tar attached and accumulated in the discharge pipe can be easily scraped off. For example, the inner diameter of the discharge pipe is attached to the tip of a rod-shaped handle that can be moved back and forth in the discharge pipe. A scraping rod to which a belt-like ring having a smaller diameter is attached may be mentioned.
一方、酸性物質(ガス)を中和して除去する際の問題点は、いかにして中和が完了したかを知ることである。この問題は、炭酸カルシウムのように水不溶性のアルカリ性物質を中和当量以上懸濁させた水相と酸性ガスを含む排ガスとを接触させて中和することにより回避できるが、過剰の炭酸カルシウムが沈降するという新たな問題を生ずる。 On the other hand, a problem in neutralizing and removing acidic substances (gas) is knowing how neutralization is completed. This problem can be avoided by bringing a water phase in which a water-insoluble alkaline substance such as calcium carbonate is suspended in a neutralization equivalent or more into contact with an exhaust gas containing acidic gas to neutralize it. This creates a new problem of settling.
また、苛性ソーダのような水溶性のアルカリを使用する場合は、アルカリが沈降するという問題はおきないが、正確に中和当量のアルカリを投入することが困難であり、過剰に投入しておいて熱分解終了後に水相のpHを測定して中和点からずれている場合(酸性側にある場合)はアルカリを添加して修正するか、熱分解処理中に中和槽のpH監視をしながらアルカリを逐次投入することが必要である。この際、pHメータの維持管理も必要である。 In addition, when using a water-soluble alkali such as caustic soda, there is no problem that the alkali settles, but it is difficult to accurately add a neutralization equivalent of alkali. If the pH of the aqueous phase is deviated from the neutralization point after completion of pyrolysis (if it is on the acidic side), correct by adding alkali, or monitor the pH of the neutralization tank during the pyrolysis process. However, it is necessary to sequentially add alkali. At this time, maintenance of the pH meter is also necessary.
本発明者らは特定な医療用廃棄物として、例えば腎透析セット廃棄物を処理する場合には、医療現場から腎透析セット廃棄物を回収する際の該廃棄物入り袋の大きさ(容量)または重量と、袋の数を規定して熱分解炉に投入することにより、発生する塩化水素等の中和当量に該当する量の苛性ソーダ等の投入が可能ではないかと考え、実験により可能であることを確認し、本発明に至った。この方法では、pHメータの管理に手間をかけることもpHの微調整も必要がない。 When treating the kidney dialysis set waste as a specific medical waste, for example, the inventors of the present invention have the size (capacity) of the waste bag when collecting the kidney dialysis set waste from the medical site. It is possible to experiment by considering that it is possible to add caustic soda in an amount corresponding to the neutralization equivalent of generated hydrogen chloride, etc. by specifying the weight and the number of bags into the pyrolysis furnace The present invention was confirmed. In this method, there is no need for time-consuming management of the pH meter and fine adjustment of the pH.
酸性物質を除去した熱分解排ガス中には、低沸点から高沸点の有機物やさらには煤が含まれているが、該排ガスを、熱分解排ガス中の可燃性ガス量が少ない場合にも安定的に燃焼できるように加熱用熱源を備えた熱分解ガス燃焼炉(消臭炉)に直接送り込んで、完全燃焼させて炭酸ガスと水蒸気にすることで脱臭および除去が可能である。 Pyrolysis exhaust gas from which acidic substances have been removed contains organic substances and soot from low to high boiling points, but the exhaust gas is stable even when the amount of combustible gas in the pyrolysis exhaust gas is small. It can be deodorized and removed by directly sending it to a pyrolysis gas combustion furnace (deodorization furnace) equipped with a heating heat source so that it can be combusted and completely burning it into carbon dioxide gas and water vapor.
酸性物質を含む排ガスの中和工程で水相に移行した高沸点成分や煤よりなる油は、油水分離後、液状廃棄物として処理することも、装置の廃熱を利用して固形化して減量することも可能である。
また、熱分解を減圧状態で実施する場合は、装置の一部、例えば洗浄装置(洗浄塔)を水封することにより、装置を簡素化することが可能である。
Oils consisting of high-boiling components and soot that have migrated to the aqueous phase in the neutralization process of exhaust gas containing acidic substances can be treated as liquid waste after oil-water separation, or solidified using the waste heat of the equipment and reduced in weight. It is also possible to do.
In the case where the thermal decomposition is performed in a reduced pressure state, it is possible to simplify the apparatus by sealing a part of the apparatus, for example, a cleaning apparatus (cleaning tower).
本発明において使用される消臭炉は、熱分解開始当初に排出される可燃ガス成分の含有量が少ない段階の排ガスの高温燃焼を十分可能とする発熱量を有する加熱熱源を備えているのが好ましい。
もし排ガス中の可燃ガス成分を高温で完全燃焼できなければ、消臭炉から出る排ガスには臭気が残り、ダイオキシンの含有量も高くなる可能性がある。一方消臭炉の容積の割りに発熱量が多すぎると消臭炉の開口部より火炎があがることがある。
加熱熱源として使用できるのは、重油、灯油等の液体燃料、あるいは都市ガス、プロパンガス、天然ガス等の気体燃料の燃焼によって得られる熱源あるいは電熱等である。熱分解触媒を使用することも可能である。
The deodorizing furnace used in the present invention includes a heating heat source having a calorific value that sufficiently enables high-temperature combustion of exhaust gas at a stage where the content of combustible gas components discharged at the beginning of thermal decomposition is small. preferable.
If the combustible gas component in the exhaust gas cannot be burned completely at a high temperature, the exhaust gas from the deodorizing furnace may have odor and the dioxin content may be high. On the other hand, if the amount of heat generated is too large for the volume of the deodorizing furnace, a flame may be generated from the opening of the deodorizing furnace.
A heat source that can be used as a heating heat source is a heat source or electric heat obtained by combustion of liquid fuel such as heavy oil or kerosene, or gaseous fuel such as city gas, propane gas, or natural gas. It is also possible to use a pyrolysis catalyst.
次に本発明の熱分解装置について図面を参照して説明する。
本発明の熱分解装置は、図1に1例を示すように、塩素含有プラスチックを含む医療用廃棄物を熱分解させる加熱容器(熱分解炉)と、それから排出される熱分解生成ガス(排ガス)の処理装置とからなる。該処理装置は排ガス中に含まれる酸性ガスを中和し、高沸点成分(タール分)を凝縮させるための排ガス洗浄装置(洗浄塔と中和槽から構成される)および酸性ガスと高沸点成分が除去された後の低沸点ガス成分(臭気源となる)を含む排ガスを燃焼させて消臭する排ガス燃焼装置(消臭炉)とから構成される。
Next, the thermal decomposition apparatus of this invention is demonstrated with reference to drawings.
As shown in FIG. 1, an example of the pyrolysis apparatus of the present invention is a heating container (pyrolysis furnace) for thermally decomposing medical waste containing chlorine-containing plastic, and a pyrolysis product gas (exhaust gas) discharged therefrom. ). The treatment apparatus neutralizes the acid gas contained in the exhaust gas and condenses the high boiling point component (tar content), and the exhaust gas cleaning device (consisting of a cleaning tower and a neutralization tank) and the acid gas and the high boiling point component It is comprised from the exhaust gas combustion apparatus (deodorization furnace) which deodorizes by burning the exhaust gas containing the low boiling-point gas component (it becomes an odor source) after removing.
加熱容器(熱分解炉)は、側面上部には開・密閉可能な投入口を設けた金属製またはセラミックス製の容器で、上方部に排ガスを排出する排出口を有している。該排出口は熱分解生成ガスを排出して排ガス処理装置に導入する排ガス管で該処理装置の洗浄塔と連結されている。加熱容器の形状は特に限定されないが、例えば、断面は円または四角形である。加熱容器は、外部加熱が一般的であることから、外部加熱可能に形成される。熱源は前記のとおりである。 The heating container (pyrolysis furnace) is a metal or ceramic container provided with an opening that can be opened and sealed at the upper part of the side surface, and has a discharge port for discharging exhaust gas at the upper part. The exhaust port is an exhaust gas pipe that exhausts the pyrolysis product gas and introduces it into the exhaust gas processing apparatus, and is connected to the cleaning tower of the processing apparatus. Although the shape of a heating container is not specifically limited, For example, a cross section is a circle or a rectangle. Since the external heating is common, the heating container is formed to be externally heated. The heat source is as described above.
本発明では熱分解炉内に、投入口より投入された廃棄物を圧縮するための簡易圧縮機が設けられていることが特徴で、廃棄物を所定の圧縮率に圧縮して、加熱容器の容積のほぼ90%まで廃棄物を充填して熱分解する。圧縮機は公知の圧縮機が使用でき、特に限定されない。
通常ポリエチレン製袋に入れられた廃棄物は加熱容器の投入口より投入される。投入された廃棄物がほぼ加熱容器を満たした状態で、投入口を密封して圧縮した後に加熱容器の加熱を開始する。このとき、湿式により排ガスを洗浄して酸性物質を除去する場合は、熱分解開始時に加熱容器内部の酸素濃度をできるだけ下げるためと、排ガスが投入口等から漏れることを防止するために、加熱容器内を水柱でマイナス20〜200ミリ程度の減圧とすることが好ましい。過度の減圧は装置の変形や空気の漏れ込みを招くので好ましくない。
The present invention is characterized in that a simple compressor is provided in the pyrolysis furnace for compressing the waste charged from the charging port, and the waste is compressed to a predetermined compression rate, Fill with waste to approximately 90% of volume and pyrolyze. A known compressor can be used as the compressor and is not particularly limited.
The waste usually put in a polyethylene bag is put in from the inlet of the heating container. In a state where the charged waste almost fills the heating container, the heating container is started to be heated after the charging port is sealed and compressed. At this time, when removing the acidic substance by washing the exhaust gas by wet, in order to reduce the oxygen concentration inside the heating container as much as possible at the start of thermal decomposition and to prevent the exhaust gas from leaking from the inlet, etc. It is preferable to make the inside into a reduced pressure of about minus 20 to 200 mm with a water column. Excessive pressure reduction is not preferable because it causes deformation of the apparatus and air leakage.
加熱の方法は、電熱、ガス状あるいは液状の燃料を熱源として利用することができ、熱分解炉内温が250〜550℃となるように加熱することが好ましく、さらに好ましくは300〜500℃である。250℃未満では熱分解が不十分であり、550℃を超えると熱分解ガス発生量が多くなって熱分解装置の運転が困難となる。 As the heating method, electric heat, gaseous or liquid fuel can be used as a heat source, and heating is preferably performed so that the temperature in the pyrolysis furnace is 250 to 550 ° C, more preferably 300 to 500 ° C. is there. If it is less than 250 ° C., thermal decomposition is insufficient, and if it exceeds 550 ° C., the amount of pyrolysis gas generated increases, making it difficult to operate the pyrolysis apparatus.
加熱により発生する熱分解ガスはブロワー(BL)により吸引され、排ガス管を通って排ガス洗浄装置に入る。排ガス中に塩化水素ガス等の酸性ガスが含まれる場合には、排ガスを水で洗浄し、水に溶け込んだ酸性物質を後でアルカリ性物質と接触させることで中和することも可能であるが、酸性ガス処理量に見合う所定量のアルカリ性物質を溶解あるいは懸濁させた水と接触させて中和することがより好ましい。この時使用できるアルカリ性物質は水酸化ナトリウム、水酸化カリウム、水酸化カルシウム、炭酸ナトリウム等である。この場合には、洗浄装置は洗浄塔とそれに水、アルカリ水またはアルカリ懸濁水を供給する水槽または中和槽とから構成され、洗浄塔の底部は、水槽または中和槽の水で水封することもできる。洗浄水は、例えば、アルカリ水を使用する場合には、中和槽からポンプ(P)で洗浄塔の塔頂へ供給される。水あるいはアルカリ水(アルカリ懸濁水も含む)による洗浄方式は、濡れ壁塔方式、シャワー方式、充填塔方式等の公知の方式がいずれも使用でき、特に限定されない。 Pyrolysis gas generated by heating is sucked by a blower (BL) and enters an exhaust gas cleaning device through an exhaust gas pipe. If the exhaust gas contains an acid gas such as hydrogen chloride gas, it is possible to wash the exhaust gas with water and neutralize the acid substance dissolved in the water by contacting it later with an alkaline substance. It is more preferable to neutralize by bringing a predetermined amount of an alkaline substance commensurate with the amount of acid gas into contact with water in which it has been dissolved or suspended. Alkaline substances that can be used at this time are sodium hydroxide, potassium hydroxide, calcium hydroxide, sodium carbonate and the like. In this case, the washing apparatus is composed of a washing tower and a water tank or neutralization tank for supplying water, alkaline water or alkali suspension water thereto, and the bottom of the washing tower is sealed with water from the water tank or neutralization tank. You can also. For example, when alkaline water is used, the washing water is supplied from the neutralization tank to the top of the washing tower by a pump (P). The washing method using water or alkaline water (including alkali suspension water) can be any known method such as a wet wall tower method, a shower method, or a packed tower method, and is not particularly limited.
水洗浄によって排ガス中に含まれるプラスチック熱分解成分のうちで沸点の比較的高い物質からなるタールや同じく熱分解時に発生する煤もタールに分散した状態で捕捉されて水相に移る。水相に移行したタールは、タール受け槽に集められる。煤を多く含むタールは放置すると沈降する可能性があるため、タール受け槽の堰のところにカゴ等を設けて捕捉することもできる。
集めたタールとタールに分散した煤は、別途廃棄物として処理することもできるが、消臭炉の廃熱を利用して蒸発乾固させ、加熱容器の熱分解残渣と共に処理し、蒸発した成分は消臭炉で焼却することにより、著しく減量することも可能である。
Tars consisting of substances having a relatively high boiling point among the plastic pyrolysis components contained in the exhaust gas by water washing and soot generated during pyrolysis are also captured in a dispersed state in the tar and transferred to the aqueous phase. Tar transferred to the aqueous phase is collected in a tar receiving tank. Since tar containing a large amount of soot may settle if left untreated, it can be captured by providing a basket or the like at the weir of the tar receiving tank.
The collected tar and soot dispersed in tar can be treated separately as waste, but it is evaporated to dryness using the waste heat of the deodorization furnace, treated with the pyrolysis residue of the heating container, and evaporated components Can be significantly reduced by incineration in a deodorizing furnace.
水洗浄装置で排ガス中に含まれる酸性物質と比較的高い沸点を有する物質が除かれた後の排ガスは、ブロワー(BL)を通過して、消臭炉に吹き込まれ、ここで、例えば、バーナー(B)により完全燃焼させる。熱源は前記のとおりである。 The exhaust gas after the acidic substance contained in the exhaust gas and the substance having a relatively high boiling point are removed by the water washing apparatus passes through the blower (BL) and is blown into the deodorizing furnace, where, for example, a burner Complete combustion by (B). The heat source is as described above.
<実施例>
図1に示す熱分解装置を用い、未使用の腎透析セットを常温で圧縮することにより72kgを処理する場合(実施例)と、圧縮しないで36kg処理する場合(対照例)を比較した。
腎透析セットは血液の透析を行なうダイアライザー約450g、軟質塩化ビニル樹脂製のチューブとアクセサリー(アタッチメント)約300gおよび針からなっているが、針が金属製の場合は処理困難であるため予め切り離して別途処理を行う。実際に医療現場から排出される腎透析セットは、ダイアライザーの内部の水が血液に置換され該チューブにも血液が付着しているが、熱分解性は未使用品と大差ないと思われる。
<Example>
The case of treating 72 kg by compressing an unused renal dialysis set at room temperature using the pyrolysis apparatus shown in FIG. 1 (Example) and the case of treating 36 kg without compression (control example) were compared.
The renal dialysis set consists of approximately 450 g of dialyzer for dialysis of blood, approximately 300 g of a soft vinyl chloride resin tube and accessory (attachment), and a needle. Separate processing is performed. In the renal dialysis set that is actually discharged from the medical field, the water inside the dialyzer is replaced with blood, and the blood also adheres to the tube, but the thermal decomposability seems not to be much different from that of an unused product.
処理に使用する加熱容器は、内容積400リットルのステンレス製円筒型容器で、側面上部には開閉可能な投入口が設けられている。
腎透析廃棄物の投入は、ポリ袋に入れられた腎透析セットを投入口から投入し、加熱容器が満杯になった時点で投入口の扉を一旦閉じて、加熱容器上部に設けられた圧縮装置を作動させ、加熱容器内部に設けられたプレス板を下降させ廃棄物を圧縮する。プレス板は圧縮物が一定の抵抗を示す時点で停止するので、プレス板を再び上昇させる。プレス板を上昇させても圧縮された廃棄物は、そのままで戻りはない。再び廃棄物入りポリ袋を投入して同様の操作を繰り返し、加熱容器が圧縮された廃棄物で満杯になるまで繰り返す。この加熱容器の場合、圧縮により満杯に投入された廃棄物の量は72kgであり、その時の嵩比重は0.18kg/リットルであった。また圧縮することなく満杯に投入された廃棄物の量は36kgで、その嵩比重は0.09kg/リットルであった。
The heating container used for the treatment is a stainless steel cylindrical container having an internal volume of 400 liters, and an opening that can be opened and closed is provided at the upper part of the side surface.
To enter kidney dialysis waste, the kidney dialysis set in a plastic bag is inserted from the inlet, and when the heating container is full, the inlet door is closed once, and the compression provided at the top of the heating container The apparatus is operated, and the press plate provided inside the heating container is lowered to compress the waste. Since the press plate stops when the compressed material shows a certain resistance, the press plate is raised again. Even if the press plate is raised, the compressed waste remains as it is. The waste plastic bag is put in again and the same operation is repeated until the heating container is filled with the compressed waste. In the case of this heating container, the amount of waste charged to a full capacity by compression was 72 kg, and the bulk specific gravity at that time was 0.18 kg / liter. Further, the amount of waste charged without compression was 36 kg, and its bulk specific gravity was 0.09 kg / liter.
熱分解で発生する酸性物質の中和用アルカリ物質として、廃棄物72kg(ポリ袋で12袋)処理の場合は、該廃棄物中の塩化ビニル樹脂量から計算される塩化水素量を中和するに要する苛性ソーダ量は約10kgと計算されるので、この量の苛性ソーダを中和水槽に予め添加した。同様に、廃棄物36kg(ポリ袋で6袋)処理の場合は苛性ソーダを約5kg予め添加した。 In the case of waste 72kg (12 bags in a plastic bag) as an alkaline substance for neutralizing acidic substances generated by pyrolysis, the amount of hydrogen chloride calculated from the amount of vinyl chloride resin in the waste is neutralized. Since the amount of caustic soda required for this is calculated to be about 10 kg, this amount of caustic soda was added in advance to the neutralized water tank. Similarly, in the case of processing 36 kg of waste (6 bags in a plastic bag), ca. 5 kg of caustic soda was added in advance.
加熱容器は、プロパンガスバーナーで外部より加熱するが、加熱に先立ち、投入口を密閉した状態でブロワー(BL)を起動し、容器内部を水柱でマイナス50mmまで減圧する。
加熱容器内温の上昇にともない水分が蒸発し始め、200℃前後から塩化ビニル樹脂が分解して塩化水素ガスが発生し始める。300℃前後からは、含まれている各種プラスチックの熱分解が始まった。
加熱容器を内温が500℃となるまで上昇させて熱分解させたが、この温度に昇温させるに要する時間は72kgを処理する場合は2.0時間で、熱分解終了までの保持時間は8.0時間であった。一方、36kgを処理する場合には、それぞれ1.5時間、5.0時間であった。
The heating container is heated from the outside with a propane gas burner. Prior to heating, the blower (BL) is started with the inlet closed, and the inside of the container is depressurized to minus 50 mm with a water column.
As the internal temperature of the heating container rises, water begins to evaporate, and the vinyl chloride resin decomposes from around 200 ° C. and hydrogen chloride gas begins to be generated. From around 300 ° C., thermal decomposition of various plastics started.
The heating vessel was pyrolyzed by raising the internal temperature to 500 ° C., but the time required to raise the temperature to this temperature was 2.0 hours when treating 72 kg, and the holding time until the end of pyrolysis was It was 8.0 hours. On the other hand, when processing 36 kg, it was 1.5 hours and 5.0 hours, respectively.
加熱容器から排出された排ガスは水洗浄装置に入る。洗浄水には、発生する塩化水素と当量の水酸化ナトリウムを溶解してあるので、排ガス中の塩化水素は中和されて食塩の水溶液となる。
水洗浄装置は中和水槽に水封された流下水膜方式塔を三基、充填塔を一基使用している。
排ガス中に含まれる油(タール分)や煤等の熱分解生成物は洗浄により中和水槽に移り、浮上する油はタール受け槽に集められ、ポンプで油槽に送られる。中和水槽の水相は、廃棄物の熱分解処理終了後、油水分離槽に送られて油分を分離した後、放流される。
The exhaust gas discharged from the heating container enters the water washing device. Since sodium hydroxide equivalent to the generated hydrogen chloride is dissolved in the washing water, the hydrogen chloride in the exhaust gas is neutralized to become an aqueous solution of sodium chloride.
The water washing apparatus uses three falling water film type towers sealed in a neutralization water tank and one packed tower.
Thermal decomposition products such as oil (tar content) and soot contained in the exhaust gas are transferred to a neutralized water tank by washing, and the floating oil is collected in a tar receiving tank and sent to the oil tank by a pump. The water phase of the neutralized water tank is discharged after being sent to the oil / water separation tank after the thermal decomposition treatment of the waste and separating the oil.
水洗浄装置で塩化水素ガス、油および煤を除去した排ガスは、ブロワーを通して消臭炉に吹込まれる。水封に使用される中和水槽の大気開放部は臭気を発するので、大気開放部の気相をブロワーにより吸引し、同じく消臭炉に吹き込む。
消臭炉はセラミック断熱材で作られた燃焼室と加熱用熱源としてプロパンガスバーナーを備えており、熱分解が終了するまでガスバーナーは点火し続けた。
熱分解の間、消臭炉の内温は72kg処理する場合は900℃、36kg処理する場合は800℃まで上昇した。熱分解終了時の消臭炉内温は、72kg処理する場合は700℃、36kg処理する場合は650℃であった。何れの場合も消臭炉の燃焼排ガスは無臭であり、中和水槽の大気開放部気相も消臭炉で処理しているため、本装置周辺で臭気を感じることはなかった。
The exhaust gas from which hydrogen chloride gas, oil and soot have been removed by the water washing device is blown into a deodorizing furnace through a blower. Since the air release part of the neutralized water tank used for water sealing emits odor, the gas phase in the air release part is sucked by a blower and blown into the deodorization furnace.
The deodorizing furnace was equipped with a combustion chamber made of ceramic heat insulating material and a propane gas burner as a heat source for heating, and the gas burner continued to ignite until pyrolysis was completed.
During the pyrolysis, the internal temperature of the deodorizing furnace rose to 900 ° C. when treating 72 kg and to 800 ° C. when treating 36 kg. The temperature in the deodorizing furnace at the end of the thermal decomposition was 700 ° C. when treating 72 kg and 650 ° C. when treating 36 kg. In any case, the combustion exhaust gas from the deodorization furnace was odorless, and the gas phase in the atmosphere of the neutralized water tank was treated in the deodorization furnace, so that no odor was felt around the apparatus.
上記の熱分解で使用した電力量は、72kg処理する場合は5kwh、36kg処理する場合は3.25kwhで、またプロパンガス使用量は、それぞれ、8m3、5m3であった。
以上の結果を表1に示す。
Amount of power used in the thermal decomposition described above, when 72kg treatment 5 kWh, in 3.25kwh the case of 36kg process, also propane gas usage, respectively, were 8m 3, 5 m 3.
The results are shown in Table 1.
表1の単位処理質量当たりの比較から、本発明における廃棄物の圧縮処理の優位性は明らかである。
また、いずれの場合も、熱分解処理廃棄物として、廃棄物中の塩素含有プラスチックの含有量が予知できる腎透析セットを用いることで、熱分解で生成する塩化水素量を中和するに必要な量のアルカリを予め中和槽に添加することで、中和槽のpHを逐次測定し、アルカリ添加でpHの調整をしなくても、熱分解終了時のpHは7〜8の範囲に入っており、廃棄物の袋数または重量を規定して中和用アルカリを定量投入するという本発明の簡便操作性が確認された。
また、熱分解炉の排出口に接続された排ガス管を解体することなく、容易に管内の清掃ができることも確認された。
From the comparison per unit processing mass in Table 1, the superiority of the waste compression processing in the present invention is clear.
In either case, it is necessary to neutralize the amount of hydrogen chloride produced by pyrolysis by using a renal dialysis set that can predict the content of chlorine-containing plastic in the waste as pyrolysis waste. By adding an amount of alkali to the neutralization tank in advance, the pH of the neutralization tank is sequentially measured, and the pH at the end of thermal decomposition is in the range of 7-8 without adjusting the pH by adding alkali. Thus, the simple operability of the present invention was confirmed, in which the number of waste bags or the weight was regulated and the alkali for neutralization was quantitatively charged.
It was also confirmed that the inside of the pipe can be easily cleaned without disassembling the exhaust pipe connected to the outlet of the pyrolysis furnace.
本発明は塩素含有プラスチックを含む比較的少量の医療用廃棄物の、該廃棄物発生場所での殺菌(無害化)、減容に有用である。 The present invention is useful for sterilization (detoxification) and volume reduction of a relatively small amount of medical waste containing chlorine-containing plastics at the waste generation site.
B:バーナー
BL:ブロワー
Pu:ポンプ
T:温度計
B: Burner BL: Blower Pu: Pump T: Thermometer
Claims (5)
The thermal decomposition apparatus for medical waste containing chlorine-containing plastic according to claim 4, wherein a wall surface scraping device is installed in the gas discharge pipe.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2003311521A JP2005076007A (en) | 2003-09-03 | 2003-09-03 | Method of thermally decomposing medical waste including chlorine-containing plastic and thermal decomposition apparatus |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2003311521A JP2005076007A (en) | 2003-09-03 | 2003-09-03 | Method of thermally decomposing medical waste including chlorine-containing plastic and thermal decomposition apparatus |
Publications (1)
Publication Number | Publication Date |
---|---|
JP2005076007A true JP2005076007A (en) | 2005-03-24 |
Family
ID=34413070
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2003311521A Pending JP2005076007A (en) | 2003-09-03 | 2003-09-03 | Method of thermally decomposing medical waste including chlorine-containing plastic and thermal decomposition apparatus |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2005076007A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009270123A (en) * | 2006-04-19 | 2009-11-19 | Kusatsu Electric Co Ltd | Decomposition method of waste plastics and organic matter, decomposition device, and decomposition system |
JP2012096186A (en) * | 2010-11-04 | 2012-05-24 | Yuichi So | Treatment method of infectious waste and treatment apparatus thereof |
CN105003916A (en) * | 2015-05-08 | 2015-10-28 | 蒋子才 | Organic waste processing furnace |
-
2003
- 2003-09-03 JP JP2003311521A patent/JP2005076007A/en active Pending
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009270123A (en) * | 2006-04-19 | 2009-11-19 | Kusatsu Electric Co Ltd | Decomposition method of waste plastics and organic matter, decomposition device, and decomposition system |
JP2012096186A (en) * | 2010-11-04 | 2012-05-24 | Yuichi So | Treatment method of infectious waste and treatment apparatus thereof |
CN105003916A (en) * | 2015-05-08 | 2015-10-28 | 蒋子才 | Organic waste processing furnace |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
TWI356892B (en) | Method and apparatus for treating waste | |
US5302254A (en) | Process and plant for the thermolysis of industrial and/or urban waste | |
JPH09511945A (en) | Dangerous waste treatment equipment and treatment method | |
Yang et al. | Kinetics study on hydrothermal dechlorination of poly (vinyl chloride) by in-situ sampling | |
JP6022745B2 (en) | Waste disposal method | |
CN108826298A (en) | A kind of environment protection garbage incineration equipment | |
JP2005076007A (en) | Method of thermally decomposing medical waste including chlorine-containing plastic and thermal decomposition apparatus | |
WO2004023039A1 (en) | Method and apparatus for treating waste | |
JP2013043149A (en) | Waste treatment equipment | |
JPH08229533A (en) | Volume reduction treatment of waste | |
JP2003320359A (en) | Method and apparatus for pyrolyzing organic waste | |
JP5852491B2 (en) | Waste treatment system and treatment method | |
JP2013043150A (en) | Sludge treatment method and sludge treatment equipment | |
JP3065898B2 (en) | Method and apparatus for dehydrochlorination of industrial waste | |
JP2009051867A (en) | Method for treating medical treatment-based plastic waste or the like and apparatus for treating the same | |
JP4160065B2 (en) | Soil treatment equipment | |
JP2006336955A (en) | Method for treating medical waste and facility thereof | |
JPH10216465A (en) | Thermal decomposition of waste | |
JP2005007381A (en) | Waste treatment apparatus and treating method | |
JP5732278B2 (en) | Waste disposal method | |
JP2000225384A (en) | Method for separating heat-meltable plastic from waste, method for volume reducing treatment of waste, and apparatus for heat treatment of waste | |
JP2014037519A (en) | Infectious medical waste processing system | |
JPH10272439A (en) | Exhaust structure for industrial waste thermal decomposition furnace | |
JP3163336B2 (en) | Waste oil treatment method | |
CN114198756A (en) | Hazardous waste disposal method for setting incineration temperature and time according to classification |