JP2005058891A - Production method for functional water - Google Patents
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本発明は、海水、河川水、汚水の浄化をはじめとする水環境の改善作用(浄化促進作用)に優れた新規な機能水の製造方法に関する。 The present invention relates to a novel method for producing functional water that is excellent in water environment improvement action (purification promotion action) including purification of seawater, river water and sewage.
水の惑星と称される地球において、水の果たす役割は全ての生命にとって非常に大きい。しかし、近年の都市化の進行に伴う、海や河川や湖沼などの汚染は年々深刻化を増しており、水が生命に対して十分な役割を果たすことができなくなってきている。特に、都市部における港内や河口や河川や排水路などでは、生活排水や企業排水に含まれる微量有害物質のほか、田畑などから河川に流れ込んだ農薬などに起因して水質が悪化し、有機物が沈殿して堆積したヘドロ(汚泥)の腐敗によって発生する悪臭などが、付近住民の生活環境を脅かしている。また、微量有害物質の混濁などによる生態系への悪影響は、生物連鎖や食物連鎖を通して人間社会に無視することができない影響を及ぼしている。 On the earth, called the water planet, the role of water is enormous for all life. However, with the progress of urbanization in recent years, pollution of the sea, rivers, and lakes has become more serious every year, and water cannot play a sufficient role for life. Particularly in urban harbors, estuaries, rivers, and drainage channels, water quality deteriorates due to trace amounts of harmful substances contained in domestic wastewater and corporate wastewater, as well as pesticides that flow into rivers from fields and other fields. The bad smell generated by the rot of sludge deposited and deposited threatens the living environment of the local residents. In addition, adverse effects on ecosystems caused by turbidity of trace toxic substances have an effect that cannot be ignored in human society through the biological chain and food chain.
水環境の改善は現代に生きる我々に課された使命であるといっても過言ではない。従って、これまでにも水環境の改善を図るための様々な方法が提案され、実践に移されている。しかし、どの方法をとってみても必ずしも満足できるに足る成果をあげることができていないのが実情である。 It is no exaggeration to say that improvement of the water environment is a mission imposed on us living in the present age. Therefore, various methods for improving the water environment have been proposed and put into practice. However, the reality is that we have not been able to achieve satisfactory results regardless of the method used.
ところで、近年、被処理水を活性化する機能を有する機能水(活性水)が注目されており、様々な機能水の開発が行われている。また、その用途開発も盛んに行われており、例えば、下記の特許文献1においては、遠赤外線セラミックスを用いて調製した機能水を利用して河川や湖沼を浄化する方法が提案されている。しかし、この方法は、海水や河川水などのような大量の水の浄化には適用しがたいという問題がある。
そこで本発明は、海水、河川水、汚水の浄化をはじめとする水環境の改善作用(浄化促進作用)に優れた新規な機能水の製造方法を提供することを目的とする。 Then, this invention aims at providing the manufacturing method of the novel functional water excellent in the improvement effect (purification promotion effect | action) of water environments including purification | cleaning of seawater, river water, and sewage.
上記の点に鑑みてなされた本発明の機能水の製造方法は、請求項1記載の通り、ドロマイトと生石灰と天然ゼオライトの各粉砕物を水と混合攪拌することにより、ミネラル成分として少なくともマグネシウムとカルシウムとケイ素を水に溶出させてミネラル溶出液を調製した後、得られたミネラル溶出液を1200℃以上で焼成したセラミック粒の充填槽に導入して混合攪拌することを特徴とする。
また、本発明の機能水は、請求項2記載の通り、請求項1記載の製造方法にて製造されてなることを特徴とする。
また、本発明の水環境の改善方法は、請求項3記載の通り、請求項2記載の機能水を被処理水に滴下投入することを特徴とする。
The method for producing functional water of the present invention made in view of the above points, as described in claim 1, by mixing and stirring each pulverized product of dolomite, quicklime and natural zeolite with water, at least magnesium as a mineral component. A mineral eluate is prepared by eluting calcium and silicon into water, and the obtained mineral eluate is introduced into a ceramic particle filling tank fired at 1200 ° C. or higher and mixed and stirred.
Moreover, the functional water of this invention is manufactured by the manufacturing method of Claim 1 as described in Claim 2. It is characterized by the above-mentioned.
The water environment improving method of the present invention is characterized in that, as described in claim 3, functional water according to claim 2 is dropped into the water to be treated.
本発明によれば、海水、河川水、汚水の浄化をはじめとする水環境の改善作用(浄化促進作用)に優れた新規な機能水の製造方法が提供される。 ADVANTAGE OF THE INVENTION According to this invention, the manufacturing method of the novel functional water excellent in the improvement effect (purification promotion effect | action) of water environment including purification of seawater, river water, and sewage is provided.
本発明の機能水の製造方法においては、まず、ドロマイトと生石灰と天然ゼオライトの各粉砕物を水と混合攪拌することにより、ミネラル成分として少なくともマグネシウムとカルシウムとケイ素を水に溶出させてミネラル溶出液を調製する。 In the method for producing functional water of the present invention, first, each pulverized product of dolomite, quicklime, and natural zeolite is mixed with water and stirred to elute at least magnesium, calcium, and silicon as mineral components into the water. To prepare.
原料として用いるドロマイト(苦灰石・白雲石)は、炭酸マグネシウムを主成分とするものであればよい。生石灰は、酸化カルシウムを主成分とするものであればよい。天然ゼオライトとしては、例えば、化学組成がNa2Al2Si2O8・4.5H2Oで示されるものが挙げられる。 Dolomite (dolomite and dolomite) used as a raw material only needs to have magnesium carbonate as a main component. Quick lime should just be a thing which has calcium oxide as a main component. Examples of the natural zeolite include those having a chemical composition represented by Na 2 Al 2 Si 2 O 8 .4.5H 2 O.
ドロマイトと生石灰と天然ゼオライトは、各々できるだけ粉砕して、水と混合した際、これらに含まれるミネラル成分、具体的には、少なくとも、ドロマイトからはマグネシウム、生石灰からはカルシウム、天然ゼオライトからはケイ素が十分に水に溶出されるように用いることが望ましい。 When dolomite, quicklime and natural zeolite are pulverized as much as possible and mixed with water, they contain mineral components, specifically, at least magnesium from dolomite, calcium from quicklime, and silicon from natural zeolite. It is desirable to use it so that it is sufficiently eluted in water.
ドロマイトと生石灰と天然ゼオライトの各粉砕物は、ドロマイト1重量部に対し、生石灰0.7重量部〜1.3重量部、天然ゼオライト0.2重量部〜0.5重量部の重量比で用いることが望ましい。 Each pulverized product of dolomite, quicklime and natural zeolite is used in a weight ratio of 0.7 to 1.3 parts by weight of quicklime and 0.2 to 0.5 parts by weight of natural zeolite with respect to 1 part by weight of dolomite. It is desirable.
ミネラル成分として少なくともマグネシウムとカルシウムとケイ素を溶出させるための水はどのような水を用いてもよいが、地下水などのできるだけミネラル成分以外の塩素などの微量成分を含まない水を用いることが望ましい。水道水を用いる場合には塩素を十分に除去して用いるべきである。 Any water may be used for eluting at least magnesium, calcium, and silicon as mineral components, but it is desirable to use water that does not contain trace components such as chlorine other than mineral components as much as possible, such as groundwater. When tap water is used, chlorine should be removed sufficiently.
ドロマイトと生石灰と天然ゼオライトの粉砕物と水との混合攪拌は、例えば、1週間〜1月行うことが望ましい。攪拌混合を行った後は静置してその上澄み部分をミネラル溶出液として用いればよい。なお、ドロマイトと生石灰と天然ゼオライトの各粉砕物を水に投入する際は、生石灰の粉砕物は他の粉砕物を投入した後に少量ずつ投入することが望ましい。生石灰と水との急激な化学反応による水素ガスの大量発生を抑制するためである。 The mixing and stirring of dolomite, quicklime, pulverized natural zeolite, and water is preferably performed, for example, for one week to one month. After stirring and mixing, the mixture is allowed to stand and the supernatant can be used as a mineral eluate. When each pulverized product of dolomite, quicklime and natural zeolite is added to water, it is desirable to add the pulverized product of quicklime in small amounts after adding other pulverized products. This is for suppressing a large amount of hydrogen gas generated by a rapid chemical reaction between quicklime and water.
以上のようにして得られたミネラル成分として少なくともマグネシウムとカルシウムとケイ素を含むミネラル溶出液を1200℃以上で焼成したセラミック粒の充填槽に導入して混合攪拌する。 A mineral eluate containing at least magnesium, calcium and silicon as the mineral components obtained as described above is introduced into a ceramic particle filling tank fired at 1200 ° C. or higher and mixed and stirred.
1200℃以上で焼成したセラミック粒としては、珪素やアルミニウムの酸化物などを含む鉱石の粉末を球状に焼成した高密度多結晶体が挙げられる。 Examples of the ceramic particles fired at 1200 ° C. or higher include high-density polycrystals obtained by firing a powder of ore containing silicon or aluminum oxide into a spherical shape.
ミネラル成分として少なくともマグネシウムとカルシウムとケイ素を含むミネラル溶出液は、セラミック粒と混合攪拌されることで活性化され、機能水となる。ミネラル溶出液とセラミック粒との混合攪拌は、例えば、1週間〜1月行うことが望ましい。1度の混合攪拌でもミネラル溶出液の活性化は十分に行うことができるが、ミネラル溶出液をセラミック粒の充填層に循環導入することによって、セラミック粒と繰り返し混合攪拌することでより高活性化して機能水としてもよい。 A mineral eluate containing at least magnesium, calcium, and silicon as mineral components is activated by mixing and stirring with ceramic grains to become functional water. The mixing and stirring of the mineral eluate and the ceramic particles is desirably performed, for example, for one week to one month. The mineral eluate can be activated sufficiently even with one mixing and stirring. However, the mineral eluate is circulated and introduced into the packed bed of ceramic particles, so that it becomes more active by repeatedly mixing and stirring with the ceramic particles. And functional water.
このようにして製造される機能水は、pHが6〜8であり、普通の水よりもクラスターが小さいことや水素エネルギーの作用により優れた水環境の改善作用を示す。 The functional water produced in this manner has a pH of 6 to 8, and has a cluster effect smaller than that of normal water and an excellent water environment improvement effect due to the action of hydrogen energy.
この機能水の具体的な使用方法としては、次にようなものが挙げられる。
1.滴下投入法は、例えば、海水や河川水や放流水や鑑賞池や浄化装置中の水などの処理に適している。
2.噴霧法は、例えば、植物栽培現場や悪臭現場などにおける使用に適している。
3.洗浄法は、例えば、悪臭現場やビルの地下暗室などの洗浄水として使用することで効果を発揮する。
4.注入法は、例えば、港内底や河川底や湖沼底のヘドロの軟化分解や土壌改質などに適している。
5.循環法は、例えば、海水を吸い上げて処理槽の中で海水に機能水を投入し、浄化機能を有する海水を排出水として海に戻すといったような方法であり、大規模処理に適している。
The following are mentioned as a concrete usage method of this functional water.
1. The dripping method is suitable for, for example, processing of seawater, river water, effluent water, appreciation ponds, water in a purification device, and the like.
2. The spraying method is suitable for use in, for example, plant cultivation sites and odor sites.
3. The cleaning method is effective when used as cleaning water in, for example, a foul odor site or a building underground darkroom.
4). The injection method is suitable, for example, for softening and decomposing sludge on the bottom of harbors, rivers, and lakes, and soil improvement.
5). The circulation method is, for example, a method in which seawater is sucked up and functional water is poured into seawater in a treatment tank, and seawater having a purification function is returned to the sea as discharged water, and is suitable for large-scale treatment.
この機能水は、被処理水に対し、その性質を変化させて水のもつエネルギーを高めることで自己浄化作用を付与することができるほか、ヘドロに浸透してこれを効率よく軟化分解したり、塩素化合物を分解したりすることができる。また、好気性環境微生物の活動を活発化させたりすることで有機物の分解を促進し、悪臭の軽減などを図ることもできる。その結果として、この機能水は、水環境整備を行うに足る状況を作り出すことにより、総合的に水質を浄化することができる。機能水にミネラル成分として含まれるカルシウムは水質改善などに機能し、マグネシウムは土壌改質などに機能し、ケイ素は正常な生態系復元などに機能する。要約すると、この機能水は、酸性状態にある都市部における港内や河口や河川や排水路などを中性状態に戻し、生態系にとっての最適環境をもたらすことができ、水の惑星と称される地球本来の姿を我々が取り戻すために有益なものである。 This functional water can give its self-purifying action by changing its properties and increasing the energy of the water to be treated, penetrates into sludge and efficiently softens and decomposes it, It can decompose chlorine compounds. In addition, by promoting the activity of aerobic environmental microorganisms, it is possible to promote the decomposition of organic matter and reduce malodors. As a result, this functional water can comprehensively purify the water quality by creating a situation sufficient to improve the water environment. Calcium contained as a mineral component in functional water functions to improve water quality, magnesium functions to improve soil, etc., and silicon functions to restore normal ecosystems. In summary, this functional water is called an aquatic planet, which can return the neutrality of harbors, estuaries, rivers, drainage channels, etc., in urban areas that are in an acidic state, bringing an optimal environment for the ecosystem. It is useful for us to regain the original shape of the earth.
この機能水は、生体に対しても優れた作用を示す。具体的には、リゾチーム活性を有するので、膿粘液の分解や排出の容易化作用、抗リンパ作用による出血抑制作用、炎症時の組織修復過程の促進作用などが期待される。また、繊維芽細胞の増殖促進作用、創傷の治癒促進作用、結合織繊維の形成促進作用、抗炎症作用なども期待され、湿疹などの皮膚疾患に対する治療剤になりうる潜在性を有する。 This functional water exhibits an excellent effect on living bodies. Specifically, since it has lysozyme activity, it is expected to have an effect of facilitating the decomposition and excretion of pus mucus, an anti-hemorrhage-induced bleeding suppression effect, and an action of promoting tissue repair during inflammation. In addition, it is expected to have a fibroblast proliferation promoting effect, a wound healing promoting effect, a connective woven fiber formation promoting effect, an anti-inflammatory effect, and the like, and has the potential to be a therapeutic agent for skin diseases such as eczema.
以下、本発明を実施例により説明するが、本発明は以下の記載に基づいて限定して解釈されるものではない。 EXAMPLES Hereinafter, although an Example demonstrates this invention, this invention is limited and interpreted based on the following description.
(1)機能水の製造
ドロマイトと生石灰と天然ゼオライト(化学組成がNa2Al2Si2O8・4.5H2Oで示されるもの)の各粉砕物(重量比はドロマイト1:生石灰1:天然ゼオライト0.3)を水道水(塩素を十分に除去したもの)と3週間混合攪拌することにより、ミネラル成分として少なくともマグネシウムとカルシウムとケイ素を水に溶出させてミネラル溶出液を調製した。なお、ドロマイトと生石灰と天然ゼオライトの各粉砕物を水に投入する際は、生石灰の粉砕物は他の粉砕物を投入した後に少量ずつ投入することで、生石灰と水との急激な化学反応により水素ガスが大量発生しないようにした。
得られたミネラル溶出液を1200℃以上で焼成したセラミック粒の充填槽に導入して3週間混合攪拌することで機能水を製造した。
このようにして製造された機能水は、pHが7.8であり、マウスを用いた急性経口毒性試験と変異原性試験によってその高い安全性が確認された。また、この機能水について蛍光X線分析法による含有元素の定性試験を行ったところ、多量含有元素としてカルシウム、ケイ素、ナトリウム、イオウが、少量含有元素としてマグネシウムとカリウムが含まれていることがわかった。
(1) Production of functional water Dolomite, quicklime and natural zeolite (the chemical composition of which is represented by Na 2 Al 2 Si 2 O 8 · 4.5H 2 O) (weight ratio is dolomite 1: quick lime 1: A mineral eluate was prepared by mixing and stirring natural zeolite 0.3) with tap water (from which chlorine was sufficiently removed) for 3 weeks to elute at least magnesium, calcium and silicon as mineral components into water. In addition, when each pulverized product of dolomite, quicklime, and natural zeolite is added to water, a quick chemical reaction between quicklime and water can be performed by adding small amounts of quicklime pulverized product after adding other pulverized products. A large amount of hydrogen gas was prevented.
The obtained mineral eluate was introduced into a ceramic particle filling tank fired at 1200 ° C. or higher and mixed and stirred for 3 weeks to produce functional water.
The functional water produced in this way has a pH of 7.8, and its high safety was confirmed by an acute oral toxicity test and mutagenicity test using mice. In addition, when this functional water was subjected to a qualitative test of contained elements by fluorescent X-ray analysis, it was found that calcium, silicon, sodium, and sulfur were contained as a large amount of elements, and magnesium and potassium were contained as small amounts of elements. It was.
(2)機能水の河川浄化作用
(1)で製造した機能水の水環境の改善効果を、X県の都市河川であるY川(2級河川)にて許可を得て次のようにして調べた。即ち、塩分濃度が高い海水の干満に影響される区域(2キロメートル内)を実験区域とし、その最上流部地点に、河川流量や環境負荷量を勘案した設計量の機能水を1年間継続滴下投入することで、実験区域の経時変化を観察した。その結果、実験開始から約3ヶ月経過後より、実験区域において水質浄化効果や悪臭軽減効果が現れ始めたのと同時に、生態系の回帰が確認された(小魚の回遊や野鳥の飛来など)。なお、この実験結果は、X県のZ川において許可を得て行った同様の実験により再現性を確認することができた。
(2) Function water purification of functional water The effect of improving the water environment of the functional water produced in (1) is obtained with permission in the Y river (second-class river), which is the city river in X prefecture, as follows. Examined. In other words, an area (within 2 kilometers) that is affected by seawater tidality with high salinity is set as the experimental area, and functional water with a design amount that takes into account the river flow rate and environmental load is continuously dripped at the most upstream point for one year. The change over time in the experimental area was observed by the addition. As a result, after about 3 months from the start of the experiment, the water purification and odor mitigation effects began to appear in the experimental area, and at the same time, the return of the ecosystem was confirmed (such as the migration of small fish and the arrival of wild birds). In addition, reproducibility of this experimental result was able to be confirmed by the same experiment conducted with permission in the Z river of X prefecture.
本発明は、河川浄化、湖沼浄化、河口や漁港内などの海水干満水域の浄化、汚水処理場やごみ処理場における処理の効率化や処理環境の改善などに効果を有する新規な機能水の製造方法が提供される点において産業上の利用可能性を有する。 The present invention provides a novel functional water that is effective for purifying rivers, lakes and marshes, purifying seawater in the estuaries and fishing ports, improving the efficiency of treatment in sewage treatment plants and waste treatment plants, and improving the treatment environment. It has industrial applicability in that the method is provided.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010005530A (en) * | 2008-06-26 | 2010-01-14 | Osamu Hirota | Hydrogen-containing mineral water and its production method |
KR101020157B1 (en) | 2008-06-09 | 2011-03-08 | 제이엠바이오 주식회사 | Method and apparatus for producing alkali and high calcium mineral water from natural seawater |
KR101197685B1 (en) | 2009-09-11 | 2012-11-06 | 노경옥 | Composition for water purification comprising magnesiumoxide-containing mineral |
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2003
- 2003-08-11 JP JP2003291492A patent/JP2005058891A/en active Pending
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101020157B1 (en) | 2008-06-09 | 2011-03-08 | 제이엠바이오 주식회사 | Method and apparatus for producing alkali and high calcium mineral water from natural seawater |
JP2010005530A (en) * | 2008-06-26 | 2010-01-14 | Osamu Hirota | Hydrogen-containing mineral water and its production method |
KR101197685B1 (en) | 2009-09-11 | 2012-11-06 | 노경옥 | Composition for water purification comprising magnesiumoxide-containing mineral |
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