JP2004532914A5 - - Google Patents
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- JP2004532914A5 JP2004532914A5 JP2002578338A JP2002578338A JP2004532914A5 JP 2004532914 A5 JP2004532914 A5 JP 2004532914A5 JP 2002578338 A JP2002578338 A JP 2002578338A JP 2002578338 A JP2002578338 A JP 2002578338A JP 2004532914 A5 JP2004532914 A5 JP 2004532914A5
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- JP
- Japan
- Prior art keywords
- melamine
- paint
- flame retardant
- component
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003973 paint Substances 0.000 claims description 30
- 239000003063 flame retardant Substances 0.000 claims description 18
- XZTOTRSSGPPNTB-UHFFFAOYSA-N phosphono dihydrogen phosphate;1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(N)=N1.OP(O)(=O)OP(O)(O)=O XZTOTRSSGPPNTB-UHFFFAOYSA-N 0.000 claims description 12
- XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 claims description 12
- 239000011248 coating agent Substances 0.000 claims description 11
- 238000000576 coating method Methods 0.000 claims description 11
- 239000011230 binding agent Substances 0.000 claims description 9
- WXZMFSXDPGVJKK-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 5
- 229960001735 pentaerythritol Drugs 0.000 claims description 5
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N Melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K [O-]P([O-])([O-])=O Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000010452 phosphate Substances 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 3
- IUTYMBRQELGIRS-UHFFFAOYSA-N boric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OB(O)O.NC1=NC(N)=NC(N)=N1 IUTYMBRQELGIRS-UHFFFAOYSA-N 0.000 claims description 3
- 238000010000 carbonizing Methods 0.000 claims description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 3
- 239000011574 phosphorus Substances 0.000 claims description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims description 3
- 239000000945 filler Substances 0.000 claims description 2
- 230000000996 additive Effects 0.000 claims 2
- 150000007974 melamines Chemical class 0.000 claims 1
- 239000000843 powder Substances 0.000 description 7
- JDSHMPZPIAZGSV-UHFFFAOYSA-N Melamine Chemical group NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 5
- 229920000877 Melamine resin Polymers 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- ZRIUUUJAJJNDSS-UHFFFAOYSA-N Ammonium phosphates Chemical compound [NH4+].[NH4+].[NH4+].[O-]P([O-])([O-])=O ZRIUUUJAJJNDSS-UHFFFAOYSA-N 0.000 description 2
- 239000004114 Ammonium polyphosphate Substances 0.000 description 2
- 229920001276 Ammonium polyphosphate Polymers 0.000 description 2
- 235000019826 ammonium polyphosphate Nutrition 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 239000004922 lacquer Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 229920000180 Alkyd Polymers 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- 229960003563 Calcium Carbonate Drugs 0.000 description 1
- 210000003298 Dental Enamel Anatomy 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 229920000126 Latex Polymers 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000036760 body temperature Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000006103 coloring component Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000001627 detrimental Effects 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- -1 for example Substances 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000006011 modification reaction Methods 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Description
本発明は概して塗料に関するものである。 The present invention relates generally to paint.
塗料は、産業、家庭、及び現代生活の他の分野において広く知られ、利用されている。知られている塗料は、被膜の形成及び塗装する基体への接着を促す被膜形成結合剤成分を通常含有し、また、例えば顔料及び他の着色剤のような発色成分も含有している。 Paints are widely known and used in industry, home, and other areas of modern life. Known paints usually contain a film-forming binder component which promotes film formation and adhesion to the substrate to be coated, and also contains color-forming components such as, for example, pigments and other colorants.
既知の塗料は、環境の有害な作用から塗装する表面の一定の保護を提供し、塗装する表面に一定の色彩を与えるが、基体表面を火の影響から十分に保護しない。この不都合は除去したほうが望ましいだろう。 Known paints provide a certain protection of the painted surface from the detrimental effects of the environment and give the painted surface a certain color, but do not adequately protect the substrate surface from the effects of fire. It would be desirable to eliminate this disadvantage.
したがって、従来技術の不都合を回避する塗料を提供することが本発明の目的である。 Accordingly, it is an object of the present invention to provide a paint to avoid the disadvantages of the prior art.
これらの目的及び以下で明らかになる他の目的と調和して、本発明のひとつの特徴は、簡単に言えば、被膜形成結合剤成分、発色成分、及び塗装する表面を少なくとも実質的に火から保護するように適合させた難燃剤成分を有する塗料にある。 In line with these and other objects that will become apparent hereinafter, one feature of the present invention is, in brief, a film-forming binder component, a color former, and a surface to be painted that is at least substantially exposed to fire. A paint having a flame retardant component adapted to protect.
本発明に従い塗料を設計すれば、従来の塗料の特徴に加えて、本塗料は、塗装する基体表面を少なくとも実質的に火の影響から保護し、多くの場合に、腐食抵抗を増大させ、塗料の耐用年数を延長する。 By designing the paint according to the present invention, in addition to the features of conventional paints, the paints at least substantially protect the substrate surface to be coated from the effects of fire, often increase corrosion resistance, Extend the useful life of
本発明のさらなる特徴によれば、難燃剤成分は、ポリリン酸メラミン、ポリリン酸アンモニウム、二リン酸メラミン、ピロリン酸メラミン、及びリン酸メラミンなどの少なくともひとつのリン酸塩もしくはその誘導体を含有する。 According to a further feature of the invention, the flame retardant component comprises at least one phosphate or a derivative thereof, such as melamine polyphosphate, ammonium polyphosphate , melamine diphosphate, melamine pyrophosphate, and melamine phosphate.
本発明のさらなる特徴によれば、難燃剤成分は、メラミン、又はシアヌル酸メラミン、ホウ酸メラミン、ポリリン酸メラミン、二リン酸メラミン、ピロリン酸メラミン、及びリン酸メラミンからなる群より選択されるメラミン誘導体を含有する。 According to a further feature of the present invention, the flame retardant component is melamine or a melamine selected from the group consisting of melamine cyanurate, melamine borate, melamine polyphosphate, melamine diphosphate, melamine pyrophosphate, and melamine phosphate. containing emissions derivative conductor.
本発明のさらなる特徴によれば、難燃剤成分は、本発明の塗料の２０質量％、好ましくは１５質量％、を超えない。According to a further feature of the invention, the flame retardant component does not exceed 20%, preferably 15%, by weight of the paint of the invention.
また、本発明によれば、被膜形成結合剤成分を供給する工程、発色成分を供給する工程、いくつかの乾燥粉末成分以外の当該成分を混合する工程、及び前記乾燥粉末成分の代わりに難燃剤成分を添加する工程を有する塗料の製造方法を提案する。 Also, according to the present invention, a step of supplying a film-forming binder component, a step of supplying a coloring component, a step of mixing the components other than some dry powder components, and a flame retardant instead of the dry powder component A method for producing a paint having a step of adding components is proposed.
特に、添付する特許請求の範囲において、本発明の特色と考える新規な特徴を明らかにする。しかしながら、本発明の付加的な目的及び利点と共に、その構成及び実施方法に関して、本発明自体は以下の明確な実施例の説明から最もよく理解されるだろう。 In particular, the appended claims set forth the novel features which are considered characteristic of the present invention. However, the invention itself, together with its additional objects and advantages, as well as the structure and method of implementation, will be best understood from the following description of specific embodiments.
本発明によれば、被膜形成結合剤成分、発色成分、及び塗料を塗布する表面を火から少なくとも実質的に保護するように適合された難燃剤成分を含有する塗料を提供する。 According to the present invention, there is provided a paint containing a film-forming binder component, a color forming component, and a flame retardant component adapted to at least substantially protect the surface to which the paint is applied from fire.
難燃剤成分は、ポリリン酸メラミン、ポリリン酸アンモニウム、二リン酸メラミン、ピロリン酸メラミン、及びリン酸メラミンなどのリン酸塩もしくはその誘導体を含有することができる。 The flame retardant component can contain a phosphate such as melamine polyphosphate, ammonium polyphosphate , melamine diphosphate, melamine pyrophosphate, and melamine phosphate, or a derivative thereof.
また、難燃剤成分は、メラミン、又はシアヌル酸メラミン、ホウ酸メラミン、ポリリン酸メラミン、二リン酸メラミン、ピロリン酸メラミン、リン酸メラミンなどのメラミン誘導体を含有することができる。 Further, the flame retardant component can contain melamine or melamine cyanurate, boric acid melamine, melamine polyphosphate, diphosphate melamine, melamine pyrophosphate, and melamine emissions derivative conductor such as melamine phosphate.
本発明による塗料においては、難燃剤成分は、例えばペンタエリトリトール、モノペンタエリトリトール、ジペンタエリトリトールのようなペンタエリトリトール又はその誘導体の炭化剤、メラミンのような発泡剤、及び上記で明示した薬剤の群より選択される添加剤を含有することができる。 In the paint according to the invention, the flame retardant component is, for example, a group of the carbonizing agents of pentaerythritol or its derivatives such as pentaerythritol, monopentaerythritol and dipentaerythritol , blowing agents such as melamine, and the above-mentioned agents. More selected additives may be included.
耐久性、光沢、弾力性、接着、柔軟性、硬度に影響する塗料の主成分のひとつである被膜生成物質（結合材及び柔軟剤）に加えて、また、カラーバリエーションと表面着色特性を生ずるように結合剤に不溶で着色剤に可溶のカラーパウダーである顔料に加えて、塗料は、結合材料と共同して多くの場合に溶液もしくはいわゆるベースラッカー（ワニス）を生ずる揮発性成分も含有できることは言うまでもない。また、塗料の固有の特色を生ずる「補助」薬品も塗料に含有させることができる。 In addition to film-forming substances (binders and softeners), which are one of the main components of paints that affect durability, gloss, elasticity, adhesion, flexibility, and hardness, they also produce color variations and surface coloring properties. In addition to pigments, which are color powders which are insoluble in the binder and soluble in the colorant, the paints can also contain volatile components which, in cooperation with the binder, often form solutions or so-called base lacquers (varnishes). Needless to say. The coating may also contain "auxiliary" chemicals that produce the unique characteristics of the coating.
本発明による塗料は、被膜形成結合剤成分を供給する工程、発色成分を供給する工程、いくつかの乾燥粉末成分以外の前記成分を混合する工程、及び前記乾燥粉末成分に代わる難燃剤成分を加える工程を含む方法によって提供することができる。 The paint according to the invention comprises the steps of supplying a film-forming binder component, supplying a color-forming component, mixing said components other than some dry powder components, and adding a flame retardant component in place of said dry powder component The method can be provided by a method including a step.
特に、例えば炭酸カルシウム、二酸化チタンなどの充填剤の代わりに難燃剤成分を使用する。しかしながら、当然に少量の被膜生成成分を代用することもできる。 In particular, a flame retardant component is used instead of fillers such as, for example, calcium carbonate and titanium dioxide. However, it is of course possible to substitute small amounts of film-forming components.
また、本発明の塗料において、塗料中のリン含有量は、塗料の総質量の２．００質量％、好ましくは１．５質量％、を超えないことが好ましい。In the paint of the present invention, the phosphorus content in the paint preferably does not exceed 2.00% by mass, preferably 1.5% by mass of the total mass of the paint.
本発明による塗料を以下の実施例で例証する。 The coatings according to the invention are illustrated in the following examples.
エポキシ塗料−２成分 Epoxy paint-2 components
成分Ａと成分Ｂを４：１の体積比で混合する。 Components A and B are mixed in a 4: 1 volume ratio.
アルキドアンダーコート Alkyd undercoat
ウレタンエナメル Urethane enamel
剥離可能なビニルコーティング Peelable vinyl coating
ニトロセルロースサテンラッカー Nitrocellulose satin lacquer
つや消しラテックス塗料 Frosted latex paint
［製造方法］
上記サンプルは、コールズ（Ｃｏｗｌｅｓ）高速分散機で製造した。通常の塗料製造方法に従って、分散剤及び湿潤剤を含有する適量の展色剤中に粉末状の原料を高速分散させた。分散完了後、速度を落とし、展色剤の残余を残留成分と共に加えた。
[Production method]
The samples were made on a Cowles high speed disperser. The powdery raw material was dispersed at a high speed in an appropriate amount of a vehicle containing a dispersant and a wetting agent according to a usual paint production method. After dispersion was complete, the speed was reduced and the remainder of the vehicle was added along with the remaining components.
アクリル粉末コーティング Acrylic powder coating
焼き温度：１５０℃で２０分。 Baking temperature: 150 ° C for 20 minutes.
［製造方法］
Ｗ＆Ｐ ＺＳＫ−３０ミキサーを使用して粉末を混合及び調合した。
胴体温度：６０／８０℃
回転速度：２５０ｒｐｍ
等級：２００メッシュ通過１００％
[Production method]
The powder was mixed and blended using a W & P ZSK-30 mixer.
Body temperature: 60/80 ° C
Rotation speed: 250 rpm
Grade: 100% passing through 200 mesh
上記記載の各要素、もしくはその２つ以上の組み合わせが、上記記載の種類とは異なる他の種類の物質及び方法においても有効な応用となることは言うまでもないだろう。 It goes without saying that each element described above, or a combination of two or more thereof, is also an effective application in other kinds of substances and methods different from the above-mentioned kinds.
塗料及びその製造方法の実施により本発明を例示及び記載したが、本発明の意図からどのようにも外れることなく、様々な修正及び構成変更をすることができるので、本発明は記載した詳細に限定されるものではない。 Although the present invention has been illustrated and described by the practice of the paint and the method for producing the same, various modifications and changes can be made without departing from the spirit of the present invention. It is not limited.
さらなる分析がなくても、前述は本発明の要点を完全に明らかにしているので、最新の知識の適用によって、従来技術の見地から本発明の一般的または特定の形態の本質的特色を明瞭に構成する特徴を落とすことなく様々な応用に本発明を容易に適合させることができるだろう。 Without further analysis, the foregoing has fully outlined the gist of the present invention, and the application of current knowledge will clearly disclose the essential features of the general or specific form of the present invention from a prior art standpoint. The invention could easily be adapted to various applications without compromising the constituent features.
新規であるとして請求し、かつ特許証による保護を望む事項は、添付の特許請求の範囲に明示されている。
What is claimed as new and desired to be protected by Letters Patent is set forth in the appended claims.
Claims (6)
前記難燃剤成分は、少なくとも一つのリン酸塩又はその誘導体と、The flame retardant component, at least one phosphate or a derivative thereof,
炭化剤と、A carbonizing agent,
メラミン、又はシアヌル酸メラミン、ホウ酸メラミン、ポリリン酸メラミン、二リン酸メラミン、ピロリン酸メラミン、及びリン酸メラミンからなる群より選択されるメラミン誘導体と、を含有し、Melamine, or melamine cyanurate, melamine borate, melamine polyphosphate, melamine diphosphate, melamine pyrophosphate, and a melamine derivative selected from the group consisting of melamine phosphate,
前記難燃剤成分は、前記塗料の２０質量％を超えないことを特徴とする塗料。The paint, wherein the flame retardant component does not exceed 20% by mass of the paint.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US28078901P | 2001-04-02 | 2001-04-02 | |
| CA 2342662 CA2342662A1 (en) | 2001-04-02 | 2001-04-02 | Fire retardant and coatings compositions |
| US10/023,949 US6686403B2 (en) | 2001-04-02 | 2001-12-21 | Paint, and method of producing the same |
| PCT/CA2002/000467 WO2002079329A2 (en) | 2001-04-02 | 2002-04-02 | Paint, and a method of producing same |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2004532914A JP2004532914A (en) | 2004-10-28 |
| JP2004532914A5 true JP2004532914A5 (en) | 2005-12-22 |
| JP4274799B2 JP4274799B2 (en) | 2009-06-10 |
Family
ID=27171498
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002578338A Expired - Fee Related JP4274799B2 (en) | 2001-04-02 | 2002-04-02 | paint |
Country Status (13)
| Country | Link |
|---|---|
| EP (1) | EP1401965A2 (en) |
| JP (1) | JP4274799B2 (en) |
| CN (1) | CN1274771C (en) |
| AU (1) | AU2002250748A1 (en) |
| BG (1) | BG108305A (en) |
| CZ (1) | CZ305026B6 (en) |
| EA (1) | EA006144B1 (en) |
| HK (1) | HK1065059A1 (en) |
| HU (1) | HUP0402272A3 (en) |
| PL (1) | PL207152B1 (en) |
| SK (1) | SK285850B6 (en) |
| UA (1) | UA76747C2 (en) |
| WO (1) | WO2002079329A2 (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103937229A (en) * | 2013-01-17 | 2014-07-23 | 上海杰事杰新材料(集团)股份有限公司 | Fire retardant glass fiber reinforced nylon composite material, and preparation method thereof |
| CN105295681A (en) * | 2014-06-29 | 2016-02-03 | 江苏飞翔涂料实业总公司 | Fast drying paint |
| CN104194633B (en) * | 2014-08-27 | 2016-08-24 | 苏州诚晟信息技术有限公司 | A kind of uvioresistant fireproof coating and preparation method thereof |
| WO2018087315A1 (en) * | 2016-11-10 | 2018-05-17 | Ppg Coatings Europe B.V. | Surfactants for intumescent foam stabilization |
| CN106638121B (en) * | 2016-12-30 | 2018-11-13 | 北京蓝海黑石科技有限公司 | A kind of paper is containing immersion liquid and preparation method thereof |
| WO2020027175A1 (en) * | 2018-08-01 | 2020-02-06 | 関西ペイント株式会社 | Expandable coating composition |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3635970A (en) * | 1969-04-17 | 1972-01-18 | American Cyanamid Co | Crystalline melamine pyrophosphate |
| US3654190A (en) * | 1970-05-28 | 1972-04-04 | Us Navy | Fire retardant intumescent paint |
| DE3009104C2 (en) * | 1980-03-10 | 1990-10-04 | Odenwald-Chemie GmbH, 6901 Schönau | Use of an epoxy resin for the production of fire-retardant layers or coatings and processes for the production of the same |
| US4965296A (en) * | 1989-03-15 | 1990-10-23 | No Fire Engineering, Inc. | Intumescent fire-retardant and electrically-conductive coating material |
| GB2246136A (en) * | 1990-07-18 | 1992-01-22 | Prometheus Developments Ltd | Intumescent coating compositions |
-
2002
- 2002-02-04 UA UA2003109815A patent/UA76747C2/en unknown
- 2002-04-02 CZ CZ2003-2967A patent/CZ305026B6/en not_active IP Right Cessation
- 2002-04-02 HU HU0402272A patent/HUP0402272A3/en unknown
- 2002-04-02 AU AU2002250748A patent/AU2002250748A1/en not_active Abandoned
- 2002-04-02 EA EA200301085A patent/EA006144B1/en not_active IP Right Cessation
- 2002-04-02 EP EP02719578A patent/EP1401965A2/en not_active Withdrawn
- 2002-04-02 CN CNB028078276A patent/CN1274771C/en not_active Expired - Fee Related
- 2002-04-02 PL PL365338A patent/PL207152B1/en unknown
- 2002-04-02 SK SK1357-2003A patent/SK285850B6/en not_active IP Right Cessation
- 2002-04-02 JP JP2002578338A patent/JP4274799B2/en not_active Expired - Fee Related
- 2002-04-02 WO PCT/CA2002/000467 patent/WO2002079329A2/en active Application Filing
-
2003
- 2003-10-30 BG BG108305A patent/BG108305A/en unknown
-
2004
- 2004-10-15 HK HK04107977A patent/HK1065059A1/en not_active IP Right Cessation
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