RU2278880C2 - Dye semifinished product and methods for preparing dyes from dye semifinished products - Google Patents

Abstract

FIELD: dyes, building materials.

SUBSTANCE: invention relates to sets of dye semifinished products used in preparing dyes of different designation. Invention describes the dye semifinished product with properties of fluidity and covering power that can be used in preparing a single-package latex dye stained with pigment wherein the volume content of dry matter is from about 30% to about 70% with the Schtormer viscosity value from about 50 to about 250 EK and comprising the following components: (I) at least one pigment conferring the covering power property; (II) at least one dispersing agent; (III) at least one thickening agent, and (IV) water wherein at least one dispersing agent and at least one thickening agent are compatible with at least one pigment and other dye components. Also, invention describes sets for dyes and dye lines comprising a latex polymeric binding agent. Some dyes for internal and external coating of different objects are prepared by using sets of dye semifinished products. Invention provides preparing the broad assortment of dyes of different quality for external and internal workings and with different levels of polishes and bases for carrying out the coloring from dye semifinished products and by using the minimal amount and types of the dye components. Proposed dye semifinished products can be used for architecture, industrial, polygraphic, elastomeric and non-cement coatings.

EFFECT: improved preparing method, valuable properties of dyes.

51 cl, 3 tbl, 63 ex

Description

CROSS REFERENCE TO RELATED APPLICATIONS

This application claims priority for provisional patent applications US serial numbers 60/183655, filed February 18, 2000, 60/183656, filed February 18, 2000, and 60/247639, filed November 10, 2000.

BACKGROUND OF THE INVENTION

FIELD OF THE INVENTION

The present invention relates to sets of prefabricated paints and to methods for preparing paint lines using sets of prefabricated paints for them, to paints that can be used as architectural coatings, industrial coatings, printing coatings, elastomeric coatings and non-cement, complex finishing coatings and which are prepared from sets of prefabricated paint compositions.

Description of the Prior Art

For decades, professional painters / contractors and do-it-yourself consumers have been able to purchase paints that are color-coded not only at the place of production, but at the place of sale. This principle of deferred product differentiation allows the buyer to more accurately select the desired paint color in a wide variety of assortments than in the case of a limited number of colors of products manufactured by the paint manufacturer.

Although it did not find industrial application, in the paint industry there is also a theoretical possibility of applying the principle of delayed (as far as the paint preparation process allows) differentiation of the paint components themselves [see, for example, the scientific report of Carola Grundfelt-Forsius in Faerg Lack Scand. 43 (2), pp. 5-6 (1997), which describes the use of intermediates or components, i.e. mixtures of several starting materials as components of paints, which together are mixed with pastes for coloring to obtain paints of different types]. A Grundfelt-Forsius report provides an example of such a system in which a polyurethane binder is used for a solution polymer system.

Implementation of the methods for applying the principle of deferred product differentiation provides the buyer with the flexibility to choose the target finished paints with regard to both the color of the paint and the type of paint, while also allowing the manufacturer or seller of paints (retailer or wholesaler, or distribution agent) to minimize the range of initial materials, intermediate and finished products, as well as an empty storage space.

Despite these advantages, paint manufacturers are able to successfully apply the principle of delayed product differentiation only with respect to solution polymer based paint systems. Until now, paint manufacturers have not achieved any success in applying the principle of delayed product differentiation with respect to paint components in paint systems based on latex polymers. Since most of the currently used paints are based on latex polymers, there is a need to develop a practical way to apply the principle of delayed product differentiation in a latex polymer based paint system.

When latex emulsion polymers are used, due to the instability of the latex, it is much more difficult to prepare a stable paint than with the use of mortar polymers. Emulsion polymers are very sensitive to solvents and surfactants that are commonly found in paint compositions, such as conventional surfactants, dispersants, rheology modifiers, and cosolvents. Solvent polymers, by definition, are soluble in the solvent in which they are supplied, and there is no thermodynamic driving force causing agglomeration of the polymer molecules and causing their instability. In contrast, latex polymers include particulate polymer material that is insoluble in water. When such particles are supplied in an aqueous medium, substantial modification of their surface is required to give them stability. If the surface modification is inadequate, the latex particles stick together to form a coagulated mass, which is then released from the latex paint. The preparation of paint using the latex system is associated with very large technological difficulties, since the surfactants that make up the composition disrupt the fragile balance of surface forces that stabilize latex particles in an aqueous medium.

The difference between latex polymer systems (also referred to as "emulsions" in the present description) and solution polymer systems is further explained in Temple C. Patton, entitled Paint Flow and Pigment Dispersion (New York: John Wiley and Sons, Inc., 1979, c .192-193). In this work, the author describes the drying processes of both systems. The main difference lies in the time required for each polymer to reach an irreversible state. Latex polymers achieve this state much faster than mortar polymers, which makes it more difficult to stabilize latex-based paints than mortars. In a discussion of “coatings of solution-type materials” (which include solution polymers), the author writes “... during drying, the liquid binder expires rather than deforms around the pigment particles. This expiration facilitates the compaction process as the film shrinks due to the loss of volatile solvent. Although as the solvent evaporates, the binder becomes more viscous, fluidity persists for most of the drying cycle. " As the author indicates, as the solvent evaporates, the solution polymer maintains fluidity during most of the drying cycle. The polymer emulsion shows a different time. The same author notes: “... there is a preliminary outflow of the latex suspension. This occurs before the moment when the latex particles are forced to come into tight contact already as a result of the initial loss of water. However, after that a relatively short, but very important initial flow, the pigment is densified with Achieving a high, critical volumetric pigment concentration (POCC) is achieved mainly due to plastic deformation and coalescence of latex particles. " Coalescence is irreversible contact between latex particles. Such irreversible contacting can occur in liquid paint based on latex polymers, but not in liquid paint based on mortar polymers. Thus, latex polymer based paints are more difficult to prepare.

There is a great need to create a set of semi-finished paints and to develop a method for preparing paints based on latex polymers using sets of semi-finished paints.

The preparation of paints involves the process of selecting and mixing the respective components of the paints in the correct proportions to obtain paints with special technological and handling properties, as well as forming the final dry paint coating with the necessary properties. The main components of latex paint formulations are a pigment binder, opaque pigment, optional pigment fillers and water. Common optional additives include antifoam agents, coalescent agents, plasticizers, thickeners, non-thickening rheological modifiers, opacifying agents, desiccants, anti-skincing agents, surfactants, mildecides, biocides and dispersants. After preparation of the latex paint and its application to the surface due to the evaporation of water, the paint dries under the influence of heat or without it and the binder forms a film comprising particles of pigment and pigment filler, if any.

The preparation of paints is a complex process that cannot be reduced to simply mixing several components of the paint in different ratios. In a preferred embodiment, it includes the selection and mixing of different components of the paints in different ratios, depending on the type of target paint. This requires manufacturers to store many different paint components and replace paint components during preparation, depending on the particular type of paint being prepared.

Moreover, in order to ensure that the buyer offers the entire range of paints, in particular with different gloss levels, bases for tinting, exterior paints, interior paints and paints of various quality, those who are involved in the supply chain, in particular retailers paints should have large stocks of paints in storages and on storage racks. It is apparently necessary to prepare paints at the place of either relatively large-scale production or relatively small-scale production, at the point of sale or at the place of use using a limited number of paint components to obtain all of these various paint compositions, thus minimizing the number and types of paint components that are needed to prepare a full range of paints.

SUMMARY OF THE INVENTION

The “ink line” referred to in the present description includes at least two different inks that impart to the dried layers properties that differ materially from each other by at least one property which is indispensable to achieve, such as gloss, weather resistance, and color saturation. The line of paints may include, for example, three paints, the dried layers of which have different degrees of gloss, two paints, the dried layers of which have acceptable performance properties when conducting indoor or outdoor works, or four paints, the dried layers of which have different quality indicators or performance properties, such as evidenced by, for example, different levels of resistance when cleaning with a scraper.

More specifically, the line of paints could include four different paints, the dried layers of which have different degrees of gloss, usually marketed as glossy, semi-glossy, matte, glazed, or faint and dull. Gloss is determined by the volumetric content in the paint and the type of binder (s), pigment (s) and filler (s), if any.

In addition to achieving varying degrees of gloss, paints are usually prepared in such a way that they are neutral or accentuated (lack or very low pigmentation), uncolored (white) or tinted to give a wide variety of color shades using different undercoatings, including pastel or light tones, mid tones or mid tones and rich tones. To do this, you need a line of paints, including as many as five paints. In addition, paints are prepared for exterior or interior use. In addition, paints are prepared in such a way as to inform them of certain levels of performance, due to which they can be sold as good / standard, improved and best / top quality.

Ink manufacturers and retailers typically offer a range of inks that include at least two lines of inks. When referred to in the present description, "a series of paints comprising at least two lines of paints", it is understood that in this series of paints the individual selected levels of the property that is mandatory to achieve, which determine the first line of paints, are combined with the individual selected levels of the property that is mandatory to achieve, which determine the second paint lines, etc.

To prepare a series of paints, which includes four lines of paints, it may be necessary to prepare paints covering four levels of gloss, four bases for tinting, the possibility of application for interior and exterior use and three levels of quality. For all combinations, 96 different paint compositions (4 × 4 × 2 × 3) may be required. However, a number of paints are also provided, including some of these paints, which make up a certain proportion of them, equal to from 10 to 60% of the total number of paints selected for exclusion from the general list, for example, for commercial reasons or because they are unstable, as indicated in the present description. In addition, a number of paints are contemplated in which the mandatory properties of the dried paint layers substantially, but not exactly, meet standard definitions; for example, in the gloss of the dried layer, glossy mid-tone paints for exterior work in standard, improved and superior quality lines can vary in several ways without leaving the definition of a number of paints of the present invention.

The term “paint” as used in the present description is used in its broadest sense and encompasses any coating that can be applied to a surface for decorative, protective, or both. Specifically covered are those systems that are applied to obtain architectural coatings, industrial coatings, elastomeric coatings and cementless aggregate finishing layers applied to the walls as a finishing layer and in a system for external insulation and decoration (hereinafter referred to as "SVIO" in the present description) .

The semi-finished paints referred to in the present description are "compatible" if the paints prepared by mixing such semi-finished paints do not show obvious signs of colloidal instability, such as flocculation. In a preferred embodiment, paints prepared from prefabricated paints exhibit less than 5 g of residue, such as gel and sintered solids, per liter of paint when these paints are passed through a 325 mesh sieve. In a more preferred embodiment, paints prepared from prefabricated paints exhibit less than 1 g of residue per liter of paint when these paints are passed through a 325 mesh sieve. If the additives included to improve the specific properties of the inks and the dyes are fully compatible, i.e. they can be mixed in any proportions without the occurrence of colloidal instability, then they can be mixed in any combination that does not go beyond the compositional range necessary to achieve the target profile of the properties of the finished paint. However, for semi-finished paints, it is sufficient that the optional additives included to improve the specific properties of the paints and the dyes are compatible, i.e. so that to achieve the target profile of properties in a series of paints, they can be mixed in any target proportions without the occurrence of colloidal instability.

To minimize the number of components of paints that are required for the preparation of a number of paints, one should take into account the extreme values of the key properties required for a number of paints, and prepare semi-finished products of paint that are acceptable for mixing in various combinations to achieve extreme values of the necessary key properties, as well as intermediate values. By introducing such paint additives that improve their target properties, specific properties can be improved.

The above objectives are achieved by using a set of different but compatible fluid semi-finished paints sufficient to prepare at least one line of paints. This kit includes (I) at least one tinting prefabricated paint comprising at least one tinting pigment; (Ii) at least one filler prefabricated paint containing at least one filler; and (III) at least one binder prefabricated paint containing at least one latex polymer binder.

The preferred number of semi-finished paints is from 3 to 15.

Also provided is a method of forming at least one line of paints, which comprises the following steps:

(a) preparing a set of different but compatible fluid prefabricated paints sufficient to form at least one line of paints, this kit comprising: (I) at least one tinting prefabricated paint containing at least one tinting pigment; (Ii) at least one filler prefabricated paint containing at least one filler; and (III) at least one binder prefabricated paint containing at least one latex polymer binder;

(b) supplying a predetermined amount of each of the semi-finished paints to the containers or applicator (s) to form a line of paints.

The preferred total number of semi-finished paints is from 3 to 15.

The proposed method may further include the stage of mixing the semi-finished paints before, during or after their filing in containers or before or during their filing in the applicator (applicators).

In addition, a method for preparing a number of inks is provided. Such a series includes at least two lines of paints. This method includes the following steps:

(a) preparing a set of different but compatible fluid prefabricated paints sufficient to prepare a number of paints, the aforementioned kit comprising: (I) at least one tinting prefabricated paint containing at least one tinting pigment; (Ii) at least one filler prefabricated paint containing at least one filler; (III) at least one binder prefabricated paint containing at least one latex polymer binder, and (IV) at least one additional, other prefabricated paint selected from the group comprising prefabricated paints (I), (II) and (Iii);

(b) supplying a predetermined amount of each of the semi-finished paints to containers or an applicator (s) to form ink lines.

The preferred total number of semi-finished paints is from 4 to 15.

These methods may further include the step of mixing the semi-finished paints before, during, or after they are fed into the container, or before, or during their supply to the applicator (s). These methods may further include the step of adjusting the viscosity of the prefabricated paints before, during or after they are fed into the container or before or during their feeding to the applicator (s) using a thickener, water or a mixture thereof. These methods may further include the step of adding additional materials that improve the application or final performance of the paint and which contain aggregate fillers and thickeners. Further, these methods may include the step of adding at least one dye to the ink feed. These methods can be carried out at the location of the equipment for the manufacture of paints, at the point of sale or at the place of use, and their implementation can be controlled using a computer.

In another embodiment, a set of different but compatible fluid prefabricated paints is provided that is sufficient to form at least one line of paints that can be used as an elastomeric coating material. This kit includes (I) at least one tinting prefabricated paint comprising at least one tinting pigment; (Ii) at least one filler prefabricated paint containing at least one filler; (III) at least one binder prefabricated paint containing at least one latex polymer binder whose Tc is less than about 0 ° C.

Also provided is a method of forming at least one line of paints that can be used as an elastomeric coating material. This method includes the following steps:

(a) preparing a set of different but compatible fluid prefabricated paints, the kit comprising: (I) at least one tinting prefabricated paint containing at least one tinting pigment; (Ii) at least one filler prefabricated paint containing at least one filler; (III) at least one binder prefabricated paint containing at least one latex polymer binder whose Tc is less than about 0 ° C;

(b) supplying a predetermined amount of each of the semi-finished paints to the containers or applicator (s) to form a line of paints.

In addition, a method for preparing a number of inks is provided. Such a series includes at least two lines of paints that can be used as an elastomeric coating material. This method includes the following steps:

(a) preparing a set of different but compatible fluid prefabricated paints sufficient to form at least two lines of paints, this kit comprising: (I) at least one tinting prefabricated paint containing at least one tinting pigment; (Ii) at least one filler prefabricated paint containing at least one filler; (III) at least one binder prefabricated paint containing at least one latex polymer binder whose Tc is less than about 0 ° C; (IV) at least one additional, other fluid prefabricated paint selected from the group comprising prefabricated paints (I), (II) and (III);

(b) supplying a predetermined amount of each of the semi-finished paints to containers or an applicator device (s) for forming ink lines. In another embodiment, a set of different but compatible fluid non-cement semi-finished paints is provided, sufficient to form at least one line of paints that can be used as material for the non-cement aggregate finishing layer. This kit includes: (I) at least one tinting prefabricated paint comprising at least one tinting pigment; (Ii) at least one filler prefabricated paint containing at least one filler; (III) at least one binder prefabricated paint containing at least one latex polymer binder; (IV) at least one prefabricated paint comprising aggregate filler.

A method for forming at least one line of paints that can be used as a material of a cementless aggregate finishing layer is also proposed. This method includes the following steps:

(a) preparing a kit of different, but compatible, fluid, cementless prefabricated paints, the kit comprising: (I) at least one tinting prefabricated paint containing at least one tinting pigment; (Ii) at least one filler prefabricated paint containing at least one filler; (III) at least one binder prefabricated paint containing at least one latex polymer binder; (IV) at least one prefabricated paint comprising aggregate filler;

(b) supplying a predetermined amount of each of the semi-finished paints to the containers or applicator (s) to form a line of paints.

The following is a method for preparing a number of colors. Such a series includes at least two lines of paints that can be used as the material of non-cement aggregate finishing layers. This method includes the following steps:

(a) preparing a set of different but compatible fluid non-cement semi-finished paints sufficient to form at least two lines of paints, this kit comprising: (I) at least one tinting prefabricated paint containing at least one tinting pigment; (Ii) at least one filler prefabricated paint containing at least one filler; (III) at least one binder prefabricated paint containing at least one latex polymer binder; (IV) at least one prefabricated paint comprising aggregate filler; (V) at least one additional, other fluid prefabricated paint selected from the group comprising prefabricated paints (I), (II), (III) and (IV);

(b) supplying a predetermined amount of each of the semi-finished paints to containers or an applicator (s) to form ink lines.

In another embodiment, a set of different, but compatible, fluid semi-finished paints is provided, sufficient to form at least one line of paints that can be used to produce pigmented and transparent coatings. This kit includes: (I) at least one tinting prefabricated paint comprising at least one tinting pigment; (II) at least two binder prefabricated paints, each of which contains at least one latex polymer binder.

In yet another embodiment, a set of semi-finished inks is provided that is sufficient to form at least one line of inks that can be used in printing. This kit includes: (I) at least one binder prefabricated paint containing at least one latex polymer binder, Tc of which is from about -50 to about 10 ° C; (II) at least one binder prefabricated paint containing at least one latex polymer binder, Tc of which is from about 50 to about 140 ° C; and (III) optionally at least one binder prefabricated paint containing at least one latex polymer binder, whose TC is from about 0 to about 65 ° C. Semi-finished inks for printing purposes may further include additional flowable compatible semi-finished inks selected from the group consisting of: (I) semi-finished ink containing at least one alkali-soluble resin; (Ii) a semi-finished paint containing at least one gloss-giving additive; (Iii) a semi-finished paint containing at least one wax; (IV) a plurality of semi-finished paints containing at least one pigment dispersion.

If one paint line is required, i.e. if one key property is varied (for example, gloss level, base for tinting, type of application or type of quality), then a full line of paints can be prepared using one of each of such materials as tinting prefabricated paint (I), filling prefabricated paint ( II) and binder prefabricated paint (III).

If a range of paints is required, including two lines of paints, i.e. if two key properties vary (for example, two properties selected from gloss level, base for tint, type of application or type of quality), then a number of paints can be prepared using at least one of each of such materials as giving a hiding power, filling and binder prefabricated paints (I), (II) and (III) and at least one additional, another prefabricated paint selected from imparting opacity, filling and binder prefabricated paints (I), (II) and (III), depending on of which key properties to vary.

If a series of paints is required, including three lines of paints, i.e. if three key properties vary (for example, three properties selected from gloss level, base for tint, type of application or type of quality), then a number of paints can be prepared using at least one of each of such materials as imparting opacity, filling and binder prefabricated paints (I), (II) and (III), and at least two other additional prefabricated paints selected from imparting opacity, filling and binder prefabricated paints, depending on which key properties and the need to vary.

If a series of paints is required, including four lines of paints, i.e. if four key properties vary (for example, gloss level, basis for tinting, type of application or type of quality), then a full range of paints can be prepared using at least one of each of such materials as imparting opacity, filling and binder prefabricated paints ( I), (II) and (III), and at least three additional, other semi-finished paints selected from giving hiding power, filling and binder semi-finished paints, depending on what key properties are needed in to replicate.

This technique can be continued with the aim of varying as many additional key properties as necessary.

By “additional hardening, filling and binder prefabricated paints” is meant a prefabricated paint different from, respectively, giving a hiding power, filling and binder prefabricated paints (I), (II) and (III), but in other respects consistent with the restrictions associated with prefabricated colors.

As stated above, the “line of paints” includes two or more different paints, the dried layers of which differ materially from each other by at least one property necessary to achieve it. These paints differ from each other and must meet at least one of the following criteria:

(1) by volume concentration of the pigment (OKP) of the paint, which differs the most, should differ by at least 2% or

(2) the volumetric dry matter (OS) content of the paint, which varies the most, should vary by at least 2%.

Pigment volume concentration (POC) is a measure of how rich the binder composition is. In the present description, it is calculated by the following formula:

The volume content of dry matter (OS) is the volume of dry pigment (s) plus the volume of dry filler (s) plus the volume of dry binder (s). It is calculated by the following formula:

If additives are contained, then when determining the total volume of dry matter, their volume is not included. In each of the above options, semi-finished paints are selected so that they cover a wide compositional range so that the target properties of the finished paint are within the range of extreme values for mixtures determined by semi-finished paints. In many cases, the semi-finished paints themselves are essentially not paints. But pushing semi-finished paints to these extreme values makes it possible to maximize the range of mixtures available for the kit. When all semi-finished paints, additives and dyes are fully compatible, they can be mixed in target ratios to form the target line (s) of paints and a number of paints without the occurrence of colloidal instability. It is possible to prepare a specific paint in the line of paints without using each of the semi-finished paints available in the set of semi-finished paints. So, for example, for the preparation of a saturated tone paint, the use of a semi-finished paint with a pigment that imparts a hiding power is not required.

This technique is similar to the development principles used in statistical experimental development and analysis of circuit solutions for the components of mixtures, but instead of creating a range of mixtures (mixture space) to study the surface reaction in them, to maximize the flexibility of the paint system, a separate analysis of the surfaces of the mixture range has been developed. The key to success is the compatibility of the individual components of semi-finished paints and semi-finished paints in the entire range of mixtures.

The properties of paints can be predicted in a number of ways. One way is to create reaction models for the surfaces of a range of mixtures using standard Mixture Component experimental design statistical tools. In the future, these simple statistical models can be used in a linear optimization program, a massive study of the coordination grid (massive grid search), or in a graphical analysis instrument. Another way is to simply use empirical methods to determine which mixtures are necessary for specific lines of paints, followed by the introduction of these simple, empirically obtained formulations in a program that provides the preparation of paints.

An extension of this technical solution is to have a paint preparation device for automatic preliminary testing in order to determine some key properties (for example, viscosity, gloss or color during forced drying) and make minor adjustments during the preparation of paint from semi-finished paints. The presence of feedback loops in a paint preparation device can provide a more accurate selection of target colors, gloss, and viscosity.

Compatible paint components can be combined into various semi-finished paints, and paints prepared from these semi-finished paints exhibit properties characterizing the amount of component used.

In order to facilitate mixing, in a preferred embodiment, all fluid semi-finished paints used in the implementation of the methods described in this description should have similar or similar viscosity values.

It is believed that by using reduced amounts of stabilizing materials, such as surfactants that can be used in accordance with conventional cooking techniques, water resistance is improved, including resistance to blistering, adhesion of dry coat and resistance to scrubbing paints prepared from kits prefabricated paints. Moreover, the reaction of line paints or series paints prepared using such semi-finished paints to the addition of dyes can be more predictable, which simplifies color matching and makes it easier to use software in color matching. In addition, it is believed that pre-balancing the components in the semi-finished paints provides a reduction in viscosity fluctuations in the finished paint composition.

Semi-finished paints are prepared in such a way as to maximize the flexibility of the paint preparation process. Instead of purchasing individual components of paints, manufacturers of paint and even buyers at the point of sale and place of application (in paint stores, paint departments and contractors) can purchase a set of prefabricated paints for the preparation of the necessary range of paints. These prefabricated ink kits typically include at least one of each of the prefabricated paints x, y, and z and optionally additional prefabricated paints, depending on the necessary flexibility in preparation. The above prefabricated paints are optionally mixed with an additional prefabricated paint that includes at least one dye, such as a color pigment or a coloring matter.

Presented in the present description sets of semi-finished paints and methods of preparation are not limited to the preparation of only latex paints. They can also be applied to any aqueous coating materials or related building materials, the preparation of which requires a mixture of components, including, although not limited to, printing products, sealants, sealing compounds, mastics, adhesives, materials for architectural coatings ( materials for coatings applied to walls by homeowners and contractors, elastomeric materials for coatings on walls and roofs and aggregate finishing layers) and industrial coatings (such as those classified cited as being applied by the manufacturer in the manufacturing process of equipment, during maintenance for wood, metals as ordinary industrial finishing coatings and other factory-applied coatings, as well as in small quantities non-architectural coating materials applied by the owners of do-it-yourself products) .

In the field of materials for factory-applied coatings, the methods presented in this description can be applied to a wide range of coatings for automobiles, ships, aircraft, other land vehicles, electrical appliances, metal furniture, machinery and equipment, windings, metal containers, magnetic wire , concrete roofing tiles, electrical insulating varnish, electronic equipment, pipes, packaging, printing on top of a picture or text, opening mechanisms, apartment floors (flatboard), wooden furniture, plastic substrates, magnetic media, metals in general, industrial maintenance, restoration of car polish, road marking paint, flame retardants, aerosol preparations, chemical resistant coatings, roofing, tanks, flooring, concrete, water repellents for masonry, nail polish, in art and for hobbies. So, for example, the method presented in the present description can be used in the preparation of a number of materials for coating metals, including matte, glossy, applied directly to the metal, for primers, middle layers and solvent resistant coatings, using an appropriate set of prefabricated paints.

DETAILED DESCRIPTION OF THE INVENTION

In one embodiment of the opaque prefabricated paint, the latter is a flowable titanium dioxide prefabricated paint that includes (I) at least one opaque pigment, (II) at least one dispersant, (III) at least one thickener and water. Dispersant (s) and thickener (s) are compatible with pigment (s) and other optional paint components. The volumetric dry matter content of this semi-finished paint is from about 30 to about 70%, preferably from about 35 to about 50%, and its Stormer viscosity is from about 50 to about 250 KU, preferably from about 60 to about 150 KU.

In another embodiment, the opaque prefabricated paint is a flowing titanium dioxide prefabricated paint that can be used to prepare a single-pack pigmented latex paint containing other paint components. This prefabricated paint comprises (I) at least one hiding pigment, (II) at least one dispersant, (III) at least one thickener, (IV) at least one film-forming or non-film-forming polymeric binder, and ( V) water. Such dispersant (s), thickener (s) and polymer (s) are compatible with pigment (s) and other optional paint components. The volumetric dry matter content of this semi-finished paint is from about 30 to about 70%, preferably from about 35 to about 50%, OKP is from about 35 to about 100%, preferably from about 50 to about 100%, and the Stormer viscosity is from about 50 to about 250 KU, preferably from about 60 to about 150 KU. In a preferred embodiment, such a prefabricated paint is stable to sedimentation. By stability is meant the absence of a pigment deposit after 10 days at 25 ° C. The polymeric binder is optionally adsorbed on the hiding pigment.

In one embodiment of a prefabricated paint preform, this last one is a flowable pigmented prefabricated paint preform which includes (I) at least one mineral filler, (II) at least one thickener, (III) an optional polymeric binder, and (IV) water . The volumetric dry matter content of this pigment-based prefabricated ink is from about 30 to about 70%, preferably from about 35 to about 65%, OKP is from about 35 to about 100%, preferably from about 40 to about 100%, and the viscosity is Stormer is from about 50 to about 250 KU, preferably from about 60 to about 150 KU. The components of this prefabricated paint are compatible with each other and the components of other prefabricated paints that must be used with them.

In one embodiment of the binder prefabricated paint, the latter is a flowable latex polymer binder prefabricated paint, which includes a latex polymeric binder based on water, TC which is from about -40 to about 70 ° C, preferably from about -10 to about 60 ° C, and water. The volumetric dry matter content of this binder prefabricated ink is from about 25 to about 70%, preferably from about 30 to about 65%, and the Brookfield viscosity is less than about 100,000 cP, preferably from about 1000 to about 50,000 cP, at a shear rate of 1 , 25 s ^-1 . The components of this prefabricated paint are compatible with each other and the components of other prefabricated paints that must be used with them.

Such varieties of semi-finished paints, imparting opacity, filling and binder semi-finished paints (I), (II) and (III) optionally contain small amounts, i.e. less than about 20 wt.% based on the total weight of the semi-finished paint, conventional paint additives, including acid, base, antifoam, coalescent agent, mildecid, biocide, antifreeze, film rust inhibitor (flash rust ingibitior), etc. These additives must be compatible with other paint components in the semi-finished paints and paints used in the implementation of the methods described in this description. Acceptable hiding pigments include white pigments, which impart to the paint the ability to scatter light in the range of all wavelengths of visible light without a high degree of absorption. Pigment fillers are inorganic solid particles or opaque polymers that do not impart a primary color or opacity, although they may have a secondary effect on these properties. The base for tinting used for saturated color tones generally does not include or contain very small amounts of hiding pigments.

Suitable hardening pigments include titanium dioxide (TiO ₂ ) or a combination of titanium dioxide and auxiliary covering pigments, such as polymers with cellular latex particles, zinc oxide, lead oxide, synthetic polymer pigment, and mixtures thereof. For use for this purpose, titanium dioxide of rutile and anatase modifications is suitable. Rutile titanium dioxide is preferred. The surface of the particles of titanium dioxide can be treated by surface treatment with various organic and / or inorganic materials, for example silicas, alumina and zirconia. In addition, fuming titanium oxide can also be used.

The diameter of the acceptable cellular latex particles is from about 100 to about 2500 nm, and the fraction of the cavities is from about 10 to about 75%. The preferred mesh size of the latex particles that can be used in the implementation of the method according to the invention is from about 500 to about 1100 nm. Suitable particles include at least one cavity, but they may have multiple cavities, non-spherical cavities, interconnected cavities, cavities that have channels communicating with the outer surface of the particles, and may include other structures described as porous or spongy structures. Preferred particles include one cavity. The glass transition temperature (Tg) of particles such as it is determined by differential scanning calorimetry at a speed of 20 ° C./min is at least about 20 ° C., preferably at least about 50 ° C. The higher Tc, the harder the particle and the less chance of its destruction. If the particles are destroyed, they are not able to report hiding power. Cellular latex particles can be obtained by carrying out conventional polymerization methods known in the art, such as those described in US 3784391, US 4798691, US 4908271, US 4972000, US 5041464, US 5157084, US 5216044 and US 6020435, as well as in applications for Japanese Patents 60/223873, 61/62510, 61/66710, 61/86941, 62/127336, 62/156387, 01/185311 and 02/140272. In a preferred embodiment, the cellular latex particles are prepared as described in US 4427836, US 4469825, US 4594363, US 4880842, US 5494971 and US 6020435.

The fillers used for this include paint fillers for exterior and interior use, optimized for the intended end use. Paint fillers for outdoor use are insoluble in water and have a low absorption value. They are optimized for stability during outdoor work in accordance with the requirements of the particular market in which the paint is usually sold, and after the paint dries, they do not impair its target properties such as the absence of cracking and chalking and non-fading. They also increase material volume at low cost. Ink fillers are optimized for opacity, gloss and low cost. Suitable excipients include barium sulfate (with particles from 1 to 15 microns), Blanc Fixe product (with particles from 0.5 to 5 microns), calcium carbonate (with particles from 0.05 to 35 microns), silicon dioxide (with particles from 0.001 to 14 microns), magnesium silicate (with particles from 0.5 to 15 microns), aluminum silicate (with particles from 0.2 to 5 microns), nephelinsenite, mica, bentonite, magnesium aluminosilicate, fuming alumina, colloidal attapulgite, synthetic amorphous sodium aluminosilicate, sodium potassium aluminosilicate, etc.

Latex polymer binders are polymers or prepolymers that form the primary film of paint. They bind pigments and / or fillers, provide the desired fluidity of the paint and determine the gloss and hardness of the final paint layer. The choice of binders for semi-finished paints usually depends on the final destination of the finished paints. Binders suitable for exterior paints are generally suitable for interior paints, but binders suitable for interior paints may not be suitable for exterior paints.

Suitable latex polymer binders include, although not limited to, homopolymers, copolymers and ternary copolymers such as, for example, acrylate and / or methacrylate polymers and copolymers, polyvinyl acetate, styrene-acrylate copolymers, styrene-butadiene, vinyl acetate-acrylate , ethylene-vinyl acetate copolymers, vinyl acetate-vinyl reversible copolymers, vinyl acetate-vinyl maleate copolymers, vinyl acetate-vinyl chloride-acrylate triple copolymers, ethylene-vinyl acetate-acrylic triple copolymers EASURES and urethane polymers. These polymers can contain up to 10 wt.% Functional groups of monomers such as, for example, although their list is not limited to, carboxylic acids, phosphates, sulfates, sulfonates and amides, other monomers, and also mixtures thereof. Latex polymer binders, optionally incorporated into prefabricated paints x, y, x ', y' or other prefabricated paints, may be the same or different from the latex polymer binder prefabricated paint z.

It is believed that for industrial coating materials, semi-finished paints typically use a wide range of thermoplastic and thermosetting polymer binders that can be single-pack, two-pack, or curable under the influence of energy and which are used in the semi-finished paints and in the implementation of the methods of the invention, including, although their list is not limited, asphalt, paraffin wax, coal tar, alkyd resins, vinyl acetate, vinyl acetate-acrylate, styrene-butadiene high, saturated polyester, unsaturated polyester, polyurethane resins, acrylate varnishes, acrylate enamels, acrylate latexes, acrylate thermosetting, acrylate resins for electrodeposition and spontaneous deposition, styrene acrylate, acrylate, vinylacetate , urea, epoxy (diglycidyl ether of bisphenol A, bisphenol F, cycloaliphatic, monofunctional epoxy, etc.) resins, vinyl acetate copolymers N-methylolac amylamide, vinyl acetate-ethylene, vinyl acetate triple copolymers, vinyl acetate-vinyl reversatate, polyvinyl chloride, polyvinylidene chloride resins, copolymers of ethylene and acrylic acid, ethylene-methacrylic acid copolymer, ionomers, ethylene-methyl acrylate, cellulose, cellulose acetate, nitrocellulose acetate , ethyl silicate resins, polyacetals, copolymers of styrene and allyl alcohol, chlorinated rubber, polyvinyl alcohol, butyl rubber, styrene-ethylene-butylene-styrene block copolymer rubber, urethane-acrylate, polyamide imide, polyesterimide resins, silicones, silanes, polyamides, polytetrafluoroethylene, polydiallyldimethylammonium chloride, polyphenylene sulfide, aromatic polyesters, polyimides, siliconeimide, fluorinated polymers, polymers, polymers, polymers materials, as well as chlorinated polyolefin and bis-cyclobenzobutene. Preferred polymeric binders are aqueous latexes, but solution, water-dilutable, redispersible latexes and combinations thereof can also be used.

Polymeric binders can be one-pack or two-pack. If the polymeric binders are two-packaged, these polymeric binders can be used by:

(1) separating one component of a two-pack system as a separate prefabricated paint;

(2) separating one component of a two-pack system and incorporating it into either a prefabricated paint or fill prefabricated paint;

(3) adding one component of a two-pack system separately from any of the semi-finished paints and

(4) their combinations.

The term “thickener” is a general term used to refer to any material added to a paint to modify its rheological profile. Preferred thickeners are associative thickeners. Suitable thickeners for use for this purpose include polyvinyl alcohol (PVA), hydrophobically modified alkali-soluble emulsions known in the art as HMSR emulsions, alkali-soluble or alkali-swellable emulsions known in the art as ASN emulsions, hydrophobically modified ethylene oxide urethanes known in the art as GEUP thickeners, and cellulose thickeners such as hydroxymethyl cellulose (HMC), hydroxyethyl cellulose (HEC), hydrophobically modified hydroxyethyl cellulose (HMHEC), sodium carboxymethyl cellulose (NCCM), sodium carboxymethyl-2-hydroxyethyl cellulose, 2-hydroxypropyl methyl cellulose, 2-hydroxyethyl methyl cellulose, 2-hydroxyethyl cellulose, 2-hydroxyethyl, etc. Colloidal silicon dioxide, attapulgite and other types of clays, titanate chelating agents, etc. can also be used as thickeners.

Suitable dispersants for use for this purpose include nonionic, anionic and cationic dispersants, such as 2-amino-2-methyl-1-propanol (AMP), dimethylaminoethanol (DMAE), potassium tripolyphosphate (TPPA), trisodium polyphosphate (TNPA, lemon) other carboxylic acids and the like. Acceptable for use as dispersants include anionic polymers such as homopolymers and copolymers based on polycarboxylic acids, including those that have previously been hydrophobically or hydrophilically modified, for example polyacrylic acid, polymethacrylic acid, maleic anhydride, and copolymers of these products with various monomers, such as styrene, acrylate, methacrylate esters, diisobutylene and other hydrophilic and hydrophobic comonomers, as well as salts of the above dispersants and their mixtures si.

Suitable antifoam agents include antifoam agents based on silicone and mineral oils and the like.

If solvent free latex polymer binders are used in the binder prefabricated paints, there is no need for coalescent agents. Solvent-free binders are typically characterized by low Tc and low minimum film-forming temperature, as a result of which they form a film at room temperature, in particular at 20 ° C. If a coalescent agent is needed, it is preferably added to the binder prefabricated paint and all other prefabricated paints, including latex polymer binders.

Suitable coalescents, plasticizers, and other optional solvents include ethylene glycol, propylene glycol, hexylene glycol, 2,2,4-trimethyl-1,3-pentanediol monoisobutyrate (TEXANOL ^™ product), glycol ethers, white spirits, methyl carbitol, butyl adbates. etc.

Suitable mildeucides and biocides include zinc oxide, isothiazolones, triazolones, and the like.

Suitable surfactants include cationic, anionic and nonionic surfactants.

Acceptable aggregate excipients include fine-grained (typically with particle sizes corresponding to mesh number 40 or more), medium-grained (typically with particle sizes corresponding to mesh number 20 to 40) and coarse (typically with particle sizes corresponding to number mesh 20 or less) aggregate aggregates such as sand, carbonates with large particles (limestone), ceramics, glass, fibers, coal, granite, talc, multicolor quartz, crushed seashells, recycled products such as those containing as alt materials, fiberglass, vermiculite, perlite, XO-filler, etc.

Suitable film corrosion inhibitors include aminoethylethanolamine, ammonium benzoate, sodium nitrite, ammonium and amine salts of dicarboxylic acids and diphenols such as glutaric acid, malonic acid, suberic acid, sebacic acid, adipic acid, succinic acid, phthalic acid, from , tridiphenol and sulfonyl diphenol, as well as their ammonium and amine complex zinc salts, C ₁₂ -C ₁₄ tert-alkyl amines, compounds with (2-benzothiazolylthio) butanedic acid; (2-Benzothiazolylthio) butanedioic acid, addition product of 4-oxo-4-p-tolylbutyric acid and 4-ethylmorpholine, zirconium complex of 4-methyl-δ-oxobenzenebutyric acid, and the like.

Suitable crosslinking agents include polyvalent metal ions such as zinc, magnesium, zirconium, calcium and the like.

Reactive pigments are materials that are added to coating compositions in order to impart corrosion resistance to the substrate due to corrosion of the protectors. Suitable reactive pigments include calcium zinc phosphomolybdate, zinc phosphate, aluminum triphosphate, strontium zinc phosphosilicate, zinc molybdate modified zinc phosphate, and the like.

Suitable waxes include carnauba, paraffin, polyethylene waxes, a finely divided ethylene / acrylic acid copolymer, polytetrafluoroethylene (PTFE) and the like.

Alkali-soluble resins are polymers which, when neutralized with a base, contain a sufficient amount of acidic functional groups and have sufficiently low molecular weights to dissolve in an aqueous medium. They exhibit Newtonian rheological properties and perform the functions of a dispersant (i.e., reduce the surface tension of the aqueous medium). Suitable alkali-soluble resins include esters of acrylic acid and methacrylic acid copolymerized with carboxylic acid monomers (such copolymers are available, for example, from the Rohm and Haas Company and are marketed under the product names Acrysol ^™ I-62 and Acrysol ^™ 1-2074), styrene copolymers and acrylic acid with optional alpha-methyl styrene (polymers such as, for example, available from Rohm and Haas Company and marketed under the trade name Morez ^™ 101), styrene / maleic anhydride copolymers, and the like.

In another preferred embodiment, the semi-finished paints and methods of the present invention can be used in the preparation of elastomeric coating materials suitable for application to walls or roofs. These semi-finished paints can be mixed in various proportions when preparing materials of elastomeric coatings of various quality, flexibility, and the ability to protect from mold and adhesion to the substrate, suitable for application to walls or roofs.

The main features that distinguish elastomeric coating materials from materials of typical architectural coatings are the use of binders with a low temperature (<0 ° C), the manifestation of flexibility and the thickness of the applied coating (the thickness of the dry coating is usually from about 6 to about 20 mils when applied on walls and from about 15 to 40 mil when applied to roofs). Flexibility at low temperature is especially necessary for elastomeric coatings when they are applied to walls on which cracks can occur, in particular to stone walls or roofing substrates, which are characterized by a high degree of dimensional fluctuation due to climatic conditions. In addition to the flexibility of coatings, it is necessary to have a line of materials for elastomeric coatings with various degrees of flexibility at low temperature, various qualities, adhesion to different substrates, and varying appearance.

For those climatic conditions that are characterized by frost in winter, the following characteristics can be used to designate different levels of quality.

Quality level

Designations Okp OKP-TiO ₂ Flexibility temperature tall <40 > 5 <0 ° F average <40 4-5 <0 ° F average > 40 > 5 <0 ° F low > 40 <4 <0 ° F

For those climatic conditions that are characterized by only a few frosty days in winter, the following characteristics can be used to indicate different quality levels.

Quality level

Designations Okp OKP-TiO ₂ Flexibility temperature tall <40 > 5 <0 ° F average <40 4-5 <32 ° F average > 40 > 5 <32 ° F low > 40 <4 <32 ° F bad > 40 > 4 <40 ° F

The quality of the elastomeric coating can be further varied depending on whether zinc oxide (ZnO) is contained or absent in the composition. Zinc oxide alters the mechanical properties of the coating.

Finally, the elastomeric coating can be further varied by the addition of dyes. These dyes are usually ground in a dry state and a ground fraction of the coating material is prepared from them.

As for elastomeric coatings, it is possible to determine the following properties that can be varied when preparing coating materials for applying different elastomeric coatings: coating flexibility, coating quality (durability), adhesion to the substrate, and appearance.

For differentiation based on the flexibility of the elastomeric coating, it is possible to control the Tc of the binder, the TSP in the coating material, and the presence and content of zinc oxide. For differentiation based on the durability of the elastomeric coating, the content of titanium dioxide (TiO ₂ ) can be adjusted. For differentiation based on the adhesion of the elastomeric coating to the substrate, the coating material for walls and roofs can be prepared by varying the composition and content of the binder. For differentiation based on the appearance of the elastomeric coating, the content and type of dye can be adjusted. To achieve these different properties, you can prepare a set of semi-finished paints, as presented in the examples 36 to 41 below, and mix them in appropriate quantities to obtain elastomeric coating materials, varying their properties described above.

According to another preferred embodiment, the semi-finished paints and methods presented in the present description can be used in the preparation of materials of cementless aggregate finishing coat layers suitable for applying directly to the wall or as a finishing layer in systems for external insulation and finishing (SVIO). These semi-finished paints or pre-prepared components can be mixed in various ratios for coating with different flexibility, quality (durability), color and texture.

The following properties of the compositions are an example of how it is possible to affect the durability of non-cement aggregate finishing coatings applied with their use, used especially in SVIO. Aggregate finishing coatings of other types can be characterized by different intervals of OKP values, which correspond to different qualities. Thus, the designations below are just an example of aggregate finishing coatings used in the UWIS; therefore, they should not be considered as determining the OKP values used for other non-cement aggregate finishing coatings.

Quality

Designations Okp high <72 average 72-77 low > 77

In addition, you can determine the following properties of the compositions, which affect the intensity of the color. Materials of aggregate finishing coatings of other types can be characterized by different concentrations of TiO ₂ , which correspond to different values of the color intensity. Thus, the designations below are merely an example of aggregate finish coatings used in UWIS, so they should not be considered indicative of the concentration of TiO ₂ in which it is used in other finish coatings.

Designations OKP-TiO ₂ (%) white > 1.5 pastel midtones 0.5-1.5 saturated tones <0.5

Finally, one can also determine the following properties of compositions that affect the texture of coatings.

Designations Fine aggregate aggregate Coarse aggregate aggregate thin > 90% ≤10% rough ≤90% > 10%

By varying the flexibility or Tg of the binder, other options for the operational properties of aggregate finishes can be achieved.

As a specific embodiment of the present invention related to cementless aggregate finishing coatings, the following properties can be varied for preparing different coating materials: OKP value, TiO ₂ content, aggregate filler content and Tc binder.

For differentiation based on the flexibility of non-cement aggregate finishes, Tc binder can be adjusted. For differentiation, based on the durability of non-cement aggregate finishing coatings, it is possible to adjust the OKP in the coating material. For differentiation based on the coloring of non-cement aggregate finishes, it is possible to control the content of TiO ₂ , the type and concentration of the dye. For differentiation based on the texture of cementless aggregate finishing coatings, it is possible to adjust the particle size class and the content of coarse aggregate filler, as well as the ratio between coarse and fine aggregate fillers. To achieve these different properties, you can prepare a set of semi-finished paints, as presented in the examples 54 to 58 below, and mix them in appropriate quantities to prepare materials for cementless aggregate finishing coatings, thereby varying their properties described above.

In another preferred embodiment, such semi-finished paints can be used in the methods of the invention to produce a number of coating materials that can be used when some of the coating materials include opacifying pigments and / or fillers and when some of the coating materials do not contain giving opaque pigments ("transparent"). These coatings can be applied to a wide variety of substrates, including metals, wood and cement substrates, such as concrete roofing tiles.

In another preferred embodiment, such semi-finished inks can be used in the implementation of the methods of the invention in the preparation of a number of lines of printing inks that can find a number of applications, including, although not limited to, inks for gift wrapping, for printing on corrugated substrate, newspaper paper, paperboard, labels, on bags for packing the contents of freezers, on bags for department stores, on metal films, foil; as well as for coatings on top of a drawing or text, applied for ordinary purposes, such as imparting water resistance, abrasion resistance and a high degree of slip.

All ranges of quantities indicated in the present description are inclusive of both the minimum and maximum quantities between which these ranges are combined.

Test methods

Stormer viscosity of semi-finished paints is determined according to ASTM standard, method D562. The Brookfield viscosity of the semi-finished binder paints and finished paints is determined using a Brookfield viscometer with a shaft No. 4 at a rotation speed of 6 rpm The viscosity of ICI semi-finished paints and finished paints is determined according to ASTM standard, method D3205-77. The glass transition temperature ("Tc") can be determined by differential scanning calorimetry at a rate of 20 ° C / min.

EXAMPLES

Example 1

This example describes the preparation of a white semi-finished paint, which was prepared by combining the following components:

Component Quantity (lbs / 100 gallons) Pigment - suspension of titanium dioxide (76.5% dry matter) (Ti-Pure ™ R-746 - DuPont) 1152.25 Dispersant (Tamol ™ 1124 - Rohm and Haas) 7.06 Defoamer (Drewplus ™ L-475) 1.00 The binder is acrylate resin (50% dry matter at Tc 28 ° C) (Rhoplex ™ SG-10M, Rohm and Haas) 166.32 Opacifying additive cellular latex particles (Ropaque ™ OP-96 - Rohm and Haas) 151.80 Coalescent Agent (Texanol ™) 12.95 Rheological Modifier (Acrysol ™ RM-8W — Roh and Haas) 12.76 The base is ammonia (28% solution) 1.65

Prefabricated paint was prepared using a laboratory mixer with a stirrer blade tilted at an angle of 45 °. Water, dispersant and antifoam were combined and mixed. A suspension of titanium dioxide was slowly added and the mixture was stirred for 15 to 20 minutes. Then a binder, a coalescence agent, a rheological modifier, ammonia and, if necessary, an additional amount of water were added.

Prefabricated paint was characterized by a total volume of 100 gallons, a total weight of 1,505.8 pounds, a total OKP of 80.0%, a volumetric dry matter content of 44.0%, a mass dry matter content of 67.1%, a density of 15.058 pounds / gallon, 0.40 % dispersant for dry pigment and 10.0% coalescent agent for dry matter latex. The values of its initial and equilibrium viscosity according to Stormer were 88 and 90 KU. The values of its initial and equilibrium pH were 8.8 and 8.6.

Example 2

This example describes the preparation of a filler prefabricated paint with pigment for outdoor use. It was prepared according to the above by combining the following components:

Component Quantity (lbs / 100 gallons) Pigment - nephelinsenitis (with particles of 7.5 microns) (Minex ™ 4) 784.30 Dispersant (Tamol ™ 1124 - Rohm and Haas) 7.84 Defoamer (Drewplus ™ L-475) 2.00 The binder is acrylate resin (53.5% dry matter at Tc 18 ° C) (Rhoplex ™ ML-200, Rohm and Haas) 157.49 Coalescent Agent (Texanol ™) 5.90 Rheological properties modifier (Acrysol ™ RM-8W - Rohm and Haas) 2,55 Water 368.86

Prefabricated paint was characterized by a total volume of 100 gallons, a total weight of 1328.9 pounds, a total OKP of 80.0%, a volumetric dry matter content of 45.0%, a mass dry matter content of 65.4%, a density of 13.29 pounds / gallon, a total of 0.50% dispersant per dry pigment; and a total of 7.0% coalescent agent per dry binder. The values of its initial and equilibrium viscosity according to Stormer were 90 and 93. The values of its initial and equilibrium pH were 8.9 and 8.7.

Example 3

This example describes the preparation of a filling prefabricated paint with pigment for internal work, which was prepared according to the above by combining the following components:

Component Quantity (lbs / 100 gallons) Pigment - calcium carbonate (with a particle size of 12 microns) (Omyacarb ™ 12) 405.67 Pigment - calcium carbonate (with a particle size of 3.2 microns) (Vicron ™ 15-15) 203.59 Pigment - aluminum silicate (with a particle size of 1.4 microns) (Optiwhite ™) 165.41 Dispersant (Tamol ™ 1124 - Rohm and Haas) 7.75 Defoamer (Drewplus ™ L-475) 1.00 Binder - vinyl acetate-acrylate resin (55% dry matter at Tc 14 ° C) (Res ™ 3803 - Rohm and Haas) 157.61 Coalescent Agent (Texanol ™) 6.07 Rheological Properties Modifier - GEUP (Acrysol ™ RM-2020-NPR - Rohm and Haas) 17.53 The base is ammonia (28% solution) 0.87 Water 356.59

Prefabricated paint was characterized by a total volume of 100 gallons, a total mass of 1322.1 pounds, a total OKP of 80%, a volumetric dry matter content of 45%, a mass dry matter content of 65.15%, a density of 13.2210 pounds / gallon, 0.50% of the dispersant dry pigment and 7.00% coalescent agent on a dry binder. The values of its initial and equilibrium viscosity according to Stormer were 94 and 97. Both values of its initial and equilibrium pH were 9.2.

Example 4

This example describes a vinyl acetate-acrylate latex polymer binder prefabricated paint, which was prepared as described above, except that the binder, antifoam, coalescent agent, ammonia solution, water and rheological modifier were combined and mixed. Used the following components in the following quantities:

Component Quantity (lbs / 100 gallons) Defoamer (Drewplus ™ L-475) 8.00 Binder - vinyl acetate-acrylate resin (55% dry matter at Tc 14 ° C) (Res ™ 3803 - Rohm and Haas) 788.06 Coalescent Agent (Texanol ™) 30.34 Rheological Properties Modifier - GEUP (Acrysol ™ SCT-275 - Rohm and Haas) 3.02 The base is ammonia (28% solution) 1.95 Water 60.08

The prefabricated paint was characterized by a total volume of 100 gallons, a total weight of 891.5 pounds, a bulk solids content of 45.0%, a mass dry matter content of 48.6%, a density of 8.91 pounds / gallon and 7.0% dry coalescent agent binder. The values of its initial and equilibrium viscosity according to Stormer were 88 and 90. The values of its initial and equilibrium pH were 8.6 and 8.4. Its Brookfield equilibrium viscosity should have been less than 10,000 cP.

Example 5

This example describes a matte acrylate binder prefabricated paint, which was prepared according to the above by combining the following components:

Component Quantity (lbs / 100 gallons) Defoamer (Drewplus ™ L-475) 8.00 The binder is acrylate resin (53.5% dry matter at Tc 18 ° C) (Rhoplex ™ ML-200 - Rohm and Haas) 769.96 Coalescent Agent (Texanol ™) 28.83 Rheological Properties Modifier (GEUP) (Acrysol ™ RM-8W - Rohm and Haas) 1.15 The base is ammonia (28% solution) 0.57 The solvent is propylene glycol. 60.00 Water 12.84

The prefabricated paint was characterized by a total volume of 100 gallons, a total mass of 881.4 pounds, a volumetric dry matter content of 44.0%, a mass dry matter content of 46.7%, a density of 8.81 pounds / gallon and 7.0% dry coalescent agent binder. The values of its initial and equilibrium viscosity according to Stormer were 91 and 89. Both values of its initial and equilibrium pH were 8.9 / 9.0. Its Brookfield equilibrium viscosity should have been less than 10,000 cP.

Example 6

This example describes a glossy acrylate binder semi-finished paint, which was prepared according to the above by combining the following components:

Component Quantity (lbs / 100 gallons) Defoamer (Drewplus ™ L-475) 8.00 Binder - acrylate resin (50% dry matter at Tc 28 ° C) (Rhoplex ™ SG-10M - Rohm and Haas) 737.08 Coalescent Agent (Texanol ™) 36.85 Rheological Properties Modifier - GEUP (Acrysol ™ RM-8W - Rohm and Haas) 11.62 The base is ammonia (28% solution) 0.35 The solvent is propylene glycol. 60.00 Water 21.26

The prefabricated paint was characterized by a total volume of 100 gallons, a total mass of 875.2 pounds, a volumetric dry matter content of 39.0%, a mass dry matter content of 42.11%, a density of 8.75 pounds / gallon and 10.0% dry coalescent agent binder. The values of its initial and equilibrium viscosity according to Stormer were 97 and 98. The values of its initial and equilibrium pH were 9.0. Its Brookfield equilibrium viscosity should have been less than 10,000 cP.

Example 7

This example describes the preparation of a white pigment prefabricated paint, including solvent-free acrylate binder, without the use of a coalescent agent. The components were mixed as described in example 1, using the following components in the following amounts:

Component Quantity (lbs / 100 gallons) Pigment - titanium dioxide (Ti-Pure ™ R-706 - DuPont) 734.49 Opacifying additive cellular latex particles (Ropaque ™ OP-96 - Rohm and Haas) 164.43 Dispersant (Tamol ™ 731 - Rohm and Haas) 29.38 Nonionic Surfactant (Triton ™ CF-10) 2.00 Biocide [Kathon ™ LX (1.5%) - Rohm and Haas] 2.00 Defoamer (Foamaster ™ VL) 3.00 The binder is an acrylate copolymer (43.5% dry matter at Tc 28 ° C) (Rhoplex ™ SF-012 - Rohm and Haas) 165.96 Rheological Properties Modifier - GEUP (Acrysol ™ RM-825 - Rohm and Haas) 5.00 Rheological Properties Modifier - GEUP (Acrysol ™ RM-2020 NPR - Rohm and Haas) 42.69 The base is ammonia (28% solution) 0.49 Water 250,13

The prefabricated paint was to have a total volume of 100 gallons, a total weight of 1,401.3 pounds, a total OKP of 80.0%, a volumetric dry matter content of 40.0%, a mass dry matter content of 61.1%, a density of 14.01 lbs / gallon and 1.0% dispersant per dry pigment. Its calculated Stormer viscosity was 102 KU. Its pH was between 8.5 and 9.0.

Example 8

This example describes the preparation of a semi-finished filling paint with pigment for outdoor use with a solvent-free acrylate binder without the use of a coalescent agent. The components were mixed as described in example 1, using the components in quantities shown below:

Component Quantity (lbs / 100 gallons) Pigment - nephelinsenitis (with particles of 7.5 microns) (Minex ™ 4) 697.16 Dispersant (Tamol ™ 731 - Rohm and Haas) 27.89 Nonionic Surfactant (Triton ™ CF-10) 2.00 Biocide [Kathon ™ LX (1.5%) - Rohm and Haas] 2.00 Defoamer (Foamaster ™ VL) 3.00 The binder is acrylate resin (46.5% dry matter at Tc 1 ° C) (Primal ™ SF-015 - Rohm and Haas) 160.84 Rheological Properties Modifier - GEUP (Acrysol ™ RM-2020 NPR - Rohm and Haas) 101.80 Water 284.47

The finished prefabricated paint was to have a total volume of 100 gallons, a total weight of 1280.9 pounds, a total OKP of 80.0%, a volumetric dry matter content of 40.0%, a mass dry matter content of 60.27%, a density of 12.81 pounds / gallon and 1.0% dispersant per dry pigment. Its Stormer viscosity should have been 95 KU. Its pH should have been between 8.5 and 9.0. If this was not so, then the pH was adjusted as described in example 7.

Example 9

This example describes the preparation of a filling prefabricated paint with pigment for internal use, including a solvent-free vinyl acetate-acrylate binder, without the use of a coalescent agent. The components were mixed as described in example 1, using the components in quantities shown below:

Component Quantity (lbs / 100 gallons) Pigment - Calcium Carbonate (3.2 micron particle size) (Snowflake ™) 451.20 Pigment - aluminum silicate (with a particle size of 1.4 microns) (Optiwhite ™) 220.37 Dispersant (Tamol ™ 1254 - Rohm and Haas) 19.19 Nonionic Surfactant (Triton ™ CF-10) 2.00 Biocide [Kathon ™ LX (1.5%)] 2.00 Defoamer (Foamaster ™ VL) 3.00 Binder - vinyl acetate-acrylate resin (55% dry matter) (Rovace ™ 9900) 139.86 Rheological Modifier - GMRP (Acrysol ™ DR-3) 9.00 The base is ammonia (28% solution) 0.86 Water 405.69

The finished prefabricated paint was to have a total volume of 100 gallons, a total mass of 1254.9 pounds, a total OKP of 80.0%, a bulk solids content of 40.0%, a mass dry matter content of 59.65%, a density of 12.55 pounds / gallon and 1.0% dispersant per dry pigment. Its Stormer viscosity should have been 95 KU. Its pH should have been between 8.5 and 9.0.

Example 10

This example describes the preparation of a vinyl acetate-acrylate latex polymer binder prefabricated paint comprising a solvent-free vinyl acetate-acrylate binder without a coalescent agent. The components were mixed as described in Example 4 using the components in the amounts given below:

Component Quantity (lbs / 100 gallons) Binder - vinyl acetate-acrylate resin (55% dry matter at Tc 10 ° C) (Rovace ™ 9900) - Rohm and Haas) 699.25 Defoamer (Foamaster ™ VL) 3.00 Rheological Modifier - GMRP (Acrysol ™ DR-3) 12.96 The base is ammonia (28% solution) 2.90 Water 405.69

The finished semi-finished paint was to have a total volume of 100 gallons, a total weight of 885.2 pounds, a volumetric dry matter content of 40.0%, a mass dry matter content of 43.5% and a density of 8.85 pounds / gallon. Its Stormer viscosity should have been 99 KU. Its Brookfield viscosity should have been less than 10,000 cP. Its pH should have been between 8.5 and 9.0.

Example 11

This example describes the preparation of a matte latex polymer binder prefabricated paint, including a solvent-free acrylate binder, without a coalescent agent. The components were mixed as described in Example 4 using the components in the amounts given below:

Component Quantity (lbs / 100 gallons) Defoamer (Foamaster ™ VL) 8.00 The binder is an acrylate copolymer (43.5% dry matter at Tc -2 ° C) (Rhoplex ™ SF-012 - Rohm and Haas) 723.77 Rheological Properties Modifier - GEUP (Acrysol ™ RM-2020 NRP - Rohm and Haas) 3.00 Water 133.75

The finished prefabricated paint was to have a total volume of 100 gallons, a total weight of 868.5 pounds, a volumetric dry matter content of 36.0%, a mass dry matter content of 38.8%, and a density of 8.69 pounds / gallon. Its Stormer viscosity should have been 99 KU. Its Brookfield viscosity should have been less than 10,000 cP. Its pH should have been between 8.5 and 9.0. If this was not the case, then the pH was adjusted as discussed above.

Example 12

This example describes the preparation of a glossy latex polymer binder prefabricated paint using a solvent-free acrylate binder and without a coalescent agent. The components were mixed as described in Example 4 using the components in the amounts given below:

Component Quantity (lbs / 100 gallons) Defoamer (Foamaster ™ VL) 8.00 The binder is an acrylate copolymer (43.5% dry matter at Tc -2 ° C) (Rhoplex ™ SF-012 - Rohm and Haas) 767.57 Rheological Properties Modifier - GEUP (Acrysol ™ RM-2020 NRP - Rohm and Haas) 23.00

The prefabricated paint was to have a total volume of 100.0 gallons, a total weight of 860.4 pounds, a volumetric dry matter content of 37.0%, a mass dry matter content of 38.8%, and a density of 8.60 lb / gallon. Its Stormer viscosity should have been 99 KU. Its Brookfield viscosity should have been less than 10,000 cP. Its pH should have been between 8.5 and 9.0. if it was not, then it was regulated as discussed above.

Example 13

This example describes the preparation of a white pigment prefabricated paint using glossy grade titanium dioxide for internal work, which was prepared by combining the following components:

Component Quantity (lbs / 100 gallons) Pigment - titanium dioxide (Ti-Pure ™ R-900 - DuPont) 734.49 Opacifying additive - cellular latex particles (30.5% dry matter) (Ropaque ™ Ultra - Rohm and Haas) 164.43 Dispersant (Tamol ™ 1254 - Rohm and Haas) 20,99 Nonionic Surfactant (Triton ™ CF-10) 2.00 Biocide [Kathon ™ LX (1.5%)] 2.00 Defoamer (Foamaster ™ VL Source) 3.00 Binder - vinyl acetate-acrylate resin (55% dry matter at Tc 14 ° C) (Res 3083 - Rohm and Haas) 140.10 Coalescent Agent (Texanol ™) 11.37 Rheological Modifier - GMRP (Acrysol ™ DR-3) 11.47 The base is ammonia (28% solution) 1.20 The solvent is propylene glycol. 50.00 Water 264.38

The prefabricated paint was characterized by a total volume of 100 gallons, a total weight of 1405.4 pounds, a total OKP of 80%, a volumetric dry matter content of 40%, a mass dry matter content of 61.25%, a density of 14.05 pounds / gallon, 1.0% dispersant dry pigment and 9.0% coalescent agent on a dry binder. Stormer viscosity was 100 KU. Brookfield viscosity was 15300 cP. The pH value was 8.8.

Example 14

This example describes the preparation of a white pigment prefabricated paint using glossy grade titanium dioxide for outdoor applications, which was prepared by combining the following components:

Component Quantity (lbs / 100 gallons) Pigment - titanium dioxide (Ti-Pure ™ R-706 - DuPont) 734.56 Opacifying additive - cellular latex particles (30.5% dry matter) (Ropaque ™ Ultra - Rohm and Haas) 164.44 Dispersant (Tamol ™ 731 - Rohm and Haas) 29.38 Nonionic Surfactant (Triton ™ CF-10) 2.00 Biocide [Kathon ™ LX (1.5%)] 2.00 Defoamer (Foamaster ™ VL Source) 3.00 Binder-acrylate copolymer (50% dry matter at Tc 28 ° C) (Rhoplex ™ SG-10M - Rohm and Haas) 151.20 Coalescent Agent (Texanol ™) 12.49 Rheological Properties Modifier - GEUP (Acrysol ™ RM-2020 NRP - Rohm and Haas) 42.69 The base is ammonia (28% solution) 0.49 Propylene glycol solvent 50.00 Water 211.34

The prefabricated paint was characterized by a total volume of 100 gallons, a total weight of 1403.6 pounds, a total OKP of 80%, a volumetric dry matter content of 40%, a mass dry matter content of 61.2%, a density of 14.04 pounds / gallon, 1.0% dispersant dry pigment and 9.0% coalescent agent on a dry binder. Stormer viscosity was 100 KU. Brookfield viscosity was 4010 cP. The pH value was 8.8.

Example 15

This example describes the preparation of a filler prefabricated paint with pigment for outdoor use. It was prepared by combining the following components:

Component Quantity (lbs / 100 gallons) Pigment - nephelinsenitis (with particles of 7.5 microns) (Minex ™ 4) 697.16 Dispersant (Tamol ™ 731 - Rohm and Haas) 27.89 Nonionic Surfactant (Triton ™ CF-10) 2.00 Biocide [Kathon ™ LX (1.5%) - Rohm and Haas] 2.00 Defoamer (Foamaster ™ VL) 3.00 The binder is acrylate resin (53.5% dry matter at Tc 18 ° C) (Rhoplex ™ Multilobe 200 - Rohm and Haas) 139.98 Coalescent Agent (Texanol ™) 5.24 Rheological properties modifier - GEUP (Acrysol ™ RM-2020 - Rohm and Haas) 101.80 The solvent is propylene glycol. 50.00 Water 254.40

The finished prefabricated paint was characterized by a total volume of 100 gallons, a total weight of 1281.5 pounds, a total OKP of 80.0%, a volumetric dry matter content of 40.0%, a mass dry matter content of 60.3%, a density of 12.81 pounds / gallon, 1 , 0% dispersant per dry pigment, and a total of 7.0% coalescent agent per dry binder. Stormer viscosity was 96 KU. Brookfield viscosity was 7210 cP. The pH value was equal to 9.8.

Example 16

This example describes the preparation of a filling prefabricated paint with pigment for interior use. It was prepared by combining the following components:

Component Quantity (lbs / 100 gallons) Pigment - Calcium Carbonate (5 micron particle size) (Snowflake ™) 451.20 Pigment - aluminum silicate (with a particle size of 1.4 microns) (Optiwhite ™) 220.37 Dispersant (Tamol 1254 - Rohm and Haas) 19.19 Nonionic Surfactant (Triton ™ CF-10) 2.00 Biocide [Kathon ™ LX (1.5%) - Rohm and Haas] 2.00 Defoamer (Foamaster ™ VL) 3.00 Binder - vinyl acetate-acrylate resin (55% dry matter at Tc 14 ° C) (Res 3083 - Rohm and Haas) 140.10 Coalescent Agent (Texanol ™) 6.93 Rheological Properties Modifier - GMRP (Acrysol ™ DR-3 by Rohm and Haas) 11.00 The base is ammonia (28% solution) 0.86 The solvent is propylene glycol. 50.00 Water 348.48

The finished prefabricated paint was characterized by a total volume of 100 gallons, a total mass of 1255.1 pounds, a total OKP of 80.0%, a volumetric dry matter content of 40.0%, a mass dry matter content of 59.7%, a density of 12.55 pounds / gallon, 1 , 0% dispersant per dry pigment, and a total of 9.0% coalescent agent per dry binder. Stormer viscosity was 102 KU. Brookfield viscosity was 3410 cP. The pH value was 8.9.

This example describes the preparation of a vinyl acetate-acrylate binder prefabricated paint. It was prepared by combining the following components:

Component Quantity (lbs / 100 gallons) Defoamer (Foamaster ™ VL) 3.00 Binder - vinyl acetate-acrylate resin (55% dry matter at Tc 14 ° C) (Res 3083 - Rohm and Haas) 700,48 Coalescent Agent (Texanol ™) 34.67 Rheological Properties Modifier - GMRP (Acrysol ™ DR-3 by Rohm and Haas) 12.96 The base is ammonia (28% solution) 2.90 The solvent is propylene glycol. 50.00 Water 83.48

The prefabricated paint was characterized by a total volume of 100 gallons, a total weight of 887.5 pounds, a volumetric dry matter content of 40.0%, a mass dry matter content of 43.4%, a density of 8.88 pounds / gallon and 9.0% dry coalescent agent binder. Its Stormer viscosity was 98.0 KU. Brookfield viscosity was 13,600 cP. Its pH value was 9.0.

Example 18

This example describes the preparation of a matte acrylate binder prefabricated paint. It was prepared by combining the following components:

Component Quantity (lbs / 100 gallons) Defoamer (Foamaster ™ VL) 3.00 The binder is acrylate resin (53.5% dry matter at Tc 18 ° C) (Rhoplex ™ Multilobe 200 - Rohm and Haas) 699.92 Coalescent Agent (Texanol ™) 26.21 Rheological Properties Modifier - GEUP (Acrysol ™ RM-2020 NPR - Rohm and Haas) 1.44 The base is ammonia (28% solution) 0.35 The solvent is propylene glycol. 50.00 Water 96.59

The prefabricated paint was characterized by a total volume of 100 gallons, a total weight of 877.5 pounds, a volumetric dry matter content of 40.0%, a mass dry matter content of 42.7%, a density of 8.78 pounds / gallon and 7.0% dry coalescent agent binder. Its Stormer viscosity was 94.0 KU. Brookfield viscosity was 4900 cP. Its pH value was 8.9.

Example 19

This example describes the preparation of a glossy acrylate binder prefabricated paint. It was prepared by combining the following components:

Component Quantity (lbs / 100 gallons) Defoamer (Foamaster ™ VL) 3.00 The binder is an acrylate copolymer (50% dry matter at Tc 28 ° C) (Rhoplex ™ SG-10M - Rohm and Haas) 755,99 Coalescent Agent (Texanol ™) 37.80 Rheological Properties Modifier - GEUP (Acrysol ™ RM-2020 NPR - Rohm and Haas) 11.62 The base is ammonia (28% solution) 0.35 The solvent is propylene glycol. 50.00 Water 17.68

The prefabricated paint was characterized by a total volume of 100 gallons, a total weight of 876.4 pounds, a volumetric dry matter content of 40.0%, a mass dry matter content of 43.1%, a density of 8.76 pounds / gallon and 10.0% dry coalescent agent binder. Its Stormer viscosity was 96 KU. Brookfield viscosity was 5,000 cP. Its pH value was 8.8.

Example 20

This example describes the preparation of a white semi-finished paint by combining the following components:

Component Quantity (lbs / 100 gallons) Pigment - titanium dioxide (Ti-Pure ™ R-706 - DuPont) 1001.66 Dispersant (Tamol ™ 1124 - Rohm and Haas) 20.03 Defoamer (Drewplus ™ L-475) 1.00 The binder is acrylate resin (50% dry matter at Tc 28 ° C) (Rhoplex ™ SG-10M - Rohm and Haas) 189.00 Opacifying additive - cellular latex particles (Ropaque ™ OP-96 - Rohm and Haas) 172.50 Coalescent Agent (Texanol ™) 14.72 Rheological Modifier (Acrysol ™ RM-8W - Rohm and Haas) 2.00 The base is ammonia (28% solution) 1.65 Water 200,44

Prefabricated paint was characterized by a total volume of 100 gallons, a total mass of 1603.0 pounds, a total OKP of 80.0%, a volumetric dry matter content of 50.0%, a mass dry matter content of 71.7%, a density of 16.03 pounds / gallon, 1 , 0% dispersant on dry pigment and 10.0% coalescent agent on dry matter latex.

Example 21

This example describes the preparation of a white pigment prefabricated paint with a pigment dyed cellular polymer beads. This pigment-colored cellular polymer beads was characterized by a particle size of 12.5 μm, a titanium dioxide content of about 7% (dry weight / dry weight) and a cavity volume fraction of about 77%. The components were mixed as described in example 1, using the components in quantities shown below:

Component Quantity (lbs / 100 gallons) Pigment Dyed Cellular Polymer Beads (Spindrift ™ 25) 733.00 Dispersant (Tamol ™ 1124 - Rohm and Haas) 0 Defoamer (Drewplus ™ L-475) 2.00 The binder is acrylate resin (53.5% dry matter at Tc 18 ° C) (Rhoplex ™ ML-200 - Rohm and Haas) 154 Coalescent Agent (Texanol ™) 5.90 Rheological Modifier (Acrysol ™ RM-8W - Rohm and Haas) 2,55 Water 15.89

The prefabricated paint was to have a total volume of 100 gallons, a total weight of 913.3 pounds, a total OKP of 80.0%, a volumetric dry matter content of 44.0%, a mass dry matter content of 28.28% and a density of 9.13 pounds / gallon . Its Stormer viscosity should have been 91 KU. Its pH should have been between 8.5 and 9.0. If this was not so, then the pH was adjusted as described in example 7.

Example 22

This example describes the preparation of a filling prefabricated paint with pigment for outdoor work by combining the following components:

Component Quantity (lbs / 100 gallons) Pigment - nephelinsenitis (with particles of 7.5 microns) (Minex ™ 4) 871.44 Dispersant (Tamol ™ 1124 - Rohm and Haas) 8.71 Defoamer (Drewplus ™ L-475) 2.00 The binder is acrylate resin (60.5% dry matter at Tc 16 ° C) (Rhoplex ™ AC-264 - Rohm and Haas) 154.74 Coalescent Agent (Texanol ™) 6.56 Rheological Modifier (Acrysol ™ RM-8W - Rohm and Haas) 3.00 Water 326.08

The finished prefabricated paint was to have a total volume of 100 gallons, a total weight of 1382.5 pounds, a total OKP of 80.0%, a volumetric dry matter content of 50.0%, a mass dry matter content of 69.8%, a density of 13.82 pounds / gallon , 0.5% dispersant on dry pigment and 7.0% coalescent agent on dry matter latex.

Example 23

This example describes the preparation of a filling prefabricated paint with pigment for internal work by combining the following components:

Component Quantity (lbs / 100 gallons) Pigment - calcium carbonate (with a particle size of 12 microns) (Omyacarb ™ 12) 450.67 Pigment - calcium carbonate (with a particle size of 3.2 microns) (Vicron ™ 15-15) 226.17 Pigment - aluminum silicate (with a particle size of 1.4 microns) (Optiwhite ™) 183.76 Dispersant (Tamol ™ 1124 - Rohm and Haas) 8.61 Defoamer (Drewplus ™ L-475) 1.00 Binder - vinyl acetate-acrylate resin (55% dry matter at Tc 14 ° C) (Res 3803) 175.09 Coalescent Agent (Texanol ™) 6.74 Rheological Properties Modifier - GEUP (Acrysol ™ SCT-275) 15.00 The base is ammonia (28% solution) 0.87 Water 308.13

The finished prefabricated paint was to have a total volume of 100 gallons, a total weight of 1376.0 pounds, a total OKP of 80.0%, a volumetric dry matter content of 50.0%, a mass dry matter content of 69.5%, a density of 13.76 pounds / gallon , 0.5% dispersant on dry pigment and 7.0% coalescent agent on dry matter latex.

Example 24

This example describes the preparation of vinyl acetate-acrylate binder prefabricated paint by combining the following components:

Component Quantity (lbs / 100 gallons) Defoamer (Drewplus ™ L-475) 2.00 Binder - vinyl acetate-acrylate resin (55% dry matter at Tc 14 ° C) (Res 3803) 875.62 Coalescent Agent (Texanol ™) 13.00 Rheological Properties Modifier - GEUP (Acrysol ™ SCT-275 - Rohm and Haas) 9.29

The prefabricated paint was to have a total volume of 100 gallons, a total weight of 899.9 pounds, a total OKP of 0.0%, a volumetric dry matter content of 50.0%, a mass dry matter content of 53.2%, a density of 8.99 lbs / gallon and 10.0% coalescent agent on latex dry matter.

Example 25

This example describes the preparation of a matte acrylate binder prefabricated paint by combining the following components:

Component Quantity (lbs / 100 gallons) Defoamer (Drewplus ™ L-475) 8.00 The binder is acrylate resin (60.5% dry matter at Tc 16 ° C) (Rhoplex ™ AC-264 - Rohm and Haas) 773.67 Coalescent Agent (Texanol ™) 23.40 Rheological Properties Modifier (GEUP) (Acrysol ™ RM-8W - Rohm and Haas) 13 The base is ammonia (28% solution) 0.50 The solvent is propylene glycol. 60.00 Water 1.84

The prefabricated paint was to have a total volume of 100 gallons, a total mass of 880.4 pounds, a total OKP of 0.0%, a volumetric dry matter content of 50.0%, a mass dry matter content of 53.2%, a density of 8.80 lbs / gallon and 5.0% coalescent agent on latex dry matter.

Example 26

This example describes the preparation of a glossy acrylate binder prefabricated paint by combining the following components:

Component Quantity (lbs / 100 gallons) The binder is acrylate resin (50% dry matter at Tc 28 ° C) (Rhoplex ™ SG-10M - Rohm and Haas) 836.85 Coalescent Agent (Texanol ™) 41.84

The finished prefabricated paint was to have a total volume of 100 gallons, a total mass of 878.7 pounds, a total OKP of 0.0%, a bulk solids content of 44.3%, a mass dry matter content of 47.4%, a density of 8.78 pounds / gallon and 10.0% coalescent agent on latex dry matter.

Example 27

This example describes the preparation of nine matt latex paints for exterior work with varying quality and tone using different combinations of white pigment prefabricated paint from example 14, filler prefabricated paint with pigment for outdoor work from example 15, vinyl acetate-acrylate (PVA) binder prefabricated paint from example 17 and a matte acrylate binder prefabricated paint from example 18. Paints were prepared by adding a white pigment prefabricated paint and filling prefabricated paint pigment for outdoor work due semi-finished paint and thorough mixing.

Paint number OKP (%) Volume content of dry matter (%) Semi-finished paints (wt.) Water (wt.) White Filling for outdoor work PVA binder Matte Acrylate Binder (Note 14) (Note 15) (Note 17) (Note 18) 27-1 45.0 35.0 395.53 269.60 - 335.92 104.34 27-2 50,0 30,0 317.19 311.10 - 246.80 208.68 27-3 50,0 30,0 263.69 359.94 197.64 51.38 208.68 27-4 42.5 35.0 197.77 415.12 - 359.92 104.34 27-5 47.5 30,0 158.60 425.86 - 267.37 208.68 27-6 47.5 30,0 131.84 450.28 214.11 55.67 208.68 27-7 40,0 35.0 - 560.64 - 383.91 104.34 27-8 45.0 30,0 - 540.62 - 287.93 208.68 27-9 45.0 30,0 - 540.62 230.58 59.95 208.68

Paints 27-1, 27-4 and 27-7 were paints of the highest quality in light, medium and saturated colors; paints 27-2, 27-5 and 27-8 were first-class paints of light, medium and saturated colors; and paints 27-3, 27-6 and 27-9 were paints of the second grade of light, medium and saturated colors.

Example 28

This example describes the preparation of nine satin latex paints for outdoor applications with varying quality and tone using different combinations of white pigment prefabricated paint and filling prefabricated paint with pigment for outdoor work from examples 14 and 15, respectively, and vinyl acetate-acrylate (PVA) binder and matte acrylate binder prefabricated paints from examples 17 and 18. Paints were prepared as described above.

Paint number OKP (%} Volume content of dry matter (%) Semi-finished paints (wt.) Water (wt.) White Filling for outdoor work PVA binder Matte Acrylate Binder (Note 14) (Po. 15) (Note 17) (Note 18) 28-1 35.0 35.0 395.53 129.44 - 431.90 104.34 28-2 37.0 30,0 351.59 123.51 - 353.75 208.68 28-3 40,0 26.0 263.69 175.73 228.35 59.41 292.15 28-4 32,5 36.0 197.77 287.98 - 468.92 83.47 28-5 34.5 30,0 175.75 253.98 - 374.31 208.68 28-6 37.5 26.0 131.84 270.07 242.63 63.12 292.12 28-7 30,0 36.0 - 432.50 - 493.60 83.47 28-8 32,0 30,0 - 384.44 - 394.88 208.68 28-9 35.0 26.0 - 364.42 256.87 66.86 292.15

Paints 28-1, 28-4 and 28-7 were paints of the highest quality in light, medium and saturated colors; paints 28-2, 28-5 and 28-8 were first-class paints of light, medium and saturated colors; and paints 28-3, 28-6 and 28-9 were paints of the second grade of light, medium and saturated colors.

Example 29

This example describes the preparation of nine glossy latex paints for outdoor use using different combinations of white pigment and filling prefabricated paints with pigments for outdoor work from examples 14 and 15 and vinyl acetate-acrylate (PVA) binder and glossy acrylate binder prefabricated paints from examples 17 and 19. These paints were prepared as described above.

Paint number OKP (%) Volume content of dry matter (%) Semi-finished paints (wt.) Water (wt.) White PVA binder Glossy Acrylate Binder (Note 14) (Note 17) (Note 19) 29-1 26.0 35.0 435.66 - 494.85 104.34 29-2 30,0 30,0 460.50 - 413.60 166.94 29-3 30,0 30,0 429.93 304.15 88.51 208.68 29-4 13.0 35.0 217.83 - 630.87 104.34 29-5 15.0 30,0 230.25 - 557.38 166.94 29-6 15.0 30,0 214.96 409.14 119.06 208.68 29-7 - 35.0 - - 766.89 104.34 29-8 - 30,0 - - 701.15 166.94 29-9 - 30,0 - 514.12 149.61 208.68

Paints 29-1, 29-4 and 29-7 were paints of the highest quality in light, medium and saturated colors; paints 29-2, 29-5 and 29-8 were first-class paints of light, medium and saturated colors; and paints 29-3, 29-6 and 29-9 were paints of the second grade of light, medium and saturated colors.

Example 30

This example describes the preparation of nine matte latex paints for interior use using different combinations of white pigment and fill prefabricated paints for interior use from examples 14 and 16 and vinyl acetate-acrylate (PVA) and matte acrylate binder prefabricated paints from examples 17 and 18. These paints were prepared as described above.

Paint number OKP (%) Volume content of dry matter (%) Semi-finished paints (wt.) Water (wt.) White Filling for interior work PVA binder Matte Acrylate Binder (Note 14) (Note 16) (Note 17) (Note 18) 30-1 50,0 30,0 351.59 273.94 197.64 51.38 208.68 30-2 60.0 30,0 263.69 470.21 166.40 - 208.68 30-3 75.0 25.0 128.02 620.95 34.67 - 313.02 30-4 47.5 15.0 175.79 401.73 214.11 55.67 208.68 30-5 57.5 30,0 131.84 558.69 187.20 - 208.68 30-6 72.5 25.0 64.01 653.67 52.00 - 313.02 30-7 45.0 30,0 - 529.51 230.58 59.95 208.68 30-8 55.0 30,0 - 647.18 208.01 - 208.68 30-9 70.0 25.0 - 686.40 69.34 - 313.02

Paints 30-1, 30-4 and 30-7 are paints of the highest quality in light, medium and saturated colors; paints 30-2, 30-5 and 30-8 are first-class paints of light, medium and saturated colors; and paints 30-3, 30-6 and 30-9 are paints of the second grade of light, medium and saturated colors.

Example 31

This example describes the preparation of nine satin latex paints for interior use using white pigment and fill prefabricated paints for interior work from examples 14 and 16 and vinyl acetate-acrylate (PVA) and matte acrylate binder prefabricated paints from examples 17 and 18. These paints were prepared as described above.

Paint number OKP (%) Volume content of dry matter (%) Prefabricated paints (May.) Water (wt.) White Filling for interior work PVA binder Matte Acrylate Binder (Note 14) (Note 15) (Note 17) (Note 18) 31-1 35.0 36.0 395.53 140.51 355.75 92.49 83.47 31-2 37.0 30,0 351.59 120.98 357.77 - 208.68 31-3 40,0 20,0 263.69 172.12 288.43 - 292.15 31-4 32,5 36.0 197.77 282.06 375.51 97.96 83.47 31-5 34.5 30,0 175.79 248.76 378.57 - 208.68 31-6 37.5 26.0 131.84 264.52 306.46 - 292.15 31-7 30,0 36.0 - 423.61 395.28 102.77 83.47 31-8 32,0 30,0 - 376.54 399.37 - 208.68 31-9 35.0 26.0 - 356.93 324.49 - 292.15

Paints 31-1,31-4 and 31-7 are paints of the highest quality in light, medium and saturated colors; paints 31-2, 31-5 and 31-8 are first-class paints of light, medium and saturated colors; and paints 31-3, 31-6 and 31-9 are paints of the second grade of light, medium and saturated colors.

Example 32

This example describes the preparation of nine glossy latex paints for interior use using a white pigment prefabricated paint from example 14, vinyl acetate-acrylate (PVA) and a glossy acrylate binder prefabricated paint from examples 17 and 19. These paints were prepared as described above.

Paint number OKP (%) Volume content of dry matter (%) Semi-finished paints (wt.) Water (wt.) White PVA binder Glossy Acrylate Binder (Note 14) (Note 17) (Note 19) 32-1 26.0 35.0 435.66 - 494.85 104.34 32-2 30,0 38,0 429.93 304.15 88.51 208.68 32-3 30.1 28.0 403.18 366.31 - 250,42 32-4 13.0 35.0 217.83 - 630.87 104.34 32-5 15.0 30,0 214.96 409.14 119.06 208.68 32-6 15.0 28.0 201.59 493.78 - 250,42 32-7 - 35.0 - - 766.89 104.34 32-8 - 30,0 - 514.12 149.61 208.68 32-9 - 28.0 - 621.24 - 250,42

Paints 32-1, 32-4 and 32-7 are paints of the highest quality in light, medium and saturated colors; paints 32-2, 32-5 and 32-8 are first-class paints of light, medium and saturated colors; and paints 32-3, 32-6 and 32-9 are paints of the second grade of light, medium and saturated colors.

Example 33

This example describes the preparation of latex paint, which can be used when applying architectural coatings; it can be prepared using the white pigment prefabricated paint from Example 20, the pigment filler prefabricated paint for outdoor use from Example 22, and the matte acrylate binder prefabricated paint from Example 25. This paint was prepared as described above.

The finished paint was supposed to be a paint of the highest quality with a satin surface and light tone.

Example 34

This example describes the preparation of opaque paint for interior work with a low dry matter content using the white pigment prefabricated paint from Example 20, the filling prefabricated paint with pigment for the internal work from Example 23 and the vinyl acetate-acrylate (PVA) binder prefabricated paint from Example 24.

Example 35

This example describes the preparation of paints using prefabricated paints from examples 1 to 6. Such paints were prepared by mixing pigment prefabricated (prefabricated) paints with binder prefabricated (prefabricated) paints, then adding thickeners, water and dyes and thoroughly mixing. Stormer viscosity, ICI viscosity and pH were characterized as determined by equilibrium values.

Part A-matte outdoor paints (best and good) Paint Prefabricated Inks (lbs) Thickener (lbs) Water Dye No. White pigment Filling for outdoor work PVA binder Matte Acrylate Binder Acrysol SCT-275 Acrysol RM 2020 NPR (pounds) (pounds) (Note 1) (Note 2) (Note 4) (Note 6) 35-1 ^a 353.86 278.01 - 306.97 10.40 14.00 149.68 - 35-1 ^b 235.96 351.50 177.30 46.09 26.40 11.20 237.06 - 35-3 ^a - 516.00 - 351.00 32.68 - 146.45 162 35-4 ^b - 500.00 206.58 53.70 48.48 - 237.06 162 a The best colors of light tone and saturated tone
b Good colors of light tone and rich tone

Set equilibrium values Characteristics determined by calculation Paint number Stormer Viscosity ICI Viscosity pH Volume Weight Okp Volumetric dry matter content Mass dry matter Density (gallons) (pounds) (%) (b / gallon) (KU) (cp) (%) (%) 35-1 ⁱⁿ 102 1.15 8.76 one hundred 1112.92 45.05 35.08 50.66 11.13 35-2 ^g 101 0.87 8.30 one hundred 1085.52 50.04 30.05 45.68 10.86 35-3 ^d 110 1.90 9.02 one hundred 1046.13 39.94 35.00 47.92 10.46 35-4 ^e 121 1.80 8.70 one hundred 1045.82 45.09 29.76 43.25 10.36 at. Contained 0.44% dispersant in terms of dry pigment and 7.48% of coalescent agent in terms of dry polymer
d. Contained 0.46% dispersant in terms of dry pigment and 7.40% coalescent agent in terms of dry polymer
D. 0.50% dispersant, calculated on the dry pigment and 7.00% coalescent agent, calculated on the dry polymer
e. 0.50% of dispersant in terms of dry pigment and 7.00% of coalescent agent in terms of dry polymer were contained

Part B-Satin Outdoor Paint (Enhanced) Paint number Prefabricated Inks (lbs) Thickener (lbs) Water (pounds) Dye (pounds) White pigment Filling for outdoor work PVA binder Matte Acrylate Binder Acrysol SCT-275 Acrysol RM 2020 NPR (Note 1) (Note 2) (Note 4) (Note 6) 35-5 314.56 137.00 - 323.00 17.82 17.58 234.22 - Set equilibrium values Characteristics determined by calculation Paint number Stormer Viscosity (KU) ICI Viscosity
(cp) PH Volume (gallons) Weight (pounds) OKP (%) Volumetric dry matter content Mass dry matter Density (b / gallon) (%) (%) 35-5 104 1.19 8.95 100.00 1044.18 36.94 29.96 43.26 10.44 Contained 0.43% dispersant in terms of dry pigment and 7.43% coalescent agent in terms of dry polymer

Part B semi-gloss exterior paints (best and good) Paint number Prefabricated Inks (lbs) Thickener (lbs) Water (pounds) Dye (pounds) White pigment Filling for outdoor work PVA binder Glossy Acrylate Binder Acrysol SCT-275 Acrysol RM 2020 NPR (Note 1) (Note 2) (Note 4) (Note 5) 35-6 ^a 389.40 - - 530.37 - 15,20 98.44 - 35-7 ^b 383.98 - 85.33 294.89 22.40 26.00 217.67 - but. The best
b. Good

Set equilibrium values Characteristics determined by calculation Paint number Stormer Viscosity
(KU) ICI Viscosity
(cp) PH Volume (gallons) Weight (pounds) OKP (%) Volumetric dry matter content Mass dry matter Density (b / gallon) (%) (%) 35-6 ⁱⁿ 99 1.19 8.54 100.00 1033.41 26.00 35.00 46.91 10.33 35-7 ^g 102 1.05 8.20 100.00 1030.27 30.00 29.90 42,43 10.30 at. Contained 0.40% dispersant in terms of dry pigment and 10.00% coalescent agent in terms of dry polymer
d. 0.40% dispersant, calculated on the dry pigment and 7.97% coalescent agent, calculated on the dry polymer

Part G-matte for internal work Paint
No. Prefabricated Inks (lbs) Thickener (lbs) Water (pounds) Dye (pounds) White pigment Filling for outdoor work PVA binder Matte Acrylate Binder Acrysol SCT-275 Acrysol RM 2020 NPR (Note 1) (Note 2) (Note 4) (Note 5) 35-8 ^a 314.56 280.69 177.31 46.09 24.00 20.80 230.22 - 35-9 115.95 590.05 30.04 - 34.60 - 336.19 - 35-10 ^a - 496.07 206.55 53.67 41.92 - 236.60 162 35-11 - 643,99 62.04 - 51.36 - 320.17 162 but. Paints 35-8 and 35-10 were the best paints of light and saturated colors
Paints 35-9 and 35-11 were good colors of light and saturated colors

Set equilibrium values Characteristics determined by calculation Paint number Stormer Viscosity ICI Viscosity pH Volume (gallons) Weight (pounds) OKP (%) Volumetric dry matter content Mass dry matter Density (b / gallon) (KU) (cp) (%) (%) 35-8 99 1.05 8.45 100.00 1093.67 50.00 30.00 45.88 10.94 35-9 84 0.70 8.50 100.00 1106.83 75.15 24,99 43.08 11.07 35-10 120 1.90 8.60 100.00 1034.81 45.04 29,99 43.36 10.35 35-11 108 1.88 8.80 100.00 1077.56 70.00 25.05 41.74 10.78 In paints Nos. 34-8 to 34-11, the percentage of dispersant in terms of dry pigment was 0.45, 0.48, 0.50 and 0.50%, respectively.
In paints Nos. 34-8 to 34-11, the percentage of coalescent agent was 7.53, 7.47, 7.00 and 7.00%, respectively.

Part D-Satin Inner Paint Paint number Prefabricated Inks (lbs) Thickener (lbs) Water (pounds) Dye (pounds) White pigment Filling for outdoor work PVA binder Matte Acrylate Binder Acrysol SCT-275 Acrysol RM 2020 NPR (Note 1) (Note 3) (Note 4) (Note 5) 35-12 314.56 138.00 319.00 - 24.96 21.40 229.76 - The paint was an improved light-tone paint

Set equilibrium values Characteristics determined by calculation Paint number Stormer Viscosity ICI Viscosity pH Volume (gallons) Weight (pounds) OKP (%) Volume content of dry matter (%) Mass dry matter content (%) Density (b / gallon) (KU) (cp) 35-12 93 0.91 8.37 100.00 1047.68 37.05 29,99 43.54 10.48 The dispersant content in terms of dry pigment was 0.43%
The content of coalescent agent in terms of dry polymer was 7.42%

Part E-Half Glossy Helmets Paint number Prefabricated Inks (lbs) Thickener (lbs) Water (pounds) Dye (pounds) White pigment Filling for outdoor work PVA binder Glossy Acrylate Binder Acrysol SCT-275 Acrysol RM 2020 NPR (Note 1) (Note 3) (Note 4) (Note 6) 35-13 383.98 - 294.89 85.33 22.40 26.00 217.67 - 35-14 359.89 - 347.58 - 28.80 28.00 255.70 - Paints No. 35-13 and 35-14 were an improved and good paint bright colors

Set equilibrium values Characteristics determined by calculation Paint number Stormer Viscosity
(KU) ICI Viscosity
(cp) pH Volume (gallons) Weight (pounds) OKP (%) Volume content of dry matter (%) Mass dry matter content (%) Density (Barn / Gallon) (b / gal) 35-13 102 1.05 8.20 100.00 1030.27 30.01 29.91 42,43 10.30 35-14 101 1.19 7.90 100.00 1019.97 30.02 28.02 40.22 10,20 In paints 35-13 and 35-14, the content of dispersant in terms of dry pigment was 0.40%.
In paints 35-13 and 35-14, the content of the coalescent agent was 7.97 and 7.47%, respectively.

Example 36

This example describes the preparation of a white tinting pigment prefabricated paint for use in an elastomeric coating material. This prefabricated paint was prepared by combining the following components.

Component Quantity (lbs / 100 gallons) The binder is acrylate resin (50.5% dry matter at Tc - 16 ° C) (Rhoplex® 2438 - Rohm and Haas) 177.11 Water 257.90 Dispersant (Tamol® 165A - Rohm and Haas) 49.24 Defoamer (Nopco NXZ) 12.44 The base is ammonia (28% solution) 3.94 Coalescent Agent (Texanol) 2.68 Rheological Modifier (Acrysol® SCT-275) 5.00 Pigment - titanium dioxide (Ti-Pwe R-960 - DuPont company) 1292.48

This semi-finished paint was prepared using a high-speed dispersing device. Water, dispersant, acrylate binder, antifoam, base and rheological modifier were combined, briefly mixed at low speed and dry pigment was added. After adding all the dry pigment, the mixture had to be dispersed at high speed for 15 to 20 minutes, as is known to a person skilled in the art.

The prefabricated paint was to have a total volume of 100 gallons, a total weight of 1800.80 pounds, a total OKP of 80.00%, a bulk solids content of 50.00%, a mass dry matter content of 76.74%, a density of 18.008 pounds / gallon, and a content of dispersant 0.80% for dry pigment and coalescent agent 3.0% for dry matter latex.

Example 37

This example describes the preparation of a white tinting pigment prefabricated paint comprising zinc oxide for use in an elastomeric coating material. This prefabricated paint was prepared as described above by combining the following components.

Component Quantity (lbs / 100 gallons) The binder is acrylate resin (50.5% dry matter at Tc - 16 ° C) (Rhoplex® 2438 - Rohm and Haas) 177.11 Water 278.10 Dispersant (Tamol® 2001 - Rohm and Haas) 26,99 Surface-active substance 10.00 Defoamer (Nopco NXZ) 5.00 The base is ammonia (28% solution) 3.94 Coalescent Agent (Texanol) 2.68 Rheological Modifier (Acrysol® SCT-275) 5.00 Pigment - zinc oxide (XX-503, - Zinc Corporation of America) 283.26 Pigment - titanium dioxide (Ti-Pure R-706 - DuPont) 1133.50

The finished semi-finished paint was to have a total volume of 100 gallons, a total weight of 1925.58 pounds, a total OKP of 80.00%, an OKP, titanium dioxide of 67.90%, a volumetric dry matter content of 50.00%, a mass dry matter content of 78.22 %, density 19.2558 lbs / gallon, dispersant content 0.80% on dry pigment and coalescent agent 3.0% on dry matter latex.

Example 38

This example describes the preparation of a filler prefabricated paint for use in an elastomeric coating material. This prefabricated paint was prepared as described above by combining the following components.

Component Quantity (lbs / 100 gallons) Water 10.82 Dispersant (Tamol ™ 731 A - Rohm and Haas) 13.36 Defoamer (Nopco ™ NXZ) 6.68 The base is ammonia (28% solution) 1.79 Coalescent Agent (Texanol ™) 1.00 The binder is acrylate resin (50.5% dry matter at Tc - 16 ° C) (Rhoplex ™ 2438 - Rohm and Haas) 177.11 Pigment - Calcium Carbonate (Duramiter ™) 901.50

The prefabricated paint was to have a total volume of 100 gallons, a total weight of 1408.05 pounds, a total OKP of 80.00%, a volumetric dry matter content of 50.00%, a mass dry matter content of 70.38%, a density of 14.0805 pounds / gallon , a dispersant content of 0.30% on a dry pigment and a coalescent agent of 2.0% on a dry matter of latex.

Example 39

This example describes the preparation of an acrylate binder prefabricated paint with a low Tc and good flexibility at a low temperature. This prefabricated paint was prepared using a laboratory mixer equipped with a stirrer blade, inclined at an angle of 45 °.

Component Quantity (lbs / 100 gallons) Binder - acrylate resin (50.5% dry matter at Tc - 16 ° C) 814.71 Defoamer (Nopco NXZ) 1.33 Rheological Modifier (Natrosol 250 HR) 5.32 The solvent is propylene glycol. 26.62 The base is ammonia (28% solution) 2.66 Coalescent Agent (Texanol) 8.23 Water 6.06

The finished semi-finished paint was to have a total volume of 100 gallons, a total mass of 864.93 pounds, a volumetric dry matter content of 46.00%, a mass dry matter content of 47.57%, a density of 8.6493 pounds / gallon and a coalescent agent content of 2.0 % dry matter latex.

Example 40

This example describes the preparation of a styrene-acrylate binder prefabricated paint with a TC medium range and flexibility at a low temperature of only -5 ° C. This prefabricated paint was prepared using a laboratory mixer equipped with a stirrer blade, inclined at an angle of 45 °.

Component Quantity (lbs / 100 gallons) Binder - styrene - acrylate resin (55.0% dry matter at Tc - 5 ° C) (Rhoplex® 2019R - Rohm and Haas) 803.91 Defoamer (Nopco NXZ) 1.33 Rheological Modifier (Natrosol 250 HR) 5.32 The solvent is propylene glycol. 26.62 The base is ammonia (28% solution) 2.66 Coalescent Agent (Texanol) 8.84 Water 10.99

The prefabricated paint was to have a total volume of 100 gallons, a total weight of 859.69 pounds, a dry solids content of 50.00%, a dry solids content of 51.43%, a density of 8.5969 pounds / gallon and a coalescent agent content of 2.0 % dry matter latex.

Example 41

This example describes the preparation of a 100% acrylate binder prefabricated paint with high Tc (14 ° C) and poor flexibility at low temperature. This prefabricated paint was prepared using a laboratory mixer equipped with a stirrer blade, inclined at an angle of 45 °.

Component Quantity (lbs / 100 gallons) The binder is acrylate resin (53.5% dry matter at Tc 14 ° C) (Multilobe ^TM 200 - Rohm and Haas) 822.40 Defoamer (Nopco NXZ) 1.33 Rheological Modifier (Natrosol 250 HR) 5.32 The solvent is propylene glycol. 26.62 The base is ammonia (28% solution) 2.66 Coalescent Agent (Texanol) 26.40 Water 0.36

The finished semi-finished paint was to have a total volume of 100 gallons, a total mass of 885.11 pounds, a volumetric dry matter content of 47.00%, a mass dry matter content of 49.71%, a density of 8.8511 pounds / gallon and a coalescent agent content of 6.0 % dry matter latex.

Example 42

This example describes the preparation of 11 elastomeric compositions for wall coverings of varying quality and resistance to mold using different combinations of white pigment semi-finished paints from examples 36 and 37, filler semi-finished paints from example 38 and binder semi-finished paints from examples 39, 40 and 41. Paints prepared by adding white pigment prefabricated paint and filling prefabricated paint in a binder prefabricated paints and thorough mixing.

Semi-finished paints were mixed with each other in the amounts indicated below (table 1). All mass amounts are indicated in pounds, the total volume of each elastomeric coating material was 100 gallons, the volumetric dry matter content was adjusted to 45%.

Table 1 The mass of semi-finished paints examples Paint 36 37 38 39 40 41 Water Total 42-1 70.9 0,0 419.8 528.8 0,0 0,0 42,4 1061.9 42-2 0,0 89.3 409.9 528.8 0,0 0,0 42,4 1070.5 42-3 70.9 0,0 657.4 370.2 0,0 0,0 54.6 1153.1 42-4 0,0 89.3 647.5 370.2 0,0 0,0 54.6 1161.6 42-5 131.7 0,0 372.3 528.8 0,0 0,0 42,4 1075,2 42-6 0,0 165.9 353.9 528.8 0,0 0,0 42,4 1091.0 42-7 131.7 0,0 609.9 370.2 0,0 0,0 54.6 1166.3 42-8 0,0 165.9 591.5 370.2 0,0 0,0 54.6 1182,2 42-9 70.9 0,0 419.8 0,0 483.6 0,0 83.0 1057.3 42-10 0,0 89.3 647.5 0,0 338.5 0,0 83.0 1158.3 42-11 70.9 0,0 657.4 227.5 0,0 141.6 58.7 1014.5

The proposed OKP, TiO ₂ content, flexibility at a low temperature and the quality of finished elastomeric coatings are presented below (Table 2).

table 2 Paint Okp The presence of ZnO OKP-TiO ₂ Flexibility Quality 42-1 thirty absent 3,5 0 ° F average 42-2 thirty contains 3,5 0 ° F average 42-3 45 absent 3,5 0 ° F low 42-4 45 contains 3,5 0 ° F low 42-5 thirty absent 6.5 0 ° F high 42-6 thirty contains 6.5 0 ° F high 42-7 45 absent 6.5 0 ° F average 42-8 45 contains 6.5 0 ° F average 42-9 thirty absent 3,5 20 ° F average 42-10 45 contains 3,5 20 ° F low 42-11 45 absent 3,5 40 ° F unsatisfactory.

The above materials of elastomeric coatings showed the above series of qualities, which are determined by durability and flexibility at low temperature. These examples should not be construed as limiting. So, in particular, all pigmented and filling semi-finished paints can be prepared with and without binders, and binders can have higher Tc values than those used in these examples. In addition, this does not mean that the list of filling semi-finished paints is limited to those that used calcium carbonate, but also covers examples of those that could include other commonly used fillers, such as clays, silicas, magnesium silicates, etc. .

The materials of elastomeric coatings for use on roofs can be differentiated in the same way as elastomeric coatings for walls, with two additional options that use functional fillers, such as aluminum trihydrate (TGA), in order to promote the ability to slow down combustion and improve adhesion to special roofing substrates. The following examples are intended to illustrate the operational characteristics of the corresponding semi-finished paints when they are introduced into the composition of elastomeric roofing, and not with a limiting purpose.

Example 43

This example describes the preparation of a white pigment prefabricated paint, which was prepared by combining the following components.

Component Quantity (lbs / 100 gallons) Binder - acrylate resin (55.0% dry matter at Tc - 29 ° C) (Rhoplex® EC-1791 - Rohm and Haas) 159.75 Water 268.95 Dispersant (Tamol® 165A - Rohm and Haas) 49.24 Defoamer (Nopco NXZ) 12.44 The base is ammonia (28% solution) 3.94 Coalescent Agent (Texanol) 2.64 Rheological Modifier (Acrysol® SCT-275) 10.00 Pigment - titanium dioxide (Ti-Pure R-960 - DuPont company) 1292.48

This semi-finished paint was prepared using a high-speed dispersing device. Water, dispersant, acrylate binder, antifoam, base and rheological modifier were combined, briefly mixed at low speed, and then dry pigment was added. After adding all the dry pigment, the mixture could be dispersed at high speed for 15 to 20 minutes, as is known to a person skilled in the art.

The prefabricated paint was to have a total volume of 100 gallons, a total weight of 1,799.45 pounds, a total OKP of 80.00%, a volumetric dry matter content of 50.00%, a mass dry matter content of 76.71%, a density of 17.9956 pounds / gallon , a dispersant content of 0.80% on a dry pigment and a coalescent agent of 3.0% on a dry matter of latex.

Example 44

This example describes the preparation of a white tinting prefabricated paint for use in the preparation of coating materials that have good adhesion to asphalt roofing materials. This prefabricated paint was prepared by combining the following components.

Component Quantity (lbs / 100 gallons) Binder - Acrylate Resin (55.0% dry
substances at Tc - 8 ° C) (Lipacryl® MV-3640 - Rohm and Haas) 160.69 Water 269.12 Dispersant (Tamol® 165A - Pohm and Haas) 49.24 Defoamer (Nopco NXZ) 12.44 The base is ammonia (28% solution) 3.94 Coalescent Agent (Texanol) 2.65 Rheological Modifier (Acrysol® SCT-275) 10.00 Pigment - titanium dioxide (Ti-PureR-960 - DuPont) 1292.48

This prefabricated paint was prepared using a high-speed dispersing device, as illustrated in Example 43. The prefabricated paint was to have a total volume of 100 gallons, a total weight of 1799.56 pounds, a total OKP of 80.00%, a volumetric dry matter content of 50.00% , a mass dry matter content of 76.73%, a density of 17.9956 pounds / gallon, a dispersant content of 0.80% per dry pigment and a coalescent agent of 3.0% per dry matter latex. It was assumed that this prefabricated paint should show its best in the composition of coating materials applied to asphalt substrates.

Example 45

This example describes the preparation of a white tinting prefabricated paint comprising zinc oxide. This prefabricated paint was prepared by combining the following components.

Component Quantity (lbs / 100 gallons) Binder - acrylate resin (55.0% dry matter at Tc - 29 ° C) (Rhoplex® EC-1791 - Rohm and Haas) 159.75 272.67 Dispersant (Tamol® 731 A - Rohm and Haas) 44.09 Surfactant (Triton® X-405 - Union Carbide) 10.00 Defoamer (Nopco NXZ) 5.00 The base is ammonia (28% solution) 3.94 Coalescent Agent (Texanol) 2.64 Rheological Modifier (Acrysol® SCT-275) 12.00 Pigment - Zinc Oxide (XX-503 - Zinc Corporation of America) 275.47 Pigment - titanium dioxide (Ti-PureR-960 - DuPont) 1102.32

The finished prefabricated paint was to have a total volume of 100 gallons, a total weight of 1,887.88 pounds, a total OKP of 80.00%, OKP, titanium dioxide, 68.23%, a volumetric dry matter content of 50.00%, a mass dry matter content of 77, 63%, a density of 18.8788 lbs / gallon, a dispersant content of 0.80% for dry pigment and a coalescent agent of 3.0% for dry matter latex.

Example 46

This example describes the preparation of a filler prefabricated paint. This prefabricated paint was prepared as described above by combining the following components.

Component Quantity (lbs / 100 gallons) Water 310.92 Dispersant (Tamol® 731A - Rohm and Haas) 10.82 Defoamer (Nopco NXZ) 13.36 The base is ammonia (28% solution) 6.68 Coalescent Agent (Texanol) 1.76 Rheological Modifier (Natrosol 250 HR) 2.00 Binder - acrylate resin (55.0% dry matter at Tc - 29 ° C) (Rhoplex® EC-1791 - Rohm and Haas) 159.75 Pigment - Calcium Carbonate (Duramite) 901.50

The finished prefabricated paint was to have a total volume of 100 gallons, a total weight of 1406.78 pounds, a total OKP of 80.00%, a volumetric dry matter content of 50.00%, a mass dry matter content of 70.33%, a density of 14.0678 pounds / gallon , a dispersant content of 0.30% on a dry pigment and a coalescent agent of 2.0% on a dry matter of latex.

Example 47

This example describes the preparation of a prefabricated filling paint for use in the application of coatings that have good adhesion to asphalt roofing materials. This prefabricated paint was prepared as described above by combining the following components.

Component Quantity (lbs / 100 gallons) Water 310.09 Dispersant (Tamol® 731A - Rohm and Haas) 10.82 Defoamer (Nopco NXZ) 13.36 The base is ammonia (28% solution) 6.68 Coalescent Agent (Texanol) 1.77 Rheological Modifier (Natrosol 250 HR) 2.00 The binder is acrylate resin (55.0% dry matter at Tc -8 ° C) (Lipacryl® MV-3640 - Rohm and Haas) 160.69 Pigment - Calcium Carbonate (Duramite) 901.50

The prefabricated paint was to have a total volume of 100 gallons, a total weight of 1406.90 pounds, a total OKP of 80.00%, a volumetric dry matter content of 50.00%, a mass dry matter content of 70.36%, a density of 14.0690 pounds / gallon , a dispersant content of 0.30% on a dry pigment and a coalescent agent of 2.0% on a dry matter of latex.

Example 48

This example describes the preparation of a prefabricated fill paint using aluminum trihydrate, which reports, as you know, the ability to slow down combustion. It was prepared as described above by combining the following components.

Component Quantity (lbs / 100 gallons) Water 311.61 Dispersant (Tamol 731 A - Rohm and Haas) 9.70 Defoamer (Nopco NXZ) 13.36 The base is ammonia (28% solution) 6.68 Coalescent Agent (Texanol) 1.76 Rheological Modifier (Natrosol 250 HR) 2.00 Binder - acrylate resin (55.0% dry matter at Tc - 29 ° C) (Rhoplex® EC-1791 - Rohm and Haas) 159.75 Pigment - aluminum trihydrate (Solem SB-432 - (Huber) 807.94

The prefabricated paint was to have a total volume of 100 gallons, a total weight of 1312.79 pounds, a total OKP of 80.00%, a volumetric dry matter content of 50.00%, a mass dry matter content of 68.24%, a density of 13.1279 pounds / gallon , a dispersant content of 0.30% on a dry pigment and a coalescent agent of 2.0% on a dry matter of latex.

Example 49

This example describes the preparation of an acrylate binder prefabricated paint with low Tc, which should have good flexibility at a low temperature and good adhesion to a variety of roofing substrates. This prefabricated paint was prepared using a laboratory mixer equipped with a stirrer blade, inclined at an angle of 45 °.

Component Quantity (lbs / 100 gallons) The binder is acrylate resin (55.0% dry matter at Tc - 29 ° C) (Rhoplex® EC-1791 - Rohm and Haas) 798.75 Defoamer (Nopco NXZ) 1.33 Rheological Modifier (Natrosol 250 HR) 5.32 The solvent is propylene glycol. 26.62 The base is ammonia (28% solution) 2.66 Coalescent Agent (Texanol) 8.79 Water 16.45

The prefabricated paint was to have a total volume of 100 gallons, a total weight of 859.93 pounds, a dry solids content of 50.00%, a mass dry matter content of 51.09%, a density of 8.5993 pounds / gallon and a coalescent agent content of 2.0 % dry matter latex.

Example 50

This example describes the preparation of an acrylate binder prefabricated paint with TC medium range, which should have good adhesion to asphalt roofing materials. This prefabricated paint was prepared using a laboratory mixer equipped with a stirrer blade, inclined at an angle of 45 °.

Component Quantity (lbs / 100 gallons) The binder is acrylate resin (55.0% dry matter at Tc -8 ° C) (Lipacryl® MV-3640 - Rohm and Haas) 803.45 Defoamer (Nopco NXZ) 1.33 Rheological Modifier (Natrosol 250 HR) 5.32 The solvent is propylene glycol. 26.62 The base is ammonia (28% solution) 2.66 Coalescent Agent (Texanol) 8.84 Water 12.29

The finished prefabricated paint was to have a total volume of 100 gallons, a total mass of 860.52 pounds, a bulk solids content of 50.00%, a mass dry matter content of 51.35%, a density of 8.6052 pounds / gallon and a coalescent agent content of 2.0 % dry matter latex.

Example 51

This example describes the preparation of a tan pigment prefabricated paint, including zinc oxide. This prefabricated paint was prepared as described in example 46, by combining the following components.

Component Quantity (lbs / 100 gallons) Binder - acrylate resin (55.0% dry matter at Tc - 29 ° C) (Rhoplex® EC-1791 - Rohm and Haas) 143.78 Water 307.35 Dispersant (Tamol® 731A - Rohm and Haas) 30.07 Surfactant (Triton® X-405 - Union Carbide) 10.00 Defoamer (Nopco NXZ) 5.00 The base is ammonia (28% solution) 3.94 Coalescent Agent (Texanol) 2,37 Rheological Modifier (Acrysol® SCT-275) 40.00 Pigment - zinc oxide (XX-503, Zinc Corporation of America) 480.33 Pigment - Tan Red Oxide (Mapico 422) 1023.06

The finished prefabricated paint was to have a total volume of 100 gallons, a total weight of 2045.89 pounds, a total OKP of 80.00%, a bulk solids content of 45.00%, a mass dry matter content of 77.35%, a density of 20.4589 pounds / gallon , a dispersant content of 0.50% on a dry pigment and a coalescent agent of 3.0% on a dry matter of latex.

Example 52

This example describes the preparation of a prefabricated prefabricated paint using crystalline silicon dioxide. Silicon dioxide fillers are known to give good durability and abrasion resistance. This prefabricated paint was prepared as described above by combining the following components.

Component Quantity (lbs / 100 gallons) Water 296.22 Dispersant (Tamol® 731 A - Rohm and Haas) 26.54 Defoamer (Nopco NXZ) 13.36 The base is ammonia (28% solution) 6.68 Coalescent Agent (Texanol) 1.76 Thickener (Natrosol 250 HR) 2.00 Binder - acrylate resin 55.0% dry matter at Tc - 29 ° C) Rhoplex® EC-1791 - Rohm and Haas) 159.75 Silicon Dioxide Filler (Silver and B) 884.81

The finished prefabricated paint was to have a total volume of 100 gallons, a total weight of 1391.11 pounds, a total OKP of 80.00%, a volumetric dry matter content of 50.00%, a mass dry matter content of 69.92%, a density of 13.9111 pounds / gallon , a dispersant content of 0.75% on a dry pigment and a coalescent agent of 2.0% on a dry matter of latex.

Example 53

This example describes the preparation of 15 elastomeric compositions for applying roof coatings of varying quality, flexibility, adhesive ability and the ability to slow down combustion. Coating materials were prepared using different combinations of white prefabricated paints from examples 43, 44 and 45, non-white pigment prefabricated paints from example 16, filler prefabricated paints from examples 46, 47, 48 and 52 and binder prefabricated paints from examples 40, 49 and 50. Paints were prepared by adding pigment prefabricated paint and filling prefabricated paint to the binder prefabricated paints and thorough mixing. The quantities of materials to be mixed are indicated below. All mass amounts are indicated in pounds, and the total volume of each elastomeric coating material was 100 gallons. The volumetric dry matter content was 45%.

A mass of prefabricated paints examples Paint 43 44 45 51 46 47 48 52 40 49 fifty Water Total 53-1 70.9 - 419.4 - - - - - - 483.7 - 83 1057.0 53-2 - 87.2 - 409.8 - - - - - 483.7 - 83 1063.7 53-3 70.9 - 656.8 - - - - - - 338.6 - 83 1149.2 53-4 - - 87.2 - 647.2 - - - - 338.6 - 83 1156.0 53-5 131.6 - - - 371.9 - - - - 483.7 - 83 1070,2 53-6 - - 161.9 - 354.2 - - - - 483.7 - 83 1082.7 53-7 131.6 - - - 609.3 - - - - 338.6 - 83 1162.5 53-8 - - 161.9 - 591.6 - - - - 338.6 - 83 1175.0 53-9 70.9 - - - - - 391.4 - - 483.7 - 83 1028.9 53-10 - - 88.9 - - - 647.8 - - 338.5 - 83 1158.2 53-11 91.1 - - - 403.6 - - - 483.6 - - 83 1061,2 53-12 - - 112.1 - 628.7 - - - 338.5 - - 83 1162,2 53-13 - 131.6 - - - 530.2 - - - - 387.2 83 1132.1 53-14 131.6 - - - 530.2 - - - 387.2 - - 83 1132.0 53-15 - - - 179.0 - - - 548.0 - 368.0 - 76 1171.0 The proposed OKP, TiO ₂ content, flexibility at low temperature, type of filler, the presence of special adhesion and the quality of the finished mixtures for elastomeric coatings are presented in table 3.

Table 3 Paint Okp Zno OKP-TiO ₂ Color Filler Flexibility temperature Special adhesion Quality 53-1 thirty absent 3,5 white CaCO ₃ -15 ° F versatility average 53-2 thirty contains 3,5 white CaCO ₃ -15 ° F versatility average 53-3 45 absent 3,5 white CaCO ₃ -15 ° F versatility low 53-4 45 contains 3,5 white CaCO ₃ -15 ° F versatility low 53-5 thirty absent 6.5 white CaCO ₃ -15 ° F versatility high 53-6 thirty contains 6.5 white CaCO ₃ -15 ° F versatility high 53-7 45 absent 6.5 white CaCO ₃ -15 ° F versatility average 53-8 45 contains 6.5 white CaCO ₃ -15 ° F versatility average 53-9 thirty absent 3,5 white TGA -15 ° F versatility low 53-10 45 contains 3,5 white TGA -15 ° F versatility average 53-11 thirty absent 4,5 white CaCO ₃ 20 ° F versatility low 53-12 45 contains 4,5 white CaCO ₃ 20 ° F to asphalt average 53-13 40 absent 6.5 white CaCO ₃ 20 ° F to asphalt average 53-14 40 absent 6.5 white CaCO ₃ 20 ° F mixtures 53-15 42 contains 0 tan silica -15 ° F versatility average

The above compositions for elastomeric coatings were characterized by a range of qualities, which were determined by the durability and flexibility of the coating at low temperature. To facilitate the ability of dried coatings to slow down combustion, various fill-in semi-finished paints were used, including semi-finished paints prepared using dry powdered colorants and without TiO ₂ to create colorized paints. These examples should not be considered limiting. So, in particular, all pigment and filling semi-finished paints can be prepared with and without binders, and binders can have higher Tc values than those used in this example. In addition, this does not mean that the list of filling semi-finished paints is limited to those that used calcium carbonate, but also covers examples of those that could include other commonly used fillers, such as clays, silicas, magnesium silicates, etc. .

Example 54

This example describes the preparation of a white pigment prefabricated / pre-prepared paint component.

Component Quantity (lbs / 100 gallons) Water 257.83 The solvent is propylene glycol. 50.00 Dispersant (Tamol® 731 A - Rohm and Haas) 26.71 Defoamer (Nopco NXZ) 1,50 Surfactant (Triton CF-10) 1.00 Pigment - titanium dioxide (Ti-Pure R-902 - DuPont company) 1335.56 The base is ammonia (28% solution) 4.00 Defoamer (Nopco NXZ) 1,50 Thickener Acrysol® RM 2020 NPR - Rohm and Haas) 50.00 Water 93.45

Water, glycol, Defoamer, dispersant and surfactant were combined and mixed briefly at low speed. Then, dry pigment was added. After adding all the dry pigment, the mixture was stirred at a high shear rate for 15 to 20 minutes, as is known to a person skilled in the art.

The finished white pigment prefabricated paint / pre-prepared composition should have a total volume of 100 gallons, a total weight of 1839.55 pounds, a total OKP of 100.00%, a volumetric dry matter content of 40.12%, a mass dry matter content of 72.60%, a density 18.4495 pounds / gallon and a dispersant content of 0.50% per dry pigment.

Example 55

This example describes the preparation of a small particle filler prefabricated / pre-prepared paint component.

Component Quantity (lbs / 100 gallons) The binder is acrylate resin (46.5% dry matter at Tc 17 ° C) (Rhoplex® EI-2000, Rohm and Haas) 201.32 The solvent is propylene glycol. 5.00 Dispersant (Tamol® 731 A - Rohm and Haas) 10,42 Defoamer (Nopco NXZ) 2.00 Thickener No. 1 (Attagel 50) 27.96 Small Particle Filler (Minex 4) 840.53 Coalescent Agent (Texanol) 3.28 The base is ammonia (28% solution) 2.00 Water 283.42 Thickener No. 2 (Acrysol® ASE-60 - Rohm and Haas) 4.00

Water, acrylate binder, antifoam, base and glycol were combined and briefly mixed at low speed. Then, dry filler was added. After adding all the dry filler, the mixture was stirred at a high shear rate for 15 to 20 minutes, as is known to a person skilled in the art.

A prefabricated, prefabricated, prefabricated ink paint / composition should have a total volume of 100 gallons, a total weight of 1,379.93 pounds, a total OKP of 80.00%, a volumetric dry matter content of 50.00%, and a mass dry matter content of 69.72 %, density 13.7993 lbs / gallon, dispersant content 0.30% for dry pigment and coalescent agent 3.50% for dry matter latex.

Example 56

This example describes the preparation of a binder prefabricated paint / pre-prepared composition. It was prepared using a laboratory mixer equipped with a stirrer blade, inclined at an angle of 45 °.

Component Quantity (lbs / 100 gallons) The binder is acrylate resin (46.5% dry matter at Tc 17 ° C) (Rhoplex® EI-2000 - Rohm and Haas) 805.28 Defoamer (Nopco NXZ) 1.33 Thickener (Acrysol® ASE-60 - Rohm and Haas) 20.00 The solvent is propylene glycol. 10.00 The base is ammonia (28% solution) 2.66 Coalescent Agent (Texanol) 13.11 Water 21.92

The finished packaging of the semi-finished binder paint / pre-prepared composition should have a total volume of 100 gallons, a total mass of 874.31 pounds, a dry solids content of 40.00%, a dry matter mass content of 42.83%, a density of 8.7431 pounds / gallon and 3.50% coalescent agent on latex dry matter.

Example 57

This example describes the preparation of a binder prefabricated paint / pre-prepared composition for good flexibility at low temperature. It was prepared using a laboratory mixer equipped with a stirrer blade, inclined at an angle of 45 °.

Component Quantity (lbs / 100 gallons) The binder is acrylate resin (61% dry matter at Tc - 29 ° C) (Rhoplex® EC-2848 - Rohm and Haas) 584.20 Defoamer (Nopco NXZ) 1.33 Thickener (Acrysol® ASE-60 - Rohm and Haas) 20.00 The solvent is propylene glycol. 10.00 The base is ammonia (28% solution) 2.66 Coalescent Agent (Texanol) 12.47 Water 226.92

The finished packaging of the pre-cooked binder prefabricated paint should have a total volume of 100 gallons, a total weight of 857.59 pounds, a volumetric dry matter content of 40.00%, a mass dry matter content of 41.55%, a density of 8.5759 pounds / gallon and a coalescent content agent of 3.50% dry matter latex.

Example 58

This example describes aggregate particles of small sizes for use in applying an aggregate finishing layer of fine texture.

Component Quantity (lbs / 100 gallons) Sand - small particles (sand No. 90) 2211.18

The finished pre-packaged packaging was to have a total volume of 100 gallons, a total mass of 2,211.18 pounds, a bulk solids content of 100.00%, a mass dry matter content of 100.00% and a density of 22.1118 pounds / gallon.

Example 59

This example describes the preparation of aggregate additives with large particles, which cause a rough texture. It was prepared using a mixer with a tape-screw mixer.

Component Quantity (lbs / 100 gallons) Sand - large particles (sand No. 15) 442.24 Sand - small particles (sand No. 90) 1768.94

The finished pre-packaged aggregate was to have a total volume of 100 gallons, a total mass of 2,211.18 pounds, a volumetric solids content of 100.00%, a mass dry matter content of 100.00% and a density of 22.1118 pounds / gallon.

Example 60

This example describes the preparation of 19 aggregate finishing compositions of varying quality, brightness, color and texture. In the preparation of such different aggregate finishing materials in different ratios, different combinations of a pre-prepared filling composition with small particles from Example 55, binders of pre-prepared compositions from Examples 56 and 57, white pigment prefabricated paint from Example 54 and aggregate additives with large particles from examples 58 and 59. Aggregate finishing materials were prepared by adding a pre-prepared filling composition with small particles size into the binder of the pre-prepared composition, and then by adding, if necessary, a white pigment prefabricated paint and, finally, by adding water and an aggregate additive with large particles. These components were thoroughly mixed using a mixer with a tape screw mixer. The quantities of materials to be mixed are indicated below. All mass quantities are indicated in pounds, and the total volume of each aggregate finishing material was 100 gallons. The volumetric dry matter content was 67%.

Nineteen different aggregate finishing materials were prepared using pre-prepared compositions of examples 54 to 57, as well as mixtures of aggregate additives with large particles, such as those described in examples 58 and 59.

A mass of prefabricated paints examples Water Total Paint 55 56 57 58 59 54 60-1 64.72 429.09 995.56 0.00 10.03 1499.40 60-2 41.60 432.75 995.56 30.90 6.55 1507.11 60-3 6.93 438.24 995.56 77.26 1.34 1518.66 60-4 180.29 337.56 995.56 0.00 27.41 1540.82 60-5 157.17 341.22 995.56 30.90 23.93 1548.52 60-6 122.50 346.71 995.56 77.26 18.72 1560.08 60-7 295.86 246.03 995.56 0.00 44.79 1582.24 60-8 272.74 249.69 995.56 30.90 41.31 1589.94 60-9 238.07 255.18 995.56 77.26 36.10 1601.50 60-10 122.50 340.08 995.56 77.26 18.72 1553.45 60-11 64.72 429.09 995.56 0.00 10.03 1499.40 60-12 41.60 432.75 995.56 30.90 6.55 1507.11 60-13 6.93 438.24 995.56 77.26 1.34 1518.66 60-14 180.29 337.56 995.56 0.00 27.41 1540.82 60-15 157.17 341.22 995.56 30.90 23.93 1548.52 60-16 122.50 346.71 995.56 77.26 18.72 1560.08 60-17 295.86 246.03 995.56 0.00 44.79 1582.24 60-18 272.74 249.69 995.56 30.90 41.31 1589.94 60-19 238.07 255.18 995.56 77.26 36.10 1601.50

OKP, TiO ₂ content, estimated color brightness, texture and flexibility at low temperature of the prepared compositions for aggregate finishing coatings are presented below.

Paint Okp OKP-TiO ₂ texture Flexibility Color tone Quality 60-1 70 0 thin 40 ° F saturated high 60-2 70 one thin 40 ° F average high 60-3 70 2,5 thin 40 ° F pastel high 60-4 75 0 thin 40 ° F saturated average 60-5 75 one thin 40 ° F average average 60-6 75 2,5 thin 40 ° F pastel average 60-7 80 0 thin 40 ° F saturated low 60-8 80 one thin 40 ° F average low 60-9 80 2,5 thin 40 ° F pastel low 60-10 75 2,5 thin 0 ° F pastel average 60-11 70 0 rough 40 ° F saturated high 60-12 70 one rough 40 ° F average high 60-13 70 2,5 rough 40 ° F pastel high 60-14 75 0 rough 40 ° F saturated average 60-15 75 one rough 40 ° F average average 60-16 75 2,5 rough 40 ° F pastel average 60-17 80 0 rough 40 ° F saturated low 60-18 80 one rough 40 ° F average low 60-19 80 2,5 rough 40 ° F pastel low

The materials of aggregate finishing coatings presented above showed a number of qualities, textures, and color characteristics, which depended on the OKP, TiO ₂ content, and particle size ratio in the filler with large particles. Examples of these compositions should not be construed as limiting. Thus, in particular, all filling prefabricated paints / pre-prepared compositions could be obtained without a binder. In addition, this does not mean that the list of prefabricated paints / pre-formulated compositions is limited to those that use nephelinecyenite, but also includes examples of those that include other commonly used fillers, such as clays, silicas, magnesium silicates, calcium carbonates etc. A suspension of TiO ₂ can be added to the prefabricated paint / pre-prepared composition.

Example 61

The following prefabricated paints should provide a range of wood coatings, including coatings whose materials contain an opaque pigment (“pigmented coatings”) and coatings whose materials do not contain an opaque pigment or fillers (“clear coatings”).

The binder prefabricated paint 1 was prepared by introducing into the vessel 7979 g of the binder Rhoplex CL-104. Then, with good stirring, 800 g of ethylene glycol monobutyl ether, 240 g of dipropylene glycol monobutyl ether and 1800 g of water were added.

The binder prefabricated paint 2 was prepared by introducing into the vessel 6636 g of the binder Rhoplex CL-105. Then, with good stirring, 800 g of ethylene glycol monobutyl ether, 240 g of dipropylene glycol monobutyl ether and 1800 g of water were added.

The binder prefabricated paint 3 was prepared by adding 760 g of RoShield 3188 binder into the vessel. Then, 400 g of ethylene glycol monobutyl ether, 120 g of dipropylene glycol monobutyl ether, 900 g of water and 100 g of Paraplex ™ WP-1 polypropylene oxide monocresyl ether (Company Rohm and Haas , Philadelphia, PA).

An additional prefabricated paint 1 was prepared by mixing with stirring 70 g of Tego Foamex 805 antifoam, 30 g of Tego Glide ™ 410 wax (50% in Dowanol DPM solvent) (Tego Chemie Service), 30 g of Surfynol ^TM 104DPM surfactant, 25 g of GMRP thickener Acrysol ™ RM-825 and 200 g of emulsion Michem 39235.

The titanium dioxide prefabricated paint was prepared in a Cowles mixer as follows.

Shredding Weight (pounds) Volume (gallons) Water 282.96 33.90 Dispersant Tamol ™ 731 58.51 6.35 Triton ™ CF-10 Surfactant 2.19 0.25 Kathon ™ LX Biocide 1.5% 2.19 0.26 Ti-Pure ™ R-706 Titanium Dioxide
Dilution 1462.80 43.81 Ammonia (28% solution) 0.66 0.09 GEUP thickener Acrysol ™ RM-2020 NPR 54.76 6.29 Total 1939.64 100.00

White thermosetting composition AC-1024 - used with urea-formaldehyde resin in an amount of 1973 g of the total weight of the composition.

These compositions can also be used as pigmented and transparent coating materials on chipboard, MDF, plywood, oriented fiber reinforced panel.

Example 62

The following semi-finished paints were prepared and used to obtain a number of coatings on metal substrates, which, apparently, are typical as used for maintenance or initially in the manufacturing process of equipment.

Prefabricated Ink Formulations (lbs / 100 gallons) Component TiO ₂ Prefabricated Paint Filling prefabricated paint 1 Prefabricated prefabricated paint 2 Prefabricated prefabricated paint 3 Binder Prefabricated Paint Dowanol ™ DPM ester solvent 116.9 79.15 98.0 82,2 - Water 227.3 302.8 190.1 314.3 - Dispersant Tamol ^TM 165A 64.95 43.97 54.19 45.64 - Triton ™ CF-10 Surfactant 6.5 4.4 5.5 4.6 - Antifoam Tegofoamex ™ 1488 9.7 6.6 8.3 6.9 - TiO ₂ Ti-Pure ™ R-706 1266.4 - - - - Talc Lo Micron ™ 2610 - 857.5 - - - CaCO ₃ Albaglos ™ - - 1062.6 - - Reactive Pigment Halox ™ SZP-391 (Halox, Inc., Hammond, Indiana) - - - 889.9 - Ammonia (15% solution) 2,8 1.9 2,4 1.9 - Water 32,5 21.9 27.5 22.8 31,45 Kathon ™ LX Biocide 2.1 1.4 1,6 1,5 - GEUP thickener Acrysol ™ RM-2020 NPR 56.1 56.1 56.1 - - HEC thickener Natrosol ™ 250 GR (4%) - - - 58.3 - Binder Maincote ™ HG-54D - - - - 754.8 Texanol ™ Coalescent Agent - - - - 47.17 Sodium Nitrite (15%) - - - - 10.48 Ammonia (15% solution) - - - - 5.24 GMSCR Acrysol ™ Thickener RM-8W - - - - 2.62

The pH value was ~ 8.5-9

Viscosity was equal from 90 to 110 KU

Grinding in a Hegmen device to particles with sizes in the range indicated for the pigment of this variety.

The semi-finished paints presented above can be combined to produce the following range of coating materials for metals.

Product White primer with high OKP White glossy White with a low gloss Glossy topcoat Transparent top coat Components wt.% wt.% wt.% wt.% wt.% TiO ₂ Prefabricated Paint 10.1 13 12.5 - - Filling prefabricated paint 1 5,4 - - - - Prefabricated prefabricated paint 2 6.1 - 4.2 2.9 - Prefabricated prefabricated paint 3 10.8 - - - - Binder Prefabricated Paint 57.6 87 83.3 97.1 one hundred Okp 31.89 17.82 13.98 3.37 - Volumetric dry matter content 34.67 35.56 35.41 35.19 35.02 Mass dry matter 48.31 46.01 44.96 38.11 36.78

Example 63

A line of inks for printing purposes can be prepared from a limited set of mixed source materials ("semi-finished printing inks" or "semi-finished inks"). These semi-finished paints were prepared as follows.

Prefabricated paint 1 ("solid binder prefabricated paint") was prepared by loading 94 parts in a vessel. Lucidene 370 polymer (Rohm and Haas Company). With good stirring, 5 parts were added. wax Luciwax 37 (firm Rohm and Haas Company) and 1 part. defoamer.

Prefabricated paint 2 ("binder with an average Tc prefabricated paint") was prepared by loading 94 parts in a vessel. Lucidene 615 polymer (Rohm and Haas Company). With good stirring, 5 parts were added. wax Luciwax 37 (firm Rohm and Haas Company) and 1 part. defoamer.

Prefabricated paint 3 ("soft binder prefabricated paint") was prepared by loading into the vessel 89 part. polymer Lucidene 605 (Rohm and Haas Company). With good stirring, 5 parts were added. wax Luciwax 37 (firm Rohm and Haas Company), 1 part. antifoam and 5 frequent. isopropyl alcohol.

Prefabricated paint 4 ("alkali-soluble resin-based additive prefabricated paint") was Morcryl 132 resin (Rohm and Haas Company), used as supplied at a dry matter content of 32% and a pH of 8.5.

Prefabricated paint 5 ("glossy additive prefabricated paint") was a Morcryl 350 resin (Rohm and Haas Company), used as supplied at a dry matter content of 50% and a pH of 9.0.

Prefabricated paint 6 ("wax additive prefabricated paint") was a wax Michem Lube 743 (Michelman, Inc.), used in the supplied form at a dry matter content of 32% and pH 7.

The coloring matter was added to printing inks using pigment dispersions, such as SunFlexiverse (Sun Chemical Co.), which was supplied at a dry matter content of about 40% in a variety of colors.

This line of inks for printing is presented in the table below. Each product was prepared by combining these materials (mass expressed in grams) with good mixing. The final viscosity was adjusted to the required addition of water and / or isopropyl alcohol. When a number of materials intended for mixing are indicated, a number of properties of the finished product can be achieved. So, for example, the result of the use of prefabricated ink 3 in the highest concentration was the improved resistance of inks for printing on packages for freezers to crease at low temperature. The usual result of using prefabricated ink 4 at an increased concentration in most printing inks was an improved transfer in a printing press.

Printing Ink Product Binder prefabricated paint 1 Binder Prefabricated Paint 2 Binder Prefabricated Paint 3 Additional prefabricated paint 4 Additive prefabricated paint 5 Additive prefabricated paint 6 Pigment dispersion Gift Wrapping Paper 55-65 - - 10-20 - - 25-30 Corrugated Box 55-65 - - 10-20 - 4-6 25-30 Newsprint 65-75 - - - - - thirty Cardboard 55-65 - - - 10-20 - 25-30 Labels 28-33 28-33 - 10-20 - - 25-30 Freezer bags - - 55-65 10-20 - - 25-30 Department Store Bags - - 55-65 - 10-20 - 25-30 Metal foil - 28-33 28-33 - - - 25 Foil - 28-33 28-33 - 10-20 - 25-30 General purpose printing products - 80 - 15-25 - - - High Gloss Printing Products 35-45 - 35-45 - twenty - - Water resistant print products on top - 35-45 35-45 10-20 - - - Abrasion resistant print products on top - 75-85 - twenty - 4-6 - Large angle print products - 80 - 15-25 - - -

Supplier Information The product's name Characteristic Provider Tamol ™ 1124 Dispersant Rohm and Haas Company (Philadelphia, PA) Tamol ™ 1254 Dispersant Rohm and Haas Company (Philadelphia, PA) Tamol ™ 731 Dispersant Rohm and Haas Company (Philadelphia, PA) Acrysol ™ DR-3 GMSCR thickener / rheology modifier Rohm and Haas Company (Philadelphia, PA) Acrysol ™ RM-2020 GEUP thickener / rheology modifier Rohm and Haas Company (Philadelphia, PA) Acrysol ™ RM-8W GEUP thickener / modifier of rheological properties Rohm and Haas Company (Philadelphia, PA) Acrysol ™ RM-825 GEUP thickener / rheology modifier Rohm and Haas Company (Philadelphia, PA) Rhoplex ™ Multilobe 200 Emulsion polymer binder Rohm and Haas Company (Philadelphia, PA) Rhoplex ™ SG-10M
RES 3083 Emulsion polymer binder Rohm and Haas Company (Philadelphia, PA) Kathon ™ 1.5% Biocide Rohm and Haas Company (Philadelphia, PA) Triton ™ CF-10 Surface-active substance Union Carbide Corporation (Denbury, Connecticut) Foamaster ™ VL Antifoam agent Henkel Corporation (King of Prash, PA) Drewplus ™ L-475 Antifoam agent Drew Chemical Corpotation (Kearney, NJ) Ti-Pure ™ R-746 Titanium dioxide E.I. Dupont de Nemours and Co., Inc. (Wilmington, Delaware) Ti-Pure ™ R-706 Titanium dioxide E.I. Dupont de Nemours and Co., Inc. (Wilmington, Delaware) Ti-Pure ™ R-900 Titanium dioxide E.I. Dupont de Nemours and Co., Inc. (Wilmington, Delaware) Ti-Pure ™ R-902 Titanium dioxide E.I. Dupont de Nemours and Co., Inc. (Wilmington, Delaware) Minex ™ 4 Mineral filler Inim Corp. (Diving Grick, NJ) Optiwhite ™ Clay as a filler Burgess Pigment (Sandersville, PC. Georgia) Snowflake ™ Calcium Carbonate as a Filler EU With International Imerya (Silacoga, Alaska) Vicron ™ 15-15 Calcium Carbonate as a Filler Pfizer (New York, NY) Omyacarb ™ Calcium Carbonate as a Filler Omya (Proctor, VA) Texanol ™ Coalescent agent Eastman Chemical (Kings Port, Tennessee)

Claims (51)

1. A flowing opacifying semi-finished paint suitable for the preparation of a single-pack pigment-coated latex paint, in which the volume content of dry matter is from about 30 to about 70%, and the Stormer viscosity is from about 50 to about 250 EC, including: (I) at least one hiding pigment, (II) at least one dispersant, (Iii) at least one thickener; and (Iv) water, where at least one dispersant and at least one thickener are mutually compatible with at least one pigment and other paint components. 2. The semi-finished paint according to claim 1, in which the volumetric dry matter content is from about 35 to about 50%, and the Stormer viscosity is from about 60 to about 150 EC. 3. Fluid white tinting prefabricated paint for preparing a single-pack pigment-coated latex paint, in which the volume content of dry matter is from about 30 to about 70%, the volume concentration of pigment (OKP) is from about 35 to about 100%, and the viscosity according to Stormer is from about 50 to about 250 EC, including: (I) at least one hiding pigment, (II) at least one dispersant, (III) at least one thickener, (IV) at least one film-forming or non-film-forming polymeric binder and (V) water, where at least one dispersant, at least one thickener and at least one polymer binder are compatible with at least one pigment and other components of the paint, and where such a semi-finished paint is stable to sedimentation. 4. The semi-finished paint according to claim 3, the volumetric dry matter content of which is from about 35 to about 50%, OKP is from about 50 to about 100%, and the Stormer viscosity is from about 60 to about 150 EC. 5. The semi-finished paint according to claim 3, in which the polymer is adsorbed on the pigment giving opacity. 6. The prefabricated paint according to claim 1 or 3, wherein the hiding pigment is a material selected from the group consisting of titanium dioxide, zinc oxide, lead oxide, a synthetic polymer pigment, and mixtures thereof. 7. The semi-finished paint according to claim 1 or 3, wherein the hiding pigment is rutile titanium dioxide. 8. The semi-finished paint according to claim 6, in which the synthetic polymer pigment is a latex polymer with cellular particles. 9. The semi-finished paint according to claim 1 or 3, in which the dispersant is selected from the group comprising 2-amino-2-methyl-1-propanol; dimethylaminoethanol; potassium tripolyphosphate; trisodium polyphosphate; citric acid; polyacrylic acid; diolefin / maleic anhydride addition products; hydrophobically modified polyacrylic acid; hydrophilically modified polyacrylic acid and its salts and mixtures thereof. 10. The prefabricated paint according to claim 1 or 3, wherein the thickener is selected from the group consisting of alkali-soluble or alkali-swellable emulsion, hydrophobically modified alkali-soluble emulsion, hydrophobically modified ethylene oxide-urethane polymer, cellulose, hydrophobically modified cellulose, hydrophobically modified, polyacrylic alcohol, colloidal silicon dioxide, attapulgite, titanate chelating agent and mixtures thereof. 11. The prefabricated paint according to claim 3, in which the polymer is selected from the group consisting of acrylate, polyvinyl acetate, styrene-acrylate, styrene-butadiene, vinyl lapetate-acrylate, ethylene-vinyl lapetate, vinyl acetate-vinyl reversible, vinyl acetate-vinyl maleate vinyl acetate , ethylene-vinyl acetate-acrylate polymers and mixtures thereof, and in which the polymer additionally contains up to about 10 wt.% in terms of this polymer of monomer units selected from the series consisting of monomers with functional groups, comonomers and their juices tanya. 12. The prefabricated paint according to claim 1 or 3, additionally containing essentially at least one additive selected from the group consisting of acid, base, antifoam, coalescent agent, cosolvent, mildecid, biocide and antifreeze, and this additive is contained in less than about 10%, calculated on the total weight of the prefabricated paint. 13. A flowable pigment filler prefabricated paint suitable for preparing a single-pack pigmented latex paint containing other components of paints, where this prefabricated paint includes essentially: (I) at least one mineral filler that has a volumetric dry matter content of from about 30 to about 70%, OKP from about 35 to about 100%, and a Stormer viscosity of from about 50 to about 250 EC; (Ii) at least one thickener, (Iii) water and (IV) an optional polymeric binder, moreover, the components of this semi-finished paint are mutually compatible with each other and the components of the paint. 14. A set of two different mutually compatible binder prefabricated paints suitable for the preparation of latex paint, which includes: (a) an opaque prefabricated paint according to claim 1 or 3; and (b) a latex polymer binder prefabricated paint comprising a water-based latex polymer binder whose Tc is from about -40 to about 70 ° C, having a bulk solids content of from about 25 to about 70% and a Brookfield viscosity of less than 100,000 cP at a shear rate of 1.25 s ^-1 ; where the components of the prefabricated paint are mutually compatible with each other and the components of another prefabricated paint in this set. 15. The prefabricated paint kit of claim 14, wherein the binder prefabricated paint has a bulk solids content of from about 30 to about 65% and a Brookfield viscosity of from about 100 to about 50,000 cP at a shear rate of 1.25 s ^-1 and includes, essentially a water-based latex polymer binder whose Tc is from about -10 to about 60 ° C. 16. The prefabricated paint kit of claim 14, wherein the binder prefabricated paint further includes at least one additive selected from the group consisting of acid, base, antifoam, coalescent agent, cosolvent, mildecid, biocide and antifreeze, this additive is contained in an amount of less than about 10%, based on the total weight of the semi-finished paint. 17. The prefabricated paint kit of claim 14, wherein the prefabricated prefabricated paint further includes at least one additive selected from the group consisting of acid, base, antifoam, coalescent agent, cosolvent, mildecid, biocide and antifreeze, this additive is contained in an amount of less than about 20%, based on the total weight of the semi-finished paint. 18. A set of different mutually compatible fluid semi-finished paints, sufficient to form at least one line of paints, including: (I) at least one flowing opacifying prefabricated paint containing at least one opacifying pigment; (Ii) at least one fluid filler prefabricated paint comprising at least one filler pigment; and (III) at least one binder prefabricated paint comprising at least one latex polymer binder; moreover, the line of paints includes two or more different paints, the dried layers of which essentially differ from each other by at least one distinguishable property, and, in addition, the paints in the line of paints, the most different from each other, are characterized by at least different values the volume concentration of the pigment, differing from each other by at least 2%, or various values of the volume content of dry matter, differing from each other by at least 2%. 19. The set of semi-finished paints according to claim 18, in which the number of semi-finished paints is from 3 to 15. 20. The prefabricated paint kit of claim 18, wherein the opaque prefabricated ink further comprises at least one particulate polymer binder adsorbed on the opaque pigment. 21. The semi-finished paint kit of claim 18, wherein the filling semi-finished paint further comprises at least one particulate polymer binder adsorbed on the filler. 22. The method of forming at least one line of paints, which includes the following stages: (a) the preparation of a set of different mutually compatible fluid semi-finished paints according to p. 18 and (b) supplying a predetermined amount of each of the semi-finished paints to the containers or applicator (s) to form a line of paints. 23. The method according to item 22, further comprising the step of mixing the semi-finished paints before, during or after they are served in containers. 24. The method according to item 22, further comprising the step of mixing the semi-finished paints before or during their supply to the applicator (applicators). 25. The method according to item 22, further comprising the step of regulating the viscosity of the semi-finished paints before, while, or after they are already in containers. 26. The method according to item 22, further comprising the stage of regulating the viscosity of the supplied semi-finished paints before or during their supply to the applicator (applicators). 27. The method according to item 22, further comprising the stage of introducing at least one additive that improves the application or the final performance properties of the paint. 28. The method according to item 27, in which the additive is an aggregate material. 29. The method according to item 27, in which the additive is a thickener. 30. The method according to item 22, further comprising the step of adding at least one dye to the semi-finished paints. 31. The method according to item 22, in which giving the opacity of the semi-finished paint further includes at least one polymeric binder in the form of particles absorbed on the opacifying pigment. 32. The method according to item 22, in which the filler prefabricated paint further includes at least one polymeric binder in the form of particles absorbed on the pigment filler. 33. The method according to item 22, which is carried out at the place of placement of equipment for the manufacture of paints. 34. The method according to item 22, which is carried out at the point of sale of the product. 35. The method according to item 22, which is carried out at the place of application. 36. The method according to item 22, the implementation of which is controlled by a computer. 37. The method according to item 22, in which the number of semi-finished paints is from 4 to 15. 38. The method of forming a series of paints, and this series includes at least two lines of paints, comprising the following stages: (a) preparing a set of different mutually compatible fluid semi-finished paints, sufficient to form at least two lines of paints, and this set is a set according to p. 18, further containing: (IV) at least one other prefabrication, filling or binder prefabricated paint selected from the group comprising prefabricated paints (I), (II) and (III); and (b) supplying a predetermined amount of each of the semi-finished paints to containers or an applicator (s) to form a series of paints. 39. A set of three different mutually compatible fluid semi-finished paints suitable for the preparation of latex paints, which includes: (a) the semi-finished paint kit of claim 14, wherein the filling semi-finished paint product has a volumetric dry matter content of from about 30 to about 70%, OKP from about 35 to about 100%, and a Stormer viscosity of from about 50 to about 250 EC; and (b) a flowable pigment filler prefabricated paint, which includes essentially: (I) at least one mineral filler, (Ii) at least one thickener, (Iii) water and (IV) optionally a polymeric binder. 40. The set of semi-finished paints according to § 39, in which the filling semi-finished paint has a volumetric dry matter content of from about 35 to about 65%, OKP from about 40 to about 100% and a Stormer viscosity of from about 60 to about 150 EC. 41. A line of paints prepared according to the method, which includes the following stages: (a) the preparation of a set of different mutually compatible fluid semi-finished paints according to p. 18 and (b) supplying a predetermined amount of each of the semi-finished paints to containers or applicators to form a line of paints, moreover, the line of paints includes two or more different paints, the dried layers of which essentially differ from each other by at least one distinguishable property, and, in addition, the paints in the line of paints, the most different from each other, are characterized by at least different values the volume concentration of the pigment, differing from each other by at least 2%, or various values of the volume content of dry matter, differing from each other by at least 2%. 42. A set of different mutually compatible fluid semi-finished paints, sufficient to form at least one line of paints that can be used as an elastomeric coating material, and this kit is a kit according to p. 18, in which the latex polymer binder in the latex the polymer binder prefabricated paint (III) is characterized by Tc, the value of which is less than about 0 ° C, and the line of paints includes two or more different paints, the dried layers of which are essentially y differ from each other by at least one distinguishable property, and, in addition, the paints in the line of paints, the most different from each other, are characterized by at least different values of the volume concentration of the pigment, differing from each other by at least 2%, or various values of volumetric dry matter content, differing from each other by at least 2%. 43. A method of forming at least one line of paints suitable for use as an elastomeric coating material, which comprises the following steps: (a) the preparation of a set of different, mutually compatible fluid semi-finished paints according to paragraph 42 and (b) supplying a predetermined amount of each of the semi-finished paints to containers or applicators to form a line of paints, moreover, the line of paints includes two or more different paints, the dried layers of which essentially differ from each other by at least one distinguishable property, and, in addition, the paints in the line of paints, the most different from each other, are characterized by at least different values the volume concentration of the pigment, differing from each other by at least 2%, or various values of the volume content of dry matter, differing from each other by at least 2%. 44. A method of forming a series of inks comprising at least two lines of inks that can be used as an elastomeric coating material, the method comprising the following steps: (a) preparing a kit sufficient to form at least two paint lines of the semi-finished paints, the kit being the kit of claim 42, further comprising at least one other semi-finished paint selected from the group consisting of the semi-finished paints described above (I) , (II) and (III); and (b) supplying a predetermined amount of each of the semi-finished paints to containers or applicators to form a series of paints. 45. A set of different mutually compatible fluid semi-finished paints, sufficient to form at least one line of paints, suitable for use as a cementless composite finishing coating, and this kit is a kit according to p. 18, additionally containing (IV) at least one prefabricated paint containing aggregate filler, moreover, the line of paints includes two or more different paints, the dried layers of which essentially differ from each other by at least one distinguishable property, and, in addition, the paints in the line of paints, the most different from each other, are characterized by at least different values the volume concentration of the pigment, differing from each other by at least 2%, or various values of the volume content of dry matter, differing from each other by at least 2%. 46. A method of forming at least one line of paints acceptable for use as a non-cement complex finishing coat, the method comprising the following steps: (a) the preparation of a set of different, mutually compatible fluid non-cement semi-finished paints, and this set is a set according to item 45; and (b) supplying a predetermined amount of each of the semi-finished paints to containers or applicators to form a line of paints, moreover, the line of paints includes two or more different paints, the dried layers of which essentially differ from each other by at least one distinguishable property, and, in addition, the paints in the line of paints, the most different from each other, are characterized by at least different values the volume concentration of the pigment, differing from each other by at least 2%, or various values of the volume content of dry matter, differing from each other by at least 2%. 47. The method of forming a series of paints, and this series includes at least two lines of paints that can be used as a material of a cementless complex finishing coating, and this method includes the following stages: (a) the preparation of a set of different but mutually compatible fluid non-cement semi-finished paints, sufficient to prepare at least two lines of paints, and this set is a kit according to item 45, further containing (V) at least one additional, another prefabricated paint selected from the group comprising prefabricated paints (I), (II), (III) and (IV); and (b) supplying a predetermined amount of each of the semi-finished paints to containers or applicators to form a series of paints, moreover, the line of paints includes two or more different paints, the dried layers of which essentially differ from each other by at least one distinguishable property, and, in addition, the paints in the line of paints, the most different from each other, are characterized by at least different values of volume concentration pigment, differing from each other by at least 2%, or different values of the volumetric content of dry matter, differing from each other by at least 2%. 48. A set of different mutually compatible fluid semi-finished paints, sufficient to prepare at least one line of paints, acceptable for use in obtaining pigmented and transparent coatings, and this kit includes: (I) at least one prefabricated paint according to claims 1 to 3; (II) at least two latex polymer binder prefabricated paint, each of which is described in paragraph 14; moreover, the line of paints includes two or more different paints, the dried layers of which essentially differ from each other by at least one distinguishable property, and, in addition, the paints in the line of paints, the most different from each other, are characterized by at least different values the volume concentration of the pigment, differing from each other by at least 2%, or various values of the volume content of dry matter, differing from each other by at least 2%. 49. A set of different mutually compatible fluid semi-finished inks, sufficient to form at least one line of inks suitable for use in printing technology, and this set includes: (I) at least one prefabricated paint containing at least one latex polymer binder having a Tg from about -50 to about 10 ° C, characterized by a volumetric dry matter content of from about 25 to about 70% and a Brookfield viscosity of less than 100,000 cP at a shear rate of 1.25 s ^-1 ; (II) at least one prefabricated paint containing at least one latex polymer binder having a TC of from about 50 to about 140 ° C, characterized by a volumetric dry matter content of from about 25 to about 70% and a Brookfield viscosity of less than 100,000 cP at a shear rate of 1.25 s ^-1 ; and (III) optionally at least one prefabricated paint containing at least one latex polymer binder, a TC of from about 0 to about 65 ° C. characterized by a volumetric dry matter content of from about 25 to about 70% and a Brookfield viscosity of less than 100,000 centipoise at a shear rate of 1.25 s ^-1, wherein the paint line includes two or more different paints, the dried fibers are substantially different from each other by at least one distinguishable feature, and, in addition, the paint in the paint line, most e different from each other, characterized by at least different values of the pigment volume concentration different from each other by at least 2%, or different values of volume content of dry matter, distinguished from each other by at least 2%. 50. The prefabricated paint kit of claim 49, which further includes at least one additional prefabricated paint selected from the group consisting of a prefabricated paint containing at least one alkali-soluble resin, a prefabricated paint containing at least one gloss-adding additive, a prefabricated paints containing at least one wax, and at least one prefabricated paint containing at least one pigment dispersion. 51. A method of forming at least one line of paints, which comprises the following steps: (a) the preparation of a set of semi-finished paints according to paragraphs 48, 49 or 50, and (b) supplying a predetermined amount of each of the semi-finished paints to containers or applicators to form a line of paints.