JPS6399273A - Dip coating substrate material for paper product - Google Patents
Dip coating substrate material for paper productInfo
- Publication number
- JPS6399273A JPS6399273A JP24422886A JP24422886A JPS6399273A JP S6399273 A JPS6399273 A JP S6399273A JP 24422886 A JP24422886 A JP 24422886A JP 24422886 A JP24422886 A JP 24422886A JP S6399273 A JPS6399273 A JP S6399273A
- Authority
- JP
- Japan
- Prior art keywords
- base material
- paper
- water
- weight
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000463 material Substances 0.000 title claims abstract description 43
- 239000000758 substrate Substances 0.000 title abstract description 10
- 238000003618 dip coating Methods 0.000 title description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000000049 pigment Substances 0.000 claims abstract description 16
- 239000004606 Fillers/Extenders Substances 0.000 claims abstract description 11
- 239000000839 emulsion Substances 0.000 claims abstract description 9
- 239000011347 resin Substances 0.000 claims abstract description 8
- 229920005989 resin Polymers 0.000 claims abstract description 8
- 239000002562 thickening agent Substances 0.000 claims abstract description 8
- 239000007787 solid Substances 0.000 claims abstract description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract description 14
- 238000000576 coating method Methods 0.000 abstract description 12
- 239000011248 coating agent Substances 0.000 abstract description 11
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract description 7
- 239000004927 clay Substances 0.000 abstract description 5
- 229920000609 methyl cellulose Polymers 0.000 abstract description 5
- 239000001923 methylcellulose Substances 0.000 abstract description 5
- 235000010981 methylcellulose Nutrition 0.000 abstract description 5
- 239000004925 Acrylic resin Substances 0.000 abstract 1
- 229920000178 Acrylic resin Polymers 0.000 abstract 1
- 239000002245 particle Substances 0.000 description 10
- 239000004615 ingredient Substances 0.000 description 9
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- JGPMMRGNQUBGND-UHFFFAOYSA-N idebenone Chemical compound COC1=C(OC)C(=O)C(CCCCCCCCCCO)=C(C)C1=O JGPMMRGNQUBGND-UHFFFAOYSA-N 0.000 description 7
- 229960004135 idebenone Drugs 0.000 description 7
- 238000007789 sealing Methods 0.000 description 7
- 239000003973 paint Substances 0.000 description 6
- 229920000142 Sodium polycarboxylate Polymers 0.000 description 5
- 239000002518 antifoaming agent Substances 0.000 description 5
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 4
- 238000007665 sagging Methods 0.000 description 4
- 239000000454 talc Substances 0.000 description 4
- 229910052623 talc Inorganic materials 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000012752 auxiliary agent Substances 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- -1 Acrylic ester Chemical class 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 241000282376 Panthera tigris Species 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 235000003560 Valerianella locusta Nutrition 0.000 description 1
- 240000004668 Valerianella locusta Species 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/40—Coatings with pigments characterised by the pigments siliceous, e.g. clays
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/385—Oxides, hydroxides or carbonates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/52—Cellulose; Derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/58—Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
Abstract
Description
【発明の詳細な説明】
〈産業上の利用分野〉
本発明は紙用浸漬塗り下地材に関する。更に詳細には、
紙を基材とする製品に塗料を塗る場合に使用できる紙用
浸漬塗り下地材に関する。DETAILED DESCRIPTION OF THE INVENTION <Industrial Application Field> The present invention relates to dip-coated substrates for paper. More specifically,
This invention relates to a dip coating base material for paper that can be used when applying paint to paper-based products.
〈従来技術〉
従来から、張り子のダルマ、虎、人形等の紙製基材表面
を塗装するにあたっては、直接に塗料を適用すると基材
内部に塗料が浸入して良好な塗装表面を得ることができ
ないため、下地材を使用するのが通常である。このよう
な下地材としては、従来、ニカワ約１重量部、胡粉（貝
殻粉砕物から製造、炭酸カルシウムを主成分とする）約
４重量部及び湯約４〜６重量部を用い、塗装する場でニ
カワを湯に溶解し、これに胡粉等を混合して下地材とし
て使用していた。<Prior art> Conventionally, when painting the surface of paper base materials such as paper mache dolls, tigers, dolls, etc., it has been known that if paint is applied directly, the paint will penetrate into the inside of the base material, resulting in a good painted surface. Since this is not possible, a base material is usually used. Conventionally, as such a base material, about 1 part by weight of glue, about 4 parts by weight of gofun (manufactured from crushed seashells, mainly composed of calcium carbonate), and about 4 to 6 parts by weight of hot water are used. Glue was dissolved in hot water, mixed with white powder, etc., and used as a base material.
〈発明が解決しようとする問題点〉
しかしながら、このような従来法による下地材は、腐敗
抵抗性が無いために保存性が悪いこと、使用の都度調合
する必要があるため手間がががること、及び温度の低下
により固まるため、特に冬期には加熱しながら塗装する
必要があること等の欠点があった。<Problems to be solved by the invention> However, the base materials produced using such conventional methods have poor shelf life due to lack of rot resistance, and are time-consuming as they need to be prepared each time they are used. , and because it hardens as the temperature drops, it has disadvantages such as the need to apply it while heating, especially in the winter.
〈発明の目的〉
従って、本発明の目的は腐敗抵抗性が大きく長期間に渡
って品質が安定な紙用浸漬塗り下地材を提供することで
ある。OBJECTS OF THE INVENTION It is therefore an object of the present invention to provide a dip-coated substrate for paper that is highly rot resistant and of stable quality over a long period of time.
本発明の別の目的は、既調合品としての保管が可能であ
り、作業現場での成分調合の必要なく、使用できる紙用
浸漬塗り下地材を提供することである。Another object of the present invention is to provide a dip-coated base material for paper that can be stored as a ready-mixed product and used without the need for on-site mixing of ingredients.
本発明の更に別の目的は塗装時の加熱等の温度管理が不
要な紙用浸漬塗り下地材を提供することである。Still another object of the present invention is to provide a dip-coated base material for paper that does not require temperature control such as heating during coating.
本発明の更に別の目的は、仕」〕塗装後の仕上がりが著
しく向」ニする紙用浸漬塗り下地材を提供することであ
る。Yet another object of the present invention is to provide a dip-coated substrate for paper which has a significantly improved finish after coating.
本発明の別の目的は、紙製基材を浸漬し、次いで引上げ
るのみで良好な塗装の可能な紙用浸漬塗りの下地材を提
供することである。Another object of the present invention is to provide a dip coating base material for paper that can be coated well simply by dipping the paper substrate and then pulling it up.
〈発明の概要〉
本発明によれば、体質顔料１００重量部に対して、エマ
ルジョン樹脂を固形分として３〜２５重量部、増粘剤０
．０５〜０．５重量部及び水を含有し、粘度が１５０ｃ
ｐ〜１０００ｃｐであることを特徴とする紙用浸漬塗り
下地材が提供される。<Summary of the Invention> According to the present invention, 3 to 25 parts by weight of emulsion resin as solid content and 0 parts by weight of thickener for 100 parts by weight of extender pigment.
．． Contains 05 to 0.5 parts by weight and water, and has a viscosity of 150c
A dip coated substrate for paper is provided, characterized in that it has a p~1000 cp.
以下、本発明の詳細な説明する。The present invention will be explained in detail below.
〈発明の説明〉
本発明において使用できる体質顔料としては、炭酸カル
シウム、クレー、タルク、ジ−クライト。<Description of the Invention> Extender pigments that can be used in the present invention include calcium carbonate, clay, talc, and gicrite.
ベントナイト等の塗料業界で通常使用される体質顔料が
ある。このような体質顔料は紙材への着色と目止め、充
填のために使用されるものである。There are extender pigments commonly used in the paint industry such as bentonite. Such extender pigments are used for coloring, sealing, and filling paper materials.
本発明において使用できるエマルジョン樹脂としては、
アクリル酸エステル、メタアクリル酸エステル、エチレ
ン、酢酸ビニル、バーサチック酸ビニル、塩化ビニル、
塩化ビニリデン、アクリロニトリル、スチレン、マレイ
ン酸エステル、フマル酸エステル、アクリルアミド、メ
タクリルアミド、メタアクリロニトリル、ウレタン、エ
ポキシ等の単独重合物若しくは二種以上の共重合物、又
は二種以上の重合物の混合物がある。保護コロイドを使
用せずに乳化重合したものが好ましい。このようなエマ
ルジョン樹脂は１体質顔料等の固着及び紙材への下地材
の付着の作用をなす。使用するエマルジョン樹脂の量は
、上記体質顔料１００重量部に対して固形分として３〜
２５重量部、好ましくは５〜１５重量部である。固形分
として２５重量部より多いと、体質顔料の目止め及び充
填効果が低下し、また３重量部より少ないと下地材の強
度不足及び紙基剤への下地材の付着力の低下を招くので
好ましくない。Emulsion resins that can be used in the present invention include:
Acrylic ester, methacrylic ester, ethylene, vinyl acetate, vinyl versatate, vinyl chloride,
Homopolymers, copolymers of two or more, or mixtures of two or more polymers of vinylidene chloride, acrylonitrile, styrene, maleic esters, fumaric esters, acrylamide, methacrylamide, methacrylonitrile, urethane, epoxy, etc. be. It is preferable to use emulsion polymerization without using a protective colloid. Such an emulsion resin functions to fix the monolithic pigment and the like and to attach the base material to the paper material. The amount of emulsion resin used is 3 to 3 as solid content per 100 parts by weight of the extender pigment.
25 parts by weight, preferably 5 to 15 parts by weight. If the solid content is more than 25 parts by weight, the sealing and filling effect of the extender pigment will be reduced, and if it is less than 3 parts by weight, the strength of the base material will be insufficient and the adhesion of the base material to the paper base will be reduced. Undesirable.
本発明において使用できる増粘剤としては、メチルセル
ロース、ヒドロキシエチルセルロース。Thickeners that can be used in the present invention include methylcellulose and hydroxyethylcellulose.
カルボキシメチルセルロース、アルギン酸ソーダ。Carboxymethyl cellulose, sodium alginate.
ポリビニルアルコール等のアルカリ可溶及び膨潤型エマ
ルジョン等がある。増粘剤の添加により、顔料の沈降を
防止し、かつ浸漬塗装時の下地材のダレと素地紙材への
水分の浸透性を調整する。使用する増粘剤の量は、上記
体質顔料１００重量部に対して０．０５〜０．５重量部
、好ましくは０．１〜０．３重量部である。増粘剤量が
０．５重量部を越えると塗装時のダレが激しくなり、０
．０５重量部より少ないと顔料が沈降するので好ましく
ない。There are alkali-soluble and swelling emulsions such as polyvinyl alcohol. The addition of a thickener prevents the pigment from settling and adjusts the sag of the base material during dip coating and the permeability of water into the base paper material. The amount of the thickener used is 0.05 to 0.5 parts by weight, preferably 0.1 to 0.3 parts by weight, based on 100 parts by weight of the extender pigment. If the amount of thickener exceeds 0.5 parts by weight, sagging during painting will become severe, and
．． If the amount is less than 0.5 parts by weight, the pigment will settle, which is not preferable.
本発明の紙使用浸漬塗り下地材においては、希釈剤及び
溶剤として水を使用する。水の添加により、下地材の粘
度が温度２０’ＣにおいてＢ型粘度計で回Ｕ２０ＲＰＭ
で測定した場合に、１５０〜１０００ｃｐになることが
必須である。粘度が１５０ｃｐ未満だと下地剤の目止め
効果が不充分であり。Water is used as a diluent and solvent in the paper dip coated substrate of the present invention. The addition of water increases the viscosity of the substrate by U20 RPM on a Type B viscometer at a temperature of 20'C.
It is essential that it be 150 to 1000 cp when measured at If the viscosity is less than 150 cp, the sealing effect of the primer will be insufficient.
逆に１０００ｃｐを越えると塗装効率が低下し、また塗
膜が厚くなるので亀裂が入りやすくなり、かつ不経済で
ある。On the other hand, if it exceeds 1000 cp, the coating efficiency decreases, and the coating film becomes thicker, making it more prone to cracking and being uneconomical.
本発明の下地材においては、上記の成分の他に、更に分
散剤（例えばポリカルボン酸ソーダ等）、造膜助剤、防
腐剤、防カビ剤、消泡剤（例えば鉱物油系消泡剤等）、
着色顔料等の水系塗料に通常使用される助剤を添加して
もよい。In addition to the above-mentioned components, the base material of the present invention further includes a dispersant (for example, sodium polycarboxylate, etc.), a film-forming aid, a preservative, a fungicide, and an antifoaming agent (for example, a mineral oil-based antifoaming agent). etc),
Auxiliary agents commonly used in water-based paints such as colored pigments may be added.
本発明の紙用浸漬塗り下地材は、最初に体質顔料及び水
、更に必要に応じて分散剤等を公知の攪拌器にて最初に
攪拌して顔料スラリーを製造し、攪拌しなから増粘剤、
エマルジョン樹脂及び必要に応じた助剤を添加し、最後
に水により粘度を１５０〜１０００ ｃｐに調整するこ
とにより製造できる。The dip coating base material for paper of the present invention is prepared by first stirring the extender pigment and water, and if necessary, a dispersant, etc. using a known stirrer to produce a pigment slurry, and then thickening it without stirring. agent,
It can be produced by adding an emulsion resin and an auxiliary agent as necessary, and finally adjusting the viscosity to 150 to 1000 cp with water.
本発明の紙用浸漬塗り下地材は、予め水分量の少ない調
合品を製造しておき、塗装作業時に水希釈しても使用で
きる。希釈する水の量は、最終的に下地材の粘度が１５
０〜１０００ ｃｐとなる量であればよい。The paper dip-coating base material of the present invention can be used by preparing a formulation with a low water content in advance and diluting it with water during the coating process. The amount of water to be diluted is determined until the final viscosity of the base material is 15.
The amount may be 0 to 1000 cp.
本発明の紙用浸漬塗り下地材を紙基材に塗装するにあた
っては、被塗面が下地材に接触しさえすればよく、特に
下地材中に滞留させなくてもよい。When applying the dip coating base material for paper of the present invention to a paper base material, it is only necessary that the surface to be coated comes into contact with the base material, and there is no particular need for it to remain in the base material.
また被塗面の３／４〜２／３程度を下地材に浸漬した後
に引上げ、浸漬部分を上にして過剰に塗布された下地材
のダレによって残り部分を塗装してもよい。Alternatively, approximately 3/4 to 2/3 of the surface to be coated may be dipped in the base material, then pulled up, and the remaining portion may be painted with the dipped portion facing up and the excessively applied base material sag.
〈発明の効果〉
本発明による紙用浸漬塗り下地材は、腐敗抵抗性が高く
、従って保存性に極めて優れ１作業現場での成分調合及
び加熱による温度管理が不要なので作業性も良好である
。更に、本発明の紙用浸漬塗り下地材を使用することに
より仕上げ塗装後の仕上がりも著しく向上する。<Effects of the Invention> The dip-coated base material for paper according to the present invention has high rot resistance, and therefore has excellent preservability, and has good workability because it does not require component mixing or temperature control by heating at the work site. Furthermore, by using the paper dip coating base material of the present invention, the finish after finishing coating is also significantly improved.
〈実施例〉 以下、実施例により本発明を更に具体的に説明する。<Example> Hereinafter, the present invention will be explained in more detail with reference to Examples.
ヌ遣ｆｉｌ
以下の成分からなる紙用浸漬下地材をディスパーを用い
て製造した。A dipping base material for paper consisting of the following ingredients was produced using a disper.
成 分 重量部炭
酸カルシウム粉末 ５０（平均粒径５〜
９ミクロン）
クレー（平均粒径１ｏミクロン）１０
タルク（平均粒径１０ミクロン）１０
アクリロニトリル・スチレンの −５０％エルマ
ジョン １５（大日本インキ■製、商品
名ボンゴート５４１０）メチルセルロース
０．１（信越化学（＃ｌ製、商品名メトローズ
９０Ｓ）１３００００）ポリカルボン酸ソーダ
０．２（日本アクリルｍｉｓ、商品名プライア
ル８５０）鉱物油系消泡剤 ０．
２（Ｍ電化＠製、商品名アデカネートＢ−１８７）水
１４．５
上記の如くして製造した本発明による紙用浸漬塗り下地
材に更に２０重量部の水を添加して、温度２０℃１回転
数２ＯＲＰＭにてＢ型粘度計で粘度測定したところ６０
０ｃｐであった。この下地材を用いて、ダルマの紙製基
材の浸漬塗りを行なった。下地塗装後のダルマはダレの
度合い、目止め効果が良好であった。このダルマを２０
℃にて１日乾燥した後、ラッカー系ダルマ用塗料（島田
商店、商品名ダルマコート）で仕上げ塗りを行なったと
ころ、肌合い及び強度共に良好であった。Ingredients Part by weight Calcium carbonate powder 50 (average particle size 5~
9 microns) Clay (average particle size 10 microns) 10 Talc (average particle size 10 microns) 10 -50% Elumasion of acrylonitrile/styrene 15 (manufactured by Dainippon Ink ■, trade name Bongoat 5410) Methyl cellulose
0.1 (Shin-Etsu Chemical (manufactured by #l, trade name Metrose 90S) 130000) Sodium polycarboxylate
0.2 (Japan Acrylic Mis, trade name Prial 850) Mineral oil-based antifoaming agent 0.
2 (manufactured by M Denka@, product name Adekaneto B-187) water
14.5
Further, 20 parts by weight of water was added to the dip-coated base material for paper according to the present invention produced as described above, and the viscosity was measured using a B-type viscometer at a temperature of 20° C. and a rotation speed of 2 ORPM.
It was 0 cp. This base material was used to dip-coat a Daruma paper base material. The degree of sagging and sealing effect of Daruma after base coating were good. This dharma is 20
After drying at ℃ for one day, a finishing coat was applied with a lacquer-based Daruma paint (trade name: Daruma Coat, manufactured by Shimada Shoten), and the texture and strength were both good.
失庭銖ｌ
以下の成分を実施例１と同様の攪拌器を使用して、本発
明による紙用浸漬塗り下地材を製造した。A dip-coated base material for paper according to the present invention was prepared using the following ingredients using the same stirrer as in Example 1.
成 分 重量部重質炭酸カル
シウム ４５（平均粒径５〜９ミクロン
）
クレー（平均粒径１０ミクロン） １０タルク（
平均粒径１０ミクロン） ５アクリロニトリル・
スチレンの
５０％エルマジョン １０（大日本イン
キ■製、商品名ボンゴート５４１０）メチルセルロース
０．０７（信越化学■製、商品名
メトローズ９０ＳＨ３００００）ポリカルボン酸ソーダ
０．２（日本アクリル■製、商品名プ
ライアル８５０）消泡剤
０・１（旭電化曲製、商品名アデカネートＢ−１８７
）水
３０製造した下地材の粘度を実施例１と同様の方法で粘
度測定を行なったところ６００ｃｐ（２０℃。Ingredients Parts by weight Heavy calcium carbonate 45 (average particle size 5-9 microns) Clay (average particle size 10 microns) 10 Talc (
Average particle size: 10 microns) 5 Acrylonitrile
50% styrene Eluma John 10 (manufactured by Dainippon Ink ■, trade name Bongoat 5410) Methyl cellulose 0.07 (manufactured by Shin-Etsu Chemical ■, trade name Metrose 90SH30000) Sodium polycarboxylate 0.2 (manufactured by Nippon Acrylic ■, trade name Prial) 850) Antifoaming agent
0.1 (manufactured by Asahi Denka Kyoku, product name Adekaneto B-187
)water
The viscosity of the prepared base material was measured in the same manner as in Example 1 and found to be 600 cp (at 20°C).
Ｂ型粘度計２ＯＲＰＭ）であった。次いで、水希釈を行
なわない以外は実施例１と同様にして浸漬塗りを行なっ
たが、下地塗装後のダルマはダレの度合い、目止め効果
とも良好であり、また仕上げ塗り後の肌合い１強度とも
優れていた。B type viscometer 2ORPM). Next, dip coating was carried out in the same manner as in Example 1 except that water dilution was not performed, but Daruma after the base coating had good sag and sealing effect, and also had a good texture and strength after the final coating. It was excellent.
失席■主
以下の成分を実施例１と同様の攪拌器を使用して１本発
明による紙用浸漬塗り下地材を製造した。1 A dip-coated base material for paper according to the present invention was prepared using the same stirrer as in Example 1 using the following ingredients.
成 分 重量部重質炭酸カルシ
ウム ７５（平均粒径１０〜１５ミクロ
ン）
アクリロニトリル・スチレンの
５０％エルマジョン １２（大日本イン
キ■製、商品名ボンボート５４１０）メチルセルロース
０．３（信越化学■製、商品名
メトローズ９０ＳＨ３００００）ポリカルボン酸ソーダ
０．２（日本アクリル曲製、商品名プ
ライアル８５０）消泡剤
０．１（加電化■製、商品名アデカネートＢ−１８７
）水
１２．４製造した下地材に更に３０重量部の水を加えて
希釈し、その粘度を実施例１と同様の方法で粘度測定を
行なったところ３００ｃｐ（２０℃、Ｂ型粘度計２ＯＲ
ＰＭ）であった。次いで、実施例１と同様にして浸漬塗
りを行なったが、下地塗装後のダルマはダレの度合い、
目止め効果とも良好であり、また仕上げ塗り後の肌合い
、強度とも優れていた。Ingredients Parts by weight Heavy calcium carbonate 75 (average particle size 10-15 microns) 50% acrylonitrile/styrene Elumasion 12 (manufactured by Dainippon Ink ■, product name: Bomboto 5410) Methyl cellulose 0.3 (manufactured by Shin-Etsu Chemical ■, product Name Metrose 90SH30000) Sodium polycarboxylate 0.2 (Nippon Acrylic Kyokusei, trade name Prial 850) Antifoaming agent
0.1 (manufactured by Kadenka ■, product name: Adekanate B-187
)water
12.4 The produced base material was further diluted with 30 parts by weight of water, and its viscosity was measured in the same manner as in Example 1.
PM). Next, dip coating was carried out in the same manner as in Example 1, but the degree of sagging of Daruma after the base coating was
The sealing effect was good, and the texture and strength after finishing were also excellent.
去」１」乞
以下の成分を実施例１と同様の攪拌器を使用して１本発
明による紙用浸漬塗り下地材を製造した。A dip-coated base material for paper according to the present invention was prepared using the same stirrer as in Example 1 using the following ingredients.
成 分 重量部重質炭酸カル
シウム ５０（平均粒径５〜９ミクロン
）
クレー（平均粒径１０ミクロン） １０タルク（
平均粒径１０ミクロン＞ １０酢ピロ５エマルジ
ヨン １１・５（日本カーバイト開裂、商
品名二カゾールＰＬ６６８）１０％ポリビニルアルコー
ル水溶液 １．５（クラレ■製、商品名ＰＴＡ−２
１７）ポリカルボン酸ソーダ ０．２（
日本アクリル銖製、商品名プライアル８５０）水
１６．８
製造した下地材に更に３０重量部の水を加えて希釈し、
その粘度を実施例１と同様の方法で粘度測定を行なった
ところ７００ｃｐ（２０℃、Ｂ型粘度計２ＯＲＰＭ）で
あった０次いで、水希釈を行なわない以外は実施例１と
同様にして浸漬塗りを行なったが、下地塗装後のダルマ
はダレの度合１１、目止め効果とも良好であり、また仕
りげ塗り後の肌合い、強度とも優れていた。Ingredients Parts by weight Heavy calcium carbonate 50 (average particle size 5-9 microns) Clay (average particle size 10 microns) 10 Talc (
Average particle size: 10 microns
17) Sodium polycarboxylate 0.2 (
Made by Nippon Acrylic Co., Ltd., product name Prial 850) Water
16.8
Add 30 parts by weight of water to the prepared base material to dilute it,
The viscosity was measured in the same manner as in Example 1 and found to be 700 cp (20°C, B-type viscometer 2ORPM).Next, dip coating was carried out in the same manner as in Example 1 except that dilution with water was not performed. After the base coating, Daruma had a sagging degree of 11 and a good sealing effect, and was also excellent in texture and strength after the finishing coat.
Claims (1)
形分として３〜２５重量部、増粘剤０．０５〜０．５重
量部及び水を含有し、粘度が１５０ｃｐ〜１０００ｃｐ
であることを特徴とする紙用浸漬塗り下地材。Contains 3 to 25 parts by weight of emulsion resin as solid content, 0.05 to 0.5 parts by weight of thickener, and water with respect to 100 parts by weight of extender pigment, and has a viscosity of 150 cp to 1000 cp.
A dip-coated base material for paper, characterized by:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP24422886A JPS6399273A (en) | 1986-10-16 | 1986-10-16 | Dip coating substrate material for paper product |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP24422886A JPS6399273A (en) | 1986-10-16 | 1986-10-16 | Dip coating substrate material for paper product |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6399273A true JPS6399273A (en) | 1988-04-30 |
Family
ID=17115645
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP24422886A Pending JPS6399273A (en) | 1986-10-16 | 1986-10-16 | Dip coating substrate material for paper product |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6399273A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5872162A (en) * | 1993-06-04 | 1999-02-16 | The Gillette Company | Correction fluid for water-fast inks |
| US5922400A (en) * | 1997-01-09 | 1999-07-13 | The Gillette Company | Correction fluid |
| KR100375888B1 (en) * | 2000-08-01 | 2003-03-15 | 이석기 | A method for preparation of water borne coating contained water swellable clay |
| JP2019209673A (en) * | 2018-05-30 | 2019-12-12 | 株式会社偕拓堂アート | Inkjet receiving layer for silk sheet |
-
1986
- 1986-10-16 JP JP24422886A patent/JPS6399273A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5872162A (en) * | 1993-06-04 | 1999-02-16 | The Gillette Company | Correction fluid for water-fast inks |
| US5922400A (en) * | 1997-01-09 | 1999-07-13 | The Gillette Company | Correction fluid |
| KR100375888B1 (en) * | 2000-08-01 | 2003-03-15 | 이석기 | A method for preparation of water borne coating contained water swellable clay |
| JP2019209673A (en) * | 2018-05-30 | 2019-12-12 | 株式会社偕拓堂アート | Inkjet receiving layer for silk sheet |
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