JP2004526022A - 顆粒状重合体添加剤およびこれの製造 - Google Patents
顆粒状重合体添加剤およびこれの製造 Download PDFInfo
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- JP2004526022A JP2004526022A JP2002568628A JP2002568628A JP2004526022A JP 2004526022 A JP2004526022 A JP 2004526022A JP 2002568628 A JP2002568628 A JP 2002568628A JP 2002568628 A JP2002568628 A JP 2002568628A JP 2004526022 A JP2004526022 A JP 2004526022A
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- phosphite
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- 239000000654 additive Substances 0.000 title claims abstract description 90
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- 230000000996 additive effect Effects 0.000 title claims abstract description 50
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- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims abstract description 45
- 238000001035 drying Methods 0.000 claims abstract description 35
- 238000004807 desolvation Methods 0.000 claims abstract description 30
- XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical class OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 claims abstract description 28
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 claims abstract description 19
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- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical group CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 claims description 14
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- 235000010234 sodium benzoate Nutrition 0.000 claims description 6
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- YWEWWNPYDDHZDI-JJKKTNRVSA-N (1r)-1-[(4r,4ar,8as)-2,6-bis(3,4-dimethylphenyl)-4,4a,8,8a-tetrahydro-[1,3]dioxino[5,4-d][1,3]dioxin-4-yl]ethane-1,2-diol Chemical compound C1=C(C)C(C)=CC=C1C1O[C@H]2[C@@H]([C@H](O)CO)OC(C=3C=C(C)C(C)=CC=3)O[C@H]2CO1 YWEWWNPYDDHZDI-JJKKTNRVSA-N 0.000 claims description 5
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- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 claims description 5
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- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 25
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- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 4
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- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
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- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 description 2
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- 239000012963 UV stabilizer Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- QANIADJLTJYOFI-UHFFFAOYSA-K aluminum;magnesium;carbonate;hydroxide;hydrate Chemical compound O.[OH-].[Mg+2].[Al+3].[O-]C([O-])=O QANIADJLTJYOFI-UHFFFAOYSA-K 0.000 description 1
- 235000019826 ammonium polyphosphate Nutrition 0.000 description 1
- 229920001276 ammonium polyphosphate Polymers 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 150000007514 bases Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- GOJOVSYIGHASEI-UHFFFAOYSA-N bis(2,2,6,6-tetramethylpiperidin-4-yl) butanedioate Chemical class C1C(C)(C)NC(C)(C)CC1OC(=O)CCC(=O)OC1CC(C)(C)NC(C)(C)C1 GOJOVSYIGHASEI-UHFFFAOYSA-N 0.000 description 1
- XITRBUPOXXBIJN-UHFFFAOYSA-N bis(2,2,6,6-tetramethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)NC(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)NC(C)(C)C1 XITRBUPOXXBIJN-UHFFFAOYSA-N 0.000 description 1
- ZEFSGHVBJCEKAZ-UHFFFAOYSA-N bis(2,4-ditert-butyl-6-methylphenyl) ethyl phosphite Chemical compound CC=1C=C(C(C)(C)C)C=C(C(C)(C)C)C=1OP(OCC)OC1=C(C)C=C(C(C)(C)C)C=C1C(C)(C)C ZEFSGHVBJCEKAZ-UHFFFAOYSA-N 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- IZZJTKBRMQJYLA-UHFFFAOYSA-N chloro-(2,6-ditert-butyl-4-methylphenoxy)-phenylphosphane Chemical compound CC(C)(C)C1=CC(C)=CC(C(C)(C)C)=C1OP(Cl)C1=CC=CC=C1 IZZJTKBRMQJYLA-UHFFFAOYSA-N 0.000 description 1
- 238000007596 consolidation process Methods 0.000 description 1
- 150000001924 cycloalkanes Chemical class 0.000 description 1
- 150000001925 cycloalkenes Chemical class 0.000 description 1
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical class O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 235000012438 extruded product Nutrition 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000013538 functional additive Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- CAYGQBVSOZLICD-UHFFFAOYSA-N hexabromobenzene Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1Br CAYGQBVSOZLICD-UHFFFAOYSA-N 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 235000012149 noodles Nutrition 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- SMNZOWVTUJGGRR-UHFFFAOYSA-N octyl 3,5-ditert-butyl-4-hydroxybenzoate Chemical compound CCCCCCCCOC(=O)C1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SMNZOWVTUJGGRR-UHFFFAOYSA-N 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- OLLJGCZRRIRNSZ-UHFFFAOYSA-N phenyl-(2,4,6-tritert-butylphenoxy)phosphinous acid Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC(C(C)(C)C)=C1OP(O)C1=CC=CC=C1 OLLJGCZRRIRNSZ-UHFFFAOYSA-N 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- KYKFCSHPTAVNJD-UHFFFAOYSA-L sodium adipate Chemical compound [Na+].[Na+].[O-]C(=O)CCCCC([O-])=O KYKFCSHPTAVNJD-UHFFFAOYSA-L 0.000 description 1
- 239000001601 sodium adipate Substances 0.000 description 1
- 235000011049 sodium adipate Nutrition 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- ZHROMWXOTYBIMF-UHFFFAOYSA-M sodium;1,3,7,9-tetratert-butyl-11-oxido-5h-benzo[d][1,3,2]benzodioxaphosphocine 11-oxide Chemical compound [Na+].C1C2=CC(C(C)(C)C)=CC(C(C)(C)C)=C2OP([O-])(=O)OC2=C1C=C(C(C)(C)C)C=C2C(C)(C)C ZHROMWXOTYBIMF-UHFFFAOYSA-M 0.000 description 1
- YZVPCEILOYFXGI-UHFFFAOYSA-M sodium;2,2-diphenylacetate Chemical compound [Na+].C=1C=CC=CC=1C(C(=O)[O-])C1=CC=CC=C1 YZVPCEILOYFXGI-UHFFFAOYSA-M 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000000844 transformation Methods 0.000 description 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
- NSBGJRFJIJFMGW-UHFFFAOYSA-N trisodium;stiborate Chemical compound [Na+].[Na+].[Na+].[O-][Sb]([O-])([O-])=O NSBGJRFJIJFMGW-UHFFFAOYSA-N 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2/00—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
- B01J2/28—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic using special binding agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/524—Esters of phosphorous acids, e.g. of H3PO3
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/792,190 US6515052B2 (en) | 2001-02-23 | 2001-02-23 | Granular polymer additives and their preparation |
| PCT/US2002/004637 WO2002068524A1 (en) | 2001-02-23 | 2002-02-15 | Granular polymer additives and their preparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2004526022A true JP2004526022A (ja) | 2004-08-26 |
| JP2004526022A5 JP2004526022A5 (https=) | 2005-12-22 |
Family
ID=25156072
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002568628A Pending JP2004526022A (ja) | 2001-02-23 | 2002-02-15 | 顆粒状重合体添加剤およびこれの製造 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6515052B2 (https=) |
| EP (1) | EP1383833A1 (https=) |
| JP (1) | JP2004526022A (https=) |
| KR (1) | KR20030084946A (https=) |
| CN (1) | CN1492903A (https=) |
| CA (1) | CA2438894A1 (https=) |
| TW (1) | TW570972B (https=) |
| WO (1) | WO2002068524A1 (https=) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6056898A (en) * | 1998-09-22 | 2000-05-02 | Albemarle Corporation | Low dust balanced hardness antioxidant pellets and process for the production of same |
| US6821456B2 (en) * | 1998-09-22 | 2004-11-23 | Albemarle Corporation | Granular polymer additives and their preparation |
| DE10241375A1 (de) * | 2002-09-06 | 2004-03-18 | Clariant Gmbh | Granulare Flammschutzmittelzusammensetzung |
| US7667066B2 (en) * | 2004-02-27 | 2010-02-23 | Albemarle Corporation | Preparation of sterically hindered hydroxyphenylcarboxylic acid esters |
| CN1331928C (zh) * | 2004-11-19 | 2007-08-15 | 中国石油天然气集团公司 | 塑料加工用颗粒化抗氧剂的制备方法 |
| SG132634A1 (en) * | 2005-12-02 | 2007-06-28 | Sumitomo Chemical Co | Process for producing granules |
| CA2648646C (en) * | 2006-04-21 | 2012-04-24 | Ingenia Polymers Corp. | Liquid compositions of polymer additives and method for their preparation |
| WO2008033410A1 (en) * | 2006-09-14 | 2008-03-20 | Ingenia Polymers Inc. | High concentration pelletized additive concentrates for polymer |
| CA2683082A1 (en) * | 2007-04-19 | 2008-10-30 | Sru Biosystems, Inc. | Method for employing a biosensor to detect small molecules that bind directly to immobilized targets |
| JP5743327B2 (ja) | 2008-12-12 | 2015-07-01 | インジェニア・ポリマーズ・インコーポレイテッドＩｎｇｅｎｉａ Ｐｏｌｙｍｅｒｓ， Ｉｎｃ． | ポリマー用の圧縮ペレット化添加剤ブレンド |
| AU2013225065B2 (en) * | 2012-03-02 | 2016-05-12 | Basf Se | Emulsifiable granule obtainable by mixing an pesticidal emulsion with solid dispersant and extruding the resulting paste |
| CN103709439B (zh) * | 2012-09-29 | 2016-01-13 | 中国石油化工股份有限公司 | 防老剂组合物及其制备方法和苯乙烯系热塑性弹性体及其制备方法 |
| US9630349B2 (en) | 2013-08-26 | 2017-04-25 | Ingenia Polymers, Inc. | Compacted pelletized additive blends containing a polymer carrier |
| WO2015032033A1 (zh) * | 2013-09-03 | 2015-03-12 | 中国科学院化学研究所 | 一种为聚合物提供热稳定性的组合物及其应用 |
| CN104212034B (zh) * | 2014-09-04 | 2016-08-24 | 广州索润环保科技有限公司 | 一种无载体塑料母粒及其制备方法和应用 |
| EP3578599A1 (en) | 2018-06-08 | 2019-12-11 | Cytec Industries Inc. | Granular stabilizer compositions for use in polymer resins and methods of making same |
| CN111825916A (zh) * | 2019-04-15 | 2020-10-27 | 呈和科技股份有限公司 | 一种复合助剂及其制备方法 |
| GB2591482A (en) | 2020-01-29 | 2021-08-04 | Si Group Switzerland Chaa Gmbh | Non-dust blend |
Family Cites Families (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4111909A (en) * | 1977-04-11 | 1978-09-05 | Celanese Polymer Specialties Company | Controlled reactivity epoxy resin compositions |
| US4443572A (en) | 1982-09-22 | 1984-04-17 | Phillips Petroleum Company | Polyolefin stabilizers |
| US5190579A (en) | 1985-02-15 | 1993-03-02 | Eastman Kodak Company | Aqueous additive systems, methods and polymeric particles |
| DE3876110T2 (de) * | 1987-02-13 | 1993-05-27 | Enichem Sintesi | Feste stabilisatormischung fuer organische polymere und verfahren zu ihrer herstellung. |
| US4764428A (en) | 1987-05-29 | 1988-08-16 | Witco Chemical Corporation | Free-flowing, non-dusting antistatic agent composition pellets and method of forming same |
| US4929654A (en) | 1988-10-04 | 1990-05-29 | Eastman Kodak Company | Cyclic phosphites and stabilized polymeric compositions |
| US4956406A (en) | 1989-08-03 | 1990-09-11 | Eastman Kodak Company | Bis-cyclic phosphite compounds and polymeric materials stabilized therewith |
| US5153029A (en) | 1989-08-11 | 1992-10-06 | Eastman Kodak Company | Solid-form additive systems dispersible in aqueous media, methods for the preparation and application thereof to polymeric particles |
| JPH0692529B2 (ja) | 1989-12-28 | 1994-11-16 | 日本ジーイープラスチックス株式会社 | 芳香族系ポリカーボネートの製造方法 |
| IT1247941B (it) | 1991-05-17 | 1995-01-05 | Enichem Sintesi | Processo per l'ottenimento di forme granulari di additivi per polimeri organici |
| US5358560A (en) | 1991-10-04 | 1994-10-25 | Eastman Chemical Company | Solid-form additive systems dispersible in aqueous media and method for their preparation |
| IT1260530B (it) | 1992-06-04 | 1996-04-09 | Enichem Sintesi | Miscele solide di stabilizzanti per polimeri |
| ATE156706T1 (de) * | 1993-03-17 | 1997-08-15 | Silica Gel Gmbh | Superparamagnetische teilchen, verfahren zu ihrer herstellung und verwendung derselben |
| US5844042A (en) | 1993-04-06 | 1998-12-01 | Great Lakes Chemical Italia S.R.L. | Process for obtaining granular forms of additives for organic polymers |
| US5614571A (en) * | 1994-09-16 | 1997-03-25 | General Electric Company | Stabilizer blend containing phosphite |
| US6033600A (en) | 1994-10-07 | 2000-03-07 | General Electric Company | Reduced dust stabilizer blends compact and a method for making thereof |
| US5468895A (en) * | 1994-10-19 | 1995-11-21 | General Electric Company | Amine stabilized amorphous phosphite |
| US5597857A (en) | 1994-12-28 | 1997-01-28 | Ciba-Geigy Corporation | Low-dust granules of plastic additives |
| EP0719824B1 (en) * | 1994-12-28 | 2001-06-27 | Ciba SC Holding AG | Low-dust granules of plastic additives |
| AR003526A1 (es) | 1995-09-08 | 1998-08-05 | Mallinckrodt Chemical Inc | Sistema estabilizador para estabilizar materiales polimeros y metodo para producir un sistema estabilizado en forma de pellets. |
| US5844027A (en) | 1996-05-03 | 1998-12-01 | Ciba Specialty Chemicals Corporation | Stabilizer composition for thermoplastic materials |
| DE19627258C2 (de) | 1996-07-08 | 2001-04-12 | Chemson Polymer Additive | Verfahren zur Herstellung einer schmelzbaren Stabilisatorkombination |
| US5773503A (en) | 1996-12-11 | 1998-06-30 | Luzenac America, Inc. | Compacted mineral filler pellet and method for making the same |
| US6077890A (en) | 1997-12-04 | 2000-06-20 | Kimberly-Clark Worldwide, Inc. | Stabilizer formulation for thermoplastic polymers |
| US6126862A (en) | 1998-12-02 | 2000-10-03 | Ablemarle Corporation | Low dust balanced hardness antioxidant agglomerates and process for the production of same |
| US6126863A (en) | 1998-12-02 | 2000-10-03 | Albemarle Corporation | Low dust balanced hardness antioxidant agglomerates and process for the production of same |
| US6056898A (en) | 1998-09-22 | 2000-05-02 | Albemarle Corporation | Low dust balanced hardness antioxidant pellets and process for the production of same |
| WO2001070869A2 (en) * | 2000-03-20 | 2001-09-27 | Albemarle Corporation | Sterically hindered phenol antioxidant granules having balanced hardness |
-
2001
- 2001-02-23 US US09/792,190 patent/US6515052B2/en not_active Expired - Fee Related
-
2002
- 2002-02-15 KR KR10-2003-7011102A patent/KR20030084946A/ko not_active Abandoned
- 2002-02-15 WO PCT/US2002/004637 patent/WO2002068524A1/en not_active Ceased
- 2002-02-15 CA CA002438894A patent/CA2438894A1/en not_active Abandoned
- 2002-02-15 JP JP2002568628A patent/JP2004526022A/ja active Pending
- 2002-02-15 CN CNA028054636A patent/CN1492903A/zh active Pending
- 2002-02-15 EP EP02717445A patent/EP1383833A1/en not_active Withdrawn
- 2002-02-20 TW TW091102888A patent/TW570972B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| EP1383833A1 (en) | 2004-01-28 |
| WO2002068524A1 (en) | 2002-09-06 |
| KR20030084946A (ko) | 2003-11-01 |
| US20020117651A1 (en) | 2002-08-29 |
| CN1492903A (zh) | 2004-04-28 |
| CA2438894A1 (en) | 2002-09-06 |
| TW570972B (en) | 2004-01-11 |
| US6515052B2 (en) | 2003-02-04 |
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